Patent Application
20190112421
This application claims the benefit of Korean Patent Application No. 10-2016-0136730 filed on Oct. 20, 2016 with the Korean Intellectual Property Office, the disclosure of which is incorporated herein by reference in its entirety.
The present disclosure relates to a copolycarbonate having improved flowability while maintaining excellent impact strength at room temperature and low temperature, and a composition including the same.
Polycarbonate resins are prepared by condensation-polymerization of an aromatic diol such as bisphenol A with a carbonate precursor such as phosgene, and have excellent impact strength, dimensional stability, heat resistance and transparency. Thus, the polycarbonate resins have application in a wide range of uses, such as exterior materials of electrical and electronic products, automobile parts, building materials, and optical components.
Recently, in order to apply these polycarbonate resins to more various fields, many studies have been made to obtain desired physical properties by copolymerizing two or more aromatic diol compounds having different structures from each other and introducing units having different structures in a main chain of the polycarbonate.
Especially, studies for introducing a polysiloxane structure in a main chain of the polycarbonate have been undergone, but most of these technologies have disadvantages in that production costs are high, and flowability is deteriorated when impact strength or chemical resistance, particularly impact strength at low temperature is increased.
Therefore, the present inventors have studied copolycarbonate resins having improved flowability while maintaining excellent impact strength at room temperature and low temperature by solving the above disadvantages, and have found that a copolycarbonate in which a specific polysiloxane structure and a sebacoyl structure are introduced into the main chain of the polycarbonate as described below satisfies the above conditions, thereby completing the present invention.
It is an object of the present disclosure to provide a copolycarbonate having improved flowability while maintaining excellent impact strength at room temperature and low temperature.
It is another object of the present disclosure to provide a composition including the copolycarbonate.
In order to achieve the above objects, the present disclosure provides a copolycarbonate including a repeating unit represented by Chemical Formula 1, a repeating unit represented by Chemical Formula 2, a repeating unit represented by Chemical Formula 3, and a repeating unit represented by Chemical Formula 4:
in Chemical Formula 1,
R1 to R4 are each independently hydrogen, C1-10 alkyl, C1-10 alkoxy, or halogen, and
Z1 is C1-10 alkylene unsubstituted or substituted with phenyl, C3-15 cycloalkylene unsubstituted or substituted with C1-10 alkyl, O, S, SO, SO2, or CO,
in Chemical Formula 2,
each of X1 is independently C1-10 alkylene,
each of R5 is independently hydrogen; C1-15 alkyl unsubstituted or substituted with oxiranyl, oxiranyl-substituted C1-10 alkoxy, or C6-20 aryl; halogen; C1-10 alkoxy; allyl; C1-10 haloalkyl; or C6-20 aryl, and
n is an integer of 10 to 200,
in Chemical Formula 3,
each of X2 is independently C1-10 alkylene,
each of Y1 is independently hydrogen, C1-6 alkyl, halogen, hydroxy, C1-6 alkoxy or C6-20 aryl,
each of R6 is independently hydrogen; C1-15 alkyl unsubstituted or substituted with oxiranyl, oxiranyl-substituted C1-10 alkoxy, or C6-20 aryl; halogen; C1-10 alkoxy; allyl; C1-10 haloalkyl; or C6-20 aryl, and
m is an integer of 10 to 200,
in Chemical Formula 4,
Z2 is C1-10 alkylene unsubstituted or substituted with phenyl, C3-15 cycloalkylene unsubstituted or substituted with C1-10 alkyl, O, S, SO, SO2, or CO, and
l is an integer of 1 to 10.
The polycarbonate resin is prepared by condensation-polymerization of an aromatic diol such as bisphenol A with a carbonate precursor such as phosgene, and it itself has excellent mechanical properties, but it is necessary to satisfy various physical properties at the same time depending on the application field. Particularly, the polycarbonate resin may improve specific physical properties by changing the structure of the polycarbonate resin. However, in most cases, when one of the physical properties is improved, the other properties are deteriorated.
Accordingly, the present disclosure introduced the repeating units of the Chemical Formulae 2, 3, and 4 in addition to the conventional polycarbonate structure containing the repeating unit of the Chemical Formula 1 to improve flowability while maintaining excellent impact strength at room temperature and low temperature. By introducing the repeating units of the Chemical Formulae 2 to 4, various physical properties of the polycarbonate can be improved without deteriorating other physical properties.
Hereinafter, a copolycarbonate and a composition including the same according to specific embodiments of the present disclosure will be described in more detail.
Repeating Unit of Chemical Formula 1
The repeating unit represented by Chemical Formula 1 forms a basic structure of the copolycarbonate resin according to the present disclosure, and is formed by reacting an aromatic diol compound and a carbonate precursor.
In Chemical Formula 1, preferably, R1 to R4 are each independently hydrogen, methyl, chloro, or bromo.
Further, Z1 is preferably a linear or branched C1-10 alkylene unsubstituted or substituted with phenyl, and more preferably methylene, ethane-1,1-diyl, propane-2,2-diyl, butane-2,2-diyl, 1-phenylethane-1,1-diyl, or diphenylmethylene. Further, preferably, Z1 is cyclohexane-1,1-diyl, O, S, SO, SO2, or CO.
Preferably, the repeating unit represented by Chemical Formula 1 may be derived from one or more aromatic diol compounds selected from the group consisting of bis(4-hydroxyphenyl)methane, bis(4-hydroxyphenyl)ether, bis(4-hydroxyphenyl)sulfone, bis(4-hydroxyphenyl)sulfoxide, bis(4-hydroxyphenyl)sulfide, bis(4-hydroxyphenyl)ketone, 1,1-bis(4-hydroxyphenyl)ethane, bisphenol A, 2,2-bis(4-hydroxyphenyl)butane, 1,1-bis(4-hydroxyphenyl)cyclohexane, 2,2-bis(4-hydroxy-3,5-dibromophenyl)propane, 2,2-bis(4-hydroxy-3,5-dichlorophenyl)propane, 2,2-bis(4-hydroxy-3-bromophenyl)propane, 2,2-bis(4-hydroxy-3-chlorophenyl)propane, 2,2-bis(4-hydroxy-3-methylphenyl)propane, 2,2-bis(4-hydroxy-3,5-dimethylphenyl)propane, 1,1-bis(4-hydroxyphenyl)-1-phenylethane, bis(4-hydroxyphenyl)diphenylmethane, and α,ω-bis[3-(o-hydroxyphenyl)propyl]polydimethylsiloxane.
As used herein, ‘derived from aromatic diol compounds’ means that a hydroxy group of the aromatic diol compound and a carbonate precursor are reacted to form the repeating unit represented by Chemical Formula 1.
For example, when bisphenol A, which is an aromatic diol compound, and triphosgene, which is a carbonate precursor, are polymerized, the repeating unit represented by Chemical Formula 1 is represented by the following Chemical Formula 1-1:
The carbonate precursor used herein may include one or more selected from the group consisting of dimethyl carbonate, diethyl carbonate, dibutyl carbonate, dicyclohexyl carbonate, diphenyl carbonate, ditolyl carbonate, bis(chlorophenyl)carbonate, di-m-cresyl carbonate, dinaphthyl carbonate, bis(diphenyl)carbonate, phosgene, triphosgene, diphosgene, bromophosgene and bishaloformate. Preferably, triphosgene or phosgene may be used.
Repeating Unit of Chemical Formula 2 and Repeating Unit of Chemical Formula 3
The repeating units represented by Chemical Formulae 2 and 3 have a polyorganosiloxane structure, and may be introduced into copolycarbonate to improve various physical properties.
In Chemical Formula 2, each of X1 is independently preferably C2-10 alkylene, more preferably C2-4 alkylene, and most preferably propane-1,3-diyl.
Also, preferably, each of R5 is independently hydrogen, methyl, ethyl, propyl, 3-phenylpropyl, 2-phenylpropyl, 3-(oxiranylmethoxy)propyl, fluoro, chloro, bromo, iodo, methoxy, ethoxy, propoxy, allyl, 2,2,2-trifluoroethyl, 3,3,3-trifluoropropyl, phenyl, or naphthyl. In addition, each of R5 is independently preferably C1-10 alkyl, more preferably C1-6 alkyl, more preferably C1-3 alkyl, and most preferably methyl.
Preferably, n is an integer of 10 or more, 15 or more, 20 or more, 25 or more, 30 or more, 31 or more, or 32 or more, and 50 or less, 45 or less, 40 or less, 39 or less, 38 or less, or 37 or less.
In Chemical Formula 3, each of X2 is independently preferably C2-10 alkylene, more preferably C2-6 alkylene, and most preferably isobutylene.
Further, preferably, Y1 is hydrogen.
Further, preferably, each of R6 is independently hydrogen, methyl, ethyl, propyl, 3-phenylpropyl, 2-phenylpropyl, 3-(oxiranylmethoxy)propyl, fluoro, chloro, bromo, iodo, methoxy, ethoxy, propoxy, allyl, 2,2,2-trifluoroethyl, 3,3,3-trifluoropropyl, phenyl, or naphthyl. Further, preferably, each of R6 is independently C1-10 alkyl, more preferably C1-6 alkyl, more preferably C1-3 alkyl, and most preferably methyl.
Preferably, m is an integer of 30 or more, 35 or more, 40 or more, 45 or more, 46 or more, 47 or more, or 48 or more, and 70 or less, 65 or less, 60 or less, 55 or less, 54 or less, 53 or less, or 52 or less.
The repeating unit represented by Chemical Formula 2 and the repeating unit represented by Chemical Formula 3 are, respectively, derived from a siloxane compound represented by the following Chemical Formula 2-1 and a siloxane compound represented by the following Chemical Formula 3-1:
in Chemical Formula 2-1,
X1, R5 and n are the same as previously defined.
in Chemical Formula 3-1,
X2, Y1, R6 and m are the same as previously defined.
As used herein, ‘derived from a siloxane compound’ means that a hydroxy group of the respective siloxane compound and a carbonate precursor are reacted to form the repeating unit represented by Chemical Formula 2 and the repeating unit represented by Chemical Formula 3. Further, the carbonate precursors that can be used for the formation of the repeating units represented by Chemical Formulae 2 and 3 are the same as those described for the carbonate precursor that can be used for the formation of the repeating unit represented by Chemical Formula 1 described above.
Preferably, the repeating unit represented by Chemical Formula 2 is represented by the following Chemical Formula 2-2:
in Chemical Formula 2-2, R5 and n are the same as previously defined. Preferably, R5 is methyl.
Preferably, the repeating unit represented by Chemical Formula 3 is represented by the following Chemical Formula 3-2:
in Chemical Formula 3-2, R6 and m are the same as previously defined. Preferably, R6 is methyl.
Repeating Unit of Chemical Formula 4
The repeating unit represented by Chemical Formula 4 has a sebacoyl structure, and may be introduced into copolycarbonate to improve flowability.
In Chemical Formula 4, Z2 is preferably a linear or branched C1-10 alkylene unsubstituted or substituted with phenyl, and more preferably methylene, ethane-1,1-diyl, propane-2,2-diyl, butane-2,2-diyl, 1-phenylethane-1,1-diyl, or diphenylmethylene. Further, preferably, Z2 is cyclohexane-1,1-diyl, O, S, SO, SO2, or CO.
Preferably, the repeating unit represented by Chemical Formula 4 is represented by the following Chemical Formula 4-1:
Further the repeating unit represented by Chemical Formula 4 is formed by reacting a composition including a compound represented by the following Chemical Formula 4-2, an aromatic diol compound, and a carbonate precursor:
in Chemical Formula 4-2,
R′ is hydrogen, OH, C1-10 alkyl, or halogen, and 1 is the same as previously defined.
Further, the aromatic diol compound and the carbonate precursor are the same as those described for the aromatic diol compound and the carbonate precursor that can be used for the formation of the repeating unit represented by Chemical Formula 1 described above.
Copolycarbonate
The copolycarbonate according to the present disclosure includes the repeating unit represented by Chemical Formula 1, the repeating unit represented by Chemical Formula 2, the repeating unit represented by Chemical Formula 3, and the repeating unit represented by Chemical Formula 4. Preferably, the copolycarbonate is a random copolymer.
In addition, various properties of the copolycarbonate may be improved simultaneously by controlling the content of each repeating unit. The weight ratio between the repeating unit represented by Chemical Formula 2 and the repeating unit represented by Chemical Formula 3 having the polyorganosiloxane structure may be 1:99 to 99:1. Preferably, the weight ratio is 3:97 to 97:3, and more preferably 5:95 to 95:5. The weight ratio of the above repeating units corresponds to the weight ratio of siloxane compounds, for example, the siloxane compound represented by Chemical Formula 2-1 and the siloxane compound represented by Chemical Formula 3-1.
In addition, the weight ratio between the repeating unit represented by Chemical Formula 1, and the repeating units represented by Chemical Formulae 2 and 3 (Chemical Formula 1: (Chemical Formulae 2 and 3)) may be 1:0.001 to 1:0.2, and more preferably 1:0.01 to 1:0.1. The weight ratio of the above repeating units corresponds to the weight ratio of the aromatic diol compound which is used to form the repeating unit represented by Chemical Formula 1, and siloxane compounds which are used to form the repeating units represented by Chemical Formulae 2 and 3.
In addition, the weight ratio between the repeating unit represented by Chemical Formula 1 and the repeating unit represented by Chemical Formula 4 may be 1:99 to 99:1. Preferably, the weight ratio is 2:98 to 98:2, and more preferably 3:97 to 97:3. The weight ratio of the above repeating units corresponds to the weight ratio of the aromatic diol compound and the compound represented by Chemical Formula 4-2.
The copolycarbonate according to the present disclosure may be prepared by the method including the step of polymerizing the aromatic diol compound, the carbonate precursor, two kinds of siloxane compounds represented by Chemical Formulae 2-1 and 3-1, and the compound represented by Chemical Formula 4-2.
The aromatic diol compound, the carbonate precursor, and the siloxane compounds are the same as previously described.
In addition, the polymerization is preferably carried out by an interfacial polymerization method. In this case, there is an advantage in that the polymerization reaction can be made at atmospheric pressure and low temperature, and it is easy to control the molecular weight.
The reaction temperature is preferably from 0° C. to 40° C., and the reaction time is preferably from 10 minutes to 5 hours. In addition, pH is preferably maintained at 9 or more, or 11 or more during the reaction.
The solvent which can be used in the polymerization is not particularly limited as long as it is a solvent that can be usually used in the polymerization of polycarbonate. For example, halogenated hydrocarbon such as methylene chloride or chlorobenzene may be used.
Further, the polymerization is preferably conducted in the presence of an acid binding agent, and the acid binding agent may be alkali metal hydroxides such as sodium hydroxide or potassium hydroxide, or amine compounds such as pyridine.
In addition, the polymerization may be conducted in the presence of a molecular weight modifier to control the molecular weight of the copolycarbonate. As the above molecular weight modifier, C1-20 alkylphenol may be used, and specifically, p-tert-butylphenol, p-cumyl phenol, decyl phenol, dodecyl phenol, tetradecyl phenol, hexadecyl phenol, octadecyl phenol, eicosyl phenol, docosyl phenol or triacontyl phenol may be used. The molecular weight modifier may be added before the initiation of polymerization, during the initiation of polymerization, or after the initiation of polymerization. The molecular weight modifier is contained, for example, in an amount of 0.01 parts by weight or more, 0.1 parts by weight or more, or 1 parts by weight or more, and 10 parts by weight or less, 6 parts by weight or less, or 5 parts by weight or less, preferably 0.1 to 6 parts by weight, based on 100 parts by weight of the aromatic diol compound. Within this range, the required molecular weight can be obtained.
In addition, a reaction accelerator, for example, a tertiary amine compound such as triethylamine, tetra-n-butyl ammonium bromide, and tetra-n-butylphosphonium bromide, a quaternary ammonium compound, or a quaternary phosphonium compound may be further used for accelerating the polymerization reaction.
In addition, the copolycarbonate has a weight average molecular weight (g/mol) of 1,000 to 100,000, preferably 30,000 to 70,000, and more preferably 40,000 to 60,000.
Preferably, the copolycarbonate according to the present disclosure has impact strength at room temperature of 800 to 1100 J/m, measured at 23° C. in accordance with ASTM D256 (⅛ inch, Notched Izod). More preferably, the impact strength at room temperature (J/m) is 820 or more, or 850 or more. In addition, there is no specific upper limit, because the higher impact strength at room temperature can be evaluated as the better. However, for example, the upper limit may be 1050 or less, or 1000 or less.
Preferably, the copolycarbonate according to the present disclosure has impact strength at low temperature of 550 to 1000 J/m, measured at −30° C. in accordance with ASTM D256 (⅛ inch, Notched Izod). More preferably, the impact strength at low temperature (J/m) is 560 or more, or 570 or more. In addition, there is no specific upper limit, because the higher impact strength at low temperature can be evaluated as the better. However, for example, the upper limit may be 950 or less, or 900 or less.
Preferably, the copolycarbonate according to the present disclosure has melt index of 7 to 30 g/10 min, measured in accordance with ASTM D1238 (300° C., 1.2 kg condition). More preferably, the melt index (g/10 min) is 8 or more, 8.5 or more, or 9 or more, and 18 or less, 15 or less, or 13 or less.
Preferably, the copolycarbonate according to the present disclosure has chemical resistance of 18 to 50 min, measured in accordance with Mini Jig measurement method. More preferably, the chemical resistance (min) is 19 or more, or 20 or more, and 40 or less, 30 or less, or 28 or less.
Polycarbonate Composition
In addition, the present disclosure provides a polycarbonate composition including the above-mentioned copolycarbonate and a polycarbonate.
The copolycarbonate may be used alone, but it can be used together with the polycarbonate as needed to control the physical properties of the copolycarbonate.
The above polycarbonate is distinguished from the copolycarbonate according to the present disclosure in that a polysiloxane structure is not introduced in a main chain of the polycarbonate.
Preferably, the above polycarbonate includes a repeating unit represented by the following Chemical Formula 5:
in Chemical Formula 5,
R′1 to R′4 are each independently hydrogen, C1-10 alkyl, C1-10 alkoxy, or halogen, and
Z1′ is C1-10 alkylene unsubstituted or substituted with phenyl, C3-15 cycloalkylene unsubstituted or substituted with C1-10 alkyl, O, S, SO, SO2, or CO.
In addition, the above polycarbonate has a weight average molecular weight of preferably 1,000 to 100,000 g/mol, more preferably 20,000 to 60,000 g/mol.
The repeating unit represented by Chemical Formula 5 is formed by reacting the aromatic diol compound and the carbonate precursor. The aromatic diol compound and the carbonate precursor that can be used herein are the same as previously described for the repeating unit represented by Chemical Formula 1.
Preferably, R′1 to R′4 and Z1′ in Chemical Formula 5 are the same as previously described for R1 to R4 and Z1 in Chemical Formula 1, respectively.
Further, preferably, the repeating unit represented by Chemical Formula 5 is represented by the following Chemical Formula 5-1:
In addition, the polycarbonate composition may further include one or more selected from the group consisting of antioxidants, heat stabilizers, light stabilizers, plasticizers, antistatic agents, nucleating agents, flame retardants, lubricants, impact reinforcing agents, fluorescent brightening agents, ultraviolet absorbers, pigments and dyes.
In addition, the present disclosure provides an article including the above-mentioned polycarbonate composition. Preferably, the article is an injection molded article.
The method for preparing the article may include the steps of mixing the polycarbonate composition according to the present disclosure and the additives, if necessary, using a mixer, extrusion-molding the mixture with an extruder to produce a pellet, drying the pellet and then injecting the dried pellet using an injection molding machine.
As described above, the copolycarbonate according to the present disclosure may introduce a sebacoyl structure in addition to the polysiloxane structure into the main chain of the polycarbonate, thereby improving the flowability while maintaining the excellent physical properties of the polycarbonate.
The present invention will be described in more detail with reference to the following Examples. However, the following examples are for illustrative purposes only, and the invention is not intended to be limited by the following examples.
47.60 g (160 mmol) of octamethylcyclotetrasiloxane and 2.40 g (17.8 mmol) of tetramethyldisiloxane were mixed. The mixture was then placed in 3 L flask together with 1 part by weight of an acid clay (DC-A3) relative to 100 parts by weight of octamethylcyclotetrasiloxane, and reacted at 60° C. for 4 hours. After completion of the reaction, the reaction product was diluted with ethyl acetate and quickly filtered using a celite. The repeating unit (n) of the unmodified polyorganosiloxane thus prepared was 34 when confirmed through 1H NMR.
To the resulting terminal-unmodified polyorganosiloxane, 4.81 g (35.9 mmol) of 2-allylphenol and 0.01 g (50 ppm) of Karstedt's platinum catalyst were added and reacted at 90° C. for 3 hours. After completion of the reaction, the unreacted siloxane was removed by conducting evaporation under the conditions of 120° C. and 1 torr. The terminal-modified polyorganosiloxane thus prepared was designated as AP-PDMS (n=34). AP-PDMS was pale yellow oil and the repeating unit (n) was 34 when confirmed through 1H NMR using Varian 500 MHz, and further purification was not required.
47.60 g (160 mmol) of octamethylcyclotetrasiloxane and 1.5 g (11 mmol) of tetramethyldisiloxane were mixed. The mixture was then introduced in 3 L flask together with 1 part by weight of an acid clay (DC-A3) relative to 100 parts by weight of octamethylcyclotetrasiloxane, and reacted at 60° C. for 4 hours. After completion of the reaction, the reaction product was diluted with ethyl acetate and quickly filtered using a celite. The repeating unit (m) of the terminal-unmodified polyorganosiloxane thus prepared was 58 when confirmed through 1H NMR.
To the resulting terminal-unmodified polyorganosiloxane, 6.13 g (29.7 mmol) of 3-methylbut-3-enyl 4-hydroxybenzoate and 0.01 g (50 ppm) of Karstedt's platinum catalyst were added and reacted at 90° C. for 3 hours. After completion of the reaction, the unreacted siloxane was removed by conducting evaporation under the conditions of 120° C. and 1 torr. The terminal-modified polyorganosiloxane thus prepared was designated as MBHB-PDMS (m=58). MBHB-PDMS was pale yellow oil, the repeating unit (m) was 58 when confirmed through 1H NMR using Varian 500 MHz and further purification was not required.
To a 2 L main reactor equipped with a nitrogen purge device and a condenser and enabling maintenance at room temperature using a circulator, 620 g of H2O, 116.47 g of bisphenol A (BPA), 5.5 g of AP PDMS prepared in Preparation Example 1, 0.29 g of MBHB PDMS prepared in Preparation Example 2, 0.93 g of Sebacoyl chloride, 102.5 g of NaOH, and 200 ml of MeCl2 were injected, followed by stirring for a few minutes.
After stopping the nitrogen purge, 62 g of triphosgene and 120 g of MeCl2 were added to a 1 L round-bottom flask to dissolve triphosgene. Then, the dissolved triphosgene solution was slowly injected to the main reactor where the BPA solution was dissolved. After completion of injection, 2.12 g of PTBP was added, followed by stirring for about 10 minutes. After completion of stirring, 97 g of 40 wt % NaOH aqueous solution was added and 1.16 g of TEA as a coupling agent was added thereto. At this time, a reaction pH was maintained at 11˜13. After the reaction solution was allowed to stand for a time for sufficient reaction, pH was decreased to 3˜4 by addition of HCl to terminate the reaction. After stopping the stirring, a polymer layer and an aqueous layer were separated and then the aqueous layer was removed, and the residue was repeatedly washed with pure H2O again, and this washing process was repeated 3 to 5 times.
After completion of washing, only the polymer layer was extracted, and the polymer crystals were obtained by reprecipitation using a non-solvent such as methanol, H2O or the like.
In this regard, a weight average molecular weight of the prepared copolycarbonate was 55,000 g/mol.
A copolycarbonate was prepared in the same manner as in Example 1, except that the sebacoyl chloride was used in an amount of 2.92 g.
A copolycarbonate was prepared in the same manner as in Example 1, except that the AP PDMS was used in an amount of 5.24 g, and the MBHB PDMS was used in an amount of 0.58 g.
The copolycarbonate, which was prepared in the same manner as in Example 1, except that the AP PDMS was used in an amount of 5.24 g, the MBHB PDMS was used in an amount of 0.58 g, and the sebacoyl chloride was not used, and the polycarbonate (Neat PC; weight average molecular weight of 55,000 g/mol), which was prepared in the same manner as in Example 1, except that AP PDMS, MBHB PDMS, and sebacoyl chloride were not used, were mixed at a weight ratio of 1:1 and extruded.
A copolycarbonate was prepared in the same manner as in Example 1, except that the sebacoyl chloride was not used.
Each property was measured by the following method. The results are given in the following Table 1.
1) weight average molecular weight (Mw): measured by GPC with PS standard using Agilent 1200 series.
2) impact strength at room temperature and low temperature: measured in accordance with ASTM D256 (⅛ inch, Notched Izod) at room temperature and −30° C. (low temperature).
3) flowability (Melt Index; MI): measured in accordance with ASTM D1238 (300° C., 1.2 kg condition).
4) chemical resistance (Jig Test): 13 mm*64 mm*⅛ inch specimen was adhered closely to Mini Jig (58.5R), 5 mm*13 mm cotton was placed in the center, and then 0.5 ml of Nivea Sun spray was put thereon. The time at which the gap occurred in the adhered specimen was measured.
Referring to Table 1, it was confirmed that the copolycarbonates prepared in Examples 1 to 3 in which a specific polysiloxane structure and a sebacoyl structure were introduced into the main chain of the polycarbonate, exhibited not only the same level of impact strength at room temperature and low temperature but also excellent flowability and fluidity, compared with the copolycarbonate of Comparative Example 1 in which only a polysiloxane structure was introduced into the main chain of the polycarbonate, and the copolycarbonate of Comparative Example 2 in which the copolycarbonate of Comparative Example 1 was mixed with a general polycarbonate.
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/KR2017/011255 | 10/12/2017 | WO | 00 |
