This application is a 371 of International Application No. PCT/FR2019050449, filed Feb. 27, 2019, which claims priority to French Patent Application No. 1852005, filed Mar. 8, 2018, the entire contents of which are incorporated herein by reference.
The invention relates to a container for storing and transporting liquefied gas.
The invention relates more particularly to a container for storing and transporting liquefied gas, in particular cryogenic fluid such as helium, comprising a first, internal reservoir that extends in a longitudinal direction and is intended to store the liquefied gas, a second, external reservoir that is disposed around the first reservoir with a vacuum insulated space between the first and the second reservoir, the container comprising a third, annular reservoir that is disposed around the first reservoir, between the first and the second reservoir, the third, annular reservoir extending around at least a part of the first reservoir and containing a liquefied gas in order to form a heat shield for thermally insulating the first reservoir, the container comprising a device for holding the first and third reservoirs in the second reservoir, the holding system being configured to allow limited travel of the first and third reservoirs in the second reservoir in particular in the longitudinal direction when they undergo dimensional variations caused by temperature variations, the holding system comprising a set of tie rods.
The transport of liquefied gas, in particular helium, generally uses vacuum insulated containers or “iso containers”.
Specifically, it is only possible to transport liquid helium over long distances if the thermal performance levels of the cryogenic storage are excellent. The ingress of heat into a cryogenic container having a capacity of 41 000 l should be around 4.5 W for example.
Radiation represents the most significant contribution of heat ingress. In order to achieve these performance levels, it is necessary to protect the liquid helium reservoir from radiation by an active heat shield (aluminum or copper for example) cooled for example by liquid nitrogen. Cf. for example U.S. Pat. No. 5,005,362.
The flux of the radiation slowly vaporizes the nitrogen. The enthalpy of vaporization keeps the temperature of the shield at around −196° C. The nitrogen thus vaporized is evacuated to the atmosphere through a pipe in order to keep the nitrogen guard at low pressure, typically 0.5 bar. The liquid nitrogen is thus “consumed” during transport. The nitrogen reservoir is dimensioned in terms of the consumption per unit time and the maximum transport duration.
The autonomy of the container is dependent on this nitrogen reserve. Increasing this nitrogen reserve increases the autonomy (the duration for which insulation is guaranteed) but reduces the amount of available space for the interior reservoir storing the helium. For a transport duration of 45 days, the nitrogen reservoir is typically 1200 liters. In order to achieve a transport duration of 75 days, the nitrogen capacity has to be more than 3000 liters.
Moreover, the structural arrangement of these elements (including the pipe) in the external casing has to be able to withstand forces during transport or relative dimensional variations between the outer casing and the internal storage reservoirs (cold state filled with cryogenic fluid or warm state at ambient temperature).
The document U.S. Pat. No. 2,863,297 describes a reservoir comprising a fluid reserve interposed between the outer and inner walls.
However, this solution is inappropriate for addressing all or some of the above constraints.
An aim of the present invention is to remedy all or some of the drawbacks of the prior art that are set out above.
To this end, the container according to the invention, which otherwise conforms with the generic definition thereof given in the above preamble, is essentially characterized in that at least some of the tie rods have a first end connected in an articulated manner to the second reservoir and a second end connected rigidly to the first reservoir or to the third reservoir or to a structural component rigidly connected to said first or third reservoir, said articulated tie rods being movable between two given angular positions that respectively define two distinct positions of the second end of the tie rods and correspond respectively to the extremes of the dimensional variations of the first and third reservoirs with respect to the second reservoir.
Furthermore, embodiments of the invention may have one or more of the following features:
The invention may also relate to any alternative device or process comprising any combination of the features above or below within the scope of the claims.
For a further understanding of the nature and objects for the present invention, reference should be made to the following detailed description, taken in conjunction with the accompanying drawings, in which like elements are given the same or analogous reference numbers and wherein:
The container 1 for storing and transporting liquefied gas, in particular cryogenic fluid such as helium, illustrated in the figures preferably has a cylindrical overall shape that extends in a longitudinal direction A, which is horizontal in the use position.
This container 1 comprises a first, internal reservoir 2, preferably with a cylindrical overall shape, which extends in the longitudinal direction A.
This first reservoir 2, or internal reservoir, is intended to store the liquefied gas (helium or other cryogenic gas/liquid mixture).
The walls of the first reservoir 2 are made for example of a metallic material, for example an austenitic stainless steel or any other appropriate material.
The container 1 comprises a second reservoir 3, or “external” casing, disposed around the first reservoir 1 with a vacuum insulated space between the first 2 and the second 3 reservoir (and one or more layers of insulating material).
The second reservoir 3 has for example a cylindrical overall shape and may be concentric about the first reservoir 1.
The walls of the second reservoir 3 are made for example of a metallic material, for example a steel or austenitic stainless steel or any other appropriate material.
The container 1 comprises a third reservoir 4 disposed around the first reservoir 2, between the first 2 and the second 3 reservoir.
The third reservoir 4 (which is for example annular in section perpendicular to the longitudinal direction A) extends around at least a part of the first reservoir 2 in the longitudinal direction A. Preferably, this third reservoir 4 has a cylindrical shape and can be disposed concentrically around the first reservoir 2. This third reservoir 4, or intermediate reservoir, is intended to contain a liquefied gas, for example nitrogen, in order to form a heat shield ensuring thermal insulation of the first reservoir 2.
For example, the third reservoir 4 may comprise or be made up of two cylindrical shells that are concentrically spaced apart (different diameters) and are connected and closed at their ends by bulkheads. These two cylindrical walls thus form an annular volume having the dual function of storing the liquid nitrogen and of acting as a heat shield for the first reservoir 2.
For a small annular height, for example 40 mm, the volume thus created can be 3100 liters for a 40 foot (approximately 12 meter) ISO container.
Preferably, the container 1 also comprises one or more shielding walls 11, 12 that are thermally connected to the third reservoir 4 and are disposed at the ends of the reservoir between the first 2 and the second 3 reservoir.
These walls 11, 12 (aluminum or copper plates for example) form covers at the ends or bottoms of the container to close the shield around the first reservoir 2. These plates are “thermalized” (that is to say cooled) by the third reservoir 4.
The container 1 comprises a device for holding the first 2 and third 4 reservoirs in the second reservoir 3.
The holding system supports/suspends the 2 and third 4 reservoirs in the second reservoir 3.
This holding system is configured to allow limited travel of the first 2 and third 4 reservoirs in the second reservoir 3, in particular in the longitudinal direction A, when they undergo dimensional variations (expansions/contractions in hot or cold states).
As can be seen in the figures, the holding system comprises a set of tie rods 5, 6, at least some of which have a first end 7 connected in an articulated manner to the second reservoir 3 and a second end 8, 9 connected rigidly to the first reservoir 2 or to the third reservoir 4 (or to a structural component rigidly linked to said first 2 or third 4 reservoir).
As schematically depicted in
As can be seen in
Thus, in this case, the articulated tie rods 5, 6 are preferably situated at the other end (opposite to the fixed link 15), which has at least this degree of longitudinal freedom.
The holding system can have a first set of tie rods 5, having a first end 7 connected to the second reservoir 3 and a second end 8 connected rigidly to the first reservoir 2. This first set of tie rods 5 comprises a plurality of tie rods 5, in particular four tie rods 5, the first end 7 of which is situated at a first longitudinal end of the second reservoir 3 (for example the left-hand end in
As illustrated in
The upper and lower parts may be defined according to whether they are located above or below the central longitudinal axis A of the reservoir 2 or of the container 1.
In the variant in
The second reservoir 3 preferably has a cylindrical overall shape extending in the longitudinal direction A with a given radius of for example between 90 and 121.9 cm. The tie rods 5 of the first set of tie rods and of the second set of tie rods, respectively, have a length of preferably between 80 and 150% and preferably between 90 and 130% of the length of said radius.
As can be seen in
As schematically depicted in
For example, the second end 8 of each tie rod 5 is bolted (or fixed in any other appropriate way) to a sheath or tube, which is itself welded (or the like) to the first reservoir 2. In addition, as can be seen in
As illustrated in
Preferably, this first set of tie rods 5 is not articulated or is weakly articulated so as to ensure a fixed hold (or a low tolerance of movement) of the first end of the first reservoir 2 with respect to the second reservoir 3 (in particular in the case of the fixed link 15).
The container 1 comprises a second set of tie rods 5 of the same kind as the first set at the other longitudinal end of the container 1 (on the right in
The tie rods of the second set of tie rods 5 may be arranged like those of the first set (cf.
At each longitudinal end of the container 1, the second ends 8 of the tie rods 5 can be connected to the first reservoir 2 or to a neck fixed to the latter.
In addition, preferably, the ends 7 of the tie rods 5 of the second set are articulated so as to allow in particular travel of the second end of the first reservoir 2 in the longitudinal direction (cf.
As can be seen in
The third set of tie rods 6 comprises preferably two upper tie rods 6, the first end 10 of which is situated in the upper part of the second reservoir 3 and the second end 9 of which is situated in the upper part of the first reservoir 2 (cf.
Preferably, in a plane perpendicular to the longitudinal direction A (cf.
The container 1 comprises a fourth set of tie rods 6 at the other end of the container 1, which may be arranged in the same configuration as the third set (cf. above and
The tie rods 6 of the third set of tie rods, and of the fourth set of tie rods, respectively, have a length of between 30 and 80% and preferably between 40 and 60% of the length of the radius of the section of the second reservoir 2.
Thus, the two internal reservoirs 2, 4 are carried and suspended in the first, external reservoir 1 via tie rods 5, 6 situated at the two ends of the container 1.
As illustrated in
This means that the second ends 9 of the tie rods 6 can be connected to respective annuli 13 that also form the support for the shielding walls 11, 12.
In addition, as can be seen in
Further tie rods or holding/support members may potentially optionally be provided between these two ends of the container 1.
The articulated tie rods 5, 6 (at the free end of the first and third reservoirs) are configured to pivot about their end 7, 10 connected to the second reservoir 3 through an angle of for example between 10 and 20 degrees and corresponding to travel in the longitudinal direction of their second end 8, 9 of for example between 1 and 50 mm and in particular between 30 and 40 mm (for a container having a length of about 12 meters).
In the case of a the fixed and rigid link 15 at one longitudinal end, this prevents the longitudinal movement of one longitudinal end of the first 2 and of the third 4 reservoir with respect to the second reservoir 3 while allowing longitudinal travel of the opposite longitudinal end of the first 2 and third 4 reservoir with respect to the second reservoir 3. This travel is made possible via the articulated tie rods 5, 6.
In addition, preferably, at least some of the ends 10 and 7 of the tie rods 5, 6 connected to the lower part of the second reservoir 3 are mounted on respective elastic supports 14 that allow and a dampening a limited vertical travel with respect to the second reservoir 3. These elastic supports 14 may comprise for example a stack of Belleville washers, a damper, a spring or any other appropriate member.
Conventionally, the fixed and rigid link 15 may comprise tubular walls that extend back and forth in the longitudinal direction A so as to create an insulating thermal path between the second reservoir 3, for the one part, and the first 2 and third 4 reservoirs, for the other part (cf. for example DE102014206370A1). This thermal path may comprise a tube made of epoxy/glass composite or the like on the thermal path.
As schematically depicted in
As illustrated in
As can be seen in
Thus, while having a simple and inexpensive structure, the container 1 makes it possible to increase the nitrogen volume, for example from 1200 to 3000 liters with an annular height of 40 mm (distance between the two concentric walls of the third reservoir 4). This configuration minimizes the reduction in volume of the first reservoir 2.
The hyperstatic support structure allows a uniform distribution of the mass of the third reservoir 4 so as to avoid overfilling on the rear axles in the case of road transport or an imbalance during handling.
This architecture makes it possible to ensure very good thermalization (no need for a cooling circuit). This design functions even with a very small amount of nitrogen at the end of the journey. Ingress of heat is transmitted by conduction through the shells 4 to the liquid nitrogen. There is no risk of malfunctioning of the cooling circuit with a low rate of evaporation and increase in temperature in the upper part of the third reservoir 4.
The two cylindrical walls of the third reservoir 4 (shells) act as two heat shields in series. The outer wall receives the heat flux coming from the second reservoir 3. The inner wall receives the heat flux from the external wall, which has a temperature that is close for example to 90K. This reduces the heat flux toward the first reservoir 2 (for example to 4K).
The hyperstatic support and holding structure allows a good distribution of masses, a hold allowing expansions and contractions, and integrity during transports.
The third reservoir 4 (and the shielding walls 11, 12) is a rigid assembly that can be self-supporting by way of the tie rods 6 from the wall of the second reservoir 3. This makes it possible to avoid compression of the inter-wall insulation. This therefore avoids thermal defects and improves the degassing of the insulation, avoiding local compaction of the insulating material.
The third reservoir 4 forming a shield may bear directly on the insulation disposed around the first reservoir 2. This insulation (not shown) may comprise layers of insulating materials that are conventionally used.
The container can be housed in (fixed to) a parallelepipedal frame enabling the transport thereof.
It will be understood that many additional changes in the details, materials, steps and arrangement of parts, which have been herein described in order to explain the nature of the invention, may be made by those skilled in the art within the principle and scope of the invention as expressed in the appended claims. Thus, the present invention is not intended to be limited to the specific embodiments in the examples given above.
Number | Date | Country | Kind |
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1852005 | Mar 2018 | FR | national |
Filing Document | Filing Date | Country | Kind |
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PCT/FR2019/050449 | 2/27/2019 | WO | 00 |
Publishing Document | Publishing Date | Country | Kind |
---|---|---|---|
WO2019/170981 | 9/12/2019 | WO | A |
Number | Name | Date | Kind |
---|---|---|---|
2229080 | Zenner et al. | Jan 1941 | A |
2467428 | Hansen et al. | Apr 1949 | A |
2587204 | Patch, Jr. et al. | Feb 1952 | A |
2863297 | Johnston | Dec 1958 | A |
3129836 | Frevel | Apr 1964 | A |
5005362 | Weltmer, Jr. et al. | Apr 1991 | A |
20190145580 | Posselt et al. | May 2019 | A1 |
Number | Date | Country |
---|---|---|
10 2008 054 090 | Dec 1958 | DE |
10 2014 206 370 | Oct 2015 | DE |
WO 2017 190846 | Nov 2017 | WO |
Entry |
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International Search Report and Written Opinion for corresponding PCT/FR2019/050449, dated May 10, 2019. |
Number | Date | Country | |
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20210164614 A1 | Jun 2021 | US |