None.
The present invention relates to creating impedance matching between RF devices on the same substrate. Coupled Transmission Line Resonate Filter
Without limiting the scope of the invention, its background is described in connection with impedance matching.
One such example is taught in U.S. Pat. No. 9,819,991, issued to Rajagopalan, et al., entitled “Adaptive impedance matching interface”. These inventors are said to teach a device that includes a data interface connector, an application processor, and interface circuitry. Interface circuitry is said to be coupled between the application processor and the data interface connector, in which the data interface circuitry determines a change in a signal property of one of the signals, the change being caused by an impedance mismatch between the data interface connector and a media consumption device. The application processor is said to adjust the signal property of a subsequent one of the signals, in response to the signal property setting from the interface circuitry, to obtain an adjusted signal, or can send the adjusted signal to the media consumption device.
Another such example is taught in U.S. Pat. No. 9,755,305, issued to Desclos, et al., and entitled “Active antenna adapted for impedance matching and band switching using a shared component”. Briefly, these inventors are said to teach an active antenna and associated circuit topology that is adapted to provide active impedance matching and band switching of the antenna using a shared tunable component, e.g., using a shared tunable component, such as a tunable capacitor or other tunable component. The antenna is said to provide a low cost and effective active antenna solution, e.g., one or more passive components can be further utilized to design band switching of the antenna from a first frequency to a second desired frequency.
However, despite these advances, a need remains compact low loss RF devices.
In one embodiment, the present invention includes a method of making a mechanically stabilized RF coupled interdigitated resonate device comprising: masking a design layout comprising one or more structures to form one or more interdigitated structures with electrical conduction channels on a photosensitive glass substrate; exposing at least one portion of the photosensitive glass substrate to an activating energy source; heating the photosensitive glass substrate for at least ten minutes above its glass transition temperature; cooling the photosensitive glass substrate to transform at least part of the exposed glass to a crystalline material to form a glass-crystalline substrate; etching the glass-crystalline substrate with an etchant solution to form a mechanical support device; and coating the one or more electrical conductive interdigitated transmission line, ground plane and input and output channels with one or more metals, wherein the metal is connected to a circuitry. In one aspect, the device is covered with a lid covering all or part of the external electrical isolation structure with a metal or metallic media further comprises connecting the metal or metallic media to a ground. In another aspect, the RF filter line has mechanical and thermal stabilization structure is under less than 50%, 40%, 35%, 30%, 25%, 20%, 10%, 5% or 1% of the contact area of the RF interdigitated resonate structure. In another aspect, the metallization forms a transmission line. In another aspect, the RF transmission line interdigitated resonate filter is a bandpass, low pass, high pass, or notch. In another aspect, a metal line on the RF transmission line interdigitated resonate filter is comprised of titanium, titanium-tungsten, chrome, copper, nickel, gold, palladium or silver. In another aspect, the step of etching forms an air gap between the substrate and the RF interdigitated resonate structure, wherein the interdigitated resonate structure is connected to other RF electronic elements. In another aspect, the glass-crystalline substrate adjacent to the trenches may also be converted to a ceramic phase. In another aspect, the one or more metals are selected from Fe, Cu, Au, Ni, In, Ag, Pt, or Pd. In another aspect, the metal is connected to the circuitry through a surface a buried contact, a blind via, a glass via, a straight line contact, a rectangular contact, a polygonal contact, or a circular contact. In another aspect, the photosensitive glass substrate is a glass substrate comprising a composition of: 60-76 weight % silica; at least 3 weight % K2O with 6 weight %-16 weight % of a combination of K2O and Na2O; 0.003-1 weight % of at least one oxide selected from the group consisting of Ag2O andAu2O; 0.003-2 weight % Cu2O; 0.75 weight %-7 weight % B2O3, and 6-7 weight % Al2O3; with the combination of B2O3; and Al2O3 not exceeding 13 weight %; 8-15 weight % Li2O; and 0.001-0.1 weight % CeO2. In another aspect, the photosensitive glass substrate is a glass substrate comprising a composition of: 35-76 weight % silica, 3-16 weight % K2O, 0.003-1 weight % Ag2O, 8-15 weight % Li2O, and 0.001-0.1 weight % CeO2. In another aspect, the photosensitive glass substrate is at least one of: a photo-definable glass substrate comprises at least 0.1 weight % Sb2O3 or As2O3; a photo-definable glass substrate comprises 0.003-1 weight % Au2O; a photo-definable glass substrate comprises 1-18 weight % of an oxide selected from the group consisting of CaO, ZnO, PbO, MgO, SrO and BaO; and optionally has an anisotropic-etch ratio of exposed portion to said unexposed portion is at least one of 10-20:1; 21-29:1; 30-45:1; 20-40:1; 41-45:1; and 30-50:1. In another aspect, the photosensitive glass substrate is a photosensitive glass ceramic composite substrate comprising at least one of silica, lithium oxide, aluminum oxide, or cerium oxide. In another aspect, the RF transmission has a loss of less than 50, 40, 30, 25, 20, 15, or 10% of the signal input versus a signal output. In another aspect, the method further comprises forming the RF mechanically and thermally stabilized interdigitated resonate structure into a feature of at least one of a bandpass, low pass, high pass, or notch filter.
In another embodiment, the present invention includes a mechanically stabilized RF coupled interdigitated resonate device made by a method comprising: masking a design layout comprising one or more structures to form one or more interdigitated structures with electrical conduction channels on a photosensitive glass substrate; exposing at least one portion of the photosensitive glass substrate to an activating energy source; heating the photosensitive glass substrate for at least ten minutes above its glass transition temperature; cooling the photosensitive glass substrate to transform at least part of the exposed glass to a crystalline material to form a glass-crystalline substrate; etching the glass-crystalline substrate with an etchant solution to form a mechanical support device; coating the one or more electrical conductive interdigitated transmission line, ground plane and input and output channels with one or more metals; and coating all or part of the one or more electrical conductive interdigitated transmission line with a metallic media, wherein the metal is connected to a circuitry. In one aspect, the device is covered with a lid coating of all or part of the external electrical isolation structure with a metal or metallic media further comprises connecting the metal or metallic media to a ground. In another aspect, the RF filter line has mechanical and thermal stabilization structure is under less than 50%, 40%, 35%, 30%, 25%, 20%, 10%, 5% or 1% of the contact area of the RF interdigitated resonate structure. In another aspect, the metallization forms a transmission line. In another aspect, the RF transmission line interdigitated resonate filter is a bandpass, low pass, high pass, or notch. In another aspect, a metal line on the RF transmission line interdigitated resonate filter is comprised of titanium, titanium-tungsten, chrome, copper, nickel, gold, palladium or silver. In another aspect, the step of etching forms an air gap between the substrate and the RF interdigitated resonate structure, wherein the interdigitated resonate structure is connected to other RF electronic elements. In another aspect, the glass-crystalline substrate adjacent to the trenches may also be converted to a ceramic phase. In another aspect, the one or more metals are selected from Fe, Cu, Au, Ni, In, Ag, Pt, or Pd.
For a more complete understanding of the features and advantages of the present invention, reference is now made to the detailed description of the invention along with the accompanying figures and in which:
While the making and using of various embodiments of the present invention are discussed in detail below, it should be appreciated that the present invention provides many applicable inventive concepts that can be embodied in a wide variety of specific contexts. The specific embodiments discussed herein are merely illustrative of specific ways to make and use the invention and do not delimit the scope of the invention.
To facilitate the understanding of this invention, a number of terms are defined below. Terms defined herein have meanings as commonly understood by a person of ordinary skill in the areas relevant to the present invention. Terms such as “a”, “an” and “the” are not intended to refer to only a singular entity, but include the general class of which a specific example may be used for illustration. The terminology herein is used to describe specific embodiments of the invention, but their usage does not limit the invention, except as outlined in the claims.
The present invention relates to creating a compact 50 Ohm resonate filter RF. Compact low loss RF filters are a critical element for compact high efficiency RF communication systems. Compact low loss RF devices are the cornerstone technological requirement for future RF systems particularly for portable systems.
Photosensitive glass structures have been suggested for a number of micromachining and microfabrication processes such as integrated electronic elements in conjunction with other elements systems or subsystems. Semiconductor microfabrication using thin film additive processes on semiconductor, insulating or conductive substrates is expensive with low yield and a high variability in performance. An example of additive micro-transmission can be seen in articles Semiconductor Microfabrication Processes by Tian et al. rely on expensive capital equipment; photolithography and reactive ion etching or ion beam milling tools that generally cost in excess of one million dollars each and require an ultra-clean, high-production silicon fabrication facility costing millions to billions more. This invention provides a cost effective glass ceramic electronic individual device or as an array of passive devices for a uniform response for RF frequencies with low loss.
The interdigitated resonate RF filter is one of the most compact filter structures. This is because the resonators structures are on the side length L, where L is equal to ¼ λ, where λ is the center frequency filter. The filter configuration shown in
Traditional interdigitated band pass filters are compact relative to other forms of RF filters with relaxed tolerances using traditional machining and finishing techniques because of the relatively large spacing between resonator elements. Precision machining metal and electropolished for surface finish easily produce self-supporting resonate elements that have no supporting dielectric material. Using traditional thin film or additive manufacturing technology produce resonate elements that are not mechanically or dimensionally stable. This mechanical or dimensional instability forced the use of a solid dielectric substrate, such as quartz to produce resonate elements for a filter creating large insertion losses well in excess of 10 dB. This level of loss has precluded the use of a resonate interdigitated transmission line band pass filters in commercial markets.
W0 is the width of characteristic impedance, W is the width of resonator, K1 is the coupling efficiency Si+1 is the space between resonator, and L is the length of resonator.
The present invention includes a method of making a mechanically stabilized RF coupled interdigitated resonate device comprising: masking a design layout comprising one or more structures to form one or more interdigitated structures with electrical conduction channels on a photosensitive glass substrate; exposing at least one portion of the photosensitive glass substrate to an activating energy source; heating the photosensitive glass substrate for at least ten minutes above its glass transition temperature; cooling the photosensitive glass substrate to transform at least part of the exposed glass to a crystalline material to form a glass-crystalline substrate; etching the glass-crystalline substrate with an etchant solution to form a mechanical support device; and coating the one or more electrical conductive interdigitated transmission line, ground plane and input and output channels with one or more metals, wherein the metal is connected to a circuitry. The device can be covered with a lid covering all or part of the external electrical isolation structure with a metal or metallic media further comprises connecting the metal or metallic media to a ground. The RF filter line has mechanical and thermal stabilization structure is under less than 50%, 40%, 35%, 30%, 25%, 20%, 10%, 5% or 1% of the contact area of the RF interdigitated resonate structure. The metallization forms a transmission line, e.g., the RF transmission line that is an interdigitated resonate filter is a bandpass, low pass, high pass, or notch. A metal line on the RF transmission line interdigitated resonate filter is comprised of titanium, titanium-tungsten, chrome, copper, nickel, gold, palladium or silver. In another aspect, the step of etching forms an air gap between the substrate and the RF interdigitated resonate structure, wherein the interdigitated resonate structure is connected to other RF electronic elements The glass-crystalline substrate adjacent to the trenches may also be converted to a ceramic phase. The one or more metals are selected from Fe, Cu, Au, Ni, In, Ag, Pt, or Pd. The metal can be connected to the circuitry through a surface a buried contact, a blind via, a glass via, a straight line contact, a rectangular contact, a polygonal contact, or a circular contact. The photosensitive glass substrate is a glass substrate comprising a composition of: 60-76 weight % silica; at least 3 weight % K2O with 6 weight %—16 weight % of a combination of K2O and Na2O; 0.003-1 weight % of at least one oxide selected from the group consisting of Ag2O and Au2O; 0.003-2 weight % Cu2O; 0.75 weight %—7 weight % B2O3, and 6-7 weight % Al2O3; with the combination of B2O3; and Al2O3 not exceeding 13 weight %; 8-15 weight % Li2O; and 0.001-0.1 weight % CeO2. The photosensitive glass substrate is a glass substrate comprising a composition of: 35-76 weight % silica, 3-16 weight % K2O, 0.003-1 weight % Ag2O, 8-15 weight % Li2O, and 0.001-0.1 weight % CeO2. The photosensitive glass substrate is at least one of: a photo-definable glass substrate comprises at least 0.1 weight % Sb2O3 or As2O3; a photo-definable glass substrate comprises 0.003-1 weight % Au2O; a photo-definable glass substrate comprises 1-18 weight % of an oxide selected from the group consisting of CaO, ZnO, PbO, MgO, SrO and BaO; and optionally has an anisotropic-etch ratio of exposed portion to said unexposed portion is at least one of 10-20:1; 21-29:1; 30-45:1; 20-40:1; 41-45:1; and 30-50:1. The photosensitive glass substrate is a photosensitive glass ceramic composite substrate comprising at least one of silica, lithium oxide, aluminum oxide, or cerium oxide. The RF transmission has a loss of less than 50, 40, 30, 25, 20, 15, or 10% of the signal input versus a signal output. The method may further include forming the RF mechanically and thermally stabilized interdigitated resonate structure into a feature of at least one of a bandpass, low pass, high pass, or notch filter.
The present invention includes a method to fabricate to compact RF interdigitated resonate band pass filters in a photodefinable glass ceramic substrate. To produce the present invention the inventors developed a glass ceramic (APEX® Glass ceramic) as a novel packaging and substrate material for semiconductors, RF electronics, microwave electronics, and optical imaging. APEX® Glass ceramic is processed using first generation semiconductor equipment in a simple three step process and the final material can be fashioned into either glass, ceramic, or contain regions of both glass and ceramic. Photo-etchable glasses have several advantages for the fabrication of a wide variety of microsystems components.
Microstructures have been produced relatively inexpensively with these glasses using conventional semiconductor processing equipment. In general, glasses have high temperature stability, good mechanical a n d electrically properties, and have better chemical resistance than plastics and many metals. Photoetchable glass is comprised of lithium-aluminum-silicate glass containing traces of silver ions. When exposed to UV-light within the absorption band of ceriumoxide, the ceriumoxide acts as sensitizers, absorbing a photon and losing an electron that reduces neighboring silver oxide to form silver atoms, e.g.,
Ce3++Ag+=Ce4++Ag0
The silver atoms coalesce into silver nanoclusters during the baking process and induce nucleation sites for crystallization of the surrounding glass. If exposed to UV light through a mask, only the exposed regions of the glass will crystallize during subsequent heat treatment.
This heat treatment must be performed at a temperature near the glass transformation temperature (e.g. Greater than 465° C. in air). The crystalline phase is more soluble in etchants, such as hydrofluoric acid (HF), than the unexposed vitreous, amorphous regions. The crystalline regions etched greater than 20 times faster than the amorphous regions in 10% HF, enabling microstructures with wall slopes ratios of about 20:1 when the exposed regions are removed. See T. R. Dietrich et al, “Fabrication Technologies for Microsystems utilizing Photoetchable Glass”, Microelectronic Engineering 30,497 (1996), which is incorporated herein by reference.
In general, photoetchable glass and is composed of silicon oxide (SiO2) of 75-85% by weight, lithium oxide (Li2O) of 7-11% by weight, aluminum oxide (Al2O3) of 3-6% by weight, sodium oxide (Na2O) of 1-2% by weight, 0.2-0.5% by weight antimonium trioxide (Sb2O3) or arsenic oxide (As2O3), silver oxide (Ag2O) of 0.05-0.15% by weight, and cerium oxide (CeO2) of 0.01-0.04% by weight. As used herein the terms “APEX® Glass ceramic”, “APEX glass” or simply “APEX” is used to denote one embodiment of the glass ceramic composition of the present invention.
The APEX composition provides three main mechanisms for its enhanced performance: (1) The higher amount of silver leads to the formation of smaller ceramic crystals which are etched faster at the grain boundaries, (2) the decrease in silica content (the main constituent etched by the HF acid) decreases the undesired etching of unexposed material, and (3) the higher total weight percent of the alkali metals and boronoxide produces a much more homogeneous glass during manufacturing.
The present invention includes a method for fabricating a low loss RF Filter structure in APEX Glass structure for use in forming interdigitated structures with mechanical stabilization and electrical isolation in a glass ceramic material used. The present invention includes interdigitated structures to create in multiple planes of a glass-ceramic substrate, such process employing the (a) exposure to excitation energy such that the exposure occurs at various angles by either altering the orientation of the substrate or of the energy source, (b) a bake step and (c) an etch step. Interdigitate can be either symmetric or asymmetric. The mechanically stabilized interdigitated structures are difficult, if not infeasible to create in most glass, ceramic or silicon substrates. The present invention has created the capability to create such structures in both the vertical as well as horizontal plane for glass-ceramic substrates.
Ceramicization of the glass is accomplished by exposing a region of the APEX Glass substrate to approximately 20 J/cm2 of 310 nm light. In one embodiment, the present invention provides a quartz/chrome mask containing a variety of concentric circles with different diameters.
The present invention includes a method for fabricating a compact efficient RF filters using mechanically stabilized interdigitated resonate structures connect different electronic devices fabricated in or attached to the photosensitive glass. The photosensitive glass substrate can have a wide number of compositional variations including but not limited to: 60-76 weight % silica; at least 3 weight % K2O with 6 weight %—16 weight % of a combination of K2O and Na2O; 0.003-1 weight % of at least one oxide selected from the group consisting of Ag2O and Au2O; 0.003-2 weight % Cu2O; 0.75 weight %—7 weight % B2O3, and 6-7 weight % Al2O3; with the combination of B2O3; and Al2O3 not exceeding 13 weight %; 8-15 weight % Li2O; and 0.001-0.1 weight % CeO2. This and other varied compositions are generally referred to as the APEX glass.
The exposed portion may be transformed into a crystalline material by heating the glass substrate to a temperature near the glass transformation temperature. When etching the glass substrate in an etchant such as hydrofluoric (HF) acid, the anisotropic-etch ratio of the exposed portion to the unexposed portion is at least 30:1 when the glass is exposed to a broad spectrum mid-ultraviolet (about 308-312 nm) flood lamp to provide a shaped glass structure that have an aspect ratio of at least 30:1, and to provide a lens shaped glass structure. The exposed glass is then baked typically in a two-step process. Temperature range heated between of 420° C.-520° C. for between 10 minutes to 2 hours, for the coalescing of silver ions into silver nanoparticles and temperature range heated between 520° C.-620° C. for between 10 minutes and 2 hours allowing the lithiumoxide to form around the silver nanoparticles. The glass plate is then etched. The glass substrate is etched in an etchant, of HF solution, typically 5% to 10% by volume, where in the etch ratio of exposed portion to that of the unexposed portion is at least 30:1. Create the mechanically and thermally stabilized interdigitated resonate structure through thin film additive and subtractive processes requires the general processing approach.
The wafer is then annealed at temperature range heated between of 420° C.-520° C. for between 10 minutes to 2 hours, for the coalescing of silver ions into silver nanoparticles and temperature range heated between 520° C.-620° C. for between 10 minutes and 2 hours allowing the lithium oxide to form around the silver nanoparticles. The wafer is then cooled and placed into an HF bath to etch the ceramic portion of the wafer. The wafer is then placed into a CVD deposition system for a deposition between 200 Å and 10,000 Å thick of titanium. The wafer is then coated with a photoresist and the via pattern is exposed and developed. The wafer is then placed into a copper-electroplating bath where between 25 μm and 35 μm of copper are deposited. The photoresist is then removed lifting off the majority of the cooper and leaving the cooper filled via. The wafer is then lapped and polished to remove any excess copper and planarize the surface of the glass and cooper filled via.
The wafer is then exposed with approximately 20 J/cm2 of 310 nm light to a photo mask consisting of a rectangular pattern of ˜5.3 mm by 2.2 mm of exposed glass 74 separated with two parallel lines 72 (150 μm wide) of unexposed glass that are approximately 200 μm from the edge of the rectangle pattern. The 150 μm wide glass structure is the mechanical and thermal stabilization element for the interdigitated resonate structure. The contact area between the interdigitated resonate and glass stabilization structure represents about 2% of the surface area contact to the final metal interdigitated resonate structure. The greater the stabilization structure, the higher the RF losses. As such we elect not to make the stabilization structure greater than 50% of the contact area of the interdigitated resonate structure and preferably less than 1%. Less than 1% is achievable with 3DGS' technology, as we have demonstrated 7 μm diameter pedestals that are over 400 μm high further reducing the insertion loss from 2.2 dB for the 6-pole bandpass filter demonstrated in
The wafer is then annealed under an inert gas (e.g., Argon) at temperature range heated between of 420° C.-520° C. for between 10 minutes to 2 hours, for the coalescing of silver ions into silver nanoparticles and temperature range heated between 520° C.-620° C. for between 10 minutes and 2 hours allowing the lithium oxide to form around the silver nanoparticles. The wafer is then cooled and coated with photoresist and expose to the interdigitated resonate and ground plane pattern. The wafer with the interdigitated transmission line resonate pattern and ground plane (front and backside metallization connected by through glass via) and electrical contact pads are patterned in the photoresist, is then coated with 200 Å and 10,000 Å thick of titanium using CVD. The wafer is then placed into a copper electroplating bath where cooper is deposited at a thickness between 0.5 μm and 10 μm. The photoresist is then removed leaving the cooper coated titanium interdigitated transmission line resonate structure and ground plane and any unwanted remaining seed layer is removed using any number of well-established techniques.
The ceramic portion of the exposed/converted glass is then etched away using 10% HF solution leaving the interdigitated, ground plane and input and output structures. The wafer is then rinsed and dried using DI water and IPA.
The wafer is then annealed at temperature range heated between of 420° C.-520° C. for between 10 minutes to 2 hours, for the coalescing of silver ions into silver nanoparticles and temperature range heated between 520° C.-620° C. for between 10 minutes and 2 hours allowing the lithium oxide to form around the silver nanoparticles. The wafer is then cooled and placed into a 10% HF bath to etch the ceramic portion of the wafer. The wafer is then placed into a CVD deposition system for a deposition between 200 Å and 10,000 Å thick of titanium. The wafer is then coated with a photoresist and the via pattern is exposed and developed. The wafer is then placed into a copper-electroplating bath where between 25 μm and 35 μm of copper are deposited. The photoresist is then removed lifting off the majority of the cooper and leaving the cooper filled via. The wafer is then lapped and polished to remove any excess copper and planarize the surface of the glass and cooper filled via.
The wafer is then exposed with approximately 20 J/cm2 of 310 nm light to a photo mask consisting of a rectangular pattern of ˜5.3 mm by ˜2.2 mm. As can be seen in
The lid and bases of the 28 GHz interdigitated RF filter can be diced out of the wafers. A lid can be coated with a solder, e.g., a gold tin solder, on the external edge. The lid is then placed on the base and sealed using a thermal sealer. Thus, the present invention has built and simulated a coupled transmission line resonate filter using air and glass as the dielectric material.
The present inventors used a photo-definable glass ceramic (APEX®) Glass Ceramic or other photo definable glass as a novel substrate material for semiconductors, RF electronics, microwave electronics, electronic components and/or optical elements. In general, a photo definable glass is processed using first generation semiconductor equipment in a simple three step process and the final material can be fashioned into either glass, ceramic, or contain regions of both glass and ceramic. A coupled transmission line resonate structures enable a wide number of filters, e.g.: Bandpass, Notch, Low Pass, and High Pass used in RF circuits at frequencies from MHz to THz devices while reducing the size, cost and power consumption.
It is contemplated that any embodiment discussed in this specification can be implemented with respect to any method, kit, reagent, or composition of the invention, and vice versa. Furthermore, compositions of the invention can be used to achieve methods of the invention.
It will be understood that particular embodiments described herein are shown by way of illustration and not as limitations of the invention. The principal features of this invention can be employed in various embodiments without departing from the scope of the invention. Those skilled in the art will recognize, or be able to ascertain using no more than routine experimentation, numerous equivalents to the specific procedures described herein. Such equivalents are considered to be within the scope of this invention and are covered by the claims.
All publications and patent applications mentioned in the specification are indicative of the level of skill of those skilled in the art to which this invention pertains. All publications and patent applications are herein incorporated by reference to the same extent as if each individual publication or patent application was specifically and individually indicated to be incorporated by reference.
The use of the word “a” or “an” when used in conjunction with the term “comprising” in the claims and/or the specification may mean “one,” but it is also consistent with the meaning of “one or more,” “at least one,” and “one or more than one.” The use of the term “or” in the claims is used to mean “and/or” unless explicitly indicated to refer to alternatives only or the alternatives are mutually exclusive, although the disclosure supports a definition that refers to only alternatives and “and/or.” Throughout this application, the term “about” is used to indicate that a value includes the inherent variation of error for the device, the method being employed to determine the value, or the variation that exists among the study subjects.
As used in this specification and claim(s), the words “comprising” (and any form of comprising, such as “comprise” and “comprises”), “having” (and any form of having, such as “have” and “has”), “including” (and any form of including, such as “includes” and “include”) or “containing” (and any form of containing, such as “contains” and “contain”) are inclusive or open-ended and do not exclude additional, unrecited elements or method steps. In embodiments of any of the compositions and methods provided herein, “comprising” may be replaced with “consisting essentially of” or “consisting of”. As used herein, the phrase “consisting essentially of” requires the specified integer(s) or steps as well as those that do not materially affect the character or function of the claimed invention. As used herein, the term “consisting” is used to indicate the presence of the recited integer (e.g., a feature, an element, a characteristic, a property, a method/process step or a limitation) or group of integers (e.g., feature(s), element(s), characteristic(s), property(ies), method/process steps or limitation(s)) only.
The term “or combinations thereof” as used herein refers to all permutations and combinations of the listed items preceding the term. For example, “A, B, C, or combinations thereof” is intended to include at least one of: A, B, C, AB, AC, BC, or ABC, and if order is important in a particular context, also BA, CA, CB, CBA, BCA, ACB, BAC, or CAB. Continuing with this example, expressly included are combinations that contain repeats of one or more item or term, such as BB, AAA, AB, BBC, AAABCCCC, CBBAAA, CABABB, and so forth. The skilled artisan will understand that typically there is no limit on the number of items or terms in any combination, unless otherwise apparent from the context.
As used herein, words of approximation such as, without limitation, “about”, “substantial” or “substantially” refers to a condition that when so modified is understood to not necessarily be absolute or perfect but would be considered close enough to those of ordinary skill in the art to warrant designating the condition as being present. The extent to which the description may vary will depend on how great a change can be instituted and still have one of ordinary skill in the art recognize the modified feature as still having the required characteristics and capabilities of the unmodified feature. In general, but subject to the preceding discussion, a numerical value herein that is modified by a word of approximation such as “about” may vary from the stated value by at least ±1, 2, 3, 4, 5, 6, 7, 10, 12 or 15%.
All of the compositions and/or methods disclosed and claimed herein can be made and executed without undue experimentation in light of the present disclosure. While the compositions and methods of this invention have been described in terms of preferred embodiments, it will be apparent to those of skill in the art that variations may be applied to the compositions and/or methods and in the steps or in the sequence of steps of the method described herein without departing from the concept, spirit and scope of the invention. All such similar substitutes and modifications apparent to those skilled in the art are deemed to be within the spirit, scope and concept of the invention as defined by the appended claims.
To aid the Patent Office, and any readers of any patent issued on this application in interpreting the claims appended hereto, applicants wish to note that they do not intend any of the appended claims to invoke paragraph 6 of 35 U.S.C. § 112, U.S.C. § 112 paragraph (f), or equivalent, as it exists on the date of filing hereof unless the words “means for” or “step for” are explicitly used in the particular claim.
For each of the claims, each dependent claim can depend both from the independent claim and from each of the prior dependent claims for each and every claim so long as the prior claim provides a proper antecedent basis for a claim term or element.
This application is a continuation of U.S. patent application Ser. No. 17/030,089 filed on Sep. 23, 2020, now U.S. Pat. No. 11,367,939 issued on Jun. 21, 2022, which is a continuation of U.S. patent application Ser. No. 16/219,362 filed on Dec. 13, 2018, now U.S. Pat. No. 10,854,946 issued on Dec. 1, 2020, which claims priority to U.S. Provisional Patent Application Ser. No. 62/599,504 filed Dec. 15, 2017, the contents of which is incorporated by reference herein in its entirety.
Number | Name | Date | Kind |
---|---|---|---|
2515937 | Stookey | Dec 1943 | A |
2515943 | Stookey | Jan 1949 | A |
2515940 | Stookey | Jul 1950 | A |
2515941 | Stookey | Jul 1950 | A |
2628160 | Stookey | Feb 1953 | A |
2684911 | Stookey | Jul 1954 | A |
2971853 | Stookey | Feb 1961 | A |
3281264 | Cape et al. | Oct 1966 | A |
3292115 | La Rosa | Dec 1966 | A |
3904991 | Ishli et al. | Sep 1975 | A |
3985531 | Grossman | Oct 1976 | A |
3993401 | Strehlow | Dec 1976 | A |
4029605 | Kosiorek | Jun 1977 | A |
4131516 | Bakos et al. | Dec 1978 | A |
4413061 | Kumar | Nov 1983 | A |
4444616 | Fujita et al. | Apr 1984 | A |
4514053 | Borrelli et al. | Apr 1985 | A |
4537612 | Borrelli et al. | Aug 1985 | A |
4611882 | Susumu | Sep 1986 | A |
4647940 | Traut et al. | Mar 1987 | A |
4692015 | Loce et al. | Sep 1987 | A |
4788165 | Fong et al. | Nov 1988 | A |
4942076 | Panicker et al. | Jul 1990 | A |
5078771 | Wu | Jan 1992 | A |
5147740 | Robinson | Sep 1992 | A |
5212120 | Araujo et al. | May 1993 | A |
5215610 | Dipaolo et al. | Jun 1993 | A |
5312674 | Heartling et al. | May 1994 | A |
5352996 | Kawaguchi | Oct 1994 | A |
5371466 | Arakawa et al. | Dec 1994 | A |
5374291 | Yabe et al. | Dec 1994 | A |
5395498 | Gombinsky et al. | Mar 1995 | A |
5409741 | Laude | Apr 1995 | A |
5733370 | Chen et al. | Mar 1998 | A |
5779521 | Muroyama et al. | Jul 1998 | A |
5850623 | Carman, Jr. et al. | Dec 1998 | A |
5902715 | Tsukamoto et al. | May 1999 | A |
5919607 | Lawandy et al. | Jul 1999 | A |
5998224 | Rohr et al. | Dec 1999 | A |
6046641 | Chawla et al. | Apr 2000 | A |
6066448 | Wohlstadter et al. | May 2000 | A |
6094336 | Weekamp | Jul 2000 | A |
6136210 | Biegelsen et al. | Oct 2000 | A |
6171886 | Ghosh | Jan 2001 | B1 |
6258497 | Kropp et al. | Jul 2001 | B1 |
6287965 | Kang et al. | Sep 2001 | B1 |
6329702 | Gresham et al. | Dec 2001 | B1 |
6373369 | Huang et al. | Apr 2002 | B2 |
6383566 | Zagdoun | May 2002 | B1 |
6417754 | Bernhardt et al. | Jul 2002 | B1 |
6485690 | Pfost et al. | Nov 2002 | B1 |
6495411 | Mei | Dec 2002 | B1 |
6511793 | Cho et al. | Jan 2003 | B1 |
6514375 | Kijima | Feb 2003 | B2 |
6562523 | Wu et al. | Feb 2003 | B1 |
6678453 | Bellman et al. | Jan 2004 | B2 |
6686824 | Yamamoto et al. | Feb 2004 | B1 |
6771860 | Trezza et al. | Aug 2004 | B2 |
6783920 | Livingston et al. | Aug 2004 | B2 |
6824974 | Pisharody et al. | Nov 2004 | B2 |
6830221 | Janson et al. | Dec 2004 | B1 |
6843902 | Penner et al. | Jan 2005 | B1 |
6875544 | Sweatt et al. | Apr 2005 | B1 |
6932933 | Helvajian et al. | Aug 2005 | B2 |
6977722 | Wohlstadter et al. | Dec 2005 | B2 |
7033821 | Kim et al. | Apr 2006 | B2 |
7064045 | Yang | Jun 2006 | B2 |
7132054 | Kravitz et al. | Nov 2006 | B1 |
7179638 | Anderson | Feb 2007 | B2 |
7277151 | Ryu et al. | Oct 2007 | B2 |
7306689 | Okubora et al. | Dec 2007 | B2 |
7326538 | Pitner et al. | Feb 2008 | B2 |
7407768 | Yamazaki et al. | Aug 2008 | B2 |
7410763 | Su et al. | Aug 2008 | B2 |
7439128 | Divakaruni | Oct 2008 | B2 |
7470518 | Chiu et al. | Dec 2008 | B2 |
7497554 | Okuno | Mar 2009 | B2 |
7603772 | Farnworth et al. | Oct 2009 | B2 |
7915076 | Ogawa et al. | Mar 2011 | B2 |
7948342 | Long | May 2011 | B2 |
8062753 | Schreder et al. | Nov 2011 | B2 |
8076162 | Flemming et al. | Dec 2011 | B2 |
8096147 | Flemming et al. | Jan 2012 | B2 |
8361333 | Flemming et al. | Jan 2013 | B2 |
8492315 | Flemming et al. | Jul 2013 | B2 |
8709702 | Flemming et al. | Apr 2014 | B2 |
9385083 | Herrault et al. | Jul 2016 | B1 |
9449753 | Kim | Sep 2016 | B2 |
9635757 | Chen et al. | Apr 2017 | B1 |
9755305 | Desclos et al. | Sep 2017 | B2 |
9819991 | Rajagopalan et al. | Nov 2017 | B1 |
9843083 | Cooper et al. | Dec 2017 | B2 |
10070533 | Flemming et al. | Sep 2018 | B2 |
10201901 | Flemming et al. | Feb 2019 | B2 |
11367939 | Flemming | Jun 2022 | B2 |
11524807 | Gentili et al. | Dec 2022 | B2 |
20010051584 | Harada et al. | Dec 2001 | A1 |
20020015546 | Bhagavatula | Feb 2002 | A1 |
20020086246 | Lee | Jul 2002 | A1 |
20020100608 | Fushie et al. | Aug 2002 | A1 |
20030025227 | Daniell | Feb 2003 | A1 |
20030107459 | Takahashi et al. | Jun 2003 | A1 |
20030124716 | Hess et al. | Jul 2003 | A1 |
20030135201 | Gonnelli | Jul 2003 | A1 |
20030143802 | Chen et al. | Jul 2003 | A1 |
20030156819 | Pruss et al. | Aug 2003 | A1 |
20030174944 | Dannoux | Sep 2003 | A1 |
20030228682 | Lakowicz et al. | Dec 2003 | A1 |
20030231076 | Takeuchi et al. | Dec 2003 | A1 |
20030231830 | Hikichi | Dec 2003 | A1 |
20040008391 | Bowley et al. | Jan 2004 | A1 |
20040020690 | Parker et al. | Feb 2004 | A1 |
20040058504 | Kellar et al. | Mar 2004 | A1 |
20040104449 | Yoon | Jun 2004 | A1 |
20040155748 | Steingroever | Aug 2004 | A1 |
20040171076 | Dejneka et al. | Sep 2004 | A1 |
20040184705 | Shimada et al. | Sep 2004 | A1 |
20040198582 | Borrelli et al. | Oct 2004 | A1 |
20040227596 | Nguyen et al. | Nov 2004 | A1 |
20050089901 | Porter et al. | Apr 2005 | A1 |
20050105860 | Oono | May 2005 | A1 |
20050111162 | Osaka et al. | May 2005 | A1 |
20050118779 | Ahn | Jun 2005 | A1 |
20050150683 | Farnworth et al. | Jul 2005 | A1 |
20050170670 | King et al. | Aug 2005 | A1 |
20050194628 | Kellar et al. | Sep 2005 | A1 |
20050212432 | Neil et al. | Sep 2005 | A1 |
20050277550 | Brown et al. | Dec 2005 | A1 |
20060092079 | Rochemont | May 2006 | A1 |
20060118965 | Matsui | Jun 2006 | A1 |
20060147344 | Ahn et al. | Jul 2006 | A1 |
20060158300 | Korony et al. | Jul 2006 | A1 |
20060159916 | Dubrow et al. | Jul 2006 | A1 |
20060171033 | Shreder et al. | Aug 2006 | A1 |
20060177855 | Utermohlen et al. | Aug 2006 | A1 |
20060188907 | Lee et al. | Aug 2006 | A1 |
20060193214 | Shimano et al. | Aug 2006 | A1 |
20060201201 | Fushie et al. | Sep 2006 | A1 |
20060283948 | Naito | Dec 2006 | A1 |
20070023386 | Kravitz et al. | Feb 2007 | A1 |
20070034910 | Shie | Feb 2007 | A1 |
20070120263 | Gabric et al. | May 2007 | A1 |
20070121263 | Liu et al. | May 2007 | A1 |
20070155021 | Zhang et al. | Jul 2007 | A1 |
20070158787 | Chanchani | Jul 2007 | A1 |
20070248126 | Liu et al. | Oct 2007 | A1 |
20070254490 | Jain | Nov 2007 | A1 |
20070267708 | Courcimault | Nov 2007 | A1 |
20070272829 | Nakagawa et al. | Nov 2007 | A1 |
20070279837 | Chow et al. | Dec 2007 | A1 |
20070296520 | Hosokawa et al. | Dec 2007 | A1 |
20080042785 | Yagisawa | Feb 2008 | A1 |
20080079565 | Koyama | Apr 2008 | A1 |
20080136572 | Ayasi et al. | Jun 2008 | A1 |
20080174976 | Satoh et al. | Jul 2008 | A1 |
20080182079 | Mirkin et al. | Jul 2008 | A1 |
20080223603 | Kim et al. | Sep 2008 | A1 |
20080226228 | Tamurar | Sep 2008 | A1 |
20080231402 | Jow et al. | Sep 2008 | A1 |
20080245109 | Flemming et al. | Oct 2008 | A1 |
20080291442 | Lawandy | Nov 2008 | A1 |
20080305268 | Norman et al. | Dec 2008 | A1 |
20080316678 | Ehrenberg et al. | Dec 2008 | A1 |
20090029185 | Lee et al. | Jan 2009 | A1 |
20090075478 | Matsui | Mar 2009 | A1 |
20090130736 | Collis et al. | May 2009 | A1 |
20090170032 | Takahashi et al. | Jul 2009 | A1 |
20090182720 | Cain et al. | Jul 2009 | A1 |
20090200540 | Bjoerk et al. | Aug 2009 | A1 |
20090243783 | Fouquet et al. | Oct 2009 | A1 |
20090290281 | Nagamoto et al. | Nov 2009 | A1 |
20100009838 | Muraki | Jan 2010 | A1 |
20100022416 | Flemming et al. | Jan 2010 | A1 |
20100044089 | Shibuya et al. | Feb 2010 | A1 |
20100059265 | Kim | Mar 2010 | A1 |
20100237462 | Beker et al. | Sep 2010 | A1 |
20110003422 | Katragadda et al. | Jan 2011 | A1 |
20110045284 | Matsukawa et al. | Feb 2011 | A1 |
20110065662 | Rinsch et al. | Mar 2011 | A1 |
20110084371 | Rotay et al. | Apr 2011 | A1 |
20110086606 | Chen et al. | Apr 2011 | A1 |
20110108525 | Chien et al. | May 2011 | A1 |
20110114496 | Dopp et al. | May 2011 | A1 |
20110115051 | Kim et al. | May 2011 | A1 |
20110170273 | Helvajian | Jul 2011 | A1 |
20110195360 | Flemming et al. | Aug 2011 | A1 |
20110217657 | Flemming et al. | Sep 2011 | A1 |
20110284725 | Goldberg | Nov 2011 | A1 |
20110304999 | Yu et al. | Dec 2011 | A1 |
20120080612 | Grego | Apr 2012 | A1 |
20120161330 | Hlad et al. | Jun 2012 | A1 |
20130015467 | Krumbein et al. | Jan 2013 | A1 |
20130015578 | Thacker et al. | Jan 2013 | A1 |
20130105941 | Vanslette et al. | May 2013 | A1 |
20130119401 | D'evelyn et al. | May 2013 | A1 |
20130142998 | Flemming et al. | Jun 2013 | A1 |
20130143381 | Kikukawa | Jun 2013 | A1 |
20130183805 | Wong et al. | Jul 2013 | A1 |
20130207745 | Yun et al. | Aug 2013 | A1 |
20130209026 | Doany et al. | Aug 2013 | A1 |
20130233202 | Cao et al. | Sep 2013 | A1 |
20130278568 | Lasiter et al. | Oct 2013 | A1 |
20130308906 | Zheng et al. | Nov 2013 | A1 |
20130337604 | Ozawa et al. | Dec 2013 | A1 |
20140002906 | Shibuya | Jan 2014 | A1 |
20140035540 | Ehrenberg | Feb 2014 | A1 |
20140035892 | Shenoy | Feb 2014 | A1 |
20140035935 | Shenoy | Feb 2014 | A1 |
20140070380 | Chiu et al. | Mar 2014 | A1 |
20140104284 | Shenoy et al. | Apr 2014 | A1 |
20140104288 | Shenoy et al. | Apr 2014 | A1 |
20140144681 | Pushparaj et al. | May 2014 | A1 |
20140145326 | Lin et al. | May 2014 | A1 |
20140169746 | Hung et al. | Jun 2014 | A1 |
20140203891 | Yazaki | Jul 2014 | A1 |
20140247269 | Berdy et al. | Sep 2014 | A1 |
20140272688 | Dillion | Sep 2014 | A1 |
20140367695 | Barlow | Dec 2014 | A1 |
20150035638 | Stephanou et al. | Feb 2015 | A1 |
20150048901 | Rogers | Feb 2015 | A1 |
20150071593 | Kanke | Mar 2015 | A1 |
20150210074 | Chen et al. | Jul 2015 | A1 |
20150228712 | Yun | Aug 2015 | A1 |
20150263429 | Vahidpour et al. | Sep 2015 | A1 |
20150277047 | Flemming et al. | Oct 2015 | A1 |
20160048079 | Lee et al. | Feb 2016 | A1 |
20160181211 | Kamagin et al. | Jun 2016 | A1 |
20160185653 | Fushie | Jun 2016 | A1 |
20160254579 | Mills | Sep 2016 | A1 |
20160265974 | Erte et al. | Sep 2016 | A1 |
20160268665 | Sherrer et al. | Sep 2016 | A1 |
20160320568 | Haase | Nov 2016 | A1 |
20160380614 | Abbott et al. | Dec 2016 | A1 |
20170003421 | Flemming et al. | Jan 2017 | A1 |
20170077892 | Thorup | Mar 2017 | A1 |
20170094794 | Flemming et al. | Mar 2017 | A1 |
20170098501 | Flemming et al. | Apr 2017 | A1 |
20170213762 | Flemming et al. | Apr 2017 | A1 |
20170370870 | Fomina et al. | Dec 2017 | A1 |
20180310399 | Nair et al. | Oct 2018 | A1 |
20180315811 | Cho et al. | Nov 2018 | A1 |
20180323485 | Gnanou et al. | Nov 2018 | A1 |
20190280079 | Bouvier et al. | Jul 2019 | A1 |
20200060513 | Ito et al. | Feb 2020 | A1 |
20200066443 | Lu et al. | Feb 2020 | A1 |
20200119255 | Then et al. | Apr 2020 | A1 |
20200168536 | Link et al. | May 2020 | A1 |
20200211985 | Pietambaram et al. | Jul 2020 | A1 |
20200227470 | Then et al. | Jul 2020 | A1 |
20200235020 | Boek | Jul 2020 | A1 |
20200252074 | Healy et al. | Aug 2020 | A1 |
20200275558 | Fujita | Aug 2020 | A1 |
20210013303 | Chen et al. | Jan 2021 | A1 |
20210271275 | Kim et al. | Sep 2021 | A1 |
Number | Date | Country |
---|---|---|
1562831 | Apr 2004 | CN |
105047558 | Nov 2015 | CN |
105938928 | Sep 2016 | CN |
210668058 | Jun 2020 | CN |
102004059252 | Jan 2006 | DE |
0311274 | Dec 1989 | EP |
0507719 | Oct 1992 | EP |
0685857 | Dec 1995 | EP |
0949648 | Oct 1999 | EP |
1683571 | Jun 2006 | EP |
619779 | Mar 1949 | GB |
1407151 | Sep 1975 | GB |
56-155587 | Dec 1981 | JP |
61149905 | Jul 1986 | JP |
61231529 | Oct 1986 | JP |
62202840 | Sep 1987 | JP |
63-128699 | Jun 1988 | JP |
H393683 | Apr 1991 | JP |
05139787 | Jun 1993 | JP |
08179155 | Dec 1994 | JP |
08026767 | Jan 1996 | JP |
H10007435 | Jan 1998 | JP |
10199728 | Jul 1998 | JP |
11344648 | Dec 1999 | JP |
2000228615 | Aug 2000 | JP |
2001033664 | Feb 2001 | JP |
2001284533 | Oct 2001 | JP |
2005302987 | Oct 2005 | JP |
2005215644 | Nov 2005 | JP |
2006032982 | Feb 2006 | JP |
2006179564 | Jun 2006 | JP |
2006324489 | Nov 2006 | JP |
2008252797 | Oct 2008 | JP |
2011192836 | Sep 2011 | JP |
2012079960 | Apr 2012 | JP |
2013062473 | Apr 2013 | JP |
2013217989 | Oct 2013 | JP |
2014241365 | Dec 2014 | JP |
2015028651 | Feb 2015 | JP |
H08026767 | Jan 2016 | JP |
2018200912 | Dec 2018 | JP |
2021145131 | Sep 2021 | JP |
1020040001906 | Jan 2004 | KR |
1020050000923 | Jan 2005 | KR |
20060092643 | Aug 2006 | KR |
1020060092643 | Aug 2006 | KR |
100941691 | Feb 2010 | KR |
101167691 | Jul 2012 | KR |
101519760 | May 2015 | KR |
2005027606 | Mar 2005 | WO |
2007088058 | Aug 2007 | WO |
2008119080 | Oct 2008 | WO |
2008154931 | Dec 2008 | WO |
2009029733 | Mar 2009 | WO |
2009062011 | May 2009 | WO |
2009126649 | Oct 2009 | WO |
2010011939 | Jan 2010 | WO |
2011100445 | Aug 2011 | WO |
2011109648 | Sep 2011 | WO |
2012078213 | Jun 2012 | WO |
2014043267 | Mar 2014 | WO |
2014062226 | Apr 2014 | WO |
2014062311 | Apr 2014 | WO |
2014193525 | Dec 2014 | WO |
2015108648 | Jul 2015 | WO |
2015171597 | Nov 2015 | WO |
2017132280 | Aug 2017 | WO |
Entry |
---|
Supplemental European Search Report for EP 20792242.8 dated Mar. 5, 2022, 10 pp. |
Kim, Dongsu, et al., “A Compact and Low-profile GaN Power Amplifier Using Interposer-based MMCI Technology,” 2014 IEEE 16th Electronics Packaging Technology Conference, pp. 672-675. |
Aslan, et al., “Metal-Enhanced Fluorescence: an emerging tool in biotechnology” Current opinion in Biotechnology (2005), 16:55-62. |
Azad, I., et al., “Design and Performance Analysis of 2.45 GHz Microwave Bandpass Filter with Reduced Harmonics,” International Journal of Engineering Research and Development (2013), 5(11):57-67. |
Bakir, Muhannad S., et al., “Revolutionary Nanosilicon Ancillary Technologies for Ultimate-Performance Gigascale Systems,” IEEE 2007 Custom Integrated Circuits Conference (CICC), 2007, pp. 421-428. |
Beke, S., et al., “Fabrication of Transparent and Conductive Microdevices,” Journal of Laser Micro/Nanoengineering (2012), 7(1):28-32. |
Brusberg, et al. “Thin Glass Based Packaging Technologies for Optoelectronic Modules” Electronic Components and Technology Conference, May 26-29, 2009, pp. 207-212, DOI:10.1109/ECTC.2009.5074018, pp. 208-211; Figures 3, 8. |
Cheng, et al. “Three-dimensional Femtosecond Laser Integration in Glasses” The Review of Laser Engineering, vol. 36, 2008, pp. 1206-1209, Section 2, Subsection 3.1. |
Chou, et al., “Design and Demonstration of Micro-mirrors and Lenses for Low Loss and Low Cost Single-Mode Fiber Coupling in 3D Glass Photonic Interposers,” 2016 IEEE 66th Electronic Components and Technology Conference, May 31-Jun. 3, 7 pp. |
Chowdhury, et al, “Metal-Enhanced Chemiluminescence”, J Fluorescence (2006), 16:295-299. |
Crawford, Gregory P., “Flexible Flat Panel Display Technology,” John Wiley and Sons, NY, (2005), 9 pages. |
Dang, et al. “Integrated thermal-fluidic I/O interconnects for an on-chip microchannel heat sink,” IEEE Electron Device Letters, vol. 27, No. 2, pp. 117-119, 2006. |
Dietrich, T.R., et al., “Fabrication Technologies for Microsystems Utilizing Photoetchable Glass,” Microelectronic Engineering 30, (1996), pp. 407-504. |
Extended European Search Report 15741032.5 dated Aug. 4, 2017, 11 pp. |
Extended European Search Report 15789595.4 dated Mar. 31, 2017, 7 pp. |
Extended European Search Report 17757365.6 dated Oct. 14, 2019, 14 pp. |
Extended European Search Report 17744848.7 dated Oct. 30, 2019, 9 pp. |
European Search Report and Supplemental European Search Report for EP 18828907 dated Mar. 25, 2020, 11 pp. |
European Search Report and Supplemental European Search Report for EP 18889385.3 dated Dec. 2, 2020, 8 pp. |
European Search Report and Supplemental European Search Report for EP 18898912.3 dated Feb. 2, 2021, 10 pp. |
European Search Report and Supplemental European Search Report for EP 19784673.6 dated Feb. 2, 2021, 8 pp. |
European Search Report and Supplemental European Search Report for EP 19811031.4 dated Feb. 26, 2021, 7 pp. |
Geddes, et al, “Metal-Enhanced Fluorescence” J Fluorescence, (2002), 12:121-129. |
Gomez-Morilla, et al. “Micropatterning of Foturan photosensitive glass following exposure to MeV proton beams” Journal of Micromechanics and Microengineering, vol. 15, 2005, pp. 706-709, DOI:10.1088/0960-1317/15/4/006. |
Green, S., “Heterogeneous Integration of DARPA: Pathfinding and Progress in Assembly Approaches,” viewed on and retrieved from the Internet on Feb. 26, 2021, <URL:https://web.archive.org/web/20181008153224/https://www.ectc.net/files/68/Demmin%20Darpa.pdf>, published Oct. 8, 2018 per the Wayback Machine. |
Grine, F. et al., “High-Q Substrate Integrated Waveguide Resonator Filter With Dielectric Loading,” IEEE Access vol. 5, Jul. 12, 2017, pp. 12526-12532. |
Hyeon, I-J, et al., “Millimeter-Wave Substrate Integrated Waveguide Using Micromachined Tungsten-Coated Through Glass Silicon Via Structures,” Micromachines, vol. 9, 172 Apr. 9, 2018, 9 pp. |
Intel Corporation, “Intel® 82566 Layout Checklist (version 1.0)”, 2006. |
International Search Report and Written Opinion for PCT/US2008/058783 dated Jul. 1, 2008, 15 pp. |
International Search Report and Written Opinion for PCT/US2008/074699 dated Feb. 26, 2009, 11 pp. |
International Search Report and Written Opinion for PCT/US2009/039807 dated Nov. 24, 2009, 13 pp. |
International Search Report and Written Opinion for PCT/US2009/051711 dated Mar. 5, 2010, 15 pp. |
International Search Report and Written Opinion for PCT/US2011/024369 dated Mar. 25, 2011, 13 pp. |
International Search Report and Written Opinion for PCT/US2013/059305 dated Jan. 10, 2014, 6 pp. |
International Search Report and Written Opinion for PCT/US2015/012758 dated Apr. 8, 2015, 11 pp. |
International Search Report and Written Opinion for PCT/US2015/029222 dated Jul. 22, 2015, 9 pp. |
Optics 101, “What is a Halogen Lamp?”, Apr. 25, 2014, p. 1-2. |
European Search Report and Supplemental European Search Report for EP 19861556.9 dated Jan. 18, 2022, 9 pp. |
European Search Report and Supplemental European Search Report for EP 19905255.6 dated Jul. 26, 2022, 8 pp. |
International Search Report and Written Opinion for PCT/US2017/026662 dated Jun. 5, 2017, 11 pp. |
International Search Report and Written Opinion for PCT/US2018/029559 dated Aug. 3, 2018, 9 pp. |
International Search Report and Written Opinion for PCT/US2018/039841 dated Sep. 20, 2018 by Australian Patent Office, 12 pp. |
International Search Report and Written Opinion for PCT/US2018/065520 dated Mar. 20, 2019 by Australian Patent Office, 11 pp. |
International Search Report and Written Opinion for PCT/US2018/068184 dated Mar. 19, 2019 by Australian Patent Office, 11 pp. |
International Search Report and Written Opinion for PCT/US2019/024496 dated Jun. 20, 2019 by Australian Patent Office, 9 pp. |
International Search Report and Written Opinion for PCT/US2019/34245 dated Aug. 9, 2019 by Australian Patent Office, 10 pp. |
International Search Report and Written Opinion for PCT/US2019/50644 dated Dec. 4, 2019 by USPTO, 9 pp. |
International Search Report and Written Opinion for PCT/US2019/068586 dated Mar. 12, 2020 by USPTO, 10 pp. |
International Search Report and Written Opinion for PCT/US2019/068590 dated Mar. 5, 2020 by USPTO, 9 pp. |
International Search Report and Written Opinion for PCT/US2019/068593 dated Mar. 16, 2020 by USPTO, 8 pp. |
International Search Report and Written Opinion for PCT/US2020/026673 dated Jun. 22, 2020, by the USPTO, 13 pp. |
International Search Report and Written Opinion for PCT/US2020/28474 dated Jul. 17, 2020 by the USPTO, 7 pp. |
International Search Report and Written Opinion for PCT/US2020/54394 dated Jan. 7, 2021 by the USPTO, 15 pp. |
International Search Report and Written Opinion for PCT/US2021/21371 dated May 20, 2021 by the USPTO, 10 pp. |
International Search Report and Written Opinion for PCT/US2021/27499 dated Jun. 16, 2021 by the USPTO, 7 pp. |
International Technology Roadmap for Semiconductors, 2007 Edition, “Assembly and Packaging,” 9 pages. |
Kamagaing, et al., “Investigation of a photodefinable glass substrate for millimeter-wave radios on package,” Proceeds of the 2014 IEEE 64th Electronic Components and Technology Conference, May 27, 2014, pp. 1610-1615. |
Lakowicz, et al; “Advances in Surface-Enhanced Fluorescence”, J Fluorescence, (2004), 14:425-441. |
Lewis, Sr., “Hawley's Condensed Chemical Dictionary.” 13th ed, 1997, John Wiley and Sons. p. 231. |
Lin, C.H., et al., “Fabrication of Microlens Arrays in Photosensitive Glass by Femtosecond Laser Direct Writing,” Appl Phys A (2009) 97:751-757. |
Livingston, F.E., et al., “Effect of Laser Parameters on the Exposure and Selective Etch Rate in Photostructurable Glass,” SPIE vol. 4637 (2002); pp. 404-412. |
Lyon, L.A., et al., “Raman Spectroscopy,” Anal Chem (1998), 70:341R-361R. |
Mohamedelhassan, A., “Fabrication of Ridge Waveguides in Lithium Niobate,” Independent thesis Advanced level, KTH, School of Engineering Sciences, Physics, 2012, 68 pp. |
Muharram, B., Thesis from University of Calgary Graduate Studies, “Substrate-Integrated Waveguide Based Antenna in Remote Respiratory Sensing,” 2012, 97 pp. |
Papapolymerou, I., et al., “Micromachined patch antennas,” IEEE Transactions on Antennas and Propagation, vol. 46, No. 2, 1998, pp. 275-283. |
Perro, A., et al., “Design and synthesis of Janus micro- and nanoparticles,” J Mater Chem (2005), 15:3745-3760. |
Quantum Leap, “Liquid Crystal Polymer (LCP) LDMOS Packages,” Quantum Leap Datasheet, (2004), mlconnelly.com/QLPKG.Final_LDMOS_DataSheet.pdf, 2 pages. |
Scrantom, Charles Q., “LTCC Technology—Where We Are and Where We're Going—IV,” Jun. 2000, 12 pages. |
TechNote #205, Bangs Laboratories, www.bangslabs.com/technotes/205.pdf, “Covalent Coupling”. |
TechNote #104, Bangs Laboratories, www.bangslabs.com/technotes/104.pdf, “Silica Microspheres”. |
TechNote #201, Bangs Laboratories, www.bangslabs.com/technotes/201.pdf, “Working with Microspheres”. |
Topper, et al., “Development of a high density glass interposer based on wafer level packaging technologies,” 2014 IEEE 64th Electronic Components and Technology Conference, May 27, 2014, pp. 1498-1503. |
Wang, et al. “Optical waveguide fabrication and integration with a micro-mirror inside photosensitive glass by femtosecond laser direct writing” Applied Physics A, vol. 88, 2007, pp. 699-704, DOI:10.1007/S00339-007-4030-9. |
Zhang, H., et al., “Biofunctionalized Nanoarrays of Inorganic Structures Prepared by Dip-Pen Nanolithography,” Nanotechnology (2003), 14:1113-1117. |
Zhang, H., et al., Synthesis of Hierarchically Porous Silica and Metal Oxide Beads Using Emulsion-Templated Polymer Scaffolds, Chem Mater (2004), 16:4245-4256. |
Extended European Search Report for EP 19906040.1 dated Feb. 4, 2022, 16 pp. |
International Search Report and Written Opinion for PCT/US2017/019483 dated May 19, 2017, 11 pp. |
European Search Report and Supplemental European Search Report for EP 19905255.6 dated Aug. 4, 2022, 8 pp. |
European Search Report and Supplemental European Search Report for EP 20783596.8 dated Oct. 26, 2022, 13 pp. |
European Search Report and Supplemental European Search Report for EP 20877664.1 dated Oct. 28, 2022, 10 pp. |
Flemming, J.H., et al., “Cost Effective 3D Glass Microfabrication for Advanced RF Packages,” Microwave Journal, Apr. 14, 2014, 12 pp. |
Foster, T., “High-Q RF Devices in APEX Glass,” Jun. 21, 2018, https://nanopdf.com/download/high-q-rf-devices-in-apex-glass_pdf, retrieved on Oct. 3, 2022, 8 pp. |
International Search Report and Written Opinion for PCT/US2022/31993 dated Sep. 9, 2022 by the USPTO, 9 pp. |
International Search Report and Written Opinion for PCT/US2022/29442 dated Oct. 6, 2022 by the USPTO, 20 pp. |
International Search Report and Written Opinion for PCT/US2022/42516 dated Feb. 3, 2023 by the USPTO, 22 pp. |
International Search Report and Written Opinion for PCT/US2023/010118 dated Apr. 5, 2023 by the USPTO, 12 pp. |
Supplementary European Search Repor for EP 21768296.2 dated May 5, 2023, 10 pp. |
European Search Report and Supplemental European Search Report for EP 21787618.4 dated Jul. 28, 2023, 10 pp. |
International Search Report and Written Opinion for PCT/US2023/064364 dated Sep. 27, 2023, by USPTO 11 ps. |
International Search Report and Written Opinion for PCT/US2023/17311 dated Aug. 14, 2023 by the USPTO, 16 pp. |
Number | Date | Country | |
---|---|---|---|
20220278435 A1 | Sep 2022 | US |
Number | Date | Country | |
---|---|---|---|
62599504 | Dec 2017 | US |
Number | Date | Country | |
---|---|---|---|
Parent | 17030089 | Sep 2020 | US |
Child | 17746287 | US | |
Parent | 16219362 | Dec 2018 | US |
Child | 17030089 | US |