Claims
- 1. A pesticide polymer, which has a macromolecular backbone with pendant pesticidal groups chemically linked thereto by linkages which are broken under environmental conditions of use to controllably release an effective amount of active pesticide, is prepared by reacting a pesticide having a replaceable hydrogen with a multifunctional organic isocyanate to form a pesticide-isocyanate adduct and then reacting the adduct with a polymer having pendant groups containing a replaceable hydrogen, to form linkages which are cleaved under enviromental conditions of use to controllably release an effective amount of pesticide.
- 2. The pesticide polymer of claim 1 in which the replaceable hydrogen of the polymer is derived from a pendant hydroxyl group.
- 3. The pesticide polymer of claim 1 in which the replaceable hydrogen of the pesticide is derived from a group selected from hydroxyl, sulfyhydryl, amino, imino, carboxyl, amido, sulfonamido, sulfonimido, phosphoramido, phosphorimido, thiophosphoramido, and thiophosphorimido.
- 4. A pesticide-polymer of claim 1 in which the pesticide is 4-amino-6-tert-butyl-3-(methylthio)-as-triazin-5(4H)-one.
- 5. A pesticide-polymer of claim 1 in which the polymer is polyvinyl alcohol.
- 6. The method of preparing a pesticide-polymer for the controlled release of pesticide under field of use conditions which comprises reacting a pesticide having a replaceable hydrogen with a multifunctional organic isocyanate to form a pesticide-isocyanate adduct and then reacting the adduct with a polymer having pendant groups containing a replaceable hydrogen to form a pesticide-polymer in which the pesticide is linked chemically to the pendant groups by linkages which are cleaved under environmental conditions of use to controllably release an effective amount of the active pesticide.
- 7. The method of claim 6 in which the replaceable hydrogen of the polymer is derived from hydroxyl groups.
- 8. The method of claim 6 in which the reaction is carried out in a mutual solvent for the polymer and the pesticide-isocyanate adduct.
- 9. The method of claim 1 in which the pesticide is 4-amino-6-tert-butyl-3-(methylthio)-as-triazin-5(4H) one.
- 10. The method of claim 1 in which the polymer is polyvinyl alcohol.
RELATED APPLICATION
This is a continuation-in-part application of my earlier applications Ser. No. 766,522 filed Feb. 7, 1977, and Ser. No. 929,749 filed July 31, 1978, both now abandoned.
US Referenced Citations (3)
Number |
Name |
Date |
Kind |
3269900 |
Rubin |
Aug 1966 |
|
3966902 |
Chromocek |
Jun 1976 |
|
4177038 |
Biebricher et al. |
Dec 1979 |
|
Foreign Referenced Citations (2)
Number |
Date |
Country |
855181 |
Nov 1970 |
CAX |
863310 |
Feb 1971 |
CAX |
Non-Patent Literature Citations (1)
Entry |
Scher (Editor), Controlled Release Pesticides, ACS Symposium Series 53, (1977), pp. 112-125. |
Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
766522 |
Feb 1977 |
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