Claims
- 1. A cosmetic composition consisting essentially of, in a cosmetically acceptable aqueous medium, 0.05 to 30% by weight of the total weight of the composition of at least one non-ionic surfactant selected from the group consisting of an alkylpolyglycoside surfactant and a polyglycerol surfactant, and 0.1 to 5% by weight of the total weight of the composition of at least one polydimethylsiloxane/polyoxyalkylene block copolymer,
- said polydimethylsiloxane/polyoxyalkylene block copolymer has the following formula
- (�Y((R.sub.2)SiO).sub.a (R.sub.2)SiYO!�(C.sub.n H.sub.2n O).sub.b !).sub.c(I)
- where
- R identical or different, denotes a methyl, ethyl, propyl, butyl, pentyl or hexyl,
- n is 2, 3 or 4,
- a is an integer not less than 5,
- b is an integer not less than 4,
- c is a number not less than 4,
- Y denotes a group selected from among:
- --R'--, --R'--CO--, and --R.sup.1 --NHCO--,
- where
- R' of Y in formula (I) is selected from the group consisting of ethylene, propylene and butylene,
- said alkylpolyglycoside surfactant has the following formula (II):
- R(C.sub.6 H.sub.10 O.sub.5).sub.x --H (II)
- where
- R (of formula II) is defined by:
- R.sub.1 --O--
- where
- R.sub.1 is a branched or linear alkyl group having 8 to 18 carbon atoms, a branched or linear alkenyl group having 8 to 18 carbon atoms, or an alkylphenyl group having 8 to 18 carbon atoms, the alkyl portion of said alkylphenyl group being either linear or branched, and
- where
- x denotes a number between 1 and 10; and
- said polyglycerol surfactant is selected from among the following polyhydroxypropylethers:
- compounds of the formula (IV):
- RO�C.sub.3 H.sub.5 (OH)--O--!.sub.n --H (IV)
- in which the �C.sub.3 H.sub.5 (OH)--O--! group represents at least one of the following structures: ##STR5## and R and n (of formula IV) have the following meanings: (a) R is a radical or a mixture of C.sub.10 -C.sub.14 alkyl radicals and n is a whole or decimal number from 2 to 10;
- (b) R is
- R.sub.2 CONHCH.sub.2 --CH.sub.2 OCH.sub.2 --CH.sub.2 -- (V)
- where
- R.sub.2 denotes a radical or a mixture of alkyl or alkenyl radicals of C.sub.11 -C.sub.17 and
- n denotes a whole or decimal number from 1 to 5; or
- (c) R is
- R.sub.3 --CHOH--CH.sub.2 -- (VI)
- where
- R.sub.3 denotes an aliphatic, cycloaliphatic, arylaliphatic radical of C.sub.7 -C.sub.21 and their mixtures, and
- n denotes a whole or decimal number from 1 to 10.
- 2. The composition of claim 1, wherein the polydimethylsiloxane/polyoxyalkylene block copolymer of formula (I) has an average molecular weight greater than or equal to 3000; the average molecular weight of each polyalkylene or siloxane block being between 300 and 10,000 and the proportion of siloxane blocks being between 10 and 95% by weight of the total weight of the block copolymer.
- 3. The composition of claim 1 where the polydimethylsiloxane/polyoxyalkylene block copolymer corresponds to the following formula (IA):
- �C.sub.4 H.sub.8 O(C.sub.n H.sub.2n O).sub.b C.sub.4 H.sub.8 SiMe.sub.2 O(SiMe.sub.2 O).sub.a SiMe.sub.2 !.sub.c (IA)
- where
- a is an integer greater than or equal to 4,
- b is an integer greater than or equal to 4,
- c is a number greater than or equal to 4, and
- n is an integer from 2 to 4.
- 4. The composition of claim 1 wherein the polydimethylsiloxane/polyoxyalkylene block copolymer has a recurrent motif with the following structure:
- --�--(Si--Me.sub.2 O).sub.x --Si--Me.sub.2 --C.sub.4 H.sub.8 O--(C.sub.2 H.sub.4 O).sub.y --(C.sub.3 H.sub.6 O).sub.z --C.sub.4 H.sub.8 --!--
- in which
- x is between 5 and 15 inclusive,
- y is between 15 and 30 inclusive, and
- z is between 20 and 30 inclusive.
- 5. The composition according to claim 1 where said polyhydroxypropylethers are compounds of formula (IV), n is a whole number or decimal number from 3 to 6.
- 6. The composition according to claim 1 where when R of said polyhydroxypropylethers is a compound of formula (V), n is a whole or decimal number from 1.5 to 4.
- 7. The composition according to claim 1 where when R of said polyhydroxypropylethers is a compound of formula (VI), said aliphatic, cycloaliphatic or arylaliphatic radicals further contain 1-6 ether, thioether or hydroxymethylene groups.
- 8. The composition of claim 1, wherein the polyglycerolated non-ionic surfactants are selected from among the following polyhydroxypropylethers: ##STR6## where R.sub.1 denotes a mixture of alkyl radicals C.sub.10 H.sub.21 and C.sub.12 H.sub.25 ;
- (.beta.) compounds prepared by condensation, in alkaline catalysis, of 3.5 moles of glycidol on an alpha-diol having 12 carbon atoms;
- (.gamma.) compounds of the formula:
- R.sub.2 --CONH--CH.sub.2 --CH.sub.2 --O--CH.sub.2 --CH.sub.2 --O--(CH.sub.2 --CHOH--CH.sub.2 --O--).sub.3.5 --H (IX)
- where
- R.sub.2 denotes a mixture of radicals containing the following alkyl and alkenyl radicals: C.sub.11 H.sub.23 H.sub.27, the radicals derived from fatty acids of copra and the radical derived from oleic acid; and
- (.delta.) compounds prepared by condensation of 3.5 moles of glycidol on a mixture of alpha-diols in C.sub.11 -C.sub.14.
- 9. The composition of claim 1 wherein said composition contains 0.05 to 5% by weight of the total weight of said composition of said non-ionic surfactant.
- 10. The composition of claim 1 wherein the cosmetically acceptable aqueous medium consists exclusively of water or of a mixture of water and a cosmetically acceptable solvent.
- 11. The composition of claim 1 further comprising anionic, cationic, amphoteric or zwitterionic surfactants, non-ionic surfactants other than those described previously, acidizing or alkalinizing agents, preservatives, thickeners, suspending agents, softeners, sun filters, perfumes, biocides, anti-oxidants, pigments, dyes, pearl lustering agents, repellents, oxidants, reducing agents, moisturizers, vitamins, foam reinforcers, electrolytes, ceramides, UV filters, anti-bacterial agents, anti-dandruff agents, anti-seborrhoeic agents, or pesticides.
- 12. The composition of claim 1 wherein said composition contains 1 to 30% by weight of the total weight of said composition of said non-ionic surfactant.
- 13. A cosmetic composition consisting essentially of, in a cosmetically acceptable aqueous medium, 0.05 to 30% by weight of the composition of at least one polyglycerol surfactant, and 0.1 to 5% by weight of the composition of at least one polydimethylsiloxane/polyoxyalkylene block copolymer,
- said polydimethylsiloxane/polyoxyalkylene block copolymer has the following formula
- (�Y( (R.sub.2)SiO).sub.a (R.sub.2)SiYO!�(C.sub.n H.sub.2n O).sub.b !).sub.c(I)
- where
- R identical or different, denotes a methyl, ethyl, propyl, isopropyl, butyl, pentyl or hexyl,
- n is 2, 3 or 4,
- a is an integer not less than 5,
- b is an integer not less than 4,
- c is a number not less than 4,
- Y denotes a group selected from among:
- --R'--, --R'--CO--, and --R'--NHCO--,
- where
- R' of Y in formula (I) is selected from the group consisting of ethylene, propylene and butylene,
- said polyglycerol surfactant is selected from among the following polyhydroxypropylethers:
- compounds of the formula (IV):
- RO�C.sub.3 H.sub.5 (OH)--O--!.sub.n --H (IV)
- in which the �C.sub.3 H.sub.5 (OH)--O--! group represents at least one of the following structures: ##STR7## and R and n (of formula IV) have the following meanings: (a) R is a radical or a mixture of C.sub.10 -C.sub.14 alkyl radicals and n is a whole or decimal number from 2 to 10;
- (b) R is
- R.sub.2 CONHCH.sub.2 --CH.sub.2 OCH.sub.2 --CH.sub.2 -- (V)
- where
- R.sub.2 denotes a radical or a mixture of alkyl or alkenyl radicals of C.sub.11 -C.sub.17 and
- n denotes a whole or decimal number from 1 to 5; or
- (c) R is
- R.sub.3 --CHOH--CH.sub.2 -- (VI)
- where
- R.sub.3 denotes an aliphatic, cycloaliphatic, arylaliphatic radical of C.sub.7 -C.sub.21 and their mixtures, and
- n denotes a whole or decimal number from 1 to 10.
- 14. The composition of claim 13, wherein the polydimethylsiloxane/polyoxyalkylene block copolymer of formula (I) has an average molecular weight greater than or equal to 3000; the average molecular weight of each polyalkylene or siloxane block being between 300 and 10,000 and the proportion of siloxane blocks being between 10 and 95% by weight of the total weight of the block copolymer.
- 15. The composition of claim 13 where the polydimethylsiloxane/polyoxyalkylene block copolymer corresponds to the following formula (IA):
- �C.sub.4 H.sub.8 O(C.sub.n H.sub.2n O).sub.b C.sub.4 H.sub.8 SiMe.sub.2 O(SiMe.sub.2 O).sub.a SiMe.sub.2 !.sub.c (IA)
- where
- a is an integer greater than or equal to 4,
- b is an integer greater than or equal to 4,
- c is a number greater than or equal to 4, and
- n is an integer from 2 to 4.
- 16. The composition of claim 13 wherein the polydimethylsiloxane/polyoxyalkylene block copolymer has a recurrent motif with the following structure:
- --�--(Si--Me.sub.2 O).sub.x --Si--Me.sub.2 --C.sub.4 H.sub.8 O--(C.sub.2 H.sub.4 O).sub.y --(C.sub.3 H.sub.6 O).sub.z --C.sub.4 H.sub.8 --!--
- in which
- x is between 5 and 15 inclusive,
- y is between 15 and 30 inclusive, and
- z is between 20 and 30 inclusive.
- 17. The composition according to claim 13 where said polyhydroxypropylethers are compounds of formula (IV), n is a whole number or decimal number from 3 to 6.
- 18. The composition according to claim 13 where when R of said polyhydroxypropylethers is a compound of formula (V), n is a whole or decimal number from 1.5 to 4.
- 19. The composition according to claim 13 where when R of said polyhydroxypropylethers is a compound of formula (VI), said aliphatic, cycloaliphatic or arylaliphatic radicals further contain 1-6 ether, thioether or hydroxymethylene groups.
- 20. The composition of claim 13, wherein the polyglycerolated non-ionic surfactants are selected from among the following polyhydroxypropylethers: ##STR8## where R.sub.1 denotes a mixture of alkyl radicals of C.sub.10 H.sub.21 and C.sub.12 H.sub.25 ;
- (.beta.) compounds prepared by condensation, in alkaline catalysis, of 3.5 moles of glycidol on an alpha-diol having 12 carbon atoms;
- (.gamma.) compounds of the formula:
- R.sub.2 --CONH--CH.sub.2 --CH.sub.2 --O--CH.sub.2 --CH.sub.2 --O--(CH.sub.2 --CHOH--CH.sub.2 --O--).sub.3.5 --H (IX)
- where
- R.sub.2 denotes a mixture of radicals containing the following alkyl and alkenyl radicals: C.sub.11 H.sub.23 H.sub.27, the radicals derived from fatty acids of copra and the radical derived from oleic acid; and
- (.delta.) compounds prepared by condensation of 3.5 moles of glycidol on a mixture of alpha-diols in C.sub.11 -C.sub.14.
- 21. The composition of claim 13 wherein said composition contains 0.05 to 5% by weight of the total weight of said composition of said polyglycerol surfactant.
- 22. The composition of claim 13 wherein the cosmetically acceptable aqueous medium consists exclusively of water or of a mixture of water and a cosmetically acceptable solvent.
- 23. The composition of claim 13 further comprising anionic, cationic, amphoteric or zwitterionic surfactants, non-ionic surfactants other than those described previously, acidizing or alkalinizing agents, preservatives, thickeners, suspending agents, softeners, sun filters, perfumes, biocides, anti-oxidants, pigments, dyes, pearl lustering agents, repellents, oxidants, reducing agents, moisturizers, vitamins, foam reinforcers, electrolytes, ceramides, UV filters, anti-bacterial agents, anti-dandruff agents, anti-seborrhoeic agents, or pesticides.
- 24. The composition of claim 13 wherein said composition contains 1 to 30% by weight of the total weight of said composition of said polyglycerol surfactant.
Priority Claims (1)
Number |
Date |
Country |
Kind |
93 10939 |
Sep 1993 |
FRX |
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Parent Case Info
This is a continuation of application Ser. No. 08/304,833, filed Sep. 13, 1994, now abandoned.
US Referenced Citations (15)
Foreign Referenced Citations (6)
Number |
Date |
Country |
0398177 |
Nov 1990 |
EPX |
0440542 |
Aug 1991 |
EPX |
0492657 |
Jul 1992 |
EPX |
0535367 |
Apr 1993 |
EPX |
2242129 |
Sep 1991 |
GBX |
9208439 |
May 1992 |
WOX |
Continuations (1)
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Number |
Date |
Country |
Parent |
304833 |
Sep 1994 |
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