Claims
- 1. A control system for a furfural refining unit receiving medium sweet charge oil and furfural, one of which is maintained at a fixed flow rate while the flow rate of the other is controlled by the control system, treats the received charge oil with the received furfural to yield extract mix and raffinate, comprising gravity analyzer means for sampling the medium sweet charge oil and providing a signal API corresponding to the API gravity of the medium sweet charge oil, flash point analyzer means for sampling the medium sweet charge oil and providing a signal FL corresponding to the flash point temperature of the charge oil, viscosity analyzer means for sampling the medium sweet charge oil and providing signals KV.sub.150 and KV.sub.210 corresponding to the kinematic viscosities, corrected to 150.degree. F. and 210.degree. F., respectively, sulfur analyzer means for sampling the medium sweet charge oil and providing a signal S corresponding to the sulfur content of the medium sweet charge oil, a refractometer samples the medium sweet charge oil and provides a signal RI corresponding to the refractive index of the medium sweet charge oil, flow rate sensing means for sensing the flow rates of the medium sweet charge oil and of the furfural and providing signals CHG and SOLV, corresponding to the medium sweet charge oil flow rate and the furfural flow rate, respectively, means for sensing the temperature of the extract mix and providing a corresponding signal T, and control means connected to all of the analyzer means, the refractometer, and to all the sensing means for controlling the other flow rate of the charge oil and the furfural flow rates in accordance with signals API, FL, KV.sub.150, S, RI, CHG, T and SOLV.
- 2. A system as described in claim 1, in which the control means includes VI signal means connected to the viscosity analyzer means for providing a signal VI corresponding to the viscosity index of the medium sweet charge oil in accordance with viscosity signals KV.sub.150 and KV.sub.210 ; SUS.sub.210 signal means connected to the viscosity analyzer means for providing a signal SUS.sub.210 corresponding to the medium sweet charge oil viscosity in Saybolt Universal Seconds corrected to 210.degree. F.; W signal means connected to the viscosity analyzer means, to the gravity analyzer means and to the sulfur analyzer means for providing a signal W corresponding to the wax content of the medium sweet charge oil in accordance with signals KV.sub.210, API and S; A signal means connected to the viscosity analyzer means, to the gravity analyzer means and to the flash point temperature analyzer means for providing a signal A corresponding to an interim factor A in accordance with signals KV.sub.210, API and FL; .DELTA.VI signal means connected to the gravity analyzer means, to the flash point temperature analyzer means, to the refractometer, to the VI signal means, to the W signal means and to the SUS.sub.210 signal means and receiving voltage VI.sub.RP for providing a signal .DELTA.VI corresponding to the change in viscosity index in accordance with signals VI, W, API, FL, RI, SUS.sub.210 and voltage VI.sub.RP ; J signal means connected to the .DELTA.VI signal means, to the A signal means, and to the temperature sensing means for providing a J signal corresponding to the furfural dosage for medium sweet charge oil in accordance with the signals .DELTA.VI, A and T; control signal means connected to the J signal means and to the flow rate sensing means for providing a control signal in accordance with the J signal and one of the sensed flow rate signals, and apparatus means connected to the control network means for controlling the one flow rate of the medium sweet charge oil and furfural flow rates in accordance with the control signal.
- 3. A system as described in claim 2 in which the SUS.sub.210 signal means includes SUS signal means connected to the viscosity analyzer means, and receiving direct current voltages C.sub.5 through C.sub.12 for providing a signal SUS corresponding to an interim factor SUS in accordance with signal KV.sub.210, voltages C.sub.5 through C.sub.12 and the following equation:
- SUS=C.sub.5 (KV.sub.210)+[C.sub.6 +C.sub.7 (KV.sub.210)]/[C.sub.8 +C.sub.9 (KV.sub.210)+C.sub.10 (KV.sub.210).sup.2 +C.sub.11 (KV.sub.210).sup.3 ](C.sub.12),
- where C.sub.5 through C.sub.12 are constants; and SUS.sub.210 network means connected to the SUS signal means and to the .DELTA.VI signal means and receiving direct current voltages C.sub.13 through C.sub.16 dor providing signal SUS.sub.210 to the .DELTA.VI signal means in accordance with signal SUS, voltages C.sub.13 through C.sub.16 and the following equation:
- SUS.sub.210 =[C.sub.13 +C.sub.14 (C.sub.15 -C.sub.16)]SUS,
- where C.sub.13 through C.sub.16 are constants.
- 4. A system as described in claim 3 in which the W signal means further receives direct current voltages C.sub.43 through C.sub.49 and provides signal W in accordance with signals API, KV.sub.210 and S, voltages C.sub.43 through C.sub.49, and the following equation:
- W=C.sub.43 -C.sub.44 API+C.sub.45 /KV.sub.210 -C.sub.46 S+C.sub.47 (API).sup.2 -C.sub.48 API/KV.sub.210 +C.sub.49 (S) (API),
- where C.sub.43 through C.sub.49 are constants.
- 5. A system as described in claim 4 in which the VI signal means includes K signal means receiving direct current voltages C.sub.2, C.sub.3, C.sub.4 and T.sub.150 for providing a signal K.sub.150 corresponding to the kinematic viscosity of the charge oil corrected to 150.degree. F. in accordance with voltages C.sub.2, C.sub.3, C.sub.4 and T.sub.150, and the following equation:
- K.sub.150 =C.sub.2 -[ln(T.sub.150 +C.sub.3)]/C.sub.4,
- where C.sub.2 through C.sub.4 are constants, and T.sub.150 corresponds to a temperature of 150.degree. F.; H.sub.150 signal means connected to the viscosity analyzer means and receiving a direct current voltage C.sub.1 for providing a signal H.sub.150 corresponding to a viscosity H value for 150.degree. F. in accordance with signal KV.sub.150 and voltage C.sub.1 in the following equation:
- H.sub.150 =lnln(KV.sub.150 +C.sub.1),
- where C.sub.1 is a constant; H.sub.210 signal means connected to the viscosity analyzer means and receiving voltage C.sub.1 for providing signal H.sub.210 corresponding to a viscosity H value for 210.degree. F. in accordance with signal KV.sub.210, voltage C.sub.1 and the following equation:
- H.sub.210 =lnln(KV.sub.210 +C.sub.1),
- H.sub.100 signal means connected to the K signal means, to the H.sub.150 signal means and the H.sub.210 signal means for providing a signal H.sub.100 corresponding to a viscosity H value for 100.degree. F., in accordance with signals H.sub.150, H.sub.210 and K.sub.150 and the following equation:
- H.sub.100 =H.sub.210 +(H.sub.150 -H.sub.210)/K.sub.150
- Kv.sub.100 signal means connected to the H.sub.100 signal means and receiving voltage C.sub.1 for providing a signal KV.sub.100 corresponding to a kinematic viscosity for the charge oil corrected to 100.degree. F. in accordance with signal H.sub.100, voltage C.sub.1, and the following equation:
- KV.sub.100 =exp[exp(H.sub.100)]-C.sub.1,
- and VI memory means connected to the KV.sub.100 signal means and to the viscosity analyzer means having a plurality of signals stored therein, corresponding to different viscosity indexes and controlled by signals KV.sub.100 and KV.sub.210 to select a stored signal and providing the selected stored signal as signal VI.
- 6. A system as described in claim 5 in which the A signal means also receives direct current voltages C.sub.55 through C.sub.56 and provides A signal in accordance with signals API, FL and KV.sub.210, voltages C.sub.55 through C.sub.57 and the following equation:
- A=C.sub.55 -C.sub.56 (API)+C.sub.57 (FL) (KV.sub.210),
- where C.sub.55 through C.sub.57 are constants.
- 7. A system as described in claim 6 in which the .DELTA.VI signal means includes a VI.sub.DWC.sbsb.O signal means connected to the gravity analyzer means, the flash point temperature analyzer means, the refractometer, the VI signal means and the W signal means, and receives direct current voltages C.sub.50 through C.sub.54 and provides a VI.sub.DWC.sbsb.O signal in accordance with signals RI, VI, FL, W and API, voltages C.sub.50 through C.sub.54 and the following equation:
- VI.sub.DWC.sbsb.O =C.sub.50 -C.sub.51 RI+C.sub.52 (RI) (VI)+C.sub.53 (FL) (API)-C.sub.54 (W) (VI),
- where C.sub.50 through C.sub.54 are constants, a VI.sub.DWC.sbsb.P signal means and to the SUS.sub.210 signal means for providing a VI.sub.DWC.sbsb.P signal in accordance with signals SUS.sub.210 and VI.sub.DWC.sbsb.O, voltages C.sub.21 through C.sub.23 and Pour, and the following equation:
- VI.sub.DWC.sbsb.P =VI.sub.DWC.sbsb.O +(POUR)[C.sub.21 -C.sub.22 lnSUS.sub.210 +C.sub.23 (lnSUS.sub.210).sup.2 ],
- and subtracting means connected to the J signal means and to the VI.sub.DWC.sbsb.P signal means and receiving voltage VI.sub.RP for subtracting signal VI.sub.DWC.sbsb.P from voltage VI.sub.RP to provide the .DELTA.VI signal to the J signal means.
- 8. A control system as described in claim 7 in which the J signal means receives direct current voltages C.sub.58 through C.sub.61 and provides the J signal in accordance with the received voltages C.sub.58 through C.sub.61, signals A, T and .DELTA.VI and the following equation:
- J={{-C.sub.58 A+{(C.sub.58 A).sup.2 -4C.sub.59 A(C.sub.60 +C.sub.61 .sqroot.T-.DELTA.VI)}.sup.1/2 }/2C.sub.59 A}.sup.2,
- where C.sub.58 through C.sub.61 are constants.
- 9. A system as described in claim 8 in which flow rate of the medium sweet charge oil is controlled and the flow of the furfural is maintained at a constant rate and the control signal means receives signal SOLV from the flow rate sensing means, the J signal from the J signal means and a direct current voltage corresponding to a value of 100 and provides a signal C to the apparatus means corresponding to a new medium sweet charge oil flow rate in accordance with the J signal, signal SOLV and the received voltage and the following equation:
- C=(SOLV) (100)/J,
- so as to cause the apparatus means to change the charge oil flow to the new flow rate.
- 10. A system as described in claim 8 in which the controlled flow rate is the furfural flow rate and the flow of the medium sweet charge oil is maintained constant, and the control signal means is connected to the sensing means, to the selection means and receives a direct current voltage corresponding to the value of 100 for providing a signal SO corresponding to a new furfural flow rate in accordance with signals CHG, J and the received voltage, and the following equation:
- SO=(CHG) (J)/100,
- so as to cause the furfural flow to change to the new flow rate.
CROSS REFERENCE TO RELATED APPLICATIONS
This application is a continuation as to all subject matter common to U.S. application Ser. No. 851,995 filed Nov. 16, 1977, now abandoned, by Avilino Sequeira, Jr. John D. Begnaud and Frank L. Barger and assigned to Texaco Inc., assignee of the present invention, and a continuation in-part for additional subject matter.
US Referenced Citations (4)
Continuations (1)
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851995 |
Nov 1977 |
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