Claims
- 1. A new composition of matter which comprises the product resulting from thermally treating, at a temperature of from about 190.degree. C. to about 350.degree. C. for from about 10 minutes to about 48 hours, the product resulting from reacting, in the presence or absence of a suitable solvent,
- (A) acrolein, crotonaldehyde or a combination thereof; and
- (B) at least one organic polyamine represented by the formula ##STR5## wherein R is a divalent saturated C.sub.2 to C.sub.4 aliphatic hydrocarbon group; each R.sup.1 and R.sup.2 is independently hydrogen or a saturated alkyl amino or an alkyloxy group containing from 2 to about 4 carbon atoms or when two adjacent R.sup.2 groups are taken together, they form a bridging alkylene radical containing 2 carbon atoms such that the R group containing 2 carbon atoms and two adjacent R.sup.2 groups and two nitrogen atoms form a heterocyclic ring containing 4 carbon atoms and 2 nitrogen atoms; x has a value from 1 to about 8; and
- wherein components (A) and (B) are employed in a mole ratio of (A) to (B) of from about 1:1 to about 1:6.
- 2. A composition of claim 1 wherein the polyamine is ethylenediamine, diethylenetriamine, triethylenetetramine, tetraetylenepentamine, pentaethylenehexamine, hexaethyleneheptamine, or any combination thereof.
- 3. A new composition of matter which is the reaction product resulting from reacting at a temperature of from about 25.degree. C. to about 250.degree. C. for a time sufficient to complete the reaction as determined by halide or residual acid number titrations,
- (I) the product resulting from thermally treating, at a temperature of from about 190.degree. C. to about 350.degree.L0 C. for from about 10 minutes to about 48 hours, the product resulting from reacting, in the presence or absence of a suitable solvent,
- (A) acrolein, crotonaldehyde or a combination thereof; and
- (B) at least one organic diamine represented by the formula ##STR6## wherein R is a divalent saturated C.sub.2 to C.sub.4 aliphatic hydrocarbon group; each R.sup.1 and R.sup.2 is independently hydrogen or a saturated alkyl amino or an alkyloxy group containing from 2 to about 4 carbon atoms or when two adjacent R.sup.2 groups are taken together, they form a bridging alkylene radical containing 2 carbon atoms such that the R group containing 2 carbon atoms and two adjacent R.sup.2 groups and two nitrogen atoms form a heterocyclic ring containing 4 carbon atoms and 2 nitrogen atoms; x has a value from 1 to about 8; and
- wherein components (A) and (B) are employed in a mole ratio of (A) to (B) of from about 1:1 to about 1:6; and
- (II)
- (A) at least one saturated or unsaturated, cyclic or acyclic aliphatic mono- or polycarboxylic acid having from about 2 to about 50 carbon atoms; or
- (B) at least one saturated or unsaturated, cyclic or acyclic aliphatic alkyl monohalide or alkyl polyhalide having from about 2 to about 50 carbon atoms; or
- (C) a combination of (A) and (B);
- wherein components (I) and (II) are employed in quantities which provide from about 0.4 to about 1 equivalent of carboxyl or halide or both groups from component (II) for each theoretically active amino hydrogen atom contained in component (I).
- 4. A composition of claim 3 wherein
- (a) components (II-A) or (II-B) or both each has from about 12 to about 36 carbon atoms; and
- (b) components (I) and (II) are employed in quantities which provide from about 0.55 to about 0.85 equivalent of carboxyl and/or halide groups from component (II) for each theoretically active amino hydrogen atom contained in component (I).
- 5. A composition of claim 4 wherein
- (a) components (II-A) or (II-B) or both each has from about 16 to about 20 carbon atoms; and
- (b) components (I) and (II) are employed in quantities which provide from about 0.65 to about 0.75 equivalent of carboxyl and/or halide groups from component (II) for each theoretically active amino hydrogen atom contained in component (I).
- 6. A composition of claim 4 wherein (a) component (I-B) is ethylenediamine, diethylenetriamine, triethylenetramine, tetraethylenepentamine pentaethylenehexamine, hexaethyleneheptamine or any combination thereof; and (b) component (II) is tall oil fatty acid, dimerized tall oil fatty acid, or any combination thereof.
- 7. A composition of claim 5 wherein (a) component (I-B) is ethylenediamine, diethylenetriamine, triethylenetetramine, tetraethylenepentamine, pentaethylenehexamine, hexaethyleneheptamine or any combination thereof; and (b) component (II) is high molecular weight fatty acid.
- 8. A composition of claim 3 wherein the reaction product of components (I-A) and (I-B) is an oligomer having an amine hydrogen equivalent weight of from about 50 to about 80.
- 9. A composition of claim 4 wherein the reaction product of components (I-A) and (I-B) is an oligomer having an amine hydrogen equivalent weight of from about 50 to about 80.
- 10. A composition of claim 5 wherein the reaction product of components (I-A) and (I-B) is an oligomer having an amine hydrogen equivalent weight of from about 50 to about 80.
- 11. A composition of claim 6 wherein the reaction product of components (I-A) and (I-B) is an oligomer having an amine hydrogen equivalent weight of from about 50 to about 80.
- 12. A composition of claim 7 wherein the reaction product of components (I-A) and (I-B) is an oligomer having an amine hydrogen equivalent weight of from about 50 to about 80.
CROSS-REFERENCE TO RELATED APPLICATION
This application is a continuation-in-part of application Ser. No. 843,521 filed Mar. 24, 1986, now abandoned, which is a continuation-in-part of application Ser. No. 691,329, filed Jan. 14, 1985, now abandoned.
Continuation in Parts (2)
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Number |
Date |
Country |
Parent |
843521 |
Mar 1986 |
|
Parent |
691329 |
Jan 1985 |
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