Patent Application
20230290959
This application is a continuation of International Application No. PCT/CN2021/092986, filed on May 11, 2021, which claims priority to Chinese Patent Application No. 202010473157.1, filed on May 29, 2020. The disclosures of the aforementioned applications are hereby incorporated by reference in their entireties.
The present disclosure relates to a current collector and an application thereof, and, to the technical field of lithium-ion batteries.
Due to the high energy density and high power density, at present, lithium-ion batteries have become secondary batteries that are used very extensively. A conventional current collector of a lithium-ion battery is made of metal foil material, a positive electrode usually adopts metal aluminum foil and a negative electrode usually adopts metal copper foil; however, once an internal short circuit occurs in the lithium-ion battery which is directly prepared with the metal foil, the current cannot be cut off inside the battery, so that heat is accumulated and then thermal runaway is finally caused. In order to solve this problem, some researchers use a new type of polymer/metal composite current collector, in which a non-conductive polymer film is usually used as substrate and the upper and lower surfaces of the polymer film is coated with a layer of metal material, to replace a conventional metal current collector. For example, the upper and lower surfaces of the PET (polyethylene terephthalate) film are coated with metal aluminum as a positive current collector, and the upper and lower surfaces of the PET (polyethylene terephthalate) film are coated with metal copper as a negative current collector, which have achieved a certain effect of improving the safety performance of the battery.
However, after the above polymer/metal composite current collector is connected to a tab, the contact impedance of the tab connection region is high due to a poor binding force between the tab and the current collector, and in addition, a qualified rate of the tab connected to the composite current collector is also relatively low, which ultimately has a certain impact on the performance of the composite current collector and the lithium ion battery. Therefore, how to improve the contact resistance and the connection qualified rate of the tab connected to the polymer/metal composite current collector has attracted more and more attention.
The present disclosure provides a current collector for solving an existing problem of high contact resistance and low connection qualified rate of the tab on a polymer/metal composite current collector.
A first aspect of the present disclosure provides a current collector, which includes M metal layers and N polymer layers. The metal layer and the polymer layer are stacked. Each of L metal layers includes a tab connection region and a non-tab connection region, and a thickness of the tab connection region is greater than that of the non-tab connection region. M≥1, N≥1, L≥1, and M≥L.
The present disclosure provides a current collector having an improved structure compared to the existing composite current collector, including a polymer layer and a metal layer that are stacked. The metal layer is connected with a tab and thus the metal layer connected with the tab is divided into the tab connection region and the non-tab connection region. Those skilled in the art may set the number of polymer layers and metal layers and the connection pattern of the tabs according to the prior art and in combination with the actual preparation requirements, and then perform a thickening treatment to the metal layer in the tab connection region so that, in the final current collector structure, the thickness of a portion of the metal layer corresponding to the tab connection region is greater than that of a portion of the metal layers corresponding to the non-tab connection region. Specifically, in the preparation process of a current collector, those skilled in the art may prepare a current collector according to actual needs and existing process methods. For example, the current collector with a uniform thickness of metal layer may be first prepared according to the prior art, and then the portion of the metal layer corresponding to the tab connection region is subjected to a thickening treatment by conventional evaporation, sputtering or electroplating methods; alternatively, a region with the same area as that of the tab connection region may be reserved firstly in the polymer layer, and then a metal layer with a corresponding thickness is directly disposed on the reserved region. The current collector structure provided by the present application may be obtained by any of the above two methods, and there is no further limitation on the preparation pattern in the disclosure. The present disclosure provides a current collector, which effectively improves the welding strength of the tab by performing a thickening treatment on the tab connection region for connecting the tab in the metal layer, so as to improve the binding force between the tab and the current collector, reduce the contact impedance of the tab connection region, and increase the connection qualified rate between the tab and the metal layer.
The present disclosure is applicable to a variety of current collector structures, which are described in detail as follows.
In one specific embodiment, the current collector includes the polymer layer and the metal layer disposed on an upper surface or a lower surface of the polymer layer.
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In another specific embodiment, the current collector includes at least one unit which includes the polymer layer, a first metal layer disposed on the upper surface of the polymer layer and a second metal layer disposed on a lower surface of the polymer layer, and the first metal layer and/or the second metal layer in at least one unit each include a tab connection region and a non-tab connection region.
The current collector structure provided by the present disclosure is also applicable to a current collector structure with multiple units.
It's understood that
Those skilled in the art may set the number and connection position of the tab according the actual requirements, and then perform a thickening treatment on the tab connection region for connecting the tab that is located in the metal layer, which is not specified in detail by the present disclosure.
When the current collector includes two or more units, the applicant further finds that the problems of low connection qualified rate and high contact impedance also exist at the connections between the units, and similarly to the connection of the tab, the method of thickening the metal layer of the tab connection region is also applicable to the connection of the metal layers between the units. Those skilled in the art can perform a thickening treatment on a metal layer connection region which is located in a certain metal layer and configured for connecting with another metal layer according to actual requirements, that is, the certain metal layer includes a metal layer connection region and a non-metal layer connection region and the metal layer connection region is configured for connecting with a metal layer in another unit, thereby obtaining a current collector structure with multiple units. And the thickness of a portion of the metal layer corresponding to the metal layer connection region is greater than that of a portion of the metal layer corresponding to the non-metal layer connection region. In addition, it should be noted that since the connection of the metal layers between units involves the metal layer in the upper unit and the metal layer in the lower unit, both of the two metal layers may be thickened or only one of the two metal layers may be thickened in the actual preparation process, and the number of the thickened metal layers is not specifically limited by the present disclosure.
In one specific embodiment, the current collector includes X units, where the first metal layer and/or the second metal layer in Z units include the tab connection region and the non-tab connection region, and the first metal layer and/or the second metal layer of at least one unit in the remaining (X-Z) units include a metal layer connection region and a non-metal layer connection region, where the thickness of the metal layer connection region is greater than that of the non-metal layer connection region, X≥2, Z≥1 and X−Z≥0.
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In another specific embodiment, the current collector includes X units. One of the first metal layer and the second metal layer in at least one unit of Z units includes the tab connection region and the non-tab connection region, and the other of the first metal layer and the second metal layer includes a metal layer connection region and a non-metal layer connection region, where the thickness of the metal layer connection region is greater than that of the non-metal layer connection region, X≥2, Z≥1 and X−Z≥0.
In yet another specific embodiment, the current collector includes X units, where X≥2, and the first metal layer or the second metal layer in Z units, or each of the first metal layer and the second metal layer in Z units includes the tab connection region and the non-tab connection region. One of the first metal layer and second metal layer in at least one unit of the Z units includes the tab connection region and the non-tab connection region, and the other of the first metal layer and second metal layer includes the metal layer connection region and the non-metal layer connection region. Meantime, the first metal layer and/or the second metal layer in at least one unit in the remaining X-Z units each include the metal layer connection region and the non-metal layer connection region, where the thickness of the metal layer connection region is greater than that of the non-metal layer connecting region and Z≥1.
Through further research, the applicant finds that the thickness difference between the portion of the metal layer corresponding to the tab connection region and the portion of the metal layer corresponding to the non-tab connection region also has a certain influence on the performance of the current collector, and specifically, the thickness of the portion of the metal layer corresponding to the tab connection region is 1.05-10 times to that of the portion of the metal layer corresponding to the non-tab connection region.
Further, the thickness of the portion of the metal layer corresponding to the tab connection region is 1.5-3 times to that of the portion of the metal layer corresponding to the non-tab connection region.
Similarly to the influence of the thickness difference between the tab connection region and the non-tab connection region, the thickness difference between the metal layer connection region and the non-metal layer connection region also has a certain influence on the performance of the current collector. Specifically, the thickness of the portion of the metal layer corresponding to the metal layer connection region is 1.05-10 times to that of the portion of the metal layer corresponding to the non-metal layer connection region.
By adopting the current collector structure provided by the present disclosure, the welding strength of the tab and the current collector is effectively improved, and specifically, the welding strength of the tab is more than or equal to 0.4 N/mm.
To sum up, the present disclosure provides a current collector, which effectively improves the welding strength of the tab by performing a thickening treatment on the tab connection region for connecting the tab in the metal layer, thereby improving the binding force between the tab and the current collector, reducing the contact impedance of the tab connection region, and improving the connection qualified rate between the tab and the metal layer.
A second aspect of the present disclosure provides a lithium-ion battery, which includes any of the above current collectors.
On the basis of the current collector provided by the present application, those skilled in the art can prepare a positive sheet according to the prior art and then a lithium-ion battery by combination with a negative sheet, a separator, electrolyte, a tab, and the like. The lithium-ion battery provided by the present disclosure effectively reduces the impedance of the lithium ion battery and improves the connection qualified rate of the lithium ion batteries by using the current collector of the present disclosure.
The implementation of the present disclosure has at least the following advantages:
1. The present disclosure provides a current collector, which effectively improves the welding strength of the tab by performing a thickening treatment on the tab connection region for connecting the tab on the metal layer, thereby improving the binding force between the tab and the current collector, reducing the contact impedance of the tab connection region, and improving the connection qualified rate between the tab and the metal layer.
2. When the current collector includes multiple units, the welding strength between the units may be effectively improved by thickening the metal layer connection region which is located in the metal layer and used for the connection between the units, thereby reducing the contact resistance between the current collector units and improving the connection qualified rate between the current collector units.
3. The lithium-ion battery provided by the present disclosure effectively uses the current collector provided by the present disclosure, which reduces the ohmic impedance of the lithium ion battery and improves the connection qualified rate of lithium ion batteries.
1-polymer layer; 2-metal layer; 2-1-first metal layer; 2-2-second metal layer; 3-tab.
To make the objectives, technical solutions, and advantages of the present disclosure clearer, the technical solutions in embodiments of the present disclosure will be described clearly and comprehensively below with reference to the embodiments of the present disclosure. Apparently, the described embodiments are merely a part rather than all embodiments of the present disclosure. All other embodiments obtained by persons of ordinary skill in the art based on embodiments of the present disclosure without creative effort shall fall within the protection scope of the present disclosure.
Positive tabs used in the following Examples and Comparative Examples were purchased from Lianyungang Delixin Electronic Technology Co., Ltd., and the positive tabs are made of aluminum; the negative tabs were purchased from Lianyungang Delixin Electronic Technology Co., Ltd., and the negative tabs are made of one of nickel, metal nickel coated with copper on its surface, and stainless steel.
UM-20 ultrasonic-wave metal welder from Shenzhen STGN Electronic Technology Co., Ltd. was used for ultrasonic welding, where welding parameters were as follows: welding power of 3000 W, welding frequency of 20 kHz, welding vibration amplitude of 40 μm, welding time of 0.42 s and welding pressure of 0.3 MPa.
Type ZXL-200W laser welder from Dongguan Zhengxin Laser Science and Technology Co., Ltd. is used for laser welding, where welding parameters were as follows: laser wavelength of 1064 nm, laser power of 200 W, pulse frequency of 150 Hz, and pulse width of 10 ms.
The structure of current collector provided by this Example is shown in
The tab was clamped with a clamp by using LK-108A Tensile Tester from Likong
Instrument Technology Co., Ltd., and then a tensile force value N for pulling the tab off the current collector was tested by using the Tensile Tester. The width of the tab was represented as D, and then the tab welding strength F may be calculated according to the equation F=N/D. Results showed that the tab welding strength in this Example was 0.6 N/mm.
The structure of current collector provided by this Example is shown in
With the same welding strength test method as that in Example 1, results showed that the tab welding strength in this Example was 1.1 N/mm.
The structure of current collector provided by this Example was shown in
With the same welding strength test method as that in Example 1, results showed that the tab welding strength in this Example was 1.6 N/mm.
The structure of current collector provided by this Example was shown in
With the same welding strength test method as that in Example 1, results showed that the tab welding strength in this Example was 2.2 N/mm.
The structure of current collector provided by this Example was shown in
With the same welding strength test method as that in Example 1, results showed that the tab welding strength in this Example was 1.9 N/mm.
The structure of current collector provided by this Example was shown in
With the same welding strength test method as that in Example 1, results showed that the tab welding strength in this Example was 0.4 N/mm.
The structure of current collector provided by this Example was shown in
With the same welding strength test method as that in Example 1, results showed that the tab welding strength in this Example was 0.9 N/mm.
The structure of current collector provided by this Example was shown in
With the same welding strength test method as that in Example 1, results showed that the tab welding strength in this Example was 1.5 N/mm.
The structure of current collector provided by this Example was shown in
With the same welding strength test method as that in Example 1, results showed that the tab welding strength in this Example was 2.1 N/mm.
The structure of current collector provided by this Example was shown in
With the same welding strength test method as that in Example 1, results showed that the tab welding strength in this Example was 1.8 N/mm.
The structure of current collector provided by this Example was shown in
With the same welding strength test method as that in Example 1, results showed that the tab welding strength in this Example was 1.9 N/mm.
The structure of current collector provided by this Example was shown in
With the same welding strength test method as that in Example 1, results showed that the tab welding strength in this Example was 1.7 N/mm.
The structure of current collector provided by this Example was shown in
With the same welding strength test method as that in Example 1, results showed that the tab welding strength in this Example was 2.3 N/mm.
The structure of current collector provided by this Example was shown in
With the same welding strength test method as that in Example 1, results showed that the tab welding strength in this Example was 2 N/mm.
The structure of current collector provided by this Example was shown in
With the same welding strength test method as that in Example 1, results showed that the tab welding strength in this Example was 1.9 N/mm.
The structure of current collector provided by this Example was shown in
With the same welding strength test method as that in Example 1, results showed that the tab welding strength in this Example was 1.7 N/mm.
The structure of current collector provided by this Example was shown in
With the same welding strength test method as that in Example 1, results showed that the tab welding strength in this Example was 1.5 N/mm.
The structure of current collector provided by this Example was shown in
With the same welding strength test method as that in Example 1, results showed that the tab welding strength in this Example was 1.5 N/mm.
The structure of current collector provided by this Example was shown in
With the same welding strength test method as that in Example 1, results showed that the tab welding strength in this Example was 2.6 N/mm.
The structure of current collector provided by this Example was shown in
With the same welding strength test method as that in Example 1, results showed that the tab welding strength in this Example was 2.4 N/mm.
The structure of current collector provided by this Example was shown in
With the same welding strength test method as that in Example 1, results showed that the tab welding strength in this Example was 2.9 N/mm.
The structure of current collector provided by this Example was shown in
With the same welding strength test method as that in Example 1, results showed that the tab welding strength in this Example was 2.7 N/mm.
The structure of current collector provided by this Example was shown in
With the same welding strength test method as that in Example 1, results showed that the tab welding strength in this Example was 2 N/mm.
The structure of current collector provided by this Example was shown in
With the same welding strength test method as that in Example 1, results showed that the tab welding strength in this Example was 1.9 N/mm.
The current collector provided by the Comparative Example included a polymer layer and a metal layer, and the metal layer was disposed on the upper surface of the polymer layer. The polymer layer was a PET layer, the metal layer was an aluminum layer, the thickness of the polymer PET layer was 6 μm, and the thickness of the metal layer was 1 μm. A positive tab was welded to the metal aluminum layer by ultrasonic welding. The positive tab had a thickness of 0.1 mm and a width of 6 mm.
With the same welding strength test method as that in Example 1, results showed that the tab welding strength in this Comparative Example was 0.2 N/mm.
The current collector provided by the Comparative Example included a polymer layer and a metal layer, and the metal layer was disposed on the upper surface of the polymer layer. The polymer layer was a PET layer, the metal layer was a copper layer, the thickness of the polymer PET layer was 6 μm, and the thickness of the metal layer was 1 μm. A negative tab was welded to the metal copper layer by ultrasonic welding, and was made of nickel. The negative tab had a thickness of 0.1 mm and a width of 6 mm.
With the same welding strength test method as that in Example 1, results showed that the tab welding strength in this Comparative Example was 0.1 N/mm.
The current collector provided by the Comparative Example included a polymer layer and metal layers, and the metal layers were respectively disposed on the upper surface and lower surface of the polymer layer. The polymer layer was a PP layer, the metal layers were aluminum layers, the thickness of the polymer PP layer was 22 μm, and the thickness of each metal layer was 1.1 μm. A positive tab was welded to the metal aluminum layer that was located on the upper surface of the polymer layer by ultrasonic welding. The positive tab had a thickness of 0.08 mm and a width of 8 mm.
With the same welding strength test method as that in Example 1, results showed that the tab welding strength in this Comparative Example was 0.3 N/mm.
The current collector provided by the Comparative Example included a polymer layer and metal layers, and the metal layers were respectively disposed on the upper surface and lower surface of the polymer layer. The polymer layer was a PP layer, the metal layers were copper layers, the thickness of the polymer PP layer was 25 μm, and the thickness of each metal layer was 0.9 μm. A negative tab was welded to the metal copper layer that was located on the upper surface of the polymer layer by ultrasonic welding, and was made of nickel. The negative tab had a thickness of 0.08 mm and a width of 6 mm.
With the same welding strength test method as that in Example 1, results showed that the tab welding strength in this Comparative Example was 0.2 N/mm.
The current collector provided by the Comparative Example included a polymer layer and metal layers, and the metal layers were respectively disposed on the upper surface and lower surface of the polymer layer. The polymer layer was a PP layer, the metal layers were aluminum layers, the thickness of the polymer PP layer was 8 μm, and the thickness of each metal layer was 0.7 μm. A positive tab was welded to each of metal aluminum layers that were respectively located on the upper surface and lower surface of the polymer layer by ultrasonic welding. The positive tab had a thickness of 0.05 mm and a width of 8 mm.
With the same welding strength test method as that in Example 1, results showed that the tab welding strength in this Comparative Example was 0.2 N/mm.
The current collector provided by the Comparative Example included a polymer layer and metal layers, and the metal layers were respectively disposed on the upper surface and lower surface of the polymer layer. The polymer layer was a PP layer, the metal layers were copper layers, the thickness of the polymer PP layer was 8 μm, and the thickness of each metal layer was 0.7 μm. A negative tab was welded to each of metal copper layers that were respectively located on the upper surface and lower surface of the polymer layer by ultrasonic welding; and was made of metal nickel coated with copper on its surface. The negative tab had a thickness of 0.05 mm and a width of 8 mm.
With the same welding strength test method as that in Example 1, results showed that the tab welding strength in this Comparative Example was 0.2 N/mm.
The current collector provided by the Comparative Example included 9 units, each unit included a polymer layer and metal layers, and the metal layers were respectively disposed on the upper surface and the lower surface of the polymer layer. The polymer layer was a PP layer, the metal layers were aluminum layers, the thickness of the polymer PP layer was 8 μm, and the thickness of each metal layer was 0.6 μm. A positive tab was welded to the metal aluminum layer that was located on the upper surface of the polymer layer in first unit by ultrasonic welding. The positive tab had a thickness of 1 mm and a width of 10 mm.
With the same welding strength test method as that in Example 1, results showed that the tab welding strength in this Comparative Example was 0.2 N/mm.
The current collector provided by the Comparative Example included 10 units, each unit included a polymer layer and metal layers, and the metal layers were respectively disposed on the upper surface and the lower surface of the polymer layer. The polymer layer was a PP layer, the metal layers were nickel layers, the thickness of the polymer PP layer was 8 μm, and the thickness of each metal layer was 0.6 μm. A negative tab was welded to the metal nickel layer that was located on the upper surface of the polymer layer in first unit by ultrasonic welding; and was made of nickel. The negative tab had a thickness of 1 mm and a width of 10 mm.
With the same welding strength test method as that in Example 1, results showed that the tab welding strength in this Comparative Example was 0.1 N/mm.
The current collector provided by the Comparative Example included 9 units, each unit included a polymer layer and metal layers, and the metal layers were respectively disposed on the upper surface and the lower surface of the polymer layer. The polymer layer was a PET layer, the metal layers were aluminum layers, the thickness of the polymer PET layer was 9 μm, and the thickness of each metal layer was 1 μm. A positive tab was welded to each of the metal aluminum layers that were respectively located on the upper surface of the polymer layer in first unit and the lower surface of the polymer layer in ninth unit by ultrasonic welding. The positive tab had a thickness of 0.2 mm and a width of 12 mm.
With the same welding strength test method as that in Example 1, results showed that the tab welding strength in this Comparative Example was 0.3 N/mm.
The current collector provided by the Comparative Example included 10 units, each unit included a polymer layer and metal layers, and the metal layers were respectively disposed on the upper surface and the lower surface of the polymer layer. The polymer layer was a PET layer, the metal layers were stainless steel layers, the thickness of the polymer PET layer was 9 μm, and the thickness of each metal layer was 1 μm. A negative tab was welded to each of the metal stainless steel layers that were respectively located on the upper surface of the polymer layer in first unit and the lower surface of the polymer layer in tenth unit by laser welding. The negative tab was made of stainless steel and had a thickness of 0.2 mm and a width of 12 mm.
With the same welding strength test method as that in Example 1, results showed that the tab welding strength in this Comparative Example was 0.3 N/mm.
The current collector provided by the Comparative Example included 9 units, each unit included a polymer layer and metal layers, and the metal layers were respectively disposed on the upper surface and the lower surface of the polymer layer. The polymer layer was a PP layer, the metal layers were aluminum layers, the thickness of the polymer PP layer was 8 μm, and the thickness of each metal layer was 0.8 μm. A positive tab was welded to each of the metal aluminum layers that were respectively located on the upper surface and lower surface of the polymer layer in first unit and the lower surface of the polymer layer in ninth unit by laser welding. The positive tab had a thickness of 0.03 mm and a width of 15 mm.
With the same welding strength test method as that in Example 1, results showed that the tab welding strength in this Comparative Example was 0.3 N/mm.
The current collector provided by the Comparative Example included 10 units, each unit included a polymer layer and metal layers, and the metal layers were respectively disposed on the upper surface and the lower surface of the polymer layer. The polymer layer was a PP layer, the metal layers were nickel layers, the thickness of the polymer PP layer was 8 μm, and the thickness of each metal layer was 0.8 μm. A negative tab was welded to each of the metal nickel layers that were respectively located on the upper surface and the lower surface of the polymer layer in first unit and the lower surface of the polymer layer in tenth unit by laser welding. The negative tab was made of nickel and had a thickness of 0.03 mm and a width of 15 mm.
With the same welding strength test method as that in Example 1, results showed that the tab welding strength in this Comparative Example was 0.2 N/mm.
According to the disclosure, the lithium-ion battery is prepared on the basis of the current collectors provided by the above Examples and Comparative Examples. In the following Examples and Comparative Examples, lithium-cobaltate positive electrode material with a specific capacity of 181 mAh/g was purchased from Beijing Dangsheng Material Science and Technology Co., Ltd.; and graphite negative electrode material with a specific capacity of 359 mAh/g was purchased from Shanghai Shanshan Science and Technology Co., Ltd.
Polyethylene (PE) porous separator with a thickness of 12 μm was a wet-process separator ND12 prepared by Shanghai Enjie New Material Technology Co., Ltd.; and electrolyte was LBC445B33 electrolyte from Shenzhen Xinzhoubang Science and Technology Co., Ltd.
95 parts by mass of lithium-cobaltate positive electrode material, 2 parts by mass of acetylene black conductive agent, 0.5 parts by mass of carbon nanotube conductive agent, 2.5 parts by mass of PVDF binder, and 60 parts by mass of solvent NMP were stirred in a dual planet mixer under a condition of 30 r/min for revolution and 1,500 r/min for rotation in vacuum for 4 h and dispersed to form a uniform slurry, then the slurry was coated on the current collector provided by Example 1 and baked at 120° C. to dry, rolled under 40 tons of rolling pressure and cut into a positive electrode sheet. The areal density of the positive electrode sheet was 20 mg/cm2, and the compaction density of the positive electrode sheet was 4.16 g/cm3.
95 parts by mass of graphite negative electrode material, 1.5 parts by mass of acetylene black conductive agent, 0.5 parts by mass of carbon nanotube conductive agent, 2.0 parts by mass of styrene-butadiene rubber (SBR) binder, 1.0 part by mass of carboxymethyl cellulose (CMC), and 100 parts by mass of solvent water were stirred in a dual planet mixer under a condition of 30 r/min for revolution and 1,500 r/min for rotation in vacuum for 4 h and dispersed to form a uniform slurry, then the slurry was coated on the current collector provided by Example 6 and baked at 110° C. to dry, rolled under 40 tons of rolling pressure and cut into a negative electrode sheet. The areal density of the negative electrode sheet was 10 mg/cm2, and the compaction density of the negative electrode sheet was 1.74 g/cm3.
The above positive electrode sheet and the negative electrode sheet were combined with polyethylene (PE) porous separator and electrolyte to prepare the lithium-ion battery C1 through a conventional preparation process.
The current collector provided in Example 2 was used as a positive electrode, the current collector provided in Example 7 was used as a negative electrode, and the lithium-ion battery C2 was prepared using the same preparation method as that used in Example 25.
The current collector provided in Example 3 was used as a positive electrode, the current collector provided in Example 8 was used as a negative electrode, and the lithium-ion battery C3 was prepared using the same preparation method as that used in Example 25.
The current collector provided in Example 4 was used as a positive electrode, the current collector provided in Example 9 was used as a negative electrode, and the lithium-ion battery C4 was prepared using the same preparation method as that used in Example 25.
The current collector provided in Example 5 was used as a positive electrode, the current collector provided in Example 10 was used as a negative electrode, and the lithium-ion battery C5 was prepared using the same preparation method as that used in Example 25.
The current collector provided in Example 11 was used as a positive electrode, the current collector provided in Example 12 was used as a negative electrode, and the lithium-ion battery C6 was prepared using the same preparation method as that used in Example 25.
The current collector provided in Example 13 was used as a positive electrode, the current collector provided in Example 14 was used as a negative electrode, and the lithium-ion battery C7 was prepared using the same preparation method as that used in Example 25.
The current collector provided in Example 15 was used as a positive electrode, the current collector provided in Example 16 was used as a negative electrode, and the lithium-ion battery C8 was prepared using the same preparation method as that used in Example 25.
The current collector provided in Example 17 was used as a positive electrode, the current collector provided in Example 18 was used as a negative electrode, and the lithium-ion battery C9 was prepared using the same preparation method as that used in Example 25.
The current collector provided in Example 19 was used as a positive electrode, the current collector provided in Example 20 was used as a negative electrode, and the lithium-ion battery C10 was prepared using the same preparation method as that used in Example 25.
The current collector provided in Example 21 was used as a positive electrode, the current collector provided in Example 22 was used as a negative electrode, and the lithium-ion battery C11 was prepared using the same preparation method as that used in Example 25.
The current collector provided in Example 23 was used as a positive electrode, the current collector provided in Example 24 was used as a negative electrode, and the lithium-ion battery C12 was prepared using the same preparation method as that used in Example 25.
The current collector provided in Comparative Example 1 was used as a positive electrode, the current collector provided in Comparative Example 2 was used as a negative electrode, and the lithium-ion battery A1 was prepared using the same preparation method as that used in Example 25.
The current collector provided in Comparative Example 3 was used as a positive electrode, the current collector provided in Comparative Example 4 was used as a negative electrode, and the lithium-ion battery A2 was prepared using the same preparation method as that used in Example 25.
The current collector provided in Comparative Example 5 was used as a positive electrode, the current collector provided in Comparative Example 6 was used as a negative electrode, and the lithium-ion battery A3 was prepared using the same preparation method as that used in Example 25.
The current collector provided in Comparative Example 7 was used as a positive electrode, the current collector provided in Comparative Example 8 was used as a negative electrode, and the lithium-ion battery A4 was prepared using the same preparation method as that used in Example 25.
The current collector provided in Comparative Example 9 was used as a positive electrode, the current collector provided in Comparative Example 10 was used as a negative electrode, and the lithium-ion battery A5 was prepared using the same preparation method as that used in Example 25.
The current collector provided in Comparative Example 11 was used as a positive electrode, the current collector provided in Comparative Example 12 was used as a negative electrode, and the lithium-ion battery A6 was prepared using the same preparation method as that used in Example 25.
In the present disclosure, the lithium-ion batteries C1-C12 prepared in Examples 25-36 and the lithium-ion batteries A1-A6 prepared in Comparative Examples 13-18 were tested for their ohmic impedance and connection qualified rate, and the results were shown in Table 1.
The method for testing ohmic impedance includes: testing the ohmic impedance of the battery through an internal resistance tester (RBM-200 intelligent battery internal resistance tester of Shenzhen Chaosisi Technology Co., Ltd.), with the AC signal frequency set to be 1 KHz.
The method for testing the connection qualified rate of the battery includes the following steps of: preparing 100 identical lithium-ion batteries, and carrying out visual inspection and welding strength test on a welding point of each lithium-ion battery, where the visual inspection requires that metal layers between two units are connected together and the metal layer is connected with an external tab. At the same time, it is required that the welding strength of each metal layer that is tested through a Tensile Tester is not less than 80% of a normal welding strength value. If there is one metal layer which fails to meet the requirements through visual inspection and welding strength test, the lithium-ion battery is considered as a defective product. The number of non-defective battery is counted. The qualified rate=the number of the non-defective battery/100*100%.
Finally, it should be noted that: the foregoing embodiments are merely intended for describing the technical solutions of the present disclosure rather than limiting the present disclosure; although the present disclosure is described in detail with reference to the foregoing embodiments, persons of ordinary skill in the art should understand that the technical solutions described in the foregoing embodiments may be modified or made equivalent substitutions to some or all technical features thereof; and these modifications and substitutions shall not cause the essence of the corresponding technical solutions to depart from the scope of the technical solutions of embodiments of the present disclosure.
| Number | Date | Country | Kind |
|---|---|---|---|
| 202010473157.1 | May 2020 | CN | national |
| Number | Date | Country | |
|---|---|---|---|
| Parent | PCT/CN2021/092986 | May 2021 | US |
| Child | 18051879 | US |
