Patent Application
20160035385
Hard disc drives are common information storage devices having a series of rotatable discs that are accessed by magnetic reading and writing elements. These data elements, commonly known as transducers, or merely as a transducer, are typically carried by and embedded in a slider that is held in a close relative position over discrete data tracks formed on a disc to permit a read or write operation to be carried out.
As distances between the slider and the disc decrease, due to the ever-growing desire to reduce the size of the disc drive and to pack more data per square inch, the potentially negative impact due to contamination on the slider increases. Unwanted contaminants on the slider can adversely affect fly height behavior, such as with elevated or decreased fly height, create fly asymmetry in roll or pitch character, produce excessive modulation, and even result in head-disc crashing or contact, all possibly due to contaminant build up on the slider. All of these mechanisms result in degraded performance of the read or write operation of the head (e.g., skip-writes, modulated writers, weak writes, clearance stability and settling, and incorrect clearance setting).
What is needed is a mechanism to remove and/or control contaminants from between the slider and the disc surface while maintaining acceptable contact sensing between the transducer and the disc.
One particular implementation described herein is a cleaning head for removing contaminants from a data storage media, the cleaning head having a cleaning surface comprising a self-assembled monolayer, with the cleaning surface leading a read/write transducer.
Another particular implementation described herein is an assembly having a cleaning surface. The assembly comprises data storage media, a read/write head having a transducer and an air-bearing surface (ABS) opposite the media, the head having a leading edge and a trailing edge, and a cleaning surface comprising a self-assembled monolayer, the cleaning surface leading the transducer in respect to the media.
Yet another particular implementation described herein is a method of cleaning a data storage media having a surface. The method includes providing a cleaning surface comprising a self-assembled monolayer, and attracting contaminants from the surface of the data storage media to the self-assembled monolayer by bringing the self-assembled monolayer in close proximity to the surface of the data storage media.
The self-assembled monolayer of the cleaning surface is selected so as to have a terminal functional group that has a high affinity to the contaminant(s) desired to be attracted and/or removed.
This Summary is provided to introduce a selection of concepts in a simplified form that are further described below in the Detailed Description. This Summary is not intended to identify key features or essential features of the claimed subject matter, nor is it intended to be used to limit the scope of the claimed subject matter. These and various other features and advantages will be apparent from a reading of the following detailed description.
The described technology is best understood from the following Detailed Description describing various implementations read in connection with the accompanying drawings.
Hard disc drives are common information storage devices having of a series of rotatable discs that are accessed by magnetic reading and writing elements. These data elements, commonly known as transducers, or merely as a transducer, are typically carried by and embedded in a slider that is held in a close relative position over discrete data tracks formed on a disc to permit a read or write operation to be carried out. As distances between the slider and the disc decrease, due to the ever-growing desire to reduce the size of the disc drive and to pack more data per square inch, the potentially negative impact of any contamination between the slider and the disc increases. Unwanted contaminants can adversely affect fly height behavior of the slider, such as leading to elevated or decreased fly height, fly asymmetry in roll or pitch character, excessive modulation, and head-disc crashing or contact by contaminant build up and accumulation on the slider and/or “bridging” mechanisms between the head and disc. All of these mechanisms result in degraded performance of the read and/or write operation of the head (e.g. skip-writes, modulated writers, weak writes, clearance stability and settling, and incorrect clearance setting).
The present disclosure provides various implementations of devices and methods to remove contaminants from the disc surface. The term “contaminant” refers to any unwanted material or substance present on the storage medium, even if such substance is placed on the article intentionally. For example, in many implementations, lubricants such as hydrocarbon based oils and greases and dioctylphthalate are intentionally applied to the surface of carbon coated discs to improve the flying height of the slider in relation to the disc. Droplets of, or otherwise unattached or “free” lubricant is a contaminant readily removed from the disc surface by the devices and methods of the present disclosure. Contaminants that can be removed by the device include, but are not limited to, free disc lubricants, organic materials (e.g., solvents), silicones, and particulates.
In the following description, reference is made to the accompanying drawing that forms a part hereof and in which is shown by way of illustration at least one specific implementation. The following description provides additional specific implementations. It is to be understood that other implementations are contemplated and may be made without departing from the scope or spirit of the present disclosure. The following detailed description, therefore, is not to be taken in a limiting sense. While the present disclosure is not so limited, an appreciation of various aspects of the disclosure will be gained through a discussion of the examples provided below.
Referring to
In accordance with some of the implementations of this disclosure, present in disc drive 100 is a cleaning surface that includes a self-assembled monolayer or SAM, selected with an affinity for a class of contaminants (e.g., an oleophilic SAM for the removal of oil-based contaminants) and often a high surface energy SAM, configured to remove contaminant(s) from media 108 prior to operable interaction of the transducer on slider 112 with media 108. In other implementations of this disclosure, media 108 is brought into operational contact with the cleaning surface prior to assembly of media 108 into disc drive 100.
Slider 200 includes a transducer 220 that is proximate to or at trailing edge 206 of slider body 202; transducer 220 includes at least one read head 222 and at least one write head 224. In some implementations, transducer 220 is present on the trailing wall of slider body 202.
Although one particular implementation of a slider has been illustrated in
Provided herein are various implementations of cleaning or wiper devices having a cleaning surface comprising a self-assembled monolayer coating, or SAM coating, the coating configured to accumulate (e.g., coalesce) and remove contaminants from the surface of disc or media 108, prior to operable engagement of read head 222 and write head 224 with media 108. The cleaning surface may be present on the ABS of the slider (e.g., on ABS 210 of slider 200) generally upstream from the transducer, or the cleaning surface may be present as a cleaning bar or head separate from the slider. If the cleaning surface is present as a separate cleaning head, the cleaning head may be supported by the same actuator arm or assembly (e.g., actuator assembly 110 in
Returning to
Alternately or additionally, cleaning surface(s) 230 may be present on either or both sides of the transducer 220, between transducer 220 and side edge(s) 205 (e.g., laterally in relation to transducer 220). With such a configuration, the surface of media 108 will be cleaned by the cleaning surface(s) 230 prior to interaction with transducer 220 as slider 200 sweeps across media 108.
In another implementation, illustrated in
In the implementation of
In
In another implementation, illustrated in
In each of the implementations described above, and in variations thereof, contaminants (e.g., oil(s), moisture, particles) are accumulated (e.g., coalesced) on the cleaning surface due to the SAM coating. Often, when a sufficiently large droplet coalesces, the droplet may fall off from the cleaning surface and be removed from the immediate area of the media disc by the air currents caused by the rotating media disc. In other situations, the amount of liquid contaminant is sufficiently small that no droplet forms during the working life of the disc drive assembly. In some implementations, the cleaning surface or cleaning head also includes an adsorbent or absorbent material, such as a zeolite, to hold and/or retain the contaminants.
Occasionally, the cleaning surface can be refreshed or recharged; that is, the accumulated contaminant(s) are removed and/or new SAM material is applied to the cleaning surface. This may be done, for example, during scheduled maintenance of the disc drive assembly, or when the assembly is repaired or otherwise maintained or serviced. Accumulated contaminants can be removed, for example, under high heat or by a plasma process. After the contaminants are removed, the SAM material can be replenished if needed. For example, after attracting contaminants on the cleaning surface, the cleaning surface can be recharged by subsequent cleaning or reactivation of the cleaning surface through either (for example) solution or plasma based cleaning processes, and then reapplication of the SAM coating.
In each of the implementations described above, and in variations thereof, the cleaning surface comprises a self-assembled monolayer. The terms “self-assembled monolayer” and “SAM” as used herein refer to a thin monolayer of surface-active molecules are provided (e.g., adsorbed and/or chemisorbed) on the surface (i.e., the cleaning surface).
Self-assembled monolayer materials, or SAM materials, are widely available in a range of surface energies and can be readily applied to a desired surface (i.e., to the cleaning surface). Self-assembled monolayer materials can have a low surface energy or a high surface energy. The term “low surface energy” and variations thereof, as used herein, refers to the tendency of a surface to resist wetting (high contact angle) or adsorption by other unwanted materials or solutions; whereas, “high surface energy” refers to the tendency of a surface to increase or promote wetting (low contact angle) or adsorption by other unwanted materials or solutions. In a low surface energy material, such as a low energy SAM, the functional terminal groups of the molecules are chosen to result in weak physical forces (e.g., Van der Waals forces) between the coating and a liquid and thus allow for partial wetting or no wetting of the resulting coating (i.e., a high contact angle between the liquid and the coating). Conversely in a high surface energy material, such as a high energy SAM, the functional terminal groups of the SAM molecules are chosen to result in a stronger molecular force between the coating and a liquid and allow for full wetting of the of the liquid (i.e., a very small contact angle between the liquid and the coating). Values that are typically representative of “low surface energy” are in the range of 5-30 dyne/cm and high surface energy materials are relatively higher than this range, typically anything greater than 30 dyne/cm. An example of a high energy self-assembled monolayer or SAM material includes 3-aminopropyltrimethoxysilane. Examples of low energy self-assembled monolayer or SAM materials include perfluorodecyltricholorsilane (FDTS) and other fluorinated organosilane derivatives.
The SAM material for the cleaning surface can be selected to remove and/or attract a particular contaminant or type of contaminant. Examples of contaminants that are common in disc drive assembles include alumina (Al2O3), talc, and hydrocarbons. For example, the alkylsilane class of SAM materials, such as n-decyltrichlorosilane and dodecyltrichlorosilane (DTS), can be used to remove hydrocarbon contaminants such as sebacate and blasocut oils (oils often present in spindle bearings), paraffins (often present in the media, adhesives, and plastics present within the disc drive housing), and tooling oil (which might be residual from the assembly process of the disc drive). A polar (strong fixed dipole) SAM, such as 3-aminopropyltrimethoxysilane, can be used to remove (e.g., adsorb or absorb) polar contaminants such as acidic gases (e.g., SOx, NOx), surfactants (soap) from upstream cleaning processes for the media, polar or statically charged particles (e.g., alumina particles, metal oxide particles, talc particles) and any moisture that might be present on the media.
The precursor compound for forming the SAM contains molecules having a head group, a tail group, and functional end group. Common head groups include thiols, silanes, phosphonates, etc. SAMs are created by chemisorption of the head groups onto the surface area material (i.e., the cleaning surface) from either a vapor or liquid phase, by processes such as immersion, spraying, vapor deposition (e.g., chemical vapor deposition), vacuum deposition, etc. The head groups closely assemble on the material with the tail groups extending away from the material.
The precursor compound of the SAM may be present in any conventionally-used organic solvent, water, fluid, or any mixture thereof. Examples of suitable organic solvents may include, but are not limited to, alcohols (e.g., methyl alcohol, ethyl alcohol, n-propyl alcohol, isopropyl alcohol, n-butyl alcohol, sec-butyl alcohol, t-butyl alcohol, isobutyl alcohol, and diacetone alcohol); ketones (e.g., acetone, methylethylketone, methylisobutylketone); glycols (e.g., ethyleneglycol, diethyleneglycol, triethyleneglycol, propyleneglycol, butyleneglycol, hexyleneglycol, 1,3-propanediol, 1,4-butanediol, 1,2,4-butantriol, 1,5-pentanediol, 1,2-hexanediol, 1,6-haxanediol); glycol ethers (e.g., ethyleneglycol dimethyl ether, and triethyleneglycol diethyl ether); glycol ether acetates (e.g., propylene glycol monomethyl ether acetate (PGMEA)); acetates (e.g., ethylacetate, butoxyethoxy ethyl acetate, butyl carbitol acetate (BCA), dihydroterpineol acetate (DHTA)); terpineols (e.g., trimethyl pentanediol monoisobutyrate (e.g., “TEXANOL” from Eastman Chemical Co.)); dichloroethene (DCE); chlorobenzene; and N-methyl-2-pyrrolidone (NMP).
The concentration of the precursor compound in the solution may be determined by those skilled in the art according to the intended applications and purposes and may be in the range of about 5 to about 20 mM. An immersion step may be performed without particular limitation and may be carried out at room temperature for about 20 to 120 minutes. Similarly, other methods (e.g., vacuum deposition, vapor deposition, etc.) may be carried out by conventional means.
An example of a commercially available low surface energy SAM is 1H,1H,2H,2H-perfluorodecyltrichlorosilane (alternately, heptadecafluoro-1,1,2,2-tetrahydro-decyl-1-trichlorosilane) [CAS: 78560-44-8], of course, other low surface energy SAM materials could be used. In general the class of fluorinated organosilane derivatives would work as low energy SAM materials. Other examples of commercially available low surface energy SAMs include: trifluoropropyltrimethoxysilane, heneicosafluorododecyltrichlorosilane, nonafluorohexyltrimethoxysilane, methyltrichlorosilane, ethyltrichlorosilane, propyltrimethoxysilane, hexyltrimethoxysilane, n-octyltriethoxysilane, n-decyltrichlorosilane, dodecyltrichlorosilane, and octadecyltrichlorosilane.
An example of a commercially available high surface energy SAM is (3-aminopropyl)-trimethoxysilane [CAS: 13822-56-5]. Of course, other high surface energy SAM materials could be used. The general class of organosilanes with amine, alcohol, or mercapto substituents would provide for a high surface energy SAM, relative to the above. Some commercially available examples include: (3-Mercaptopropyl)trimethoxysilane, methyl 11-[dichloro(methyl)silyl]undecanoate, acetoxyethyltrichlorosilane, and vinyltriethoxysilane.
Examples of commercially available oleophilic SAM materials fall within the general class of 1-18 carbon alkylsilanes with a hydrolyzable reactive group (e.g., halides such as F, Cl, Br, and I, and alkoxys such as methoxy, ethoxy, and propoxy). Such chemicals are readily available, for example, from Gelest and Sigma Aldrich, and include methyltrichlorosilane, ethyltrichlorosilane, propyltrimethoxysilane, hexyltrimethoxysilane, n-octyltriethoxysilane, n-decyltrichlorosilane, dodecyltrichlorosilane, and octadecyltrichlorosilane. In addition to the alkyl class, other functional SAMs, such as the following, are also are advantageous: 3-aminopropyltrimethoxysilane, methyl 11-[dichloro(methyl)silyl]undecanoate, acetoxyethyltrichlorosilane, vinyltriethoxysilane, and nonafluorohexyltrimethoxysilane.
Any of the SAM materials described above can be used to form a cleaning surface, either on a cleaning head or on a read/write head. The SAM material is selected to have a terminal functional group that has a high affinity to the contaminants desired to be removed from the media surface.
As described above and illustrated in the figures, the present disclosure is directed to various implementations for managing the accumulation of contaminants, including lubricant and other organic contaminants, on the media surface prior to operable engagement of the transducer with the media surface.
The above specification and examples provide a complete description of the structure and use of exemplary implementations of the invention. The above description provides specific implementations. It is to be understood that other implementations are contemplated and may be made without departing from the scope or spirit of the present disclosure. The above detailed description, therefore, is not to be taken in a limiting sense. While the present disclosure is not so limited, an appreciation of various aspects of the disclosure will be gained through a discussion of the examples provided.
Unless otherwise indicated, all numbers expressing feature sizes, amounts, and physical properties are to be understood as being modified by the term “about,” whether or not the term “about” is immediately present. Accordingly, unless indicated to the contrary, the numerical parameters set forth are approximations that can vary depending upon the desired properties sought to be obtained by those skilled in the art utilizing the teachings disclosed herein.
As used herein, the singular forms “a”, “an”, and “the” encompass implementations having plural referents, unless the content clearly dictates otherwise. As used in this specification and the appended claims, the term “or” is generally employed in its sense including “and/or” unless the content clearly dictates otherwise.
Spatially related terms, including but not limited to, “bottom,” “lower”, “top”, “upper”, “beneath”, “below”, “above”, “on top”, “on,” etc., if used herein, are utilized for ease of description to describe spatial relationships of an element(s) to another. Such spatially related terms encompass different orientations of the device in addition to the particular orientations depicted in the figures and described herein. For example, if a structure depicted in the figures is turned over or flipped over, portions previously described as below or beneath other elements would then be above or over those other elements.
Since many implementations of the invention can be made without departing from the spirit and scope of the invention, the invention resides in the claims hereinafter appended. Furthermore, structural features of the different implementations may be combined in yet another implementation without departing from the recited claims.
This application is a divisional application of U.S. application Ser. No. 14/570,351 filed Dec. 15, 2014, now U.S. Pat. No. 9,xxx,xxx, which claims priority to U.S. provisional application 61/918,926 filed Dec. 20, 2013, the entire disclosures of which are incorporated herein by reference for all purposes.
| Number | Date | Country | |
|---|---|---|---|
| 61918926 | Dec 2013 | US |
| Number | Date | Country | |
|---|---|---|---|
| Parent | 14570351 | Dec 2014 | US |
| Child | 14884596 | US |
