Patent Application
20230375134
The present application claims priority under 35 U.S.C. § 119 to German Patent Publication No. DE 102022204884.9 (filed on May 17, 2022), which is hereby incorporated by reference in its complete entirety.
One or more embodiments of the present disclosure relates to a cryotank system comprising a first cryotank device and a second cryotank device, wherein the first cryotank device comprises a first cryotank and the second cryotank device comprises a second cryotank, in particular respectively to hold hydrogen.
Cryotank systems that comprise a cryotank for holding hydrogen are known, and are used in particular as mobile cryotank systems, for example in motor vehicles. Each cryotank may comprise an inner container and an outer container, in which case an insulating vacuum space may be established between the inner container and the outer container.
Cryotank systems may also comprise a plurality of cryotanks, for example two cryotanks, for holding hydrogen. Each of the cryotanks must then also be capable of being filled, for which purpose a plurality of separate filling lines are conventionally provided.
In order to regulate the pressure in a cryotank, in particular during or after the extraction of hydrogen from the cryotank, pressure regulating devices may be provided, for example electrical heating in the cryotank or a recirculating line, through which extracted and warmed hydrogen is partially returned into the cryotank in order to raise the temperature and therefore the pressure in the cryotank.
One or more embodiments are to provide a cryotank system of the type mentioned, which comprises at least two cryotanks, the intention being to allow fueling on one side and simple operation of the system consisting of a plurality of cryogenic liquid-hydrogen tanks, in particular mobile cryogenic liquid-hydrogen tanks. Fueling via supercritical hydrogen and subcooled hydrogen is in this case also intended to be possible.
In accordance with one or more embodiments, a cryotank system comprises a first cryotank device having a first cryotank, and a second cryotank device having a second cryotank. The first cryotank and the second cryotank are operable to hold hydrogen. The first cryotank device has an extraction line for feeding a consumer and a pressure sensor for measuring the pressure in the first cryotank. A partial flow of the extraction line can be branched off at a first junction into a heating line. The heating line leads through a first heat exchanger arranged in the first cryotank and returns into the extraction line after the first heat exchanger at a second junction. The first cryotank device further includes at least one switching element which is operable in such a way that the first heat exchanger is activated or deactivated depending on the pressure measured in the first cryotank by the pressure sensor. The first cryotank can be filled via a first filling line and the second cryotank can be filled via a second filling line. A connecting line is operable to fluidically connect the first filling line to the second filling line.
In accordance with one or more embodiments, a cryotank system comprises two cryotank devices that includes a first cryotank device having a first cryotank and a second cryotank device having a second cryotank. The first cryotank device has a switching element with which, depending on the pressure measured in the first cryotank by a pressure sensor, a first heat exchanger in the first cryotank can be activated or deactivated so that the medium in the first cryotank can be warmed via the heat exchanger and the pressure in the first cryotank can therefore be controlled. The first heat exchanger in the first cryotank may preferably be activated or deactivated by the fluid flowing through the extraction line being branched off towards the first heat exchanger, for example partially or fully, or not, via the switching element. The first cryotank pressure-regulatable in this way is connected to the second cryotank by a connecting line being operable to fluidically connect the first filling line to the second filling line.
The cryotanks may in particular be intended to hold liquid, gaseous or supercritical hydrogen, and the extraction line may be operable to extract gaseous or supercritical hydrogen for feeding a consumer.
The present dual tank system may use two tank systems, preferably with substantially the same design, which are connected via a cryogenic connecting line. This preferentially vacuum-insulated connecting line allows transfer of cryogenic fluid from one cryotank into the other.
Shut-off valves in the filling lines and/or in the connecting line may in this case allow series or parallel fueling of both tanks.
The pressure regulation of the two tanks may be controlled either separately or from one tank, for example from the first cryotank.
The present invention therefore allows fueling of a plurality of cryogenic tanks of a mobile cryogenic tank system for hydrogen storage from one side, from one filling connection, and allows not only fueling via two-phase or multi-phase hydrogen mixtures but also fueling via supercritical hydrogen and subcooled hydrogen, as well as simple operation of the multi-tank system.
In accordance with one or more embodiments, a second heat exchanger is arranged on the extraction line between the first cryotank and the first junction, the second heat exchanger preferably being warmed by a warm fluid, for example by water or a G40 (GLYSANTIN G40) mixture.
In accordance with one or more embodiments, a third heat exchanger is arranged on the heating line between the first heat exchanger and the second junction, i.e., downstream of the first heat exchanger. The third heat exchanger is operable to be warmed by a warm fluid, for example, by water or a G40 mixture. The switching element branches off a part of the hydrogen flow after the second heat exchanger towards the first heat exchanger, where the warm hydrogen is cooled again. The cold hydrogen flow may subsequently be warmed to ambient temperature in the third heat exchanger and, for example, fed back to the remaining part of the hydrogen flow.
In accordance with one or more embodiments, a valve, preferably a switching valve, is provided on the filling line, preferably on each filling line, particularly after the junction of the connecting line and before the first cryotank. Alternatively or in addition, one or two valves, in particular switching valves, may be provided on the connecting line. The pressure regulation of the two tanks may therefore be controlled either separately, when both switching valves are closed, or from one tank, for example, from the first cryotank device, when both valves are open.
As used herein, the term “valve” means a switching valve in the context of this disclosure. By a valve, a throughput may be at least blocked or, depending on the design, also reduced.
In accordance with one or more embodiments, the first heat exchanger is formed by a tube, the tube preferably having inner and/or outer fins.
In accordance with one or more embodiments, the first cryotank is arranged together with the first heat exchanger and preferably also with the second heat exchanger in the interior of a thermally insulating housing, at least the extraction line being fed outwards by passing through the housing. The switching element may be arranged outside the housing or inside the housing. The interior of the housing may furthermore contain valves or hydrodynamic impedances. The second heat exchanger may also be arranged outside the housing.
In accordance with one or more embodiments, the third heat exchanger is arranged outside the housing. It may also be arranged inside the housing. The pressure sensor is preferably likewise arranged outside the housing, or is arranged inside the housing.
In accordance with one or more embodiments, the housing has a filling connection and a venting connection, the filling connection being connected to the filling line and the venting connection being connected to a venting line.
In accordance with one or more embodiments, at least one of the extraction line, the filling line, and the venting line (e.g., the extraction line and the venting line) is provided with at least an overpressure relief which passes through the housing.
In accordance with one or more embodiments, the first cryotank device comprises an electrical heater that is thermally linked to the first cryotank and arranged between the first cryotank and the housing.
The switching element of the first cryotank device may fulfill two functions, namely distribution of the main flow from the first cryotank via the extraction line into flows on the one hand to the pressure regulating system via the heating line and on the other hand of the remaining flow to the consumer further via the extraction line, as well as the generation of pressure losses in the extraction line so that the pressure losses in the pressurization system, i.e., in the heating line and in the first and third heat exchangers are compensated for.
The switching element may preferably be formed by a 3/2-way valve, which has an integrated pressure loss element and is arranged at the first junction or second junction. Preferentially, the 3/2-way valve is therefore arranged before the first heat exchanger or optionally after the third heat exchanger.
In accordance with one embodiment, the switching element comprises two valves, namely one valve at the entry to the pressure regulating system in the heating line and the other valve in the main flow in the extraction line, or the switching element comprises two valves, namely one valve at the exit of the pressure regulating system in the heating line and the other valve in the main flow in the heating line.
In accordance with another embodiment, the switching element comprises a valve at the entry of the pressure regulating system in the heating line, i.e., at the entry of the heating line after the first junction, and a hydrodynamic impedance, for example, a diaphragm, in the main flow of the extraction line, or a valve at the exit of the pressure regulating system in the heating line, i.e., at the exit of the heating line before the second junction, and a hydrodynamic impedance, for example, a diaphragm, in the main flow of the extraction line.
In accordance with one or more embodiments, the switching element comprises a valve in the main flow of the extraction line and a hydrodynamic impedance, for example a diaphragm, at the entry of the pressure regulating system in the heating line, i.e., at the entry of the heating line after the first junction, or a valve in the main flow of the extraction line and a hydrodynamic impedance, for example a diaphragm, at the exit of the pressure regulating system in the heating line, i.e., at the exit of the heating line before the second junction, or the switching element is formed only by a valve in the main flow of the extraction line.
In accordance with one or more embodiments, the second cryotank device is configured with substantially the same design as the first cryotank device, i.e., it has the same components described above as the first cryotank device. In particular, the second cryotank device may likewise have a pressure regulating system as described for the first cryotank device. A venting line may in this case also be provided only on one of the two cryotank devices, for example on the first cryotank device. The gas may therefore, when necessary, be discharged from only one side.
In accordance with one or more embodiments, the pressure sensor is attached to the extraction line.
In accordance with one or more embodiments, a valve is arranged in the venting line. In this case, the venting connection may be configured straightforwardly, for example with a seal for hydrogen gas.
One or more embodiments will be illustrated by way of example in the drawings and explained in the description hereinbelow.
The second cryotank device 32 is in this case configured with substantially the same design as the first cryotank device 31, i.e., it has the same components as the first cryotank device 31. Although the following description of the components relates to the first cryotank device 31, it therefore also applies for the second cryotank device 32.
The first cryotank 1 can be filled via a first filling line d and the second cryotank 1 can be filled via a second filling line d. A connecting line f is operable to fluidically connect the first filling line d to the second filling line d.
A valve 19 is provided on the filling lined, after the junction of the connecting line f and before the first cryotank 1. When the valve 19 is closed, the medium supplied to the filling line d only reaches the connecting line f and therefore the other cryotank 1, or enters into the other cryotank 1 if its valve 19 is not closed.
The first cryotank device 31 comprises an extraction line a for feeding a consumer (at the right-hand end of the extraction line a, indicated in
At a first junction 33, a partial flow of the extraction line a can be branched off into a heating line b. The heating line b leads through a first heat exchanger 14 arranged in the first cryotank 1 and, after this first heat exchanger 14, back into the extraction line a at a second junction 34.
The first cryotank device 31 comprises at least one switching element 15, which is adapted in such a way that the first heat exchanger 14 is activated or deactivated depending on the pressure in the first cryotank 1 measured by the pressure sensor 9, the activation and deactivation of the heat exchanger 14 being carried out by at least one partial flow from the extraction line a being conveyed or not conveyed into the heating line b, and therefore to the heat exchanger 14, via the switching element 15.
The return of the medium from the extraction line a via the heating line b with the heat exchanger 14 via the switching element 15 forms a pressure regulating system. Several variants of the switching element 15, and therefore of pressure regulating systems, are represented in
The first heat exchanger 14 is formed by a tube, in which case the tube may have inner and/or outer fins.
A second heat exchanger 12 is arranged on the extraction line a between the first cryotank 1 and the first junction 33, the second heat exchanger 12 being warmed by a warm fluid, for example, by water or a G40 mixture.
A third heat exchanger 13 is arranged on the heating line b between the first heat exchanger 14 and the second junction 34, the third heat exchanger 13 being warmed by a warm fluid, for example by water or a G40 mixture.
The first cryotank 1 is arranged together with the first heat exchanger 14 and with the second heat exchanger 12 in the interior of a thermally insulating housing 2. The extraction line a is fed outwards through the housing 2. The housing 2 has a filling connection 4 and a venting connection 3, the filling connection 4 being connected to the filling line d and the venting connection 3 being connected to a venting line e. A valve 18 is arranged in the venting line e. The switching element 15, the third heat exchanger 13 and the pressure sensor 9 are arranged outside the housing 2. A valve 18 is arranged in the venting line e.
Besides the pressure sensor 9, a further pressure sensor 11 and a temperature sensor 10 are arranged on the extraction line a. The temperature sensor 10 is arranged after the switching element 15 and before the valve 16, while the further pressure sensor 11 is arranged after the valve 16 and a further valve 17 on the extraction line a. After the valve 17, the extraction line a leads to a consumer connection and/or to a consumer.
A filling level sensor 7 and a temperature sensor 8 are furthermore arranged in the first cryotank 1.
The first cryotank device 31 also comprises an electrical heater 22, the electrical heater 22 being thermally linked to the first cryotank 1 and being arranged between the first cryotank 1 and the housing 2, inside the housing 2.
The extraction line a and the venting line e are each arranged with an overpressure relief 5, 6 which passes through the housing 2, via overpressure lines c.
For the extraction line a,
Similarly, in
In
In another embodiment, which is not represented here, the switching element 15 is a valve 22 in the main flow of the extraction line a2 and a hydrodynamic impedance 20, for example a diaphragm, is arranged at the entry of the pressure regulating system in the heating line b1. Alternatively, a valve 22 may also be arranged in the main flow of the extraction line a2 and a hydrodynamic impedance 20, for example a diaphragm, may be arranged at the exit of the pressure regulating system in the heating line b3.
Lastly,
The terms “coupled,” “attached,” or “connected” may be used herein to refer to any type of relationship, direct or indirect, between the components in question, and may apply to electrical, mechanical, fluid, optical, electromagnetic, electromechanical, or other connections. In addition, the terms “first,” “second,” etc. are used herein only to facilitate discussion, and carry no particular temporal or chronological significance unless otherwise indicated.
Those skilled in the art will appreciate from the foregoing description that the broad techniques of the embodiments can be implemented in a variety of forms. Therefore, while the embodiments have been described in connection with particular examples thereof, the true scope of the embodiments should not be so limited since other modifications will become apparent to the skilled practitioner upon a study of the drawings, specification, and following claims.
| Number | Date | Country | Kind |
|---|---|---|---|
| 102022204884.9 | May 2022 | DE | national |
