Patent Application
20170281495
The present invention relates to a composition containing (A): an acyl basic amino acid derivative and (B): at least one kind of inorganic powder, which is used for, for example, cosmetics. In addition, it relates to a production method of a surface treatment powder containing (A) and (B).
Pigments are used for various products such as paint, cosmetics and the like, and are generally often used after coating the surface thereof depending on various objects such as improvement of dispersibility, condition and durability of coated film, color tone and the like and improvement of sense of use and the like. The surface treatment of pigments is very important since it is greatly affected by the production conditions and the like of the product.
As an example of the surface treatment of pigments in cosmetics, in powder foundation, a surface treatment of pigments is performed with a highly polar material by a wet production method or a surface treatment of pigments is performed with a material with a sense of use affording smooth texture, to realize a feeling of non-powdery covering.
As one of the materials used for surface treatment, Nε-lauroyl-L-lysine is known (non-patent document 1). As characteristics of the surface treatment with Nε-lauroyl-L-lysine, disclosed are reduced damage on the skin since a lipophilic treatment decreases oil absorption, improvement of attachability, comparatively small coagulation due to compression, enhanced usability and texture and the like (patent document 1, non-patent document 2).
However, the effect of surface treatment with Nε-lauroyl-L-lysine is not sufficiently satisfactory. In addition, a method of producing a powder surface-treated with Nε-lauroyl-L-lysine includes dissolving Nε-lauroyl-L-lysine which is poorly soluble in water in a strong alkaline aqueous solution, and adding the solution dropwise to a hydrochloric acid slurry of pigment to neutralize same, which is followed by filtration, drying, pulverization, and sieve treatment (patent document 1), and the method is very laborious.
It has been reported that a compound represented by the following formula:
wherein Ra and Rb are each a hydrogen atom or an alkyl group, and n is an integer of 0 to 12, or a salt thereof (hereinafter to be also referred to as “lauroyl amino acid derivative”) is useful for gelation or solidifying water and a liquid organic medium (patent document 2, non-patent document 3 and non-patent document 4 etc.).
However, a composition containing a lauroyl amino acid derivative and an inorganic powder, and a cosmetic containing the composition have not been reported heretofore.
patent document 1: JP-A-2005-2077
patent document 2: JP-A-2004-323505
non-patent document 1: Bull. Chem. Soc. Jpn., 1983, 56, 2569-2571
non-patent document 2: Manufacturing Technology of Cosmetics Fragrance Journal (2001), 162-164
non-patent document 3: Org. Biomol. Chem., 2003, 1, 4124-4131
non-patent document 4: New J. Chem., 2005, 29, 1439-1444
An object of the present invention is to provide a composition which can be produced conveniently, has good dispersibility, is superior in the sense of use such as moist feeling, feeling of close adhesion and affinity, and is superior in the condition and durability of the coated film.
The present inventors have conducted intensive studies in an attempt to achieve the above-mentioned object and found that a composition of component (B): at least one kind of inorganic powder coating, which is coated with component (A): a compound represented by the following formula (1) (hereinafter sometimes to be also referred to as “compound (1)”) or a salt thereof has good dispersibility, is superior in the sense of use such as moist feeling, feeling of close adhesion, and affinity, and improves the condition and durability of the coated film, which resulted in the completion of the present invention.
Therefore, the present invention provides the following.
wherein
R1 and R2 are each independently an alkyl group having 5-21 carbon atoms or an alkenyl group having 5-21 carbon atoms,
R3 and R4 are each independently a hydrogen atom, an alkyl group having 1-22 carbon atoms or an alkenyl group having 2-22 carbon atoms,
z is an integer of not less than 0,
x and y are each independently an integer of 2-4, or a salt thereof, and
component (B): at least one kind of inorganic powder.
wherein
R1 and R2 are each independently an alkyl group having 5-21 carbon atoms or an alkenyl group having 5-21 carbon atoms,
R3 and R4 are each independently a hydrogen atom, an alkyl group having 1-22 carbon atoms or an alkenyl group having 2-22 carbon atoms,
z is an integer of not less than 0, and
x and y are each independently an integer of 2-4, or a salt thereof.
According to the present invention, a cosmetic composition which can be produced conveniently, has good dispersibility, and is superior in the sense of use such as moist feeling, feeling of close adhesion, and affinity can be provided.
According to the present invention, a cosmetic with less makeup collapse and the like can be provided since a coated film having superior condition and durability can be provided.
The composition of the present invention is characterized in that it is a composition containing component (A): a compound represented by the formula (1)
wherein
R1 and R2 are each independently an alkyl group having 5-21 carbon atoms or an alkenyl group having 5-21 carbon atoms,
R3 and R4 are each independently a hydrogen atom, an alkyl group having 1-22 carbon atoms or an alkenyl group having 2-22 carbon atoms,
z is an integer of not less than 0,
x and y are each independently an integer of 2-4, or a salt thereof, and
component (B): at least one kind of inorganic powder.
The embodiment of the present invention is described in detail in the following.
R1 and R2 are each independently an alkyl group having 5-21 carbon atoms or an alkenyl group having 5-21 carbon atoms.
The alkyl group having 5-21 carbon atoms means a straight-chain or branched-chain alkyl group having 5-21 carbon atoms. Specific examples thereof include pentyl group, isopentyl group, neopentyl group, a hexyl group, isohexyl group, neohexyl group, heptyl group, isoheptyl group, neoheptyl group, octyl group, isooctyl group, nonyl group, isononyl group, decyl group, isodecyl group, undecyl group, dodecyl group, tridecyl group, tetradecyl group, pentadecyl group, hexadecyl group, heptadecyl group, octadecyl group, nonadecyl group, icosyl group and the like.
The alkenyl group having 5-21 carbon atoms means a straight-chain or branched-chain alkenyl group having 5-21 carbon atoms. Specific examples thereof include pentenyl group, hexenyl group, heptenyl group, octenyl group, nonenyl group, decenyl group, undecenyl group, dodecenyl group, tridecenyl group, tetradecenyl group, pentadecenyl group, hexadecenyl group, heptadecenyl group, octadecenyl group, nonadecenyl group, icosenyl group and the like.
An alkyl group having 5-15 carbon atoms means a straight-chain or branched-chain alkyl group having 5-15 carbon atoms. Specific examples thereof include pentyl group, a hexyl group, heptyl group, octyl group, nonyl group, decyl group, undecyl group, dodecyl group, tridecyl group, tetradecyl group, pentadecyl group and the like.
An alkyl group having 7-11 carbon atoms means a straight-chain or branched-chain alkyl group having 7-11 carbon atoms. Specific examples thereof include heptyl group, octyl group, nonyl group, decyl group, undecyl group and the like.
R1 and R2 are preferably each independently an alkyl group having 5-15 carbon atoms, more preferably each independently an alkyl group having 7-11 carbon atoms.
Preferably, R1 and R2 are each a straight-chain alkyl group. Furthermore, R1 and R2 are preferably the same.
R3 and R4 are each independently a hydrogen atom, an alkyl group having 1-22 carbon atoms or an alkenyl group having 2-22 carbon atoms.
An alkyl group having 1-22 carbon atoms means a straight-chain or branched-chain alkyl group having 1-22 carbon atoms. Specific examples thereof include methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, an isobutyl group, a sec-butyl group, a tert-butyl group, a pentyl group, isopentyl group, neopentyl group, a hexyl group, isohexyl group, neohexyl group, heptyl group, isoheptyl group, neoheptyl group, octyl group, isooctyl group, nonyl group, isononyl group, decyl group, isodecyl group, undecyl group, dodecyl group, tridecyl group, tetradecyl group, pentadecyl group, hexadecyl group, heptadecyl group, octadecyl group, nonadecyl group, icosyl group and the like.
An alkenyl group having 2-22 carbon atoms means a straight-chain or branched-chain alkenyl group having 2-22 carbon atoms. Specific examples thereof include ethenyl group, 1-propenyl group, 2-propenyl group, 1-butenyl group, 2-butenyl group, 3-butenyl group, pentenyl group, hexenyl group, heptenyl group, octenyl group, nonenyl group, decenyl group, undecenyl group, dodecenyl group, tridecenyl group, tetradecenyl group, pentadecenyl group, hexadecenyl group, heptadecenyl group, octadecenyl group, nonadecenyl group, icosenyl group and the like.
Preferably, both R3 and R4 are hydrogen atoms.
z is an integer of not less than 0.
z is preferably an integer of 0-10, more preferably 7 or 8.
x and y are each independently an integer of 2-4.
x and y are each preferably 4.
As a compound represented by the formula (1), the following compounds can be preferably recited.
A compound wherein R1 and R2 are each independently a straight-chain alkyl group having 5-15 carbon atoms,
R3 and R4 are each a hydrogen atom,
z is an integer of 0-10, and
x and y are each 4.
A compound wherein R1 and R2 are each a straight-chain alkyl group having 5-15 carbon atoms,
R3 and R4 are each a hydrogen atom,
z is 7 or 8, and
x and y are each 4.
A compound wherein R1 and R2 are each a straight-chain alkyl group having 7-11 carbon atoms,
R3 and R4 are each a hydrogen atom,
z is 7 or 8, and
x and y are each 4.
Specific examples of the compound represented by the formula (1) include
bis(Nε-lauroyl-L-lysine)sebacoyl amide,
bis(Nε-octanoyl-L-lysine)sebacoyl amide, and a salt thereof.
The salt of the compound represented by the formula (1) is not particularly limited. Examples thereof include alkali metal salts such as sodium salt, potassium salt and the like, alkaline earth metal salts such as calcium salt, magnesium salt and the like, inorganic salts such as aluminum salt, salt with zinc and the like, and organic salts such as organic amine salts such as ammonium salt, monoethanolamine salt, diethanolamine salt, triethanolamine salt and the like, basic amino acid salts such as arginine salt, lysine salt and the like, and the like. One kind of these may be used, or two or more kinds selected from the above-mentioned group may be used in a mixture. From the aspects of easy availability, handling property and the like, alkali metal salt, organic amine salt, or basic amino acid salt is preferable, and sodium salt and potassium salt are particularly preferable.
Compound (1) can be produced by a method known per se or a method analogous thereto (JP-A-2004-323505, Org. Biomol. Chem., 2003, 1, 4124-4131, New J. Chem., 2005, 29, 1439-1444 etc.). For example, as shown in the following formula, of compounds (1), symmetrical compound (1′) can be produced by reacting Nω-acyl amino acid (2) and dicarboxylic acid dichloride (3) in an appropriate solvent.
wherein R1′ is an alkyl group having 5-21 carbon atoms or an alkenyl group having 5-21 carbon atoms, R3′ is a hydrogen atom, an alkyl group having 1-22 carbon atoms or an alkenyl group having 2-22 carbon atoms, z′ is an integer of not less than 0, and x′ is an integer of 2-4.
Examples of the Nω-acyl amino acid (2) include Nε-acyl lysine (e.g., Nε-hexanoyl-L-lysine, Nε-octanoyl-L-lysine etc.), Nδ-acyl ornithine (e.g., Nδ-hexanoyl-L-ornithine etc.), Nγ-acyl-α,γ-diaminobutyric acid and the like.
Examples of the dicarboxylic acid dichloride (3) include oxalyl chloride, malonyl chloride, succinyl chloride, glutaryl chloride, adipoyl chloride, pimeloyl chloride, suberoyl chloride, azelaoyl chloride, sebacoyl chloride, dodecanedioyl chloride and the like. The amount of dicarboxylic acid dichloride (3) to be used is generally 0.4-0.6 equivalent relative to Nω-acyl amino acid (2).
While the solvent is not particularly limited as long as it is inert to the reaction, examples thereof include ethers such as diethyl ether, tetrahydrofuran and the like.
In addition, of compounds (1), asymmetric compound (1″) can be produced as follows. First, Nω-acyl amino acid (2) and dicarboxylic acid monochloride monoester (4) are reacted in an appropriate solvent to give compound (5) (step 1). Then, the primary ester moiety of the obtained compound (5) is hydrolyzed in the presence of a base such as sodium hydroxide, potassium hydroxide and the like, the carboxylic acid moiety is chlorinated with a chlorinating agent such as thionyl chloride and the like, and the compound is reacted with Nω-acyl amino acid (2′) which is different from Nω-acyl amino acid (2) used in the aforementioned step 1 (step 2), whereby derivative (1″) can be produced.
wherein R1′, R3′, z′ and x′ are as defined above, R2′ is an alkyl group having 5-21 carbon atoms or an alkenyl group having 5-21 carbon atoms, R4′ is a hydrogen atom, an alkyl group having 1-22 carbon atoms or an alkenyl group having 2-22 carbon atoms, R5 is an alkyl group such as a methyl group, an ethyl group and the like, and y′ is an integer of 2-4.
As Nω-acyl amino acids (2) and (2′), Nω-acyl amino acids similar to those mentioned above can be used.
As dicarboxylic acid monochloride monoester (4), a commercially available product can be used as is when it is commercially available, or one produced by a method known per se or a method analogous thereto can also be used.
Compound (1) obtained by the aforementioned method can be converted to a salt of compound (1) by a reaction with alkali metal hydroxide such as sodium hydroxide, potassium hydroxide and the like, alkali earth metal hydroxide such as calcium hydroxide and the like, organic amine base, or the like.
The “inorganic powder” in the present specification is preferably an inorganic powder having a particle size of 0.01 μm-100 μm.
Specific examples of the “inorganic powder” include alumina, talc, kaolin, mica, sericite, bismuth trioxide, bismuth oxychloride, bentonite, smectite, montmorillonite, hectorite, zeolite, calcium carbonate, magnesium carbonate, silicic anhydride, magnesium silicate, aluminum silicate, aluminum silicate magnesium, calcium silicate, barium silicate, strontium silicate, calcium phosphate, magnesium oxide, barium sulfate, magnesium alumina metasilicate, iron oxide(red iron oxide, black iron oxide, yellow iron oxide etc.), chrome oxide, titanium oxide, titanium oxide fine particle, zinc oxide, zinc oxide fine particle, cerium oxide, aluminum oxide, magnesium oxide, chromium hydroxide, ultramarine blue, iron blue, silica, calcium carbonate, magnesium carbonate, calcium phosphate, aluminum hydroxide, barium sulfate, magnesium sulfate, silicon carbide, tungsten acid metal salt, magnesium aluminate, magnesium alumina metasilicate, aluminum chlorohydrate, clay, hydroxyapatite, ceramic powder, boron nitride, aluminum nitride, titanium nitride, silicon nitride, silicone carbide, cobalt titanate, ilmenite, lithium cobalt titanate, cobalt aluminate, inorganic blue pigment, metal powder pigment (e.g., aluminum powder, gold powder, silver powder, iron powder, platinum powder, aluminum powder, copper powder, stainless powder etc.) and the like. Of these, talc, mica, sericite, iron oxide, titanium oxide, titanium oxide fine particle, zinc oxide, zinc oxide fine particle, silica and aluminum hydroxide are preferable, and talc, mica, titanium oxide and silica are more preferable.
In addition, two or more kinds of the above-mentioned inorganic powder may be used in combination. For example, a powder in which aluminum hydroxide is conjugated on the surface of titanium oxide fine particles (titanium oxide ultrafine particle TTO-55(A): manufactured by Ishihara Sangyo Kaisha, LTD.), a powder in which aluminum hydroxide is conjugated on the surface of mica particles or pearl particles (Excel Mica JP-2, Excel Pearl: manufactured by Miyoshi Kasei), a powder in which silica beads are conjugated on the surface of mica particles (SXI-5: manufactured by Miyoshi Kasei), a powder in which titanium oxide and titanium oxide fine particles are conjugated on the surface of mica particles and talc particles (TMC series, TTC series: manufactured by Miyoshi Kasei), a powder in which hydroxyapatite and zinc oxide are conjugated on the surface of sericite particles (Powder La Vie: manufactured by Miyoshi Kasei) and the like can be mentioned. Of these, an inorganic powder conjugated with aluminum hydroxide is preferable.
In the composition of the present invention, the weight ratio of component (A): compound (1) or a salt thereof and component (B): at least one kind of inorganic powder, as weight of component (A)/weight of component (B), is generally 1/1000-1/1, preferably 1/200-1/5, more preferably 1/100-1/10.
The present invention also relates to a cosmetic containing the aforementioned composition of the present invention.
Specific examples of the cosmetic include basic cosmetic (e.g., skin lotion, milky lotion, makeup base, serum, night cream, facial mask, makeup remover product (cleansing gel etc.), nail cream etc.), sun care product (e.g., sunscreen, lotion for sunburn skin etc.), hair treatment agent (e.g., hair treatment, out-bath treatment, serum for hair, split end mender etc.), hair styling products (e.g., brushing lotion, curler lotion, pomado, stick pomade, hair spray for styling, hair mist, hair liquid, styling foam, hair gel, water grease etc.), shaving product (e.g., shaving cream, after-shave lotion etc.), makeup cosmetic (e.g., foundation (solid, cream, liquid etc.), BB cream, CC cream, concealer, rouge, lip gloss, eye shadow, eyeliner, blush, mascara, bronzer etc.), perfumes, lip cream, adiaphoretic, oral cosmetic, tooth paste, bath cosmetic (e.g., bathing powder, bath salt etc.) and the like.
The cosmetic of the present invention may contain components that can be generally added to a cosmetic, as long as the effect of the present invention is not inhibited. Specific examples include amino acids, amino acid derivative, chelating agent, cosmetic powder, lower alcohol, animal and plant extract, nucleic acid, vitamin, enzyme, anti-inflammatory agent, antimicrobial agent, preservative, antioxidant, ultraviolet absorber, adiaphoretic, pigment, dye, oxidation dye, pH adjuster, pearly sheen agent, and wetting agent.
In addition, the present invention relates to a surface-treated powder, characterized in that a surface of component (B): at least one kind of inorganic powder is coated with component (A): a compound represented by the formula (1) or a salt thereof.
In addition, the present invention relates to a production method of a surface-treated powder, characterized in that a surface of component (B): at least one kind of inorganic powder is coated with component (A): a compound represented by the formula (1) or a salt thereof. Examples of the coating treatment method include a method of dispersing component (B) in a liquid of component (A) and the like. Based on a conventionally-used technique, it is possible to further perform drying, pulverization, classification and the like, whereby a surface-treated powder can be produced. The mixing ratio, definitions of (A) and (B) and the like in the production method of the present invention are as defined above.
The composition of the present invention, and a cosmetic containing the composition can be produced according to a conventional method.
Other features of the invention will become apparent in the course of the following descriptions of exemplary embodiments which are given for illustration of the invention and are not intended to be limiting thereof.
The present invention is concretely explained in the following by referring to Production Example and Examples. The present invention is not limited by the following Production Example and Examples. Unless particularly indicated, “%” means “wt %”.
Nε-lauroyl-L-lysine (8.2 g, 25 mmol) was dissolved in water (70 g) and 25% aqueous sodium hydroxide solution (10 g), and diethyl ether (80 g) was added. Sebacoyl chloride (3.3 g, 14 mmol) was slowly added to the ether layer. The two-layer solution was stirred for about 1 hr while maintaining at 0° C., and then at room temperature for 23 hr. Then, 75% sulfuric acid was added dropwise to adjust to pH 2, the obtained white precipitate was collected by filtration, washed well with water and dried. The obtained compound was dissolved in an aqueous sodium hydroxide solution to give a 10% aqueous bis(Nε-lauroyl-L-lysine)sebacoyl amide disodium salt solution.
Nε-octanoyl-L-lysine (6.8 g, 25 mmol) was dissolved in water (70 g) and 25% aqueous sodium hydroxide solution (10 g), and diethyl ether (80 g) was added. Sebacoyl chloride (3.3 g, 14 mmol) was slowly added to the ether layer. The two-layer solution was stirred for about 1 hr while maintaining at 0° C., and then at room temperature for 23 hr. Then, 75% sulfuric acid was added dropwise to adjust to pH 2, the obtained white precipitate was collected by filtration, washed well with water and dried. The obtained compound was dissolved in an aqueous sodium hydroxide solution to give a 10% aqueous bis(Nε-octanoyl-L-lysine)sebacoyl amide disodium salt solution.
1H-NMR of bis(Nε-octanoyl-L-lysine)sebacoyl amide (free form)
1H-NMR (400 MHz, DMSO-d6, TMS, 25° C) :δ0.85 (t, J=6.8 Hz, 6H), 1.20-1.29 (m, 28H), 1.32-1.38 (m, 4H), 1.45-1.50 (m, 8H), 1.54-1.59 (m, 4H), 2.02 (t, J=7.4 Hz, 4H), 2.09 (t, J=7.4 Hz, 4H), 2.99 (q, J=6.5 Hz, 4H), 4.08-4.47 (m, 2H), 7.73 (t, J=5.6 Hz, 2H), 7.97 (d, J=8.0 Hz, 2H).
Component (I) and component (II) described in the following Table 1 and Table 2 were mixed (numerical value of each component in the Tables is in wt %), stirred in LAB.MIXER (LM-110T, HANIL) for 1 min and dried at 50° C. for 8 hr to give the compositions of Examples 1-14.
Component (I) and component (II) described in the following Table 2 were mixed (numerical value of each component 5 in the Tables is in wt %), stirred in LAB.MIXER (LM-110T, HANIL) for 1 min to give the compositions of Comparative Examples 1 and 2.
The compositions obtained by the above-mentioned production methods were evaluated for dispersibility, condition and durability of coated film, and sense of use (moist feeling, feeling of close adhesion, affinity). The evaluation methods and evaluation criteria are as follows.
As an index showing the dispersibility of a powder, oil absorption is generally used. For the evaluation of dispersibility, the oil absorption was measured as follows.
An oil agent (linseed oil) was added to samples (each 1 g) by small portions, and mixed with a spatula. The time point when the whole became one lump was taken as the end-point, the weight of the oil agent added before reaching the end-point was determined, and the oil absorption (%) was calculated from the following formula.
oil absorption (%)=weight (g) of oil agent÷weight (g) of sample×100
With the oil absorption of an untreated powder free of component (I) (hereinafter to be simply referred to as “untreated powder”) as the standard, the difference from the oil absorption in the Examples and Comparative Examples was evaluated according to the following criteria.
Samples (each 2 mg) were applied to artificial leather (Sapurare, manufactured by Idemitsu Technofine) with a force of 20-30 g to 1 cm square, and the appearance thereof was observed with a microscope (Video Loupe VL-7EX, manufactured by Scalar). On the basis of the obtained image, unevenness and sulcus cutis of the coated film were each scored according to the following criteria, and the sum was taken as the score of the coated film.
Then, the difference from the scoring results of an untreated powder was evaluated according to the following criteria.
For the evaluation of durability of the coated film, the coated film after tape detachment was evaluated as follows. Cellophane tape (manufactured by NICHIBAN) was placed on the artificial leather after the above-mentioned evaluation 2 and closely adhered thereto by drawing a circle 5 times with the ball of a finger with a force of 50-70 g. The tape was peeled off, and the leather was observed again with a microscope (Video Loupe VL-7EX, manufactured by Scalar). On the basis of the obtained image, unevenness of coated film, sulcus cutis, and residual amount on crista cutis were scored according to the following criteria, and the sum was taken as the score of the coated film.
Then, the difference from the scoring results of an untreated powder was evaluated according to the following criteria.
As regards moist feeling, feeling of close adhesion, and affinity, the compositions (2 mg) prepared as mentioned above were applied to the skin within the range of 5×2 cm on the inner side of the forearm and tested in 8 healthy male and female test subjects. On the basis of the number of subjects who answered that the compositions of the Examples and Comparative Examples were superior as compared to an untreated powder, they were evaluated according to the following criteria. The test subjects were made to previously recognize the sense of use (moist feeling, feeling of close adhesion, affinity) of the untreated powder.
The results are shown in Table 1 and Table 2.
As is clear from Table 1 and Table 2, the compositions of the present invention (Examples 1-14) showed good dispersibility, and were superior in the condition and durability of coated film, and the sense of use such as moist feeling, feeling of close adhesion, and affinity.
Preferable blending examples of the composition of the present invention are explained below.
A pressed powder foundation of the formulation shown in the following Table 3 was prepared according to a conventional method.
A stick foundation of the formulation shown in the following Table 4 was prepared according to a conventional method.
A talc-free loose powder foundation of the formulation shown in the following Table 5 was prepared according to a conventional method.
A Sun Protector (O/W) of the formulation shown in the following Table 6 was prepared according to a conventional method.
A sunscreen (W/O) of the formulation shown in the following Table 7 was prepared according to a conventional method.
A lipstick of the formulation shown in the following Table 8 was prepared according to a conventional method.
A stick adiaphoretic of the formulation shown in the following Table 9 was prepared according to a conventional method.
The cosmetics of Blending Examples 1-7 all showed good dispersibility, were superior in the condition and durability of coated film, and superior in the sense of use such as moist feeling, feeling of close adhesion, and affinity.
The details of the materials used are as follows.
The present invention can provide a composition which can be produced conveniently, shows good dispersibility, and is superior in the sense of use such as moist feeling, feeling of close adhesion, and affinity. Since a coated film formed from the composition has good condition and is superior in durability, it can be widely utilized as cosmetics.
Where a numerical limit or range is stated herein, the endpoints are included. Also, all values and subranges within a numerical limit or range are specifically included as if explicitly written out.
As used herein the words “a” and “an” and the like carry the meaning of “one or more.”
Obviously, numerous modifications and variations of the present invention are possible in light of the above teachings. It is therefore to be understood that, within the scope of the appended claims, the invention may be practiced otherwise than as specifically described herein.
All patents and other references mentioned above are incorporated in full herein by this reference, the same as if set forth at length.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2014-262160 | Dec 2014 | JP | national |
This application is a continuation of International Patent Application No. PCT/JP2015/086213, filed on Dec. 25, 2015, and claims priority to Japanese Patent Application No. 2014-262160, filed on Dec. 25, 2014, all of which are incorporated herein by reference in their entireties.
| Number | Date | Country | |
|---|---|---|---|
| Parent | PCT/JP2015/086213 | Dec 2015 | US |
| Child | 15631837 | US |
