The present invention relates to a container closure device capable of dispensing metered amounts of liquid inside a container upon closure.
A variety of packaging materials represented by devices such as stoppers, lid seals, seals, caps, lids, plugs and valves designed to close bottles, flask, jars, boxes, cans, barrels, tanks, tubs and other containers used to package and store food, dietary products and cosmetic products are commercially available. A container is generally defined as an assembly of materials designed to receive, contain and protect a good intended to be stored, transported and opened by the consumer.
A suitable container may contribute to the preservation of its contents by forming a physical barrier to for example, external germs and microbes, moisture and direct sun-light. The barrier afforded by the container is breached upon opening, whereupon the contents may be exposed to air, which may initiate and/or quicken spoilage. A suitable container closure device, such as a screw-on cap, allows the opening and re-closure of the container, such as a bottle or jar, limiting the exposure and possibly extending the open shelf-life. The open shelf-life is defined as the time during which the contents are considered safe to consume after opening the container for the first time. For example, many food products have a maximum ‘open’ shelf-life during which they are considered safe to use after the container is opened for the first time by the consumer.
A known method to extend the open shelf-life is to mix chemical preservatives directly into the food product during manufacture such as antioxidants and antimicrobial compounds. However, the presence of preservatives, especially artificial preservatives in foods, is disliked by consumers and is considered unhealthy. Furthermore, typically a relatively large amount of preservatives are mixed throughout the product since it is not known beforehand which parts of the contents may experience exposure (e.g. surface layer).
US 2008/0169217 discloses a closure device capable of releasing preservatives directly on the surface of a product in a container (i.e. the contents) upon closing of the container. Most of the preservatives held by the spongy material of the closure device are released into the container during the first closing action of the container with the closure device.
In addition, depending on the shape of the container neck the spongy material can be completely compressed, thereby forcing any remaining preservatives upon a first closing action. For example, a container can have an external thread, which does not run up to the mouth of the container, but leaves a smooth and relatively long (unthreaded) neck area. With such a container, the mouth of the container can completely push superimposed layer 6b up against the interior roof of the cap, and therewith completely compress the spongy material.
The release of most of the preservatives during the first closing action is undesirable. It may lead to a high local concentration on the surface (i.e. top-layer) of the product, which in turn may result in an off-taste when food is sampled by the consumer. Furthermore, when the top-layer of the food product is consumed the level of preservatives remaining in the food product may drop below their effective concentration.
WO 01/68470 discloses a device capable of releasing a diffused gaseous aromatic material during several successive opening actions of a container. The closure device comprises an expandable/contractible hollow, which fills with gas evaporated from an impregnated body when the device is in place on the container (i.e. container is closed). When the container is opened gaseous material is expelled from the hollow into the headspace of the container.
Said closure device neither enables dispensing of liquid material nor teaches how to dispense material during closure of a container. Since the dispensed material is released by evaporation from an impregnated body, it is unlikely the device is capable of releasing a significant amount of material during each of several closing actions when performed in quick succession.
It is an object of the present invention to provide a container closure device capable of dispensing a metered amount of liquid into a container during several successive closing actions.
It is a further object of the present invention to provide a container closure device capable of dispensing a metered amount of liquid into a container during several successive closing actions even when performed in quick succession.
It is a further object of the invention to provide a container closure device capable of dispensing a metered amount of liquid and to subsequently allow contact of the dispensed material to contact the container contents in gaseous form.
It is a further object of the invention to prolong the open shelf-life of spoilage sensitive products inside a container.
We have met these objectives by the closure device of the present invention, which is capable of dispensing a metered amount of a liquid into a container during each closing action for several successive closing actions. The closure device comprises a cap wall, a deformable reservoir capable of being filled with a liquid; and a rigid plate with one or more perforations. Upon closure the deformable reservoir is compressed by being squeezed between the rigid plate and the cap wall. The rigid plate is capable of compressing the reservoir up to 50 volume percent of the uncompressed volume and the rigid plate is adjustable to a pre-determined level. Therefore, the closure device according to the invention prevents a complete compression of the reservoir during a closing action. This enables the device to dispense a metered amount of liquid into the container and do so at least a second time. The closure device according to the invention is in that the deformable reservoir is also elastic and capable of re-attaining its uncompressed volume when the container is opened.
Accordingly in a first aspect the present invention relates to a container closure device capable of dispensing metered amounts of a liquid into a container, wherein said closure device comprises:
It was further found that a closure device according to the invention may suitably be filled with a preservative and used to prolong the open shelf-life of spoilage sensitive content of the container. Upon each closing action of the container, at least for the first two closing actions with the closure device, the container interior and its contents may be treated with liquid dispensed from the reservoir, such as a preservative.
Accordingly in a second aspect the present invention relates to a process to prolong the open shelf-life of spoilage sensitive contents held by a container comprising the step of closing the container with a closure device according to the invention.
The closure device according to the present invention is intended to include any form of closure for a container, and preferably includes various kinds of caps such as screw-caps, push-on caps, composite caps having a retractable pouring spout and the like. Also the invention is applicable to any type of container, though containers having a mouth-like opening such as bottles and jars are preferred. Other types of containers such as drums, tubs or cans are also within the ambit of the present invention. Preferably the closure device is applied to containers comprising foods, but non-food spoilage sensitive products also fall within the ambit of the invention. Solid products, semi-solid, semi-liquid as well as liquid products are applicable to the utilisation of the present invention.
According to the invention liquid is dispensed into the container, which is typically the headspace of the container. The headspace generally indicates the region of the interior of the container above the level of any product contained therein. Also encompassed is the situation wherein liquid from the reservoir is dispensed into a structure to evaporate, which allows at least part of the dispensed liquid to contact the container contents in gaseous form by diffusion. For the purpose of the present invention with ‘dispensed into the container’ is implied the transfer of liquid material from the reservoir through the one or more perforations of the rigid plate, such that a metered amount of liquid is capable of contacting to container contents (in liquid and/or gaseous form).
Embodiments of the present invention will now be described, by way of example, with reference to the accompanying drawings, in which;
According to a first general preferred but not exclusive embodiment of the closure device according to the invention the screw-cap according to
The rigid plate (4, 14) is so arranged as to be adjustable relative to the cap wall (3) and capable of compressing (i.e. reducing the volume of) the reservoir (5, 13). Typically the force of compression of the reservoir is provided by the muscle power of the consumer closing the container with the closure device. During a closing action the reservoir (5, 13) is compressed between the rigid plate (4, 14) and preferably the wall (3) of the closure device. The wall of the closure device (3) preferably is made at least partly of a rigid material. The rigid plate (4, 14) may lend its rigidity by the presence of any suitable rigid material such as metal and/or hard polymer. More preferably the rigid plate (4, 14) is capable of providing an air-tight seal of the mouth of the container opening (10). For example, the surface of the rigid plate (4) which may abut the container mouth (10) when the closure device is in place may be coated by a rubber and/or silicon layer. Preferably the closure device is made of materials which are suitable for use in food containers, such as materials which are non-toxic.
The rigid plate (4, 14) is adjustable to a predetermined level and may maximally compress the reservoir (5, 13) to 50 volume percent of the initial (i.e. uncompressed) volume. The predetermined level of the rigid plate (4, 14) may be established by way the hard ridge (7) or other protrusion extending from the cap wall (3) or in any other suitable way which limits the movement of the rigid plate (4, 14). It will be appreciated that the number of metered dispensing actions will depend on the actual level of compression of the reservoir (5, 13). Preferably the maximum compression of the reservoir (5, 13) is 1 to 35 volume percent, more preferably 5 to 25 volume percent, even more preferably 8 to 20 volume percent and still more preferably from 10 to 15 volume percent. When the reservoir (5, 13) is compressed by volume percent this indicates that the compressed reservoir has 65 percent of the volume of the non-compressed reservoir. For example when the reservoir (5, 13) is compressed by 15 volume percent this indicates that the reservoir has 85 percent of the volume of the uncompressed reservoir. Preferably in case the reservoir (5, 13) of the closure device according to the invention is completely filled with liquid, the device is capable of dispensing a metered amount of liquid during 1 to 50, more preferably 2 to 25, even more preferably 3 to 12 and still more preferably 4 to 6 successive closing actions.
The rigid plate (4, 14) of the enclosure device according to the invention comprises one or more perforations (6) capable of allowing liquid to transfer from the reservoir (5, 13) into the container during active compression. Active compression refers to the time during which the size of the reservoir (5, 13) decreases in volume. Once the closure device is in place on the container (e.g. as shown in
Preferably the reservoir (5, 13) comprises an absorbent material and more preferably comprises a material with an open cell structure, a sponge-like structure or a low-density fibre structure or combinations thereof. Examples of low-density fibre structures are a piece of cotton and a piece of cloth. Preferably said open cell, sponge-like and/or low-density fibre structures comprise, more preferably are essentially made of, polymers and/or natural polymers, even more preferably comprise, still even more preferably are essentially made of, compounds selected from the list consisting of polypropylene, polyurethane, polyvinyl, polysulphone, polymers of starch, cellulose, agarose, casein, chitosan or lactic acid and combinations thereof.
The reservoir (5, 13) is deformable and elastic. A closed container (
When the container is opened, the expansion of the reservoir (5, 13) adjusts the position of rigid plate (4, 14) and effectively re-sets the closure device to dispense another metered amount. Throughout this specification, unless specifically indicated, the uncompressed volume of the reservoir (5, 13) is defined as the maximum volume of the reservoir attainable when the closure device is not in place on the container (e.g. when the container is completely opened,
A metered amount of liquid is defined as an amount falling within a chosen minimum and maximum amount. Subject to considerations such as the specific application of the closing device, the volume of container, the volume of the reservoir (5, 13), the concentration of an active in the liquid, if any, and the desired number of dispensing actions the minimum and maximum volume chosen to form the metered amount of liquid may vary. Preferably a metered amount is 0.1 to 50 volume percent, more preferably 0.5 to 25 volume percent, even more preferably 0.75 to 15 volume percent and still more preferably 1 to 5 volume percent of the volume of the liquid with which the closure device is initially loaded.
Preferably the ratio of the volume of the uncompressed reservoir (5, 13) to the volume of the container is 0.001:1 to 1:1, more preferably 0.01:1 to 2:1, even more preferably 0.05:1 to 3:1 and still even more preferably is 0.1:1 to 5:1.
It will be appreciated that preferably before the container is opened for the first time by the consumer, the reservoir (5, 13) of the closure device is filled as far as possible with liquid material to be dispensed. Also encompassed are embodiments of the closure device which allow refilling of the reservoir (5, 13) with liquid material. The maximum volume of liquid with which the reservoir (5, 13) may be filled depends on the structure of the reservoir, such as the density of the reservoir. The density of the reservoir (5, 13) may affect the deformable and elastic properties of the reservoir. To strike a balance between the deformable and elastic properties of the reservoir (5, 13) and the suitable volume of liquid to provide a number of metered dispensing actions, preferably the reservoir is filled with 10 to 95 volume percent, more preferably 20 to 80 volume percent, even more preferably 30 to 70 volume percent and still more preferably 30 to 60 volume percent of liquid based on the uncompressed volume of the reservoir (5, 13).
The liquid which may be present in the reservoir (5, 13) may have any suitable chemical property and for example form a watery or oily solution. For example, the liquid may be an organic and/or inorganic solvent or comprises a mixture of solvents. For example the liquid may be a volatile material. It will be appreciated that preferably the liquid does not compromise the structural integrity of the closure device, for example by dissolving the structural components of the reservoir (5, 13). The liquid may be a mixture of liquids. Preferably the reservoir (5, 13) comprises a liquid and more preferably a liquid which is a water-continuous system and even more preferably a liquid which is a Newtonian fluid. Preferably the liquid comprises one or more actives selected from the list consisting of dietary supplements, antioxidants, flavours, colouring agents, preservatives, thickeners, surfactants, dispersing agents, release agents, diffusing agents and stabilisers and combinations thereof, more preferably one or more antimicrobials and even more preferably bacteriocides or fungicides and combinations thereof. Preferably the liquid comprises compounds selected from the list consisting of lactic acid, acetic acid, peracetic acid, tartaric acid, benzoic acid, sodium and potassium sulphites, sodium and potassium nitrites, sodium and potassium bicarbonate, sodium and potassium sorbates, sodium and potassium benzoates, hydroxyl-8 quinoline, peroxide, salts, ethanol, sodium hypochlorite, nisin and other bacteriocins and combinations thereof. The liquid may essentially consist of said compounds in case these are liquid themselves. The actives may be dissolved and/or suspended in the liquid according to the standard way in accordance with the chosen ingredients. It will be appreciated that the particle size of any suspended actives is suitably small as to prevent clogging of the one or more perforations (6) of the rigid plate (4, 14). Preferably suspended particles when present in the liquid have a diameter of at most 50 micrometer, more preferably at most 10 micrometer and even more preferably at most 5 micrometer. It will be further appreciated that based on the specific properties of the liquid, liquid may be dispensed directly onto the product or may suitably be dispensed onto a porous structure (12) to allow evaporation. For example, when the liquid and/or any compounds present in the liquid leave a residue when the liquid evaporates (e.g. salts) preferably these kinds of liquids are not dispensed into a porous structure (12) but dispensed directly onto the contents more preferably as liquid drops.
By virtue of its pump-driven dispensing action, it was found that the closure cap according to the invention is especially suitable for dispensing metered amounts of viscous liquids. Preferably the reservoir (5, 13) comprises a liquid with a viscosity of 0.001 to 100000 mPa·s, more preferably 0.1 to 1000 mPa·s, even more preferably 0.2 to 100 mPa·s and still even more preferably 0.5 to 50 mPa·s at a temperature of 2 to 40 degrees Celsius, and more preferably at a temperature of 15 to 30 degrees Celsius.
It will be appreciated that the porous structure (12) is positioned such that it may contact at least part, preferably all, of the liquid released from the reservoir (5, 13). The porous structure (12) is preferably positioned against the rigid plate (4, 14) on the side opposite the reservoir (5, 13) and overlays the one or more perforations (6) or valves (11) or combinations thereof and preferably overlays all the perforations (6) or valves (11) or combinations thereof.
The characteristic advantage of the caps shown in
Preferably at least one, more preferably at least 50 percent and even more preferably all the perforations (6) are formed by pressure operated valves (11). A pressure operated valve restricts transfer of liquid and gas from the reservoir (13) through a perforation to the time of active compression of the reservoir (e.g. when the pressure in the reservoir is higher than the pressure in the container). Said valves are known to the person skilled in the art and may reduce liquid lost during storage due to leakage and/or evaporation. Furthermore, the use of pressure operated valves (11) may widen the scope of suitable liquids (e.g. liquids with a very low viscosity and/or liquid having a high vapour pressure). Throughout this specification with perforations (6) are indicated holes in the rigid plate (4, 14). It will be appreciated that in case perforations are formed of pressure operated valves (11) said perforations (i.e. holes) form typically only at specific times (e.g. during the act of closing),It will be further appreciated that upon opening of the closure device the deformable and elastic reservoir (13) will expand, creating a pressure difference over the rigid plate whereby air may enter the reservoir through the valve (11) allowing the closure device to reset.
Suitably the rigid plate (4, 14) may be covered by a removable gas- and/or liquid impermeable film to prevent loss of liquid material during storage and which may be removed by the consumer before (the first time) use.
Liquid may be dispensed into a porous structure (12). Liquid may be release from the porous structure (12) into the container by dripping (i.e. as droplets). As such it may effectively be dosed onto the surface of the container contents. Liquid present in the porous structure (12) may leave the structure as a gas, for example by evaporation. As a gas the dispensed material may efficiently distribute over the entire air-exposed surface of the container (e.g. headspace, the interior face of the container walls as well as its contents). Liquid present in the porous structure (12) may also leave the structure by a combination of dripping and evaporation. A combination of dripping and evaporation enables distribution of the dispensed material over the entire air-exposed surface of the container but with a relatively high concentration dispensed onto the surface of the container contents (e.g. a food).
Dripping of dispensed liquid directly onto the container contents may lead to a high local concentration (e.g. on the surface), off-taste and/or a reduced overall effectiveness of the dispensed material (e.g. preservative). Preferably at least part of the dispensed liquid is transformed into a gas, for example by evaporation) before coming into contact with the contents of the container. Therefore, preferably liquid is dispensed from the reservoir (13) into a structure (12) which allows liquid to transform into a gas. Suitably a porous structure (12) may be formed by a sponge-like body or fibrous structure, such as a piece of cloth, which may be impregnated by the dispensed liquid and positioned to be in contact with the interior (e.g. headspace) of the container. Suitably such a structure (12) may be formed by a sponge-like disk attached to the face of the rigid plate (14) which is exposed to the container interior. Preferably the closure device according to the invention comprises a porous structure (12) and more preferably a porous structure comprising, even more preferably essentially formed by, a sponge-like structure, a low-density fibre structure or combinations thereof.
A closure device according to the invention is capable of dispensing a metered amount of preservative liquid (i.e. a liquid which is preservative itself and/or comprises a preservative) into the container. This allows the areas of the container and the contents therein which have come into contact with the air (e.g. surface of a sauce such as a mayonnaise) to be treated with preservative. Furthermore, the container interior and its contents may be treated with said material during several closing actions. The dispensed material may contact the contents of the container in the form of liquid, but preferably the dispensed liquid is first transformed at least partially into a gaseous form before contacting the contents. Said transformation may suitably occur in a porous structure (12). Therefore, by virtue of allowing treatment and re-treatment of the air-exposed area with a preservative the open shelf-life of the container contents may be prolonged. Accordingly the present invention encompasses a method to prolong the open shelf-life of spoilage sensitive contents, such as food, held in a container by closing the container with a closure device according to the invention wherein the reservoir (5, 13) comprises a preservative liquid.
In more traditional methods to improve the open shelf-life of foods, preservatives (i.e. chemical preservatives) may be completely mixed throughout the food product during manufacture. Mixing of a relatively large amount of preservatives is required since it is not know beforehand which parts of the product will be directly exposed (e.g. which parts of the product will form part of an exposed surface during use) and which parts will not. By use of the closure device according to the invention, preservatives are added to the area of the container and its contents which have been directly exposed to the air (e.g. the surface). Therefore a lower amount of total preservatives may be required to provide an adequate open shelf-life. The present invention encompasses a method to reduce the amount of required preservative to provide a suitable open shelf-life of spoilage-sensitive food by closing the container by a closure device according to the invention. It will be appreciated that in a method according to the invention to reduce the amount of chemical preservatives preferably, during manufacturing the food contents will have undergone one or more physical preservation processes such as, heating, irradiation, drying and/or freezing.
Preferably the methods to prolong the open shelf-life and/or reduce the amount of preservative are applied to a container comprising an edible product comprising 5 to 95 weight percent of water, more preferably an edible product selected from the list consisting of sauces, purees, candied fruits, jams, cooked vegetables, compotes, water-in-oil emulsions, oil-in-water emulsions, pastes, creams, dairy products and food concentrates and combinations thereof and even more preferably comprises an edible product selected from the list consisting of dairy based spreads, low-fat margarines, margarines, preservative free margarines, mayonnaise, dressings, puddings, tomato sauce, beverages such as teas and milk teas, condiments such as pesto sauce, jelly-based soup-, gravy- and sauce concentrates and combinations thereof.
Number | Date | Country | Kind |
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11195070.5 | Dec 2011 | EP | regional |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/EP2012/072700 | 11/15/2012 | WO | 00 | 6/17/2014 |