Claims
- 1. A vulcanizate comprising a product prepared by vulcanizing a blend of chlorobutyl rubber with (1) 25 to about 200 phr of a filler selected from the group consisting of calcium carbonate, magnesium carbonate, magnesium silicate, calcium silicate, aluminum silicate, whiting, pyrogenic silica, hydrated silica, barium sulfate, calcium sulfate, titanium dioxide and mica and (2) a vulcanization agent comprising from about 0.25 to about 10 phr of an alkyl phenol disulfide and from about 0.25 to about 10 phr of a guanidine compound selected from the group consisting of diphenyl guanidine, di-ortho-tolylguanidine, triphenyl guanidine and di-ortho-tolyguanidine salt of dicatechol borate.
- 2. The vulcanizate of claim 1 wherein the vulcanization agent comprises an alkyl phenol disulfide and di-ortho-tolylguanidine salt of dicatechol borate.
- 3. The vulcanizate of claim 1 wherein the mixtures of chlorobutyl rubber and vulcanization agent additionally contains zinc oxide.
- 4. The vulcanizate of claim 1 wherein the vulcanization agent comprises from about 1 to about 5 phr of alkyl phenol disulfide and from about 1 to about 5 phr of a guanidine compound.
- 5. The vulcanizate of claim 3 wherein the zinc oxide is present in the mixture in amounts ranging from about 2 to about 20 phr.
- 6. The vulcanizate of claim 3 wherein the zinc oxide is present in the mixture in amounts ranging from about 3 to about 7 phr.
- 7. The vulcanizate of claim 1 wherein the chlorobutyl rubber is crosslinked in the presence of steam.
- 8. The vulcanizate of claim 1 wherein the alkyl phenol disulfide contains from about 16% to about 28% sulfur, has a specific gravity ranging from about 1.00 to about 1.42.
- 9. The vulcanizate of claim 1 wherein the alkyl phenol disulfide has a specific gravity ranging from about 1.34 to about 1.42.
- 10. The vulcanizate of claim 2 wherein the di-ortho-tolylguanidine salt of dicatechol borate has a specific gravity from about 1.20 to about 1.25, a melting point of about 165.degree. C. and a molecular weight of about 467.
- 11. The vulcanizate of claim 1 wherein the vulcanization composition additionally contains fillers.
- 12. The vulcanizate of claim 11 wherein the fillers are selected from the group consisting of calcium carbonate, magnesium carbonate, magnesium silicate, calcium silicate, aluminum silicate, whiting, pyrogenic silica, hydrated silica, barium sulfate, calcium sulfate, titanium dioxide and mica.
Parent Case Info
This is a Divisional of application Ser. No. 07/374,807, filed July 3, 1989, now U.S. Pat. No. 4,929,688 which is a divisional of application Ser. No. 07/231,288, filed Aug. 11, 1988, now U.S. Pat. No. 4,873,290.
US Referenced Citations (2)
Non-Patent Literature Citations (1)
Entry |
W. Warrach and Don Tsou, "A Curative for Chlorobutyl Rubber 3-Methyl-Thiazolidine-Thione-2" Elastomerics, Nov. 1984, pp. 26-29. |
Divisions (2)
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Number |
Date |
Country |
Parent |
374807 |
Jul 1989 |
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Parent |
231288 |
Aug 1988 |
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