Patent Application
20230170555
The present invention relates to means for connecting an electrochemical cell to an external device, and methods for the production of such means.
A thin film electrochemical cell typically comprises a stack of layers supported on a substrate and arranged in the following order: a first electrode layer proximal to the substrate, an electrolyte layer, a second electrode layer, and a current collector layer distal from the substrate. The stack of layers is generally covered by an encapsulating layer, which serves to help shield the stack of layers from atmospheric constituents such as moisture and/or oxygen.
Other layers may be present in the electrochemical cell: for example, an electrically-insulating passivation layer may be provided between the current collector layer and the encapsulating layer, and/or a further current collector may be provided between the substrate and the first electrode layer.
In certain cases, the electrochemical cell is a solid state cell, that is, the electrolyte layer is provided by a solid state electrolyte. In other cases, the electrolyte layer may comprise a porous separator that is impregnated with a liquid or polymer electrolyte.
In certain cases, the electrochemical cell may be a rechargeable cell, also known as a secondary cell. In such cases, the cell may be a lithium-ion cell, in which at least one of the first electrode layer, the second electrode layer and the electrolyte layer is provided by a lithium-containing compound, and the process of charging and discharging the cell involves the migration of lithium ions between the two electrodes.
In the case that the electrochemical cell is a lithium-ion cell, one of the first and second electrode layers may be provided by a layer of lithium and may be first formed during the initial charging cycle of the cell.
In order to connect the electrochemical cell to an external device, it is necessary to provide an electrical connection between the first electrode and the device, and a further electrical connection between the second electrode and the device.
In the case that a further current collector layer is present between the substrate and the first electrode layer, the further current collector layer may have a portion that remains uncovered by the encapsulating layer, to provide a contact pad that allows connection of the further current collector layer to the external device. In other cases, the substrate may be electrically conductive, thus allowing an electrical connection between the first electrode and the external device to be provided via the substrate.
In general, the current collector layer that is distal from the substrate has a region that remains uncovered by the encapsulating layer, so as to allow connection of that current collector layer to the external device, to complete an electrical circuit comprising the cell and the device.
It is desirable to configure the cell so that a reliable connection may be formed between the external device and the current collector layer that is distal to the substrate.
In certain cases, it has been attempted to provide an electrically-conductive track layer over the outer surface of the encapsulation layer, such a track layer serving to provide a conductive path between the substrate and the uncovered portion of the current collector layer that is distal to the substrate. In such cases, the track layer may allow a further contact pad to be provided on the substrate, so as to allow an electrical connection to be provided between the current collector that is distal to the substrate and an external device. However, it is thought that such a track layer may not be sufficiently mechanically robust to withstand changes in the thickness of the first and/or second electrode layers that occur as a result of the migration of charged species (such as lithium ions) during operation of the cell. In the case that the cell is a secondary cell, the first and/or second electrode layers may undergo multiple cycles of swelling and contraction, as the cell is alternately charged and discharged.
Other techniques to make the required electric connection between the current collector layer that is distal to the substrate and the external device have been attempted, such as wire-bonding of a conductive element to the exposed portion of the current collector layer. However, it is thought that in such cases, reaction products may be formed at the exposed surface of the current collector layer during operation of the cell. These reaction products have been found to impede the bonding between the wire and the current collector layer, such that electrical contact may be lost after only a few cycles of the cell. It is thought that the formation of these reaction products may be due to diffusion of species from the first electrode layer, the second electrode layer and/or the electrolyte layer towards the exposed surface of the current collector layer that is distal to the substrate.
In a first aspect, the present invention may provide an electrochemical cell comprising at least the following layers stacked in the following order:
In certain cases, the contact pad is configured to allow wire-bonding of a conductive element to provide electric connection of the current collector layer to an external device. However, in other cases, the contact pad may be configured to allow electrical connection to the external device to be provided through other means, such as reflow soldering or the provision of conductive epoxy or conductive ink.
It is thought that by providing a contact pad that is displaced from the current collector layer, the extent of diffusion of species from the first electrode layer, the second electrode layer and/or the electrolyte layer to the contact pad may be reduced. This is thought to help prevent the formation of reaction products at the contact pad, which are thought to impede the bonding required to connect the cell to an external device.
Typically at least a portion of the electrically-conductive pathway extends in a direction that is not perpendicular to the face of the current collector layer.
In general, at least a portion of the electrically-conductive pathway is oriented at an angle of 80° or less relative to the face of the current collector layer. In certain cases, at least a portion of the electrically-conductive pathway is oriented at an angle of 50° or less relative to the face of the current collector layer. In certain cases, at least a portion of the electrically-conductive pathway is aligned with the face of the current collector layer.
Typically, the contact pad is offset from the connection site in a lateral direction with respect to the current collector layer.
In general, the electrically-conductive pathway follows an indirect route between the connection site and the contact pad. For example, the electrically-conductive pathway may change direction through an angle in the range 80-100° between the connection site and the contact pad.
Typically, the electrically-conductive pathway follows a tortuous path between the connection site and the contact pad. For example, the electrically-conductive pathway may follow a zigzag route between the connection site and the contact pad.
The exposed surface of the contact pad may be, for example, circular, oval, polygonal (for example, square, rectangular, or hexagonal), or any other two-dimensional shape.
Typically, the electrically-conductive pathway and the contact pad are integrally formed. However, this is not always the case.
In certain cases, at least one of the electrically-conductive pathway and the contact pad comprises a material selected from the group consisting of aluminium and titanium nitride. In certain cases, one or both of the electrically-conductive pathway and the contact pad may be provided by the same material as the current collector layer, for example, a material selected from the group consisting of platinum, nickel, molybdenum, copper, titanium nitride, aluminium, gold and stainless steel.
Typically, the electrically-conductive pathway has a thickness in the range 20-2000 nm, wherein the thickness is measured in a transverse direction to the surface of the pathway and the surface of the pathway is effectively a continuation of the exposed surface of the contact pad.
In general, the protective cover comprises a plurality of layers. This is thought to impede ingress of atmospheric constituents such as moisture and/or oxygen into the active layers of the cell. Furthermore, the plurality of layers may help to impede diffusion of species from the first electrode layer, the second electrode layer and/or the electrolyte layer to the contact pad.
The protective cover typically comprises a plurality of first layers and a plurality of second layers, the first layers each being provided by a polymeric material and the second layers each being provided by one of a metal and a ceramic material, wherein the first and second layers are arranged in a stacked configuration to provide alternating first and second layers.
Typically, at least one of the first layers has a thickness in the range 1-10 μm, for example, 3-7 μm. Typically, at least one of the second layers has a thickness in the range 20-2000 nm, for example, 100-500 nm.
In certain cases in which at least one of the second layers is provided by an electrically-conductive material, a portion of the electrically-conductive pathway may extend along that layer.
In other cases in which at least one of the second layers is provided by an electrically-conductive material, the electrically-conductive pathway may be electrically insulated from that layer.
In certain cases, at least one of the first layers may comprise a poly(p-xylylene) polymer, such as parylene™.
In other cases, at least one of the first layers comprises a photoresist material, for example a photoresist material comprising an epoxy resin. This may allow the layer to be patterned directly, by exposing the layer to a pattern of light that causes chemical changes within certain portions of the layer, followed by the application of a solvent that provides selective removal of the layer, depending on the pattern of light that has been applied.
In certain cases, at least one of the second layers comprises a material selected from the group comprising aluminium and titanium nitride. Titanium nitride is considered to provide an effective diffusion barrier to lithium species, and so in the case that the cell is a lithium-ion cell, may be particularly beneficial in hindering the migration of such species from the active cell layers (e.g. the first electrode layer, the second electrode layer and/or the electrolyte layer) to the contact pad. In certain cases, the second layer of the protective cover and the current collector layer are provided by the same material, for example, a material selected from the group consisting of platinum, nickel, molybdenum, copper, titanium nitride, aluminium, gold and stainless steel.
In certain cases, the protective cover may comprise a passivation layer immediately adjacent the current collector layer. The passivation layer is provided by an electrically-insulating material that may be selected from the group comprising ceramics, inorganic oxides and complex inorganic oxides. For example, the passivation layer may be selected from the group consisting of aluminium oxide, silicon oxide, silicon nitride, tantalum oxide, hafnium oxide, tungsten oxide, titanium oxide, zinc oxide, zirconium oxide, molybdenum oxide and aluminium nitride. The passivation layer typically has a thickness in the range 100 nm-5 μm.
Typically, a substrate is provided on the side of the first electrode layer that is distal from the electrolyte layer. In certain cases, a further current collector layer is provided between the substrate and the first electrode layer.
In certain cases, at least one further electrically-conductive pathway is provided between the contact pad and the connection site.
In certain cases, the cell comprises a plurality of electrically-conductive pathways, each pathway being associated with a respective connection site at which the pathway contacts the current collector layer, and each pathway extending through the protective cover to reach one of one or more contact pads that are provided on the side of the protective cover that is opposed to the current collector layer.
In certain cases, the cell comprises a plurality of contact pads provided on the side of the protective cover that is opposed to the current collector layer, each of the plurality of contact pads being associated with a respective electrically-conductive pathway that extends between the respective contact pad and the current collector layer.
These arrangements provide redundancy within the cell, so that the cell may still be electrically connected to an external device even in the case that a single electrically-conductive pathway fails. This is particularly advantageous, since the electrically-conductive pathway typically has a thickness in the range 20-2000 nm, and so failure of the pathway may occur, for example, where the underlying surface changes orientation, such as at an edge or corner.
By providing a contact pad on an external side of the protective cover, the contact pad may be located within the overall footprint of the stack of layers that provide the cell. In such cases, the overall footprint of the cell is not increased by the presence of the contact pad.
Typically, the footprint of the cell, defined as the area of one face of the electrolyte layer, is less than 500 mm2, in certain cases less than 400 mm2, in certain cases less than 300 mm2, and in certain cases less than 200 mm2. Effectively, therefore, the footprint of the cell is bounded by the perimeter of the electrolyte layer. In still further cases, the footprint of the cell may be less than 100 mm2, for example, less than 50 mm2.
One of the first and second electrode layers provides the cathode of the cell, while the other of the first and second electrode layers provides the anode of the cell.
The cathode typically has a thickness in the range 5-40 μm.
The anode typically has a thickness in the range 500 nm to 5 μm.
Typically, the electrolyte layer has a thickness in the range of 1-5 μm. In certain cases, the electrolyte layer has a thickness in the range 2-4 μm.
Typically, the current collector layer has a thickness in the range 100-500 nm. In certain cases, the current collector layer has a thickness in the range 200-400 nm.
In general, at least one of the first electrode and the electrolyte is provided by a lithium-containing compound.
In general, the cell comprises a further contact pad that is electrically-connected to the first electrode, wherein an imaginary line extending directly between the contact pad and the further contact pad passes through at least one of the first electrode, the electrolyte, the second electrode and the current collector. Typically, the further contact pad is an exposed portion of a further current collector, the further current collector layer being in direct contact with the first electrode.
For the avoidance of doubt, the first electrode layer, the electrolyte layer, the second electrode layer, the current collector layer and the protective cover are not necessarily coextensive. For example, in certain embodiments, the perimeter of the first electrode layer may not match the perimeter of the current collector layer. In such cases, for example, the connection site may be located outside the perimeter of the first electrode layer, that is, the connection site does not overlie the first electrode layer. Effectively, the connection site is offset from the first electrode layer in a lateral direction of the first electrode layer. This may assist in reducing migration of deleterious species from the first electrode layer to the connection site, particularly in the case that the first electrode is a lithium-containing electrode, for example, a lithium-containing cathode.
By contrast, the contact pad typically lies within the perimeter of the first electrode layer.
Since the layers are not necessarily coextensive, certain layers, for example, the current collector layer, may not be entirely planar. For the avoidance of doubt, references to the face of the current collector layer, in the context of defining the relative orientations of the electrically-conductive pathway and the face of the current collector layer, relate to the portion of the current collector at the connection site.
In certain cases, the electrochemical cell is a solid state electrochemical cell. In certain cases, the electrochemical cell is a secondary cell.
In certain embodiments of the electrochemical cell according to the first aspect of the invention, the anode is formed in situ during initial charging of the cell.
Therefore, in a second aspect, the present invention may provide a precursor for an electrochemical cell according to the first aspect of the invention, the precursor comprising a stack of layers including a cathode layer, an electrolyte layer, a current collector layer, and a protective cover, the protective cover being located on a first side of the current collector layer, and the cathode layer and electrolyte layer being located on a second side of the current collector layer;
The cathode may be located between the electrolyte layer and the current collector layer. Alternatively, the cathode may be located on the side of the electrolyte layer that is opposed to the current collector layer.
Typically, initial charging of the precursor results in the formation of a lithium anode layer on the side of the electrolyte layer that is opposed to the cathode layer.
The precursor according to the second aspect of the invention may have one or more of the optional features of the cell of the first aspect of the invention, taken alone or in combination.
In a third aspect, the present invention may provide a method of manufacturing a cell according to the first aspect of the invention, comprising the steps of:
In general, a passivation layer is provided between the current collector layer and the first electrically-insulating layer, the passivation layer being provided with a respective through-thickness aperture, and the step of providing an aperture through the thickness of the first electrically-insulating layer comprises aligning the aperture in the first electrically-insulating layer with the aperture in the passivation layer.
The passivation layer is provided by an electrically-insulating material that may be selected from the group comprising ceramics, inorganic oxides and complex inorganic oxides. Typically, the passivation layer is provided by a ceramic material selected from the group consisting of: aluminium oxide, aluminium nitride, silicon oxide, silicon nitride, tantalum oxide, hafnium oxide, tungsten oxide, titanium oxide, zinc oxide, zirconium oxide, molybdenum oxide and combinations thereof.
In certain less preferred cases, the first electrically-insulating layer corresponds to such a passivation layer, that is, it is provided by a ceramic material selected from the group consisting of: aluminium oxide, aluminium nitride, silicon oxide, silicon nitride, tantalum oxide, hafnium oxide, tungsten oxide, titanium oxide, zinc oxide, zirconium oxide, molybdenum oxide and combinations thereof.
In general, the step of providing an aperture through the thickness of the first electrically-insulating layer comprises selectively etching the first electrically-insulating layer, for example, through a photolithographic process.
In certain cases, the photolithographic process comprises the step of depositing a photoresist material on the first electrically-insulating layer, for example, through spin-coating. In other cases, before the step of depositing a photoresist material, a metal layer may be deposited on the first electrically-insulating layer, such that the metal layer lies between the photoresist material and the first electrically-insulating layer. In such cases, the photoresist material may be used to pattern the metal layer through a photolithographic process, and the patterned metal layer may subsequently function as a mask in an etching process to provide an aperture in the first electrically-insulating layer.
In further cases, the first electrically-insulating layer comprises a photoresist material, and the step of selectively etching the first electrically-insulating layer may comprise exposing at least one part of the surface of the first electrically-insulating layer to incident light that causes chemical changes within that part of the surface of the first electrically-insulating layer.
Typically, the method according to the third aspect of the invention further comprises the step, after the step of creating the electrically-conductive pathway, of depositing a second electrically-insulating layer over the first electrically-insulating layer and creating a through-thickness aperture through the second electrically-insulating layer, so as to expose a portion of the electrically-conductive pathway. In such cases, the aperture in the second electrically-insulating layer is displaced from the aperture in the first electrically-insulating layer in a lateral direction of the second electrically-insulating layer.
Typically, the first and second electrically-insulating layers are each provided by a polymer material. In certain cases, the first and/or second electrically-insulating layers may comprise a poly(p-xylylene) polymer, such as parylene™. In other cases, the first and/or second electrically-insulating layers comprise a photoresist material, for example a photoresist material comprising an epoxy resin.
Typically, the first and second electrically-insulating layers are each deposited to a thickness in the range 1-10 μm, for example 3-7 μm.
Typically, the electrically-conductive material is deposited to a thickness of 20-2000 nm, for example 100-500 nm. In certain cases, the electrically-conductive material is aluminium. The electrically-conductive material may be deposited through a physical vapour deposition process, such as sputtering. It is preferable that the electrically-conductive material is deposited to a thickness of 2000 nm or less, as this allows the material to be deposited as a layer (for example, through the vapour deposition process), which is subsequently shaped (for example, through etching) to provide the electrically-conductive pathway. If the thickness of the electrically-conductive material is greater than 2000 nm, it may be difficult to remove the unwanted portions of the material fully, so that there is a risk that a short circuit will occur between different parts of the cell.
In certain cases, the stack of layers comprises an anode layer. However, in other cases, the anode layer may be formed during initial charging of the cell.
The invention will now be described by way of example with reference to the following Figures in which:
Referring to
The protective cover 102 comprises an electrically-insulating ceramic passivation layer 14 immediately adjacent the current collector layer 12, and polymer layers 104,108,112 arranged in an alternating sequence with metal layers 106,110,114.
An aperture 116 is provided in the passivation layer. The polymer layer 104 immediately adjacent the passivation layer 14 extends through the aperture 116 in the passivation layer and to contact the current collector layer 12.
The current collector layer 12 may be provided by a material selected from the group consisting of platinum, nickel, molybdenum, copper, titanium nitride, aluminium, gold and stainless steel. The second face of the current collector layer 12 (that is, the face that is opposed to the passivation layer 14) contacts a core battery stack comprising first and second electrode layers 6,10 having an electrolyte layer 8 located therebetween.
Referring to
In the configuration shown in
The exposed section of the current collector layer 12 may provide a contact pad to allow connection of the cell to external devices. Typically, this requires a wire to be bonded to the contact pad.
However, it has been found that during cycling of a cell having a contact pad arranged according to this configuration, a change is observed in the appearance of the contact pad, thought to be due to the presence of reaction products at the exposed surface of the current collector layer 12. These reaction products are considered to impede the bonding between the wire and the contact pad, such that electrical contact may be lost after only a few cycles of the cell (in certain cases, electrical contact may be lost after the cell has undergone only three cycles).
The formation of reaction products on the contact pad (that is, at the exposed surface of the current collector layer 12) is thought to be due to the diffusion of species from the battery stack underlying the current collector layer 12 to the contact pad, where these species react with the ambient environment.
Referring to
The stack of layers comprises the following layers arranged in the following order: an adhesion layer 316, located immediately adjacent the substrate 314, a cathode current collector layer 318, a cathode layer 320, an electrolyte layer 322, an anode layer 324, and an anode current collector 326.
The external surface of the stack of layers is covered by an electrically-insulating encapsulating layer 330, with the exception of a section of the anode current collector 326 that lies within a through-thickness aperture 332 in the encapsulating layer, and a section of cathode current collector layer 318. Following formation of the aperture 332, a metal track layer 334 is deposited over the outer surface of the cell 328.
The metal track layer 334 provides a conductive path from the anode current collector 326 to the substrate 314, where a contact pad may be provided (not shown). The contact pad enables connection of the cell 328 to an external device (not shown).
However, during operation of the cell, it is likely that one or more layers within the stack of layers will undergo changes in thickness. For example, in the case that the cell is a lithium-ion cell, the anode layer will tend to swell during charging of the cell, as lithium ions become embedded in it. Conversely, the anode layer will tend to shrink during discharge of the cell, as lithium ions leave the layer.
It is thought that these changes in volume of the layers during operation of the cell will have a negative impact on the integrity of the metal track layer 334 that connects the anode current collector 326 to the substrate 314, thus reducing the reliability of the conductive pathway that it provides.
Referring to
An aperture 16 is provided in the passivation layer. The first polymer layer 18 extends through the aperture 16 to contact the current collector layer 12.
The current collector layer 12 may be provided by a material selected from the group consisting of platinum, nickel, molybdenum, copper, titanium nitride, aluminium, gold and stainless steel. The second face of the current collector layer 12 (that is, the face that is opposed to the passivation layer 14) typically contacts a core battery stack (not shown), the core battery stack comprising first and second electrode layers having an electrolyte layer located therebetween. However, in certain cases, the cell may be manufactured such that, initially, no electrode layer is provided between the current collector layer 12 and the electrolyte layer of the cell (not shown). In such cases, the cell is typically configured such that during the first charging of the cell, a lithium anode is formed between the electrolyte and the current collector layer 12.
The passivation layer 14 is typically provided by a ceramic material, for example, a material selected from the group consisting of aluminium oxide and aluminium nitride. In certain embodiments, the passivation layer has a thickness of about 1.5 μm.
In certain cases, the first polymer layer 18 may be provided by a poly(p-xylylene) polymer, such as parylene™. In other cases, the polymer layer may be provided by a photoresist material, that is, a material that undergoes chemical changes in response to incident light, these chemical changes altering its solubility in certain solvents. The photoresist material may contain an epoxy resin.
The thickness of the first polymer layer 18 is typically 5 μm (this refers to the thickness of the portion of the first polymer layer that overlies the passivation layer 14).
The aperture 16 in the passivation layer 14 is typically formed through an etching process prior to deposition of the first polymer layer 18.
Referring to
The aperture 20 is typically created through a photolithography process. In certain cases, this photolithography process may comprise depositing a photoresist layer on the exposed surface of the first polymer layer 18 and exposing the photoresist layer to a pattern of light that causes chemical changes within certain portions of the layer. A solvent (that is, a developer solution) may then be applied to the photoresist layer, whose effect varies depending on the chemical changes caused by the light pattern (for example, a positive tone photoresist layer becomes more soluble in developer solution after exposure to UV light, while a negative photoresist layer becomes less soluble in developer solution after exposure to UV light). Thus, a masking layer may be provided on the surface of the first polymer layer 18, allowing etching to be performed to create aperture 20.
However, in the case that the first polymer layer 18 is provided by a photoresist material, the aperture 20 may be created without the need to provide a separate masking layer, since the layer may be exposed directly to the light and the solvent in order to create the aperture.
The aperture 20 formed in the first polymer layer 18 is typically narrower than the aperture 16 provided in the passivation layer 14. As a result, the internal surfaces of aperture 16 are typically covered with a coating of the material of first polymer layer 18.
Referring to
The first electrically-conductive layer 22 typically comprises aluminium or titanium nitride. The thickness of the first electrically-conductive layer is typically 200 nm. In the case that the first electrically-conductive layer 22 is provided by an aluminium layer, the deposition of the first electrically-conductive layer 22 typically comprises a sputtering process.
Following the deposition of the first electrically-conductive layer 22, a second polymer layer 24 is deposited on the exposed surface of the first electrically-conductive layer 22. The second polymer layer 24 therefore follows the profile of the exposed surface of the first electrically-conductive layer 22. The second polymer layer 24 typically has the same composition as the first polymer layer 18, and is typically deposited to the same thickness.
Referring to
Aperture 26 is typically created through the same procedure as aperture 20 of
Referring to
After the deposition of the second electrically-conductive layer 28, a third polymer layer 30 is deposited on the exposed surface of the second electrically-conductive layer 28. The third polymer layer 30 typically has the same composition as the first and second polymer layers 18, 24, and is typically deposited to the same thickness.
Referring to
Thus, as a result of the process described with reference to
The steps of depositing an electrically-conductive layer, depositing a polymer layer and creating an aperture in the polymer layer to expose a section of the electrically-conductive layer (as shown, for example, in
It is thought that by providing alternating layers of electrically-conductive material (for example, aluminium) and polymer material, the ingress of moisture into the cell (from the exposed surface of the protective cover towards the current collector layer 12) may be inhibited.
At the same time, an electrically-conductive pathway is provided between the contact pad 32 and the current collector layer 12. This electrically-conductive pathway follows the second electrically-conductive layer 28 from the contact pad to the region 25 where the first and second electrically-conductive layers 22,28 coincide, and subsequently follows the first electrically-conductive layer 22 to the current collector layer 12.
As may be seen from
It is thought that the provision of this tortuous pathway helps to reduce the extent of diffusion of species from the core battery stack underlying the current collector layer 12 to the contact pad 32. This is thought to help to impede the formation of reaction products at the contact pad 32 that might interfere with the connection of the cell to an external device.
Referring to
One or more electrode and/or electrolyte layers (not shown) are disposed on the side of the current collector layer 12 that is opposed to the passivation layer 14.
The composition and thickness of the passivation layer 214 are typically the same as for the passivation layer 14 shown in
Multiple apertures are provided through the thickness of the passivation layer 214 and the first polymer layer 218, such that multiple portions 220 of the face of the current collector layer 12 that contacts the passivation layer 214 are exposed.
Referring to
The first electrically-conductive layer 222 typically has the same composition and thickness as the first and second electrically-conductive layers 22,28 shown in
Referring to
Referring to
The second electrically-conductive layer 228 typically has the same composition and thickness as the first electrically-conductive layer 222, although this is not always the case.
Referring to
Each exposed portion 232 of the second electrically-conductive layer 230 provides a contact pad, allowing connection of the cell to an external device.
It is thought that by providing alternating layers of electrically-conductive material (for example, aluminium) and polymer material, a protective cover 234 is formed that helps to inhibit the ingress of moisture into the cell from the exposed surface of the protective cover 234 towards the current collector layer 12.
The steps of depositing an electrically-conductive layer, depositing a polymer layer and creating apertures in the polymer layer, as described with reference, for example, to
At the same time, multiple electrically-conductive pathways are provided between each contact pad (at the respective exposed section 232 of the second electrically-conductive layer 228) and the current collector layer 12. These electrically-conductive pathways follow the second electrically-conductive layer 228 from the contact pad to a region where the first and second electrically-conductive layers 222,228 coincide, and subsequently follow the first electrically-conductive layer 222 to the current collector layer 12.
The provision of multiple contact pads and multiple electrically-conductive pathways connecting each contact pad to the current collector layer 12 provides redundancy within the cell, such that the cell can continue to be connected to an external device even if a single electrically-conductive pathway between a contact pad and the current collector layer 12 fails.
As may be seen from
Referring to
A through-thickness apertures is provided in the protective cover 102, so that a portion 118 of the current collector layer 12 is exposed. This may provide a contact pad for connecting to cell to an external device.
The assembly of
Referring to
Referring to
Referring to
Referring to
Referring to
Referring to
Referring to
As shown in
An aperture 428 is provided in the corner portion 434 of the cell 400, the aperture extending through the stack of alternating polymer and metal layers 424 and the electrically-insulating passivation layer 422 (for simplicity, details of the configuration of the internal wall of aperture 428 are not shown, but these are generally similar to those shown in
As shown with reference to
The outer polymer layer 430 overlies the stack of alternating polymer and metal layers 424 and the electrically-conductive trace 426, the outer polymer layer 430 comprising an aperture 432 in the region overlying the second circular portion 426b of the electrically-conductive trace 426.
The exposed section of the electrically-conductive trace 426 at the location of the aperture 432 provides a contact pad, allowing the cell to be connected to an external device.
Since aperture 428 is provided in the corner portion 434 of the cell 400, it does not overlie the cathode layer 414. It is thought that this helps to prevent cracking of the electrically-conductive trace 426 at the location of the aperture 428, which might otherwise occur through migration of chemical species (for example, lithium) from the cathode 414 to the aperture 428.
By providing an electrically-conductive trace 426 having three legs 426c,d,e connecting the first and second circular portions 426a,b, an electrical connection may be maintained between the first and second circular portions even if one or two of the legs 426c,d,e fail. This redundancy is beneficial, since the thickness of the electrically-conductive trace 426 is only about 200 nm and the legs may be vulnerable, for example, at the edge between the internal wall of aperture 428 and the stack of alternating polymer and metal layers 424. The use of a thicker electrically-conductive trace 426 is not desirable, since the trace is formed by depositing a layer of the electrically-conductive material and etching it to provide the required configuration. Care must be taken during etching to avoid leaving residual electrically-conductive material that may create a short-circuit between different sections of the cell, and this is more difficult with a thicker trace.
For the avoidance of doubt, the terms “overlying,” “overlie,” “underlying,” and “underlie” refer to the relative positions of cell components when the assembled cell components are oriented as shown in
| Number | Date | Country | Kind |
|---|---|---|---|
| 2006391.3 | Apr 2020 | GB | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/GB2021/051016 | 4/27/2021 | WO |
