This disclosure generally relates to fabrication processes using plastic materials, and more specifically to a method for the continuous fabrication of parts using in-feed spools of continuous fiber reinforced thermoplastic material.
Numerous processes exist for the fabrication of Thermoplastic composite (TPC) laminates of constant thickness and straight length. In addition to non-continuous processes such as pressing, stamping and autoclave forming, continuous processes exist, such as extrusion, pultrusion, roll forming, and compression molding. Although these latter processes are capable of producing parts in continuous lengths, they lack the ability to produce parts having varying thickness and/or curvature along their length that are needed for lightweight aerospace structures and other structures where weight is of particular importance. Moreover, these continuous fabrication processes rely on the in-feed of multiple discrete lengths TPC materials to form features of an individual part. Thus, the discrete lengths of TPC must be cut, sorted, labeled, stored and individually fed into the machine performing the continuous fabrication process. The use of discrete lengths of TPC material reduces automation of the fabrication process, increases factory space requirements and may add to material costs.
Accordingly, a need exists for a method for continuous fabrication of TPC laminate parts, including those with tailored thicknesses and/or curvature that reduce or eliminate the need for feeding discrete lengths of TPC materials. Illustrated embodiments of the disclosure are intended to satisfy this need.
According to the disclosed embodiments, a method is provided for manufacturing a reinforced thermoplastic part in a continuous process in which thermoplastic materials from one or more spools are continuously fed into processing equipment used to pre-form and then consolidate the part, in a continuous process. By continuously feeding the thermoplastic materials from spools, the manufacturing process is more fully automated, and the need for cutting, sizing, labeling, sorting and storing individual lengths of the thermoplastic materials may be reduced or eliminated.
In one embodiment, a method is provided for manufacturing a reinforced thermoplastic laminate part in a continuous process. The method comprises the steps of: continuously feeding thermoplastic materials from at least two spools into a pre-forming structure; pre-forming the part in the pre-forming structure using the materials being continuously fed; feeding the pre-formed part through a press; and, pressing the pre-formed part to compact the thermoplastic materials. The method may further include forming a length of multi-ply reinforced thermoplastic material, and winding the multi-ply length onto at least one of the two spools. The plies may be tacked together along their length so that they remain registered, and unwind from the spools as a single length of material. The plies in the material on each spool may contain reinforcing fibers arranged at differing angles relative to a reference direction of orientation. The spooled lengths of thermoplastic material may be fed along with pre-formed, multi-ply stacks of composite materials into the pre-forming structure. Following pre-forming, the part is consolidated in a continuously operating press, such as a continuous compression molding machine.
In accordance with another embodiment, a method is provided for manufacturing a thermoplastic composite part, comprising the steps of: continuously feeding multiple rolls of reinforced thermoplastic plies into a pre-forming structure; feeding tooling into the pre-forming structure as the plies are being fed; pre-forming the part while the plies are being fed; feeding the pre-formed part into a press; and, pressing the pre-formed part to compact the plies. The method may further include the steps of forming first and second lengths of fiber reinforced thermoplastic plies, joining together the first and second lengths of the plies in face-to-face relationship, and winding the joined lengths onto a spool. The plies may be tacked together at spaced apart locations in order to maintain their relative registration and assure that the plies may be unwound together. The plies of each spool may include reinforcing fibers arranged at differing angles of orientation in order to improve part strength and rigidity.
According to still another embodiment, a manufacturing method is provided, comprising the steps of: forming a roll of fiber reinforced thermoplastic material having at least two plies; continuously feeding material from the formed roll into a pre-forming structure; pre-forming a part in a pre-forming structure as the material is being continuously fed; and, consolidating the pre-formed part. The roll of fiber reinforced thermoplastic material may be formed by placing two plies in face-to-face relationship, attaching the plies together, and winding the attached plies onto a spool. Fiber orientation in one of the plies may be altered relative to fibers in another ply by dividing one of the plies into sections, rotating the sections and then reattaching the sections.
The disclosed method may be employed to manufacture a variety of parts including, for example, structural beams having a variety of cross sectional geometries, tailored thicknesses and curvature.
Other features, benefits and advantages of the embodiments will become apparent from the following description, when viewed in accordance with the attached drawings and appended claims.
The illustrated embodiments provide a novel fabrication method of forming a thermoplastic composite (“TPC”) laminate material with tailored and varying thicknesses in a continuous process. The embodiments find applicable uses in a wide variety of potential applications, including for example, in the aerospace industry. The disclosed method is ideally suited for forming thermoplastic composite stiffened members in the supporting framework of an aircraft fuselage. Potential examples of thermoplastic composite stiffened members include but are not limited to fuselage skins, wing skins, control surfaces, door panels and access panels. Stiffening members include but are not limited to keel beams, floor beams, and deck beams. For illustrative purposes only, the method will initially be described in reference to forming a thermoplastic composite floor beam 20 for use in a commercial aircraft fuselage. However, while an I-section is shown, other stiffened member geometries such as Z-section, U-section, T-section, etc. will also be later described, including those having curvature along their length.
Referring now to
In alternative versions (not shown), a thermoplastic composite laminate such as the floor beam 20 may alternatively be formed by consolidating one or more uniform or non-uniform tacked multi-layer ply sheets 74,76 with either one or more single ply (shown as 32 in
The thermoplastic materials 30 used in plies 32, 34 include thermoplastic matrix polymers (shown as 40 in FIG. 3) such as polyetheretherketone (“PEEK”), polyetherketoneketone (“PEKK”), polyphenylsulfone (“PPS”), polyetherimide (“PEI”) preferably reinforced with a fibrous component (shown as 38 in
The nuggets 26 are preferably formed from a thermoplastic material 37 that is compatible with the thermoplastic material 30 via extrusion or other well-known forming process. Preferably the matrix resin composition 42 of the nuggets 26 is the same as the matrix resin composition 40 of the materials 30. In addition, the filler nuggets 26 may utilize fibers 44 similar to the fibers 38 contained within the thermoplastic material 30.
Referring now to the logic flow diagram (
Next, in Step 160, multiple plies 32, 34 of the thermoplastic materials 30 are stacked in a desired configuration to form either a non-uniform thickness or uniform thickness untacked multi-layer ply sheet stack 58 or 60 using either a hand lay-up or automated process.
In the automated process, as shown in
An example of an untacked, non-uniform thickness multi-layer sheet stack 58 made according to the process of
Next, in Step 170, some or all of various plies 32, 34 of the untacked stacks 58, 60 formed in
In Step 175, the tacked stacks 74, 76 may then be cut into smaller pieces, or are ready for use in forming the thermoplastic composite laminates such as floor beam 20 of
Next, in Step 180, a combination of at least one uniform or non-uniform thickness tacked stack 74, 76, and at least one of either a non-uniform thickness tacked stack 76, a uniform thickness tacked stack 74, or a single ply 32, and optionally at least one filler nugget 26 of thermoplastic material 30, 37 are fused together in a consolidation structure 78 to form a single integrated thermoplastic composite laminate such as floor beam 20. One preferred consolidation structure 78 specifically designed to form the thermoplastic composite laminate floor beam 20 of
Referring now to
Referring now to
A first pair 94 of tacked stacks 74 or 76 is introduced between the respective central portions 88 and within the gap 90 of the U-shaped channels 86. At the same time, an optional filler nugget 26 and either the additional tacked stack 74 or 76 or ply 32, are introduced along each flange 96 of the first pair 94 and within the respective side-tooling member 92. For the purposes of description in the following paragraphs with respect to the illustrations of
As the tacked stacks 74, 76 and nuggets 26 move through the performing zone 80 towards the consolidation zone 82, the flanges 96 of the first pair 94 of non-uniform thickness tacked stacks 76 on either side of the u-shaped channel 86 are bent outwardly under heat and pressure away from each other towards the respective outer portions 98 of the U-shaped channel 86. The flanges 96 are therefore coupled flat against the inner side of the uniform or non-uniform thickness tacked stacks 76, with the nuggets 26 located between the flanges 96 and the respective inner end of the uniform or non-uniform thickness tacked stacks 76. The heat within the pre-forming zone 80 is elevated sufficiently to allow deformation of the flanges 96 of the non-uniform thickness tacked stacks 76, but is below the temperature in which the polymeric component of the matrix resin 40, 42 of the respective stacks 74, 76 and nuggets 26 has the consistency of a viscous liquid. Bending of the flanges 96 is initiated by pressure applied to the flange 96 by external forming devices such as rollers (not shown). The side-tooling sheet members 92 squeeze the tacked stack 74 inwardly against the flange 96, causing additional pressure to be applied to the flange 96 which aids in bending the flange 96. The preformed part 84 is then ready to move to the consolidation zone 82.
As best shown in
The consolidating structure 102 has a pulsating structure 106 that incrementally moves the preformed part 84 forward within the consolidation zone 82 and away from the pre-forming zone 80. As the part 84 moves forward, the part first enters a heating zone 108 that heats the part to a temperature which allows the free flow of the polymeric component of the matrix resin 40, 42 of the stacks 74, 76 and nuggets 26. Next, the part 84 moves forward to a pressing zone 112, wherein standardized dies 104 are brought down collectively or individually at a predefined force (pressure) sufficient to consolidate (i.e. allow free flow of the matrix resin) the various plies 32, 34 of the tacked stacks 74, 76 and nuggets 26 into its desired shape and thickness, here forming the web region 22 and pair of cap regions 24 of the floor beam 20.
Each die 104 is formed having a plurality of different temperature zones with insulators. The dies 104 do not actually contact the part 84, but contact the outer surfaces of the U-shaped channels 86 and side-tooling sheet members 92 opposite the part 84. Thus, the respective inner surfaces of the channels 86, 92 compress against the portion of the part 84. The compression may occur wherein all of the dies 104 compress in one independent yet coordinated step. The dies 104 are opened, and the part 84 is advanced within the consolidating zone 102 away from the pre-forming zone 80. The dies 104 are then closed again, allowing a portion of the part 84 to be compressed under force within a different temperature zone. The process is repeated for each temperature zone of the die 104 as the part 84 is incrementally advanced along the guide rollers 105 towards the cooling zone 114.
The formed and shaped part 84 then enters a cooling zone 114, which is separated from the pressing zone 112, wherein the temperature is brought below the free flowing temperature of the matrix resin 40, 42, thereby causing the fused or consolidated part to harden to its ultimate pressed shape 116. The pressed part 116 then exits the consolidating structure 102, wherein the side sheet members 92 are re-rolled onto rollers 120 as scrap.
While not shown, the consolidating structure 102 may have additional parts or devices that can introduce shapes or features into the pressed shape 116.
The consolidating zone structure 102 may be a continuous compression molding (“CCM”) process. However, other molding processes known to those of ordinary skill in the art are specifically contemplated by the disclosed embodiments, including but not limited to pultrusion or roll forming.
Next, in Step 190, the pressed part 116 is trimmed or otherwise post-processed to its desired final shape to form the thermoplastic composite laminate 20. In Step 200, the laminate 20 is inspected visually, preferably using ultrasonic non-destructive inspection techniques, or by other means to confirm that the laminate 20 is correctly shaped and does not contain any visual or other defects. After inspection, in Step 210, the laminate 20 such as the thermoplastic composite floor beam 20 may be installed onto its assembly. In the case of the floor beam 20, it is introduced within an aircraft fuselage.
While embodiments of the method have been described in terms of forming a thermoplastic composite floor beam 20 having essentially an I-beam shape, other potential shapes are specifically contemplated by the disclosed method. This includes thermoplastic composite laminates having an L-shape, a C-shape, a T-shape, or even a flat panel shape in which thickness transitions may occur in any section of the part. These alternatively shaped laminates, or even other forms of the floor beam 20, are formed by consolidating one or more uniform or non-uniform tacked multi-layer ply sheets 74, 76 with either one or more plies 32 of a thermoplastic composite material 30, one or more partial plies 34 of a thermoplastic material 30, or one or more uniform or non-uniform thickness tacked multi-layer tacked stacks 74, 76, and any combination thereof, in a similar method to that described herein.
Further, one or more filler nuggets 26 may also be used to form additional alternative versions of the thermoplastic composite laminates 20. To accomplish any of these alternative preferred variations, modifications to the tooling within the pre-forming zone 80 is necessary so as to match the desired thickness variations for the TPC laminate 20. For example, the U-shaped tool 86 of
While the disclosed method is ideally suited for forming thermoplastic composite laminates, by using a modified single-step consolidation zone, thermosetting laminate composites can also be formed. In this modified version of the consolidation process, the heating and pressing zones achieve a temperature above the reaction or curing temperature of the matrix resin to form a thermosetting part. Accordingly, the single pressing process achieves a part having its ultimate desired shape without subsequent pressing steps.
The illustrated method provides an innovative method to fabricate complex thermoplastic composite laminates with tailored and varying thickness in a continuous process. This innovative process utilizes automated equipment or hand lay-up to collate parts or components into a multi-layer stack. Each stack contains all plies, including ply build-up areas, tacked in the proper location to maintain orientation and location. The consolidation structure utilizes a two-stage method for forming the composite laminates from the multi-layer stacks and contains all necessary part features to achieve this result. The tooling, such as the U-shaped tool 86 in the pre-forming zone 80 is created with an appropriate shape to create the desired thickness variations in the formed TPC laminates 20 and is further designed to mate with standardized dies with the consolidation zone 82
The composite part formed by the above method may find use in a wide variety of applications, including, for example, automotive and aerospace applications. One example of a composite part formed in accordance with the illustrated method is ideally suited for use as structural stiffened members, including thermoplastic composite laminate floor beams 20, in a commercial aircraft.
The illustrated method may be used to manufacture thermoplastic laminate parts that are both curved and have tailored and/or varying thickness along their length. Curved laminates can be produced in which the curvature is either constant (circular) or variable along the length of the laminate part. As in the case of the embodiment previously described, the curved thermoplastic laminate part may include tailored areas and areas of varying thickness achieved by adding partial or local plies, or areas containing pockets. “Tailored” or “tailoring” refers to the profile of the part surface, wherein the selective addition or reduction of plies in specific areas of the part can be used to achieve a desired surface profile after the plies are consolidated during the compaction process. Curved parts produced by this embodiment of the method may be used in a variety of applications such as frames, rings, formers and structural aircraft stiffened members or fuselage skins, wing skins, door panels and access panels, keel beams, floor beams, and deck beams. The curved parts can be produced with a variety of cross sections.
Referring now to
Although not specifically shown in
As shown in
Referring now to
At step 312, the sheet 314 is cut into longitudinal strips 316 that are then arranged in end-to-end relationship, and welded together at a butt splice 318. The welding may be performed, for example, using a soldering iron or a heat gun. The spliced strips 316 form a sheet 334 that is wound onto spools 300, as shown at step 320.
The foregoing description illustrates the production of spools 300 of strips 316 having a single ply. However, multilayer (multi-ply) sheets 334 may be fabricated by stacking multiple sheets 334 after each of them is formed in the manner shown at step 312. The multiple layers may include reinforcing fibers having any directional orientation. The multilayer stack is tacked together using, for example, a soldering iron or heat gun.
At step 322, the spools 300 of single or multilayer, reinforced thermoplastic material sheets are continuously fed into a continuously operating compression molding line 324 which will be discussed later in more detail. Nuggets 306 may also be fed into the molding line 324, as may be required for particular part. The molding line 324 forms successive sections of a part in a continuous operation. In the illustrated example, the formed part is a structural beam 332 having a C-shape cross section.
The fully formed and consolidated part 332 is inspected and/or subjected to nondestructive testing at step 326. At step 328 the part is trimmed and drilled, as required, to receive fasteners (not shown), depending upon the application. The finished part 332 is then ready for use, at step 330.
Additional details of the compression molding line 324 are shown in
The press unit 344 contains appropriate tooling (not shown) for pressing the material plies together and may be heated in order to elevate the polymeric component of the matrix resin in the stack 335 to its free-flowing temperature. The cooling zone 346 cools the polymeric component below the free-flow temperature, thereby causing the fused or consolidated part 332 to harden to its ultimate pressed shape. As previously described with reference to
Attention is now directed to
The axes of the spools 300b are disposed vertically so that the sheets dispensed from these spools have their flat surfaces vertically oriented. The sheets dispensed from spools 300b are guided and combined by guide rollers 369. The single or multi-ply sheets dispensed from spools 300a, 300b are continuously fed into the pre-forming unit 362 where the sheets are combined and preformed into a desired part. The preformed part then moves through a consolidation area 364 which includes the continuously operating compression molding press previously described along with a pulsating unit (not shown). The fully-formed part exits the line 360 where it is guided and supported by rollers 371. Control units 366 are provided which may include electrical controls, a hydraulic system and a computerized controller, for example.
The molding line 360 shown in
Parts such as structural beams having other geometries may be formed according to the disclosed embodiments, including those, for example, shown in
As previously indicated, the sheet 334 of reinforced thermoplastic material wound onto the spools 300 may have multiple plies or layers in which the reinforcing fibers are arranged at more than one angle relative to an orientation reference axis. For example, as shown in
Referring now to
Next, a second length of tape is unwound from a supply roll and is placed beneath the joined sections 422 which form a continuous ply. At step 414 the two plies 396, 398 are tacked together at 426 using a heat gun or soldering iron so that the edges of these two plies 396, 398 remain in registered relationship, and the plies may be wound or unwound from a spool 300 as a single sheet 394. Other methods may be used for connecting the plies 396, 398, such as passing these plies through an oven so as to heat the resin matrix just above their melting temperatures so as to bond the plies 396, 398 together. Finally, at step 416 the sheet 394 is wound onto a spool 300.
Although the embodiments of this disclosure have been described with respect to certain exemplary embodiments, it is to be understood that the specific embodiments are for purposes of illustration and not limitation, as other variations will occur to those of skill in the art.
This application is a continuation-in-part of U.S. patent application Ser. No. 11/347,122, filed Feb. 2, 2006 now U.S. Pat. No. 7,807,005.
Number | Name | Date | Kind |
---|---|---|---|
2440228 | Yardeny et al. | Apr 1948 | A |
2708288 | Fuller et al. | May 1955 | A |
4061817 | Maxel | Dec 1977 | A |
4151031 | Goad et al. | Apr 1979 | A |
4414266 | Archer et al. | Nov 1983 | A |
4414269 | Lubowitz et al. | Nov 1983 | A |
4462946 | Goldsworthy | Jul 1984 | A |
4571355 | Elrod | Feb 1986 | A |
4608220 | Caldwell et al. | Aug 1986 | A |
4674712 | Whitener et al. | Jun 1987 | A |
4749613 | Yamada et al. | Jun 1988 | A |
4759815 | Frey | Jul 1988 | A |
4818460 | Nied | Apr 1989 | A |
4913910 | McCarville et al. | Apr 1990 | A |
5021283 | Takenaka et al. | Jun 1991 | A |
5026447 | O'Connor | Jun 1991 | A |
5026514 | Hauwiller et al. | Jun 1991 | A |
5043128 | Umeda | Aug 1991 | A |
5057175 | Ashton | Oct 1991 | A |
5064439 | Chang et al. | Nov 1991 | A |
5139407 | Kim et al. | Aug 1992 | A |
5182060 | Berecz | Jan 1993 | A |
5192330 | Chang et al. | Mar 1993 | A |
5413472 | Dietterich et al. | May 1995 | A |
5681513 | Farley | Oct 1997 | A |
5716487 | Sumerak | Feb 1998 | A |
5759325 | Davis | Jun 1998 | A |
5820804 | Elmaleh | Oct 1998 | A |
5958550 | Childress | Sep 1999 | A |
6007917 | Weigel et al. | Dec 1999 | A |
6024555 | Goodridge et al. | Feb 2000 | A |
6162314 | Kassuelke et al. | Dec 2000 | A |
6291049 | Kunkel et al. | Sep 2001 | B1 |
6319346 | Clark et al. | Nov 2001 | B1 |
6425969 | van den Akker | Jul 2002 | B1 |
6689448 | George et al. | Feb 2004 | B2 |
6696009 | Davis | Feb 2004 | B2 |
6764057 | Fanucci et al. | Jul 2004 | B2 |
6869558 | Polk, Jr. et al. | Mar 2005 | B2 |
7186361 | Kasai et al. | Mar 2007 | B2 |
7191982 | Vetillard et al. | Mar 2007 | B2 |
7300693 | Albers et al. | Nov 2007 | B2 |
7419372 | Kasai et al. | Sep 2008 | B2 |
7431875 | Rule | Oct 2008 | B2 |
7513769 | Benson et al. | Apr 2009 | B2 |
7670525 | Weidmann et al. | Mar 2010 | B2 |
7807005 | Rubin et al. | Oct 2010 | B2 |
7871553 | Wilkerson et al. | Jan 2011 | B2 |
8151529 | Weidmann et al. | Apr 2012 | B2 |
8163221 | Suzuki et al. | Apr 2012 | B2 |
20020088549 | Fanucci et al. | Jul 2002 | A1 |
20020135093 | Davis | Sep 2002 | A1 |
20030044570 | George et al. | Mar 2003 | A1 |
20030168555 | Livi et al. | Sep 2003 | A1 |
20030175520 | Grutta et al. | Sep 2003 | A1 |
20030232176 | Polk, Jr. et al. | Dec 2003 | A1 |
20040009338 | Jo et al. | Jan 2004 | A1 |
20040096535 | Hudecek et al. | May 2004 | A1 |
20050029707 | Kasai et al. | Feb 2005 | A1 |
20050053765 | Albers et al. | Mar 2005 | A1 |
20050056362 | Benson et al. | Mar 2005 | A1 |
20050252603 | Rule | Nov 2005 | A1 |
20060011289 | Suriano | Jan 2006 | A1 |
20060083806 | Kasai et al. | Apr 2006 | A1 |
20060216480 | Weidmann et al. | Sep 2006 | A1 |
20060226288 | Vetillard et al. | Oct 2006 | A1 |
20060249868 | Brown et al. | Nov 2006 | A1 |
20070175571 | Rubin et al. | Aug 2007 | A1 |
20070175573 | Fox et al. | Aug 2007 | A1 |
20070175575 | Rubin et al. | Aug 2007 | A1 |
20080168619 | Gonzalez et al. | Jul 2008 | A1 |
20080185756 | Wilkerson et al. | Aug 2008 | A1 |
20080277058 | Schmier, II et al. | Nov 2008 | A1 |
20090065977 | Suzuki et al. | Mar 2009 | A1 |
20090074905 | Matsen et al. | Mar 2009 | A1 |
20090078362 | Wilkerson et al. | Mar 2009 | A1 |
20100148005 | Weidmann et al. | Jun 2010 | A1 |
20100225016 | Prebil et al. | Sep 2010 | A1 |
20100319841 | Rubin et al. | Dec 2010 | A1 |
20110206906 | Rubin et al. | Aug 2011 | A1 |
20120175049 | Suzuki et al. | Jul 2012 | A1 |
Number | Date | Country |
---|---|---|
834458 | Feb 1976 | BE |
1504302 | Apr 1969 | DE |
1629830 | Jan 1971 | DE |
2165470 | Jul 1973 | DE |
2647821 | Apr 1978 | DE |
3709480 | Oct 1988 | DE |
4017978 | Sep 1993 | DE |
29711917 | Aug 1997 | DE |
0024895 | Mar 1971 | EP |
0277727 | Aug 1988 | EP |
0317861 | May 1989 | EP |
1336469 | Aug 2003 | EP |
1504880 | Feb 2005 | EP |
1614624 | Jan 2006 | EP |
1666353 | Jun 2006 | EP |
1813404 | Aug 2007 | EP |
1995040 | Nov 2008 | EP |
2014448 | Jan 2009 | EP |
2587649 | Mar 1987 | FR |
2888155 | Jan 2007 | FR |
531357 | Jan 1941 | GB |
1157239 | Jul 1969 | GB |
8302085 | Jun 1983 | WO |
8810186 | Dec 1988 | WO |
2007092371 | Aug 2007 | WO |
2008073164 | Jun 2008 | WO |
2008094227 | Aug 2008 | WO |
2008097847 | Aug 2008 | WO |
2010101744 | Sep 2010 | WO |
2011106117 | Sep 2011 | WO |
Entry |
---|
Thermoplastic Composite Sheet Forming Alfred C. Loos and Romesh C Batra, Department of Engineering Science and Mechanics, VA Polytechnic Institute and State University, Blacksburg, VA 24061. |
International Search Report dated Oct. 23, 2007, regarding Application No. PCT/US2007/003021 (WO2007092371), 3 pages. |
International Search Report dated Oct. 27, 2008, regarding Application No. PCT/US2007/018611 (WO2008073164), 3 pages. |
International Search Report dated Mar. 31, 2008, regarding Application No. PCT/US2007/022234 (WO2008094227), 3 pages. |
International Search Report dated Jul. 17, 2008, regarding Application No. PCT/US2008/052806 (WO2008097847), 2 pages. |
International Search Report dated Oct. 28, 2010, regarding Application No. PCT/US2010/025176 (WO2010101744), 5 pages. |
International Search Report dated Apr. 28, 2011, regarding Application No. PCT/US2011/022003 (WO2011106117), 3 pages. |
Prebil et al., USPTO U.S. Appl. No. 13/419,187, filed Mar. 13, 2012, 67 pages. |
Preliminary Amendment, dated Aug. 1, 2008, regarding U.S. Appl. No. 11/347,122, 39 pages. |
USPTO Office Action, dated Mar. 12, 2009, regarding U.S. Appl. No. 11/347,122, 16 pages. |
Response to Office Action, dated Apr. 6, 2009, regarding U.S. Appl. No. 11/347,122, 14 pages. |
USPTO Final Office Action, dated Jul. 9, 2009, regarding U.S. Appl. No. 11/347,122, 8 pages. |
Response to Final Office Action, dated Sep. 9, 2009, regarding U.S. Appl. No. 11/347,122, 13 pages. |
USPTO Office Action, dated Nov. 23, 2009, regarding U.S. Appl. No. 11/347,122, 9 pages. |
Response to Office Action, dated Mar. 19, 2010, regarding U.S. Appl. No. 11/347,122, 16 pages. |
USPTO Final Office Action, dated Jun. 24, 2010, regarding U.S. Appl. No. 11/347,122, 12 pages. |
Response to Final Office Action, dated Jun. 29, 2010, regarding U.S. Appl. No. 11/347,122, 9 pages. |
USPTO Notice of Allowance, dated Jul. 21, 2010, regarding U.S. Appl. No. 11/347,122, 6 pages. |
USPTO Office Action, dated Feb. 4, 2010, regarding U.S. Appl. No. 11/584,923, 16 pages. |
USPTO Final Office Action, dated Jul. 13, 2010, regarding U.S. Appl. No. 11/584,923, 12 pages. |
USPTO Office Action, dated Jul. 27, 2011, regarding U.S. Appl. No. 11/584,923, 10 pages. |
USPTO Office Action, dated Feb. 2, 2010, regarding U.S. Appl. No. 11/699,653, 15 pages. |
USPTO Final Office Action, dated Jul. 16, 2010, regarding U.S. Appl. No. 11/699,653, 10 pages. |
USPTO Office Action, dated Feb. 16, 2011, regarding U.S. Appl. No. 11/699,653, 12 pages. |
USPTO Final Office Action, dated Jul. 7, 2011, regarding U.S. Appl. No. 11/699,653, 14 pages. |
USPTO Office Action, dated Oct. 1, 2009, regarding U.S. Appl. No. 11/701,789, 17 pages. |
USPTO Final Office Action, dated Mar. 25, 2010, regarding U.S. Appl. No. 11/701,789, 15 pages. |
USPTO Office Action, dated Jun. 21, 2010, regarding U.S. Appl. No. 11/701,789, 11 pages. |
USPTO Final Office Action, dated Dec. 29, 2010, regarding U.S. Appl. No. 11/701,789, 14 pages. |
USPTO Office Action, dated Apr. 20, 2011, regarding U.S. Appl. No. 11/701,789, 15 pages. |
USPTO Final Office Action, dated Oct. 12, 2011, regarding U.S. Appl. No. 11/701,789, 17 pages. |
USPTO Office Action, dated Sep. 11, 2009, regarding U.S. Appl. No. 11/859,057, 10 pages. |
USPTO Final Office Action, dated Mar. 23, 2010, regarding U.S. Appl. No. 11/859,057, 10 pages. |
USPTO Notice of Allowance, dated Oct. 4, 2010, regarding U.S. Appl. No. 11/859,057, 9 pages. |
USPTO Office Action, dated Jan. 24, 2011, regarding U.S. Appl. No. 12/398,071, 14 pages. |
USPTO Final Office Action, dated Jun. 8, 2011, regarding U.S. Appl. No. 12/398,071, 9 pages. |
USPTO Office Action, dated Dec. 16, 2011, regarding U.S. Appl. No. 12/711,401, 21 pages. |
USPTO Final Office Action dated Jun. 15, 2012 regarding U.S. Appl. No. 12/711,401, 33 pages. |
USPTO Final Office Action dated Jul. 5, 2012 regarding U.S. Appl. No. 11/701,789, 30 pages. |
USPTO Notice of Allowance dated Jul. 25, 2012 regarding U.S. Appl. No. 11/584,923, 19 pages. |
Rubin et al., “Method for Fabricating Thermoplastic Composite Parts,” USPTO U.S. Appl. No. 13/673,989 and Preliminary Amendment, filed Nov. 9, 2012, 52 pages. |
European Patent Office Communication, dated Aug. 9, 2011, regarding Application No. EP08728832.0, 5 pages. |
Final Office Action, dated Apr. 16, 2012, regarding USPTO U.S. Appl. No. 11/584,923, 9 pages. |
Cai et al., “Consolidation Techniques and Cure Control,” In: Handbook of Composites, Second Edition, Peters (Ed), Chapman & Hall, London, 1998, pp. 576-577. |
Final Office Action, dated Dec. 13, 2012, regarding U.S. Appl. No. 11/701,789, 9 pages. |
Office Action, dated Feb. 20, 2013, regarding U.S. Appl. No. 12/398,071, 24 pages. |
Office Action, dated Jan. 18, 2013 regarding U.S. Appl. No. 12/711,401, 32 pages. |
Number | Date | Country | |
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20070175572 A1 | Aug 2007 | US |
Number | Date | Country | |
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Parent | 11347122 | Feb 2006 | US |
Child | 11697378 | US |