Claims
- 1. A curl-resistant, cross-sectionally symmetrical, laminated multilayer film substrate for use in the production of banknotes and security papers comprising:(a) an unprinted, imbalanced biaxially oriented first layer having inner and outer sides, comprising at least about 50 weight percent of a high density polyethylene having a density of at least about 0.94, said first layer being oriented in at least a first direction to a degree which is at least three times less than the degree of orientation present in a second direction substantially normal to the first direction; (b) a balanced biaxially oriented second layer having inner and outer sides and a tensile strength of greater than about 18,000 lb./in2, wherein said second layer comprises print features on at least one outer side, said second layer being oriented in at least a first direction at an orientation ratio of at least 4:1 and oriented in a second direction substantially normal to said first direction at an orientation ratio of at least 6:1; (c) an unprinted, imbalanced biaxially oriented third layer, wherein the ratio of initiated tear resistances is greater than about 10:1, having inner and outer sides, comprising at least about 50 weight percent of a high density polyethylene having a density of at least about 0.94, said third layer being oriented in at least a first direction to a degree which is at least three times less than the degree of orientation present in a second direction substantially normal to the first direction; and (d) a laminating adhesive resin disposed between the inner sides of (a) and (c), said second layer being laminated to said first and third layers so that the first direction of orientation of said third layer is substantially aligned with the first direction of orientation of said first layer and wherein (a) further comprises a coextruded propylene copolymer skin on its inner side.
- 2. The film substrate of claim 1 wherein said second layer comprises polypropylene and/or polyester.
- 3. The film substrate of claim 1, having a 45° gloss measurement less than about 85%.
- 4. The film substrate of claim 1 wherein (a) is surface embossed.
- 5. The film substrate of claim 1 wherein (a) and (c) are surface embossed.
- 6. The film substrate of claim 1 wherein (a) has diagonal and/or unidirectional microperforations.
- 7. The film substrate of claim 6 wherein said microperforations are in the range of from about 50 to about 300 dots per inch.
- 8. The film substrate of claim 1 wherein (a) and (c) have diagonal and/or unidirectional microperforations.
- 9. The film substrate of claim 1 wherein both (a) and (c) further comprise a copolymer polypropylene skin on at least one side thereof.
- 10. The film substrate of claim 1 wherein (d) comprises a solventless adhesive.
- 11. The film substrate of claim 10 wherein (d) comprises polyurethane.
- 12. The film substrate of claim 1 wherein (d) comprises a component selected from the group consisting of low density polyethylene (LDPE) and linear low density polyethylene (LLDPE).
- 13. The film substrate of claim 1 further comprising (e) a security device between (a) and (c).
- 14. The film substrate of claim 11 wherein said security device is selected from the group consisting of optically variable devices (OVDs), magnetic devices, electronic devices, and rare earth element-containing devices.
- 15. The film substrate of claim 1 further comprising (e) a security device printed on layer (b) prior to laminating with laminating adhesive resin (d).
- 16. The film substrate of claim 9 wherein said copolymer polypropylene skins on said outer sides are externally coated with an opacifying coating.
- 17. The film substrate of claim 13 further comprising a clear window through the film substrate.
- 18. The film substrate of claim 1 in the form of a bank note.
- 19. The film substrate of claim 1 wherein said first direction is machine direction (MD) and said second direction is transverse direction (TD).
- 20. A curl-resistant, cross-sectionally symmetrical, laminated multilayer film substrate for use in the production of banknotes and security papers comprising:(a) an unprinted, imbalanced biaxially oriented first layer having inner and outer sides, comprising at least about 50 weight percent of a high density polyethylene having a density of at least about 0.94, said first layer being oriented in at least a first direction to a degree which is at least three times greater than the degree of orientation present in a second direction substantially normal to the first direction; (b) a balanced biaxially oriented second layer having inner and outer sides and a tensile strength of greater than about 18,000 lb./in2, wherein said second layer comprises print features on at least one outer side, said second layer being oriented in at least a first direction at an orientation ratio of at least 4:1 and oriented in a second direction substantially normal to said first direction at an orientation ratio of at least 6:1; (c) an unprinted, imbalanced biaxially oriented third layer having inner and outer sides, comprising at least about 50 weight percent of a high density polyethylene having a density of at least about 0.94, said third layer being oriented in at least a first direction to a degree which is at least three times greater than the degree of orientation present in a second direction substantially normal to the first direction; and (d) a laminating adhesive resin disposed between the inner sides of (a) and (c), said second layer being laminated to said first and third layers so that the first direction of orientation of said third layer is substantially aligned with the first direction of orientation of said first layer and wherein (a) further comprises a coextruded propylene copolymer skin on its inner side.
- 21. The film substrate of claim 20 wherein said first direction is machine direction (MD) and said second direction is transverse direction (TD).
- 22. A curl-resistant, cross-sectionally symmetrical, laminated multilayer film substrate for use in the production of banknotes and security papers comprising:(a) an unprinted first layer having inner and outer sides, comprising at least about 50 weight percent of an unoriented, blown high density polyethylene having a density of at least about 0.94; (b) a second layer having inner and outer sides and a tensile strength greater than about 18,000 lb./in2, wherein said second layer comprises print features on at least one outer side, said second layer being oriented in at least a first direction at an orientation ratio of at least 4:1 and oriented in a second direction substantially normal to said first direction at an orientation ratio of at least 6:1; (c) an unprinted third layer having inner and outer sides, comprising at least about 50 weight percent of an unoriented, blown high density polyethylene having a density of at least about 0.94; (d) a laminating adhesive resin disposed between the inner sides of (a) and (c) and wherein (a) further comprises a coextruded propylene copolymer skin on its inner side.
RELATED APPLICATIONS
This application is a continuation in part of U.S. application Ser. Nos. 09/064,993, filed Apr. 23, 1998, now U.S. Pat. No. 5,879,028; and Ser. No. 08/467,484 filed Jun. 6, 1995, which is a divisional of U.S. application Ser. No. 08/266,918, filed Jun. 27, 1994, now U.S. Pat. No. 5,698,333 and 08/762,089, filed Dec. 9, 1997, now U.S. Pat. No. 5,716,695, which is a divisional of U.S. application Ser. No. 08/601,886, filed Feb. 15, 1996, now U.S. Pat. No. 5,618,630, incorporated herein by reference.
US Referenced Citations (27)
Foreign Referenced Citations (2)
Number |
Date |
Country |
488652 |
Apr 1976 |
AU |
1287527 |
Aug 1972 |
GB |
Continuation in Parts (2)
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Number |
Date |
Country |
Parent |
09/064993 |
Apr 1998 |
US |
Child |
09/162219 |
|
US |
Parent |
08/467484 |
Jun 1995 |
US |
Child |
09/064993 |
|
US |