Patent Application
20230225956
The present invention relates to a cosmetic composition.
For changing the color of hair, it is known to use an oxidation hair dye, an acid dye, etc. However, hair dyeing with an oxidation hair dye may often cause hair damages, and in hair dyeing with an acid dye, fading due to color loss may occur fast.
Given the situation, techniques of changing the color tone of hair without using an oxidation hair dye or an acid dye are investigated.
For example, Patent Literature 1 (JP S57-192310 A) discloses that a hair dye composition characterized by containing a silicone derivative is excellent in a concealing power and a dyeing and coloring power without increasing the dye/pigment concentration in the composition, and additionally can deepen the color tone of the dyed hair.
Patent Literature 2 (JP 2007-512388 A) discloses use of an aminosilicone as a method of optically improving the perception of the color of artificially colored hair.
The present invention relates to the following [1] to [7].
[1] A cosmetic composition containing (A) a silicone film-forming agent, (B) a high-molecular-weight organopolysiloxane having a degree of polymerization of 2,350 or more and 20,000 or less, and (C) an organopolysiloxane containing a cationic group other than the component (A) and the component (B), wherein the total content of the components (A) to (C) is 2% by mass or more and 50% by mass or less, and the content of water is 10% by mass or less.
[2] The cosmetic composition according to the above [1], which is a hair cosmetic composition.
[3] The cosmetic composition according to the above [1], which is a hair dye composition.
[4] A method for treating a keratin substance, including a step of applying the cosmetic composition of the above [1] to a keratin substance and then drying it.
[5] A method for treating hair, including a step of applying the hair cosmetic composition of the above [2] to hair and then drying it.
[6] A method for dyeing hair, including a step of applying the hair dye composition of the above [3] to hair and then drying it.
[7] A cosmetic kit with at least two compositions, wherein:
“Polymer” used in the present specification means a compound corresponding to a repetition of one or plural units (these units are derived from a compound known as a monomer). This or these units are repeated at least two times preferably at least three times.
“Hair” used in the present specification means mainly head hair.
“Hydrophobic” used in the present specification means that a solubility in water of a substance is less than 1% by mass at 25° C.
“Film formation” used in the present specification means that, when applied to a keratin substance, a film is left thereon.
“Volatile” used in the present specification means a substance having a boiling point of 260° C. or lower under normal pressure.
The cosmetic composition of the present invention contains:
(A) a silicone film-forming agent,
(B) a high-molecular-weight organopolysiloxane having a degree of polymerization of 2,350 or more and 20,000 or less, and
(C) an organopolysiloxane containing a cationic group other than the component (A) and the component (B), wherein:
the total content of the components (A) to (C) is 2% by mass or more and 50% by mass or less, and the content of water is 10% by mass or less.
Having the above constitution, the cosmetic composition of the present invention is, when applied to a keratin substance such as skin or hair, able to improve the color density and impart a good feel, and even after washing, is able to be excellent in sustainability of these effects.
The techniques of PTLs 1 and 2 cause stickiness of hair after treated and are insufficient in imparting a smooth feel and in improving the color density of hair, and there is room for improvement in durability of the effect.
It is an object of the present invention to provide a cosmetic composition which improves the color density without damaging keratin substances such as skin or hair, and can give a good feel particularly when applied to hair, and is excellent in sustainability of these effects even after washing.
The present inventors have found that a cosmetic composition containing a silicone film-forming agent, a predetermined high-molecular-weight organopolysiloxane and a cationic group-having organopolysiloxane, each in a predetermined amount, and having a water content of 10% by mass or less can solve the above-mentioned problems, and have completed the present invention.
According to the present invention, there can be provided a cosmetic composition which improves the color density without damaging keratin substances such as skin or hair, and can give a good feel particularly when applied to hair, and is excellent in sustainability of these effects even after washing.
The reason why the cosmetic composition of the present invention exhibits the above-mentioned effect is, though not clear, presumed as follows.
The cosmetic composition containing the component (A), the component (B) and the component (C) is, when applied to the surface of a keratin substance, able to form a hydrophobic film.
The component (B) is considered to exhibit an effect of imparting a good feel to the surface of a keratin substance and play a role in protecting the function of protecting the surface of the hydrophobic film. The component (C) has a cationic group and is therefore considered to have high adsorbability to a keratin substance such as skin or hair. Consequently, the component (C) is considered to eccentrically located on the side of the keratin substance, and is considered to firmly adsorb the formed film to the surface of the keratin substance to exhibit the film peeling preventing effect. The component (A) is considered to maintain the strength and the washing durability of the entire film formed and to also exhibit the durability improving effect of various characteristics given to the keratin substance owing to the synergistic effect with the component (B) and the component (C).
Further, since the components (A) to (C) are silicone substances, the refractive index thereof is generally lower than that of the keratin substances such as skin or hair. Consequently, when a film is formed on the surface of a keratin substance, using the cosmetic composition of the present invention, it is considered that the visual color density of keratin substances such as skin or hair can be improved by the light reflection inhibiting effect.
The mechanism of the action of the present invention is not limited to the above.
Components contained in the cosmetic composition of the present invention are described below.
The cosmetic composition of the present invention contains a silicone film-forming agent as the component (A). Containing the component (A), the cosmetic composition of the present invention is, when applied to a keratin substance such as skin or hair, able to visually improve color density of keratin substances and is able to form a hydrophobic film having high durability. In the case where a functional powder to be mentioned hereinunder is blended in the cosmetic composition, the functional powder can be held in the film to improve various functions and sustainability thereof.
As the component (A), a silicone film-forming agent usable in ordinary cosmetic materials can be used, and is preferably solid at 25° C.
From the viewpoint of visually improving color density of keratin substances and from the viewpoint of improving film formability and durability, the component (A) is preferably at least one selected from the group consisting of the following components (A1) and (A2).
(A1) A silicone resin represented by an average formula, (R1)mSiO(4·m)/2
wherein R1 represents a hydrocarbon group having 1 or more and 12 or less carbon atoms and optionally substituted with fluorine, or a hydroxy group, plural R1's can be the same as or different from each other, and m is an average number, representing a number of more than 0 and less than 3,
which contains at least one unit selected from the group consisting of a T unit represented by R1SiO3/2 and a Q unit represented by SiO4/2.
(A2) A silicone polymer containing a polysiloxane moiety and a moiety formed of a non-silicone organic chain.
Preferably, the component (A1) includes those containing at least one selected from the group consisting of the following component (A1-1) and component (A1-2).
(A1-1) A silicone resin represented by the above-mentioned average formula, containing a T unit represented by R1SiO3/2 and substantially not containing a Q unit represented by SiO4/2.
(A1-2) A silicone resin represented by the above-mentioned average formula, and containing a Q unit represented by SiO4/2 and an M unit represented by (R1)3SiO1/2.
Preferably, the component (A2) includes those containing at least one selected from the group consisting of the following component (A2-1) to (A2-4).
(A2-1) An acryl silicone polymer.
(A2-2) A silicone-modified alicyclic structure-containing polymer.
(A2-3) A silicone-modified pullulan.
(A2-4) A polyurea/urethane silicone.
The component (A1) is a silicone resin represented by an average formula, (R1)mSiO(4·m)/2
wherein R1 represents a hydrocarbon group having 1 or more and 12 or less carbon atoms and optionally substituted with fluorine, or a hydroxy group, plural R1's can be the same as or different from each other, and m is an average number, representing a number of more than 0 and less than 3,
which contains at least one unit selected from the group consisting of a T unit represented by R1SiO3/2 and a Q unit represented by SiO4/2.
The component (A1) is represented by the above-mentioned average formula and contains at least one unit selected from the above-mentioned T unit and Q unit, and therefore has a crosslinked structure in the molecule. Having the structure, the silicone resin is considered to be able to form a film having higher durability. The component (A1) does not contain a polyorganosiloxane cured product powder which is infusible and does not have a softening point and which is generally insoluble in an organic solvent.
In the average formula, R1 represents a hydrocarbon group having 1 or more and 12 or less carbon atoms and optionally substituted with fluorine, or a hydroxy group. The carbon number of the hydrocarbon group is, from the viewpoint of improving film formability and durability, 1 or more and preferably 9 or less, more preferably 6 or less, even more preferably 4 or less.
The hydrocarbon group may be any of an aliphatic group or an aromatic group, and examples thereof include an alkyl group, an alkenyl group, an aryl group and an aralkyl group. The alkyl group and the alkenyl group may be linear or branched.
Among the above, from the viewpoint of availability and stability, the hydrocarbon group is preferably an alkyl group, an aryl group or an aralkyl group.
The alkyl group includes a methyl group, an ethyl group, an n-propyl group, an isopropyl group, various butyl groups, various pentyl groups, various hexyl groups, various heptyl groups, various octyl groups, various nonyl group, various decyl groups, various undecyl groups, and various dodecyl groups. The word “various” means a linear or branched hydrocarbon group, and for example, “various butyl groups” include “an n-butyl group, a sec-butyl group, an isobutyl group and a tert-butyl group”.
The aryl group includes a phenyl group, a toluyl group, a dimethylphenyl group, and a naphthyl group, and is preferably a phenyl group.
The aralkyl group includes a benzyl group, a phenylethyl group, a phenylpropyl group, and a phenylbutyl group, and is preferably a phenylpropyl group.
In the case where R1 is substituted with fluorine, at least one hydrogen atom of the hydrocarbon group may be substituted with a fluorine atom.
R1 is, from the viewpoint of improving film formability and durability, preferably an optionally fluorine-substituted, alkyl group having 1 or more and 12 or less carbon atoms, aryl group having 6 or more and 12 or less carbon atoms or aralkyl group having 7 or more and 12 or less carbon atoms, more preferably an optionally fluorine-substituted, alkyl group having 1 or more and 8 or less carbon atoms or phenyl group, even more preferably an optionally fluorine-substituted, alkyl group having 1 or more and 6 or less carbon atoms or phenyl group. The fluorine-substituted alkyl group is preferably a group represented by CF3—R—wherein R represents an alkylene group having 2 or more and 7 or less carbon atoms, preferably 2 or more and 5 or less carbon atoms.
R1 is more preferably a trifluoropropyl group, an alkyl group having 1 or more and 4 or less carbon atoms, or a phenyl group, even more preferably a trifluoropropyl group, a methyl group, an ethyl group, an n-propyl group, an isopropyl group or an n-butyl group, further more preferably a trifluoropropyl group, a methyl group or an n-propyl group, and further more preferably a methyl group.
The component (A1) may contain at least one unit selected from the group consisting of a T unit represented by R1SiO3/2 and a Q unit represented by SiO4/2 and, from the viewpoint of improving film formability and durability, preferably further contains at least one unit selected from the group consisting of an M unit represented by (R1)3SiO1/2 and a D unit represented by (R1)2SiO2/2. R1 is the same as above.
From the viewpoint of visually improving color density of keratin substances, and from the viewpoint of improving film formability and durability, the component (A1) is preferably at least one selected from the group consisting of a silicone resin (A1-1) represented by the above-mentioned compositional formula, containing a T unit represented by R1SiO3/2 and substantially not containing a Q unit represented by SiO4/2, and a silicone resin (A1-2) represented by the above-mentioned compositional formula, and containing a Q unit represented by SiO4/2 and an M unit represented by (R1)3SiO1/2.
The silicone resin (A1-1) represented by the above-mentioned average formula, containing a T unit represented by R1SiO3/2 and substantially not containing a Q unit represented by SiO4/2 (hereinafter also referred to as “component (A1-1)”) is a silicone resin containing a T unit and may contain an M unit and a D unit, and is preferably a silicone resin containing a T unit and optionally containing an M unit, which is represented by [R1SiO3/2]n[(R1)3SiO1/2]b wherein a and b each are an average repeating unit number, and a>0 and b≥0. The wording “substantially not containing XX” means the constituent ratio of XX in the silicone resin is less than 1 mol %.
R1 is the same as above, and is preferably an alkyl group having 1 or more and 4 or less carbon atoms or a phenyl group, more preferably a methyl group, an ethyl group, an n-propyl group or an isopropyl group, even more preferably a methyl group, an n-propyl group or an isopropyl group.
The component (A1-1) includes polysilsesquioxanes such as polymethylsilsesquioxane, polypropylsilsesquioxane, polyphenylsilsesquioxane, polymethylphenylsilsesquioxane, and fluorine-modified alkyldimethylpolysilsesquioxanes, and among these, one or more can be used. Fluorine-modified alkyldimethylpolysilsesquioxanes include, as INCI nomenclature, trifluoropropyldimethylsiloxy/trimethylsiloxy)silsesquioxane.
Above all, from the viewpoint of visually improving color density of keratin substances, and from the viewpoint of improving film formability and durability, the component (A1-1) is preferably at least one selected from the group consisting of polymethylsilsesquioxane and polypropylsilsesquioxane.
Commercial products of the component (A1-1) include SilForm Flexible Resin (polymethylsilsesquioxane), SilForm FR-5 (polydimethylsiloxane solution of (trifluoropropyldimethylsiloxy/trimethylsiloxy)silsesquioxane) (all by Momentive Performance Materials Corporation), DOWSIL 680 ID Fluid (isododecane solution of 75 mass % polypropylsilsesquioxane) (by Day Toray Corporation), SR-21 (polyphenylsilsesquioxane), SR-23 (polyphenylsilsesquioxane), SR-33 (polymethylphenylsilsesquioxane) (all by Konishi Chemical Industry Co., Ltd.).
The silicone resin (A1-2) represented by the above-mentioned average formula, and containing a Q unit represented by SiO4/2 and an M unit represented by (R1)3SiO1/2 (hereinafter also referred to as “component (A1-2)” is a silicone resin substantially containing a Q unit and an M unit and optionally containing a D unit or a T unit, and is preferably a silicone resin represented by [SiO4/2]c[(R1)3SiO1/2]d wherein c and d each are an average repeating unit number and c>0 and d>0.
R1 is the same as above, and is preferably an optionally-fluorine substituted, alkyl group having 1 or more and 6 or less carbon atoms or phenyl group, more preferably a trifluoropropyl group, an alkyl group having 1 or more and 4 or less carbon atoms, or a phenyl group, even more preferably a trifluropropyl group, methyl group, an ethyl group, an n-propyl group, or an isopropyl group, further more preferably a trifluoropropyl group or a methyl group, and further more preferably a methyl group.
The component (A1-2) includes trimethylsiloxysilicate, phenylpropyldimethylsiloxysilicate, fluorine-modified alkyldimethylsiloxysilicates, and crosspolymers produced by crosslinking these siloxysilicates with dimethiconol, and at least one of these can be used. Fluorine-modified alkyldimethylsiloxysilicates include trifluoroalkyldimethyltrimethylsiloxysilicate, such as trifluoropropyldimethyltrimethylsiloxysilicate of, as ICNI nomenclature, trifluoropropyldimethyl/trimethylsiloxysilicate. Crosspolymers produced by crosslinking siloxysilicates with dimethiconol include, as ICNI nomenclature, (trimethylsiloxysilicate/dimethiconol) crosspolymer.
Above all, from the viewpoint of visually improving color density of keratin substances, and from the viewpoint of improving film formability and durability, the component (A1-2) is preferably at least one selected from the group consisting of trimethylsiloxysilicate, trifluoropropyldimethyltrimethylsiloxysilicate and (trimethylsiloxysilicate/dimethiconol) crosspolymer, more preferably at least one selected from the group consisting of trimethylsiloxysilicate, and trifluoropropyldimethyltrimethylsiloxysilicate, even more preferably trimethylsiloxysilicate.
Commercial products of trimethylsiloxysilicate of the component (A1-2) include KF-7312J (50 mass % decamethylcyclopentasiloxane solution), KF-9021 (50 mass % decamethylcyclopentasiloxane solution), X-21-5249(50 mass % decamethylcyclopentasiloxane solution), X-21-5595 (60 mass % isododecane solution), and X-21-5616 (60 mass % isododecane solution) (all by Shin-Etsu Chemical Industry Co., Ltd.), SS4267 (35 mass % dimethylpolysiloxane solution), SR1000, SS4230 (45 mass % cyclopentasiloxane solution), SS4267 (35 mass % dimethylpolysiloxane solution), and Silsoft 74 (75 mass % isododecane solution) (all by Momentive Performance Materials Corporation), BY11-018 (30 mass % cyclopentasiloxane solution), and MQ-1600 Solid Resin (all by Dow Toray Corporation), and BELSIL TMS 803 (by Wacker Asahi Kasei Silicone Co., Ltd.).
Commercial products of phenylpropyldimethylsiloxysilicate include SilShine 151 (by Momentive Performance Materials Corporation).
Commercial products of fluorine-modified alkyldimethylsiloxysilicates include, XS66-B8226 (50 mass % cyclopentasiloxane solution), XS66-C1191, and XS66-B8636 (50 mass % dimethicone solution) (all by Momentive Performance Materials Corporation), as INCI nomenclature, (trifluoropropyldimethyl/trimethylsiloxysilicate).
Commercial products of trimethylsiloxysilicate crosspolymer include DOWSIL FC-5002 IDD Resin Gum (40 mass % isododecane solution of (trimethylsiloxysilicate/dimethicol) crosspolymer) (by Dow Toray Corporation).
The component (A2) is a silicone polymer containing a polysiloxane moiety and a moiety formed of a non-silicone organic chain. The non-organic silicone organic monomer to constitute the moiety of a non-silicone organic chain is, from the viewpoint of availability on the market, preferably selectable from a radical-polymerizable ethylenically-unsaturated monomer, a polycondensation-polymerizable monomer (e.g., those to form polyamides, polyesters or polyurethanes), and a ring-cleavable monomer (e.g., oxazoline or caprolactone-type ones).
Preferably, the component (A2) includes those containing at least one selected from the group consisting of the following component (A2-1) to (A2-4), more preferably those containing the component (A2-1).
(A2-1) An acryl silicone polymer.
(A2-2) A silicone-modified alicyclic structure-containing polymer.
(A2-3) A silicone-modified pullulan.
(A2-4) A polyurea/urethane silicone.
The acryl silicone polymer of the component (A2-1) includes an acrylic polymer having a carbosiloxane dendrimer structure in the side chain, an acryl-silicone graft copolymer, and a graft-type copolymer or alternate block-type copolymer where a structural unit of a polysiloxane group and a structural unit of a polymer of an unsaturated monomer bond via a sulfide bond.
The acrylic polymer having a carbosiloxane dendrimer structure in the side chain includes a silicone dendrimer-acryl copolymer, and for example, can be produced according to the production method described in JP H11-1530 A and JP 2000-63225 A.
The acrylic polymer having a carbosiloxane dendrimer structure in the side chain is preferably, as INCI nomenclature, acrylates/polytrimethylsiloxymethacrylate copolymer. Commercial products thereof include DOWSIL FA 4001 CM Silicone Acrylate (30 mass % decamethylcyclopentasiloxane solution), DOWSIL FA 4002 ID Silicone Acrylate (40 mass % isododecane solution) (all by Dow Toray Corporation).
The acryl-silicone graft copolymer includes a radical polymer of an organopolysiloxane compound having a radical polymerizable group at one terminal of the molecular chain and a radical polymerizable monomer mainly composed of an acrylate and/or a methacrylate.
Examples of the radical polymer of an organopolysiloxane compound having a radical polymerizable group at one terminal of the molecular chain and a radical polymerizable monomer mainly composed of an acrylate and/or a methacrylate usable here include those described in JP H2-25411 A and JP H2-132141 A, and acryl-silicone graft copolymers described in JP H3-162442 A and JP 2003-104825 A.
The acryl-silicone graft copolymer is preferably, as INCI nomenclature, (acrylates/dimethicone) copolymer. Commercial products thereof include KP-545 (30 mass % decamethylcyclopentasiloxane solution), KP-549 (40 mass % methyltrimethicone solution), and KP-550 (40 mass % isododecane solution) (all by Shin-Etsu Chemical Industry Co., Ltd.).
The graft-type copolymer or alternate block-type copolymer where a structural unit of a polysiloxane group and a structural unit of a polymer of an unsaturated monomer bond via a sulfide bond include graft-type copolymers or alternate block-type copolymers described in JP H6-92825 A.
Above all, from the viewpoint of improving film formability and wash resistance, the component (A2-1) is preferably at least one selected from the group consisting of an acrylic polymer having a carbosiloxane dendrimer structure in the side chain and an acryl-silicone graft copolymer, more preferably at least one selected from (acrylates/polytrimethylsiloxymethacrylate) copolymer and (acrylates/dimethicone) copolymer.
Examples of the silicone-modified alicyclic structure-containing polymer include silicone-modified cyclic polyolefins, and preferred examples thereof include silicone-modified polynorbornenes represented by the following general formula (A2-2-1).
wherein R2 each independently represents an alkyl group having 1 or more and 12 or less carbon atoms, X represents a group represented by the following formula (i), a1 is an integer of 1 or more and 3 or less, b1 and c1 each are a repeating unit number, and are each independently an integer of 1 or more.
wherein R3 each independently represents a hydrocarbon group having 1 or more and 12 or less carbon atoms, and d1 is an integer of 1 or more and 5 or less.
In the general formula (A2-2-1), R2 is preferably a methyl group, an ethyl group, an n-propyl group, a butyl group or a pentyl group, more preferably a methyl
X is a group represented by the formula (i), and in the formula (i), R3 each are independently a hydrocarbon group having 1 or more and 12 or less carbon atoms. R3 is preferably an alkyl group having 1 or more and 12 or less or a phenyl group, more preferably an alkyl group having 1 or more and 3 or less carbon atoms, even more preferably a methyl group. d1 is an integer of 1 or more and 5 or less, and is, from the viewpoint of versatility, preferably d1=1. Specifically, X is preferably a trimethylsiloxy group.
a1 is an integer of 1 or more and 3 or less, and, for example, in the polymer, a repeating unit of a1=2 and a repeating unit of a1=3 may exist as mixed. From the viewpoint of versatility, a1 is preferably 3.
The proportion of b1 and c1 in the general formula (A2-2-1) is preferably b1/c1=20/80 to 90/10 (mol/mol), more preferably 30/70 to 80/20 (mol/mol), even more preferably 50/50 to 70/30 (mol/mol). The proportion of b1 and c1 can be determined by 1H-NMR measurement.
The silicone-modified polynorbornene is preferably a silicone-modified polynorbornene represented by the following general formula (A2-2-2).
wherein b1 and c1 are the same as above.
The silicone-modified polynorbornene represented by the general formula (A2-2-2) includes a compound of, as INCI nomenclature, (norbornene/tris(trimethylsiloxy)silylnorbornene copolymer).
Commercial products of the silicone-modified polynorbornene include NBN-30-ID (isododecane solution of (norbornene/tris(trimethylsiloxy)silylnorbornene) copolymer) (by Shin-Etsu Chemical Industry Co., Ltd.).
The silicone-modified pullulan includes a pullulan having a silicone structure in the side chain, and specifically preferred is a silicone-modified pullulan in which at least a part of the hydrogen atoms of the OH groups in pullulan are substituted with a group represented by the following general formula (ii).
—R4—SiXa1R23-a1 (ii)
wherein R4 represents a single bond or a divalent organic group, and R2, X and a1 are the same as above. From the viewpoint of versatility, X is preferably a trimethylsiloxyl group, and a1 is preferably 3.
In the general formula (ii), R4 is preferably a divalent organic group, more preferably a divalent group represented by the following general formula (iii) or (iv), even more preferably a divalent group represented by the general formula (iv).
wherein R5 represents an alkylene group having 1 or more and 10 or less carbon atoms, and examples thereof include a methylene group, an ethylene group, a trimethylene group, a propylene group and a butylene group. Among these, preferred are an ethylene group, a trimethylene group and a propylene group; and more preferred are a trimethylene group and a propylene group.
Commercial products of the silicone-modified pullulan include TSPL-30-ID (isododecane solution of tri(trimethylsiloxy)silylpropylcarbamate pullulan), and TSPL-30-D5 (cyclopentasiloxane solution of tri(trimethylsiloxy)silylpropylcarbamate pullulan) (all by Shin-Etsu Chemical Industry Co., Ltd.).
The polyurea/urethane silicone of the component (A2-4) includes a polysiloxane/polyurea/polyurethane block terpolymer. For example, it is a dimethylpolysiloxane/urea copolymer of “polyurea-dimethicone” as INCI nomenclature.
The polymer can be produced by copolymerization of an am-aminosilicone and a diisocyanate. Commercial products of the polyurea/urethane silicone include Wacker-Belsil UD 60, Wacker-Belsil UD 80, Wacker-Belsil UD 140 and Wacker-Belsil UD 200 (all by Wacker Corporation).
One or more can be used as the component (A). Among the above, from the viewpoint of visually improving color density of keratin substances, and from the viewpoint of improving film formability and durability, the component (A) preferably contains at least one selected from the group consisting of the component (A1), the component (A2-1) and the component (A2-2), more preferably at least one selected from the group consisting of the component (A1) and the component (A2-1), and even more preferably contains the component (A1), further more preferably the component (A1-2).
More specifically, from the viewpoint of visually improving color density of keratin substances, and from the viewpoint of improving film formability and durability, the component (A) preferably contains at least one selected from the group consisting of trimethylsiloxysilicate, phenylpropyldimethylsiloxysilicate, trifluoropropyldimethyltrimethylsiloxysilicate, (trimethylsiloxysilicate/dimethiconol) crosspolymer, polymethylsilsesquioxane, polypropylsilsesquioxane, (acrylates/polytrimethylsiloxymethacrylate) copolymer, (acrylates/dimethicone) copolymer, and (norbornene/tris(trimethylsiloxy)silylnorbornene) copolymer, more preferably contains at least one selected from the group consisting of trimethylsiloxysilicate, phenylpropyldimethylsiloxysilicate, trifluoropropyldimethyltrimethylsiloxysilicate, (trimethylsiloxysilicate/dimethiconol) crosspolymer, polymethylsilsesquioxane, polypropylsilsesquioxane, (acrylates/polytrimethylsiloxymethacrylate) copolymer, and (acrylates/dimethicone) copolymer, even more preferably contains at least one selected from the group consisting of trimethylsiloxysilicate, phenylpropyldimethylsiloxysilicate, trifluoropropyldimethyltrimethylsiloxysilicate, (trimethylsiloxysilicate/dimethiconol) crosspolymer, polymethylsilsesquioxane, and polypropylsilsesquioxane, further more preferably contains at least one selected from the group consisting of trimethylsiloxysilicate, trifluoropropyldimethyltrimethylsiloxysilicate, and (trimethylsiloxysilicate/dimethiconol) crosspolymer, further more preferably contains at least one selected from the group consisting of trimethylsiloxysilicate, and trifluoropropyldimethyltrimethylsiloxysilicate, further more preferably contains trimethylsiloxysilicate, and is further more preferably trimethylsiloxysilicate.
The cosmetic composition of the present invention contains, as the component (B), a high-molecular-weight organopolysiloxane having a degree of polymerization of 2,350 or more and 20,000 or less. The component (B) has a low refractive index, and when the cosmetic composition of the present invention is applied to a keratin substance such as skin or hair, the component is considered to visually improve the color density of keratin substances and to give a good feel.
The degree of polymerization of the component (B) is, from the viewpoint of visually improving color density of keratin substances, and from the viewpoint of imparting a good feel to the surfaces of keratin substances, preferably 2,500 or more, more preferably 2,600 or more, even more preferably 2,650 or more, further more preferably 2,700 or more, further more preferably 2,800 or more, further more preferably 2,900 or more, further more preferably 3,000 or more, further more preferably 3,100 or more, further more preferably 3,200 or more, and is, from the viewpoint of availability, preferably 20,000 or less, more preferably 15,000 or less, even more preferably 10,000 or less, further more preferably 7,000 or less, further more preferably 5,000 or less, further more preferably 4,500 or less, further more preferably 4,300 or less, further more preferably 4,200 or less, further more preferably 4,000 or less.
The specific range of the degree of polymerization of the component (B) is 2,350 to 20,000, preferably 2,500 to 15,000, more preferably 2,600 to 15,000, even more preferably 2,650 to 10,000, further more preferably 2,700 to 10,000, further more preferably 2,800 to 7,000, further more preferably 2,900 to 7,000, further more preferably 2,900 to 5,000, further more preferably 3,000 to 5,000, further more preferably 3,000 to 4,500, further more preferably 3,000 to 4,300, further more preferably 3,000 to 4,200, further more preferably 3,000 to 4,000, further more preferably 3,100 to 4,000, further more preferably 3,200 to 4,000.
More precisely, the component (B) is preferably an organopolysiloxane represented by the following general formula (1).
wherein R11 each independently represents a hydrocarbon group having 1 or more and 6 or less carbon atoms, R12 each independently represents a hydroxy group, an alkoxy group having 1 or more and 6 or less carbon atoms, or a hydrocarbon group having 1 or more and 6 or less carbon atoms, R13 represents a hydrocarbon group having 1 or more and 6 or less carbon atoms, or a primary to tertiary amino group-containing group, n indicates a degree of polymerization, and is a number of 2,350 or more and 20,000 or less, and n's R13's can be the same as or different from each other.
In the formula (1), the hydrocarbon group for RH may be any of an aliphatic group or an aromatic group, and examples thereof include an alkyl group, an alkenyl group and a phenyl group. The alkyl group and the alkenyl group may be any of linear or branched ones.
Among the above, RH is preferably an alkyl group having 1 or more and 6 or less carbon atoms, or a phenyl group, more preferably an alkyl group having 1 or more and 3 or less carbon atoms or a phenyl group, even more preferably a methyl group or a phenyl group, further more preferably a methyl group.
In the general formula (1), R12 each independently represent a hydroxy group, an alkoxy group having 1 or more and 6 or less carbon atoms, or a hydrocarbon group having 1 or more and 6 or less carbon atoms.
The alkoxy group for R12 includes a methoxy group, an ethoxy group, a propoxy group and a butoxy group.
The hydrocarbon group for R12 is the same as that for RH, and is preferably an alkyl group having 1 or more and 6 or less carbon atoms, or a phenyl group, more preferably an alkyl group having 1 or more and 3 or less carbon atoms, or a phenyl group, even more preferably a methyl group or a phenyl group, further more preferably a methyl group.
R12 is, from the viewpoint of imparting a good feel to the surfaces of keratin substances, preferably a hydroxy group, an alkyl group having 1 or more and 6 or less carbon atoms, or a phenyl group, more preferably a hydroxy group, an alkyl group having 1 or more and 3 or less carbon atoms, or a phenyl group, even more preferably a hydroxy group, a methyl group or a phenyl group, further more preferably a methyl group.
In the general formula (1), R13 represents a hydrocarbon group having 1 or more and 6 or less carbon atoms, or a primary to tertiary amino group-containing group.
The hydrocarbon group for R13 is the same as that for RH, and is preferably an alkyl group having 1 or more and 6 or less carbon atoms, or a phenyl group, more preferably an alkyl group having 1 or more and 3 or less carbon atoms, or a phenyl group, even more preferably a methyl group or a phenyl group, further more preferably a methyl group.
The primary to tertiary amino group-containing group (hereinafter also referred to simply as “amino group-containing group”) for R13 is preferably a group represented by —N(R14)2, —NR14(CH2)qN(R14)2, or —NR14(CH2)qN(R15)CO—R16. Here, R14 represents a hydrogen atom or a monovalent hydrocarbon group having 1 or more and 4 or less carbon atoms, and is preferably a hydrogen atom, a methyl group or an ethyl group. R15 represents a monovalent hydrocarbon group having 1 or more and 4 or less carbon atoms, and is preferably a methyl group or an ethyl group. R16 represents a monovalent hydrocarbon group having 1 or more and 4 or less carbon atoms. q indicates a number of 2 or more and 6 or less, and is preferably a number of 2 or more and 4 or less.
The amino group-containing group for R13 is preferably —(CH2)3—NH2, —(CH2)3—N(CH3)2, —(CH2)3—NH—(CH2)2—NH2, or —(CH2)2—NH—(CH2)2—N(CH3)2, more preferably —(CH2)3—NH2.
From the viewpoint of imparting a good feel to the surfaces of keratin substances, R13 is preferably a hydrocarbon group having 1 or more and 6 or less carbon atoms, more preferably an alkyl group having 1 or more and 6 or less carbon atoms or a phenyl group, even more preferably an alkyl group having 1 or more and 3 or less carbon atoms or a phenyl group, further more preferably a methyl group or a phenyl group, further more preferably a methyl group.
In the general formula (1), n indicates a degree of polymerization and is a number of 2,350 or more and 20,000 or less. From the viewpoint of visually improving the color density of keratin substances and from the viewpoint of imparting a good feel to the surfaces of keratin substances, n is preferably 2,500 or more, more preferably 2,600 or more, even more preferably 2,650 or more, further more preferably 2,700 or more, further more preferably 2,800 or more, further more preferably 2,900 or more, further more preferably 3,000 or more, further more preferably 3,100 or more, further more preferably 3,200 or more, and is, from the viewpoint of availability, preferably 20,000 or less, more preferably 15,000 or less, even more preferably 10,000 or less, further more preferably 7,000 or less, further more preferably 5,000 or less, further more preferably 4,500 or less, further more preferably 4,300 or less, further more preferably 4,200 or less, further more preferably 4,000 or less
A specific range of n in the general formula (1) is 2,350 to 20,000, and is preferably 2,500 to 15,000, more preferably 2,600 to 15,000, even more preferably 2,650 to 10,000, further more preferably 2,700 to 10,000, further more preferably 2,800 to 7,000, further more preferably 2,900 to 7,000, further more preferably 2,900 to 5,000, further more preferably 3,000 to 5,000, further more preferably 3,000 to 4,500, further more preferably 3,000 to 4,300, further more preferably 3,000 to 4,200, further more preferably 3,000 to 4,000, further more preferably 3,100 to 4,000, further more preferably 3,200 to 4,000.
The viscosity of the component (B) is, from the viewpoint of visually improving the color density of keratin substances, and from the viewpoint of imparting a good feel to the surfaces of keratin substances, preferably 1,500,000 mm2/s or more, more preferably, 2,000,000 mm2/s or more, even more preferably 3,000,000 mm2/s or more, further more preferably 5,000,000 mm2/s or more, further more preferably 8,000,000 mm2/s or more, further more preferably 10,000,000 or more. The upper limit of the viscosity of the component (B) is, from the viewpoint of availability, preferably 12,500 mm2/s or less, more preferably 80,000,000 mm2/s or less, even more preferably 50,000,000 mm2/s or less, further more preferably 40,000,000 mm2/s or less, further more preferably 35,000,000 mm2/s or less, further more preferably 30,000,000 mm2/s or less.
A specific range of the viscosity of the component (B) is preferably 1,500,000 to 125,000,000 mm2/s, more preferably 2,000,000 to 80,000,000 mm2/s, even more preferably 3,000,000 mm2/s to 80,000,000 mm2/s, further more preferably 5,000,000 to 80,000,000 mm2/s, further more preferably 8,000,000 to 80,000,000 mm2/s, further more preferably 10,000,000 to 80,000,000 mm2/s, further more preferably 10,000,000 to 50,000,000 mm2/s, further more preferably 10,000,000 to 40,000,000 mm2/s, further more preferably 10,000,000 to 35,000,000 mm2/s, further more preferably 10,000,000 to 30,000,000 mm2/s.
The viscosity is a value measured at 25° C. according to JIS Z8803:2011 “Method for Measurement of Viscosity of Liquid”. For example, using a suitable one selected from a capillary viscometer, a falling ball viscometer, a rotational viscometer and a vibration-type viscometer at 25° C., the viscosity can be measured. In the case where the viscosity oversteps an ordinary measurement range of a viscometer, it can be determined from a diluted solution of the component (B) according to the following method.
A toluene solution of the component (B) having a concentration of 1 g/100 mL is prepared, and a specific viscosity thereof qsp (25° C.) is calculated according to the following mathematical expression (1). Next, the resultant value is introduced into the Huggins relational expression represented by the following mathematical expression (2) to give an intrinsic viscosity [q]. Further, [η] is introduced into the expression by A. Kolorlov represented by the following mathematical expression (3) to give a molecular weight M. Finally, M is introduced into the expression by A. J. Barry represented by the following mathematical expression (4) to give a viscosity q of the component (B). (For example, see Silicone Oil KF-96 Performance Test Results 4.2, by Shin-Etsu Chemical Industry Co., Ltd.).
ηsp=(η/η0)·1 (1)
wherein η0 represents a viscosity of toluene, and η is a viscosity of the solution.
ηsp=[η]+K′[η]2 (2)
wherein the Hoggins' constant K′ is one described in Nakamuta, Nihon Kagakukai-shi, 77588 [1956].
[η]=0.215×10−4M0.65 (3)
logη=1.00+0.0123M0.5 (4)
Commercial products of the dimethylpolysiloxane used as the component (B) include X-21-5686 (viscosity 3,000,000 mm2/s), X-25-9074 (viscosity 30,000,000 mm2/s) (both by Shin-Etsu Chemical Industry Co., Ltd.), and Silsoft B3020 (viscosity 20,000,000 mm2/s) (by Momentive Performance Materials Corporation).
The component (B) is, from the viewpoint of visually improving color density of keratin substances, and from the viewpoint of imparting a good feel to the surfaces of keratin substances, preferably at least one selected from the group consisting of dimethylpolysiloxane, methylphenylpolysiloxane, aminopropylmethylpolysiloxane and dimethiconol, of which the degree of polymerization falls within the above-mentioned range, more preferably dimethylpolysiloxane of which the degree of polymerization falls within the range.
<Component (C): Cationic Group-Having Organopolysiloxane Other than the Component (A) and the Component (B)>
The cosmetic composition of the present invention contains, as the component (C), a cationic group-having organopolysiloxane other than the component (A) and the component (B). Since the component (C) has high adsorbability to keratin substances such as skin or hairs, it is considered that the component can firmly adhere the formed film to the surfaces of keratin substances, and owing to the synergistic effect with the component (A) and the component (B), can provide wash resistance of the formed film. In addition, since the component (C) also has a low refractive index, the component can contribute the effect of visually improving the color density of keratin substances.
The cationic group that the component (C) has includes a cation group or a group capable of being ionized to be a cation group. Specifically, the group includes a primary amino group, a secondary amino group, a tertiary amino group, and a quaternary ammonium group, and is, from the viewpoint of adsorbability to the surfaces of skin or hairs, preferably at least one selected from the group consisting of a primary amino group, a secondary amino group and a tertiary amino group.
The component (C) is, from the viewpoint of visually improving color density of keratin substances, and from the viewpoint of improving wash resistance of films owing to the synergistic effect with the component (A) and the component (B), preferably at least one selected from the group consisting of an amino-modified silicone (C1) and an aminopolyether-modified silicone (C2), more preferably an amino-modified silicone (C1).
In the present invention, the amino-modified silicone (C1) is a silicone having an amino group and not having a polyether moiety, other than the component (A) and the component (B), and is preferably a silicone represented by the following general formula (2).
wherein R11 each independently represents a hydrocarbon group having 1 or more and 6 or less carbon atoms, R12 each independently represents a hydroxy group, an alkoxy group having 1 or more and 6 or less carbon atoms, or a hydrocarbon group having 1 or more and 6 or less carbon atoms, R17 represents a primary to tertiary amino group-containing group, nc1 is a number of 0 or more, nc2 is a number of 1 or more, nc1+nc2 indicates a degree of polymerization and is a number of less than 2,350, nc2's R17's can be the same as or different from each other.
In the general formula (2), the hydrocarbon group for RH may be any of an aliphatic group or an aromatic group, and examples thereof include an alkyl group, an alkenyl group and a phenyl group. The alkyl group and the alkenyl group may be linear or branched.
Among the above, RH is preferably an alkyl group having 1 or more and 6 or less carbon atoms, or a phenyl group, more preferably an alkyl group having 1 or more and 3 or less carbon atoms, or a phenyl group, even more preferably a methyl group or a phenyl group, further more preferably a methyl group.
In the general formula (2), R12 each independently represents a hydroxy group, an alkoxy group having 1 or more and 6 or less carbon atoms, or a hydrocarbon group having 1 or more and 6 or less carbon atoms.
The alkoxy group for R12 includes a methoxy group, an ethoxy group, a propoxy group and a butoxy group.
The hydrocarbon group for R12 is the same as that for RH, and is preferably an alkyl group having 1 or more and 6 or less carbon atoms, or a phenyl group, more preferably an alkyl group having 1 or more and 3 or less carbon atoms, or a phenyl group, even more preferably a methyl group or a phenyl group, further more preferably a methyl group.
R12 is, from the viewpoint of visually improving color density of keratin substances, and from the viewpoint of improving wash resistance of films, preferably a hydroxy group, an alkyl group having 1 or more and 6 or less carbon atoms, or a phenyl group, more preferably a hydroxy group, an alkyl group having 1 or more and 3 or less carbon atoms, or a phenyl group, even more preferably a hydroxy group, a methyl group or a phenyl group, further more preferably a methyl group.
In the general formula (2), R17 represents a primary to tertiary amino group-containing group.
The primary to tertiary amino group-containing group for R17 is preferably a group represented by —N(R18)2, —NR18(CH2)qN(R18)2, or —NR18(CH2)qN(R19)CO—R20. Here, R18 represents a hydrogen atom or a monovalent hydrocarbon group having 1 or more and 4 or less carbon atoms, preferably a hydrogen atom, a methyl group or an ethyl group. R19 represents a monovalent hydrocarbon group having 1 or more and 4 or less carbon atoms, preferably a methyl group or an ethyl group. R20 represents a monovalent hydrocarbon group having 1 or more and 4 or less carbon atoms. q is a number of 2 or more and 6 or less, preferably a number of 2 or more and 4 or less.
The amino group-containing group for R17 is preferably —(CH2)3—NH2, —(CH2)3—N(CH3)2, —(CH2)3—NH—(CH2)2—NH2, or —(CH2)2—NH—(CH2)2—N(CH3)2, more preferably —(CH2)3—NH2, or —(CH2)3—NH—(CH2)2—NH2.
In the general formula (2), nc1 is a number of 0 or more, nc2 is a number of 1 or more, nc1+nc2 indicates a degree of polymerization and is a number of less than 2,350. From the viewpoint of visually improving color density of keratin substances, and from the viewpoint of improving wash resistance of films, nc1+nc2 is preferably 1 or more and less than 2,350.
Commercial products of the amino-modified silicone used as the component (C1) include KF-8004, KF-8005S (aminoethylaminopropylmethylsiloxane/dimethylsiloxane copolymer) (all by Shin-Etsu Chemical Industry Co., Ltd.) and XF42-B1989 (aminoethylaminopropylmethylsiloxane/dimethylsiloxane copolymer) (by Momentive Performance Materials Corporation).
In the present invention, the aminopolyether-modified silicone (C2) is a silicone having an amino group and a polyether moiety, other than the component (A) and the component (B). In the component (C2), the amino group and the polyether moiety can exist in the silicone main chain or can exist in the side chain part.
More specifically, the component (C2) is more preferably at least one selected from an aminopolyether-modified silicone (C2-1) having a repeating unit represented by the following general formula (3) and an aminopolyether-modified silicone (C2-2) having a repeating unit represented by the following general formula (4).
In the following description, the aminopolyether-modified silicone (C2-1) having a repeating unit represented by the general formula (3) may be referred to as “component (C2-1)”, and the aminopolyether-modified silicone (C2-2) having a repeating unit represented by the general formula (4) may be referred to as “component (C2-2)”.
The component (C2-1) is an aminopolyether-modified silicone having a repeating unit represented by the following general formula (3).
In the formula (3), R21 represents a monovalent hydrocarbon group having 1 or more and 6 or less carbon atoms, R22 represents any of R21 or E1, E1 represents a monovalent group represented by —R23—Z1 (where R23 represents a divalent hydrocarbon group having 1 or more and 6 or less carbon atoms, Z1 represents a primary to tertiary amino group-containing group), R24 represents a divalent hydrocarbon group having 1 or more and 6 or less carbon atoms, R25 represents a hydrogen atom or a monovalent hydrocarbon group having 1 or more and 4 or less carbon atoms.
e is a number of 1 or more and 50 or less, f is a number of 1 or more and 50 or less, g is a number of 1 or more and 50 or less, h is a number of 1 or more, j is a number of 2 or more and 100 or less, p is a number of 2 or more and 10 or less. The bonding order of the parenthesized structural units is not limited, and the bonding form thereof may be in a block form or a random form. j's (OCpH2p)s can be the same or different. Plural R21's, R22's, R24's, R25's and E1's can be the same or different.
In the general formula (3), R21 represents a monovalent hydrocarbon group having 1 or more and 6 or less carbon atoms, and is preferably an alkyl group having 1 or more and 6 or less carbon atoms, or a phenyl group, more preferably a methyl group or an ethyl group, even more preferably a methyl group. R22 is any of R21 or E1, and is preferably R21.
In the general formula (3), E1 represents a monovalent group represented by —R23—Z1 (where R23 represents a divalent hydrocarbon group having 1 or more and 6 or less carbon atoms, Z1 represents a primary to tertiary amino group-containing group). R23 is preferably a divalent hydrocarbon group having 2 or more and 4 or less carbon atoms, more preferably an ethylene group, a trimethylene group, a propylene group or a tetramethylene group.
Z1 is a primary to tertiary amino group-containing group, and is preferably a group represented by —N(R26)2, —NR26(CH2)qN(R26)2, or —NR26(CH2)qN(R27)CO—R28. Here, R26 represents a hydrogen atom or a monovalent hydrocarbon group having 1 or more and 4 or less carbon atoms, preferably a hydrogen atom, a methyl group or an ethyl group. R27 represents a monovalent hydrocarbon group having 1 or more and 4 or less carbon atoms, and is preferably a methyl group or an ethyl group. R28 represents a monovalent hydrocarbon group having 1 or more and 4 or less carbon atoms. q is a number of 2 or more and 6 or less, and is preferably a number of 2 or more and 4 or less.
In the general formula (3), the group E1 is preferably —(CH2)3—NH2, —(CH2)3—N(CH3)2, —(CH2)3—NH—(CH2)2—NH2, or —(CH2)2—NH—(CH2)2—N(CH3)2, more preferably —(CH2)3—NH2, or —(CH2)3—NH—(CH2)2—NH2.
In the general formula (3), R24 is a divalent hydrocarbon group having 1 or more and 6 or less carbon atoms, preferably a divalent hydrocarbon group having 2 or more and 4 or less carbon atoms, more preferably an ethylene group, a trimethylene group, a propylene group or a tetramethylene group.
R25 is a hydrogen atom or a monovalent hydrocarbon group having 1 or more and 4 or less carbon atoms, and is preferably a methyl group or an ethyl group.
In the general formula (3), e is a number of 1 or more and 50 or less, f is a number of 1 or more and 50 or less, g is a number of 1 or more and 50 or less, h is a number of 1 or more, j is a number of 2 or more and 100 or less. p is a number of 2 or more and 10 or less, preferably 2 or more and 6 or less, more preferably 2 or more and 4 or less.
In particular, the component (C2-1) is more preferably one represented by the following general formula (3-1).
In the formula (3-1), E1, R24, R25, e, f, and g are the same as above, R29 represents a monovalent hydrocarbon group having 1 or more and 4 or less carbon atoms, or a trimethylsilyl group, k is a number of 1 or more and 50 or less, 1 is a number of 0 or more and 50 or less, and is preferably 1 or more and 50 or less.
R29 is preferably a methyl group, an ethyl group or a trimethylsilyl group, more preferably a trimethylsilyl group.
As the component (C2-1), one or more can be used either singly or as combined.
As the component (C2-1), commercially-available aminopolyether-modified silicones can be used. Examples thereof include ABIL Soft AF10 (aminopolyether-modified silicone represented by the general formula (3-1) (methoxy PEG/PPG-7/3 aminopropyl dimethicone)) (by Evonik Corporation).
The component (C2-2) is an aminopolyether-modified silicone having a repeating unit represented by the following general formula (4).
In the formula (4), R31 represents a monovalent hydrocarbon group having 1 or more and 6 or less carbon atoms, R32 represents any of R31 or E2, E2 represents a monovalent group represented by —R33—Z2 (where R33 represents a single bond, or a divalent hydrocarbon group having 1 or more and 20 or less carbon atoms, Z2 represents a primary to tertiary amino group-containing group), Y represents a single bond, or a divalent group having 1 or more and 12 or less carbon atoms. In the case where all R32's are R31's, at least one Y is an amino group-containing divalent group. In the case where all Y's are divalent groups not containing an amino group, at least one R32 is E2. r is a number of 1 or more, s is a number of 1 or more, t is a number of 2 or more and 100 or less, u is a number of 1 or more. p is the same as above, and is a number of 2 or more and 10 or less. The bonding order of the parenthesized structural units is not limited, and the bonding form thereof may be in a block form or a random form. t's (CpH2pO)s can be the same or different. Plural R31's, R32's, E2's and Y's can be the same or different.
In the general formula (4), R31 represents a monovalent hydrocarbon group having 1 or more and 6 or less carbon atoms, and is independently preferably an alkyl group having 1 or more and 6 or less carbon atoms, or a phenyl group, more preferably a methyl group or an ethyl group, even more preferably a methyl group.
In the general formula (4), R32 is any of R31 or E2. E2 represents a monovalent group represented by —R33—Z2 (where R33 represents a single bond, or a divalent hydrocarbon group having 1 or more and 20 or less carbon atoms).
R33 is preferably a divalent hydrocarbon group having 1 or more and 20 or less carbon atoms, more preferably an alkylene group having 1 or more and 20 or less carbon atoms, even more preferably a linear or branched alkylene group having 1 or more and 6 or less carbon atoms, further more preferably a methylene group, an ethylene group, a trimethylene group, a propylene group, a tetramethylene group, or a hexamethylene group, further more preferably a trimethylene group or a propylene group.
Z3 is a primary to tertiary amino group-containing group, and is preferably an amino group-containing group represented by —N(R34)2, —NR34(CH2)qN(R34)2, or —NR34(CH2N(R35)CO—R36. Here, R34 and R35 each independently represent a hydrogen atom or an alkyl group having 1 or more and 3 or less carbon atoms, preferably a hydrogen atom or a methyl group. R36 represents an alkyl group having 1 or more and 3 or less carbon atoms, q is a number of 1 or more and 6 or less, and is preferably a number of 2 or more and 4 or less.
In the general formula (4), the group E2 is preferably —(CH2)3—NH2, —(CH2)3—N(CH3)2, —(CH2)3—NH—(CH2)2—NH2, or —(CH2)2—NH—(CH2)2—N(CH3)2, more preferably —(CH2)3—NH2, or —(CH2)3—NH—(CH2)2—NH2.
In the general formula (4), Y is a single bond, or a divalent group having 1 or more and 12 or less carbon atoms. The divalent group having 1 or more and 12 or less carbon atoms is preferably an alkylene group having 1 or more and 6 or less carbon atoms, an alkyleneoxy group having 1 or more and 6 or less carbon atoms, or a divalent group represented by —R37—O—CH2—CH(OH)—CH2—N(R38)—R39—O— of an amino group-containing divalent group. Here, R37 and R39 each independently represent an alkylene group having 1 or more and 6 or less carbon atoms, preferably an alkylene group having 2 or more and 4 or less carbon atoms, more preferably a propylene group. R38 represents a hydrogen atom or an alkyl group having 1 or more and 3 or less carbon atoms.
In the general formula (4), the alkylene group having 1 or more and 6 or less carbon atoms and the alkylene group in the alkyleneoxy group having 1 or more and 6 or less carbon atoms for Y are preferably an ethylene group, a propylene group, a trimethylene group, an n-butylene group (tetramethylene group) or an isobutylene group, more preferably an n-butylene group or an isobutylene group. The isobutylene group as referred to herein includes —CH(CH3)CH2CH2—, —CH2CH(CH3)CH2—, and —CH2CH2CH(CH3)—.
In the general formula (4), r is a number of 1 or more, s is a number of 1 or more, t is a number of 2 or more and 100 or less, u is a number of 1 or more. r is preferably a number of 1 or more and 1000 or less, more preferably a number of 2 or more and 200 or less. s is preferably a number of 1 or more and 100 or less, t is preferably a number of 4 or more and 80 or less, more preferably 10 or more and 50 or less, u is preferably a number of 1 or more and 300 or less, more preferably a number of 1 or more and 150 or less.
In the general formula (4), p is a number of 2 or more and 10 or less, preferably 2 or more and 6 or less, more preferably 2 or more and 4 or less.
The component (C2-2) is more preferably at least one selected from the group consisting of an aminopolyether-modified silicone having a structure represented by the following general formula (4-1) and an aminopolyether-modified silicone having a structure represented by the following general formula (4-2). Even more preferably, the component is at least one selected from the group consisting of an aminopolyether-modified silicone composed of a structure represented by the following general formula (4-1) and an aminopolyether-modified silicone composed of a structure represented by the following general formula (4-2), further more preferably an aminopolyether-modified silicone composed of a structure represented by the following general formula (4-1).
In the formula (4-1), r, s, t and u are the same as above.
In the formula (4-2), R38, r, s and u are the same as above. v is a number of 0 or more and 50 or less, preferably 2 or more and 50 or less. w is a number of 2 or more and 100 or less. v+w is a number of 2 or more and 100 or less, preferably 4 or more and 80 or less, more preferably 10 or more and 50 or less.
As the component (C2-2), one or more can be used either singly or as combined.
As the component (C2-2), commercially-available aminopolyether-modified silicones can be used. Examples thereof include, as the aminopolyether-modified silicone having a structure represented by the general formula (4-1), DOWSIL SS-3588 Fluid ((bisisobutyl-PEG-15/amodimethicone) copolymer), DOWSIL SILSTYLE 104 ((bisisobutyl-PEG-14/amodimethicone) copolymer), DOWSIL SILSTYLE 201 ((bisisobutyl-PEG-14/amodimethicone) copolymer), DOWSIL SILSTYLE 401((bisisobutyl PEG/PPG-20/35/amodimethicone) copolymer) (all by Dow Toray Corporation), and include, as the aminopolyether-modified silicone having a structure represented by the general formula (4-2), Silsoft A+(PEG-40/PPG-8 methylaminopropyl/hydroxypropyldimethicone copolymer) (by Momentive Performance Materials Corporation).
As the component (C), one or more of the above can be used either singly or as combined. In particular, from the viewpoint of visually improving color density of keratin substances, and from the viewpoint of improving wash resistance of films, the component (C) is preferably at least one selected from the group consisting of an amino-modified silicone (C1) of the above general formula (2) and an aminopolyether-modified silicone (C2-2) having a repeating unit represented by the above general formula (4), more preferably an amino-modified silicone (C1) of the above general formula (2).
The content of the component (A) in the cosmetic composition is, from the viewpoint of improving film formability and durability, preferably 0.1% by mass or more, more preferably 0.5% by mass or more, even more preferably 1% by mass or more, further more preferably 2% by mass or more, further more preferably 3% by mass or more, and is, from the viewpoint of imparting a good feel to the surfaces of keratin substances such as skin or hair, preferably 30% by mass or less, more preferably 25% by mass or less, even more preferably 20% by mass or less, further more preferably 15% by mass or less. A specific range of the content of the component (A) in the cosmetic composition of the present invention is preferably 0.1 to 30% by mass, more preferably 0.5 to 25% by mass, even more preferably 1 to 20% by mass, further more preferably 2 to 15% by mass, further more preferably 3 to 15% by mass.
The content of the component (B) in the cosmetic composition is, from the viewpoint of visually improving color density of keratin substances, and from the viewpoint of imparting a good feel to the surfaces of keratin substances, and also from the viewpoint of improving sustainability of various effects after washing, preferably 0.1% by mass or more, more preferably 0.3% by mass or more, even more preferably 0.5% by mass or more, further more preferably 1% by mass or more, and is, from the viewpoint of imparting a good feel to the surfaces of keratin substances, preferably 20% by mass or less, more preferably 15% by mass or less, even more preferably 10% by mass or less, further more preferably 8% by mass or less. A specific range of the content of the component (B) in the cosmetic composition of the present invention is preferably 0.1 to 20% by mass, more preferably 0.5 to 15% by mass, even more preferably 1 to 10% by mass, further more preferably 1 to 8% by mass.
The content of the component (C) in the cosmetic composition is, from the viewpoint of visually improving color density of keratin substances, preferably 0.01% by mass or more, more preferably 0.05% by mass or more, even more preferably 0.1% by mass or more, further more preferably 0.5% by mass or more. Also from the viewpoint of improving wash resistance of films, the content is preferably 10% by mass or less, more preferably 5% by mass or less, even more preferably 3% by mass or less. A specific range of the content of the component (C) in the cosmetic composition of the present invention is preferably 0.01 to 20% by mass, more preferably 0.05 to 15% by mass, even more preferably 0.1 to 10% by mass, further more preferably 0.5 to 5% by mass, further more preferably 0.5 to 3% by mass.
The total content of the components (A) to (C) in the cosmetic composition of the present invention is, from the viewpoint of visually improving color density of keratin substances, and from the viewpoint of improving sustainability of various effects after washing, 2% by mass or more, preferably 4% by mass or more, more preferably 5% by mass or more, even more preferably 6% by mass or more. Also from the viewpoint of providing a good feel, the total content is preferably 50% by mass or less, more preferably 35% by mass or less, even more preferably 25% by mass or less. A specific range of the total content of the components (A) to (C) in the cosmetic composition of the present invention is 2 to 50% by mass, preferably 4 to 35% by mass, more preferably 4 to 25% by mass, even more preferably 5 to 25% by mass, further more preferably 6 to 25% by mass.
A ratio of the content by mass of the component (A) to the total content by mass of the component (A) and the component (B) in the cosmetic composition of the present invention, [(A)/((A)+(B))] is, from the viewpoint of providing a good feel and from the viewpoint of improving sustainability of various effects after washing, preferably 50% or more, more preferably 55% or more, even more preferably 60% or more, and is preferably 95% or less, more preferably 90% or less, even more preferably 80% or less. A specific range of the ratio of the content by mass of the component (A) to the total content by mass of the component (A) and the component (B) in the cosmetic composition of the present invention, [(A)/((A)+(B))] is, preferably 50 to 95%, more preferably 55 to 90%, even more preferably 60 to 80%.
A ratio of the content by mass of the component (C) to the total content by mass of the components (A) to (C) in the cosmetic composition of the present invention, [(C)/((A)+(B)+(C))] is, from the viewpoint of visually improving color density of keratin substances and from the viewpoint of providing a good feel, preferably 0.01% or more, more preferably 0.2% or more, even more preferably 1% or more, further more preferably 5% or more, and is, from the viewpoint of improving sustainability of various effects after washing, preferably 85% or less, more preferably 75% or less, even more preferably 50% or less, further more preferably 40% or less, further more preferably 30% or less. A specific range of the ratio of the content by mass of the component (C) to the total content by mass of the components (A) to (C) in the cosmetic composition of the present invention, [(C)/((A)+(B)+(C))] is, preferably 0.01 to 85%, more preferably 0.2 to 85%, even more preferably 1 to 75%, further more preferably 1 to 50%, further more preferably 5 to 50%, further more preferably 5 to 40%, further more preferably 5 to 30%.
The cosmetic composition of the present invention can further contain a functional powder as a component (D), depending on the product form thereof.
In the present invention, the functional powder means a powder capable of providing various characteristics such as coloring performance, concealing performance, gloss, UV scattering, and feel controlling. In the case where the cosmetic composition of the present invention is a sunscreen cosmetic material, preferably, a UV scattering agent is incorporated therein as the component (D), from the viewpoint of providing a desired sunscreen effect. In the case where the cosmetic composition of the present invention is a makeup cosmetic composition or a hair dye composition, preferably, a pigment is incorporated therein as the component (D), from the viewpoint of providing a desired color tone.
As the UV scattering agent, preferably usable is at least one metal oxide powder selected from the group consisting of zinc oxide, titanium oxide and cerium oxide. An average particle size of the fine particle metal oxide powder is, from the viewpoint of UV protective effect, preferably 10 to 500 nm, more preferably 12 to 100 nm, even more preferably 15 to 50 nm. The average particle size can be measured according to a laser diffraction/scattering method.
The pigment may be any pigment generally used in makeup cosmetic materials and hair dye compositions, and examples thereof include a white inorganic pigment such as titanium oxide, zinc oxide, cerium oxide and barium sulfate; a colored inorganic pigment such as yellow iron oxide, black iron oxide, red iron oxide, carbon black, chromium oxide, chromium hydroxide, Prussian blue and ultramarine blue; a luster powder such as titanium oxide-coated mica, titanium oxide-coated bismuth oxychloride, iron oxide-coated mica titanium, iron oxide mica, Prussian blue-processed mica titanium, carmine-processed mica titanium, bismuth oxychloride, and fish scale guanine; an organic pigment such as Red No. 201, Red No. 202, Red No. 205, Red No. 226, Red No. 228, Orange No. 203, Orange No. 204, Blue No. 404, and Yellow No. 401; a chelate pigment such as a zirconium, barium or aluminum chelate of Red No. 3, Red No. 104, Red No. 106, Orange No. 205, Yellow No. 4, Yellow No. 5, Green No. 3 or Blue No. 1; and a composite pigment such as fine particle titanium oxide-coated mica titanium, fine particle zinc oxide-coated mica titanium, barium sulfate-coated mica titanium, titanium oxide-containing silicone dioxide and zinc oxide-containing silicon dioxide. One or more of these can be used either singly or as combined. Those prepared by coating the surfaces of these functional powders with various surface treatment agents are also usable. The surface treatment agent is not specifically limited. Various surface treatments can be applied to the powders, and examples thereof include fluorine compound treatment, silicone treatment, silicone resin treatment, pendant treatment, silane coupling agent treatment, titanium coupling agent treatment, oil treatment, metal soap treatment, N-acylated lysine treatment, polyethylene glycol treatment, PVA treatment, polyacrylic acid treatment, hyaluronic acid treatment, alginic acid treatment, inorganic compound treatment, plasma treatment and mechanochemical treatment.
In the case where the cosmetic composition of the present invention contains the component (D), the content thereof is, from the viewpoint of providing desired performance, preferably 0.01% by mass or more in the cosmetic composition, more preferably 0.1% by mass or more, even more preferably 0.2% by mass or more, further more preferably 0.3% by mass or more, and is, from the viewpoint of dispersibility in the cosmetic composition and economic efficiency, and from the viewpoint of maintaining a good feel, preferably 50% by mass or less, more preferably 30% by mass or less. A specific range of the content of the component (D) in the cosmetic composition of the present invention is preferably 0.01 to 50% by mass, more preferably 0.1 to 50% by mass, even more preferably 0.2 to 30% by mass, further more preferably 0.3 to 30% by mass.
<Component (E): solvent>
From the viewpoint of dissolving or dispersing the components (A) to (C) and other components, and from the viewpoint of controlling the viscosity to be easily applicable to keratin substances such as skin or hair, the cosmetic composition of the present invention can further contain a solvent as a component (E).
The solvent is, from the viewpoint of easy handleability, preferably a liquid organic solvent, including an alcohol solvent, an ether solvent, a ketone solvent, an ester solvent, a hydrocarbon solvent and a silicone solvent, and these can be appropriately selected depending on the formulation form. Among these, from the viewpoint of bettering sense of use after drying (from the viewpoint of reducing stickiness), a volatile solvent is preferably contained.
Among volatile solvents, the alcohol solvent includes ethanol, 1-propanol, 2-propanol, 1-butanol, 2-butanol and benzyl alcohol; the ether solvent includes diethyl ether, and tetrahydrofuran; the ketone solvent includes acetone, and methyl ethyl ketone; the ester solvent includes methyl acetate, ethyl acetate, butyl acetate, and isobutyl acetate; the hydrocarbon solvent includes light liquid isoparaffin (containing, as a main component, isoparaffin having 8 to 16 carbon atoms), pentane, isopentane, hexane, isohexene, heptane, isoheptane, decane, isodecane, dodecane, isododecane, tetradecane, isotetradecane, tridecane, and isotridecane; the silicone solvent includes a cyclic silicone such as decamethylcyclopentasiloxane, dimethylpolysiloxane having a viscosity of 10 mm2/s or less at 25° C., alkyltrimethicone such as methyltrimethicone, and methylphenylpolysiloxane having a viscosity of 20 mm2/s or less at 25° C. One or more of these can be used.
From solubility of the components (A) to (C) therein, the component (E) preferably contains at least one selected from the group consisting of dimethylpolysiloxane having a viscosity of 10 mm2/s or less at 25° C., methyltrimethicone, methylphenylpolysiloxane having a viscosity of 20 mm2/s or less at 25° C., pentane, isopentane, hexane, isohexene, heptane, isoheptane, decane, isodecane, dodecane, isododecane, tridecane, isotridecane, tetradecane, isotetradecane and light liquid isoparaffin, more preferably at least one selected from the group consisting of dimethylpolysiloxane having a viscosity of 5 mm2/s or less at 25° C., methyltrimethicone, isodecane, isododecane, isotetradecane and light liquid isoparaffin, even more preferably at least one selected from the group consisting of isodecane, isododecane, isotetradecane and light liquid isoparaffin. The viscosity is measured according to the above-mentioned measurement method.
From the viewpoint of maintaining good solubility of the components (A) to (C) therein, and from the viewpoint of controlling speed for film formation, the component (E) preferably contains a volatile alcohol solvent and at least one of a volatile hydrocarbon solvent or a volatile silicone solvent, more preferably contains at least one selected from the group consisting of ethanol, 1-propanol, 2-propanol, 1-butanol and 2-butanol, and at least one selected from the group consisting of dimethylpolysiloxane having a viscosity of 10 mm2/s or less at 25° C., methyltrimethicone, methylphenylpolysiloxane having a viscosity of 20 mm2/s or less at 25° C., pentane, isopentane, hexane, isohexene, heptane, isoheptane, decane, isodecane, dodecane, isododecane, tridecane, isotridecane, tetradecane, isotetradecane, and light liquid isoparaffin, even more preferably contains ethanol and at least one selected from the group consisting of dimethylpolysiloxane having a viscosity of 5 mm2/s or less at 25° C., methyltrimethicone, isodecane, isododecane, isotetradecane and light liquid isoparaffin, further more preferably contains ethanol and at least one selected from the group consisting of isodecane, isododecane, isotetradecane and light liquid isoparaffin.
In the case where the cosmetic composition of the present invention contains the component (E), the content thereof is, from the viewpoint of dissolving or dispersing the components (A) to (C) and other components, preferably 1% by mass or more in the cosmetic composition, more preferably 10% by mass or more, even more preferably 20% by mass or more, further more preferably 40% by mass or more, further more preferably 50% by mass or more, and is, from the viewpoint of controlling the viscosity of the cosmetic composition to be easily applicable to skin or hair, preferably 97% by mass or less, more preferably 95% by mass or less, further more preferably 90% by mass or less. A specific range of the content of the component (E) in the cosmetic composition of the present invention is preferably 1 to 97% by mass, more preferably 10 to 97% by mass, even more preferably 20 to 97% by mass, further more preferably 40 to 97% by mass, further more preferably 50 to 97% by mass, further more preferably 50 to 95% by mass, further more preferably 50 to 90% by mass.
The cosmetic composition of the present invention can contain components generally used in cosmetic compositions, for example, an oily agent other than the above-mentioned components, an antioxidant, a fragrance, a colorant, a dye, a preservative, a thickener, a pH regulator, a blood circulation promoter, a cooling sensation agent, an antiperspirant, a bactericide, a skin activator, a moisturizer and a refrigerant, in addition to the above-mentioned components.
The cosmetic composition of the present invention can be produced according to an ordinary method.
From the viewpoint of visually improving color density of keratin substances, from the viewpoint of providing a good feel, and from the viewpoint of improving sustainability of various effects after washing, the water content in the cosmetic composition of the present invention is 10% by mass or less, preferably 5% by mass or less, more preferably less than 5% by mass, even more preferably less than 2% by mass.
From the viewpoint of visually improving color density of keratin substances, from the viewpoint of providing a good feel, and from the viewpoint of improving sustainability of various effects after washing, the content of the solid oil in the cosmetic composition of the present invention is preferably small. The solid oil is an oil that is solid at 25° C., and includes a solid paraffin such as paraffin wax, a polyolefin wax such as polyethylene wax, and beeswax. The content is preferably less than 50% by mass in the cosmetic composition, more preferably less than 20% by mass, even more preferably less than 10% by mass, further more preferably less than 5% by mass, further more preferably less than 1% by mass.
In the cosmetic composition of the present invention, the content of a nonvolatile liquid oily agent except the component (B) and the component (C) is preferably smaller, from the viewpoint of visually improving color density of keratin substances, from the viewpoint of providing a good feel, and from the viewpoint of improving sustainability of various effects after washing. The nonvolatile liquid oily agent is an oily agent that has a boiling point of higher than 260° C. under normal pressure and is liquid at 25° C., and examples thereof include a nonvolatile liquid silicone except the component (B) and the component (C); a triglyceride such as glyceryl trioctanoate, avocado oil, olive oil, sesame oil, rice bran oil, safflower oil, soybean oil, corn oil, rapeseed oil, castor oil, cotton seed oil, and mink oil; a fatty acid such as oleic acid and isostearic acid; an ester oil such as isopropyl myristate, butyl myristate, isopropyl palmitate, ethyl oleate, ethyl linoleate, isopropyl linoleate, cetyl caprylate, hexyl laurate, decyl myristate, decyl oleate, oleyl oleate, isostearyl laurate, isotridecyl myristate, isocetyl myristate, isostearyl myristate, octyl dodecyl myristate, octyl palmitate, isocetyl palmitate, isostearyl palmitate, isodecyl oleate, isopropyl isostearate, cetyl 2-ethylhexanoate, stearyl 2-ethylhexanoate, propylene glycol dicaprylate, propylene glycol dioleate, glyceryl tri-2-ethylhexanoate, glyceryl tri(caprate/caprylate), isononyl isononanoate, diisopropyl sebacate, propylene glycol isostearate, 2-ethylhexyl paramethoxycinnamate, 2-ethoxyethyl paramethoxycinnamate, isopropyl paramethoxycinnamate/diisopropylcinnamate mixture, methylbis(trimethylsiloxy)silylisopentyl trimethoxycinnamate, amyl paradimethylaminobenzoate, 2-ethylhexyl paradimethylaminobenzoate, ethylene glycol salicylate, 2-ethylhexyl salicylate, benzyl salicylate, homomenthyl salicylate, octocrylene, and dimethyldiethylbenzal malonate; and a branched or unsaturated higher alcohol such as 2-octyldodecanol, isostearyl alcohol, and oleyl alcohol. The content thereof is, in the cosmetic composition, preferably less than 50% by mass, more preferably less than 40% by mass, even more preferably less than 30% by mass, further more preferably less than 20% by mass, further more preferably less than 10% by mass.
From the viewpoint of visually improving color density of keratin substances, from the viewpoint of providing a good feel, and from the viewpoint of improving sustainability of various effects after washing, the content of a polyalcohol in the cosmetic composition of the present invention is preferably small. The polyalcohol includes a polyalcohol having a boiling point of higher than 260° C. under normal pressure, and examples thereof include propylene glycol and glycerin. The content is preferably less than 5% by mass in the cosmetic composition, more preferably less than 2% by mass, even more preferably less than 1% by mass, further more preferably less than 0.5% by mass, further more preferably less than 0.1% by mass.
The formulation form of the cosmetic composition of the present invention is not specifically limited, and depending on the product form thereof, the cosmetic composition can have various formation forms such as liquid, paste, cream, gel, foam, spray and wax. From the viewpoint of temporal stability of the components (A) to (C), the cosmetic composition of the present invention is preferably a waterless composition. Here, the waterless composition means a composition having a water content of less than 1% by mass, preferably less than 0.5% by mass, more preferably less than 0.1% by mass.
The cosmetic composition of the present invention includes various skin cosmetic compositions, eyebrow or eyelash makeup compositions and hair cosmetic compositions.
The skin cosmetic composition includes various skin cosmetic compositions for makeup, foundation, skincare, sunscreen, etc.
The eyebrow or eyelash makeup composition includes various eyebrow or eyelash makeup compositions such as mascara, mascara base coat, mascara topcoat, and eyebrow mascara.
The hair cosmetic composition includes a hair wash composition such as shampoo, as well as a rinse composition, a conditioner composition, a treatment composition (including non-washing type), a styling composition, a hair dye composition, and a hair tonic composition. Among these, from the viewpoint of visually improving color density of keratin substances, from the viewpoint of providing a good feel, and from the viewpoint of improving sustainability of various effects after washing, preferred are a conditioner composition, a treatment composition, a styling composition and a hair dye composition.
The above-mentioned composition is preferably a so-called leave-on preparation that is used without washing after application to keratin substances such as skin, eyebrow, eyelash or hair.
From the viewpoint that the cosmetic composition of the present invention can promptly form a film excellent in wash resistance on the surfaces of keratin substances, the present invention also provides a treatment method for keratin substances, including a step of applying the cosmetic composition to a keratin substance and then drying it.
The keratin substance includes skin, eyebrow, eyelash, hair and nails, and is preferably skin, eyelash, eyebrow or hair, more preferably hair. The keratin substance to which the cosmetic composition is applied may be in any of a dry state or wet state, but from the viewpoint of attaining the effects of the present invention, the cosmetic composition is preferably applied to a keratin substance in a dry state.
From the viewpoint of uniform application, and from the viewpoint of improving the uniformity of the structure of the film to be formed, it is preferable that the cosmetic composition of the present invention is temporarily compatibilized or dispersed prior to application to keratin substances, and then applied to the surfaces of keratin substances. As the temporarily compatibilizing or dispersing method, arbitrarily employable is any of a thermodynamical method of heating, a physical method of mechanically imparting shear stress, or a chemical method of adding a compatible solvent. From the viewpoint of user-friendliness, preferably, the cosmetic composition is uniformly compatibilized or dispersed by a physical method of stirring or shaking.
In the case where the cosmetic composition of the present invention is a skin cosmetic composition, or an eyebrow or eyelash cosmetic composition, preferably, the composition is applied to skin, eyebrow or eyelash and then spontaneously dried. From the viewpoint of maintaining various effects of the skin cosmetic composition, it is preferable that the composition is not washed off after drying, and is used as a leave-on preparation.
The skin cosmetic composition and the eyebrow or eyelash cosmetic composition is, after applied to skin, preferably dried before being brought into contact with clothes and other articles. The drying time is not specifically limited so far as, after the skin cosmetic composition has been applied, it can substantially form a film on the surface of skin, eyebrow or eyelash, and the time can be appropriately controlled depending on the coating amount and the coating area, and preferably, the formed film is dried for 4 minutes or less, more preferably 2 minutes or less.
In the case where the cosmetic composition of the present invention is a hair cosmetic composition, from the viewpoint of promptly forming a film excellent in wash resistance on the surface of hair, it is preferable that the application process includes a step of applying the composition to hair and then drying it. From the viewpoint of maintaining various effects of the hair cosmetic composition, it is preferable that the composition is applied to hair in a dry state and then dried, and is used as a leave-on preparation that is not washed off after application. Drying the hair after application of the hair cosmetic composition thereto may be spontaneous drying, or the hair may be dried using a device such as a hair drier hood, a hand hair drier, or a straight iron.
In the case of using the device, preferably, the hair is dried at a temperature of 40 to 220° C. from the viewpoint of suppressing thermal damages of keratin substances. More preferred is drying with a hair drier hood or a hand hair drier, and the drying temperature is preferably 40 to 110° C., more preferably 50 to 90° C.
The drying time is not specifically limited so far as a film is substantially formed on the surface of hair, and can be appropriately controlled depending on the amount and the quality of hair. For example, the time may fall within a range of 10 seconds to 120 minutes.
After drying, the hair may be brushed for scattering the hair.
In the treatment method of the present invention, the amount of the cosmetic composition to be applied to keratin substances is not specifically limited. In the case of a skin cosmetic composition, in general, the amount falls within a range of 0.1 to 1000 mg per cm2 of skin. In the case of an eyebrow or eyelash cosmetic composition or a hair cosmetic composition, in general, the amount falls within a range of 0.005 to 1 g per gram of eyebrow, eyelash or hair.
From the viewpoint of promptly forming a film excellent in wash resistance on the surfaces of keratin substances, the present invention further provides a hair dyeing method that includes a step of applying the hair dye composition of the present invention to hair and then drying it.
The hair dye composition of the present invention is applied to hair and then dried, and is used without washing. Drying the hair after applying the hair dye composition thereto may be spontaneous drying, or the hair may be dried with a drier or the like.
By the above-mentioned simple operation, the hair dye composition of the present invention can temporarily or semi-permanently dye hair as an out-bath treatment. In addition, the composition can give a good feel to hair, and even after shampooing, the good feel can be sustained as such.
After drying, the hair can be brushed for scattering.
The above-mentioned components (A) to (C) can be mixed before use to prepare the cosmetic composition of the present invention and can be applied to keratin substances such as skin or hair. For example, the present invention can also provide a cosmetic kit provided with at least two compositions, wherein the cosmetic composition obtained by mixing the compositions constituting the cosmetic kit contains the following components (A) to (C).
Namely, the cosmetic kit of the present invention is a cosmetic kit provided with at least two compositions, wherein the cosmetic composition obtained by mixing all the compositions constituting the cosmetic kit contains the following components (A) to (C). From the viewpoint of visually improving color density of keratin substances, from the viewpoint of providing a good feel, and from the viewpoint of improving sustainability of various effects after washing, preferably, the cosmetic kit is preferably such that the total content of the following components (A) to (C) in the cosmetic composition obtained by mixing all the constituent components is 2% by mass or more and 50% by mass or less, and the water content therein is 10% by mass or less.
(A) A silicone film-forming agent.
(B) A high-molecular-weight organopolysiloxane having a degree of polymerization of 2,350 or more and 20,000 or less.
(C) An organopolysiloxane containing a cationic group other than the component (A) and the component (B).
Specifically, the present invention provides the following cosmetic kits 1 to 4, but is not limited thereto. The cosmetic kit of the present invention may be further provided with a composition not containing any of the components (A) to (C).
A cosmetic kit provided with the following compositions (I), (II) and (III).
(I) A composition containing (A) a silicone film-forming agent.
(II) A composition containing (B) a high-molecular-weight organopolysiloxane having a degree of polymerization of 2,350 or more and 20,000 or less.
(III) A composition containing (C) a cationic group-containing organopolysiloxane other than the component (A) and the component (B).
A cosmetic kit provided with the following compositions (IV) and (V).
(IV) A composition containing (A) a silicone film-forming agent, and (B) a high-molecular-weight organopolysiloxane having a degree of polymerization of 2,350 or more and 20,000 or less.
(V) A composition containing (C) a cationic group-containing organopolysiloxane other than the component (A) and the component (B).
(Cosmetic Kit 3)
A cosmetic kit provided with the following compositions (VI) and (VII).
(VI) A composition containing (A) a silicone film-forming agent.
(VII) A composition containing (B) a high-molecular-weight organopolysiloxane having a degree of polymerization of 2,350 or more and 20,000 or less, and (C) a cationic group-containing organopolysiloxane other than the component (A) and the component (B).
A cosmetic kit provided with the following compositions (VIII) and (IV).
(VIII) A composition containing (A) a silicone film-forming agent, and (C) a cationic group-containing organopolysiloxane other than the component (A) and the component (B).
(IX) A composition containing (B) a high-molecular-weight organopolysiloxane having a degree of polymerization of 2,350 or more and 20,000 or less.
The components (A), (B) and (C) used in the cosmetic kit and preferred embodiments thereof are the same as those described hereinabove for the cosmetic composition. From the viewpoint of visually improving color density of keratin substances, from the viewpoint of providing a good feel, and from the viewpoint of improving sustainability of various effects after washing, preferably, the total content of the components (A) to (C) in the cosmetic composition obtained by mixing all the compositions constituting the cosmetic kit is 2% by mass or more and 50% by mass or less and the water content therein is 10% by mass or less.
The compositions constituting the cosmetic kit can optionally contain, as needed, the functional powder (D), the solvent (E) and other optional components exemplified hereinabove for the cosmetic composition.
The concentration of each composition constituting the cosmetic kit is not specifically limited, but preferably, the content and the ratio of the components (A), (B) and (C) in the cosmetic composition obtained by mixing all the compositions constituting the cosmetic kit can fall within the range described hereinabove for the cosmetic composition.
Before use, all the compositions constituting the cosmetic kit of the present invention are mixed and used.
Regarding the above-mentioned embodiments, the present invention discloses the following.
<1>
A cosmetic composition containing:
(A) a silicone film-forming agent,
(B) a high-molecular-weight organopolysiloxane having a degree of polymerization of 2,350 or more and 20,000 or less, and
(C) an organopolysiloxane containing a cationic group other than the component (A) and the component (B), wherein:
the total content of the components (A) to (C) in the cosmetic composition is 2% by mass or more and 50% by mass or less, and the water content is 10% by mass or less.
<2>
A cosmetic composition containing:
(A) 0.1 to 25% by mass of a silicone resin represented by an average formula, (R1)mSiO(4·m)/2
wherein R1 represents a hydrocarbon group having 1 or more and 12 or less carbon atoms and optionally substituted with fluorine, or a hydroxy group, plural R1's can be the same as or different from each other, and m is an average number, representing a number of more than 0 and less than 3,
which contains a Q unit represented by SiO4/2 and an M unit represented by (R1)3SiO1/2,
(B) 0.1 to 20% by mass of an organopolysiloxane represented by the following general formula (1),
wherein R11 each independently represents a hydrocarbon group having 1 or more and 6 or less carbon atoms, R12 each independently represents a hydroxy group, an alkoxy group having 1 or more and 6 or less carbon atoms, or a hydrocarbon group having 1 or more and 6 or less carbon atoms, R13 represents a hydrocarbon group having 1 or more and 6 or less carbon atoms, or a primary to tertiary amino group-containing group, n indicates a degree of polymerization, and is a number of 2,500 to 15,000, and n's R13's can be the same as or different from each other,
(C) an organopolysiloxane containing at least one cationic group selected from the group consisting of a primary amino group, a secondary amino group and a tertiary amino group, other than the component (A) and the component (B), wherein:
the total content of the components (A) to (C) in the cosmetic composition is 2% by mass or more and 50% by mass or less, and
the ratio by mass of the content of the component (C) to the total content of the components (A) to (C) in the cosmetic composition, [(C)/((A)+(B)+(C))], is 5% or more and 50% or less, and
the water content is 10% by mass or less.
<3>
A cosmetic composition containing:
(A) 0.1 to 25% by mass of a silicone resin represented by an average formula, (R1)mSiO(4·m)/2
wherein R1 represents a hydrocarbon group having 1 or more and 12 or less carbon atoms and optionally substituted with fluorine, or a hydroxy group, plural R1's can be the same as or different from each other, and m is an average number, representing a number of more than 0 and less than 3, which contains a Q unit represented by SiO4/2 and an M unit represented by (R1)3SiO1/2,
(B) 0.1 to 20% by mass of an organopolysiloxane represented by the following general formula (1),
wherein R11 each independently represents a hydrocarbon group having 1 or more and 6 or less carbon atoms, R12 each independently represents a hydroxy group, an alkoxy group having 1 or more and 6 or less carbon atoms, or a hydrocarbon group having 1 or more and 6 or less carbon atoms, R13 represents a hydrocarbon group having 1 or more and 6 or less carbon atoms, or a primary to tertiary amino group-containing group, n indicates a degree of polymerization, and is a number of 3,000 to 5,000 or less, and n's R13's can be the same as or different from each other,
(C) an organopolysiloxane containing a cationic group other than the component (A) and the component (B), wherein:
the total content of the components (A) to (C) in the cosmetic composition is 4% by mass or more and 25% by mass or less, and
the ratio by mass of the content of the component (C) to the total content of the components (A) to (C) in the cosmetic composition, [(C)/((A)+(B)+(C))], is 5% or more and 40% or less, and
the water content is 10% by mass or less.
<4>
A cosmetic composition containing:
(B) 0.1 to 20% by mass of an organopolysiloxane represented by the following general formula (1),
wherein R11 each independently represents a hydrocarbon group having 1 or more and 6 or less carbon atoms, R12 each independently represents a hydroxy group, an alkoxy group having 1 or more and 6 or less carbon atoms, or a hydrocarbon group having 1 or more and 6 or less carbon atoms, R13 represents a hydrocarbon group having 1 or more and 6 or less carbon atoms, or a primary to tertiary amino group-containing group, n indicates a degree of polymerization, and is a number of 2,500 to 15,000 or less, and n's R13's can be the same as or different from each other,
(C) 0.01 to 25% by mass of at least one selected from an amino-modified silicone represented by the following general formula (2) and an aminopolyether-modified silicone having a repeating unit represented by the following general formula (3),
wherein R11 each independently represents a hydrocarbon group having 1 or more and 6 or less carbon atoms, R12 each independently represents a hydroxy group, an alkoxy group having 1 or more and 6 or less carbon atoms, or a hydrocarbon group having 1 or more and 6 or less carbon atoms, R17 represents a primary to tertiary amino group-containing group, nc1 is a number of 0 or more, nc2 is a number of 1 or more, nc1+nc2 indicates a degree of polymerization and is a number of less than 2,350, nc2's R17's can be the same as or different from each other,
wherein R21 represents a monovalent hydrocarbon group having 1 or more and 6 or less carbon atoms, R22 represents any of R21 or E1, E1 represents a monovalent group represented by —R23—Z1 (where R23 represents a divalent hydrocarbon group having 1 or more and 6 or less carbon atoms, Z1 represents a primary to tertiary amino group-containing group), R24 represents a divalent hydrocarbon group having 1 or more and 6 or less carbon atoms, R25 represents a hydrogen atom or a monovalent hydrocarbon group having 1 or more and 4 or less carbon atoms,
e is a number of 1 or more and 50 or less, f is a number of 1 or more and 50 or less, g is a number of 1 or more and 50 or less, h is a number of 1 or more, j is a number of 2 or more and 100 or less, p is a number of 2 or more and 10 or less, the bonding order of the parenthesized structural units is not limited, and the bonding form thereof may be in a block form or a random form, j's (OCpH2p)s can be the same or different, plural R21'S, R22'S, R24'S, R25'S and E1's can be the same or different, wherein:
the total content of the components (A) to (C) in the cosmetic composition is 2% by mass or more and 50% by mass or less,
the ratio by mass of the content of the component (C) to the total content of the components (A) to (C) in the cosmetic composition, [(C)/((A)+(B)+(C))], is 5% or more and 50% or less, and
the water content is 10% by mass or less.
<5>
A cosmetic composition containing:
(A) 0.1 to 25% by mass of a silicone resin represented by [SiO4/2]c[(R1)3SiO1/2]d wherein c and d each are an average repeating unit number and c>0 and d>0,
(B) 0.1 to 20% by mass of an organopolysiloxane represented by the following general formula (1),
wherein R11 each independently represents a hydrocarbon group having 1 or more and 6 or less carbon atoms, R12 each independently represents a hydroxy group, an alkoxy group having 1 or more and 6 or less carbon atoms, or a hydrocarbon group having 1 or more and 6 or less carbon atoms, R13 represents a hydrocarbon group having 1 or more and 6 or less carbon atoms, or a primary to tertiary amino group-containing group, n indicates a degree of polymerization, and is a number of 3,000 or more and 5,000 or less, and n's R13'S can be the same as or different from each other,
(C) 0.01 to 25% by mass of at least one selected from an amino-modified silicone represented by the following general formula (2), an aminopolyether-modified silicone having a repeating unit represented by the following general formula (3), and an aminopolyether-modified silicone having a repeating unit represented by the following general formula (4),
wherein R11 each independently represents a hydrocarbon group having 1 or more and 6 or less carbon atoms, R12 each independently represents a hydroxy group, an alkoxy group having 1 or more and 6 or less carbon atoms, or a hydrocarbon group having 1 or more and 6 or less carbon atoms, R17 represents a primary to tertiary amino group-containing group, nc1 is a number of 0 or more, nc2 is a number of 1 or more, nc1+nc2 indicates a degree of polymerization and is a number of less than 2,350, nc2's R17's can be the same as or different from each other,
wherein R21 represents a monovalent hydrocarbon group having 1 or more and 6 or less carbon atoms, R22 represents any of R21 or E1, E1 represents a monovalent group represented by —R23—Z1 (where R23 represents a divalent hydrocarbon group having 1 or more and 6 or less carbon atoms, Z1 represents a primary to tertiary amino group-containing group), R24 represents a divalent hydrocarbon group having 1 or more and 6 or less carbon atoms, R25 represents a hydrogen atom or a monovalent hydrocarbon group having 1 or more and 4 or less carbon atoms,
e is a number of 1 or more and 50 or less, f is a number of 1 or more and 50 or less, g is a number of 1 or more and 50 or less, h is a number of 1 or more, j is a number of 2 or more and 100 or less, p is a number of 2 or more and 10 or less, the bonding order of the parenthesized structural units is not limited, and the bonding form thereof may be in a block form or a random form, j's (OCpH2p)s can be the same or different, plural R21'S, R22'S, R24'S, R25'S and E1's can be the same or different,
wherein R31 represents a monovalent hydrocarbon group having 1 or more and 6 or less carbon atoms, R32 represents any of R31 or E2, E2 represents a monovalent group represented by —R33—Z2 (where R33 represents a single bond, or a divalent hydrocarbon group having 1 or more and 20 or less carbon atoms, Z2 represents a primary to tertiary amino group-containing group), Y represents a single bond, or a divalent group having 1 or more and 12 or less carbon atoms, in the case where all R32'S are R31's, at least one Y is an amino group-containing divalent group, in the case where all Y's are divalent groups not containing an amino group, at least one R32 is E2,
r is a number of 1 or more, s is a number of 1 or more, t is a number of 2 or more and 100 or less, u is a number of 1 or more, p is the same as above, and is a number of 2 or more and 10 or less, the bonding order of the parenthesized structural units is not limited, and the bonding form thereof may be in a block form or a random form, t's (CpH2pO)s can be the same or different, plural R31's, R32's, E2's and Y's can be the same or different, wherein:
the total content of the components (A) to (C) in the cosmetic composition is 4% by mass or more and 25% by mass or less,
the ratio by mass of the content of the component (C) to the total content of the components (A) to (C) in the cosmetic composition, [(C)/((A)+(B)+(C))], is 5% or more and 40% or less, and
the water content is 10% by mass or less.
<6>
The cosmetic composition according to <1>, wherein the component (A) is at least one selected from the group consisting of the following components (A1) and (A2),
(A1) a silicone resin represented by an average formula, (R1)mSiO(4·m)/2
wherein R1 represents a hydrocarbon group having 1 or more and 12 or less carbon atoms and optionally substituted with fluorine, or a hydroxy group, plural R1's can be the same as or different from each other, and m is an average number, representing a number of more than 0 and less than 3,
which contains at least one unit selected from the group consisting of a T unit represented by R1SiO3/2 and a Q unit represented by SiO4/2,
(A2) a silicone polymer containing a polysiloxane moiety and a moiety formed of a non-silicone organic chain.
<7>
The cosmetic composition according to <6>, wherein the component (A1) contains at least one selected from the group consisting of the following component (A1-1) and component (A1-2),
(A1-1) a silicone resin represented by the above-mentioned average formula, containing a T unit represented by R1—SiO4/2 and substantially not containing a Q unit represented by SiO4/2,
(A1-2) a silicone resin represented by the above-mentioned average formula, and containing a Q unit represented by SiO4/2 and an M unit represented by (R1)3SiO1/2.
<8>
The cosmetic composition according to <6> or <7>, wherein the component (A2) contains at least one selected from the group consisting of the following components (A2-1) and component (A2-4),
(A2-1) an acryl silicone polymer,
(A2-2) a silicone-modified alicyclic structure-containing polymer,
(A2-3) a silicone-modified pullulan,
(A2-4) a polyurea/urethane silicone.
<9>
The cosmetic composition according to any one of <6> to <8>, wherein the component (A1) contains the component (A1-2).
<10>
The cosmetic composition according to any one of <6> to <9>, wherein the component (A2) contains the acryl silicone polymer (A2-1).
<11>
The cosmetic composition according to any one of <1>, and <6> to <10>, wherein the component (A) contains at least one selected from the group consisting of trimethylsiloxysilicate, phenylpropyldimethylsiloxysilicate, trifluoropropyldimethyltrimethylsiloxysilicate, (trimethylsiloxysilicate/dimethiconol) crosspolymer, polymethylsilsesquioxane, polypropylsilsesquioxane, (acrylates/polytrimethylsiloxymethacrylate) copolymer, (acrylates/dimethicone) copolymer, and (norbornene/tris(trimethylsiloxy)silylnorbornene) copolymer, preferably contains at least one selected from the group consisting of trimethylsiloxysilicate, phenylpropyldimethylsiloxysilicate, trifluoropropyldimethyltrimethylsiloxysilicate, (trimethylsiloxysilicate/dimethiconol) crosspolymer, polymethylsilsesquioxane, polypropylsilsesquioxane, (acrylates/polytrimethylsiloxymethacrylate) copolymer, and (acrylates/dimethicone) copolymer, more preferably contains at least one selected from the group consisting of trimethylsiloxysilicate, phenylpropyldimethylsiloxysilicate, trifluoropropyldimethyltrimethylsiloxysilicate, (trimethylsiloxysilicate/dimethiconol) crosspolymer, polymethylsilsesquioxane, and polypropylsilsesquioxane, even more preferably contains at least one selected from the group consisting of trimethylsiloxysilicate, trifluoropropyldimethyltrimethylsiloxysilicate, and (trimethylsiloxysilicate/dimethiconol) crosspolymer, further more preferably contains at least one selected from the group consisting of trimethylsiloxysilicate, and trifluoropropyldimethyltrimethylsiloxysilicate, further more preferably contains trimethylsiloxysilicate, and is further more preferably trimethylsiloxysilicate.
<12>
The cosmetic composition according to any one of <1>, and <6> to <11>, wherein the component (B) is an organopolysiloxane represented by the following general formula (1),
wherein R11 each independently represents a hydrocarbon group having 1 or more and 6 or less carbon atoms, R12 each independently represents a hydroxy group, an alkoxy group having 1 or more and 6 or less carbon atoms, or a hydrocarbon group having 1 or more and 6 or less carbon atoms, R13 represents a hydrocarbon group having 1 or more and 6 or less carbon atoms, or a primary to tertiary amino group-containing group, n indicates a degree of polymerization, and is a number of 2,350 to 20,000 or less, and n's R13's can be the same as or different from each other.
<13>
The cosmetic composition according to <2> or <12>, wherein the degree of polymerization in the general formula (1) is preferably 2,500 to 15,000, more preferably 2,600 to 15,000, even more preferably 2,650 to 10,000, further more preferably 2,700 to 10,000, further more preferably 2,800 to 7,000, further more preferably 2,900 to 7,000, further more preferably 2,900 to 5,000, further more preferably 3,000 to 5,000, further more preferably 3,000 to 4,500, further more preferably 3,000 to 4,300, further more preferably 3,000 to 4,200, further more preferably 3,000 to 4,000, further more preferably 3,100 to 4,000, further more preferably 3,200 to 4,000.
<14>
The cosmetic composition according to any one of <1>, <3> and <6> to <13>, wherein the cationic group in the component (C) is at least one selected from the group consisting of a primary amino group, a secondary amino group and a tertiary amino group.
<15>
The cosmetic composition according to any one of <1> to <3> and <6> to <14>, wherein the component (C) is at least one selected from the group consisting of an amino-modified silicone (C1) having an amino group and not having a polyether moiety other than the component (A) and the component (B), and an aminopolyether-modified silicone (C2) having an amino group and a polyether moiety other than the component (A) and the component (B).
<16>
The cosmetic composition according to <15>, wherein the component (CO is a silicone represented by the following general formula (2),
wherein R11 each independently represents a hydrocarbon group having 1 or more and 6 or less carbon atoms, R12 each independently represents a hydroxy group, an alkoxy group having 1 or more and 6 or less carbon atoms, or a hydrocarbon group having 1 or more and 6 or less carbon atoms, R17 represents a primary to tertiary amino group-containing group, nc1 is a number of 0 or more, nc2 is a number of 1 or more, nc1+nc2 indicates a degree of polymerization and is a number of less than 2,350, nc2's R17's can be the same as or different from each other.
<17>
The cosmetic composition according to <15> or <16>, wherein the component (C2) is at least one selected from an aminopolyether-modified silicone (C2-1) having a repeating unit represented by the following general formula (3), and an aminopolyether-modified silicone (C2-2) having a repeating unit represented by the following general formula (4),
wherein R21 represents a monovalent hydrocarbon group having 1 or more and 6 or less carbon atoms, R22 represents any of R21 or E1, E1 represents a monovalent group represented by —R23—Z1 (where R23 represents a divalent hydrocarbon group having 1 or more and 6 or less carbon atoms, Z1 represents a primary to tertiary amino group-containing group), R24 represents a divalent hydrocarbon group having 1 or more and 6 or less carbon atoms, R25 represents a hydrogen atom or a monovalent hydrocarbon group having 1 or more and 4 or less carbon atoms,
e is a number of 1 or more and 50 or less, f is a number of 1 or more and 50 or less, g is a number of 1 or more and 50 or less, h is a number of 1 or more, j is a number of 2 or more and 100 or less, p is a number of 2 or more and 10 or less, the bonding order of the parenthesized structural units is not limited, and the bonding form thereof may be in a block form or a random form, j's (OCpH2p)s can be the same or different, plural R21's, R22's, R24's, R25's and E1's can be the same or different,
wherein R31 represents a monovalent hydrocarbon group having 1 or more and 6 or less carbon atoms, R32 represents any of R31 or E2, E2 represents a monovalent group represented by —R33—Z2 (where R33 represents a single bond, or a divalent hydrocarbon group having 1 or more and 20 or less carbon atoms, Z2 represents a primary to tertiary amino group-containing group), Y represents a single bond, or a divalent group having 1 or more and 12 or less carbon atoms, in the case where all R32's are R31's, at least one Y is an amino group-containing divalent group, in the case where all Y's are divalent groups not containing an amino group, at least one R32 is E2,
r is a number of 1 or more, s is a number of 1 or more, t is a number of 2 or more and 100 or less, u is a number of 1 or more, p is the same as above, and is a number of 2 or more and 10 or less, the bonding order of the parenthesized structural units is not limited, and the bonding form thereof may be in a block form or a random form, t's (CpH2pO)s can be the same or different, plural R31'S, R32'S, E2'S and Y's can be the same or different.
<18>
The cosmetic composition according to any one of <15> to <17>, wherein the component (C2) is an aminopolyether-modified silicone (C2-2) having a repeating unit represented by the general formula (4).
<19>
The cosmetic composition according to <17> or <18>, wherein the component (C2-1) is an aminopolyether-modified silicone represented by the following general formula (3-1),
wherein E1, R24, R25, e, f, and g are the same as above, R29 represents a monovalent hydrocarbon group having 1 or more and 4 or less carbon atoms, or a trimethylsilyl group, k is a number of 1 or more and 50 or less, 1 is a number of 0 or more and 50 or less, and is preferably 1 or more and 50 or less.
<20>
The cosmetic composition according to any one of <17> to <19>, wherein the component (C2-2) is at least one selected from the group consisting of an aminopolyether-modified silicone having a structure represented by the following general formula (4-1) and an aminopolyether-modified silicone having a structure represented by the following general formula (4-2),
wherein r, s, t and u are the same as above,
wherein R38, r, s and u are the same as above, v is a number of 0 or more and 50 or less, preferably 2 or more and 50 or less, w is a number of 2 or more and 100 or less, v+w is a number of 2 or more and 100 or less, preferably 4 or more and 80 or less, more preferably 10 or more and 50 or less.
<21>
The cosmetic composition according to <20>, wherein the component (C2-2) is an aminopolyether-modified silicone composed of a structure of the general formula (4-1).
<22>
The cosmetic composition according to any one of <1> and <6> to <21>, wherein the ratio by mass of the content of the component (C) to the total content of the components (A) to (C) in the cosmetic composition, [(C)/((A)+(B)+(C))], is preferably 0.01 to 85%, more preferably 0.2 to 85%, even more preferably 1 to 75%, further more preferably 1 to 50%, further more preferably 5 to 50%, further more preferably 5 to 40%, further more preferably 5 to 30%.
<23>
The cosmetic composition according to any one of <1> and <6> to <22>, wherein the ratio by mass of the content of the component (A) to the total content of the components (A) and (B) in the cosmetic composition, [(A)/((A)+(B))], is preferably 50 to 95%, more preferably 55 to 90%, even more preferably 60 to 80%.
<24>
The cosmetic composition according to any one of <1> and <6> to <23>, wherein the total content of the components (A) to (C) in the cosmetic composition is preferably 4 to 35% by mass, more preferably 4 to 25% by mass, even more preferably 5 to 25% by mass, further more preferably 6 to 25% by mass.
<25>
The cosmetic composition according to any one of <1> to <24>, wherein the content of the component (A) in the cosmetic composition is preferably 0.1 to 30% by mass, more preferably 0.5 to 25% by mass, even more preferably 1 to 20% by mass, further more preferably 2 to 15% by mass, further more preferably 3 to 15% by mass.
<26>
The cosmetic composition according to any one of <1> to <25>, wherein the content of the component (B) in the cosmetic composition is preferably 0.1 to 20% by mass, more preferably 0.5 to 15% by mass, even more preferably 1 to 10% by mass, further more preferably 1 to 8% by mass.
<27>
The cosmetic composition according to any one of <1> to <26>, wherein the content of the component (C) in the cosmetic composition is preferably 0.01 to 20% by mass, more preferably 0.05 to 15% by mass, even more preferably 0.1 to 10% by mass, further more preferably 0.5 to 5% by mass, further more preferably 0.5 to 3% by mass.
<28>
The cosmetic composition according to any one of <1> to <27>, further containing a functional powder as a component (D).
<29>
The cosmetic composition according to <28>, wherein the content of the component (D) in the cosmetic composition is preferably 0.01 to 50% by mass, more preferably 0.1 to 50% by mass, even more preferably 0.2 to 30% by mass, further more preferably 0.3 to 30% by mass.
<30>
The cosmetic composition according to any one of <1> to <29>, further containing a solvent as a component (E).
<31>
The cosmetic composition according to <30>, wherein the component (E) contains at least one selected from the group consisting of dimethylpolysiloxane having a viscosity at 25° C. of 10 mm2/s or less, methyltrimethicone, methylphenylpolysiloxane having a viscosity of 20 mm2/s or less at 25° C. pentane, isopentane, hexane, isohexene, heptane, isoheptane, decane, isodecane, dodecane, isododecane, tetradecane, isotetradecane, tridecane, isotridecane, and light liquid isoparaffin, preferably at least one selected from the group consisting of dimethylpolysiloxane having a viscosity of 5 mm2/s or less at 25° C., methyltrimethicone, isodecane, isododecane, isotetradecane and light liquid isoparaffin, more preferably at least one selected from the group consisting of isodecane, isododecane, isotetradecane and light liquid isoparaffin.
<32>
The cosmetic composition according to <30> or <31>, wherein the component (E) preferably contains a volatile alcohol solvent and at least one of a volatile hydrocarbon solvent or a volatile silicone solvent, more preferably contains at least one selected from the group consisting of ethanol, 1-propanol, 2-propanol, 1-butanol and 2-butanol, and at least one selected from the group consisting of dimethylpolysiloxane having a viscosity at of 10 mm2/s or less at 25° C., methyltrimethicone, methylphenylpolysiloxane having a viscosity of 20 mm2/s or less at 25° C., pentane, isopentane, hexane, isohexene, heptane, isoheptane, decane, isodecane, dodecane, isododecane, tetradecane, isotetradecane, tridecane, isotridecane, and light liquid isoparaffin, even more preferably contains ethanol and at least one selected from the group consisting of dimethylpolysiloxane having a viscosity of 5 mm2/s or less at 25° C., methyltrimethicone, isodecane, isododecane, isotetradecane and light liquid isoparaffin, further more preferably contains ethanol and at least one selected from the group consisting of isodecane, isododecane, isotetradecane and light liquid isoparaffin.
<33>
The cosmetic composition according to any one of <30> to <32>, wherein the content of the component (E) in the cosmetic composition is preferably 1 to 97% by mass, more preferably 10 to 97% by mass, even more preferably 20 to 97% by mass, further more preferably 40 to 97% by mass, further more preferably 50 to 97% by mass, further more preferably 50 to 95% by mass, further more preferably 50 to 90% by mass.
<34>
The cosmetic composition according to any one of <1> to <33>, which is a hair cosmetic composition.
<35>
The cosmetic composition according to any one of <1> to <34 which is a hair dye composition.
<36>
A method for treating a keratin substance, including a step of applying the cosmetic composition of any one of <1> to <33> to a keratin substance and then drying it.
<37>
A method for treating hair, including a step of applying the hair cosmetic composition of <34> to hair and then drying it.
<38>
A method for dyeing hair, including a step of applying the hair dye composition of <35> to hair and then drying it.
<39>
A cosmetic kit provided with at least two compositions, wherein:
the cosmetic composition obtained by mixing all the compositions constituting the cosmetic kit contains the following components (A) to (C),
(A) a silicone film-forming agent,
(B) a high-molecular-weight organopolysiloxane having a degree of polymerization of 2,350 or more and 20,000 or less,
(C) an organopolysiloxane containing a cationic group other than the component (A) and the component (B).
<40>
The cosmetic kit according to <39>, wherein the total content of the components (A) to (C) in the cosmetic composition obtained by mixing all the compositions constituting the cosmetic kit is 2% by mass or more and 50% by mass or less, and the water content is 10% by mass or less.
<41>
The cosmetic kit according to <39> or <40>, wherein:
the total content of the components (A) to (C) in the cosmetic composition obtained by mixing all the compositions constituting the cosmetic kit is 2% by mass or more and 50% by mass or less,
the ratio by mass of the content of the component (C) to the total content of the components (A) to (C) in the cosmetic composition obtained by mixing all the compositions, [(C)/(A)+(B)+(C)))], is 5% or more and 50% or less, and the water content is 10% by mass or less.
<42>
The cosmetic kit according to any one of <39> to <41>, wherein: the total content of the components (A) to (C) in the cosmetic composition obtained by mixing all the compositions constituting the cosmetic kit is 4% by mass or more and 25% by mass or less, the ratio by mass of the content of the component (C) to the total content of the components (A) to (C) in the cosmetic composition obtained by mixing all the compositions, [(C)/((A)+(B)+(C)))], is 5% or more and 40% or less, and the water content is 10% by mass or less.
Hereinunder the present invention is described with reference to Examples, but the present invention is not restricted to the range of Examples. In these Examples, various measurements and evaluations were carried out according to the following methods.
Untreated black hair bundles (BS-B-A, by Beaulax Co., Ltd., length 10 cm, mass 1 g) were bleached to 7 tone (in a range of luminance L* of 22.5 to 25.1, and chroma C* of 12.3 to 15.9; measured with a colorimeter (CR-400 by Konica Minolta, Inc.)) to prepare hair bundles for evaluation.
The bundle for evaluation was combed to align the hair in one direction, and then using a color difference meter (CR-400 by Konica Minolta, Inc.), the luminance (L0*) thereof was measured in a CIE color system (L*,a*,b*). L0* was measured at different 6 points on the hair bundle (2 central points of each region obtained by equally dividing the hair bundle into three in the length direction), and the found data were averaged to give an average value.
Next, 0.2 g of the hair cosmetic composition of each example was applied to the hair bundle, and then, while kept combed, this was dried for 1 minute with a drier (“P2-D250” by Hitachi Limited, setting HIGH) by applying hot air from a position separated by 18 cm from the hair bundle, and was thereafter further dried with hot air for 30 seconds for hair treatment. After dried, the hair bundle was combed, and in the same manner as above, the luminance (L1*) of the treated hair bundle was measured. According to the following equation, the luminance difference (ΔL*) from the untreated hair bundle was calculated.
ΔL* of 1.0 or more means that the composition is effective for color deepening, 2.0 or more means that the effect is better, and 3.0 or more means that the effect is further better.
ΔL*=L0*−L1*
wherein:
L0*: luminance of untreated hair bundle,
L1*: luminance of treated hair bundle.
0.2 g of the hair cosmetic composition of each example was applied to the hair bundle for evaluation, and then dried with a drier for hair treatment. Three expert panelists organoleptically evaluated feel of the hair bundle after treatment under the following criteria, and a total point of N=3 was calculated.
A total point of 7 or more means a good feel, and 12 or more means a better feel.
5: Not sticky at all.
4: Sticky little.
3: Sticky slightly.
2: Sticky.
1: Extremely sticky
<Sustainability of Color Deepening Effect after 7-Time Shampooing>
Hair bundles treated in the same manner as that for the above “color deepening effect” were shampooed with a plain shampoo having a formulation mentioned below, rinsed with warm water at 40° C., and dried. This process was repeated 7 times. After shampooing 7 times, the luminance of the dried hair bundles was measured in the same manner as above, and the luminance difference (ΔL*) from the untreated hair bundle was calculated.
<Feel in dry state after 7-time shampooing>
The hair bundles treated in the same manner as in the above “feel in dry state” were shampooed with the plain shampoo having the formulation as above, rinsed with warm water at 40° C. and dried. The process was repeated 7 times. After shampooing 7 times, the feel of the dried hair bundles was organoleptically evaluated in the same manner as above.
Examples 1 to 9, Comparative Examples 1 to 2 (preparation and evaluation of hair cosmetic composition)
Ingredients shown in Tables 1 to 4 were blended according to the formulation described in each Table, and then mixed until uniform to prepare hair cosmetic compositions. The resultant hair cosmetic compositions were evaluated according to the above-mentioned methods. The results are shown in Tables 1 to 4.
The blending amount (mass %) shown in Tables is an active ingredient amount.
(Table 1: comparative investigation of effects of cosmetic compositions of the present invention and amino-modified silicone)
PTLs 1 and 2 describe a hair color tone improving effect by amino-modified silicones, and therefore in Comparative Example 1 herein, an aminoethylaminopropylmethylsiloxane/dimethylsiloxane copolymer (amodimethicone) “KF-8004” by Shin-Etsu Chemical Industry Co., Ltd., a side chain amino-modified silicone alone was used for comparison with the present invention.
As shown in Comparative Example 1, by applying amodimethicone to hair, a good color deepening effect could be obtained, but in the case, stickiness in a dry state was extremely strong. On the other hand, in Examples 1 and 2, it is shown that, by using the component (A), the component (B) and the component (C) together, a color deepening effect improved more, and stickiness in a dry state was significantly suppressed.
(Table 2: Investigation of total content of components (A) to (C))
Comparison between Examples 1, 3 and 4, and Comparative Example 2 shows a good color deepening effect and a stickiness suppressing effect in a dry state within a range of the present invention. In addition, it is shown that with increase in the total content of the component (A), the component (B) and the component (C), the color deepening effect improved more and a stickiness suppressing effect in a dry state sustained well.
It is also shown that these effects sustained well even after shampooing 7 times.
(Table 3: Investigation of degree of polymerization of high-molecular-weight dimethylpolysiloxane)
The results of Examples 1, 5 and 6 indicate a good color deepening effect and a stickiness suppressing effect in a dry state in the range of the present invention. In addition, it is also shown that these effects sustained well even after shampooing 7 times.
(Table 4: Investigation of ratio by mass of content of component (C) to total content of components (A) to (C))
The results of Examples 1, 7 to 9 indicate a good color deepening effect and a stickiness suppressing effect in a dry state in the range of the present invention. In addition, it is also shown that these effects sustained well even after shampooing 7 times.
Components shown in Tables are as follows.
*1: X-21-5595, by Shin-Etsu Chemical Industry Co., Ltd., isododecane solution of trimethylsiloxysilicate (60 mass %)
*2: X-21-5686, by Shin-Etsu Chemical Industry Co., Ltd., high-molecular-weight dimethylpolysiloxane, viscosity at 25° C.; 3,000,000 mm2/s
*3: Silsoft B3020, by Momentive Performance Materials Corporation, high-molecular-weight dimethylpolysiloxane, viscosity at 25° C.; 20,000,000 mm2/s
*4: X-25-9074, by Shin-Etsu Chemical Industry Co., Ltd., high-molecular-weight dimethylpolysiloxane, viscosity at 25° C.; 30,000,000 mm2/s
*5: KF-8004, by Shin-Etsu Chemical Industry Co., Ltd., aminoethylaminopropylmethylsiloxane/dimethylsiloxane copolymer (amodimethicone)
*6: DOWSIL SS-3588 Fluid, by Dow Toray Corporation, (bisisobutyl PEG-15/amodimethicone) copolymer
*7: Marukasol R, by Maruzen Petrochemical Co., Ltd., isododecane
The degree of polymerization (P) of the components *2 to *4 can be calculated as follows. From the viscosity (η), the molecular weight (M) is derived according to the above-mentioned formula (4). Since the molecular weight of the base unit of dimethylpolysiloxane is 74, the degree of polymerization (P) is calculated according to the following formula (5).
P=M/74 (5)
The above results indicate that, when the cosmetic composition of the present invention is applied to hair, the color density can be improved and a good feel can be provided, and even after shampooing, the sustainability of these effects is excellent.
According to the present invention, there can be provided a cosmetic composition capable of increasing color density without giving damages to keratin substances such as skin or hair, and especially when applied to hair, capable of giving a good feel. Even after shampooing, the sustainability of these effects of the cosmetic composition is still excellent.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2020-095668 | Jun 2020 | JP | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/JP2021/020131 | 5/27/2021 | WO |
