The present invention relates to a coating system and corresponding process for containers made of plastic material, such as PET bottles, made by blow moulding.
One-stage or blowing machines are currently used for the production of food-grade containers in plastic materials of various shapes, such as for example bottles and pots made of PET, PP, HDPE, PEN, etc.
A one-stage machine for the production of containers, such as bottles, pots, etc., is a system which, through an injection and subsequent stretching and blowing sequence, goes from transforming raw plastic material granules to producing a blown container in its final shape all in one machine.
A blowing machine is, instead, an apparatus which, through a process of heating and subsequent stretching and blowing, transforms preforms, obtained separately by means of an injection machine, into blown containers. This is known as a two-stage machine.
In some cases, when a particular performance is required for such containers, for example in relation to the particular type of liquid that they must contain, the blowing step is followed by a coating operation. Products particularly suitable for making the container impermeable to gas, such as oxygen and/or carbon dioxide, are employed for this application. The problem of gas permeability of the container walls is particularly felt, for example, for bottles intended to contain carbonated beverages, but also for other food products and beverages in which oxidation causes a decay of the organoleptic properties of the products thus reducing its shelf-life. In other cases, the coating is performed simply in order to decorate the outside of the containers.
Coating is the application of an external protection consisting of one or more paint layers to a container, which increases the oxygen and/or carbon dioxide barrier properties thereof without altering, or even improving, the other mechanical and strength properties of the non-treated container.
A coating system is, instead, an industrial production line adapted to perform a coating process with a specific continuity and frequency on containers of predetermined features coming either directly from an output section of the one-stage or blowing machines or from storage areas, e.g. silos.
The known coating systems may have a size varying widely according also to the required production rate of the systems, which today varies in the range from hundreds to tens of thousands of bottles per hour.
Such systems are therefore highly automated and are generally controlled by dedicated computers or general application computers which, in particular cases, may also be personal computers running specifically developed software.
The common structure of these systems comprises at least one loading station of the containers to be coated, a coating station, a coating reticulation station, comprising for example ovens of various types depending on the paint employed, and also an unloading or transfer station of the coated containers to other machines. In such systems, the containers are conveyed along the various stations forming the system by means of chains provided with gripping devices, in particular the so-called preform holders, or conveyor belts on which the containers rest.
Given the increasing diffusion of plastic containers on certain markets, one-stage or blowing machines with increasingly high production rates are made today, but the existing coating systems do not efficiently allow continuous operation of an elaborate process, such as the coating process, which envisages coating, drying and reticulating the paint at such high production rates. Indeed, coatings or paints increasingly effective for extending the shelf-life of products in containers have been developed, but such paints require more complex and more numerous operations than in the past to complete the coating process. In order to perform such operations, a high consumption of energy and considerable time is required to the detriment of production speed in such systems, this speed further decreasing if more than one paint layer is applied and reticulated. Furthermore, it is desirable to have the opportunity to feed a coating system directly with containers from a one-stage or blowing machine because of the advantages that this entails, including a better level of cleanliness of the containers themselves, with consequent better paint adhesion and lower risk of defects. On the other hand, the better paint adhesion causes a more uniform distribution and, therefore, reticulation of the same, with consequent improved quality of the general performance of the paint (barrier effect, chemical resistance, mechanical strength, aesthetic qualities, etc.). In this way, the number of wastes would also be reduced. Disadvantageously, the existing coating systems, in particular those capable of higher production rates, also envisage high energy consumption, which causes a distinctively unfavourable energy balance, and exhibit a very large structure with processing stations occupying large surfaces, therefore also determining high construction costs. The need is therefore felt to obtain a coating system and corresponding process capable of overcoming the aforesaid drawback.
The primary object of the present invention is to obtain a coating system for blown plastic material containers, which, thanks in particular to the paint coating drying and reticulating oven configuration, is capable of considerably improving the energy balance while ensuring production rates and flexibility so as to allow efficient coupling to the most advanced one-stage machines or to blowing machines.
Another object of the invention is to obtain a coating system which, despite the high production rate, has a compact global structure and low implementation costs.
A further object of the invention is to make a coating process which allows an effective and rapid application of several paint layers on plastic containers.
The present invention, therefore, intends to reach the above discussed objects by means of a coating system for blown plastic material containers which presents the features of claim 5 and a corresponding coating process which presents, instead, the features of claim 15. The system of the invention comprises a first oven and a second drying-reticulating oven of a first and second paint layer respectively, said first and second oven having a modular structure comprising one or more thermal treatment tunnels according to claim 1.
The production rate of the system of the invention may vary in the range of approximately 6000 to 42000 bottles/hour and may even be higher. Advantageously, thanks to its innovative features, the system according to the invention may be configured so as to be adapted to the various production needs, and may be configured in increasing steps, for example from 6000 bottles to 42000 bottles per hour.
The number of thermal treatment tunnels can also be increased without needing to redesign the system or without major structural interventions, maintaining the surface occupied by the system virtually unaltered. Such modular system facilitates system range expansion, allowing to increase or decrease the production rate.
Advantageously, the reticulation and drying ovens for the paint layers applied to the containers envisage two levels, each level comprising two banks, with the result of a considerable space saving.
In order to reduce energy consumption, energy recovery of infrared radiation, used in some portions of the ovens, not absorbed by the container/coating system, is advantageously envisaged. This recovery is performed by means of air/water heat exchangers appropriately arranged near the banks on which the containers pass. This energy recovery may also concern UV radiation not absorbed by the containers.
A further advantage is represented by the possibility of adjusting the air temperature within the ovens by operating on the feeding temperature of the water to the air/water heat exchangers.
Mixing systems, independent for the infrared area and the hot air area, are envisaged to mix at least part of the exhausted hot air flow from the ovens with the air taken from the outside before it is conveyed back into the oven.
Furthermore, the presence of at least one fan impeller, arranged in a central area of the ovens or of the single thermal treatment tunnels, allows a uniform distribution of the air to the oven compartments or sectors, by exploiting the symmetries and the different configurations envisaged by the internal structure of the ovens themselves.
The dependent claims describe preferred embodiments of the invention.
Further features and advantages of the invention will be more apparent in light of the detailed description of a preferred, but not exclusive, embodiment, of a coating system illustrated by way of non-limitative example, with the aid of the accompanying drawings, in which:
a is a schematic sectional view of a first part of said first station;
b is a schematic sectional view of a second part of said first station;
With reference to the figures, there is shown a preferred embodiment of a coating system according to the present invention, in particular a system envisaging the application of a two-layer paint coating on containers or bottles made of plastic material, for example PET, PP, HDPE, etc.
The first layer to be applied, named base coating, is generally a type of coating having O2 and/or CO2 barrier properties, simply named barrier coating. The second layer, named top coating, is generally a type of protective paint. The number of coats applied to the containers may be equal to one or greater than two.
The coating system according to the invention, shown as a whole by reference 1, comprises:
The loading/unloading station 2 comprises a loading drum capable of:
Preferably, the containers are held in vertical position with respect to the single transfer chain 10 by means of a series of fastening supports or grips, for example preform holders, uniformly spaced out along the chain itself. Advantageously, the loading drum is such that:
The optional surface treatment or pre-treatment station immediately downstream of the loading drum envisages an activation system of the container surface by means of methods such as crown effect, plasma, UV, skin-drying, for increasing the container wettability before applying paint and therefore obtaining a better result. In particular, PP containers must be activated by passing through a ionised environment created by a series of customised electrodes (crown effect).
The estimated treatment time is approximately 4 s, or less in the case of a plasma effect surface activation system.
If the containers come from storage areas, these may be subjected in this same station to a deionised air blowing operation to remove possible electrostatic charges, dusts, etc. which are deposited on the external surface of the containers. When required by the process, the subsequent step consists in subjecting the containers to an electrical charge in an electrical field, for example of approximately 10-15 kV, to charge the containers with an appropriate electrical current before sending them to the following step in the coating station.
The coating station 3 for the application of the barrier or top coating layers, shown in figures from 3 to 5b, comprises an application machine or roundabout 4. Such application roundabout 4 is a rotary machine which receives containers 9 and in turn comprises:
Underneath the first and second immersion wheels or drums 5, 7, around which said transfer chain 10 is wound to change the direction of motion as shown in
With reference to
The application roundabout 4 performs the following functions:
The total immersion stroke depends on the adopted mechanical configuration and is subdivided into two parts: a first approach stroke of the fluid front in tank 11 to container 9 in which the average raising speed must be the maximum speed compatible with the reliability of the mechanical system; and a second stroke in which the immersion process, in which the average speed of immersion and emersion must be no more than 300 mm/sec, is performed. The immersion stroke depends on the geometric configuration of the tank in which immersion occurs. The cam system must maintain the container in immersed position for approximately 0.2 seconds.
In a first variant (not shown), the coating is supplied to the tanks by means of a delivery pump or of a plurality of delivery pumps if the dimensions of the system so require, and a revolving joint.
The delivery pump continuously supplies coating to tanks 11 by means of the revolving joint through a first chamber in the joint which envisages attachments for the flexible delivery tubes communicating with the tanks. The revolving joint is also provided with a second chamber, separate from the first, which instead envisages attachments for the flexible return tubes, the latter also communicating with the tanks, for evacuating the excess paint using a suction pump. The rotating joint is connected with its lower end by means of respective delivery and return tubes of the coating to a collection tank, arranged in an intermediate position between the revolving joints themselves and a central tank of the base coating (not shown).
In a second variant, shown in
The two communicating vessel feeding systems and a pump with revolving joint may also be appropriately used in combination, if this is advantageous.
Progressively, as the containers leave the first immersion wheel 5, chain 10 starts winding about the first spinning wheel 6 to adjust the thickness of the base coat of barrier paint. In this wheel 6, each container, during its advancement, is turned about its axis for a certain period of time within a respective cell or protective shield 60 (
Such cell advantageously has a system for the total recovery of excess paint eliminated by the spinner itself. Such system comprises either a revolving joint whose lower end is connected by means of paint return tubes to the collection tank or, as shown in
The rotation speed of the containers during the spinning step is adjustable in the range from 200 to 3000 revolutions per minute and is independent from the rotation speed of roundabout 4. The spinning time is approximately 1 second. The applied wet barrier paint film has a thickness which may vary from 100 to 20 microns with a tolerance of 5 microns; the thickness of the wet film must be maintained within the required tolerances on the entire surface of the container and for the entire duration of operation of the machine.
Having applied the first paint layer on the containers by immersion and having the containers been spun in order to eliminate the excess paint itself, the transfer chain 10 conveys the containers to a base coat drying-reticulation oven 14, simply named base oven 14. The aim of base oven 14 is to remove a solvent, generally water, from the barrier paint and to fully polymerise the latter. The maximum temperature allowed for the coated surface of the container is 65±2° C.; the maximum temperature allowed for the non-coated parts, i.e. neck and neck ring, is 55±2° C.
Before introduction into the base oven 14, the direction of motion of transfer chain 10 is deviated first vertically and then again horizontally so that the grips or preform holders are turned in order to place the containers with their longitudinal axis in horizontal position, as shown for example in
The drying step, whose purpose is to remove the solvent, generally water, from the barrier paint is based on the combined use of infrared radiation (IR) and air convection. The containers are subjected to drying for the time required for the solvent to evaporate sufficiently for an optimal completion of the subsequent process steps, for example to prevent the formation of bubbles during the subsequent reticulation step. Furthermore, the paint itself could require a certain time to flow evenly on the surface of the container.
The part of the base oven 14 dedicated to drying is subdivided into two main areas:
The chain firstly passes through the IR area of the base oven 14, indicated as a whole by reference 15, a cross-section of which is shown in
In the preferred embodiment, IR area 15 is provided with:
The IR modules, delimited on the top and on the bottom by a perforated metallic sheet 36, for example aluminium, each comprise a battery of IR lamps 32, e.g. quartz lamps at a temperature of 1800° K of the low thermal inertia type, known as ‘medium wave IR’ lamps, or advantageously lamps known as ‘short wave’ lamps with a temperature of 2400° K.
Within the oven, the air is aspirated through filter 31 longitudinally along axis X of impeller 30 and then ejected by the same impeller at a 90° angle with respect to said axis. The side flows of air 40 thus generated are split, by impacting against the side walls of the base oven, into first upward flows 41 and second downward flows 42 through the IR modules of upper banks 20″, 20′″ and lower banks 20′, 20, respectively. In this way, the air flow within IR area 15 is advantageously optimised: the presence of fan impeller 30, arranged in the central area of the IR area, indeed allows a uniform distribution of the air to the four compartments of the oven by exploiting the symmetries of the structure.
Before reaching the containers, air flows 41, 42 respectively pass through a heat exchanger, such as for example an air-water finned heat exchanger or radiator 33, having the function of energy recovery of the radiative heat not absorbed by the container/coating system, thus advantageously implementing a heat regulating action of the air in the oven itself.
At the outlet of IR area 15, container 9 remains on the upper right bank 20′″ and enters hot air area 16, where the heat of previous radiators 33 is conveyed at a predetermined temperature and speed. In this embodiment, hot air area 16 extends on banks 20′″, 20″ and 20′ connected by curves 24, 25 and 26, each of said banks being subdivided into modules, for example into fifteen modules.
A cross-section of the part of base oven 14 comprising the hot air area 16 is shown in
The drying step times, at nominal rate, are advantageously subdivided as follows:
The thermal features of the drying step are:
The part of the base oven 14 dedicated to the barrier paint reticulation is also subdivided into two main areas:
In the preferred embodiment, areas 17 and 18 are both envisaged on lower right bank 20, separated from the other three banks, where hot air flows, by partition walls 27. The cross-section in
The times of the reticulation step are advantageously subdivided as follows:
The thermal features of the reticulation step are:
Base oven 14, in the embodiment shown in
Once the first layer of barrier paint is reticulated on the containers, transfer chain 10 takes the containers from base oven 14 back to coating station 3. At the UV area 18 outlet, chain 10 diverts its direction of motion at first vertically downwards and then again horizontally so that the preform holders are turned in order to place the containers again with their longitudinal axis in vertical position. A second torsion of chain 10 is then induced.
The containers then pass through coating station 3 in vertical position with chain 10 wound about the second immersion wheel 7, underneath which a second plurality of tanks, turning in synchrony with said second immersion wheel 7 and containing the top paint. The top coat is applied also in this case by immersing the containers into said second plurality of tanks similarly as described above for applying the base layer.
Progressively, as the containers leave the second immersion wheel 7, chain 10 starts to wind about the second spinning wheel 8 to adjust the thickness of the top layer of protective paint which occurs similarly as described for the first spinning wheel 6.
The applied wet top paint film has a thickness which may vary from 20 to 10 microns with a tolerance of 2 microns; the thickness of the wet film must be maintained within the required tolerances on the entire surface of the container and for the entire duration of operation of the machine.
Having applied the second paint layer on the containers by immersion and having the containers been spun to eliminate the excess paint itself, transfer chain 10 conveys containers 9 inside a top coating flowing-reticulation or drying-reticulation oven 14′, simply named top oven 14′. The aim of the top oven 14′ is to remove a low-boiling solvent, for example ethanol, from the top paint film, with consequent flow of the film itself, and obtain complete polymerisation of said top paint. The maximum temperature allowed for the coated surface of the container is 65±2° C.; the maximum temperature allowed for non-coated parts, i.e. neck and neck ring, is 55±2° C.
Before being immersed in top oven 14′, the direction of motion of transfer chain 10 is further deviated first vertically upwards and then again horizontally so that the preform holders are turned and place the containers again in position with longitudinal horizontal axis. A third torsion of chain 10 is then induced. The containers then pass through top oven 14′ in horizontal position remaining anchored to transfer chain 10 which follows a two-level course, schematically shown in
In the preferred embodiment, the following are envisaged on lower left bank 50:
The right lower bank 50′ and the right upper bank 50″ are provided with similar hot air modules.
The IR modules, delimited on the top and on the bottom by a perforated metallic sheet 36″, for example aluminium, each comprise a battery of IR lamps 32′, e.g. quartz lamps at a temperature of 1800° K of the low thermal inertia type, known as ‘medium wave IR’ lamps, or advantageously also lamps known as ‘short wave’ lamps with a temperature of 2400° K.
The following are envisaged within flowing-reticulation oven 14′:
The air is aspirated through filter 31″ longitudinally along axis X″ of impeller 30″ and then ejected by the same impeller at a 90° angle with respect to said axis. The side air flows 40″ thus generated are split, by impacting on the side walls of the top oven, into a first upward flow 41″ and second downward flows 42″ through the IR modules and the hot air modules, the latter respectively of banks 50, 50′ and 50″. In this case, the air aspirated by filter 31″ and ejected by impeller 30″ will form on the left side (
In both ovens 14, 14′, and particularly in each of the thermal treatment tunnels forming the modular structure of the ovens, there are advantageously envisaged at least one outlet section, comprising for example one or more adjustable shutters 200, and at least one side discharge conduit 201 for the recovery of exhausted air. The exhausted air discharge system is advantageously envisaged in both ovens 14, 14″; in the case of the base oven 14, the exhausted air will be full of humidity, in the case of the top oven 14′ it will be full of ethanol and/or other solvents.
The flowing step, the purpose of which is to remove the solvent, generally water, from the top paint is therefore based on the combined use of infrared radiation (IR) and hot air convection. The containers are subjected to infrared rays and to hot air for the time needed by the solvent to evaporate sufficiently and allow the concomitant homogenous flow of the top paint on the surface of the container. Also in this case, the completion of the subsequent process steps is thus improved, avoiding the formation of bubbles during the subsequent reticulation.
The top paint is finally reticulated in the upper left bank 50′″, separated as previously mentioned from the other banks by means of partition walls 27′. The following are envisaged in this bank 50′″:
Also in this case, the preferred embodiment envisages an area 17′ comprising a cold air pressurised channel 34′, provided with fans 35′, and an area 18′ comprising medium pressure mercury discharge lamps 28′ and an ozone discharge channel 29′.
The top paint flow-reticulation steps are subdivided as follows:
The thermal features of the flow-reticulation process are:
In the embodiment in
At this point, at the outlet of top oven 14′, the transfer chain 10 is subjected to a fourth and last torsion returning containers 9 fully dry and covered by two paint layers, to a vertical longitudinal axis position. Chain 10 finally reaches loading/unloading station 2 which takes the containers from the chain using appropriate gripping elements and shifts them to one or more downstream conveying lines of predetermined features, which take them to the subsequent processing stations, packing stations, etc. The type of conveying line may be, for example, an air conveyor or a slat conveyor.
Advantageously, in both ovens 14, 14′, containers 9 advance, fixed to the preform holders, in horizontal position: this therefore prevents the containers from being soiled by particles or drops of lubricant or other particles of dirt dropped from the transfer chain 10. In this way, chain 10 may also be abundantly lubricated within the ovens themselves, where the need for lubricant is higher and the danger of soiling the containers with lubricant is therefore also increased, because the oven temperature renders the lubricant less viscous and more fluid.
Advantageously, one or more exhausted air recovery and conditioning stations may be envisaged for both ovens 14, 14′, not shown in the figures, capable of processing high air flows. In these recovery and conditioning stations, there are envisaged systems, independent for the infrared radiation area and for the hot air area, to mix at least part of the exhausted hot air flow from the ovens with the air taken from the outside before it is conveyed back into the oven. Advantageously, in the system of the invention, it is possible to adjust air temperature within the ovens by operating on the feeding temperature of the water to the air/water heat exchangers. Other accessory stations may be envisaged for the coating process according to the invention, among which there are included a paint storage and preparation station and an exhausted air cleaning station for maintaining the emission levels compliant with the standards of the country where the system is installed. Such station may envisage a system for recovering solvents from the exhausted air or a system of burners for the partial recovery of the heating power of the solvent present in the exhausted air to be purified. The arrangement of IR modules, hot air modules, cold air modules and UV modules may be varied on the oven banks as also the times and other parameters of the various coating process phases according to the type of paints used, without departing from the scope of the invention.
Number | Date | Country | Kind |
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RM2006A000277 | May 2006 | IT | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/EP2007/054943 | 5/22/2007 | WO | 00 | 11/24/2008 |