The present invention relates to electrical connector systems used in fuel cell stacks to make electrical connections to a plurality of individual cells within a fuel cell stack.
Conventional electrochemical fuel cells convert fuel and oxidant into electrical and thermal energy and a reaction product. A typical fuel cell comprises a membrane-electrode assembly (MEA) sandwiched between an anode flow field plate and a cathode flow field plate. Gas diffusion layers may be disposed between each flow field plate and the MEA. Gaskets may be used to separate various layers and to provide requisite seals. The flow field plates typically include one or more channels extending over the surface of the plate adjacent to the MEA for delivery of fluid fuel or oxidant to the active surface of the MEA. The flow field plates also perform the function of providing an electrical contact to the MEA across the surface thereof.
In a conventional fuel cell stack, a plurality of cells are stacked together, so that the anode flow field plate of one cell is adjacent to the cathode flow field plate of the next cell in the stack, and so on. In some arrangements, bipolar flow plates are used so that a single flow field plate has fluid flow channels in both sides of the plate. One side of the bipolar plate serves as an anode flow plate for a first cell and the other side of the flow plate serves as a cathode flow plate for the adjacent cell. Power can be extracted from the stack by electrical connections made to the first and last flow plate in the stack. A typical stack may comprise many tens or even hundreds of cells. The present invention is relevant to all of these various fuel cell stack constructions.
In many fuel cell stacks, it is important to be able monitor the voltage of individual cells in the stack. Thus, it is necessary to provide electrical connection to many (and often to all) of the flow plates in the stack. Conventionally, this has been achieved by providing electrical connector tabs to at least some of the flow plates in the stack. These cell voltage monitoring tabs extend from edges of the flow plates, laterally outward from the stack thereby forming an array of tabs along an edge face of the stack, so that individual electrical connectors may be coupled to each tab. One arrangement of cell voltage monitoring tabs extending from each flow plate is shown in
The fuel cell stack 1 in
These male tabs 3 can typically be used with standard female electrical connectors, such as blade receptacles well known in the art. Use of individual blade receptacles for each tab 3 is practical for manufacture of small stacks and small volumes of cells, but is not ideal for mass production of cells in view of the high labour content of connecting individual receptacles.
One potential disadvantage to the laterally extending tabs 3 is that they are exposed and relatively prone to damage during handling of the plates, during assembly of the fuel cell stack, during attachment of suitable electrical connectors and during use of the stack. Another potential disadvantage to the laterally extending tabs 3 is that if multiple rows of tabs are required as shown, to decrease packing density, then two or more different configurations of plates is required having tabs in different positions on the plates. This increases manufacturing costs, inventory costs, and stack assembly process complexity.
It is an object of the invention to provide a fuel cell field plate with an improved facility for electrical connection thereto.
According to one aspect, the present invention provides a fluid flow field plate for an electrochemical fuel cell comprising an electrically conductive plate element having a peripheral edge encapsulated in an electrically insulating gasket material, the plate element having a laterally projecting tab with a first face covered by the peripheral gasket material and a second face at least partially exposed through the gasket material.
At least one edge of the laterally projecting tab may be covered by the peripheral gasket material. At least two edges of the laterally projecting tab may be covered by the peripheral gasket material. The leading edge of the laterally projecting tab may be covered by the peripheral gasket material. The gasket material may define a retention feature for retaining an electrical connector coupled to the laterally projecting tab. The retention feature may comprise a barb on an exposed surface of the gasket material extending over the laterally projecting tab. The retention feature may comprise a ribbed exposed surface of the gasket material overlying the first face. The fluid flow field plate may comprise a bipolar plate having fluid distribution channels in both faces of the electrically conductive plate element.
The electrically insulating gasket material may extend around the complete periphery of the electrically conductive plate element, and may define fluid distribution channels in the gasket material on at least one peripheral edge of the plate element and may define a protective structure for the laterally projecting tab on at least one different peripheral edge of the plate element.
The fluid flow field plate may further include fluid coolant flow channels defined in the first face of the laterally projecting tab and/or in the gasket material covering the first face of the laterally projecting tab.
The laterally projecting tab may define a retention feature for retaining an electrical connector coupled to the laterally projecting tab. The retention feature may comprise a contoured or profiled exposed surface of the laterally projecting tab.
The fuel cell stack may comprise a plurality of layers, in which at least some of the layers each comprise a fluid flow field plate as defined above, thereby defining a plurality of electrically conductive connection tabs extending outwardly from at least one face of the stack, each electrically conductive connection tab being protected on plural edges by the gasket material of the plurality of layers, the gasket material collectively defining a housing structure for the plurality of connection tabs.
The housing structure may comprise two end walls protecting edges of the connection tabs and defining a receptacle therebetween for receiving an electrical connector module. The fuel cell stack may further include an electrical connector module configured to engage with the plural electrically conductive connection tabs and the gasket material for separate electrical connection to each of the tabs. The electrical connector module may engage with retention features disposed on the gasket material. The retention features may comprise one or more of a barb or barbs on the housing structure and ribbed exposed surfaces of the gasket material of the housing structure. The width of the electrical connector module may be substantially less than the width of the electrically conductive connection tabs such that the electrical connector module can be engaged with the tabs at a number of different positions along a peripheral edge of the stack and/or such that multiple such electrical connector modules could be engaged with tabs of the stack simultaneously at different positions along the peripheral edge of the stack.
The electrical connector module may comprise a plurality of blades spaced from one another with a pitch that is equal to or an integer multiple of the pitch of the plates in the stack, each blade comprising a spring metal component for engagement with the second face of a laterally projecting tab and for simultaneous engagement with the gasket material covering the first face of an opposing, adjacent laterally projecting tab.
According to another aspect, the invention provides a fuel cell stack assembly having a layered construction including electrically conductive fluid flow field plates at least partially separated by gasket layers, the gasket layers each having at least one exposed edge that together define an open face of the stack assembly,
Each recess may extend through only a portion of the thickness of the respective gasket layer, each recess thereby being defined on a first side by one of said electrically conductive fluid flow plates and on a second side by the gasket material. Each gasket layer may lie between a portion of a cathode plate and an anode plate. Each gasket layer may define a retention feature associated with a respective recess. The retention feature may comprise a ribbed surface within the recess. The electrically conductive fluid flow plate may define a retention feature associated with a respective recess. The retention feature may comprise a contoured or profiled exposed surface of the electrically conductive fluid flow plate associated with a respective recess. The cathode plate may comprise a corrugated plate, and each gasket layer may correspond in thickness with the corrugation height. The gasket layers and the electrically conductive flow pates may each have at least one exposed edge that together define the open face of the stack assembly. The fuel cell stack may further include a coolant flow channel defined in the electrically conductive plate and/or the gasket, the coolant flow channel being in a position overlying the recess.
According to another aspect, the invention provides a method of making electrical connections to flow field plates of a fuel cell stack comprising:
The method may further comprise connecting an electrical connector module to said tabs by engagement into a receptacle defined by the housing, wherein the engagement of the electrical connector module is with the tabs and the gasket material.
According to another aspect, the invention provides a method of making electrical connections to flow field plates of a fuel cell stack comprising:
Embodiments of the present invention will now be described by way of example and with reference to the accompanying drawings in which:
Each plate 10 comprises an electrically conductive plate element 11 which provides an active field area of the plate and may include a set of fluid flow distribution channels 12 in the surface thereof for flow of anode or cathode fluid across the active field area. The flow channels 12 are covered by one or more gas diffusion layers 13 and a membrane electrode assembly which, in
Each electrically conductive plate element 11 (which may be referred to as a plate insert) has a peripheral edge which is encapsulated in an electrically insulating gasket material 15. The gasket material 15 is preferably formed as an overmoulded gasket 18 which is bonded to the electrically conductive plate element 11 and comprises a resilient elastomeric/rubber compound which provides a sealing surface 16 surrounding the plate element 11 edge on both faces and optionally also around one or more fluid distribution plenums 17 at one or more edges of the plates for delivery of fluids to the flow channels 12 in each plate 10.
Each electrically conductive plate element 11 also includes a laterally projecting tab 20 extending from the active field area of the plate and preferably from a peripheral edge of the plate element 11. Preferably the plate element 11 and the laterally projecting tab 20 are of a unitary construction, e.g. formed from a sheet of metal such as stainless steel stamped out or otherwise cut and formed to the appropriate shape, prior to being introduced to an overmoulding process to form the peripheral gasket around the peripheral edge of the cut sheet.
As seen in
As can be seen in
The housing structure 21 preferably defines one or more retention features for retaining an electrical connector assembly that may be removably coupled to the tab or tabs 20.
One such type of retention feature may comprise a barb 30 projecting inwards from one or both end walls 22a, 22b. The end walls 22a, 22b may be configured to elastically deform as a connector assembly is pushed onto the tabs 20 within the housing structure 21 and then resiliently return to capture a feature of the connector assembly when that feature has passed the barb 30 and is fully engaged.
Another type of retention feature may comprise a ribbed exposed surface 31 of the gasket material 15 covering the first face 24b of the tab 20, as seen in
In addition, or instead, a retention feature may be provided on the exposed surface 24a of the tab 20, e.g. as a suitably contoured or profiled surface of the tab 20 which enhances the friction between a connector blade of a connector assembly (described later in connection with
The gasket material 15 preferably extends around the complete periphery of the electrically conductive plate element 11 for most fuel cell stack types excepting the leading edge 26 of the tab 20. However, in other embodiments one or more edges or parts of edges of the plate element 11 may not require a continuous gasket, e.g. for open cathode type fuel cell plates.
The gasket material 15, i.e. gasket 18, may include other features. These may include recesses 35 each suitable for receiving a tie bar for compressing all the plates 10 together in a stack, and other projecting members 36 for engaging with or mounting stack support structures, air flow boxes etc. The gasket material 15 may generally be profiled, on the edge of the plate 10 that provides the tab 20, such that the housing 21 extends along the entire edge (or a substantial portion thereof), providing one or more specific recesses for the tabs 20.
The gasket 18 may also define fluid distribution channels such as those ending at openings 37 opening from the fluid distribution plenum 17. These channels may be configured for delivery of fluid from the distribution plenum 17 to selected ones of the flow channels 12. The fluid distribution channels may be provided on at least one, and preferably two, peripheral edges of the plate 10, typically opposite edges of the plate 10, and typically on edges of the plate different (e.g. adjacent to) the edge or edges defining the laterally extending connection tabs 20. The gasket material 15 may also include regions of enhanced compressibility, such as provided by cavities 38.
With reference to
The connector module 40 comprises a series of electrically conductive blades 41 extending outwards from a substrate 42 and spaced at intervals corresponding to the spacing of the plates 10 or integer multiples thereof. Each blade 41 may include a lug portion 43 which will co-operate with the barb 30 retention feature on the housing 21. The lug portion 43 may compress and/or displace the barb 30 as it slides past during engagement of the connector module 40 with the receptacle defined by housing 21, and then be retained behind the barb 30 when the trailing shoulder 43a of the lug portion 43 has passed the barb and the gasket material elastically recovered its position.
The blades 41 may each comprise a spring metal component folded back on itself as shown, having a main blade portion 44 coupled to the substrate 42 and a leaf spring portion 45 folded back on the main blade portion 44 but slightly separated therefrom, so as to provide a blade with an effective compressible thickness. Upon insertion of a blade 41 into a respective part of the housing 21, the main blade portion 44 bears against the exposed face 24a of a tab 20, and the leaf spring portion 45 bears against a covering part 25 of an adjacent tab 20. The retention feature of the ribbed surface 31 if present may assist in retaining the blade 41 in the receptacle. The leaf spring portions 45 of the blades 41 ensure that the main blade portion 44 is pressed firmly against the respective exposed face 24a. The main blade portion 44 and the leaf spring portion may be slightly arcuate in form, as shown in the drawings, to assist in ensuring good sliding engagement and good physical contact for electrical connection. It would also be possible to provide alternative configurations of blade 41, suitable for making optimal contact with both the exposed face 24a of a tab 20 and an opposing covering part 25 of an adjacent tab.
Thus, in a general aspect, the blades 41 may be spaced from one another with a pitch that is equal to or an integer multiple of the pitch of the plates 10 in the stack, and each blade may comprise a spring metal component 44, 45 that engages with the second (exposed) face 24a of a laterally projecting tab 20 and simultaneously may engage with the gasket material 25 covering the first (covered) face 24b of an opposing, adjacent laterally projecting tab 20.
The substrate 42 of the connector module 40 may comprise a printed circuit board or similar material which can be configured to have electrically conductive tracks thereon each providing an electrical connection to a respective blade 41.
The extended width tab arrangement also facilitates use of multiple connection modules 40 in parallel with one another (i.e. coupled to the same tabs) should it be necessary to draw a higher current from individual intermediate plates in the stack than would normally be required for simple voltage monitoring.
The connection modules 40 may also be configured with blades 41 only at selected plate positions in the stack, e.g. the blades may be double spaced to only intercept alternate tabs 20 in the stack. For example, a first connection module 40 may comprise blades 41 positioned for engagement at odd numbered plate tab positions, and a second connection module 40 may comprise blades 41 positioned for engagement at even numbered plate tab positions. The connection modules 40 may thereby be positioned side-by-side on the wide tab housing of
The configurations of electrically conductive connection tabs as described offer a number of advantages. The tabs may be protected by the gasket material within a one piece overmoulded gasket which is conveniently fabricated at one time. The tabs are less susceptible to damage. The gasket material may provide a compressible, high friction surface to assist in retaining an electrical connection module when plugged in. The increased protection for the tabs using the gasket material may enable tabs of extended length which can then provide flexibility in connector positioning, and/or extended tab surface area for extended dimension connectors or multiple connectors for higher current draw from a tab or tabs. This feature can be useful when sometimes it can be advantageous to short circuit selected cells or draw very high current from selected cells, such as during stack start-up, stack conditioning or stack protection operations.
The partial encapsulation of the tabs by the housing 21 provides improved durability during assembly and use and improved durability of the plates 10 prior to assembly, e.g. during shipping and handling. There may also be advantages in providing extended width tabs such that current can be drawn from a plate along substantially an entire edge of the plate, for improved current distribution across the surface area of the plate. Different connectors may be applied to accommodate both voltage sensing and current draw using different connector systems.
The laterally projecting tabs 20 may generally be exemplified by an edge part of the electrically conductive plate element 11 which projects laterally outward from an active field area of the plate element, or an otherwise generally rectangular outline of the plate element, such that it is capable of providing an exposed, projecting element extending from a face of a stack defined by plural plate 10 edges. Alternatively, or in addition, the laterally projecting tabs 20 may generally be exemplified by a limited area portion of the electrically conductive plate element which lies laterally outside an inner perimeter of gasket material used to seal adjacent plates together in a stack.
The housing 21 protecting the tabs is shown in the drawings as protecting, i.e. covering, two side edges 23a, 23b. In other arrangements, a more limited form of protection may be had by the housing covering only one side edge 23a or 23b. In the drawings (e.g.
As is apparent from the foregoing description, the embodiments described above provide for a general method of making electrical connections to flow field plates 10 of a fuel cell stack. The method may include forming a plurality of the fluid flow field plates 10 and stacking the fluid flow field plates together to form a fuel cell stack with aligned laterally projecting tabs 20, such that the gasket material 15 defines the housing 21 for the tabs. An electrical connector module 40 can then be coupled to the tabs 20 by engaging the connector module into the receptacle defined by the housing 21. It can be seen that the engagement of the electrical connector module 40 is robust in that the module can be engaged with both the tabs 20 (at surface 24a) and the gasket material 15, e.g. at covering part 25 and/or retention feature comprising barb 30.
The principles described above can also be adapted to fuel cell stacks in which the gasket material presents an exposed edge which at least in part defines an open (e.g. external) face of the stack assembly. This exposed edge of the gasket material enables creation of a recess therein to enable access for an electrical connector to a tab portion of a face of a fluid flow field plate, the face being otherwise sealed against the gasket material.
At one end 79 of the stack 70, or at both ends of the stack (e.g. end 79 and the opposing end not visible in
In the example shown, the recess 80 in the exposed face 81 is formed by way of a channel 82 in one surface (e.g. the upper surface as shown) of the manifold gasket 76 extending part way into the gasket from the exposed face 81. The recess 80 preferably extends through only a portion of the thickness t of the manifold gasket 76. If the manifold gasket 76 is formed from multiple layers, the channel 82 could be defined by a cut out section of an upper layer or layers, leaving a lower layer uncut. The recess 80 is defined on a top side by the anode flow plate 71, and on a bottom side by the base of the channel 82, and on the two lateral sides by the sidewalls of the channel 82.
The base of the channel 82 may define a retention feature suitable for assisting in retaining an electrical connector assembly (e.g. blade 41) that is inserted into the recess. The retention feature may comprise a ribbed surface on the base of the channel 82 and/or on one or more of the sidewalls of the channel 82. In the arrangement shown, the ribbed surface comprises longitudinal ribs 83 each extending into the recess from the exposed face 81 of the manifold gasket 76 to serve as a longitudinal guide to an electrical connector assembly being inserted therein. Alternatively, or in addition, the ribbed surface could comprise ribs extending transversely across the recess 80 to increase friction between a connector assembly and the recess 80. As described in connection with
As can be seen in the example of
The example of
The fuel cell stack arrangements described above may use any suitable male-type electrical connection assembly such as an assembly similar to those described in connection with
The fuel cell stack arrangements described above may also be adapted to provide fluid cooling, for example liquid cooling, of the portion of the plate elements that provide the electrical connection area. For example, the tabs (e.g. tabs 20) of the plate elements 11 can be fluid cooled, or the portions of the electrically conductive fluid flow plates (e.g. anode or cathode flow plate 71, 75) that are adjacent to the recesses 80 receiving an electrical connector can be fluid cooled.
In the example of
The flow channels may comprise serpentine channels that extend into and across the area of the tab 20. The flow channels may be of generally uniform width to cover a suitable area of the tab 20 area, and/or may include galleries capable of provide a greater volume of coolant at positions in the tab 20 area.
The flow channels 90 can assist in enabling higher current draw through the tab 20 than would otherwise be possible. This can be of particular benefit when the plate element 11 is particularly thin and/or of low thermal mass, and/or when it is useful to be able to sometimes draw significantly higher current from a tab 20 than would be normally required for cell voltage monitoring. Such flow channels 90 could alternatively, or additionally be provided in the gasket material 15 itself adjacent to the portion of the plate element 11 defining the tab 20.
The coolant flow channels 90 may be fed from a suitable fluid distribution plenum similar to that shown as feature 17 on
A similar modification can readily be applied to the fuel cell stack arrangement exemplified by
By providing such direct fluid cooling to the portion of the electrically conductive plate to which an electrical connector assembly is to be attached, the electrically conductive plate in the vicinity of the electrical connection area can have a very low mass and small surface area yet still provide a good current capacity without damage through overheating. By using liquid cooling which may already be available elsewhere on the plate, it is convenient, efficient and low cost to extend the cooling flow path or paths (and thereby extend the temperature-controlled surfaces of the plates) to the electrical connection area of the plates.
Other embodiments are intentionally within the scope of the accompanying claims.
Number | Date | Country | Kind |
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1520981.0 | Nov 2015 | GB | national |
Filing Document | Filing Date | Country | Kind |
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PCT/GB2016/053694 | 11/24/2016 | WO | 00 |