Claims
- 1. Hair treating cosmetic composition in the form of a thickened liquid, a gel, an emulsion, and aqueous/alcoholic lotion or a dispersion comprising, in a cosmetically acceptable aqueous medium
- (A) at least one anionic surfactant of alkylgalactoside uronate type of formula ##STR17## wherein R.sub.1 denotes a linear or branched alkyl radical containing 8 to 22 carbon atoms,
- R denotes a group ##STR18## in which the carbon carrying the hydroxyl group is connected to the endocyclic oxygen atom; R.sub.2 is a hydrogen atom, an alkali metal, an alkaline-earth metal, a quaternary ammonium group which is unsubstituted or substituted by alkyls or hydroxyalkyls or an amino acid quaternary ammonium group, and
- (B) at least one amphoteric polymer containing units A and B distributed statistically in the polymer chain, said at least one amphoteric polymer being selected from a group of polymers consisting of:
- (i) polymers in which A is a monomer unit containing at least one basic nitrogen atom and B is an acid monomer unit containing one or more carboxyl or sulfonic groups;
- (ii) polymers in which A and B are carboxy betaine or sulfobetaine zwitterionic monomer units;
- (iii) polymers in which A and B are cationic polymer chains containing primary, secondary, tertiary or quaternary amine groups, in which chains at least one of the amine groups carries a carboxylic or sulfonic group linked via a hydrocarbon radical; and
- (iv) polymers in which A and B form part of a chain of a polymer containing an ethylene-.alpha.,.beta.-dicarboxylic unit in which one of the carboxyl groups has been reacted with a polyamine containing one or more primary or secondary amine groups.
- 2. Composition according to claim 1, wherein, in formula (I), radical R.sub.2 is selected from the group consisting of sodium, potassium, magnesium, and a quaternary ammonium group.
- 3. Composition according to claim 1, wherein R.sub.1 is a C.sub.8 -C.sub.14 alkyl.
- 4. Composition according to claim 1, wherein R.sub.1 is a decyl radical.
- 5. Composition according to claim 4, wherein the compound of formula (I) is sodium decyl .alpha.-D-galactopyranoside uronate, sodium decyl .beta.-D-galactopyranoside uronate, sodium decyl .alpha.-D-galactofuranoside uronate, or sodium decyl .beta.-D-galactofuranoside uronate.
- 6. Composition according to claim 1, wherein the amphoteric polymers are selected from the group consisting of:
- (1) polymers resulting from the copolymerization of a vinyl compound carrying a carboxyl group and a basic substituted vinyl compound containing at least one basic nitrogen atom;
- (2) polymers resulting from the polymerization of a quarternary dialkyldialkylammonium monomer and at least one anionic monomer;
- (3) polymers resulting from the copolymerization of
- a) at least one monomer being acrylamides or methacrylamides substituted on the nitrogen with an alkyl radical,
- b) at least one acidic comonomer containing one or more reactive carboxyl groups, and
- c) at least one basic comonomer;
- (4) polyaminoamides, partially or completely cross-linked and alkylated, comprising units of general formula: ##STR19## in which R.sub.7 is a divalent radical selected from the group consisting of saturated dicarboxylic acid radicals, mono- or dicarboxylic aliphatic acid radicals containing an ethylenic double bond, C.sub.1 -C.sub.6 alkyl esters of these acids and radicals resulting from the addition reaction to any one of said acids of a bis-primary or bis-secondary amine, and Z is a polyalkylene poly(bis-primary or mono- or bis-secondary amine) radical, these polyaminoamides being cross-linked by means of a bifunctional cross-linking agent being epihalohydrines, diepoxides, dianhydrides or bis-unsaturated derivatives, said cross-linking agent being used in an amount of 0.025 to 0.35 mol per amine group of the polyaminoamide and said polyaminoamide being alkylated by the action of acrylic acid, chloroacetic acid, an alkane sulfone or their salts;
- (5) polymer containing zwitterionic units of formula: ##STR20## in which R.sub.8 is a polymerizable unsaturated group, x and y represent an integer from 1 to 3, R.sub.9 and R.sub.10 represent hydrogen, methyl, ethyl or propyl, and R.sub.11 and R.sub.12 represent a hydrogen atom or an alkyl radical with the proviso that the sum of the carbon atoms in R.sub.11 and R.sub.12 does not exceed 10;
- (6) polymers containing 0 to 30% of units A of formula ##STR21## 5to 50% of units B of formula ##STR22## 30to 50% of units C of formula ##STR23## wherein in formula C, R represents a radical of formula ##STR24## in which n is 0 or 1 and, when n=0 , R.sub.13, R.sub.14 and R.sub.15, which are identical or different, are selected from the group consisting of hydrogen atom, methyl, hydroxyl, acetoxy or amino residues, monoalkylamine residues, dialkylamine residues, optionally interrupted by one or more nitrogen atoms and/or optionally substituted with one or more amine, hydroxyl, carboxyl, alkylthio or sulfonic groups, and alkylthio residues in which the alkyl group carries an amino residue, at least one of the radicals R.sub.13, R.sub.14 and R.sub.15 in this case being a hydrogen atom; and when n=1, R.sub.13, R.sub.14 and R.sub.15 each represent a hydrogen atom;
- (7) polymers resulting from the N-carboxyalkylation of chitosan;
- (8) polymers corresponding to the general formula (V): ##STR25## in which R.sub.16 represents a hydrogen atom, CH.sub.3 O, CH.sub.3 CH.sub.2 O or a phenyl radical, R.sub.17 is hydrogen or lower alkyl radical, R.sub.18 is hydrogen or a C.sub.1 -C.sub.6 alkyl radical, and R.sub.19 is a lower alkyl radial or a radical corresponding to the formula: --R.sub.20 --N(R.sub.18).sub.2, wherein R.sub.20 is ##STR26## (9) amphoteric polymers type chose selected from the group consisting of a) polymers obtained by the action of chloroacetic acid or sodium chloroacetate on compounds containing at least one unit of the formula:
- -A-Z-A-Z-A- (VI)
- where A is a radical ##STR27## in which Z is a divalent radical B or B', said radicals B and B', which are identical or different, being straight- or branched-chain alkylene radicals containing up to 7 carbon atoms in the main chain, which chain is unsubstituted or substituted with hydroxyl groups, and which can contain, in addition, oxygen, nitrogen and sulfur atoms and 1 to 3 aromatic and/or heterocyclic rings; the oxygen, nitrogen and sulfur atoms when present being in the form of an ether, thioether, sulfoxide, sulfone, sulfonium, alkylamine, alkenylamine, hydroxyl, benzylamine, amine oxide, quaternary ammonium, amide, imide, alcohol, ester or urethane groups;
- b) polymers of formula -A-Z-A-Z- (VI') where A is a radical ##STR28## where Z is a divalent radical B or B', at least one being B'; B having the meaning stated above and B' is a divalent radical which is a straight- or branched-chain alkylene radical having up to 7 carbon atoms in the main chain, which chain is unsubstituted or substituted with one or more hydroxyl radicals and which contains one or more nitrogen atoms, the nitrogen atom being substituted with an alkyl chain optionally interrupted by an oxygen atom and necessarily containing one or more carboxyl functional groups and one or more hydroxyl functional groups, and converted to a betaine by reaction with chloracetic acid or sodium chloroacetate.
- 7. Composition according to claim 6, wherein
- in polymers (1), the carboxyl group carried by the vinyl compound is selected from acrylic acid, methacrylic acid, maleic acid, and alpha-chloroacrylic acid;
- in polymers (2), 60 to 99% by weight of the polymer units are quaternary diallyl dialkyl ammonium units in which the alkyl groups have 1 to 18 carbons and in which the anion is an anion of an acid having an ionization constant greater than 10.sup.-13 and 1 to 40% by weight of the units are anionic acrylic or methacrylic acid units, said polymers having a molecular weight ranging from 50,000 to 100,000 as determined by gel permeation chromatography;
- in polymers (3), said basic comonomer c) is selected from esters of acrylic and methacrylic acids containing primary, secondary, tertiary, and quaternary amine substituents and products of quaternization of diemethylaminoethylmethacrylate with dimethyl or diethylsulfate;
- in polyaminoamides (4), 60 to 100 mole % of the Z radicals have formula: ##STR29## in which either x=2 and n=2 or 3 or x=3 and n=2, 0 to 40 mol % of the Z radicals have formula (III) above in which x=2 and n=1 or formula ##STR30## and 0 to 20 mol % of the Z radicals are --NH(CH2).sub.6 --NH--; and in polymers (5), said polymers further contain non-zwitterionic units from vinylpyrrolidone, alkylacrylates or methacrylates, diethylaminoethylacrylate or methacrylate, acrylamides or methacrylamides, or vinylacetate.
- 8. Composition according to claim 1, wherein the anionic surfactants of formula (I) are present in proportions of between 1 and 50% by weight and the amphoteric polymers are present in proportions of between 0.01 and 10%, the percentages by weight being expressed with respect to the total weight of the composition.
- 9. Composition for conditioning keratinous substances according to claim 1, wherein the concentration of anionic surfactants of formula (I) is between 1 and 10% by weight with respect to the total weight of the composition.
- 10. Composition for washing keratinous substances according to claim 1, wherein the concentration of anionic surfactants of formula (I) is between 4 and 50% by weight with respect to the total weight of the composition.
- 11. Composition according to claim 1, wherein the composition contains an additional surfactant which is of anionic, nonionic, amphoteric, zwitterionic or cationic different from the surfactants of formula (I), in a proportion ranging up to 50% of the total weight of the surfactants present in the composition.
- 12. Composition according to claim 11, wherein the additional anionic surfactant is alkali metal salts, ammonium salts, amine salts, aminoalcohol salts, magnesium salts of the following compounds: fatty acids, alkyl sulfates, alkyl ether sulfates, alkylamidoether sulfates, alkylarylpolyether sulfates, monoglyceride sulfates, alkylsulfonates, alkylethersulfonates, alkyamidesulfonates, alkylarylsulfonates, olefinsulfonates, paraffinsulfonates, alkylsulfosuccinates, alkylethersulfosuccinates, alkylamidesulfosuccinates, alkylsulfosuccinamates, alkylsulfoacetates, alkyl ether phosphates, acylsarcosinates, N-acyltaurates or isethionates; the alkyl or acyl radical consisting of a carbon chain containing from 10 to 20 carbon atoms; isethionates; the alkyl or acyl radical consisting of a carbon chain containing from 10 to 20 carbon atoms; polyoxyalkylenated alkyl amide or alkyl ether carboxylic acids.
- 13. Composition according to claim 11, wherein the additional nonionic surfactant is alcohols, .alpha.-diols, alkylphenols, polyethoxylated or polypropoxylated fatty acids, with a fatty chain containing 8 to 18 carbon atoms, the number of ethylene oxide or propylene oxide groups being between 2 and 50 and the number of glycerol groups being between 2 and 30, copolymers of ethylene oxide and of propylene oxide, condensates of ethylene oxide and propylene oxide with fatty alcohols, polyethoxylated fatty amides, polyethoxylated fatty amines, oxyethylenated fatty acid esters of sorbitan, fatty acid esters of sugar, fatty acid esters of glycols or amine oxides.
- 14. Composition according to claim 11, wherein the additional amphoteric surfactant is from secondary or tertiary aliphatic amines, in which the aliphatic radical is a linear or branched chain containing 8 to 18 carbon atoms and which contains at least one water-solubilizing carboxylate, sulfonate, sulfate, phosphate or phosphonate anionic group; the (C.sub.8 -C.sub.20)alkylbetaines, the sulfobetaines, the (C.sub.8 -C.sub.20)-alkylamino(C.sub.1 -C.sub.6)alkylbetaines, the (C.sub.8 -C.sub.20)-alkylamido(C.sub.1 -C.sub.6)-alkylsulfobetaines; the alkylpeptides; or the alkylimidazolium betaines.
- 15. Composition according to claim 11, wherein the additional surfactant is selected from the quaternary ammonium salts.
- 16. Composition according to claim 1, wherein the cosmetically acceptable medium consists of water or a mixture of water and a cosmetically acceptable solvent.
- 17. Composition according to claim 1, in the form of a thickened liquid, a gel, an emulsion, and aqueous/alcoholic lotion, a dispersion or an aerosol foam.
- 18. Composition according to claim 1, wherein the composition additionally contains additives which are foam reinforcers, thickeners, sequestering agents, electrolytes, fragrances, preservatives, fatty alcohols, mineral oils or waxes, vegetable oils or waxes, animal oils or waxes, synthetic oils or waxes, ceramides, UV screening agents, agents for combating free radicals, pearlescence agents, biocides, antibacterials, antidandruff agents, antiseborrheic agents, antiparasitic agents, repellents, dyes, pigments, oxidizing agents, reducing agents, moisturizers, anionic, nonionic or cationic polymers, vitamins or .alpha.-hydroxy acids.
- 19. Process for cosmetic washing and/or conditioning of the hair or of the skin, comprising applying an effective amount of a composition according to claim 1 to the skin or the hair and then optionally rinsing the hair or skin with water.
Priority Claims (1)
Number |
Date |
Country |
Kind |
93 06530 |
Jun 1993 |
FRX |
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Parent Case Info
This application is a continuation of application Ser. No. 08/537,939, filed Nov. 8, 1995, now abandoned, which is a 371 of PCT/FR94/00631 filed May 31, 1994.
US Referenced Citations (1)
Number |
Name |
Date |
Kind |
5501812 |
Vermeer et al. |
Mar 1996 |
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Foreign Referenced Citations (1)
Number |
Date |
Country |
0 532 370 |
Mar 1993 |
EPX |
Continuations (1)
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Number |
Date |
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Parent |
537939 |
Nov 1995 |
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