Claims
- 1. In an improved curable resin composition comprising
- (I) 100 parts by weight of a curable resin selected from the group consisting of phenolic resins, formaldehyde resins, xylene resins, furan resins, urea resins, imide resins, melamine resins, alkyd resins, aniline resins, sulfonamide resins, silicone resins, epoxy resins, and copolymers obtained by reacting two or more of these resins, and
- (II) from 0.1 to 100 parts by weight of uniformly dispersed, finely divided particles of a cured silicone rubber exhibiting a particle diameter not exceeding 1 millimeter, where said particles are obtained by curing an organosiloxane composition comprising
- (A) 100 parts by weight of an organopolysiloxane having at least two silicon-bonded lower alkenyl groups in each molecule,
- (B) from 0.3 to 100 parts by weight of an organohydrogenpolysiloxane having at least two silicon-bonded hydrogen atoms in each molecule, and
- (C) an amount of a platinum-containing catalyst sufficient to promote curing of said silicone rubber,
- the improvement comprising the presence in the curable organosiloxane composition of either
- (1) from 0.1 to 50 parts by weight of (D) an aliphatically unsaturated epoxide compound or a reaction product of from 0.1 to 50 parts by weight of said epoxide compound with a quantity of said organohydrogenpolysiloxane in excess of that required to react with said organopolysiloxane; and from 0.1 to 100 parts by weight of (E) an aromatic hydrocarbon containing at least one aliphatically unsaturated group per molecule or a reaction product of said aromatic hydrocarbon with a quantity of said organohydrogenpolysiloxane in excess of that required to react with said organopolysiloxane, or
- (2) a reaction product of from 0.1 to 50 parts by weight of said epoxide compound and from 0.1 to 100 parts by weight of said aromatic hydrocarbon with a quantity of said organohydrogenpolysiloxane in excess of that required to react with said organopolysiloxane.
- 2. A curable resin composition according to claim 1 where the viscosity of ingredient A is from 0.05 to 100 Pa.s at 25.degree. C., the viscosity of ingredient B is from 0.001 to 10 Pa.s, the concentration of ingredient C is equivalent to from 0.1 to 1000 parts of platinum metal per million parts by weight of ingredient A, ingredient D is allyl glycidyl ether, vinylcyclohexene monoxide, glycidyl acrylate, glycidyl methacrylate, ##STR4## where m and n are positive integers, ingredient E is ##STR5## the diameter of said microparticulate silicone rubber is less than 300 microns, and the concentration of said microparticulate silicone rubber in said curable resin composition is from 0.5 to 70 parts.
- 3. A composition according to claim 2 where said resin is a phenolic, imide, epoxy, or a silicone resin, the viscosity of ingredient A is from 0.05 to 10 Pa.s, the hydrocarbon radicals of ingredient A are methyl and vinyl, the concentration of ingredient B is from 0.3 to 100 parts by weight per 100 parts of ingredient A, the organosiloxane composition contains a filler, the concentration of ingredient C is equivalent to from 0.5 to 200 parts by weight per one million parts by weight of ingredient A, and the diameter of the cured silicone rubber particles does not exceed 50 microns.
- 4. A composition according to claim 3 where ingredient A is a dimethylvinylsiloxy-terminated dimethylpolysiloxane, ingredient B is a methylhydrogenpolysiloxane, ingredient C is chloroplatinic acid, and prior to being added to said organosiloxane composition at least one of said epoxy compound and said aromatic compound at prereacted with a portion of the silicon-bonded hydrogen atoms present in the organohydrogenpolysiloxane.
Priority Claims (1)
Number |
Date |
Country |
Kind |
63-47215 |
Feb 1988 |
JPX |
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REFERENCE TO COPENDING APPLICATIONS
This application is a continuation-in-part of copending application Ser. No. 07/317,368, filed on Feb. 28, 1989, now abandoned, which is, in turn, a continuation-in-part of application Ser. No. 234,242, filed on Aug. 19, 1988, and now abandoned.
US Referenced Citations (3)
Number |
Name |
Date |
Kind |
4743670 |
Yoshida et al. |
May 1988 |
|
4778860 |
Morita et al. |
Oct 1988 |
|
4880882 |
Morita et al. |
Nov 1989 |
|
Foreign Referenced Citations (4)
Number |
Date |
Country |
49-132141 |
Dec 1974 |
JPX |
52-014643 |
Feb 1977 |
JPX |
58-219218 |
Dec 1983 |
JPX |
59-096122 |
Jun 1984 |
JPX |
Continuation in Parts (2)
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Number |
Date |
Country |
Parent |
317368 |
Feb 1989 |
|
Parent |
234242 |
Aug 1988 |
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