1. Field of the Application
The present application relates generally to thermoelectric cooling, heating, and power generation systems.
2. Description of the Related Art
Thermoelectric (TE) devices and systems can be operated in either heating/cooling or power generation modes. In the former, electric current is passed through a TE device to pump the heat from the cold side to the hot side. In the latter, a heat flux driven by a temperature gradient across a TE device is converted into electricity. In both modalities, the performance of the TE device is largely determined by the figure of merit of the TE material and by the parasitic (dissipative) losses throughout the system. Working elements in the TE device are typically p-type and n-type semiconducting materials. Mechanical properties of these materials can be brittle with a common mode of failure of TE devices being cracking of the elements caused by the shear loads on the elements.
One of the concerns in thermoelectric generator (TEG) design is thermal expansion management. Hot sides of TEGs can be exposed to temperatures as high as 600° C. in automotive applications (e.g., exhaust, catalytic converters, etc.) and can see temperatures up to 1000° C. in other applications such as radioisotope thermoelectric generators (RTGs). TEGs also have a cold side which in some applications can be 500° C. lower relative to the hot side. The cold side is also positioned in close proximity to the hot side in a TEG. For example, in some high power density applications, the desire is to have thermoelectric (TE) elements (positioned between the hot and cold sides of the TEG) less than or equal to 5 mm in either height and/or thickness, and/or to have a temperature gradient less than or equal to 100 C/mm. A large temperature difference (e.g., 500° C.) between the hot and cold sides of the TEGs and/or the close proximity of the hot and cold sides of the TEGs can cause a large thermal expansion mismatch. In certain designs, this thermal expansion mismatch must then be maintained by the often brittle TE elements. If not managed properly, the TE elements will be ripped apart or fail during operation of the TEG.
Certain embodiments described herein provide a thermoelectric system comprising a plurality of cold-side conduits extending parallel to one another along a first direction and configured to have a first working fluid flowing therethrough. Each cold-side conduit of the plurality of cold-side conduits comprises a cold-side tube and a plurality of cold-side shunts in thermal communication with the cold-side tube. The thermoelectric system further comprises a plurality of hot-side conduits extending parallel to one another along a second direction and configured to have a second working fluid flowing therethrough. The second direction is perpendicular to the first direction. Each hot-side conduit of the plurality of hot-side conduits comprises a hot-side tube and a plurality of hot-side shunts in thermal communication with the hot-side tube. The thermoelectric system further comprises a plurality of thermoelectric stacks. Each thermoelectric stack of the plurality of thermoelectric stacks comprises a plurality of thermoelectric elements, a first plurality of cold-side shunts of a first cold-side conduit, a first hot-side shunt of a first hot-side conduit, and a second hot-side shunt of a second hot-side conduit. Each thermoelectric stack of the plurality of thermoelectric stacks extends along a third direction and is configured to have electrical current flow through the thermoelectric stack along the third direction.
Certain embodiments described herein provide a thermoelectric system comprising a plurality of cold-side heat exchangers extending parallel to one another along a first direction. Each cold-side heat exchanger of the plurality of cold-side heat exchangers comprises a cold-side member and a plurality of cold-side shunts in thermal communication with the cold-side member. The thermoelectric system further comprises a plurality of hot-side heat exchangers extending parallel to one another along a second direction. The second direction is perpendicular to the first direction. Each hot-side heat exchanger of the plurality of hot-side heat exchangers comprises a hot-side member and a plurality of hot-side shunts in thermal communication with the hot-side member. The thermoelectric system further comprises a plurality of thermoelectric stacks. Each thermoelectric stack of the plurality of thermoelectric stacks comprises a plurality of thermoelectric elements, a first plurality of cold-side shunts of a first cold-side heat exchanger, a first hot-side shunt of a first hot-side heat exchanger, and a second hot-side shunt of a second hot-side heat exchanger. Each thermoelectric stack of the plurality of thermoelectric stacks extends along a third direction and is configured to have electrical current flow through the thermoelectric stack along the third direction.
Certain embodiments described herein provide a method of managing thermal expansion during operation of a thermoelectric system. The method comprises flowing a first working fluid through a plurality of cold-side conduits extending parallel to one another along a first direction. The method further comprises flowing a second working fluid through a plurality of hot-side conduits extending parallel to one another along a second direction. The method further comprises flowing electrical current through a plurality of thermoelectric stacks extending parallel to one another along a third direction that is either parallel or perpendicular to at least one of the first direction and the second direction. Each thermoelectric stack of the plurality of thermoelectric stacks comprises a plurality of thermoelectric elements in thermal communication with the plurality of cold-side conduits and the plurality of hot-side conduits.
The paragraphs above recite various features and configurations of one or more of a thermoelectric assembly, a thermoelectric module, or a thermoelectric system, that have been contemplated by the inventors. It is to be understood that the inventors have also contemplated thermoelectric assemblies, thermoelectric modules, and thermoelectric systems which comprise combinations of these features and configurations from the above paragraphs, as well as thermoelectric assemblies, thermoelectric modules, and thermoelectric systems which comprise combinations of these features and configurations from the above paragraphs with other features and configurations disclosed in the following paragraphs.
Various embodiments are depicted in the accompanying drawings for illustrative purposes, and should in no way be interpreted as limiting the scope of the thermoelectric devices, systems, or methods described herein. In addition, various features of different disclosed embodiments can be combined with one another to form additional embodiments, which are part of this disclosure. Any feature or structure can be removed, altered, or omitted. Throughout the drawings, reference numbers may be reused to indicate correspondence between reference elements.
A thermoelectric system as described herein can be a thermoelectric generator (TEG) which uses the temperature difference between two fluids, two solids (e.g., rods), or a solid and a fluid to produce electrical power via thermoelectric materials. Alternatively, a thermoelectric system as described herein can be a heater, cooler, or both which serves as a solid state heat pump used to move heat from one surface to another, thereby creating a temperature difference between the two surfaces via the thermoelectric materials. Each of the surfaces can be in thermal communication with or comprise a solid, a liquid, a gas, or a combination of two or more of a solid, a liquid, and a gas, and the two surfaces can both be in thermal communication with a solid, both be in thermal communication with a liquid, both be in thermal communication with a gas, or one can be in thermal communication with a material selected from a solid, a liquid, and a gas, and the other can be in thermal communication with a material selected from the other two of a solid, a liquid, and a gas.
The thermoelectric system can include a single thermoelectric assembly or a group of thermoelectric assemblies) depending on usage, power output, heating/cooling capacity, coefficient of performance (COP) or voltage. Although the examples described herein may be described in connection with either a power generator or a heating/cooling system, the described features can be utilized with either a power generator or a heating/cooling system.
Because the thermoelectric assembly and/or thermoelectric system may be exposed to significant temperature differences (for example, up to 500° C.), there are many features described herein which allow for thermal expansion and stress relief on the portions of the thermoelectric assemblies.
The term “thermal communication” is used herein in its broad and ordinary sense, describing two or more components that are configured to allow heat transfer from one component to another. For example, such thermal communication can be achieved, without loss of generality, by snug contact between surfaces at an interface; one or more heat transfer materials or devices between surfaces; a connection between solid surfaces using a thermally conductive material system, wherein such a system can include pads, thermal grease, paste, one or more working fluids, or other structures with high thermal conductivity between the surfaces (e.g., heat exchangers); other suitable structures; or combinations of structures. Substantial thermal communication can take place between surfaces that are directly connected (e.g., contact each other) or indirectly connected via one or more interface materials.
As used herein, the terms “shunt” and “heat exchanger” have their broadest reasonable interpretation, including but not limited to a component (e.g., a thermally conductive device or material) that allows heat to flow from one portion of the component to another portion of the component. Shunts can be in thermal communication with one or more thermoelectric materials (e.g., one or more thermoelectric elements) and in thermal communication with one or more heat exchangers of the thermoelectric assembly or system. Shunts described herein can also be electrically conductive and in electrical communication with the one or more thermoelectric materials so as to also allow electrical current to flow from one portion of the shunt to another portion of the shunt (e.g., thereby providing electrical communication between multiple thermoelectric materials or elements). Heat exchangers (e.g., tubes and/or conduits) can be in thermal communication with the one or more shunts and one or more working fluids of the thermoelectric assembly or system. Various configurations of one or more shunts and one or more heat exchangers can be used (e.g., one or more shunts and one or more heat exchangers can be portions of the same unitary element, one or more shunts can be in electrical communication with one or more heat exchangers, one or more shunts can be electrically isolated from one or more heat exchangers, one or more shunts can be in direct thermal communication with the thermoelectric elements, one or more shunts can be in direct thermal communication with the one or more heat exchangers, an intervening material can be positioned between the one or more shunts and the one or more heat exchangers). Furthermore, as used herein, the words “cold,” “hot,” “cooler,” “hotter” and the like are relative terms, and do not signify a particular temperature or temperature range.
There are various ways to manage thermal expansion mismatch, such as with liquid joints. For example, TEGs use thermal grease and/or liquid metal in combination with a complex cold shunt subassembly to overcome thermal expansion mismatch with adequate thermal and electrical contact. However, this can be less than ideal for maintaining the TE parts or materials in consistent operating condition. Certain embodiments disclosed herein potentially eliminate the need for both thermal grease and liquid metal.
Another desirable factor in TEG design is to have electrical and thermal contact resistances as low as possible. This factor can be at odds with managing thermal expansion mismatch because thermal expansion mismatch can often cause the hot side of a TEG to separate further from the cold side resulting in increased interfacial resistance. Certain embodiments described herein, address thermal expansion mismatch between the hot and cold sides of the TEG while still maintaining low electrical and thermal contact resistances.
For automotive as well as other applications, it can be desirable to have the voltage of a device providing power be at a certain level. In an automotive case, nominal voltage may be 14V. A cylindrical TEG has been developed that takes advantage of the hoop stress of a thermally expanding cylinder inside of a ring shunt in order to improve thermal contact as disclosed in U.S. Patent Publication No. 2011/0067742 and incorporated by reference herein. To take advantage of the hoop stress, the ring is a solid or split ring. In order to accommodate large mass flows while keeping pressure drop at a minimum, diameters of the cylindrical TEGs are relatively large, resulting in many parallel connections of the TE couples.
These multiple parallel connections can lead to very high current and very low voltage for the device. A power converter can be added to the system to increase the voltage and reduce current, but this adds additional cost and takes up valuable package space, and decreases efficiency. Certain embodiments described herein increase voltage and reduce current with more parallel/series flexibility. This design flexibility can allow certain TEG embodiments described herein to fit many different applications and package spaces.
In many TEG applications, particularly those involving a gas side, it can be very important to manage the pressure drop across the heat exchangers. In the automotive application, high pressure drop across the hot side heat exchanger of a TEG can cause excessive backpressure in the exhaust system of the vehicle. This excessive backpressure can reduce the performance of the vehicle's engine or even damage it. In other applications, high pressure drop may lead to the need for high fan or pump power which can decrease the net power output of the TEG device. The cross flow nature of certain embodiments described herein allow more flexibility to combat high pressure drop.
In certain embodiments, the TE system 10 comprises a plurality of cold-side conduits 14 extending parallel to one another along a first direction (indicated by the broken line 16). The plurality of cold-side conduits 14 are configured to have a first working fluid flowing therethrough. Each cold-side conduit of the plurality of cold-side conduits 14 comprises a cold-side tube 18 and a plurality of cold-side shunts 22 in thermal communication with the cold-side tube 18. The TE system 10 further comprises a plurality of hot-side conduits 26 extending parallel to one another along a second direction (indicated by the broken line 30). The plurality of hot-side conduits 26 are configured to have a second working fluid flowing therethrough. The second direction is perpendicular to the first direction. Each hot-side conduit of the plurality of hot-side conduits 26 comprises a hot-side tube 34 and a plurality of hot-side shunts 38 in thermal communication with the hot-side tube 34. The TE system 10 further comprises a plurality of thermoelectric stacks 42. Each TE stack of the plurality of TE stacks 42 comprises a plurality of thermoelectric elements 46 (e.g., including p-type and n-type TE elements), a first plurality of cold-side shunts 50 of a first cold-side conduit 54, a first hot-side shunt 58 of a first hot-side conduit 62, and a second hot-side shunt 66 of a second hot-side conduit 70, each thermoelectric stack of the plurality of thermoelectric stacks 42 extending along a third direction (indicated by the broken line 74) and configured to have electrical current flow through the thermoelectric stack along the third direction.
In certain embodiments as described herein, the TE elements 46, the cold-side shunts 22, and the hot-side shunts 38 are arranged in a “stacked” configuration in which p-type and n-type TE elements 46 alternate with one another and are in electrical communication with one another via the cold-side shunts 22 and the hot-side shunts 38 which are sandwiched between adjacent p-type and n-type TE elements 46 such that electrical current (and/or voltage, power) can flow generally along a single direction through the TE elements 46, the cold-side shunts 22, and the hot-side shunts 38 (e.g., generally parallel directions through the TE elements and the shunts). For example, as illustrated in
Hot-side tubes 34 in
As discussed herein, a “stonehenge” configuration refers to when the TE elements and the shunts are arranged in which p-type and n-type TE elements alternate with one another and are in electrical communication with one another via shunts which are alternately positioned on a hot side of the TE elements and a cold side of the TE elements such that electrical current can flow serially through the TE elements and the shunts in a serpentine fashion (e.g., vertically through the TE elements and horizontally through the shunts).
In some embodiments, the third direction is parallel to the first direction as illustrated in
TEGs are made of often brittle semiconductor material and are comprised of many parts and many solder connections. When placed in a high shock and vibration environment, such as an automotive application, the TEG is highly susceptible to premature failure due to shock and vibration. The use of bellows as further described herein may help isolate the TEG device from such a detrimental environment, but configurations without bellows are also in accordance with certain embodiments described herein.
As schematically illustrated in
In some embodiments, as illustrated in
Non-rigid bonds have been another way to accommodate thermal expansion mismatch. These non-rigid bonds can be positioned at interfaces between the heat exchangers and their associated shunts of a TEG. To maintain low contact resistance for these interfaces, tight tolerances on dimensions of the components of the TEG have previously been used. Such tight tolerances are not desirable from a manufacturing and subsequent cost standpoint. Certain embodiments described herein have rigid bonds between shunts 22, 38 and heat exchangers (e.g., tubes 18, 34 and/or conduits 14, 26) on at least one of the hot side, the cold side, or both. Hot-side shunts 38 and cold-side shunts 22 can be rigidly connected to the hot-side tubes 34 and cold-side tubes 18 respectively. With rigid bonds between the shunts 22, 38 and the corresponding heat exchangers, the need for such tight tolerances can be significantly reduced. There is also a reduction in contact resistance with such a configuration.
In certain embodiments, as illustrated in
In certain embodiments, as shown in
From a flow perspective,
In certain embodiments, as shown in
As described above, the interfacial resistances inherent in many TEG designs can be very detrimental to getting the heat and electrical current into and out of the TE elements. Certain embodiments described herein allow more surface area for TE element placement than some other TEG designs. While certain such designs may use more costly TE materials than other designs, a benefit is that the heat flow is spread over more TEs. This configuration can reduce the impact of harmful contact resistances and can allow the TEG to perform at a higher power output.
In certain embodiments, the plurality of thermoelectric elements 46 are arranged in a plurality of thermoelectric stacks 42. Each thermoelectric stack of the plurality of thermoelectric stacks 42 comprises a cold-side conduit 14 from each cold-side plane of the plurality of cold-side planes and a hot-side conduit 26 from each hot-side plane of the plurality of hot-side planes. In certain embodiments, each thermoelectric stack of the plurality of thermoelectric stacks 42 extends along a third direction (indicated by the broken line 74) perpendicular to the first direction and perpendicular to the second direction.
In certain embodiments, each cold-side conduit of the array of cold-side conduits 14 comprises a cold-side tube 18 and a plurality of cold-side shunts 22 in thermal communication with the cold-side tube 18. Each hot-side conduit of the array of hot-side conduits 26 comprises a hot-side tube 34 and a plurality of hot-side shunts 38 in thermal communication with the hot-side tube 34, wherein each thermoelectric element of the plurality of thermoelectric elements 46 is sandwiched between a cold-side shunt 22 of a cold-side plane and a hot-side shunt 38 of a hot-side plane adjacent to the cold-side plane.
In certain embodiments, each thermoelectric stack of the plurality of thermoelectric stacks 42 is intersected by the cold-side tubes 18 of the thermoelectric stack. In certain embodiments, each thermoelectric stack of the plurality of thermoelectric stacks 42 is intersected by the hot-side tubes 34 of the thermoelectric stack.
In some embodiments, TE couples or stacks do not have internal springs (e.g., springs between adjacent TE couples or shunts). Springs can be positioned at the end of each row of couples on the cold-side as discussed with regard to
Multiple small diameter tubes can be used for the hot-side tubes, the cold-side tubes, or both which can allow for design flexibility in terms of package space and voltage/current split. Tubes can be connected in series with one another for higher voltage and/or in parallel with one another for redundancy. These tubes and the shunts can still take advantage of beneficial hoop stress to improve thermal contact, but would have fewer TE elements in parallel electrical communication with one another. Sufficient smaller diameter tubes can be used to maintain appropriate pressure drop.
In some embodiments, as illustrated in
In certain embodiments, as illustrated in
In certain embodiments, each first manifold sub-section 126 comprises a plurality of bellows 138. Each bellows of the plurality of bellows 138 is positioned between adjacent hot-side conduits 26 of the corresponding set of the hot-side conduits 142. In certain embodiments, the at least one second manifold sub-section 134 comprises one or more bellows 146. Each bellows of the one or more bellows 146 is positioned between adjacent first manifold sub-sections 126 of the plurality of first manifold sub-sections 126. In some embodiments, the plurality of cold-side conduits 14 are in fluidic communication with an inlet cold-side manifold (not shown) and an outlet cold-side manifold 150. In certain embodiments, the manifold sub-sections do not comprise bellows.
In some embodiments, as shown in
The compression plates 158 can be made of various materials (e.g., stainless steel (SST)) and can have a copper portion 162 that connects at least two rows of TE elements 46. The SST may be used to provide extra strength to the compression plate or system. In some embodiments, flexible jumpers 166 further connect the rows of TE elements 46 electrically. In certain embodiments, the compression structures 160 of the plurality of compression structures 160 are separated from one another as illustrated in
Hot shunts 38 can encircle the hot-side conduits 26 (to take advantage of hoop stress) as illustrated in
In some embodiments, as schematically illustrated in
1. Constructing hot-side tubes with hot-side shunts rigidly bonded to the hot-side tubes with TE elements attached as shown in
2. Constructing cold-side tubes with cold-side shunts attached (cold-side shunts can either float on thermal grease or can be rigidly bonded to a bellowed cold-side tube as shown in
3. Pre-tin TE elements and cold-side shunts
4. Stack hot-side tubes and cold-side tubes, compress, and place in a reflow oven to flow solder between the cold-side shunts and TE elements (see
As described herein, in certain embodiments, the criss-cross nature of the tubes, conduits, and/or electrical current flow allows axial thermal expansion of the hot-side tubes to move the cold-side tubes, while the movement is absorbed (e.g., by bellows at the manifolds). In some embodiments, such movement does not take place in the direction of electrical compressive forces. TE couples or stacks and compressed in the direction of flow in the cold-side tubes, which have little thermal expansion movement. In some embodiments, if the cold-side tubes extend in a direction perpendicular to electrical current flow, radial thermal expansion of the hot-side tubes can also be absorbed (e.g., by the cold end bellows) as well as axial thermal expansion as discussed above.
In an operational block 310, the method 300 comprises flowing a first working fluid through a plurality of cold-side conduits extending parallel to one another along a first direction. In an operational block 320, the method 300 further comprises flowing a second working fluid through a plurality of hot-side conduits extending parallel to one another along a second direction. In an operational block 330, the method 300 further comprises flowing electrical current through a plurality of thermoelectric stacks extending parallel to one another along a third direction that is either parallel or perpendicular to at least one of the first direction and the second direction, each thermoelectric stack of the plurality of thermoelectric stacks comprising a plurality of thermoelectric elements in thermal communication with the plurality of cold-side conduits and the plurality of hot-side conduits.
In some embodiments, the third direction is parallel to the first direction. In certain embodiments, the third direction is perpendicular to the first direction and perpendicular to the second direction.
In some embodiments, the method 300 further comprises isolating the plurality of thermoelectric stacks 42 from severe shock and vibration. In some embodiments, each cold-side conduit of the plurality of cold-side conduits 14 is in fluidic communication with an inlet cold-side manifold 78 and an outlet cold-side manifold 82. Each cold-side conduit of the plurality of cold-side conduits 14 comprises at least a first bellows portion 86 mechanically coupled to the inlet cold-side manifold 78 and a second bellows portion 90 mechanically coupled to the outlet cold-side manifold 82. In certain embodiments, no bellows portions are used on at least one of the cold-side manifold or the hot-side manifold.
In some embodiments, the method 300 further comprises keeping the plurality of thermoelectric elements 46 under compression. The method 300 can further comprise rigidly connecting the hot-side shunts 38 with the hot-side tubes 34 and the cold-side shunts 22 with the cold-side tubes 18.
Although certain configurations and examples are disclosed herein, the subject matter extends beyond the examples in the specifically disclosed configurations to other alternative configurations and/or uses, and to modifications and equivalents thereof. Thus, the scope of the claims appended hereto is not limited by any of the particular configurations described below. For example, in any method or process disclosed herein, the acts or operations of the method or process may be performed in any suitable sequence and are not necessarily limited to any particular disclosed sequence. Various operations may be described as multiple discrete operations in turn, in a manner that may be helpful in understanding certain configurations; however, the order of description should not be construed to imply that these operations are order dependent. Additionally, the structures, systems, and/or devices described herein may be embodied as integrated components or as separate components. For purposes of comparing various configurations, certain aspects and advantages of these configurations are described. Not necessarily all such aspects or advantages are achieved by any particular configuration. Thus, for example, various configurations may be carried out in a manner that achieves or optimizes one advantage or group of advantages as taught herein without necessarily achieving other aspects or advantages as may also be taught or suggested herein.
Discussion of the various configurations herein has generally followed the configurations schematically illustrated in the figures. However, it is contemplated that the particular features, structures, or characteristics of any configurations discussed herein may be combined in any suitable manner in one or more separate configurations not expressly illustrated or described. In many cases, structures that are described or illustrated as unitary or contiguous can be separated while still performing the function(s) of the unitary structure. In many instances, structures that are described or illustrated as separate can be joined or combined while still performing the function(s) of the separated structures.
Various configurations have been described above. Although the invention has been described with reference to these specific configurations, the descriptions are intended to be illustrative and are not intended to be limiting. Various modifications and applications may occur to those skilled in the art without departing from the true spirit and scope of the invention as defined in the appended claims.
This application claims the benefit of U.S. Provisional Application No. 61/656,903 filed Jun. 7, 2012, which is incorporated herein in its entirety by reference.
Number | Date | Country | |
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61656903 | Jun 2012 | US |