The subject matter herein generally relates to a contact lens and a method for making the contact lens.
Contact lenses are commonly worn by users to correct vision, or for cosmetic or therapeutic reasons. Since the contact lens directly contacts eyes of the user when in use, a high water content of the contact lens is needed.
Implementations of the present technology will now be described, by way of example only, with reference to the attached figures.
It will be appreciated that for simplicity and clarity of illustration, where appropriate, reference numerals have been repeated among the different figures to indicate corresponding or analogous elements. In addition, numerous specific details are set forth in order to provide a thorough understanding of the embodiments described herein. However, it will be understood by those of ordinary skill in the art that the embodiments described herein can be practiced without these specific details. In other instances, methods, procedures, and components have not been described in detail so as not to obscure the related relevant feature being described. Also, the description is not to be considered as limiting the scope of the embodiments described herein. The drawings are not necessarily to scale and the proportions of certain parts may be exaggerated to better illustrate details and features of the present disclosure.
The term “substantially” is defined to be essentially conforming to the particular dimension, shape or other word that substantially modifies, such that the component need not be exact. For example, substantially cylindrical means that the object resembles a cylinder, but can have one or more deviations from a true cylinder. The term “comprising” when utilized, means “including, but not necessarily limited to”; it specifically indicates open-ended inclusion or membership in the so-described combination, group, series and the like.
At block 201, referring to
The female die 31 comprises a cavity 310. The cavity 310 comprises a first molding surface 311. The male die 33 comprises a mold core 330 protruding toward the female die 31 and matching the cavity 310. The mold core 330 comprises a second molding surface 332 protruding toward the female die 31.
At block 202, a first gel precursor is injected into the cavity 310, and then a second gel precursor is injected into the cavity 310 slowly which is deposited on the first gel precursor to form a gel precursor mixture. A ratio of the first gel precursor and the second gel precursor in volume can be varied according to need.
A water content of the first gel precursor is less than a water content of the second gel precursor. A density of the first gel precursor is larger than a density of the second gel precursor.
In at least one exemplary embodiment, the water content of the first gel precursor is in the range of about 25% to about 45%. The water content of the second gel precursor is in the range of about 50% to about 80%.
The first gel precursor and the second gel precursor are made of hydrogel or silicone hydrogel.
In at least one exemplary embodiment, the first gel precursor and the second gel precursor are both made of hydrogel or silicone hydrogel. In another exemplary embodiment, one of the first gel precursor and the second gel precursor is made of hydrogel, and the other one of the first gel precursor and the second gel precursor is made of silicone hydrogel.
Each of the first gel precursor and the second gel precursor comprises hydrophilic monomers, a cross-linking agent, an initiator, and a solvent.
The hydrophilic monomers may be selected from a group consisting of methacryloxyalkylsiloxanes, 3-methacryloxypropylpentamethyldisiloxane, bis(methacryloxypropyl)tetramethyl-disiloxane, monomethacrylatedpolydimethylsiloxane, mercapto-terminatedpolydimethylsiloxane, N-[tris(trimethylsiloxy)silylpropyl]acrylamide, N-[tris(trimethylsiloxy)silylpropyl]methacrylamide, tris(pentamethyldisiloxyanyl)-3-methacrylatopropylsilane (T2), 3-methacryloxypropyletris(trimethylsiloxy)silane, 2-hydroxyethylmethacrylate (HEMA), hydroxyethyl acrylate, hydroxypropyl acrylate, hydroxypropyl methacrylate (HPMA), trimethylammonium 2-hydroxy propylmethacrylate hydrochloride, dimethylaminoethyl methacrylate (DMAEMA), dimethylaminoethylmethacrylamide, acrylamide, methacrylamide, allyl alcohol, vinylpyridine, glycerol methacrylate, N-(1,1dimethyl-3-oxobutyl)acrylamide, N-vinyl-2-pyrrolidone (NVP), acrylic acid, methacrylic acid, and N,N-dimethyacrylamide (DMA), or any combination thereof.
The initiator may be a photoinitiator or a thermal initiator.
The photoinitiator may be selected from a group consisting of benzoin methyl ether, diethoxyacetophenone, a benzoylphosphine oxide initiator, ethyl 2-dimethylaminobenzoate, 2-isopropylthioxanthone, 1-hydroxycyclohexyl phenyl ketone, Darocur type initiator and Irgacur type initiator. In at least one exemplary embodiment, the photoinitiator is selected from Darocur-1173, Darocur-2959, and Irgacure-1173. The benzoylphosphine oxide initiator may be selected from a group consisting of 2,4,6-trimethylbenzoyldiphenylophosphine oxide, bis-(2,6-dichlorobenzoyl)-4-N-propylphenylphosphine oxide, and bis-(2,6-dichlorobenzoyl)-4-N-butylphenylphosphine oxide, or any combination thereof.
The thermal initiator may be selected from a group consisting of 2,2′-azobis (2,4-dimethylpentanenitrile), 2,2′-azobis (2-methylpropanenitrile), 2,2′-azobis (2-methylbutanenitrile), azobisisobutyronite (AIBN), and peroxides such as benzoyl peroxide, or any combination thereof.
The cross-linking agent may be selected from a group consisting of ethylene glycol dimethacrylate (EGDMA), trimethylolpropane trimethacrylate (TMPTMA), tri(ethylene glycol) dimethacrylate (TEGDMA), tri(ethylene glycol) divinyl ether (TEGDVE), and trimethylene glycol dimethacrylate, or any combination thereof.
In at least one exemplary embodiment, the solvent is glycerol. In another exemplary embodiment, the solvent may be tripropylene glycol methyl ether, cyclohexanol, or cyclopentanol.
At block 203, the gel precursor mixture in the cavity 310 is centrifuged, to cause a water content of the gel precursor mixture to increase from one side of the gel precursor mixture adjacent to the first molding surface 311 to the other side of the gel precursor mixture away from the first molding surface 311. That is, the water content of the gel precursor mixture emerges in gradient distribution from one side of the gel precursor mixture adjacent to the first molding surface 311 to the other side of the gel precursor mixture away from the first molding surface 311.
In at least one exemplary embodiment, the gel precursor mixture is centrifuged at a speed of about 20 rpm to about 500 rpm for a time period less than about 5 min. In the illustrated exemplary embodiment, the gel precursor mixture is centrifuged at a speed of about 150 rpm to about 200 rpm for about 1.5 min to about 4 min.
At block 204, referring to
An outer surface 13 of the contact lens 1 faces to the first molding surface 311. An inner surface 11 of the contact lens 1 faces to the second molding surface 332. A water content of the contact lens 1 increases from the outer surface 13 to the inner surface 11.
At block 203′, the mold core 330 is inserted into the cavity 310, and the gel precursor mixture in the cavity 310 is centrifuged, to cause a water content of the gel precursor mixture to increase from one side of the gel precursor mixture adjacent to the first molding surface 311 to the other side of the gel precursor mixture away from the first molding surface 311.
In at least one exemplary embodiment, the gel precursor mixture is centrifuged at a speed of about 20 rpm to about 500 rpm for a time period less than about 5 min. In the illustrated exemplary embodiment, the gel precursor mixture is centrifuged at a speed of about 150 rpm to about 200 rpm for about 1.5 min to about 4 min.
At block 204′, the gel precursor mixture is exposed to ultraviolet radiation or is heated, to cause the gel precursor mixture to undergo a polymerization reaction, thereby forming the contact lens 1.
It is to be understood, even though information and advantages of the present embodiments have been set forth in the foregoing description, together with details of the structures and functions of the present embodiments, the disclosure is illustrative only; changes may be made in detail, especially in matters of shape, size, and arrangement of parts within the principles of the present embodiments to the full extent indicated by the plain meaning of the terms in which the appended claims are expressed.
Number | Date | Country | Kind |
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106106492 | Feb 2017 | TW | national |