The present invention relates generally to pumps for cryogenic liquids and, more particularly, to a cryogenic pump that uses an intermediate fluid and reduces differential pressures across the pump seals.
Cryogenic fluids, such as liquid natural gas and hydrogen, are fluids that have boiling points below −130° F./−90° C. Cryogenic fluids are increasing in importance as energy sources and also have many important industrial uses.
For example, hydrogen has grown in importance as an alternative clean energy source as advances are being made in fuel cell technology and the use of hydrogen in home power generation. In addition, use of fuel cell technology, such as in fuel cell powered vehicles, is growing.
As in the case of other cryogenic fluids, such as liquid natural gas, hydrogen is transported and stored more efficiently in liquid form. Furthermore, it is desirable to store hydrogen at high density and to transport and use hydrogen in a reduced volume and at a low cost to aid in the establishment of a practical hydrogen infrastructure. In addition, it is often necessary to pressurize other cryogenic liquids for use and transport as well as efficient storage. Cryogenic pumps are therefore critical components in the storage and transport of cryogenic liquids.
Cryogenic pump seals, particularly in high pressure applications, are prone to leakage which is detrimental to the performance of cryogenic pumps.
There are several aspects of the present subject matter which may be embodied separately or together in the devices and systems described and claimed below. These aspects may be employed alone or in combination with other aspects of the subject matter described herein, and the description of these aspects together is not intended to preclude the use of these aspects separately or the claiming of such aspects separately or in different combinations as set forth in the claims appended hereto.
In one aspect, a pump for pumping a cryogenic liquid includes a pump housing defining a cylinder. A piston is slidably positioned within the cylinder so that an intermediate fluid chamber that is configured to receive an intermediate fluid is defined within the cylinder adjacent to a first end of the piston and a fluid pumping chamber is defined within the cylinder adjacent to a second end of the piston. The fluid pumping chamber includes an inlet and an outlet. An intermediate fluid seal is attached to the piston and is configured to engage the cylinder. A pumped fluid seal is also attached to the piston and configured to engage the cylinder. The pumped fluid seal is spaced from the intermediate fluid seal so that a differential pressure space is defined within the cylinder between the intermediate fluid and pumped fluid seals. A differential pressure vent valve is in fluid communication with the differential pressure space. A differential pressure switch is operatively connected to the differential pressure vent valve and configured to sense a pressure within the differential pressure space and open the differential pressure vent valve when the pressure within the differential pressure space reaches a predetermined pressure level.
In another aspect, a method for pumping a cryogenic liquid includes the steps of providing a pump having a piston slidably positioned within the cylinder and defining an intermediate fluid chamber and a fluid pumping chamber, an intermediate fluid seal and a pumped fluid seal so that a differential pressure space is defined between the intermediate and pumped fluid seals, actuating the piston by cyclically directing an intermediate fluid to the intermediate fluid chamber of the pump so that the cryogenic liquid is received and pumped by the fluid pumping chamber of the pump, detecting a pressure of the differential pressure space and venting the differential pressure space when the detected pressure reaches a predetermined pressure level.
It should be noted that while the embodiments illustrated and presented below are described in terms of pumping liquid hydrogen, the invention may be used to pump other types of cryogenic liquids.
A system for pumping liquid hydrogen to a high pressure is illustrated in
The embodiment of
Fluids other than propane, including but not limited to 1-butene, may alternatively be used as the intermediate fluid to drive pumps 10 and 12.
With reference to
The pump housing 20 of pump 10 defines a cylinder 32 within which a piston 34 is slidingly disposed. The piston includes an intermediate fluid or propane seal 36 and a pumped fluid or hydrogen seal 38. The pump housing 23 of pump 12 similarly defines a cylinder 42 that contains piston 44. The pistons 34 and 44 of pumps 10 and 12, respectively, move between a bottom dead center position, illustrated by pump 10 in
The piston 34 divides the cylinder 32 of pump 10 into a pumping chamber 52 and an intermediate fluid chamber 54. A pumping inlet, indicated by arrow 56 in
With continued reference to
The pressure in the annular dP space may be measured via the vent line 64 (as shown in
The cryogenic pumps 10 and 12 of
The refrigeration coil 84 receives refrigerant from a refrigeration system or other source and cools the propane within the cooling vessel 82. The refrigeration system and coil 84 are preferably configured to cool the propane within the cooling vessel to a temperature corresponding to a pressure lower than the pressure within the hydrogen sump 14 (or 16).
Liquid propane from the cooling vessel 82 is pumped via one or more high pressure intermediate fluid pumps 92 to cryogenic pump actuation valves 94a and 94b for pump 10 and pump actuation valves 96a and 96b for pump 12. As an example only, the high pressure pump(s) 92 may be, a frac style pump that pumps the propane to very high pressure, such as 1000 bar. Alternative high pressure pumps known in the art may alternatively be used.
Starting with the pistons 34 and 44 of pumps 10 and 12 in the positions illustrated in
The cycle of the previous paragraph is repeated so that cryogenic pumps 10 and 12 are driven by intermediate fluid delivered to the pumps in a cyclical fashion while liquid hydrogen is pumped at high pressure in a cyclical fashion through pump discharge lines 58 and 106 during the downstroke/discharge stroke of pumps 10 and 12. As this occurs, intermediate fluid/propane is driven back, in a cyclical fashion through recycle lines 98 and 108, to the cooling vessel 82 during the upstroke/intake strokes of pumps 10 and 12.
A high pressure recirculation valve 112 is also in fluid communication with the outlet of the intermediate fluid pump(s) 92. The high pressure recirculation valve 112 temporarily opens when a piston bottoms out/reaches bottom dead center in each of cryogenic pumps 10 and 12 to prevent over pressure of the system as the corresponding piston transitions to movement in an upstroke/intake direction. The propane flow from intermediate fluid pump(s) 92 that is not directed to the actuation valves is directed back to the cooling vessel 82 through recirculation line 108 (although a dedicated return line may be used) when valve 112 is open.
The propane flow pressure is set by the actuation valves 94a, 94b, 96a and 96b and is determined by the pressure needed to force the pistons of pumps 10 and 12 to get to 1000 bar hydrogen pressure to pump the liquid hydrogen to storage or a process.
Alternative drive systems known in the art may be used in place of the intermediate fluid circuit 80 of
Optional proximity switches 114 and 116 may be used in combination with piston position rods 115 and 117 to indicate the positions of the pistons 34 and 44 of cryogenic pumps 10 and 12. These switches may be used to control the rate of intermediate fluid flow and the speeds of the pistons and to ensure that the pistons can bottom out in the cylinders without damage to minimize the clearance volume in the pumps.
The intermediate fluid seals 36 and 122 and the pumped fluid seals 38 and 124 normally keep the annular dP space 62 of pump 10 and the annular dP space 132 of pump 20 free of hydrogen and propane.
The dP switches 68 of pump 10 and 118 of pump 12 are set to prevent propane intermediate fluid leaking into the liquid hydrogen and liquid hydrogen from leaking into the propane intermediate fluid, and in all cases to reduce the differential pressures across the intermediate fluid seals 36, 122 and the pumped fluid seals 38, 124, preferably to a minimum.
In the embodiment of
In operation, with reference to cryogenic pump 10 of
Conversely, with reference to cryogenic pump 12, during the piston upstroke, which is being completed by pump 12, the pressure of the hydrogen in the pumping chamber 104 of pump 12 will be higher than the intermediate fluid pressure in the intermediate fluid chamber 102 (and line 126). As a result, hydrogen may leak into the annular dP space 132 through pumped fluid seal 124. As in the case of pump 10, dP switch 118 will control the dP vent valve 136 so that the pressure in the annular dP space 132 is slightly less than the intermediate fluid/propane pressure. As a result, hydrogen leaked into the annular dP space 132 will be driven out open dP vent valve 136 instead of through seal 122 and into the propane intermediate fluid if the pressure in the annular dP space 122 rises to a level just below the pressure of the propane in the intermediate fluid chamber 102 (and line 126). The hydrogen exiting the open dP vent valve 136 may be vented or recovered for use, such as in the system supplying hydrogen to sumps 14 and 16.
Pump 10 then operates as described above for pump 12 during its upstroke stage while pump 12 then operates as described above for pump 10 during its downstroke stage, with the pumps 10 and 12 cycling through stages as liquid hydrogen is pumped.
As illustrated in
An embodiment where dedicated dP switches and dP valves is also illustrated in
Similarly, a pumped fluid dP vent valve 262 is in fluid communication with the pumped fluid annular dP space 246. The pumped fluid dP vent valve 262 is controlled by a pumped fluid dP switch 264, which opens and closes based on the difference between the pressure within the pumped fluid annular dP space 246 and the pressure within the intermediate fluid pump line 256. Cryogenic pump 212 features a similar arrangement.
As in the embodiment of
The cryogenic pumps 10 and 12 of
There are several aspects of the present subject matter which may be embodied separately or together in the methods, devices and systems described and claimed below. These aspects may be employed alone or in combination with other aspects of the subject matter described herein, and the description of these aspects together is not intended to preclude the use of these aspects separately or the claiming of such aspects separately or in different combinations as set forth in the claims appended hereto.
While the preferred embodiments of the invention have been shown and described, it will be apparent to those skilled in the art that changes and modifications may be made therein without departing from the spirit of the invention, the scope of which is defined by the appended claims.
This application claims the benefit of U.S. Provisional Application No. 63/243,922, filed Sep. 14, 2021, the contents of which are hereby incorporated by reference.
Number | Date | Country | |
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63243922 | Sep 2021 | US |