Patent Application
20110042052
The present invention broadly relates to a cooling material.
Various methods are used to cool interior spaces of buildings, refrigerate food, condense water or reduce the temperature of objects. These methods have in common that they require relatively large amounts of energy, which typically is provided in the form of electrical energy. For example, in countries which have a relatively warm climate the electrical energy required for cooling often exceeds the available electrical energy, which may result in a breakdown of a power grid. Further, electrical energy is at this time still at least partially generated using non-renewable energy resources, for example by burning coal, which is of concern for the environment and contributes to global warming. Consequently, it would be advantageous if cooling could be achieved in a manner that uses less energy. There is a need for technological advancement.
The present invention provides in a first aspect a cooling material which comprises:
Throughout this specification the term “spectrally selective component” is used for a component that has a wavelengths dependent property.
Because the atmosphere of the earth has very low absorption within the atmospheric window wavelength range, only a very small amount of radiation is returned from the atmosphere to the particles of the first spectrally selective component within that wavelength range and emitted radiation is largely directed through the atmosphere and into space where the typical temperature is of the order of 4 Kelvin.
The energy associated with the radiation emitted by the particles of the first component is at least partially, typically mainly, drawn from thermal energy of the cooling material or a medium that is in thermal contact with the cooling material and the thermal energy is emitted by or “pumped” away from the cooling material. As a consequence, cooling of the cooling material and the medium that may be in thermal contact with the cooling material is possible without the need for electrical energy and at low cost. Further, during the night, or when irradiation by the sun is avoided, cooling well below ambient temperature is possible.
The wavelength dependent property of the second spectrally selective component typically is arranged to facilitate the cooling. The second spectrally selective material may comprise a layer or particles and typically is arranged for emission and/or transmission and/or reflection and/or absorption of radiation in a spectrally selective manner. For example, the second spectrally selective component may be arranged for emission of radiation by a physical process that is identical to that is associated with the emission of radiation by the particles of the first spectrally selective component, but at a different or overlapping wavelength range. Alternatively, the second spectrally selective component may be arranged for emission of radiation by a physical process that differs to that associated with the emission of radiation by the particles of the first spectrally selective component. The second spectrally selective component may also be arranged for absorption of radiation.
The atmospheric window wavelength range typically includes a minimum of the average absorption of the atmosphere of the earth. The atmosphere has atmospheric windows within the wavelength ranges of 3 to 5 μm and 7.9 μm to 13 μm. Within these wavelength ranges the emission of the sun is also negligible and often regarded as zero, which has the added advantage that even during daytime the cooling material only absorbs very little radiation from the sun within that wavelength range.
In embodiments of the present invention the cooling material is arranged to enable cooling to temperatures that are 5°, 10°, 20° below an ambient temperature or even lower.
The cooling material may also be arranged to extract heat at a finite rate at a temperature below ambient. The cooling material may be arranged so that cooling rates such as 40, 60, 80 W per m2 of cooling material area are possible at temperatures that are 5°, 10° or more below ambient temperature.
The particles of the first spectrally selective component may be arranged for generation of ionic surface plasmon resonances having a wavelength or wavelength range within the atmospheric window wavelength range.
Throughout this specification the term “ionic surface plasmon” is used for a surface plasmon excitation that involves movement of ions, such as that often referred to as “Fröhlich resonance”.
The wavelength of the ionic surface plasmons depends on the composition, shape, relative orientation and size of the particles, which typically are nano-sized particles. By controlling the composition and/or shape and/or size and/or relative orientation of the particles, it is consequently possible to control the wavelength range of the ionic surface plasmons.
The particles of the first spectrally selective component typically are arranged so that at least some, typically the majority or all, of the ionic surface plasmons have a wavelength within the wavelength range from 1-7 μm, 2-6 μm, 3-5 μm, and/or any one of 5-16 μm, 7-14 μm, 8-13 μm and 7.9-13 μm.
However, it is to be appreciated that alternatively the particles of the first spectrally selective component may be arranged so that the ionic surface plasmons are generated at a wavelength range that is partially outside the atmospheric window wavelength range. Further, the atmospheric window wavelength range may be one of a plurality of atmospheric window ranges, such as the wavelength range of 3-5 μm and 7.9 to 13 μm.
In one specific embodiment of the present invention the particles of the first spectrally selective component comprise, or may be entirely composed of, SiC or another suitable material.
Alternatively, the particles of the first spectrally selective component may be arranged for emission of radiation by a physical mechanisms other than that associated with the generation of ionic surface plasmons. In this case the particles of the first spectrally selective component may for example comprise SiO, silicon oxynitride or any other suitable material that is arranged for emission of radiation having a wavelength within the atmospheric window wavelength range.
The second spectrally selective component may also comprise particles. The particles of the first spectrally selective component and the particles of the second spectrally selective component may be dispersed within another component, such as a polymeric material, or may be distributed on a substrate. The particles of the second spectrally selective component may also be arranged for emission of radiation having a wavelength within the atmospheric window wavelength range, for example by generation of ionic surface plasmons.
Alternatively, the particles of the second spectrally selective component may not be arranged for generation of ionic surface plasmons, but may be arranged for emission of radiation by other physical mechanisms. In this case the particles of the second spectrally selective component may for example comprise SiO, silicon oxynitride or any other suitable material that is arranged for emission of radiation having a wavelength within or outside the atmospheric window wavelength range within. Further, the particles of the second spectrally selective component may be arranged for absorbing radiation by generating electronic surface plasmons.
Throughout this specification the term “electronic surface plasmon” is used for a surface plasmon excitation that involves collective motion of electrons.
If the particles of the second spectrally selective component are arranged for generation of electronic surface plasmons, the particles typically have a size, shape and/or composition and/or orientation that is selected so that the radiation is absorbed at a desired wavelength or wavelength range.
The cooling material may comprise a polymeric material that may be transmissive for radiation of a predetermined range of wavelength. At least a portion of the cooling material may be of a clear or opaque appearance. For example, the polymeric material may be arranged for light diffusion by incorporation of light scattering particles of a suitable size.
In first specific embodiment of the present invention the cooling material comprises at least one layer or foil that comprises a component material that is substantially transparent in the visible and/or in the near infrared and/or in the infrared spectral range. For example, the at least one layer or foil may comprise the polymeric material in which the particles of the first and/or second component are embedded or adjacent to which the particles of the first and/or second component are positioned. The cooling material may be freestanding and may form a part of a window, roof glazing, skylight or the like.
If the second spectrally selective component is provided in the form of a layer, the particles of the first spectrally selective component may also be embedded in or positioned adjacent that layer. Further, the layer of the second spectrally selective material may be positioned adjacent the substantially transparent layer.
In a second specific embodiment of the present invention the cooling material is arranged to reflect at least some incident radiation, such as radiation from the atmosphere and/or from the sun in the daytime. The cooling material may comprise a reflective material that is provided in the form of a layer positioned below the particles and may be arranged to reflect at least a portion of incident radiation. For example, the cooling material may be a coating that forms a part of a roof tile or sheet or may form a part of any other suitable object. Alternatively or additionally, the cooling material may comprise reflective particles that are dispersed within an at least partially transparent material, such as the above-described polymeric material. For example, the particles of the first and/or second component may be embedded or positioned adjacent to the polymeric material.
The cooling material may be arranged so that the majority of incident radiation is reflected. In this case the cooling material has the significant advantage of improved cooling efficiency as then the cooling material typically only has increased absorption within the atmospheric window energy range where the intensity of incident radiation is much reduced or negligible.
The reflective material may also reflect incident radiation having a wavelength within the atmospheric window wavelength range.
In a further specific embodiment of the present invention the particles of the first spectrally selective component are arranged for generation of ionic surface plasmons and the second spectrally selective component comprises particles that are also arranged for generation of ionic surface plasmons at a wavelength or wavelength range that differs from that of the particles of the first spectrally selective component. For example, this may be achieved by selecting a shape, size, orientation or composition that is different to that of the particles of the first spectrally selective component. The particles of the second spectrally selective component typically are arranged to emit radiation at a wavelength or wavelength range at which the particles of the first spectrally selective component have reduced emission so that utilisation of the available atmospheric window wavelength range is improved.
In another specific embodiment of the present invention the particles of the first spectrally selective component are arranged for generation of ionic surface plasmons and the second spectrally selective component comprises particles that are arranged for generation of electronic surface plasmons. In this case the particles of the second spectrally selective component may be arranged for absorption of radiation in the near infrared (NIR) wavelength. The cooling material typically is arranged to block at least a portion of incident solar radiation, which further improves the cooling that can be achieved with the cooling material when exposed to sunlight. For example, the particles of the second spectrally selective component may in this case comprise LaB6, SbSn oxide, aluminium doped ZnO or another suitable material. In this embodiment the cooling material typically is arranged so that a portion of the thermal energy, that is present as a consequence of the absorbed solar radiation in the infrared (NIR) wavelength range, is emitted by the particles of the first spectrally selective component.
The particles of the second spectrally selective component may be arranged for generation of electronic surface plasmons having wavelengths at or near the visible wavelength range. In this case the cooling material typically is arranged to block at least a portion of the visible light originating from the sun, whereby the cooling material may exhibit a particular colour. For example, in this case the particles of the second spectrally selective component may comprise Au, TiN or other suitable materials.
In addition, the cooling material may comprise a layered structure that is arranged to reflect thermal radiation from the atmosphere or a portion of visible light. For example, the layered structure may comprise thin layers of metal and dielectric materials.
The particles of the second spectrally selective component may have a diameter within the range of 10-100 nm, typically of the order of 50 nm or less. The second spectrally selective material may also comprise particles having differing compositions and/or shapes and/or sizes and/or relative orientations.
It is to be appreciated that in embodiments of the present invention the first and the second spectrally selective component may each comprise a combination of particles arranged for generation of ionic plasmons, particles arranged for generation of electronic surface plasmons and particles that are not arranged for generation of surface plasmons (such as SiO particles).
It is to be appreciated that in variations of the above-described embodiments the cooling material may not necessarily comprise particles that are arranged for emission of thermal radiation having a wavelength within the atmospheric window wavelength range, but the particles may be replaced by at least one layer that is arranged for emission of thermal radiation having a wavelength within the atmospheric window wavelength range. For example, the at least one layer may comprise a granular structure, a porous structure or may have a surface that is profiled so that the at least one layer is arranged for generation of ionic surface plasmon resonances having a wavelength or wavelength range within the atmospheric window wavelength range. Alternatively, the at least one layer may be a part of a multi-layered structure that is arranged for generation of ionic surface plasmon resonances having a wavelength or wavelength range within the atmospheric window wavelength range.
The present invention provides in a second aspect a cooling material which comprises:
The spectrally selective component typically is a first spectrally selective component and the cooling material typically comprises a second spectrally selective component having a property that distinguishes the second spectrally selective component from the first spectrally selective component and facilitates at least one desired function of the cooling material. The second spectrally selective component typically is arranged to facilitate cooling of the cooling material.
The atmospheric window wavelength range typically is a wavelength range from 3 to 5 μm and/or from 7.9 μm to 13 μm.
The at least one layer typically is arranged for generation of ionic surface plasmon resonances having a wavelength or wavelength range within the atmospheric window wavelength range.
The at least one layer may have a structural property that is selected so that the at least one layer is arranged for generation of ionic surface plasmon resonances having a wavelength or wavelength range within the atmospheric window wavelength range. For example, the at least one layer may comprise grains, or may at least in part be of a porous structure and the structural property may be associated with a grain size or a thickness of residual solid between pores, respectively. Further, the at least one layer may have a surface roughness and the structural property may be associated with thickness or width of surface features of the at least one layer. The grain size, the thickness of residual solid between pores and the thickness or width of surface features of the at least one layer typically are within the range of 50 nm-150 nm.
The at least one layer may also be a part of a multi-layered structure having layer thicknesses that are selected so that the multi-layered structure is arranged for generation of ionic surface plasmon resonances having a wavelength or wavelength range within the atmospheric window wavelength range.
The present invention provides in a third aspect a method of cooling using a cooling material for emission of thermal energy, the cooling material comprising a first spectrally selective component and a second spectrally selective component, the second spectrally selective component having a property that distinguishes the second spectrally selective component from the first spectrally selective component, the method comprising:
The first spectrally selective component may comprise particles or at least one layer arranged for emitting a portion of the thermal energy in the form of radiation having a wavelength within the atmospheric window wavelength range. For example, the at least one layer may have a structural property that is selected so that the first spectrally selective component is arranged for emitting a portion of the thermal energy in the form of radiation having a wavelength within the atmospheric window wavelength range. Alternatively, the at least one layer may be a part of a multi-layered structure having layer thicknesses that are selected so that the first spectrally selective component is arranged for emitting a portion of the thermal energy in the form of radiation having a wavelength within the atmospheric window wavelength range.
The step of emitting a portion of the thermal energy from the second spectrally selective component typically comprises emitting radiation by a physical process that is identical to that associated with the emission of radiation by the particles of the first spectrally selective component, but at a wavelength or wavelength range that differs from that of the first spectrally selective component. Alternatively, the step of emitting a portion of the thermal energy from the second spectrally selective component may comprise emitting radiation by a physical process that differs to that associated with the emission of radiation by the particles of the first spectrally selective component.
In one specific example the step of emitting a portion of the thermal energy from the first spectrally selective component comprises generating ionic surface plasmon resonances having a wavelength or wavelength range within the atmospheric window wavelength range. At least some of the ionic surface plasmons typically have a wavelength within the wavelength range from 1-7 μm, 2-6 μm, 3-5 μm, and/or any one of 5-16 μm, 7-14 μm, 8-13 μm and 7.9-13 μm.
The step of emitting a portion of the thermal energy from the first spectrally selective component may also comprise generating the ionic surface plasmons at a wavelength range that is partially outside the atmospheric window wavelength range.
The step of emitting a portion of the thermal energy from the second spectrally selective component may comprise emitting radiation having a wavelength within the atmospheric window wavelength range. For example, the step of emitting a portion of the thermal energy from the second spectrally selective component may comprise emitting radiation by generation of ionic surface plasmons. Alternatively, the step of emitting a portion of the thermal energy from the second spectrally selective component may comprise absorbing radiation by generating electronic surface plasmons.
The method typically comprises reflecting at least some incident radiation. For example, the method may comprise reflecting incident radiation having a wavelength within the atmospheric window wavelength range.
The method may comprise controlling at least one of the composition of the first spectrally selective component and a structural property of the first spectrally selective component to control the wavelength range of ionic surface plasmons.
The invention will be more fully understood from the following description of specific embodiments of the invention. The description is provided with reference to the accompanying drawings.
Referring initially to
The SiC particles 24 are in this embodiment nano-particles and the majority of the surface of the particles 24 is exposed to air. The particles 24 show resonantly enhanced absorption and emission of radiation at a wavelength range of 10 to 13 μm. Within that wavelength range ionic surface plasmons are generated. The wavelength range of resonant ionic surface plasmon emission is within the above-described atmospheric window wavelength range. For that wavelength range the average absorption of the atmosphere of the earth is very low and consequently very little radiation in this wavelength range is transferred from the atmosphere to the cooling material 20.
The energy associated with the emitted radiation is largely drawn from the thermal energy of the particles 24 and/or from a medium that is in thermal contact with the particles 24. Due to the atmospheric window, the emitted radiation is largely transmitted through the atmosphere and directed to space where the temperature typically is 4 Kelvin. Consequently, the cooling material 20 functions as a pump of thermal energy even if the cooling material, or a medium that is in thermal contact with the cooling material, has a temperature below ambient temperature.
The reflective material 22 has the added advantage that a large portion of incident radiation is reflected away from the cooling material 20 and consequently thermal absorption of radiation having a wavelength within or outside the atmospheric window is reduced, which increases cooling efficiency.
The energy of the ionic surface plasmons depends on the composition of particles, the size of the particles, the shape of the particles and their orientation relative to each other. By selecting properties of the particles 24, it is possible to control the energy of the ionic surface plasmons. For example, the particles 24 may be spherical, may have an elliptical shape or any other suitable shape.
The particles 24 may comprise a first component of particles having a first shape, size, composition or orientation and a second component of particles having a second shape, size, composition or orientation. In this case the first and second components are selected so that the particles of the first and second components result in generation of ionic surface plasmons at differing wavelength ranges within the atmospheric windows.
In variations of the above-described embodiment the particles 24 may be composed of other suitable materials that show ionic surface plasmon resonances, such as BN and BeO. Further, the particles 24 may also be composed of materials that are not arranged for ionic plasmon generation at a wavelength within the atmospheric window wavelength range, but may be arranged for emission of radiation within that wavelength range by any other possible mechanism. For example, SiO, silicon oxynitride particles exhibit relatively strong emissions within that wavelength range.
The reflective material 22 improves the cooling efficiency. However, it is to be appreciated that the cooling material may not necessarily comprise a reflective material. Further, the particles 24 may be embedded in a transparent material, such as a suitable polymeric material that is positioned upon the reflective material 22. For example, the polymeric material may comprise polyethylene or a fluorinated material.
Referring now to
In contrast to the cooling material 20, incident radiation is not reflected, but largely transmitted through the cooling material 30, which also reduces thermal absorption of radiation directed to the cooling material 30 and thereby improves the cooling efficiency.
In addition, the cooling material 30 comprises particles 36. In general, the particles 36 have a spectrally selective property that complements a spectrally selective property of the particles 24. In this example, the particles 36 are arranged for generation of electronic surface plasmons in the near infrared (NIR) wavelength range. Within that wavelength range the particles 36 absorb radiation, such as radiation originating from the sun. This inhibits transmission of a portion of incident radiation, which facilitates cooling. In this embodiment the cooling material 30 is arranged so that the thermal energy, that is present as a consequence of the absorbed solar radiation, is emitted by the particles 24.
For example, the cooling material 30 may be provided in the form of a skylight or a window. In this case the cooling material 30 typically is arranged so that a large portion of the visible light originating from the sun can penetrate through the cooling material 30. The particles 24 emit radiation within the atmospheric window wavelength range, which results in cooling, and the particles 36 partially “block” thermal radiation originating from the sun which facilitates the cooling.
For example, the particles 36 may comprise indium tin oxide, tin oxide, LaB6, SbSn oxide, or aluminium doped ZnO. It is to be appreciated, however, that in variations of the above-described embodiment the particles 36 may also be arranged for generation of electronic surface plasmons at any other suitable wavelength range.
In addition, the cooling material 30 may comprise a layered structure of dielectric and/or metallic materials having layer thicknesses that are selected to effect reflection of thermal radiation, such as thermal radiation originating from the atmosphere, which further facilitates cooling.
Further, the cooling material 30 may also comprise a layer structured material that is arranged so that a portion of light within the visible wavelength range is reflected and light that is transmitted though the cooling material 30 is of a particular colour, which has advantageous applications for aesthetic purposes.
Alternatively, the particles 36 may not be arranged for generating of surface plasmons, but may be arranged for strong absorption at a predetermined wavelength range in a manner such that the spectrally selective property of the particles 24 is complemented.
The cooling material 30 may be a free-standing material. Alternatively, the cooling material 30 may be a coating, such as a paint coating that is applied to an object.
The polymeric material 34 may be a clear polymeric material but may also be a translucent or opaque material that is arranged for scattering of light. If the polymeric material 34 is clear, the incorporated particles typically have a size that is smaller than 50 nm, which avoids light scattering. If light scattering is desired and the polymeric material 34 should be of an opaque appearance, particles having a diameter larger than 50 nm typically are incorporated to effect the light scattering.
Referring now to
For example, the reflective layer 42 may be arranged to reflect the majority of thermal radiation and visible radiation originating from the sun and from the atmosphere, which facilitates cooling of the cooling material 40. The reflective material may comprise for example Al, Cu, Ag, Au, Ni, Cr, Mo, W or steel including stainless steel.
In a variation of the embodiment shown in
For example, the cooling material 40 may form a part of a roof tile or sheet or any other suitable object such as a component of a heat exchanger. The reflective material 42 may comprise a metallic portion of a roof sheet to which the polymeric material 34 incorporating the particles 24 and 36 is applied.
Referring now to
The cooling material 50 is in this embodiment largely transparent for visible light, but may also comprise further layers that affect the transmission of light such as dielectric layers that influence the color of transmitted light.
Similar to the cooling material 40, the cooling material 60 may also be used for cooling of objects and may form a part of an object, such as a roof tile or part of a heat exchanger or any other suitable object.
Referring now to
It is to be appreciated that in variations of the above-described embodiments the cooling material may not necessarily comprise particles that are arranged for emission of thermal radiation having a wavelength within the atmospheric window wavelength range, but the particles may be replaced by at least one layer, such as a multi-layered structure, that is arranged for emission of thermal radiation having a wavelength within the atmospheric window wavelength range. The layers of the multi-layered structure typically have thicknesses and internal or surface structure that are selected so that in use ionic surface plasmon resonances are generated and the ionic surface plasmon resonances have a wavelength or wavelength range within the atmospheric window wavelength range. For example, the multi-layered structure may comprise SiO and SiC layers having a thickness of the order of 50-150 nm. Alternatively, the particles may be replaced by grains of a layer having a granular structure, such as a suitable SiC layer. In this case the average diameter of the grains is selected so that the layer is arranged for emission of thermal radiation having a wavelength within the atmospheric window wavelength range. The particles may also be replaced by a porous layer or a layer having a rough surface such as a suitable SiC layer. In this case an average pore spacing or a surface profile, respectively, is selected so that the layer is arranged for emission of thermal radiation having a wavelength within the atmospheric window wavelength range. If the cooling material comprises the at least one layer arranged for emission of thermal radiation having a wavelength within the atmospheric window wavelength range, the cooling material may or may not comprise the second spectrally selective component.
In addition, it is to be appreciated that the cooling material may comprise the above-described particles in addition to the above-described at least one layer. The at least one layer and the particles may both be arranged for emission of thermal radiation having a wavelength range within the atmospheric window wavelength range.
Although the invention has been described with reference to particular examples, it will be appreciated by those skilled in the art that the invention may be embodied in many other forms. For example, It is to be appreciated that in further variations of the above-described embodiments the particles 24 and the particles 36 or the particles 24 and the layer 52, or the particles 36 and the layer 52 may also be positioned directly on a surface without being embedded in a polymeric matrix. Further, the cooling material may form a part of any suitable object.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2007202832 | Jun 2007 | AU | national |
| 2007903673 | Jul 2007 | AU | national |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/AU08/00891 | 6/19/2008 | WO | 00 | 10/26/2010 |
