Claims
- 1. A control system for a furfural refining unit receiving medium sour charge oil and furfural one of which is maintained at a fixed flow rate while the flow rate of the other is controlled by the control system, treats the received medium sour charge oil with the received furfural to yield extract mix and raffiniate, comprising gravity analyzer means for sampling the medium sour charge oil and providing a signal API corresponding to the API gravity of the medium sour charge oil, flash point analyzer means for sampling the medium sour charge oil and providing a signal FL corresponding to the flash point temperature of the medium sour charge oil, viscosity analyzer means for sampling the medium sour charge oil and providing signals KV.sub.150 and KV.sub.210 corresponding to the kinematic viscosities, corrected to 150.degree. F. and 210.degree. F., respectively, sulfur analyzer for sampling the medium sour charge oil and providing a signal S corresponding to the sulfur content of the medium sour charge oil, a refractometer samples the medium sour charge oil and provides a signal RI corresponding to the refractive index of the medium sour charge oil, flow rate sensing means for sensing the flow rates of the medium sour charge oil and of the furfural and providing signals CHG and SOLV, corresponding to the medium sour charge oil flow rate and the solvent flow rate, respectively, temperature sensing means for sensing the temperature of the extract mix and providing a corresponding signal T, A signal means connected to the gravity analyzer means, to the flash point temperature analyzer means and to viscosity analyzer means and receiving direct current voltages C.sub.55 through C.sub.56 for providing a signal A in accordance with signals API, FL, and KV.sub.210, voltages C.sub.55 through C.sub.57 and the following equation:
- A=C.sub.55 -C.sub.56 (API)+C.sub.57 (FL)(KV.sub.210),
- where C.sub.55 through C.sub.57 are constants, means for providing a .DELTA.VI signal corresponding to a change in viscosity index, J signal means connected to the A, .DELTA.VI signal means, to the temperature sensing means, to all the analyzer means and to the refractometer and receiving direct current voltages C.sub.62 through C.sub.66 for providing a signal J in accordance with signals S, KV.sub.210, KV.sub.150, API, RI, .DELTA.VI and T, voltages C.sub.62 through C.sub.66 and the following equation:
- J={{-C.sub.62 +{(C.sub.62).sup.2 -4(-C.sub.63)[C.sub.64 .sqroot.T+C.sub.65 (.sqroot.T)(A)-C.sub.66 -.DELTA.VI]}.sup.1/2 }/2C.sub.63 }.sup.2,
- and control means connected to the J signal means and to the flow rate sensing means for providing a control signal in accordance with the J signal and one of the sensed flow rate signals, and apparatus means connected to the control means for controlling the one flow rate of the medium sour charge oil and furfural flow rates in accordance with the control signal.
- 2. A system as described in claim 1 in which the .DELTA.VI signal means includes VI signal means connected to the viscosity analyzer means for providing a signal VI corresponding to the viscosity index of the medium sour charge oil in accordance with viscosity signals KV.sub.150 and KV.sub.210 ; SUS.sub.210 signal means connected to the viscosity analyzer means for providing a signal SUS.sub.210 corresponding to the medium sour charge oil viscosity in Saybolt Universal Seconds corrected to 210.degree. F.; W signal means connected to the viscosity analyzer means, to the gravity analyzer means and to the sulfur analyzer means for providing a signal W corresponding to the wax content of the medium sour charge oil in accordance with signals KV.sub.210, API and S; .DELTA.VI network means connected to the gravity analyzer means, to the flash point temperature analyzer means, to the refractometer, to the VI signal means, to the W signal means, to the J signal means and to the SUS.sub.210 signal means and receiving voltage VI.sub.RP for providing signal .DELTA.VI to the J signal means in accordance with signals VI, W, API, FL, RI, SUS.sub.210 and voltage VI.sub.RP.
- 3. A system as described in claim 2 in which the SUS.sub.210 signal means includes SUS signal means connected to the viscosity analyzer means, and receiving direct current voltages C.sub.5 through C.sub.12 for providing a signal SUS corresponding to an interim factor SUS in accordance with signal KV.sub.210, voltages C.sub.5 through C.sub.12 and the following equation:
- SUS=C.sub.5 (KV.sub.210)+[C.sub.6 +C.sub.7 (KV.sub.210)]/[C.sub.8 +C.sub.9 (KV.sub.210)+C.sub.10 (KV.sub.210).sup.2 +C.sub.11 (KV.sub.210).sup.3 ](C.sub.12),
- where C.sub.5 through C.sub.12 are constants; and SUS.sub.210 network means connected to the SUS signal means and to the .DELTA.VI signal means and receiving direct current voltages C.sub.13 through C.sub.16 for providing signal SUS.sub.210 to the .DELTA.VI signal means in accordance with signal SUS, voltages C.sub.13 through C.sub.16 and the following equation:
- SUS.sub.210 =[C.sub.13 +C.sub.14 (C.sub.15 -C.sub.16)]SUS,
- where C.sub.13 through C.sub.16 are constants.
- 4. A system as described in claim 3 in which the W signal means further receives direct current voltages C.sub.43 through C.sub.49 and provides signal W in accordance with signals API, KV.sub.210 and S, voltages C.sub.43 through C.sub.49, and the following equation:
- W=C.sub.43 -C.sub.44 API+C.sub.45 /KV.sub.210 -C.sub.46 S+C.sub.47 (API).sup.2 -C.sub.48 (API)/KV.sub.210 +C.sub.49 (S)(API),
- where C.sub.43 through C.sub.49 are constants.
- 5. A system as described in claim 4 in which the VI signal means includes K signal means receiving direct current voltages C.sub.2, C.sub.3, C.sub.4 and T.sub.150 for providing a signal K.sub.150 corresponding to the kinematic viscosity of the charge oil corrected to 150.degree. F. in accordance with voltages C.sub.2, C.sub.3, C.sub.4 and T.sub.150, and the following equation:
- K.sub.150 =[C.sub.2 -ln (T.sub.150 +C.sub.3)]/C.sub.4,
- where C.sub.2 through C.sub.4 are constants, and T.sub.150 corresponds to a temperature of 150.degree. F.; H.sub.150 signal means connected to the viscosity analyzer means and receiving a direct current voltage C.sub.1 for providing a signal H.sub.150 corresponding to a viscosity H value for 150.degree. F. in accordance with signal KV.sub.150 and voltage C.sub.1 in the following equation:
- H.sub.150 =lnln (KV.sub.150 +C.sub.1),
- where C.sub.1 is a constant; H.sub.210 signal means connected to the viscosity analyzer means and receiving voltage C.sub.1 for providing signal H.sub.210 corresponding to a viscosity H value for 210.degree. F. in accordance with signal KV.sub.210, voltage C.sub.1 and the following equation:
- H.sub.210 =lnln (KV.sub.210 +C.sub.1),
- H.sub.100 signal means connected to the K signal means, to the H.sub.150 signal means and the H.sub.210 signal means for providing a signal H.sub.100 corresponding to a viscosity H value for 100.degree. F., in accordance with signals H.sub.150, H.sub.210 and K.sub.150 and the following equation:
- H.sub.100 =H.sub.210 +(H.sub.150 -H.sub.210)/K.sub.150,
- Kv.sub.100 signal means connected to the H.sub.100 signal means and receiving voltage C.sub.1 for providing a signal KV.sub.100 corresponding to a kinematic viscosity for the charge oil corrected to 100.degree. F. in accordance with signal H.sub.100, voltage C.sub.1, and the following equation:
- KV.sub.100 =exp [exp (H.sub.100)]-C.sub.1,
- and VI memory means connected to the KV.sub.100 signal means and to the viscosity analyzer means having a plurality of signals stored therein, corresponding to different viscosity indexes and controlled by signals KV.sub.100 and KV.sub.210 to select a stored signal and providing the selected stored signal as signal VI.
- 6. A system as described in claim 5 in which the .DELTA.VI network means includes a VI.sub.DWC.sbsb.O signal means connected to the gravity analyzer means, the flash point temperature analyzer means, the refractometer, the VI signal means and the W signal means, and receives direct current voltages C.sub.50 through C.sub.54 and provides a signal VI.sub.DWC.sbsb.O in accordance with signals RI, VI, FL, W and API, voltages C.sub.50 through C.sub.54 and the following equation:
- VI.sub.DWC.sbsb.O =C.sub.50 -C.sub.51 RI+C.sub.52 (RI)(VI)+C.sub.53 (FL)(API)-C.sub.54 (W)(VI),
- where C.sub.50 through C.sub.54 are constants; a VI.sub.DWC.sbsb.P signal means connected to the VI.sub.DWC.sbsb.O signal means and to the SUS.sub.210 signal means for providing a VI.sub.DWC.sbsb.P signal in accordance with signals SUS.sub.210 and VI.sub.DWC.sbsb.O, voltages C.sub.21 through C.sub.23 and Pour, and the following equation:
- VI.sub.DWC.sbsb.P =VI.sub.DWC.sbsb.P +(Pour)[C.sub.21 -C.sub.22 ln SUS.sub.210 +C.sub.23 (ln SUS.sub.210).sup.2 ],
- and subtracting means connected to the J signal means and to the VI.sub.DWC.sbsb.P signal means and receiving voltage VI.sub.RP for subtracting signal VI.sub.DWC.sbsb.P from voltage VI.sub.RP to provide the .DELTA.VI signal to the J signal means.
- 7. A system as described in claim 6 in which flow rate of the medium sour charge oil is controlled and the flow of the furfural is maintained at a constant rate and the control means receives signal SOLV from the flow rate sensing means, the J signal from the J signal means and a direct current voltage corresponding to a value of 100 and provides a signal C to the apparatus means corresponding to a new medium sour charge oil flow rate in accordance with the selected J signal, signal SOLV and the received voltage and the following equation:
- C=(SOLV)(100)/J,
- so as to cause the apparatus means to change the medium sour charge oil flow to the new flow rate.
- 8. A system as described in claim 6 in which the controlled flow rate is the furfural flow rate and the flow of the medium sour charge oil is maintained constant, and the control means is connected to the sensing means, to the J signal means and receives a direct current voltage corresponding to the value of 100 for providing a signal SO corresponding to a new furfural flow rate in accordance with signals CHG and the J signal and the received voltage, and the following equation:
- SO=(CHG)(J)/100,
- so as to cause the furfural flow to change to the new flow rate.
CROSS REFERENCE TO RELATED APPLICATIONS
This application is a continuation-in-part to U.S. application Ser. No. 851,993, filed Nov. 16, 1978, and now abandoned by Avilino Sequeira, Jr. John D. Begnaud and Frank L. Barger, and assigned to Texaco Inc., assignee of the present invention.
US Referenced Citations (4)
Continuation in Parts (1)
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Number |
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851993 |
Nov 1978 |
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