Cooling of extruded and compression molded materials

Information

  • Patent Grant
  • 6637213
  • Patent Number
    6,637,213
  • Date Filed
    Wednesday, April 24, 2002
    22 years ago
  • Date Issued
    Tuesday, October 28, 2003
    21 years ago
Abstract
The present invention relates to a system and a method for cooling extruded and molded materials. The present invention is especially useful to thoroughly cool an extrudate by directing a cooling fluid toward a surface of the extrudate (e.g., an interior surface that defines a hollow portion of an extrudate). Hollows may be created in order to reduce material, weight, and/or processing time. A cooling fluid is diverted toward the surface of the extrudate so as to cool the material and assist in solidification. A baffle may serve to divert the cooling fluid in the desired direction. Increases in production line throughput may result by rapidly cooling the molded material. In addition, the more efficient cooling may be achieved with a lesser amount of the cooling fluid, and the velocity and temperature of the cooling fluid may be reduced. Other uses for the present invention include injection molding, compression molding, gas assist molding, and co-extrusion.
Description




BACKGROUND AND SUMMARY OF THE INVENTION




The present invention relates generally to a system and method for cooling manufactured articles and, more particularly, to a system and method for cooling extruded and molded materials with a fluid that is below about 80 degrees Fahrenheit. The present invention may also be used in other types of manufacturing techniques in which the output or material must be cooled from a heated state. The present invention includes a system and method for cooling synthetic wood composite materials including, but not limited to, cellulosic-filled plastic composites. In addition, the present invention may also be used to cool other types of pure or mixed materials including, but not limited to, plastics, polymers, foamed plastics, plastic compositions, inorganic-filled plastic compositions, metals, metallic compositions, alloys, mixtures including any of the aforementioned materials, and other similar, conventional, or suitable materials that need to be cooled after being processed. For instance, the present invention may be used to cool polyvinyl chloride (PVC) products and products made from other plastics.




For several reasons, there is a need to find materials that exhibit the look and feel of natural wood. The supply of wood in the world's forests for construction and other purposes is dwindling. Consequently, the supply of wood from mature trees has become a concern in recent years, and the cost of wood has risen. As a result, several attempts have been made by others to find a suitable wood-like material.




Cellulosic/polymer composites have been developed as replacements for all-natural wood, particle board, wafer board, and other similar materials. For example, U.S. Pat. Nos. 3,908,902, 4,091,153, 4,686,251, 4,708,623, 5,002,713, 5,055,247, 5,087,400, 5,151,238, 6,011,091, and 6,103,791 relate to processes and/or compositions for making wood replacement products. As compared to natural woods, cellulosic/polymer composites offer superior resistance to wear and tear. In addition, cellulosic/polymer composites have enhanced resistance to moisture, and it is well known that the retention of moisture is a primary cause of the warping, splintering, and discoloration of natural woods. Moreover, cellulosic/polymer composites may be sawed, sanded, shaped, turned, fastened, and finished in the same manner as natural woods. Therefore, cellulosic/polymer composites are commonly used for applications such as interior and exterior decorative house moldings, picture frames, furniture, porch decks, deck railings, window moldings, window components, door components, roofing structures, building siding, and other suitable indoor and outdoor items. However, many attempts to make products from cellulosic/polymer composite materials have failed due to poor or improper manufacturing techniques.




In the present invention, a product or article is manufactured by a desired technique such as, but not limited to, extrusion, compression molding, injection molding, or other similar, suitable, or conventional manufacturing techniques. The product is then cooled by subjecting it to a cooling fluid. The present invention can be used alone or in conjunction with other known or later developed cooling methods. Accordingly, the present invention can more thoroughly and efficiently cool the manufactured product or article to a desired level. This can lead to faster production times as well as a product having improved structural, physical, and aesthetic characteristics.




In addition to the novel features and advantages mentioned above, other objects and advantages of the present invention will be readily apparent from the following descriptions of the drawings and exemplary embodiments.











BRIEF DESCRIPTION OF THE DRAWINGS





FIG. 1

is a cross sectional view of an extrudate.





FIG. 2

is a view of an extrusion die showing an exemplary location of a cryogenic nozzle.





FIG. 3

is an elevation view of one embodiment of a system implementing the present invention.





FIG. 4

is a partial cross sectional view along the line A—A of FIG.


3


.





FIG. 5

is a partial elevation view of another embodiment of a system of the present invention.





FIG. 6

shows a sectioned schematic of an extruder line used in accordance with the practice of one embodiment of the present invention.





FIG. 7

is a cross sectional view from a lateral side angle of an exemplary die of the present invention.





FIG. 8

is a cross sectional view from a top side angle of the die of FIG.


7


.





FIG. 9

is a cross sectional view from an exit side angle of the die of FIG.


7


.





FIG. 10

is a cross sectional view from a lateral side angle of an exemplary die of the present invention that includes a baffle.





FIG. 11

is a cross sectional view from a lateral side angle of another exemplary die of the present invention that includes a baffle.











DETAILED DESCRIPTION OF EXEMPLARY EMBODIMENT(S)




The present invention is directed to a system and method for cooling manufactured articles or products. It is not intended to limit the present invention to particular manufacturing techniques or particular materials. The present invention may be used to cool articles or products made by variety of different manufacturing techniques. Examples of manufacturing techniques that may utilize the present invention include, but are not limited to, extrusion (including co-extrusion), compression molding, injection molding, and other known, similar, or conventional techniques for manufacturing products or articles from plastic, wood, metal, mixtures of these materials, or other materials used to make products.




The present invention is particularly useful for cooling plastics, polymers, and cellulosic/polymer composite materials that have been extruded or molded. The materials that may be used to make cellulosic/polymer composites include, but are not limited to, cellulosic fillers, polymers, plastics, thermoplastics, inorganic fillers, cross-linking agents, lubricants, process aids, stabilizers, accelerators, inhibitors, enhancers, compatibilizers, blowing agents, foaming agents, thermosetting materials, and other similar, suitable, or conventional materials. Examples of cellulosic fillers include sawdust, newspapers, alfalfa, wheat pulp, wood chips, wood fibers, wood particles, ground wood, wood flour, wood flakes, wood veneers, wood laminates, paper, cardboard, straw, cotton, rice hulls, coconut shells, peanut shells, bagass, plant fibers, bamboo fiber, palm fiber, kenaf, flax, and other similar materials. In addition to PVC, examples of polymers include multilayer films, high density polyethylene (HDPE), polypropylene (PP), low density polyethylene (LDPE), chlorinated polyvinyl chloride (CPVC), acrylonitrile butadiene styrene (ABS), ethyl-vinyl acetate, other similar copolymers, other similar, suitable, or conventional thermoplastic materials, and formulations that incorporate any of the aforementioned polymers. Examples of inorganic fillers include talc, calcium carbonate, kaolin clay, magnesium oxide, titanium dioxide, silica, mica, barium sulfate, acrylics, and other similar, suitable, or conventional materials. Examples of thermosetting materials include polyurethanes, such as isocyanates, phenolic resins, unsaturated polyesters, epoxy resins, and other similar, suitable, or conventional materials. Combinations of the aforementioned materials are also examples of thermosetting materials. Examples of lubricants include zinc stearate, calcium stearate, esters, amide wax, paraffin wax, ethylene bis-stearamide, and other similar, suitable, or conventional materials. Examples of stabilizers include tin stabilizers, lead and metal soaps such as barium, cadmium, and zinc, and other similar, suitable, or conventional materials. In addition, examples of process aids include acrylic modifiers and other similar, suitable, or conventional materials.





FIG. 1

shows one example of an extrudate


100


that may be cooled by the present invention. The extrudate


100


includes an exterior surface


102


, a hollow


104


, an interior surface


106


, and two ends


108


. The exterior surface


102


may be cooled by a traditional method such as using a warm water bath or water mist. However, the interior surface


106


may not be sufficiently cooled by many traditional methods because the surface may not be available for contact with the cooling medium. The interior surface


106


defines the boundary of the hollow


104


. The interior surface


106


may be accessed from either end


108


. The interior surface


106


may not be cooled to a desired level within a desired amount of time by externally applied coolants.





FIG. 2

shows one example of an extrusion die


200


adapted with the present invention. The extrusion die


200


defines the cross section of the extrudate by the shape of the profile form/flow channel


206


. Hollows in the cross section of the extrudate are each formed with a standing core


202


. The standing core


202


is fitted with a nozzle


204


. The nozzle


204


is adapted to connect with a source of the cooling fluid (not shown). The nozzle


204


is oriented to spray into the hollow formed in the extrudate cross section by the standing core


202


.





FIG. 3

shows one example of a system


300


that may utilize the present invention. The system


300


includes an extruder


302


and an extruder


304


. In this example, a crosshead die


306


puts a cap layer from the extruder


304


on the material extruded by the extruder


302


. A container


308


may be used to hold a cooling fluid of the present invention. The fluid is used to cool the extruded product or article


312


after it exits the die


306


. In this embodiment, a valve is used to control the release of gas, e.g., vapor, from the fluid. A hose, conduit, tube, or any other suitable transfer device


310


may be used to direct the gas from the container


308


to the desired location for cooling the extruded product


312


. The transfer device


310


may be formed by one integral component or a plurality of interconnected components. For instance, a portion of the transfer device


310


may be a passage through the die


306


. In this example, the transfer device


310


extends through the die


306


so that the gas is released in the hollow of the extruded product


312


after it exits the die


306


. In this manner, the present invention can provide efficient and thorough cooling of the extruded product


312


. Moreover, the extruded product


312


may be further introduced into a liquid bath


314


, a spray mist chamber


316


, and/or any other desired cooling system to achieve additional cooling of the extruded product


312


if desired. Examples of the liquid bath


314


and the spray mist chamber


316


are provided in U.S. Pat. No. 5,827,462.




Depending on the type of cooling fluid and the desired expulsion rate of the cooling fluid, the container


308


may be pressurized. The container


308


may be connected to a compressor, e.g., an air compressor or any other similar, suitable, or conventional compressing device, in order to maintain the desired pressure in the container


308


. Additionally, the container


308


may be in fluid communication with a blower or a pump to obtain the desired expulsion rate of the cooling fluid from the container


308


. A blower in fluid communication with the container


308


may also be utilized to accelerate the cooling fluid to a desired velocity after it has been expelled.





FIG. 4

is a cross section view along the line A—A of FIG.


3


. The extruded product


312


includes a cap layer


404


. The transfer device


310


may extend through the die


306


to a nozzle


406


that releases gas from the cooling fluid into a hollow of the extruded product


312


. In this instance, gas vapor


402


permeates through the hollow of the extruded product


312


, thereby providing much improved cooling of the extruded product


312


. In fact, the inventors have surprisingly discovered that using the present invention to inject the cooling fluid into a hollow portion of a product may be sufficient to thoroughly cool the entire product, i.e., the inside and the outside of the product. As a result, the present invention may eliminate the need to provide another cooling system to cool the outer surface of the product.




It should be recognized that

FIGS. 3 and 4

are merely one example of a manufacturing system that may utilize the present invention. As noted above, the present invention may be used in any manufacturing system in which the processed material needs to be cooled to a desired level. For example, the present invention may be used in an extrusion system consisting of a single extruder that is in-line with a die. Also, the present invention may be used to cool any type of material including, but not limited to, injection molded materials and compression molded materials.




It should also be recognized that the cooling fluid of the present invention may be expelled elsewhere relative to the manufactured product (i.e., other than in a hollow portion of the product). For example,

FIG. 5

shows an embodiment in which the gas vapor


500


is dispersed by the transfer device


502


onto the exterior of the product


504


. The present invention also includes dispersing multiple streams of the cooling fluid onto the same or different portions of the manufactured product. For instance, flows of the cooling fluid may be simultaneously dispersed onto the exterior and interior surfaces of the manufactured product.




Turning to

FIG. 6

, this Figure shows a sectioned schematic of an extruder line


600


used in accordance with the practice of one embodiment of the present invention.

FIG. 6

shows an extruder line


600


which includes co-extrusion apparatus


602


. Co-extrusion apparatus


602


includes insulated transport tube


604


that is adapted to carry cooling fluid


606


. The cooling fluid


606


may be gas that may be delivered from a supply of cryogenic fluid. Co-extrusion apparatus


602


also includes a cross head extruder


608


which is adapted to prepare the thermoplastic material


610


for extrusion through a die which forms a hollow, rectangular profile and urges it along longitudinal direction


612


. Further layers of thermoplastic material such as layer


614


may be added through the use of additional extruders such as extruder


616


. Such additional layers of thermoplastic material may include layers of material with specific characteristics for exterior use, such as fluoropolymers and PVC having greater or lesser durability and resistance to changes in aesthetic appearance resulting from exposure to weather and environmental/atmospheric conditions, as dictated by the desired end user. The thermoplastic material


610


is formed by the forming die


618


into the desired final shape, such as a rectangular cross-section. The cooling fluid


606


permeates through the hollow space created in thermoplastic material


610


. The cooling fluid


606


may be at a significantly lower temperature than the surrounding thermoplastic material


610


. The cooling fluid


606


cools the thermoplastic material


610


, assisting the thermoplastic material to “skin” or solidify.





FIGS. 7 through 9

show a cross sectional view of one example of a die


700


that is configured to be in-line with an extruder. The extruded material flows through the die in the direction indicated by arrow


702


. In this example, the resultant extrudate


704


defines three hollow portions that are separated by webs


706


and


708


. The cooling fluid enters the die


700


through passages


710


. In some embodiments, it should be recognized that a tube, conduit, or any other type of transfer device may extend through the passages


710


for directing the flow of the cooling fluid through the passages


710


. The cooling fluid exits the die


700


through passages


710


in the direction indicated by arrows


712


. In such an embodiment, the passages


710


intersect the path of flow of the extruded material through the die


700


. In other words, the passages


710


intersect the flow channel in the die


700


.




The die


700


may be heated to a sufficient level to facilitate extrusion and limit premature curing of the extrudate in the die


700


. In this example of an in-line system, the passages


710


actually extend through the die


700


, intersecting the path of flow of the extruded material through the die


700


. In such embodiments, it may be preferable to limit cooling of the die


700


by the cooling fluid in the passages


710


. Accordingly, the passages


710


may be insulated by a suitable material. For example, the passages


710


may be lined with ceramic insulation, putty ceramics, or any other similar, suitable, or conventional insulating material in order to limit undesired heat loss by the die


700


. In fact, it should be recognized that the transfer device for the cooling fluid in any type of embodiment may be insulated in order to limit undesired cooling of surrounding items.




As best seen in the example of

FIG. 9

, the passages


710


may be substantially surrounded by die material


714


even where the passages


710


intersect the path of flow of the extruded material. In this manner, direct contact between the extruded material and the passages


710


may be avoided, if desired. The die material


714


surrounding the passages


710


may be heated to facilitate the extrusion process. Also, air gaps may be provided between the die material


714


and the passages


710


for additional insulation.




Any desired cooling fluid may be used in the present invention. In one exemplary embodiment, the cooling fluid, e.g., gas or liquid, may have a temperature below about 80 degrees Fahrenheit, more preferably below about 68 degrees Fahrenheit, still more preferably below about 32 degrees Fahrenheit, even more preferably below about minus 100 degrees Fahrenheit. On the other hand, the temperature may be above about minus 325 degrees Fahrenheit, more preferably above about minus 300 degrees Fahrenheit, still more preferably above about minus 275 degrees Fahrenheit, even more preferably above about minus 250 degrees Fahrenheit. However, in some embodiments of the present invention, the cooling fluid may be above about 80 degrees Fahrenheit or below about minus 325 degrees Fahrenheit. Examples of the cooling fluid are air and water. Another example of the cooling fluid is gas or vapor that is produced from a cryogenic fluid. For instance, a cryogenic fluid may have a temperature below about minus 250 degrees Fahrenheit. Examples of cryogenic fluids include, but are not limited to, liquid oxygen, liquid nitrogen, liquid neon, liquid hydrogen, liquid helium, and other similar, suitable, or conventional cryogenic fluids.




In addition to the temperature, the velocity of the cooling fluid may also impact its effectiveness. By selecting a suitable velocity and temperature of the cooling fluid, the inventors have discovered that an entire product can be thoroughly cooled just by injecting the cooling fluid into a hollow portion of the product. The velocity of the cooling fluid may be greater than about 10 miles per hour, more preferably greater than about 40 miles per hour, and it may be less than about 100 miles per hour, more preferably less than about 50 miles per hour. However, it should be recognized that the velocity of the cooling fluid may be less than about 10 miles per hour or greater than about 100 miles per hour in some embodiments.




The efficiency of the present invention may be further increased by diverting the flow of the cooling fluid toward the surface of the extruded product as it exits the die. By concentrating the cooling fluid on a surface of the extrudate, the desired amount of cooling may occur more quickly resulting in the use of less cooling fluid as compared to non-diversion methods. Moreover, the increased cooling efficiency enables the use of warmer cooling fluids and a reduction in the velocity of the cooling fluid as compared to non-diversion methods. For example, this embodiment of the present invention may be particularly useful if it is desired to use a cooling fluid that is warmer than about 80 degrees Fahrenheit. However, it should be recognized that, in many embodiments, it may be desirable to use a cooling fluid below about 80 degrees Fahrenheit for optimal cooling efficiency.





FIG. 10

shows one example of a die that is adapted to divert a cooling fluid toward a surface of an extruded project. The die


800


of this embodiment may include any of the optional or preferred features of the die


700


shown in

FIGS. 7 through 9

. The cooling fluid may enter the die


800


through a passage


810


. A baffle


820


is in fluid communication with the passage


810


such it receives the cooling fluid. The baffle


820


is adapted to then divert the flow of the cooling fluid such that it is directed to a desired surface of the extrudate. By directing the cooling fluid toward a surface of the extrudate, the baffle


820


may also create a more turbulent flow of the cooling fluid (as compared to a straight line flow that is not directed toward a surface of the extrudate) which further enhances the efficiency of the cooling process. The baffle


820


may be any device or structure that is suitable for diverting the flow of the cooling fluid to the desired location (e.g., an interior or exterior surface of a product). In this particular example, the baffle


820


is adapted to divert the cooling fluid in the direction of arrows


830


toward an interior surface of a hollow portion of the extrudate. For this purpose, the baffle


820


includes an inner conical portion


840


that forces the cooling fluid in the direction of arrows


830


.





FIG. 10

shows one example of a design of a baffle


820


. It should be recognized that the design of a baffle of the present invention may vary so as to divert the cooling fluid in the desired direction. Of course, the desired direction will vary according to the type of product being extruded and the location of the baffle relative to the extruded product.




The baffle


820


may be placed in fluid communication with the passage


810


in any suitable manner. In the example of

FIG. 10

, the baffle


820


is secured to an end portion of a conduit


850


that extends through the passage


810


. The baffle


820


may be secured to the end portion of the conduit


850


in any desired manner. For example, the baffle


820


may be threaded, i.e., screwed, onto the end portion of the conduit


850


. For other examples, the baffle


820


may be secured to the conduit


850


using other mechanical means (e.g., screws, pins, and other types of mechanical fastening devices) and/or adhesives. As previously noted, the conduit


850


may be insulated. The baffle


820


may also be insulated, if desired. The baffle


820


is offset from the heated portion


860


of the die


800


in this particular example. Optionally, there may be an insulated layer


870


on an exit end of the die


800


. The insulated layer


870


may be useful to prevent the cooling fluid from cooling the heated portion


860


of the die


800


.





FIG. 11

shows another example of a die which may include any of the optional or preferred features of the other embodiments of the present invention. In this embodiment, the die


900


includes a passage


910


that is in fluid communication with the baffle


920


. The baffle


920


is not offset from the heated portion


930


of the die


900


in this example. In order to limit undesired cooling of the heated portion


930


, it may be preferred to use an insulated baffle


920


or otherwise provide a layer of insulation between the baffle


920


and the heated portion


930


. As in the previous example, the baffle


920


may be connected to a conduit


940


that lines that passage


910


. It should also be recognized that the baffle


920


may be placed in fluid communication with the passage


910


in any other suitable manner. For example, the baffle


920


may have a threaded connection with the heated portion


930


. In other examples, the baffle


920


may be connected to the heated portion


930


using other mechanical means (e.g., screws, pins, and other types of mechanical fastening devices) and/or adhesives. As in the previous example, an exit end of the die


900


may include a layer of insulation


950


.




The exemplary embodiments herein disclosed are not intended to be exhaustive or to unnecessarily limit the scope of the invention. The exemplary embodiments were chosen and described in order to explain the principles of the present invention so that others skilled in the art may practice the invention. Having shown and described exemplary embodiments of the present invention, those skilled in the art will realize that many variations and modifications may be made to affect the described invention. Many of those variations and modifications will provide the same result and fall within the spirit of the claimed invention. It is the intention, therefore, to limit the invention only as indicated by the scope of the claims.



Claims
  • 1. A method for cooling a product, said method comprising:providing a die, said die having a passage lined with an insulating material; extruding a material through said die to form said product, said product having a surface; directing a cooling fluid through said passage; and diverting said cooling fluid such that said cooling fluid is directed toward said surface of said product.
  • 2. The method of claim 1 wherein said insulating material is selected from the group consisting of ceramic insulation and putty ceramics.
  • 3. The method of claim 1 wherein said material is selected from the group consisting of plastics, metals, cellulosic/polymer compositions, inorganic-filled plastic compositions, and foamed plastics.
  • 4. The method of claim 1 wherein said cooling fluid has a temperature between about 80 degrees Fahrenheit and about minus 325 degrees Fahrenheit.
  • 5. The method of claim 4 wherein said cooling fluid has a temperature between about 68 degrees Fahrenheit and about minus 300 degrees Fahrenheit.
  • 6. The method of claim 5 wherein said cooling fluid has a temperature between about 32 degrees Fahrenheit and about minus 275 degrees Fahrenheit.
  • 7. The method of claim 6 wherein said cooling fluid has a temperature between about minus 100 degrees Fahrenheit and about minus 250 degrees Fahrenheit.
  • 8. The method of claim 1 wherein said cooling fluid is selected from liquid oxygen, liquid nitrogen, liquid neon, liquid hydrogen, liquid helium, and air.
  • 9. The method of claim 1 wherein said cooling fluid is selected from the group selected from liquids, gases, and vapors.
  • 10. The method of claim 1 wherein said die is in-line with an extruder.
  • 11. The method of claim 10 wherein said passage intersects a path of flow of said material through said die.
  • 12. The method of claim 1 wherein said surface is an interior surface that defines a hollow portion of said product.
  • 13. The method of claim 1 wherein said surface is an exterior surface of said product.
  • 14. A die adapted to be used with an extruder to form a product, said die comprising:a flow channel adapted to be in fluid communication with said extruder such that an extruded material is forced through said flow channel to form said product; a passage extending through said die, said passage adapted to be in fluid communication with a source of a cooling fluid; and a baffle in fluid communication with said passage, said baffle adapted to divert said cooling fluid toward a surface of said product as said product exits said die.
  • 15. The die of claim 14 wherein said passage is lined with an insulating material.
  • 16. The die of claim 15 wherein said insulating material is selected from the group consisting of ceramic insulation and putty ceramics.
  • 17. The die of claim 14 wherein said die is adapted to be in-line with said extruder.
  • 18. The die of claim 14 wherein said baffle is situated relative to said flow channel such that said baffle is adapted to divert said cooling fluid toward said surface which is an interior surface that defines a hollow portion of said product.
  • 19. The die of claim 14 wherein said baffle is situated relative to said flow channel such that said baffle is adapted to divert said cooling fluid toward said surface which is an exterior surface of said product.
  • 20. The die of claim 14 wherein said baffle has an inner conical portion adapted to divert said cooling fluid toward said surface of said product.
  • 21. The die of claim 14 further comprising a layer of insulating material on an exit end of said die.
  • 22. A die adapted to be used with an extruder to form a product having an interior surface that defines a hollow portion, said die comprising:a flow channel adapted to be in fluid communication with said extruder such that an extruded material is forced through said flow channel to form said product; a passage extending through said die and intersecting said flow channel, said passage adapted to be in fluid communication with a source of a cooling fluid; and a baffle in fluid communication with said passage, said baffle adapted to divert said cooling fluid toward said interior surface of said product as said product exits said die.
  • 23. The die of claim 22 wherein said passage is lined with an insulating material.
  • 24. The die of claim 23 wherein said insulating material is selected from the group consisting of ceramic insulation and putty ceramics.
  • 25. The die of claim 22 wherein said die is adapted to be in-line with said extruder.
  • 26. The die of claim 22 wherein said baffle has an inner conical portion adapted to divert said cooling fluid toward said interior surface of said product.
  • 27. The die of claim 22 further comprising a layer of insulating material on an exit end of said die.
Parent Case Info

This is a continuation-in-part of U.S. application Ser. No. 10/025,432, filed Dec. 19, 2001, which is a continuation-in-part of U.S. application Ser. No. 09/766,054, filed Jan. 19, 2001, each of which is hereby incorporated by reference in its entirety.

US Referenced Citations (229)
Number Name Date Kind
2010207 Topham et al. Aug 1935 A
2188396 Semon Jan 1940 A
2489373 Gilman Nov 1949 A
2514471 Calhoun Jul 1950 A
2519442 Delorme et al. Aug 1950 A
2558378 Petry Jun 1951 A
2635976 Meiler et al. Apr 1953 A
2680102 Becher Jun 1954 A
2789903 Lukman et al. Apr 1957 A
2935763 Newman et al. May 1960 A
3287480 Wechsler et al. Nov 1966 A
3308218 Etal Mar 1967 A
3308507 Black Mar 1967 A
3309444 Schueler Mar 1967 A
3492388 Inglin-Knüsel Jan 1970 A
3493527 Schueler Feb 1970 A
3562373 Logrippo Feb 1971 A
3645939 Gaylord Feb 1972 A
3671615 Price Jun 1972 A
3864201 Susuki et al. Feb 1975 A
3867493 Seki Feb 1975 A
3878143 Baumann et al. Apr 1975 A
3879505 Boutillier et al. Apr 1975 A
3888810 Shinomura Jun 1975 A
3899559 Johnanson et al. Aug 1975 A
3922328 Johnson Nov 1975 A
3931384 Forquer et al. Jan 1976 A
3943079 Hamed Mar 1976 A
3954555 Kole et al. May 1976 A
3956541 Pringle May 1976 A
3956555 McKean May 1976 A
3969459 Fremont et al. Jul 1976 A
4005162 Bucking Jan 1977 A
4012348 Chelland et al. Mar 1977 A
4016232 Pringle Apr 1977 A
4016233 Pringle Apr 1977 A
4018722 Baker Apr 1977 A
4029831 Daunheimer Jun 1977 A
4045603 Smith Aug 1977 A
4054632 Franke Oct 1977 A
4056591 Goettler et al. Nov 1977 A
4058580 Flanders Nov 1977 A
4071479 Broyde et al. Jan 1978 A
4071494 Gaylord Jan 1978 A
4097648 Pringle Jun 1978 A
4102106 Golder et al. Jul 1978 A
4107110 Lachowicz et al. Aug 1978 A
4115497 Halmø et al. Sep 1978 A
4145389 Smith Mar 1979 A
4157415 Lindenberg Jun 1979 A
4168251 Schinzel et al. Sep 1979 A
4178411 Cole et al. Dec 1979 A
4181764 Totten Jan 1980 A
4187352 Klobbie Feb 1980 A
4191798 Schumacher et al. Mar 1980 A
4192839 Hayashi et al. Mar 1980 A
4203876 Dereppe et al. May 1980 A
4221621 Seki et al. Sep 1980 A
4228116 Colombo et al. Oct 1980 A
4239679 Rolls et al. Dec 1980 A
4241133 Lund et al. Dec 1980 A
4244903 Schnause Jan 1981 A
4248743 Goettler Feb 1981 A
4248820 Haataja Feb 1981 A
4250222 Mavel et al. Feb 1981 A
4263184 Leo et al. Apr 1981 A
4263196 Schumacher et al. Apr 1981 A
4272577 Lyng Jun 1981 A
4273688 Porzel et al. Jun 1981 A
4277428 Luck et al. Jul 1981 A
4290988 Nopper et al. Sep 1981 A
4303019 Haataja et al. Dec 1981 A
4305901 Prince et al. Dec 1981 A
4317765 Gaylord Mar 1982 A
4323625 Coran et al. Apr 1982 A
4376144 Goettler Mar 1983 A
4382108 Carroll et al. May 1983 A
4382758 Nopper et al. May 1983 A
4393020 Li et al. Jul 1983 A
4414267 Coran et al. Nov 1983 A
4420351 Lussi et al. Dec 1983 A
4430468 Schumacher Feb 1984 A
4440708 Haataja et al. Apr 1984 A
4480061 Coughlin et al. Oct 1984 A
4481701 Hewitt Nov 1984 A
4491553 Yamada et al. Jan 1985 A
4503115 Hemels et al. Mar 1985 A
4505869 Nishibori Mar 1985 A
4506037 Suzuki et al. Mar 1985 A
4508595 Gåsland Apr 1985 A
4562218 Fornadel et al. Dec 1985 A
4573893 Waters et al. Mar 1986 A
4594372 Natov et al. Jun 1986 A
4597928 Terentiev et al. Jul 1986 A
4610900 Nishibori Sep 1986 A
4645631 Hegenstaller et al. Feb 1987 A
4659754 Edwards et al. Apr 1987 A
4663107 Takada et al. May 1987 A
4663225 Farley et al. May 1987 A
4687793 Motegi et al. Aug 1987 A
4717742 Beshay Jan 1988 A
4734236 Davis Mar 1988 A
4737532 Fujita et al. Apr 1988 A
4746688 Bistak et al. May 1988 A
4769109 Tellvik et al. Sep 1988 A
4769274 Tellvik et al. Sep 1988 A
4783493 Motegi et al. Nov 1988 A
4789604 van der Hoeven Dec 1988 A
4790966 Sandberg et al. Dec 1988 A
4791020 Kokta Dec 1988 A
4801495 van der Hoeven Jan 1989 A
4818604 Tock Apr 1989 A
4820749 Beshay Apr 1989 A
4851458 Hopperdietzel Jul 1989 A
4865788 Davis Sep 1989 A
4889673 Takimoto Dec 1989 A
4894192 Warych Jan 1990 A
4915764 Miani Apr 1990 A
4927572 van der Hoeven May 1990 A
4927579 Moore May 1990 A
4935182 Ehner et al. Jun 1990 A
4960548 Ikeda et al. Oct 1990 A
4968463 Levasseur Nov 1990 A
4973440 Tamura et al. Nov 1990 A
4978489 Radvan et al. Dec 1990 A
4988478 Held Jan 1991 A
5002713 Palardy et al. Mar 1991 A
5008310 Beshay Apr 1991 A
5009586 Pallmann Apr 1991 A
5049334 Bach Sep 1991 A
5057167 Gersbeck Oct 1991 A
5064592 Ueda et al. Nov 1991 A
5075057 Hoedl Dec 1991 A
5075359 Castagna et al. Dec 1991 A
5078937 Eela Jan 1992 A
5082605 Brooks et al. Jan 1992 A
5087400 Theuveny Feb 1992 A
5088910 Goforth et al. Feb 1992 A
5096046 Goforth et al. Mar 1992 A
5096406 Brooks et al. Mar 1992 A
5120776 Raj et al. Jun 1992 A
5137673 Bourcier et al. Aug 1992 A
5153241 Beshay Oct 1992 A
5194461 Bergquist et al. Mar 1993 A
5219634 Aufderhaar Jun 1993 A
5272000 Chenoweth et al. Dec 1993 A
5276082 Forry et al. Jan 1994 A
5288772 Hon Feb 1994 A
5302634 Mushovic Apr 1994 A
5369147 Mushovic Nov 1994 A
5393536 Brandt et al. Feb 1995 A
5406768 Giuseppe et al. Apr 1995 A
5422170 Iwata et al. Jun 1995 A
5435954 Wold Jul 1995 A
5441801 Deaner et al. Aug 1995 A
5458834 Faber et al. Oct 1995 A
5474722 Woodhams Dec 1995 A
5480602 Nagaich Jan 1996 A
5486553 Deaner et al. Jan 1996 A
5497594 Giuseppe et al. Mar 1996 A
5516472 Laver May 1996 A
5518677 Deaner et al. May 1996 A
5532065 Gübitz Jul 1996 A
5537789 Minke et al. Jul 1996 A
5539027 Deaner et al. Jul 1996 A
5576374 Betso et al. Nov 1996 A
5585155 Heikkila et al. Dec 1996 A
5593625 Riebel et al. Jan 1997 A
5597586 Wilson et al. Jan 1997 A
5695874 Deaner et al. Dec 1997 A
5730914 Ruppman, Sr. Mar 1998 A
5773138 Seethamraju et al. Jun 1998 A
5783125 Bastone et al. Jul 1998 A
5827462 Brandt et al. Oct 1998 A
5827607 Deaner et al. Oct 1998 A
5836128 Groh et al. Nov 1998 A
5866264 Zehner et al. Feb 1999 A
5882564 Puppin Mar 1999 A
5932334 Deaner et al. Aug 1999 A
5948505 Puppin Sep 1999 A
5948524 Seethamraju et al. Sep 1999 A
5981067 Seethamraju et al. Nov 1999 A
5985429 Plummer et al. Nov 1999 A
6004668 Deaner et al. Dec 1999 A
6007656 Heikkila et al. Dec 1999 A
6011091 Zehner Jan 2000 A
6015611 Deaner et al. Jan 2000 A
6015612 Deaner et al. Jan 2000 A
6035588 Zehner et al. Mar 2000 A
6054207 Finley Apr 2000 A
6103791 Zehner Aug 2000 A
6106944 Heikkila et al. Aug 2000 A
6117924 Brandt Sep 2000 A
6122877 Hendrickson et al. Sep 2000 A
6131355 Groh et al. Oct 2000 A
6153293 Dahl et al. Nov 2000 A
6180257 Brandt et al. Jan 2001 B1
6210616 Suwanda Apr 2001 B1
6210792 Seethamraju et al. Apr 2001 B1
6248813 Zehner Jun 2001 B1
6265037 Godavarti et al. Jul 2001 B1
6272808 Groh et al. Aug 2001 B1
6280667 Koenig et al. Aug 2001 B1
6284098 Jacobsen Sep 2001 B1
6295778 Burt Oct 2001 B1
6323279 Guntherberg et al. Nov 2001 B1
6337138 Zehner Jan 2002 B1
6341458 Burt Jan 2002 B1
6342172 Finley Jan 2002 B1
6344504 Zehner et al. Feb 2002 B1
6346160 Puppin Feb 2002 B1
6357197 Serino et al. Mar 2002 B1
6358585 Wolff Mar 2002 B1
6360508 Pelfrey et al. Mar 2002 B1
6409952 Hacker et al. Jun 2002 B1
6423257 Stobart et al. Jul 2002 B1
6453630 Buhrts et al. Sep 2002 B1
6464913 Korney, Jr. Oct 2002 B1
6498205 Zehner Dec 2002 B1
6511757 Brandt et al. Jan 2003 B1
20010019749 Godavarti et al. Sep 2001 A1
20010051242 Godavarti et al. Dec 2001 A1
20010051243 Godavarti et al. Dec 2001 A1
20020015820 Puppin Feb 2002 A1
20020038684 Puppin Apr 2002 A1
20020040557 Felton Apr 2002 A1
20020092256 Hendrickson et al. Jul 2002 A1
20020192401 Matsumoto et al. Dec 2002 A1
20020192431 Edgman Dec 2002 A1
Foreign Referenced Citations (19)
Number Date Country
2042176 Apr 1971 DE
3801574 Aug 1989 DE
40333849 Oct 1990 DE
4221070 Dec 1993 DE
0269470 Jan 1988 EP
0586211 Mar 1994 EP
0586212 Mar 1994 EP
0586213 Mar 1994 EP
0747419 Dec 1996 EP
2270311 Feb 1974 FR
2365017 Apr 1978 FR
2445885 Aug 1980 FR
2564374 Nov 1985 FR
1443194 Jul 1976 GB
2036148 Jun 1980 GB
2104903 Mar 1983 GB
2171953 Sep 1986 GB
2186655 Aug 1987 GB
WO 9008020 Jul 1990 WO
Non-Patent Literature Citations (37)
Entry
Bendtsen et al., Mechanical Properties of Wood, pp. 4-2 to 4-44.
Bibliography of Solid Phase Extrusion, pp. 187-195.
Brzoskowski et al., Air-Lubricated Die for Extrusion of Rubber Compounds, Rubber Chemistry and Technology, vol. 60, p. 945-956.
Collier et al., High Strength Extrudates by Melt Transformation Coextrusion, ANTEC, 1987, pp. 497-502.
Collier et al., Streamlined Dies and Profile Extrusion, ANTEC, 1987, pp. 203-206.
Company News, Plastics Industry News, May 1994, pp. 70-71.
Dalväg et al., The Efficiency of Cellulosic Fillers in Common Thermoplastics. Part II. Filling with Processing Aids and Coupling Agents, 1985, vol. 11, pp. 9-38.
Fiberloc Polymer Composites, B.F. Goodrich, Geon Vinyl Division, section 1, pp. 2-15.
Fill Thermoplastics with Wood, Modern Plastics, May 1974, pp. 54-55.
Fillers for Thermoplastics: Beyond Resin Stretching, Modern Plastics International, Oct. 1976, pp. 12-15.
From Sweden: Extruded Interior Trim Made of PVC and Wood Flour, Plastic Building.
Construction, vol. 9 No. 5, 1986, pp. 5-6.
Henrici-Olive et al., Integral/Structural Ploymer Foams, Technology, Properties and Applications, Springer-Verlag, pp. 111-122.
Klason et al., The Efficiency of Cellulosic Fillers in Common Thermoplastics. Part 1. Filling without Processing Aids or Coupling Agents, Polymeric Materials, 1984, vol. 10, pp. 159-187.
Kokta et al., Composites of Poly(Vinyl Chloride) and Wood Fibers. Part II: Effect of Chemical Treatment, Polymer Composites, Apr. 1990, pp. 84-89.
Kokta et al., Composites of Polyvinyl Chloride—Wood Fibers. I. Effect of Isocyanate as a Bonding Agent, Polym.—Plast. Technol. Eng., 1990, 29(1&2), pp. 87-118.
Kokta et al., Composites of Polyvinyl Chloride—Wood Fibers. III: Effect of Silane as Coupling Agent, Journal of Vinyl Technology, Sep. 1990, pp. 146-153.
Kokta et al., Use of Grafted Wood Fibers in Thermoplastic Composites v. Polystyrene, Centre de recherche en pâtes et papiers, Université du Québec á Trois-Riviéres, Canada.
Kokta et al., Use of Wood Fibers in Thermoplastics Composites, Polymer Composites, Oct. 1983, pp. 229-232.
Maldas et al., Composites of Polyvinyl Chloride—Wood Fibers: IV. Effect of the Nature of Fibers, Journal of Vinyl Technology, Jun. 1989, pp. 90-98.
Maldas, et al., Improving Adhesion of Wood Fiber with Polystrene by the Chemical Treatment of Fiber with a Coupling Agent and the Influence on the Mechanical Properties of Composites, Journal of Adhesion Science Technology, vol. 3 No. 7, pp. 529-539 (1989).
Myers et al., “Wood flour and polypropylene or high-density polyethylene composites: influence of maleated polypropylene concentration and extrusion temperature on properties”, “Wood Fiber/Polymer Composites: Fundamental Concepts, Processes, and Material Options”, pp. 49-56.
Myers et al., Bibliography: Composites from Plastics and Wood-Based Fillers, USDA Forest Products Laboratory, Madison, WI, pp. 1-27 odds (1991).
Myers et al., Effects of Composition and Polypropylene Melt Flow on Polypropylene-Waste Newspaper Composites, ANTEC, 1984, pp. 602-604.
Pornnimit et al., Extrusion of Self-Reinforced Polyethylene, Advances in Polymer Technology, vol. 11, No. 2, pp. 92-98.
Raj et al., Use of Wood Fiber as Filler in Common Thermoplastics: Studies on Mechanical Properties, Science and Engineering of Composite Materials, vol. 1 No. 3, 1989, pp. 85-98.
Raj et al., Use of Wood Fibers in Thermoplastics. VII. The Effect of Coupling Agents in Polyethylene-Wood Fiber Composites, Journal of Applied Polymer Science, vol. 37, pp. 1089-1103 (1989).
Resin Stretching: Accent on Performance, Modern Plastic International, Jan. 1974, pp. 58-60.
Rogalski et al., Poly(Vinyl-Chloride) Wood Fiber Composites, ANTEC, 1987, pp. 1436-1441.
Sonwood Outline, Apr., 1975.
Sonwood: a new PVC wood-flour alloy for Extrusions and other Plastic Processing Techniques, Sonesson Plast AB, Malmo, Sweden.
Thomas et al., Wood Fibers for Reinforcing Fillers for Polyolefins, ANTEC, 1984, pp. 687-689.
Wood Filled PVC, Plastics Industry News, Jul. 1996, p. 6.
Woodhams et al., Wood Fibers for Reinforcing Fillers for Polyolefins, Polymer Engineering and Science, Oct. 1984, pp. 1166-1171.
Yam et al., Composites from Compounding Wood Fibers With Recycled High Density Polyethylene, Polymer Engineering and Science, mid-Jun. 1990, pp. 693-699, vol. 30, No. 11.
Yuskova et al., Interaction of Components in Poly(Vinyl Choloride) Filled in Polymetization, Makroniol Chem., Macromol. Symp. 29, 315-320 (1989).
Zadorecki et al., Future Prospects for Wood Cellulose as Reinforcement In Organic Polymer Composites, Polymer Composites, Apr. 1989, pp. 69-77.
Continuation in Parts (2)
Number Date Country
Parent 10/025432 Dec 2001 US
Child 10/131578 US
Parent 09/766054 Jan 2001 US
Child 10/025432 US