Claims
- 1. A crystalline MWW-type titanosilicate catalyst for producing an oxidized compound, which is usable in producing an oxidized compound by an oxidation reaction of a compound having a carbon-carbon double bond and at least one other functional group wherein the carbon-carbon double bond of the compound is oxidized by using a peroxide as an oxidizing agent; the catalyst having an MWW structure and being represented by the following composition formula (1):
- 2. A crystalline MWw-type titanosilicate catalyst for providing an oxidized compound according to claim 1, wherein x is a number of 0.005 to 0.2.
- 3. A crystalline MWW-type titanosilicate catalyst for producing an oxidized compound, which is usable in producing an oxidized compound by an oxidation reaction of a compound having a carbon-carbon double bond and at least one other functional group wherein the carbon-carbon double bond of the compound is oxidized by using a peroxide as an oxidizing agent; the catalyst having an MWW structure and being represented by the following composition formula (2):
- 4. A crystalline MWW-type titanosilicate catalyst for providing an oxidized compound according to claim 3, wherein M in the composition formula (2) is boron.
- 5. A crystalline MWW-type titanosilicate catalyst for providing an oxidized compound according to claim 3, wherein x is a number from 0.005 to 0.2.
- 6. A crystalline MWW-type titanosilicate catalyst for providing an oxidized compound according to claim 3, wherein y is a number from 0.0001 to 0.05.
- 7. A process for producing a crystalline MWW-type titanosilicate catalyst for providing an oxidized compound according to claim 1, said production process comprising:
a first step of heating a mixture comprising a template compound, a titanium-containing compound, a boron-containing compound, a silicon-containing compound and water, to thereby obtain a precursor; and a second step of calcining the precursor obtained in the first step, to thereby obtain a crystalline titanosilicate.
- 8. A process for producing a crystalline MWW-type titanosilicate catalyst for providing an oxidized compound according to claim 7, wherein the template compound is a nitrogen-containing compound.
- 9. A process for producing a crystalline MWW-type titanosilicate catalyst for providing an oxidized compound according to claim 8, wherein the nitrogen-containing compound is at least one compound selected from the group consisting of piperidine, hexamethyleneimine and a mixture thereof.
- 10. A process for producing a crystalline MWW-type titanosilicate catalyst for providing an oxidized compound according to claim 7, wherein the titanium-containing compound is at least one compound selected from the group consisting of titanium oxide, titanium halide and tetraalkyl orthotitanates.
- 11. A process for producing a crystalline MWW-type titanosilicate catalyst for providing an oxidized compound according to claim 7, wherein the boron-containing compound is at least one compound selected from the group consisting of boric acid, boric acid salt, boron oxide, boron halide and trialkylborons.
- 12. A process for producing a crystalline MWW-type titanosilicate catalyst for providing an oxidized compound according to claim 7, wherein the silicon-containing compound is at least one compound selected from the group consisting of silicic acid, silicic acid salt, silicon oxide, silicon halide, fumed silicas, tetraalkylorthosilicates and colloidal silica.
- 13. A process for producing a crystalline MWW-type titanosilicate catalyst for providing an oxidized compound according to claim 7, wherein the ratio between titanium and silicon in the mixture to be used in the first step is 0.001 to 0.3:1 (titanium:silicon) in terms of the molar ratio therebetween.
- 14. A process for producing a crystalline MWW-type titanosilicate catalyst for providing an oxidized compound according to claim 7, wherein the ratio between boron and silicon in the mixture to be used in the first step is 0.3 to 10:1 (boron:silicon) in terms of the molar ratio therebetween.
- 15. A process for producing a crystalline MWW-type titanosilicate catalyst for providing an oxidized compound according to claim 7, wherein the ratio between water and silicon in the mixture to be used in the first step is 5 to 200:1 (water:silicon) in terms of the molar ratio therebetween.
- 16. A process for producing a crystalline MWW-type titanosilicate catalyst for providing an oxidized compound according to claim 7, wherein the ratio between the template compound and silicon in the mixture to be used in the first step is 0.1 to 5:1 (template compound:silicon) in terms of the molar ratio therebetween.
- 17. A process for producing a crystalline MWW-type titanosilicate catalyst for providing an oxidized compound according to claim 7, wherein the heating temperature in the first step is in the range from 110 to 200° C.
- 18. A process for producing a crystalline MWW-type titanosilicate catalyst for providing an oxidized compound according to claim 7, wherein the calcining temperature in the second step is in the range from 200 to 700° C.
- 19. A process for producing a crystalline MWW-type titanosilicate catalyst for providing an oxidized compound according to claim 7, wherein the precursor obtained in the first step is contacted with an acid, and thereafter the second step is performed.
- 20. A process for producing an oxidized compound, comprising: performing an oxidation reaction of a compound having a carbon-carbon double bond and at least one other functional group wherein the carbon-carbon double bond of the compound is oxidized by using a peroxide as an oxidizing agent in the presence of the crystalline MWW-type titanosilicate catalyst for providing an oxidized compound according to claim 1.
- 21. A process for producing an oxidized compound according to claim 20, wherein the oxidizing agent is at least one compound selected from the group consisting of:
hydrogen peroxide, tert-butyl hydroperoxide, tert-amyl hydroperoxide, cumene hydroperoxide, ethylbenzene hydroperoxide, cyclohexyl hydroperoxide, methylcyclohexyl hydroperoxide, tetralin hydroperoxide, isobutylbenzene hydroxide, ethylnaphthalene hydroperoxide and peracetic acid.
- 22. A process for producing an oxidized compound according to claim 20, wherein the other functional group in the compound having a carbon-carbon double bond and at least one of other functional group is at least one functional group selected from the group consisting of:
an alkenyl group, an alkynyl group, an aryl group, an arene group, an alcohol group, a phenol group, an ether group, an epoxide group, a halogen group, an aldehyde group, a ketone group, a carbonyl group, an ester group, an amide group, a cyanate group, an isocyanate group, a thiocyanate group, an amine group, a diazo group, a nitro group, a nitrile group, a nitroso group, a sulfide group, a sulfoxide group, a sulfone group, a thiol group, an orthoester group, a urea group and an imine group.
- 23. A process for producing an oxidized compound according to claim 20, wherein the compound having a carbon-carbon double bond and at least one other functional group is at least one compound selected from the group consisting of: allyl ethers, compounds having from 3 to 10 carbon atoms, ethers of polyhydric alcohol, and carboxylic acid esters.
- 24. A process for producing an oxidized compound according to claim 23, wherein the allyl ether is at least one compound selected from the group consisting of: allyl methyl ether, allyl ethyl ether, allyl propyl ether, allyl butyl ether, allyl vinyl ether and diallyl ether.
- 25. A process for producing an oxidized compound according to claim 23, wherein the compound having a carbon-carbon double bond and at least one other functional group is diallyl ether or allyl alcohol and the oxidizing agent is hydrogen peroxide.
- 26. A process for producing an oxidized compound according to claim 23, wherein the compound having from 3 to 10 carbon atoms is at least one compound selected from the group consisting of: allyl alcohol, allyl bromide, an allyl chloride, acrolein, methacrolein and acrylic acid.
- 27. A process for producing an oxidized compound according to claim 23, wherein the ether of a polyhydric alcohol is at least one compound selected from the group consisting of; ethylene glycol monoalkenyl ether, ethylene glycol dialkenyl ether, 1,2-propanediol monoalkenyl ether, 1,2-propanediol dialkenyl ether, 1,3-propanediol monoalkenyl ether, 1,3-propanediol dialkenyl ether, 1,2-butanediol monoalkenyl ether, 1,2-butanediol dialkenyl ether, 1,3-butanediol monoalkenyl ether, 1,3-butanediol dialkenyl ether, 1,4-butanediol monoalkenyl ether, 1,4-butanediol dialkenyl ether, pentaerythritol monoalkenyl ether, pentaerythritol dialkenyl ether, pentaerythritol trialkenyl ether and pentaerythritol tetraalkenyl ether.
- 28. A process for producing an oxidized compound according to claim 23, wherein the carboxylic acid ester is at least one compound selected from the group consisting of: allyl formate, allyl acetate, allyl propionate, allyl tartrate and allyl methacrylate, trimethylolpropane monoalkenyl ether, trimethylolpropane dialkenyl ether, and trimethylolpropane trialkenyl ether.
- 29. A process for producing an oxidized compound according to claim 20, wherein the oxidation reaction is performed in the presence of at least one solvent selected from the group consisting of: alcohols, ketones, nitrites and water.
- 30. A process for producing an oxidized compound according to claim 20, wherein the oxidized compound is a compound resulting from the epoxidation of the carbon-carbon double bond site of a raw material compound having a carbon-carbon double bond and at least one other functional group, a diol compound resulting from the conversion of the carbon-carbon double bond site of the raw material compound having a carbon-carbon double bond and at least one other functional group, and/or a mixture thereof.
- 31. A crystalline MWW-type titanosilicate catalyst for producing an oxidized compound, which is usable in producing an oxidized compound by an oxidation reaction of a compound containing carbon atoms of not smaller than 2 and not larger than 5, and having a carbon-carbon double bond, wherein the carbon-carbon double bond of the compound is oxidized by using a peroxide as an oxidizing agent; the catalyst having an MWW structure and being represented by the following composition formula (1):
- 32. A crystalline MWW-type titanosilicate catalyst for providing an oxidized compound according to claim 31, wherein the compound containing carbon atoms of not smaller than 2 and not larger than 5, and having a carbon-carbon double bond is propylene or butene.
- 33. A process for producing an oxidized compound, comprising: performing an oxidation reaction of a compound containing carbon atoms of not smaller than 2 and not larger than 5, and having a carbon-carbon double bond, wherein the carbon-carbon double bond of the compound is oxidized by using an oxidizing agent in the presence of a crystalline MWW-type titanosilicate catalyst for producing an oxidized compound, which is usable in producing an oxidized compound by an oxidation reaction of a compound containing carbon atoms of not smaller than 2 and not larger than 5, and having a carbon-carbon double bond, wherein the carbon-carbon double bond of the compound is oxidized by using an oxidizing agent; the catalyst having an MWW structure and being represented by the following composition formula (1):
- 34. A process for producing an oxidized compound according to claim 33, wherein the compound containing carbon atoms of not smaller than 2 and not larger than 5, and having a carbon-carbon double bond is propylene or butene.
- 35. A process for producing an oxidized compound according to claim 33, wherein the oxidizing agent is a peroxide.
- 36. A process for producing an oxidized compound according to claim 33, wherein the oxidized product of the oxidation reaction is an epoxide.
- 37. A process for producing an oxidized compound according to claim 35, wherein the oxidized product of the oxidation reaction is an epoxide.
Priority Claims (1)
Number |
Date |
Country |
Kind |
2000-298133 |
Sep 2000 |
JP |
|
Parent Case Info
[0001] This application is a continuation-in-part application of U.S. application Ser. No. 09/959,937 filed on Nov. 13, 2001, which was the National Stage of International Application No. PCT/JP01/08469, filed on Sep. 27, 2001, which claims the benefit of an application based on U.S. Provisional Application Serial No. 60/247,963 (filed on Nov. 14, 2000).
Provisional Applications (1)
|
Number |
Date |
Country |
|
60247963 |
Nov 2000 |
US |
Continuation in Parts (1)
|
Number |
Date |
Country |
Parent |
09959937 |
Nov 2001 |
US |
Child |
10373168 |
Feb 2003 |
US |