The present invention relates generally to methods of achieving corrosion and mar resistance of steel components.
It is difficult to find, in a single coating, a deep black color, good scratch resistance, good corrosion resistance, low smut levels that evenly cover low and high silicon steels, as well as smooth or rough surfaces.
The present invention relates to a method of improving corrosion and mar resistance of steel components by creating a black magnetite finish, with a medium temperature process, prior to application of a phosphate layer coating.
For the purpose of facilitating an understanding of the subject matter sought to be protected, there are illustrated in the accompanying drawings embodiments thereof, from an inspection of which, when considered in connection with the following description, the subject matter sought to be protected, its construction and operation, and many of its advantages should be readily understood and appreciated.
While this invention is susceptible of embodiments in many different forms, there is shown in the drawings, and will herein be described in detail, a preferred embodiment of the invention with the understanding that the present disclosure is to be considered as an exemplification of the principles of the invention and is not intended to limit the broad aspect of the invention to embodiments illustrated. As used herein, the term “present invention” is not intended to limit the scope of the claimed invention and is instead a term used to discuss exemplary embodiments of the invention for explanatory purposes only.
The present invention relates to a method of improving corrosion and mar resistance of steel components by creating a black magnetite finish, with a medium temperature process, prior to application of a phosphate layer coating.
In step 106, the steel component is subjected to acidic surface preparation to facilitate surface pickling/activation to facilitate chemical reaction. For example, the steel component may be immersed in an acid or acidic solution at ambient temperature for about 4.5-5 minutes. Any acidic compound can be used that provides good descaling properties on the steel to be used. In step 108, the steel component is rinsed to remove any acid on the steel component from step 106. For example, the steel component may be immersed in water at ambient temperature for about 0.5 minutes.
In step 110, the steel component is subjected to black oxide treatment to facilitate creation of a conversion layer on the surface of the steel component. The reaction allows the formation of magnetite on the surface of the steel component (Fe3O4). This layer is about 1 micrometer deep or thick, thus providing a mechanical resistance to surface abrasion during the chemical reactions that occur while moving in a barrel. For example, the steel component may be immersed in a black oxide at about 210-220° F. for about 10 minutes. The black oxide is an aqueous solution with sodium nitrate at about 7 to 13% and sodium hydroxide at about 1 to 5%. In step 112, the steel component is rinsed to remove chemical(s) remaining on the steel component from step 110. For example, the steel component may be immersed in water at ambient temperature for about 2 minutes.
In step 114, the steel component is subjected to a grain refining treatment to facilitate creation of a fine crystalline manganese phosphate coating (described in step 116 below). For example, the steel component may be immersed in a grain refining solution containing one or more activating agents at about 86° F. for about 2 minutes. The grain refining solution may be a combination of Tetrasodium pyrophosphate at a concentration of about 2.5 pounds per 100 gallons of water, and Triethanolamine at a concentration of about 0.4 to 2.5 pounds per 100 gallons of water. In step 116, the steel component is subjected to a manganese phosphate. For example, the steel component may be immersed in a phosphating solution at about 180° F. for about 15 minutes. The phosphating solution may be a combination of Manganese dihydrogenphosphate at about 3 to 4%, Phosphoric acid at about 0.7% to 1.4%, Manganese nitrate at about 0.1 to 0.7% and Nickel nitrate at about 0.1%. The acid reacts with the iron on the surface of the steel component, locally precipitating the phosphates at the surface.
In step 118, the steel component is rinsed to remove the previous chemicals/chemistry on the steel component from steps above. For example, the steel component may be immersed in water at ambient temperature for about 2 minutes. In step 120, the steel component is subjected to a rust inhibitor treatment to provide additional corrosion protection and a shiny appearance to the steel component. For example, the steel component may be immersed in one or more rust inhibitors at ambient temperature for about 1 minute. The rust inhibitor may be any oil based on hydrotreated petroleum distillates that provides corrosion protection and a deep black appearance. Different additives on the oil may provide enhanced properties, such as increased corrosion protection or a shinier appearance.
In an embodiment, the steel component(s) may be transferred though the process of
In another embodiment, the process of
The process described above with respect to
For example, the use of a medium temperature black oxide treatment requires use of expensive rust inhibitor and replacement/rework of corroded parts. Further, high smut causes blackening of packaging and skin during handling.
As described above with reference to
As used herein, the term “coupled” and its functional equivalents are not intended to necessarily be limited to direct, mechanical coupling of two or more components. Instead, the term “coupled” and its functional equivalents are intended to mean any direct or indirect mechanical, electrical, or chemical connection between two or more objects, features, work pieces, and/or environmental matter. “Coupled” is also intended to mean, in some examples, one object being integral with another object. As used herein, the term “a” or “one” may include one or more items unless specifically stated otherwise.
The matter set forth in the foregoing description and accompanying drawings is offered by way of illustration only and not as a limitation. While particular embodiments have been shown and described, it will be apparent to those skilled in the art that changes and modifications may be made without departing from the broader aspects of the inventors' contribution. The actual scope of the protection sought is intended to be defined in the following claims when viewed in their proper perspective based on the prior art.