The present application generally relates to an apparatus and method for the electrolytic production of a metal. In particular, the apparatus and method are adapted for the production of a metal, such as aluminum, using vertical electrodes of inert or oxygen-evolving anodes and cathode plates.
An electrolytic cell for the production of aluminum or other metals comprises alternating rows of inert anodes and wettable inert cathodes in the shape of flat plates, immersed in a molten salt bath with sufficient ionic conductivity to pass current. The molten salt bath has the capacity to dissolve a compound of the metal to be reduced (e.g. a metal oxide, chloride, carbonate, etc.). Gas, such as oxygen, chlorine or carbon dioxide, is produced on the anodes and exits the cell as an offgas. Liquid metal is produced on the cathode plates and runs down in a thin film by gravity into a pool or sump for collection. The anodes and cathode plates are separated by a distance, known as the anode-cathode distance (ACD), and have an overlapping dimension, known as anode-cathode overlapping (ACO).
Cathodes are electrically conductive cathode plates, chemically resistant to metal and electrolyte, and have good wettability for the produced metal. The optimum shape and size of the cathode plates is related to the desired cell resistance, current density, anode dimensions and cell dimensions.
It would be possible to simply reduce the width of each electrode plate to increase the current density everywhere. However, simply reducing the area of the electrode plates in all regions comes at a cost of increasing the cell resistance and specific energy consumption. This increases the heat generation and makes it more difficult or impossible to design a cell with the proper heat balance.
There is thus a need for a new configuration or design of an electrolytic cell and method thereof for making a metal, such as aluminum, by increasing the current density of the electrodes.
The shortcomings of the prior art are generally mitigated by a new apparatus and method for increasing current density of the electrodes during the electrolytic production of a metal, such as aluminum.
Therefore, according to a first aspect, it is disclosed an electrode plate for the electrolytic production of a metal using an electrolytic cell comprising a plurality of said electrodes plates defining anode and cathode plates vertically aligned and arranged in alternating rows of said anode and cathode plates. The electrode plate defines: a connecting region adjacent a first end of the electrode plate for connecting the electrode plate to the electrolytic cell; a middle region extending from the connecting region without overlapping adjacent electrode plates; and an anode-cathode overlapping (ACO) region extending from the middle region to a second end of the electrode plate opposite to the first end, and configured for overlapping adjacent electrode plate(s); wherein the electrode plate comprises two opposite surfaces for facing surfaces of electrode plates of adjacent rows; and wherein a ratio of the ACO region's surface area to the middle region's surface area is superior to one in order to maximize current density in the ACO region. Preferably, the ACO/middle surface ratio is equal or superior to 2.
According to a preferred embodiment for the above first aspect, the electrode plate may have a rectangular shape, wherein a width of the electrode plate is constant from the ACO region to the middle and connecting regions.
According to a second aspect, it is disclosed an electrode plate for the electrolytic production of a metal using an electrolysis cell comprising a plurality of said electrodes plates defining anode and cathode plates vertically aligned and arranged in alternating rows of said anode and cathode plates, the electrode plate defining: a connecting region adjacent a first end of the electrode plate for connecting the electrode plate to the electrolytic cell; a middle region extending from the connecting region without overlapping adjacent electrode(s); and an ACO region extending from the middle region and configured for overlapping adjacent electrodes(s); wherein an average cross-sectional area ratio of the ACO region to the middle and connecting regions is superior to one in order to maximize current density in the ACO region while retaining a mechanical strength of the connecting region for supporting the electrode plate. Preferably, the average ACO/middle cross-sectional area ratio is equal or superior to 2.
The following preferred embodiments apply for the first and second aspects disclosed above, unless otherwise stated.
According to a preferred embodiment, the electrode plate may have a goal post shape wherein the middle and connecting regions define a pair of legs on either side thereof, with a central gap between the legs below the ACO region.
According to a preferred embodiment, the electrode plate may have a paddle shape, wherein the ACO region has a first width, the middle and connecting regions have a second width, the second width being inferior to the first width.
According to a preferred embodiment, the electrode plate may have a trapezoid shape wherein a width of the electrode plate constantly decreases from the second end to the first end of the electrode plate.
According to a preferred embodiment, the ACO region and the middle region of the electrode plate has a trapezoid shape with a width of the electrode plate constantly decreases from the second end of the electrode plate to a junction between the middle and connecting regions, the connecting region having a rectangular shape.
According to a preferred embodiment for the first aspect disclosed above, a surrounding edge of the surfaces has round transitions between the first end of the plate and the connecting region, and/or the surrounding edge has round transitions between the second end the ACO region.
According to a preferred embodiment of the second aspect disclosed above, the electrode plate comprises two opposite surfaces for facing surfaces of electrode plates of adjacent rows, and a surrounding edge of the surfaces which has round transitions between the first end of the plate and the connecting region, and/or the surrounding edge has round transitions between the second end the ACO region.
According to a preferred embodiment, the metal to produce is aluminum, the electrode plate being wettable by liquid aluminum metal.
According to a preferred embodiment, the electrode plate is a cathode plate.
According to a third aspect, it is disclosed an electrolytic cell for the electrolytic production of a metal comprising one or more electrode plates as disclosed herein. Preferably, the metal is aluminum.
According to a third aspect, it is disclosed the use of the electrode plate as disclosed herein, or the electrolytic cell as disclosed herein, for manufacturing an electrolysis cell comprising a plurality of said electrode plate.
According to a fourth aspect, it is disclosed the use of the electrode plate as disclosed herein, or the electrolytic cell as disclosed herein, for the electrolytic production of aluminum.
According to a fifth aspect, it is disclosed a method for controlling the current density of a plurality of electrodes plates defining anode and cathode plates vertically aligned and arranged in alternating rows in an electrolytic cell, the electrode plate defining: a connecting region for connecting the electrode plate to the electrolytic cell; a middle region extending from the connecting region without overlapping adjacent electrode(s); and an ACO region extending from the middle region and configured for overlapping adjacent electrodes(s); wherein each electrode plate comprises a surface for facing another electrode plate of the adjacent row; the method comprising the step of: maximizing current density in the ACO region by varying a ratio of the ACO region's surface area to the middle region's surface area such as the ACO/middle surface area ratio is superior to one.
According to a sixth aspect, it is disclosed a method for controlling the current density of a plurality of electrodes plates defining anode and cathode plates vertically aligned and arranged in alternating rows in an electrolytic cell, the electrode plate defining: a connecting region for connecting the electrode plate to the electrolytic cell; an middle region extending from the connecting region without overlapping adjacent electrode(s); and an ACO region extending from the middle region and configured for overlapping adjacent electrodes(s); the method comprising the step of: providing electrode plates in which an average cross-sectional area ratio of the ACO region to the middle and connecting regions is superior to one in order to maximize current density in the ACO region while retaining a mechanical strength of the connecting region for supporting the electrode plate.
According to a seventh aspect, it is disclosed a method for maximizing the current density of an electrolytic cell comprising a plurality of electrodes plates defining anode and cathode plates vertically aligned and arranged in alternating rows in an electrolytic cell, the method comprising the steps of: replacing each of existing electrodes plates of the cell by the electrodes plate as disclosed herein.
The electrode plates, in particular the cathodes plates, as disclosed herein allows:
Furthermore, the electrode plates, in particular cathodes plates, as disclosed herein, can be used for the manufacturing of new electrolytic cells, but also for replacing electrodes of existing electrolytic cells, in order to reduce the energy (e.g. electricity) consumption, providing as such an environmentally friendly process for metal production, in particular aluminum production, more preferably when the cathodes plates as disclosed herein are used conjointly with inert—oxygen evolving anodes.
The above and other aspects, features and advantages of the invention will become more readily apparent from the following description, reference being made to the accompanying drawings in which:
Novel apparatus and method will be described hereinafter. Although the invention is described in terms of specific illustrative embodiments, it is to be understood that the embodiments described herein are by way of example only and that the scope of the invention is not intended to be limited thereby.
The terminology used herein is in accordance with definitions set out below.
By “about”, it is meant that the value of weight % (wt. %), time, voltage, resistance, volume or temperature can vary within a certain range depending on the margin of error of the method or device used to evaluate such weight %, time, voltage, resistance, volume or temperature. A margin of error of 10% is generally accepted.
The description which follows, and the embodiments described therein are provided by way of illustration of an example of particular embodiments of principles and aspects of the present invention. These examples are provided for the purposes of explanation and not of limitation, of those principles of the invention. In the description that follows, like parts and/or steps are marked throughout the specification and the drawing with the same respective reference numerals.
As aforesaid, the invention as disclosed herein is directed to a new configuration of an electrolytic cell, in particular the electrodes plates, for increasing the current density.
In vertical inert anode cells, cathode and anode plates are arranged in parallel, alternating rows as illustrated on
The opposed, vertically oriented electrodes 12E, 14E permit the gaseous phases (O2) generated proximal thereto to detach therefrom and physically disassociate from the anodes 12E due to the buoyancy of the O2 gas bubbles in the molten electrolyte. Since the bubbles are free to escape from the surfaces of the anode 12, they do not build up on the anode surfaces to form an electrically insulative/resistive layer allowing the build-up of electrical potential, resulting in high resistance and, high energy consumption. The anodes 12E may be arranged in rows or columns with or without a side-to side clearance or gap between them to create a channel that enhances molten electrolyte movement, thereby improving mass transport and allowing dissolved alumina to reach the surfaces of the anode module 12. The number of rows of anodes 12E can vary from 1 to any selected number and the number of anodes 12E in a row can vary from 1 to any number. The cathodes 14E may be similarly arranged in rows with or without side-to-side clearance (gaps) between them and may similarly vary in the number of rows and the number of cathodes 14E in a row from 1 to any number.
The shapes of both vertical anodes and cathodes illustrated on
New electrode shapes have then been developed and are described herein below in reference to
As illustrated by the double-head arrows on the left side of
As a consequence of using inert or oxygen-evolving anodes, there is a voltage penalty of approximately 1 volt and an energy consumption penalty of approximately 3 kWh/kg compared to conventional technology. This is because inert anodes produce oxygen gas (O2) instead of the carbon dioxide gas (CO2) produced by carbon anodes. These penalties can be compensated by decreasing the current density (both anode current density and cathode plate current density).
This decrease in current density is achieved by developing proprietary anode and cathode plate materials that are dimensionally stable. The cathode plate is preferably wettable by liquid aluminum metal. These proprietary materials are then arranged in the vertical configuration as disclosed herein that allows retaining the same current per square foot of building space at a lower current density at the active surfaces.
Minimizing the middle region 120 minimizes the impact on cell resistance and energy efficiency, since there is little amount of current in this region.
Various shapes for vertical electrodes are proposed. Complexity, difficulty in manufacturing, and concerns about cracking and inadequate strength have to be taken into account when considering the shape of the electrode plates, in particular the cathode plates where the metal is produced.
Another approach consists in decreasing the middle region 120 of the electrode plate 100 as far as its mechanical strength and stability allow. For example, for a thin electrode plate, where the thickness is much smaller than its length or width and where the length-to-average-width aspect ratio is between 5 and 10, approximately 8 in a preferred embodiment, then the ratio of cross-sectional area at the top of the electrode plate to the cross-sectional area at the bottom of the electrode plate should be superior to 1, more preferably equal or superior to 2.
As illustrated on
The shape which results in the highest current density is the one that has the least area in the middle/connecting regions 120, 130 below the ACO region 110, such as with goal post shape 200 and the paddle shape 300.
The trapezoidal shape 400 of
Typically, the electrode plates as defined herein, when used as a cathode plate, can be made of titanium diboride (TiB2) or zirconium diboride (ZrB2). Any material that is electrically conductive, resistant to molten metal and electrolyte, and wettable to a metal, such as aluminum, can be used without departing from the scope of the present disclosure.
As illustrated on
As illustrated on
As illustrated on
As illustrated on
The electrode plate 500 and the trapezoidal electrode plate 400 of
According to a preferred embodiment, as shown on
Table 1 below provides some dimensions of the electrodes plates 500 illustrated on
The electrode plates as disclosed herein avoids the weaknesses discussed in accordance with the previous embodiments because there are no sharp geometry changes or narrow cross sections. The parts can be made into net shapes, without cut-outs, which can introduce flaws and crack initiation sites.
The invention enables metal production with competitive energy efficiency. The invention also allows for less heat loss in the cathode plate(s).
While illustrative and presently preferred embodiments of the disclosure have been described in detail hereinabove, it is to be understood that the inventive concepts may be otherwise variously embodied and employed and that the appended claims are intended to be construed to include such variations except insofar as limited by the prior art.
The present patent application claims the benefits of priority of U.S. Provisional Patent Application No. 63/118,774 entitled “APPARATUS AND METHOD FOR CONTROLLING ELECTRODE CURRENT DENSITY OF AN ELECTROLYTIC CELL”, and filed at the United States Patent and Trademark Office on Nov. 27, 2020, the content of which is incorporated herein by reference.
Filing Document | Filing Date | Country | Kind |
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PCT/CA2021/051689 | 11/25/2021 | WO |
Number | Date | Country | |
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63118774 | Nov 2020 | US |