Patent Grant
9533345
The present invention relates to a core molding machine and core molding method for molding a core by filling a core box with core sand.
A so-called top-blow type core molding machine in which a blow head is arranged above a core box so as to blow core sand down into the core box from thereabove has conventionally been used (e.g., Patent Literature 1).
In the case of the top-blow type core molding machine, however, the blow head is arranged above the core box, and a sand tank is further arranged above the blow head. This increases the size of the machine in its height direction, which may make the machine bulky. For reducing the size of the machine in its height direction and making it smaller in size, a so-called under-blow type in which a blow head is arranged under a core box so as to blow core sand up into the core box from thereunder may be employed. However, the under-blow type blows the core sand into the core box against gravity and thus may affect the filling property of the core sand for the core box.
Patent Literature 1: Japanese Patent Publication No. S47-013179
It is an object of the present invention to provide a core molding machine and core molding method which, even when employing the under-blow type for blowing core sand into a core box located on the upper side, can favorably fill the core box with the core sand.
The core molding machine in accordance with one aspect of the present invention comprises a core box having a pair of laterally separable dies and a sand filling device, having a blow head disposed under the core box, for filling the core box with core sand directed upward from the blow head, the blow head having a sand blow chamber for guiding the core sand to the core box while being connected to the core box and a sand storage chamber communicating with the sand blow chamber, the sand filling device having a compressed air supply unit for supplying the sand storage chamber with a compressed air for blowing the core sand into the core box and an aeration air supply unit for supplying an aeration air for floating and fluidizing the core sand within the sand blow chamber.
In the core molding machine in accordance with this aspect of the present invention, in a state where the core sand within the sand blow chamber is floated and fluidized by the aeration air supply unit, the compressed air supply unit blows the compressed air into the sand blow chamber through the sand storage chamber, thereby feeding the core sand from within the sand blow chamber to the core box. Therefore, even when employing the under-blow type for blowing the core sand to the core box located on the upper side, the core box can favorably be filled with the core sand.
The core molding machine in accordance with this aspect of the present invention may further comprise a frame member for holding a fixed die as one of the pair of dies, a first actuator for driving a movable die as the other of the pair of dies to move closer to or away from the fixed die, a second actuator for vertically driving the blow head to move closer to or away from the core box, and a rotary drive unit for rotating the movable die moved away from the fixed die by the first actuator. In this case, as the movable die moved away from the fixed die is rotated by the rotary drive unit, the core held by the movable die is easier to release and remove from the movable die.
The rotary drive unit may have a rotary axis member provided in a movable die holding member for holding the movable die, an abutment member provided in the rotary axis member so as to be rotatable with the rotary axis member, and an orientation change member for changing an orientation of the movable die through the rotary axis member when abutting against the abutment member; the orientation change member being located at a position, different from a height position of the rotary axis member, on a movement locus of the abutment member accompanying a movement of the movable die caused by the first actuator; when the movable die having the abutment member in contact with the orientation change member is moved away from the fixed die by the first actuator, the abutment member, while changing an orientation thereof along a surface of the orientation change member, may rotate the movable die with the aid of the rotary axis member and the movable die holding member. In this case, simply moving the movable die away from the fixed die by the first actuator can rotate the movable die separated from the fixed die. This makes it unnecessary to provide a separate actuator for rotating the movable die. Therefore, the machine can be made further simpler and smaller.
The core molding machine in accordance with this aspect of the present invention may further comprise a first release unit for releasing a core from the movable die after the movable die holding the core is rotated by the rotary drive unit such that the core is on the upper side. In this case, the first release unit releases the core from the movable die having been rotated such that the core is on the upper side. Therefore, the core released from the movable die by the first release unit can be kept held by the movable die. This can prevent the released core from dropping out of the movable die and make the released core easier to be handled by users.
The first release unit may comprise a slide member provided in the movable die and a guide member, provided on the frame member side, having a slide surface for changing a height position of the slide member when abutting against the slide member, the slide surface being located on a movement locus of the slide member accompanying a movement of the movable die caused by the first actuator after the movable die is rotated by the rotary drive unit; when the movable die having been rotated by the rotary drive unit is moved away from, the fixed die by the first actuator, the slide member slides along the slide surface so as to push the core held by the movable die away from the movable die. In this case, simply moving the movable die away from the fixed die by the first actuator can release the core from the movable die having been rotated. This makes it unnecessary to provide a separate actuator for releasing the core from the movable die. Therefore, the machine can be made further simpler and smaller.
The core molding machine in accordance with this aspect of the present invention may comprise a first cleaning unit adapted to abut against a blow head nozzle in the blow head when coming closer to the blow head and a second cleaning unit adapted to abut against a fixed die nozzle in the fixed die when coming closer to the fixed die; the first and second cleaning units being moved closer to or away from the fixed die together with the movable die by the first actuator; when moved closer to the blow head together with the movable die by the first actuator, the first cleaning unit may slide while abutting against the blow head nozzle, so as to clean the blow head nozzle; and when moved closer to the fixed die together with the movable die by the first actuator, the second cleaning unit may slide while abutting against the fixed nozzle, so as to clean the fixed die nozzle. In this case, simply moving the first and second cleaning units closer to or away from the fixed die by the first actuator can clean the blow head nozzle and fixed die nozzle. This makes it unnecessary to provide separate actuators for moving the first and second cleaning units, respectively. Therefore, the machine can be made further simpler and smaller.
The core molding machine in accordance with this aspect of the present invention may further comprise a third cleaning unit provided in the frame member and adapted to abut against a movable die nozzle in the movable die when coming closer to the movable die; when the movable die moved by the first actuator comes closer, the third cleaning unit may slide while abutting against the movable die nozzle, so as to clean the movable die nozzle. In this case, simply moving the movable die closer to or away from the fixed die by the first actuator can clean the movable die nozzle when the movable die comes closer to the third cleaning unit. This makes it unnecessary to provide a separate actuator for cleaning the movable die nozzle. Therefore, the machine can be made further simpler and smaller.
The core molding machine in accordance with this aspect of the present invention may further comprise a sand tank for supplying the sand storage chamber with the core sand through a supply port of the sand storage chamber and an on/off gate, disposed between the sand tank and the supply port, for opening and closing the supply port, the on/off gate being driven by the first actuator, so as to close the supply port when the movable die forms a cavity for forming the core together with the fixed die. In this case, simply driving the on/off gate by the first actuator can control the opening and closing of the supply port. This makes it unnecessary to provide a separate actuator for driving the on/off gate. Therefore, the machine can be made further simpler and smaller.
The core molding machine in accordance with this aspect of the present invention may further comprise a flexible hose disposed between the sand tank and the supply port of the sand storage chamber. Since the flexible hose is deformable in this case, when the blow head is moved up and down by the second actuator while in a state where the sand tank is fixed, the flexible hose deforms so as to follow the movement of the blow head. This makes it unnecessary to move the sand tank up and down together with the blow head. Therefore, the machine can be made further simpler and smaller.
The core molding machine in accordance with this aspect of the present invention may further comprise a second release unit for releasing a core from the fixed die such that the core is held by the movable die when the core is molded within a cavity, formed by the movable die and the fixed die, for forming the core and the movable die is separated from the fixed die by the first actuator. In this case, the core can be held by the movable die while being released from the fixed die by the second release unit. Therefore, the core can be taken out from the core box more easily.
The second release unit may have a push member, provided in the fixed die and movable between a projected position protruding from the fixed die toward the movable die and a retracted position receding more from the movable die than is the projected position, for separating the core from the fixed die, an operating member connected to the push member and located outside of the cavity, and a biasing member for biasing the push member and the operating member toward the movable die; when the movable die moved by the first actuator is assembled with the fixed die, so as to form the cavity, the operating member may be pushed by the movable die against a biasing force from the biasing member, so as to move the push member from the projected position to the retracted position. In this case, the push member can be moved between the projected position and the retracted position depending on whether the movable die moved by the first actuator pushes the operating member or not. This makes it possible to release the core from the fixed die without providing a separate actuator for driving the push member. Therefore, the machine can be made further simpler and smaller.
The core molding machine in accordance with this aspect of the present invention may further comprise a sand collection device for collecting the sand having dropped from the core box to an upper face of the blow head. In this case, the sand having dropped on the upper face of the blow head is collected by the sand collection device without directly returning into the blow head. Therefore, sand masses in which sand is assembled and solidified and the like contained in the sand having dropped on the upper face of the blow head, if any, are also collected by the sand collection device. This can prevent the sand masses from affecting the molding of the next core.
The sand collection device may have a conduit member for guiding the sand from the upper face of the blow head to the sand storage chamber and a fourth cleaning unit for removing and discharging the sand having dropped on the upper face of the blow head away from the upper face of the blow head to the conduit member. In this case, the sand having dropped on the upper face of the blow head is returned to the sand storage chamber when discharged to the conduit member by the fourth cleaning unit. Hence, the sand can be reused.
The conduit member may slope down from the upper face of the blow head to the sand storage chamber. This allows the sand to slide down the conduit member under gravity when returning from the upper face of the blow head to the sand storage chamber, thereby making it unnecessary to provide a separate transport device such as a conveyor. Therefore, the machine can be made simpler.
The conduit member may be provided with a filter member adapted to pass therethrough sand having a predetermined particle size or smaller. In this case, even when the sand returned from the blow head to the sand storage chamber contains a sand mass or the like greater than the predetermined particle size, the filter member can remove the sand mass.
The core molding method in accordance with another aspect of the present invention comprises a cavity formation step of assembling a pair of laterally separable dies with each other, so as to yield a core box having a cavity therewithin; a communication step of connecting a blow head to the core box, so as to communicate the cavity and the blow head to each other; a fluidization step of blowing an aeration air into a sand blow chamber in the blow head by an aeration air supply unit, so as to float and fluidize core sand within the sand blow chamber; and a filling step of blowing a compressed air into a sand storage chamber, communicating with the sand blow chamber, in the blow head by a compressed air supply unit, so as to blow the floated and fluidized core sand within the sand blow chamber upward from the blow head, thereby filling the cavity communicating with the blow head with the core sand.
In the core molding method in accordance with this aspect of the present invention, in a state where the core sand within the sand blow chamber is floated and fluidized by the aeration air supply unit, the compressed air supply unit blows the compressed air into the sand blow chamber, thereby feeding the core sand from within the sand blow chamber to the core box. Therefore, even when employing the under-blow type for blowing the core sand to the core box located on the upper side, the core box can favorably be filled with the core sand.
The core molding method in accordance with this aspect of the present invention may further comprise a separation step of driving a movable die as one of the pair of dies by a first actuator after the filling step, so as to separate the movable die from a fixed die as the other of the pair of dies, and a die rotation step of rotating the movable die after the separation step; the die rotation step including moving the movable die held by a movable die holding member away from the fixed die by the first actuator, so as to bring an abutment member attached to the movable die holding member through a rotary axis member into contact with an orientation change member located on an advancing path of the abutment member and the rotating the movable die with the aid of the rotary axis member and movable die holding member by changing an orientation of the abutment member along a surface of the orientation change member while further moving the movable die away from the fixed die by the first actuator in a state where the abutment member is in contact with the orientation change member. In this case, simply moving the movable die away from the fixed die by the first actuator can rotate the movable die separated from the fixed die. This makes it unnecessary to provide a separate actuator for rotating the movable die. Therefore, the machine can be made further simpler and smaller.
The core molding method in accordance with this aspect of the present invention may further comprise a release step of releasing a core from the movable die after the movable die holding the core is rotated such that the core is on the upper side after the die rotation step. In this case, the core released from the movable die can be kept held by the movable die. This can prevent the released core from dropping out of the movable die and make the released core easier to be handled by users.
The core molding method in accordance with this aspect of the present invention may further comprise a first cleaning step of driving a first cleaning unit together with the movable die by the first actuator such that the first cleaning unit slides while abutting against a blow head nozzle in the blow head, so as to clean the blow head nozzle, and a second cleaning step of driving a second cleaning unit together with the movable die by the first actuator such that the second cleaning unit slides while abutting against a fixed die nozzle in the fixed die, so as to clean the fixed die nozzle. In this case, simply moving the first and second cleaning units by the first actuator can clean the blow head nozzle and fixed die nozzle. This makes it unnecessary to provide separate actuators for moving the first and second cleaning units, respectively. Therefore, the machine can be made further simpler and smaller.
The core molding method in accordance with this aspect of the present invention may further comprise a third cleaning step of driving the movable die by the first actuator such that a third cleaning unit slides while abutting against a movable die nozzle in the movable die, so as to clean the movable die nozzle. In this case, simply moving the movable die by the first actuator can clean the movable die nozzle when the movable die comes closer to the third cleaning unit. This makes it unnecessary to provide a separate actuator for moving the third cleaning unit. Therefore, the machine can be made further simpler and smaller.
The core molding method in accordance with this aspect of the present invention may further comprise an opening and closing step of driving by the first actuator an on/off gate located between a supply port of the sand storage chamber and a sand tank for supplying the sand storage chamber with the core sand, so as to open and close the supply port; the opening and closing step may close the supply port when the movable die forms the cavity for forming the core together with the fixed die. In this case, simply driving the on/off gate by the first actuator can control the opening and closing of the supply port. This makes it unnecessary to provide a separate actuator for driving the on/off gate. Therefore, the machine can be made further simpler and smaller.
The core molding method in accordance with this aspect of the present invention may further comprise a die open step of releasing the core from the fixed die such that the core is held by the movable die when the core is molded within the cavity, formed by the movable and fixed dies, for forming the core and the movable die is moved away from the fixed die by the first actuator between the filling and die rotation steps. In this case, the core can be held by the movable die while being released from the fixed die. Therefore, the core can be taken out from the core box more easily.
The core molding method in accordance with this aspect of the present invention may further comprise a hollow part formation step of moving the core box and the blow head away from each other before all of the core sand filling the core box is solidified after the filling step, so as to discharge an unsolidified part of the core sand from the core box to an upper face of the blow head, thereby molding a hollow core having a hollow part formed in the core, and a sand collection step of removing from the upper face of the blow head the sand discharged thereto and collecting the removed sand by a sand collection device. In this case, the sand having dropped on the upper face of the blow head is collected by the sand collection device without directly returning into the blow head. Therefore, sand masses in which sand is assembled and solidified and the like contained in the sand having dropped on the upper face of the blow head, if any, are also collected by the sand collection device. This can prevent the sand masses from affecting the molding of the next core.
The sand collection step may supply the collected sand to the sand storage chamber. In this case, the sand having dropped on the upper face of the blow head can be reused.
Even when employing the under-blow type for blowing core sand into a core box located on the upper side in a core molding machine and core molding method, the present invention can favorably fill the core box with the core sand.
(a) and (b) of
(a) and (b) of
(a) and (b) of
(a) and (b) of
(a) and (b) of
(a) and (b) of
(a) and (b) of
(a) and (b) of
(a) and (b) of
(a) and (b) of
(a) and (b) of
(a) and (b) of
(a) of
(a) of
(a) of
(a) and (b) of
(a) and (b) of
(a) and (b) of
(a) and (b) of
(a) and (b) of
In the following, a core molding machine 1 in accordance with a first embodiment will be explained with reference to the drawings. As
As
The pair of dies constituting the core box 30 are a fixed die 32 and a movable die 33. The movable die 33 is driven to move horizontally closer to the fixed die 32, so as to form a cavity (molding space) 30a ((a) of
The blow head 2 has a sand blow chamber 4, which is connected to the core box 30 and guides the core sand 28 to the core box 30, and a sand storage chamber 5 communicating with the sand blow chamber 4. The sand filling device 31 has a compressed air supply unit 7 for supplying a compressed air for blowing the core sand 28 into the core box 30 and an aeration air supply unit 9 for supplying an aeration air for floating and fluidizing the core sand. 28 within the sand blow chamber 4 (see
The core molding machine 1 comprises frame members 34a, 34b, 34c, 34d erected on a base plate 29. The frame member 34a secures and holds the fixed die 32, which is one of the pair of dies. Specifically, the frame member 34a holds the fixed die 32 through a fixed die holding unit 35. The fixed die holding unit 35 holds the fixed die 32 by a gripper 35b. An attachment member 55a of the sand tank 55 is also secured to the base plate 29.
The core molding machine 1 comprises a first actuator 36 and second actuators 37. The first actuator 36 linearly drives the movable die 33, which is the other of the pair of dies, so as to move it horizontally closer to or away from the fixed die 32. By the direction of moving closer to or away from the fixed die 32 is meant the horizontal direction in this embodiment. The second actuators 37 drive the blow head 2 linearly, so as to move it vertically closer to or away from the core box 30. While a pair of second actuators 37 are provided so as to hold the blow head 2 therebetween as seen from the front face in this embodiment, this is not restrictive.
Each of the first and second actuators 36, 37 is a uniaxial actuator. An example of the first actuator 36 is an air-on-oil (air-hydro) cylinder. By the air-on-oil cylinder is meant a cylinder which uses an air pressure converted into an oil pressure and combines air and oil pressures. The air-on-oil cylinder does not use a dedicated hydraulic unit employing a hydraulic pump, but a compressed air source alone. The air-on-oil cylinder is advantageous over air cylinders in its higher positional accuracy, easier controllability of migration speed, and the like. Though the first actuator 36 is not limited to the air-on-oil cylinder, the latter is suitable when the driving force, accuracy in driving position, and cost are concerned. The second actuators 37 are air cylinders, for example, but are not limited thereto. The second actuators 37 may also be air-on-oil cylinders, for example.
The first actuator 36 rotates the movable die 33 by 90° after separating it from the fixed die 32 (see the states 1-7 to 1-8 in (a) and (b) of
The first actuator 36 moves a rotary axis member 39, which is provided in a movable die holding member 38 for holding the movable die 33, closer to or away from the fixed die 32 (see (b) of
The frame member 34c is located between the first actuator 36 and fixed die 32. A leading end part of the frame member 34c is provided with an orientation change member 42. The orientation change member 42 is located lower than the rotary axis member 39 and has a curved surface adapted to abut against the abutment member 41 and change the orientation of the movable die 33, while the abutment member 41 is a plate-like member, for example. An example of the orientation change member 42 is a roller member which is free to rotate. In this embodiment, the rotary axis member 39, abutment member 41, and orientation change member 42 constitute a rotary drive unit for rotating the movable die 33.
When the rotary axis member 39 is further moved away from the fixed die 32 from the state where the abutment member 41 abuts against the orientation change member 42, the abutment member 41 changes its orientation along the curved surface of the orientation change member 42, whereby the movable die 33 is rotated by 90° (see the state 1-8 in (a) of
In this core molding machine 1, the first actuator 36 moves the movable die 33 closer to or away from the fixed die 32 in order to form the cavity 30a. When the first actuator 36 moves the movable die 33 away from the fixed die 32, the abutment member 41, while changing its orientation along the surface of the orientation change member 42, rotates the movable die 33 by 90° with the aid of the rotary axis member 39 and movable die holding member 38. This makes it unnecessary to provide a separate actuator for rotating the movable die 33 by 90°, whereby the machine can be made simpler and smaller.
Here, the abutment member 41, rotary axis member 39, and movable die holding member 38 are configured such that the movable die 33 confronts the fixed die 32 (i.e., opposes a vertical plane) in the state where the abutment member 41 is not in contact with the orientation change member 42 or at a timing when the abutment member 41 abuts against the orientation, change member 42 as illustrated in (a) and (b) of
Specifically, as (a) of
The movable die 33 is provided with a positioning abutment member 65 for making the movable die 33 confront the fixed die 32 in the state where the biasing force in the R1 direction is generated by the spring member 44 (see (b) of
After the movable die 33 is rotated by 90° as mentioned above, a core 43 held within the movable die 33 is released therefrom (see the state 1-9 illustrated in (a) of
The movable die 33 is provided with a slide member 45 which is moved closer to or away from the movable die 33 when the movable die 33 having rotated by 90° is moved closer to or away from the fixed die 32 by the first actuator 36.
Provided on the frame member 34 side is a guide member 46 having a slide surface 46a, which abuts against the slide member 45 when the movable die 33 having rotated by 90° is moved away from the fixed die 32, for changing the position in the height direction of the slide member 45 (see (b) of
The slide member 45, when its position in the height direction is changed by the guide member 46, pushes the core 43 held by the movable die 33 away from the movable die 33 ((a) of
Specifically, as
A pair of guide members 45e are provided on the other surface side (the lower face side in the state of
The push member 47 has a plate unit 47a adapted to abut against the abutment units 45d of the slide member 45 and push units 47b disposed on one surface side (the upper face side in the state of
In this core molding machine 1, the first actuator 36 moves the movable die 33 closer to or away from the fixed die 32 in order to form a cavity. When the movable die 33 having been rotated is moved away from the fixed die 32 by the first actuator 36, the core held by the movable die 33 is released therefrom by the first release unit. This makes it unnecessary to provide a separate actuator for releasing the core 43 from the movable die 33, whereby the machine can be made simpler and smaller.
As
A base end part of the holding member 57 is attached to the movable frame 40. The movable frame 40 is moved by the first actuator 36 while holding the movable die holding member 38 rotatably. The movable frame 40 is attached to a rod 36a of the first actuator 36 and is moved closer to or away from the fixed die 32. The frame member 34a is provided with guide members 40a for guiding the movable frame 40. The movable frame 40 is horizontally moved by the guide members 40a, while keeping its orientation. The guide members 40a are disposed at two locations on the lower left and upper right when seen from the right side face as illustrated in (a) of
The leading end of the frame member 34d is provided with a third cleaning unit 53 for cleaning a movable die nozzle 49. When the movable die 33 moved by the first actuator 36 comes closer to the third cleaning unit 53, the latter cleans the movable die nozzle 49 by sliding while abutting thereagainst. The first, second, and third cleaning units 51, 52, 53, examples of which include plate-like rubber members (rubber plates), clean their corresponding nozzles 50, 48, 49 by coming into slidable contact therewith.
Specifically, as (a) and (b) of
Further, when the first actuator 36 shifts the movable die 33 from the state 1-6 to 1-7 as illustrated in (b) of
In this core molding machine 1, the first actuator 36 moves the movable die 33 closer to or away from the fixed die 32 in order to form the cavity 30a. When the first actuator 36 moves the movable die 33 away from the fixed die 32, the first to third cleaning units 51 to 53 clean the blow head nozzle 50, fixed die nozzle 48, and movable die nozzle 49. This makes it unnecessary to provide separate actuators for cleaning the nozzles 50, 48, 49, whereby the machine can be made simpler and smaller.
The sand storage chamber 5 is provided with an on/off gate 18 for opening and closing a supply port 56 for supplying the core sand 28 from the sand tank 55 to the sand storage chamber 5 (blow head 2). The on/off gate 18 is driven when the first actuator 36 drives the movable die 33. The on/off gate 18 closes the supply port 56 when the movable die 33 forms the cavity 30a together with the fixed die 32 ((a) and (b) of
Specifically, the on/off gate 18 is provided with a communication hole 18a for communicating the supply port 56 to the sand tank 55. When the communication hole 18a is positioned on the supply port 56 and communicates therewith as illustrated in (a) of
The on/off gate 18 is provided with the biasing member 68 as illustrated, in
The holding member 57 holding the first and second cleaning units 51, 52 is provided with a push member 58 formed so as to extend to the lower part. The holding member 57 and push member 58 are moved together with the movable die 33 by the first actuator 36.
When the first actuator 36 shifts the movable die 33 from the state 1-1 to 1-2, the push member 58 slides the on/off gate 18 in the direction of X2 as illustrated in (a) and (b) of
The supply port is kept closed by the on/off gate 18 from the state 1-2 to 1-6 as illustrated in (b) of
In this core molding machine 1, the first actuator 36 functions not only to move the movable die 33 closer to or away from the fixed die 32, but also to slide the on/off gate 18 so as to open the support port 56 of the sand storage chamber 5, thereby communicating it to the sand tank 55, and close the supply port 56 with the on/off gate 18. This makes it unnecessary to provide a separate actuator for sliding the on/off gate 18, whereby the machine can be made simpler and smaller.
A flexible hose 59 is disposed between the sand tank 55 and the supply port 56 of the sand storage chamber 5. The flexible hose 59 makes it possible to secure the sand tank 55 also when the blow head 2 is raised by the second actuators 37 as illustrated in (b) of
After the core is molded in the core-forming cavity 30a formed by moving the movable die 33 toward the fixed die 32, the first actuator 36 moves the movable die 33 away from the fixed die 32, so as to release the core 43 from the fixed die 32 and let the movable die 33 hold the core 43 (see (a) and (b) of
The fixed die 32 is provided with a push member 61 for pushing the core 43 molded in the cavity 30a away from the fixed die 32 when the movable die 33 is moved away from the fixed die 32. The fixed die 32 is also provided with a biasing member 62 for biasing the push member 61 for biasing the push member 61 in such a direction as to push out the core 43 ((a) of
When the fixed die 32 and movable die 33 are assembled with each other, so as to form the cavity 30a, the member 63 is pushed by the movable die 33 moved by the first actuator 36, so as to move the push member 61 (see (b) of
Filling and molding with sand as illustrated in (b) of
The push member 61 has a plate unit 61a and push units 61b disposed on one surface side of the plate unit 61a (see
The biasing member 62 has spring members 62a each having one end attached to the fixed die holding unit 35, a plate member 62b, attached to the other end of the spring member 62a, for transmitting the biasing force, and abutment units 62c formed on one surface (the right surface in (b) of
In this core molding machine 1, the first actuator 36 moves the movable die 33 closer to or away from the fixed die 32 in order to form the cavity 30a. When the first actuator 36 moves the movable die 33 away from the fixed die 32, the second release unit releases the core 43 from the fixed die 32. This makes it unnecessary to provide a separate actuator for releasing the core 43 from the fixed die 32, whereby the machine can be made simpler and smaller.
A specific structural example of the sand filling device 31 constituting the core molding machine 1 will now be explained with reference to
As (a) of
The blow head 2 has the sand blow chamber 4 and sand storage chamber 5, adjacent to each other, separated by a partition 3. The upper end of the sand blow chamber 4 is provided with a plate 4a coming into close contact with the core box 30. The plate 4a is formed with sand blow holes 4b for blowing the core sand from within the sand blow chamber 4 into the cavity 30a of the core box 30. The core box 30 may be provided with vent holes for discharging the blown-in air for filling with sand. When no vent holes are provided, the air may be discharged through a minute gap between the pair of dies.
As (a) of
An opening 3a (see (b) of
A compressed air supply unit 7 for supplying a compressed air into the sand storage chamber 5 is provided in a lower part of the slope 5a in the sand storage chamber 5 (see (a) of
Disposed in an upper part of a side wall of the sand blow chamber 4 are aeration air supply units 9 for supplying into the sand blow chamber 4 an aeration air for floating and fluidizing the core sand therewithin. A sintered body 9a of bronze is disposed at the leading end of each aeration air supply unit 9. The aeration air supply unit 9 is connected to (communicates with) the sand blow chamber 4 through the sintered body 9a.
Here, the aeration air supply unit 9 is attached to a plate-like member 4d. The plate-like member 4d is detachably attached to the sand blow chamber 4 through undepicted fastening means. The plate-like member 4d may be attached upside down so as to change the position of the aeration air supply unit 9. Though three aeration air supply units 9 are provided here as illustrated in (b) of
An air pipe 10 communicates with the aeration air supply units 9. The air pipe 10 is provided with an on/off valve 11. The on/off valve 11 communicates with a compressed air source which is not depicted.
A branch air pipe 12 is disposed in the middle of the air pipe 10. The branch air pipe 12 is provided with an exhaust valve 13 for evacuating the compressed air remaining within the sand blow chamber 4. The exhaust valve 13 is connected to the sand blow chamber 4 through the pipes 10, 12.
A pressure sensor 14 for measuring the pressure within the sand blow chamber 4 is disposed in an upper part of a side wall orthogonal to the side wall provided with the aeration air supply unit 9. A pressure sensor 15 for measuring the pressure within the sand storage chamber 5 is mounted to an upper part of a side wall in the sand storage chamber 5.
A plank 5c is attached to the upper end of the sand storage chamber 5. A hole to become the supply port 56 penetrates through the ceiling board 5b and plank 5c of the sand storage chamber 5. A flange 16 provided with a hole 16a for supplying sand is disposed above the plank 5c. The flexible hose 59 serving as a sand supply pipe communicating with the hole 16a is attached to the upper end of the flange 16. The flexible hose 59 communicates with the sand tank 55.
The on/off gate 18 provided with the communication hole 18a is disposed between the plank 5c and flange 16. As mentioned above, the on/off gate 18 slides as the movable die 33 is driven by the first actuator 36, so as to open and close the supply port 56. When the blow head 2 is moved down by the second actuators 37, the plank 5c, on/off gate 18, and flange 16 also move down.
Operations of thus constructed sand filling device 31 will now be explained. The following will provide a general explanation including a case where the device is provided in the core molding machine 1. The assembled core box 30 is arranged at a predetermined position. Subsequently, the on/off gate 18 closes the supply port 56. Then, the blow head 2 is moved up, so as to be placed in the state of
Next, the on/off valve 11 is opened, and the aeration air supply unit 9 is operated. The sintered body 9a of the aeration air supply unit 9 spouts an air (aeration air), thereby floating and fluidizing the core sand within the sand blow chamber 4. After a lapse of a predetermined time, the on/off valve 8 is opened, and the compressed air supply unit 7 is operated. The sintered body 7a of the compressed air supply unit 7 spouts the compressed air, thereby feeding the core sand from within the sand storage chamber 5 to the sand blow chamber 4. The core sand is blown from within the sand blow chamber 4 into the cavity 30a of the core box 30 through the sand blow nozzles 6 and sand blow holes 4b. At this time, the compressed air blown into the cavity 30a together with the core sand is discharged through the vent holes or minute gap as mentioned above. A step of filling the cavity 30a with the floated and fluidized core sand from within the sand blow chamber 4 by the compressed air supply unit 7 may be performed after or in a manner at least partly overlapping with the step of floating and fluidizing the core sand within the sand blow chamber 4 by the aeration air supply unit 9.
After a lapse of a predetermined time from starting operating the compressed air supply unit 7, the on/off valves 11, 8 are closed, and the aeration air supply unit 9 and compressed air supply unit 7 are stopped from operating. At this time, as mentioned above, the exhaust through the vent holes or minute gap generates a pressure difference between the sand blow chamber 4 and sand storage chamber 5. The pressure within the sand blow chamber 4 is lower than that within the sand storage chamber 5. This pressure difference acts to move the core sand from within the sand blow chamber 4 and sand storage chamber 5 into the cavity 30a of the core box 30. The core sand filling the cavity 30a does not fall down.
Next, the exhaust valve 13 is opened, so as to evacuate the compressed air remaining within the sand blow chamber 4. That is, the compressed air remaining within the sand blow chamber 4 enters the aeration air supply unit 9 through the sintered body 9a and travels through the air pipe 10 and branch air pipe 12, so as to exit from the exhaust valve 13. At this time, such an airflow occurs that the compressed air remaining within the blow chamber 4 and sand storage chamber 5 is guided to the aeration air supply port 9 through the sintered body 9a, along which the core sand migrates from within the sand storage chamber 5 into the sand blow chamber 4. The sand blow chamber 4 is filled with the core sand.
When the pressure sensors 14, 15 detect that the gauge pressure within the blow head 2 is zero (the pressure within the blow head 2 is substantially the same as the atmospheric pressure), the blow head 2 is moved down, so as to be separated from the core box 30. Subsequently, the exhaust valve 13 is closed.
The core box 30 is disassembled, and the core is taken out therefrom. Then, the on/off gate 18 is opened. The core sand is supplied from within the sand tank 55 into the sand storage chamber 5 through the flexible hose 59, hole 16a, communication hole 18a, and supply port 56.
Though the compressed air supply unit 7 communicates with the sand storage chamber 5 in the above-mentioned sand filling device 31, this is not restrictive. It may communicate with the sand blow chamber 4, for example. In this case, a sand feed air supply unit for supplying a sand feed air for supplying the core sand from within the sand storage chamber 5 into the sand blow chamber 4 may be provided. Each of the compressed air supply unit and aeration air supply unit may be provided in addition.
A sand filling device 71 illustrated in
A slope 4c forming a part of the bottom face of the sand blow chamber 4 in the sand filling device 71 is provided with second aeration air supply units 21 for supplying the sand blow chamber 4 with art aeration air for floating and fluidizing the core sand therewithin. The second aeration air supply units 21 communicate with the sand blow chamber 4. The leading end of each second aeration air supply unit 21 is provided with a sintered body 21a of bronze. Though the slope 4c forming a part of the bottom face of the sand blow chamber 4 is provided with two second aeration air supply units 21 here as illustrated in (b) of
The sand filling device 71 has the same structure as with the above-mentioned sand filling device 31 except for the differences explained here. The constituents identical to those of the sand filling device 31 will be referred to with the same signs while omitting their detailed explanations.
Operations of thus constructed sand filling device 71 will now be explained. The following will provide a general explanation including a case where the device is provided in the core molding machine 1. The assembled core box 30 is arranged at a predetermined position. Subsequently, the on/off gate 18 closes the supply port 56. Then, the blow head 2 is moved up, so as to be placed in the state of
Next, the on/off valves 11, 22 are opened, and the aeration air supply unit 9 and second aeration air supply unit 21 are operated. The sintered body 9a of the aeration air supply unit 9 and the sintered body 21a of the second aeration air supply unit 21 spout an air (aeration air), thereby floating and fluidizing the core sand within the sand blow chamber 4. After a lapse of a predetermined time, the on/off valve 8 is opened, and the compressed air supply unit 7 and second compressed air supply unit 19 are operated. The sintered body 7a of the compressed air supply unit 7 and the sintered body 19a of the second compressed air supply unit 19 spout the compressed air, thereby feeding the core sand from within the sand storage chamber 5 to the sand blow chamber 4. The core sand is blown from within the sand blow chamber 4 into the cavity 30a of the core box 30 through the sand blow nozzles 6 and sand blow holes 4b. At this time, the compressed air blown into the cavity 30a together with the core sand is discharged through the vent holes or minute gap as mentioned above.
After a lapse of a predetermined time from starting operating the compressed air supply unit 7 and second compressed air supply unit 19, the on/off valves 11, 22, 8 are closed, and the aeration air supply unit 9, second aeration air supply unit 21, compressed air supply unit 7, and second compressed air supply unit 19 are stopped from operating. At this time, as mentioned above, the exhaust through the vent holes or minute gap generates a pressure difference between the sand blow chamber 4 and sand storage chamber 5. The pressure within the sand blow chamber 4 is lower than that within, the sand storage chamber 5. This pressure difference acts to move the core sand from within the sand blow chamber 4 and sand storage chamber 5 into the cavity 30a of the core box 30. The core sand filling the cavity 30a does not fall down.
Next, the exhaust valve 13 is opened, so as to evacuate the compressed air remaining within the sand blow chamber 4. That is, the compressed air remaining within the sand blow chamber 4 enters the aeration air supply unit 9 through the sintered body 9a and travels through the air pipe 10 and branch air pipe 12, so as to exit from the exhaust valve 13. At this time, such an airflow occurs that the compressed air remaining within the blow chamber 4 and sand storage chamber 5 is guided to the aeration air supply port 9 through the sintered body 9a, along which the core sand migrates from within the sand storage chamber 5 into the sand blow chamber 4. The sand blow chamber 4 is filled with the core sand.
When the pressure sensors 14, 15 detect that the gauge pressure within the blow head 2 is zero (the pressure within the blow head 2 is substantially the same as the atmospheric pressure), the blow head 2 is moved down, so as to be separated from the core box 30. Subsequently, the exhaust valve 13 is closed.
The core box 30 is disassembled, and the core is taken out therefrom. Then, the on/off gate 18 is opened. The core sand is supplied from within the sand tank 55 into the core storage chamber 5 through the flexible hose 59, hole 16a, communication hole 18a, and supply port 56.
The aeration air supply unit 9 and compressed air supply unit 7 may have the same operation pressure in the sand filling devices 31, 71. Having the same pressure is advantageous in that the amount of air consumption can be reduced. The operating pressure of the compressed air supply unit 7 may be higher than that of the aeration air supply unit 9. This is advantageous in that the pressure within the sand storage chamber 5 becomes higher than that within the sand blow chamber 4, thus generating a greater pressure difference, whereby the core sand migrates easily from the sand storage chamber 5 to the sand blow chamber 4.
In the sand filling devices 31, 71, the blow head 2 partitioned into the sand blow chamber 4 and sand storage chamber 5 communicating with each other is arranged under the core box 30. This can reduce the size of the machine in its height direction as compared with the top-blow type core molding machine, thereby making the machine smaller.
Each of the sand filling devices 31, 71 comprises two air supply means, i.e., the compressed air supply unit 7 and aeration air supply unit 9, and causes them to spout airs, for blowing the core sand for filling, whereby the filling property of core sand can further be improved.
A part of the bottom face of the sand storage chamber 5 is formed into the slope 5a, and the compressed air supply unit 7 is mounted thereto. Its operation and effect will now be explained. The core sand supplied into the sand storage chamber 5 typically attains a conical form therein because of an angle of repose of sand. In this case, the sand layer is lower in a part where the partition 3 and core sand are in contact with each other, so that, when the core sand is moved from the sand storage chamber 5 to the sand blow chamber 4, the core sand and air may not mix well with each other, whereby only the air may pass through the opening 3a, thus yielding so-called air blow-by. In the sand filling devices 31, 71, by contrast, the slope 5a forming a part of the bottom face of the sand storage chamber 5 is provided with the compressed air supply unit 7, so as to supply the compressed air as mentioned above, whereby a conical pile of core sand is collapsed, and the core sand is stirred. This makes the core sand flat within the sand storage chamber 5, thereby raising the height of the sand layer in the part where the partition 3 and core sand are in contact with each other. This can prevent the above-mentioned air blow-by from occurring and increase the amount of core sand migrating from the sand storage chamber 5 to the sand blow chamber 4, i.e., the amount of sand effectively used.
In the sand filling devices 31, 71, the exhaust valve 13 communicates with the sand blow chamber 4 through the air pipe connected to the aeration air supply unit 9. Since the evacuated air enters the aeration air supply unit 9 through the sintered body 9a, the aeration air supply unit 9 also functions as exhaust means. Even when clogged with sand at the time of exhaust, the sintered body 9a subsequently spouts the compressed air and thus can be relieved from being clogged with sand.
Since the sand filling device 71 comprises the second compressed air supply unit 19 in addition to the compressed air supply unit 7, the conical pile of core sand is collapsed within the sand storage chamber 5, whereby the action of stirring the core sand is further promoted. This is advantageous in that the core sand migrates from the sand storage chamber 5 to the sand blow chamber 4 more smoothly.
The sand filling device 71 comprises the second aeration air supply unit 21 in addition to the aeration air supply unit 9 and thus is advantageous in that the action of floating and fluidizing the core sand within the sand blow chamber 4 is further promoted.
Each of the sand filling devices 31, 71 is equipped with the pressure sensors 14, 15 for measuring the pressures within the sand blow chamber 4 and sand storage chamber 5 and thus can easily measure the pressure difference between the sand blow chamber 4 and sand storage chamber 5.
The operation and effect of projecting the sand blow nozzles 6 from the lower end of the plate 4a will now be explained in the sand filling devices 31, 71. After the core sand is blown from within the sand blow chamber 4 into the cavity 30a, the aeration air supply unit 9 and compressed air supply unit 7 are stopped from operating. The core sand drops from within the sand blow chamber 4 under gravity, thereby forming an air layer (gap) K between the upper face of core sand within the sand blow chamber 4 and the lower face of the plate 4a (see
In the state illustrated in
In the sand filling devices 31, 71, the inner face of the sand blow hole 4b and the outer face of the sand blow nozzle 6 are formed with female and male threads, respectively, which are brought into threadable engagement with each other, so as to project the sand blow nozzle 6 from the lower end of the plate 4a. This is not restrictive; they may be firmly secured to each other by welding or the like. Though cylindrical pipes are used as the sand blow nozzles 6, they are not limited thereto but may be elliptical, for example.
Though each of the sand filling devices 31, 71 operates the compressed air supply unit 7 after a lapse of a predetermined time from starting the aeration air supply unit 9, this is not restrictive. The compressed air supply unit 7 may be operated when the pressure sensor 14 detects a predetermined pressure value within the sand blow chamber 4 after starting the aeration air supply unit 9. The predetermined pressure value within the sand blow chamber 4 in this case is required to be lower than the operating pressure of the compressed air supply unit 7 and more preferably falls within the range of 0.01 to 0.2 MPa.
Timings for starting and stopping the aeration air supply unit 9 and second aeration air supply unit 21 may be either simultaneous or not in the sand filling device 71. Timings for starting and stopping the compressed air supply unit 7 and second compressed air supply unit 19 may also be either simultaneous or not. For shifting the respective timings for starting or stopping the compressed air supply unit 7 and second compressed air supply unit 19, dedicated on/off valves may be provided so as to communicate with the compressed air supply unit 7 and second compressed air supply unit 19, respectively.
Though the blow head 2 moves up and down with respect to the core box 30 arranged at a predetermined position in the sand filling devices 31, 71, this is not restrictive; the core box 30 may be moved up and down with respect to the blow head 2 arranged at a predetermined position.
While the sand filling devices 31, 71 illustrate an example using a shell core molding machine in which heated dies are filled with resin-coated sand blown thereinto so as to mold a shell core, this is not restrictive; the present invention is also applicable to a cold box method which is a normal-temperature gas-hardening method.
Though each of the sand filling devices 31, 71 stops the aeration air supply unit 9 and compressed air supply unit 7 from operating at the same time, this is not restrictive; the aeration air supply unit 9 may be stopped before the compressed air supply unit 7.
The operating pressures of the aeration air supply unit 9, second aeration air supply unit 21, compressed air supply unit 7, and second compressed air supply unit 19 in the sand filling devices 31, 71 are not limited to specific pressure values. Preferably, each of the aeration air supply unit 9, second aeration air supply unit 21, compressed air supply unit 7, and second compressed air supply unit 19 has an operating pressure of 0.1 to 0.5 MPa.
A core molding method using thus constructed core molding machine 1 will now be explained. This method molds a core by performing steps corresponding to the states 1-1 to 1-10 in sequence. Though the following explanation assumes that there is the sand filling device 31, the same holds in the case using the sand filling device 71 except for the points mentioned above.
To begin with, the state 1-1 illustrated in (a) of
The state 1-3 illustrated in (a) of
The state 1-4 illustrated in (b) of
The state 1-5 illustrated in (a) of
The state 1-6 illustrated in (b) of
The state 1-7 illustrated in (a) of
The state 1-8 illustrated in (b) of
The state 1-9 illustrated in (a) of
The state 1-10 illustrated in (b) of
In the core molding method using the core molding machine 1, as mentioned above, the first to third cleaning units 51, 52, 53 clean the nozzles 50, 48, 49 during when the state shifts from 1-1 to 1-10 and then returns to 1-1 again.
In the core molding machine 1 and the core molding method using the same, as mentioned above, the blow head 2 has the sand blow chamber 4 and sand storage chamber 5, the compressed air supply unit 7 supplies the compressed air, and the aeration air supply unit 9 supplies the aeration air to fill the cavity 30a of the core box 30 with the sand, whereby the core sand filling property in the under-blow type is improved. In this machine 1 and method, the blow head 2 is arranged under the core box 30, whereby the machine is made smaller. Hence, the core sand filling property can be improved while making the machine smaller.
In the machine 1 and method, as mentioned above, a common actuator (first actuator 36) can drive the movable die 33 (so as to open it, close it, and so forth), rotate the movable die 33, release the core from the movable die 33, clean the nozzles 50, 48, 49, drive the on/off gate 18, and release the core from the fixed die 32 at the time of opening the dies. This simplifies the machine. It also makes the machine smaller. In this core molding machine 1, constituent components can be driven by the first and second actuators 36, 37 alone.
A core molding machine 1A in accordance with the second embodiment will now be explained with reference to
The sand collection device 100 has a third actuator 110 secured to a base plate 29 through an undepicted frame member and a conduit member 120 bridging the blow head 2 and on/off gate 18. The third actuator 110 is a uniaxial actuator. An example of the third actuator 110 is an air-on-oil (air-hydro) cylinder. A fourth cleaning unit 112 is disposed at the leading end of the third actuator 110.
The third actuator 110 horizontally drives the fourth cleaning unit 112. This moves the cleaning unit 112 closer to or away from the blow head 2 (blow head nozzle 50). The fourth cleaning unit 112, an example of which is a plate-like rubber member (rubber plate), cleans the nozzle 50 by coming into slidable contact therewith.
The conduit member 120 is a ramp (chute) sloping down from the upper end of the blow head nozzle 50 (the upper end of the sand blow chamber 4) to the on/off gate 18. Therefore, the sand discharged from the upper end of the blow head nozzle 50 to the conduit member 120 reaches the on/off gate 18 through the conduit member 120. When the on/off gate 18 is open, the sand having reached the on/off gate 18 is supplied to the sand storage chamber 5 through the communication hole 18a and supply port 56.
Disposed in a middle part of the conduit member 120 is a filter member 122 adapted to pass therethrough sand having a predetermined particle size or smaller. The filter member 122 may be constituted by a mesh sieve, for example. The mesh size of the filter member 122 may be set such as to prevent a sand mass in which sand is assembled and solidified and impurities and the like having a size not smaller than that of the sand mass from passing through the filter member 122 while allowing the sand itself to pass therethrough.
A method of manufacturing the core 43 by using the core molding machine 1A will now be explained. To begin with, the state 2-1 illustrated in
Subsequently, as illustrated in
Then, as illustrated in
Next, as illustrated in
Subsequently, as illustrated in
In the core molding machine 1A in accordance with the second embodiment, which is of the under-blow type as with the core molding machine 1 in accordance with the first embodiment, the sand blow chamber 4 is always filled with the core sand 28 when filling the cavity 30a with the core sand 28. That is, the sand blow chamber 4 is filled with the core sand 28 up to the leading end of the blow head nozzle 50 also when moving the blow head 2 away from the core box 30 in the state 2-5. Therefore, the sand 130 dropping to the upper face of the blow head 2 does not enter the sand blow chamber 4 through the blow head nozzle 50. Since the sand 130 is discharged to the conduit member 120 by the fourth cleaning unit 112 in the subsequent step, sand masses, impurities, and the like contained in the sand 130, if any, can be prevented from adversely affecting the molding of the next core. That is, extremely excellent effects can be exhibited in molding the hollow core when utilizing the core molding machine 1A in accordance with the second embodiment, in which the blow head 2 has the sand blow chamber 4 and sand storage chamber 5, employing the under-blow type.
Then, as illustrated in
Next, as illustrated in
Subsequently, as illustrated in
Subsequently, as illustrated in
The foregoing second embodiment is equipped with the sand collection device 100 for collecting the sand 130 having dropped from the core box 30 to the upper face of the blow head 2. Therefore, the sand 130 having dropped on the upper face of the blow head 2 is collected by the sand collection device 100 without directly returning into the blow head 2. Hence, sand masses in which sand is assembled and solidified and the like contained in the sand 130 having dropped on the upper face of the blow head 2, if any, are collected by the sand collection device 100. This can prevent the sand masses from affecting the molding of the next core.
In the foregoing second embodiment, the sand collection device 100 has the conduit member 120 for guiding the sand from the upper face of the blow head 2 to the sand storage chamber 5 and the fourth cleaning unit 112 for removing the sand 130 having dropped on the upper face of the blow head 5 away therefrom to the conduit member 120. Therefore, the sand 130 having dropped on the upper face of the blow head 5 and then discharged to the conduit member 120 by the fourth cleaning unit 112, if any, is returned to the sand storage chamber 5. Hence, the sand 130 can be reused.
In the foregoing second embodiment, the conduit member 120 slopes down from the upper face of the blow head 2 to the sand storage chamber 5. This allows the sand 130 to slide down through the conduit member 120 under gravity when returning from the upper face of the blow head 2 to the sand storage chamber 5, thereby making it unnecessary to provide a separate transport device such as a conveyor. Therefore, the core molding machine 1A can be made simpler.
In the foregoing second embodiment, the conduit member 120 is provided with the filter member 122 adapted to pass therethrough sand having a predetermined particle size or smaller. Therefore, sand masses and the like contained in the sand 130 returned from the blow head 2 to the sand storage chamber 5, if any, can be removed by the filter member 122.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2012-117196 | May 2012 | JP | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/JP2013/052930 | 2/7/2013 | WO | 00 |
| Publishing Document | Publishing Date | Country | Kind |
|---|---|---|---|
| WO2013/175813 | 11/28/2013 | WO | A |
| Number | Name | Date | Kind |
|---|---|---|---|
| 20020157800 | Kaneto | Oct 2002 | A1 |
| Number | Date | Country |
|---|---|---|
| 2506375 | Aug 2002 | CN |
| 2701552 | May 2005 | CN |
| 1968771 | May 2007 | CN |
| 201249253 | Jun 2009 | CN |
| 101862816 | Oct 2010 | CN |
| 101954459 | Jan 2011 | CN |
| 103492104 | Jan 2014 | CN |
| S31-004119 | Mar 1956 | JP |
| S31-6413 | Jul 1956 | JP |
| S47-13179 | Apr 1972 | JP |
| S47-41368 | Dec 1972 | JP |
| S56-84155 | Jul 1981 | JP |
| S59-041821 | Oct 1984 | JP |
| S60-113146 | Jul 1985 | JP |
| S61-202747 | Sep 1986 | JP |
| S63-202747 | Aug 1988 | JP |
| H05-305386 | Nov 1993 | JP |
| H10-166106 | Jun 1998 | JP |
| H10-216902 | Aug 1998 | JP |
| 2001-198653 | Jul 2001 | JP |
| 2008-213036 | Sep 2008 | JP |
| 2008-264867 | Nov 2008 | JP |
| 2009-183984 | Aug 2009 | JP |
| WO 2008120559 | Oct 2008 | WO |
| WO-2012165056 | Dec 2012 | WO |
| WO-2012165181 | Dec 2012 | WO |
| Entry |
|---|
| U.S. Appl. No. 14/123,329, Sintokogio Ltd. |
| U.S. Appl. No. 14/402,753, Sintokogio Ltd. |
| Number | Date | Country | |
|---|---|---|---|
| 20150144283 A1 | May 2015 | US |
