Patent Grant
10276873
The present disclosure is a national phase filing under 35 U.S.C. § 371 of International Patent Application No. PCT/KR2013/003371, filed on Apr. 22, 2013, which claims priority to Korean Patent Application No. 10-2012-0049224 filed on May 9, 2012, Korean Patent Application No. 10-2012-0049228 filed on May 9, 2012, Korean Patent Application No. 10-2012-0049231 filed on May 9, 2012 and Korean Patent Application No. 10-2012-0049234 filed on May 9, 2012 in the Korean Intellectual Property Office, and all the benefits accruing therefrom under 35 U.S.C. 119, the disclosures of each of which are expressly incorporated herein by reference in their entireties.
The present invention relates to a current collector for a battery including a metal mesh layer, and a method of manufacturing the same, and more particularly, to a current collector for a battery including a metal mesh layer, which is capable of preventing an active material from being deintercalated, and a method of manufacturing the same.
Recently, portable electronic devices have become rapidly small and light, so that a demand for a small and high capacity battery used as a driving power source thereof has increased. Particularly, an operational voltage of a lithium rechargeable battery has 3.6 V or more, which is three times higher than that of a nickel-cadmium battery or a nickel-hydrogen battery widely used as a power source of a portable electronic device, and the energy density per unit weight thereof is high, so that the lithium rechargeable battery has rapidly expanded.
The lithium rechargeable battery generates electric energy by oxidation and reduction reactions when lithium ions are intercalated and deintercalated in a positive electrode and a negative electrode. The lithium rechargeable battery uses a material, which is capable of reversibly intercalating and deintercalating lithium ions, as an active material of the positive electrode and the negative electrode, and is manufactured by charging an organic electrolyte or a polymer electrolyte between the positive electrode and the negative electrode.
The lithium rechargeable battery includes an electrode assembly, in which a negative electrode plate and a positive electrode plate are wound in a predetermined shape, for example, a jelly-roll shape, with a separator interposed therebetween, a can, in which the electrode assembly and an electrolyte are accommodated, and a cap assembly coupled to an upper part of the can.
In this case, the negative electrode plate and the positive electrode plate may be formed by coating the active materials, that is, a negative electrode active material and a positive electrode active material, on the current collectors, for example, a negative electrode current collector and a positive electrode current collector, respectively.
However, the lithium rechargeable battery has a problem in that the active materials are deintercalated from the current collectors due to charging and discharging which are repeated several tens to several hundreds of times, so that battery efficiency deteriorates.
The present invention has been made in an effort to provide a method of manufacturing a current collector for a rechargeable battery, which is capable of preventing a positive electrode active material or a negative electrode active material from being deintercalated from a negative electrode current collector or a positive electrode current collector.
The objects of the present invention are not limited to the aforementioned object, and other objects, which are not mentioned above, will be apparently understood by a person skilled in the art from the following description.
An embodiment of the present invention provides a current collector for a battery, including: a base material; adhesive layers positioned on the base material; and metal mesh layers positioned on the adhesive layers, in which the metal mesh layer includes a plurality of metal mesh patterns, and holes positioned between the metal mesh patterns.
Another embodiment of the present invention provides a method of manufacturing a current collector for a battery, including: providing a base material; providing metal mesh layers including a plurality of metal mesh patterns and holes positioned between the metal mesh patterns; and forming adhesive layers on the base material; and positioning and compressing the metal mesh layers onto the adhesive layers.
Still another embodiment of the present invention provides a current collector for a battery, including: a base material; metal mesh layers positioned on the base material; and adhesive layers positioned between the base material and the metal mesh layers, in which the metal mesh layer includes a plurality of metal mesh patterns, and holes positioned between the metal mesh patterns.
Yet another embodiment of the present invention provides a method of manufacturing a current collector for a battery, including: providing a base material; providing metal mesh layers including a plurality of metal mesh patterns and holes positioned between the metal mesh patterns; forming adhesive layers on the metal mesh layers; and positioning and compressing the adhesive layers onto the base material.
According to the embodiments of the present invention, the active material is applied onto the metal mesh layer through the holes of the metal mesh layer, and thus a contact area of the metal mesh layer and the active material is increased, thereby restricting the active material from being deintercalated from the current collector and improving a cycle lifespan property of a battery.
According to the embodiments of the present invention, the active material is also applied onto the adhesive layer through the holes positioned between the metal mesh patterns, so that it is possible to more firmly apply the active material according to an adhesive property of the adhesive layer.
The above and other features and advantages of the present invention will become more apparent by describing in detail embodiments thereof with reference to the attached drawings in which:
Advantages and features of the present invention and methods of accomplishing the same may be understood more readily by reference to the following detailed description of preferred embodiments and the accompanying drawings. The present invention may, however, be embodied in many different forms and should not be construed as being limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete and will fully convey the concept of the invention to those skilled in the art, and the present invention will only be defined by the appended claims. Like reference numerals refer to like elements throughout the specification.
The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. As used herein, the singular forms “a”, “an” and “the” are intended to include the plural forms as well, unless the context clearly indicates otherwise. It will be further understood that the terms “comprises” and/or “comprising,” when used in this specification, specify the presence of stated features, integers, steps, operations, elements, and/or components, but do not preclude the presence or addition of one or more other features, integers, steps, operations, elements, components, and/or groups thereof.
It will be understood that when an element or layer is referred to as being “on”, “connected to” or “coupled to” another element or layer, it can be directly on, connected or coupled to the other element or layer or intervening elements or layers may be present. In contrast, when an element is referred to as being “directly on”, “directly connected to” or “directly coupled to” another element or layer, there are no intervening elements or layers present. As used herein, the term “and/or” includes any and all combinations of one or more of the associated listed items.
It will be understood that, although the terms first, second, etc. may be used herein to describe various elements, components, regions, layers and/or sections, these elements, components, regions, layers and/or sections should not be limited by these terms. These terms are only used to distinguish one element, component, region, layer or section from another region, layer or section. Thus, a first element, component, region, layer or section discussed below could be termed a second element, component, region, layer or section without departing from the teachings of the present invention.
Spatially relative terms, such as “beneath”, “below”, “lower”, “above”, “upper”, and the like, may be used herein for ease of description to describe one element or feature's relationship to another element(s) or feature(s) as illustrated in the figures. It will be understood that the spatially relative terms are intended to encompass different orientations of the device in use or operation in addition to the orientation depicted in the figures. For example, if the device in the figures is turned over, elements described as “below” or “beneath” other elements or features would then be oriented “above” the other elements or features. Thus, the exemplary term “below” can encompass both an orientation of above and below. The device may be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein interpreted accordingly.
Embodiments are described herein with reference to cross-section illustrations that are schematic illustrations of idealized embodiments (and intermediate structures). As such, variations from the shapes of the illustrations as a result, for example, of manufacturing techniques and/or tolerances, are to be expected. Thus, these embodiments should not be construed as limited to the particular shapes of regions illustrated herein but are to include deviations in shapes that result, for example, from manufacturing. For example, an implanted region illustrated as a rectangle will, typically, have rounded or curved features and/or a gradient of implant concentration at its edges rather than a binary change from implanted to non-implanted region. Likewise, a buried region formed by implantation may result in some implantation in the region between the buried region and the surface through which the implantation takes place. Thus, the regions illustrated in the figures are schematic in nature and their shapes are not intended to illustrate the actual shape of a region of a device and are not intended to limit the scope of the present invention.
Unless otherwise defined, all terms (including technical and scientific terms) used herein have the same meaning as commonly understood by one of ordinary skill in the art to which the present invention belongs. It will be further understood that terms, such as those defined in commonly used dictionaries, should be interpreted as having a meaning that is consistent with their meaning in the context of the relevant art and this specification and will not be interpreted in an idealized or overly formal sense unless expressly so defined herein.
Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings.
Referring to
In this case, the electrode assembly 1 may be formed in a jelly roll type in which the positive electrode 10, the negative electrode 20, and the separators 2a and 2b are stacked and wound.
Hereinafter, a configuration of the electrode assembly will be described below.
First, the separators may include a first separator 2b positioned between the positive electrode 10 and the negative electrode 20, and a second separator 2a positioned at a lower side or an upper side of the two electrodes 10 and 20, and the separators 2a and 2b are interposed at a part, at which the two stacked and wound electrodes are in contact with each other, to prevent a short circuit between the two electrodes. In this case, the separator may be formed of a thermoplastic resin, such as polyethylene (PE) and polypropylene (PP), but a material of the separator is not limited thereto in the present invention.
Next, the positive electrode 10 includes a positive electrode current collector 11 for collecting electrons generated by a chemical reaction and transferring the collected electrons to an external circuit, and positive electrode active material layers 12a and 12b formed by applying a slurry for the positive electrode including the positive electrode active material onto one surface or both surfaces of the positive electrode current collector 11.
The positive electrode 10 may include an insulating member 13 formed to cover at least one end of both distal ends of the positive electrode active material layers 12a and 12b.
A positive electrode uncoated part, in which the slurry for the positive electrode including the positive electrode active material is not applied onto one side or both sides of both distal ends of the positive electrode current collector 11, so that the positive electrode current collector 11 is exposed as it is, is formed, and a positive electrode tap 14, which may transfer the electrons collected in the positive electrode current collector 11 to the external circuit, and be formed by a thin plate made of nickel or aluminum, is bonded to the positive electrode uncoated part.
In this case, a protection member 14a may be provided on an upper surface of the part to which the positive electrode tap 14 is bonded.
Stainless steel, nickel, aluminum, titanium, or an alloy thereof, aluminum or stainless steel surface-processed with carbon, nickel, titanium, and silver, and the like may be used as the positive electrode current collector 11, and aluminum or an aluminum alloy among them is preferable, and a material of the positive electrode current collector 11 is not limited in the present invention.
The positive electrode active material of the positive electrode active material layer includes a positive electrode active material which is capable of reversibly intercalating or deintercalating lithium ions, and a representative example of the positive electrode active material is a lithium-transition metal oxide, such as LiCoO2, LiNiO2, LiMnO2, LiMn2O4, or LiNi1-x-yCoxMyO2 (0≤x≤1, 0≤y≤1, 0≤x+y≤1, M is metal, such as Al, Sr, Mg, and La), but the type of positive electrode active material is not limited in the present invention.
Next, the negative electrode 20 includes a negative electrode current collector 21 for collecting electrons generated by a chemical reaction and transferring the collected electrons to an external circuit, and negative electrode active material layers 22a and 22b formed by applying a slurry for the negative electrode including the negative electrode active material onto one surface or both surfaces of the negative electrode current collector 21.
The negative electrode 20 may include an insulating member 23 formed to cover at least one end of both distal ends of the negative electrode active material layers 22a and 22b.
A negative electrode uncoated part, in which the slurry for the negative electrode including the negative electrode active material is not applied onto one side or both sides of both distal ends of the negative electrode current collector 21, so that the negative electrode current collector 21 is exposed as it is, is formed, and a negative electrode tap 24, which may transfer the electrons collected in the negative electrode current collector 21 to the external circuit, and be formed by a thin plate made of nickel, is bonded to the negative electrode uncoated part.
A protection member 24a may be provided on an upper surface of the part to which the negative electrode tap 24 is bonded.
Stainless steel, nickel, copper, titanium, or an alloy thereof, copper or stainless steel surface-processed with carbon, nickel, titanium, and silver, and the like may be used as the negative electrode current collector 21, and copper or a copper alloy among them is preferable, and a material of the negative electrode current collector 23a is not limited in the present invention.
The negative electrode active material of the negative electrode active material layer includes a negative electrode active material which is capable of intercalating and deintercalating lithium ions, and crystalline or amorphous carbon, or a carbon based negative electrode active material of a carbon complex may be used as the negative electrode active material, but the type of negative electrode active material is not limited in the present invention.
As described above, the active materials, that is, the negative electrode active material and the positive electrode active material, are coated on the current collectors, for example, the negative electrode current collector and the positive electrode current collector, respectively, so that the negative electrode and the positive electrode serve as a rechargeable battery.
However, charging and discharging are repeated several tens to several hundreds of times in the rechargeable battery, and the active material is deintercalated from the current collector due to degradation of the active material according to the repeat of the charging and the discharging, so that there is a problem in deterioration of battery efficiency.
Hereinafter, a structure of the current collector for the rechargeable battery according to the present invention will be described. In this case, the current collector for the rechargeable battery according to the present invention may be the negative electrode current collector or the positive electrode current collector which is described above, and the rechargeable battery in the present invention has a concept including all kinds of rechargeable battery capable of repeating charging and discharging, and may be, for example, the rechargeable battery including the electrode assembly illustrated in
First, referring to
The base material 110 may be varied according to whether the current collector is a positive electrode current collector or a negative electrode current collector.
For example, when the current collector is the positive electrode current collector, the base material 110 may use stainless steel, nickel, aluminum, titanium, or an alloy thereof, aluminum or stainless steel surface-processed with carbon, nickel, titanium, and silver, and among them, aluminum or an aluminum alloy may be preferable.
When the current collector is the negative electrode current collector, the base material 110 may use stainless steel, nickel, copper, titanium, or an alloy thereof, copper or stainless steel surface-processed with carbon, nickel, titanium, and silver, and among them, copper or a copper alloy may be preferable.
Subsequently, referring to
The first adhesive layer 120a and the second adhesive layer 120b are provided for attaching a metal mesh layer, which is to be described below, onto the base material 110, and the first adhesive layer and the second adhesive layer may be solder layers, and in this case, the solder layer may be formed of lead (Pb), tin (Sn), zinc (Zn), indium (In), cadmium (Cd), bismuth (Bi), and an alloy thereof.
Subsequently, referring to
The metal mesh layers 130a and 130b may be formed of at least one material among copper (Cu), silver (Ag), chrome (Cr), nickel (Ni), iron (Fe), cobalt (Co), and an alloy thereof, but a material of the metal mesh layer is not limited in the present invention.
However, it is preferable that the metal mesh layer serves as a unique current collector of the rechargeable battery in the present invention, so that when the current collector is the positive electrode current collector, the metal mesh layer is preferably aluminum or an aluminum alloy, and when the current collector is the negative electrode current collector, the metal mesh layer is preferably copper or a copper alloy.
In this case, the first metal mesh layer 130a includes a plurality of first metal mesh patterns 131a and first holes 132a positioned between the first metal mesh patterns 131a, and the second metal mesh layer 130b includes a plurality of second metal mesh patterns 131b and second holes 132b positioned between the second metal mesh patterns 131b.
That is, the current collector 100 for the rechargeable battery according to the first embodiment of the present invention includes the metal mesh layers 130a and 130b formed on the first surface and the second surface of the base material 110, respectively, and each of the metal mesh layers includes a plurality of metal mesh patterns 131a and 131b, and holes 132a and 132b positioned between the metal mesh patterns, respectively, and in this case, the current collector 100 include adhesive layers 120a and 120b for attaching the base material and the metal mesh layers.
As described above, the active material is deintercalated from the current collector due to degradation of the active material according to the repeat of charging and discharging several tens to several hundreds of times in the rechargeable battery having a general structure, so that battery efficiency deteriorates.
However, in the present invention, since the metal mesh layers are attached onto the current collector, on which the active material is coated, more particularly, the base material, through the adhesive layers, and the metal mesh layers include the holes 132a and 132b positioned between the metal mesh patterns, the active material is applied onto the metal mesh layers through the holes 132a and 132b, and thus contact areas of the metal mesh layers and the active material are increased, thereby restricting the active material from being deintercalated from the current collector and improving a cycle lifespan property of the battery.
In the present invention, the active material is applied onto the metal mesh layers, and in this case, and the active material is applied onto the adhesive layers through the holes positioned between the metal mesh patterns, so that the active material may be more firmly applied according to an adhesive property of the adhesive layer.
Next, referring to
The metal mesh layer 230 includes a plurality of metal mesh patterns 231, and holes 232 positioned between the metal mesh patterns 231.
As described above, in the rechargeable battery, for example, in a positive electrode, a positive electrode active material may be applied onto one surface or both surfaces of a positive electrode current collector.
That is, the current collector 200 for the rechargeable battery according to the second embodiment of the present invention is an embodiment in which the metal mesh layer 230 is formed on only one surface of the base material 210, so that the metal mesh layer may be formed on a first surface and/or a second surface of the base material in the present invention.
The current collector for the rechargeable battery according to the second embodiment of the present invention may be the same as the current collector for the rechargeable battery according to the first embodiment of the present invention except for the described matter, so that a detailed description thereof will be omitted below.
Hereinafter, a method of manufacturing the current collector for the rechargeable battery according to the present invention will be described.
First, referring to
In this case, a chain connected with a motor, which provides rotational force so that the drum 41a is rotated, may be coupled to one end of the rotation shaft 41b.
In the meantime, a mesh 42 having a shape desired to be fabricated is formed on a surface of the drum 40. In this case, the mesh 42 may be formed in a net shape, in which a plurality of approximate hexagons is connected, to be shaped like a honeycomb, but the shape of the mesh may be a quadrangle, a triangle, a pentagon, and the like, so that the shape of the mesh is not limited in the present invention.
The mesh 42 may be formed of single metal or an alloy according to a component of an electrolyte for plating, and may be used by directly processing a surface of the cylindrical drum 41a and integrally forming the cylindrical drum 41a and the mesh 42, or attaching a mesh 50, which is processed in a weaving type or a batch type formed by weaving metal wires similar to weaving threads, to the surface of the cylindrical drum 41a.
Continuously, referring to
In this case, the insulating layer 43 in the spaces between the meshes may be formed by forming the mesh 42 having the shape, which is desired to be fabricated, on the surface of the cylindrical drum 41a as described above, applying an insulating material by a publicly known spray method or deposition method, and planarizing a cross section of the mesh by using a publicly known chemical mechanical polishing (CMP) process.
Then, through the mesh type negative electrode drum 40, the metal mesh may be formed by an electroforming process by forming a metal mesh layer (not illustrated) on the mesh 42 of the surface of the mesh type negative electrode drum by the electroforming process and peeling the metal mesh layer (not illustrated).
In the meantime, the mesh type negative electrode drum is an electroforming master, and the electroforming master in the present invention collectively refers to all of the members including a mesh having a shape corresponding to the shape of the metal mesh layer, which is desired to be fabricated, so as to form the metal mesh layer by the electroforming process, and the electroforming master may have a drum type as illustrated in
That is, the electroforming master according to the present invention includes a base plate and a mesh formed on the base plate, and having a shape corresponding to the shape of the metal mesh layer desired to be fabricated, and when a shape of the base plate is a drum type, the electroforming master according to the present invention may be the drum type, and when a shape of the base plate is a flat plate type, the electroforming master according to the present invention may be the flat plate type.
Hereinafter, the forming of the metal mesh layer through the aforementioned mesh type negative electrode drum will be described.
Referring to
In order to form the metal mesh layer according to the present invention, the electrolyte may be formed of at least one material among copper (Cu), silver (Ag), chrome (Cr), nickel (Ni), iron (Fe), cobalt (Co), and an alloy thereof, but the type of electrolyte is not limited in the present invention.
Subsequently, referring to
An auxiliary tank 30 for accommodating the electrolyte over-flowing from the electrolyzer 34 is formed under the electrolyzer 34, so that a structure for accommodating the electrolyte may be a dual structure of the electrolyte 34 and the auxiliary tank 30.
Accordingly, a part, that is, about a half, of the rotating mesh type negative electrode drum 40 is submerged in the electrolyzer 34, so that the electrolyte of the electrolyzer 34 is stirred by an electrolyte injected from an electrolyte injection path 32, which is to be described below, and the electrolyte over flowing from the electrolyzer 34 is accommodated in the auxiliary tank 30 while the electrolyte is stirred by the injection of the electrolyte from the electrolyte injection path 32.
The mesh type negative electrode drum 40 rotating while about a half thereof is submerged in the electrolyte is installed in the electrolyzer 34.
The mesh type negative electrode drum 40 may include the rotation shaft 41b connected to a negative (−) electrode of an applied power source, and serving as a center so that the mesh type negative electrode drum 40 is rotatable, and the cylindrical drum 41a surrounding the rotation shaft 41b and having a predetermined width.
In the meantime, although not illustrated in the drawing, a power supply device for supplying a negative (−) electrode from a rectifier may be provided at one end of the rotation shaft 41b, and the motor for providing rotational force so as to rotate the cylindrical drum 41a may be coupled to the other end of the rotation shaft 41b.
Accordingly, when power is supplied to the motor so that rotational power is generated, the rotation power is transmitted to the rotation shaft 41b to rotate the cylindrical drum 41a.
In the meantime, as illustrated in
This has been described with reference to
A positive electrode basket 31 formed of an insoluble positive electrode (+) or titanium (Ti) is installed under the mesh type negative electrode drum 40.
The positive electrode basket 31 is completely submerged in the electrolyte of the electrolyzer 34, and is formed in a circular arc shape, of which a half is cut, so as to correspond to the mesh type negative electrode drum 40 and is installed to maintain a predetermined distance from the mesh type negative electrode drum 40.
A metal cluster 33 having the same component as that of the electrolyte of the electrolyzer 34 may be accommodated inside the positive electrode basket 31.
The metal cluster 33 is surrounded by a separation preventing net for preventing the metal cluster 33 from being separated from the inside of the positive electrode basket 31 to the inside of the electrolyzer 34 to be stored.
The metal cluster 33 is dissolved in the electrolyte of the electrolyzer 34 as a metal lump having the same component as that of the electrolyte of the electrolyzer 34, so that the metal cluster 33 may serve to adjust a quantity and a concentration of the electrolyte plated on the surface of the cylindrical drum 41a.
Accordingly, when a current is applied to the positive electrode basket 31, positive (+) ions dissolved from the metal cluster 33 move to the surface of the cylindrical drum 41a and are electrodeposited, so that the surface of the cylindrical drum 41a is plated.
The electrolyte injection path 32 for injecting the electrolyte so that the electrolyte of the electrolyzer 34 is stirred may be formed at a lower end part of the electrolyzer 34, more particularly, a center of a lower end of the positive electrode basket 31, and an inner side of the electrolyte injection path 32 may communicate with an inner side of the electrolyzer 34, and the electrolyte injection path 32 may be formed of an elongated cylindrical plastic pipe.
Accordingly, when the electrolyte is injected and supplied into the electrolyzer 34 through the electrolyte injection path 32, the electrolyte inside the electrolyzer 34 is stirred, and hydrogen (H2) gas generated in the mesh type negative electrode drum 40 may be smoothly removed.
Although it is not illustrated in the drawing, the continuous electroforming device may further include a circulation-filtering means, and the circulation-filtering means may serve to remove foreign materials in the electrolyte while circulating the electrolyte inside the auxiliary tank 30 to the electrolyzer 34, but the circulation-filtering means is a general configuration, so that a detailed description thereof will be omitted below.
Next, referring to
A winding roller 70 may be provided at a right side of the cleaning bath 60, and the winding roller 70 may continuously wind the metal mesh 50 which is cleaned while passing through the cleaning bath 60.
Hereinafter, a method of fabricating the metal mesh by using the continuous electroforming device will be described below with reference to
First, an electrolyte stirring operation (S10), in which when electricity is conducted in the electrolyte of the electrolyzer 34 by applied power, electrolysis is incurred, and the electrolyte is injected to the electrolyzer 34 by the electrolyte injection path 32 to stir the electrolyte, is performed. However, the electrolyte stirring operation is an optional matter in the present invention, so that the electrolyte stirring operation may be omitted in some cases.
After the electrolyte stirring operation (S10), a drum rotating operation (S20), in which the mesh type negative electrode drum 40 installed inside the electrolyzer 34 is rotated, is performed. In this case, the drum rotating operation is an operation corresponding to the case where the electroforming master is a drum type, and may be omitted when the electroforming master is a flat plate type.
Next, an electrodepositing operation (S30), in which a metal mesh layer is formed by electrodepositing at least one material among copper (Cu), silver (Ag), chrome (Cr), nickel (Ni), iron (Fe), cobalt (Co), and an alloy thereof, which are melted in the electrolyte, for example, copper (Cu), on an upper surface of a mesh, is performed.
A current density in the electrodepositing operation (S30) may be 0.1 to 30 mA/cm2, but a range of the current density is not limited in the present invention, and the current density may be varied according to a material desired to be electrodeposited.
For example, the range of 0.1 to 1 mA/cm2 in the range of the current density may be a range in which copper (Cu) is actively electrodeposited, and the range of 3 to 15 mA/cm2 in the range of the current density may be a range in which nickel (Ni) is actively electrodeposited.
It is preferable that the electrodepositing operation is performed within a predetermined temperature range of the electrolyte, so that the electrodeposition of the metal mesh layer is more actively performed in the range of the current density.
For example, the electrodeposition of copper (Cu) or nickel (Ni) may be actively performed when a temperature of the electrolyte is 10 to 50° C., but a temperature of the electrolyte is not limited in the present invention.
According to the aforementioned condition, after the completion of the electrodepositing operation (S30), the metal mesh layer is formed on an external surface of the mesh type negative electrode drum 40, more particularly, an upper part of the mesh 42 (see
After the electrodepositing operation (S30), an electrodeposited layer peeling operation (S40) of peeling the metal mesh layer from the external surface of the mesh type negative electrode drum 40, particularly, the mesh, continues.
The electrodeposited layer peeling operation (S40) is performed while the metal mesh layer attached to the external surface of the mesh type negative electrode drum 40 is guided to an upper and right side by a rotation of the guide roller 51.
More particularly, the metal mesh 50 may be formed by an electroforming process by applying an adhesive on a protection film (not illustrated), such as PET, PC, and PMMA, laminating the protection film on the metal mesh layer formed on the mesh on the surface of the mesh type negative electrode drum 40, and then peeling the protection film (not illustrated) and the metal mesh layer together.
After the electrodeposited layer peeling operation (S40), an electrodeposited layer washing operation (S50), in which the metal mesh 50 separated from the mesh type negative electrode drum 40 is submerged into the cleaning bath 60 and is washed, is performed, and a metal mesh winding operation (S60), in which the metal mesh 50 washed through the electrodeposited layer washing operation (S50) is wound while being transferred to the winding roller 70, is performed.
When all of the operations are completed, the metal mesh 50 may be stored in a state of being wound around the winding roller 70, and the metal mesh 50 may be cut in a demanded length and shape according to a necessity and applicable to various fields as a matter of course.
In the meantime, it is illustrated that in the electrodeposited layer peeling operation, the metal mesh 50 is formed by an electroforming process by applying the adhesive on the protection film (not illustrated), laminating the protection film on the metal mesh layer formed on the mesh on the surface of the mesh type negative electrode drum, and then peeling the protection film (not illustrated) and the metal mesh layer together, but by contrast without a separate protection film, only the metal mesh layer is separable from the mesh of the mesh type negative electrode drum, and in this case, the metal mesh layer is thin, so that it is difficult to treat the metal mesh layer according to a process, and thus the metal mesh 50, which is washed through the electrodeposited layer washing operation (S50), may be attached to a separate protection film to be used.
As described above, in the present invention, it is possible to form the metal mesh layer through the continuous electroforming device for fabricating the metal mesh, and the formed metal mesh layer may be used as the aforementioned metal mesh layer of the current collector.
First, referring to
In the meantime, it has been described that the metal mesh layer is manufactured by an electroforming method using the continuous electroforming device, but, by contrast, the metal mesh layer may be manufactured by a weaving or mechanical processing method, and thus, the method of manufacturing the metal mesh layer is not limited in the present invention.
In this case, a width d1 of the metal mesh layer 130 may be 1 to 500 μm, and a thickness d2 of the metal mesh layer may be 1 to 500 μm, and further, an interval between the metal mesh patterns, that is, a size of the hole 132 positioned between the metal mesh patterns 131 may be 1 μm to 3 mm, but numerical values thereof are not limited in the present invention.
Next, referring to
The first adhesive layer 120a and the second adhesive layer 120b may be the solder layers, and the solder layer may be formed by a publicly known electroplating method or electroless plating method, but the method of forming the solder layer is not limited in the present invention.
In this case, a thickness of the base material 110 may be 1 to 100 μm, a thickness of the first adhesive layer or the second adhesive layer is 1 to 20 μm, and a thickness d3 of the base material, the first adhesive layer, and the second adhesive layer may be 2 to 120 μm, but numerical values thereof are not limited in the present invention.
Next, referring to
In this case, the first metal mesh layer and the second metal mesh layer may be compressed at a predetermined temperature in order to improve performance of adhesion of the adhesive layers and the metal mesh layers, and the predetermined temperature may be 150 to 500° C.
Accordingly, it is possible to manufacture the current collector for the rechargeable battery including the metal mesh layer according to the present invention.
That is, as illustrated in
Hereinafter, a method of manufacturing the current collector for the rechargeable battery according to the present invention will be described in more detail.
First, referring to
The base material 611 may be varied according to whether the current collector is a positive electrode current collector or a negative electrode current collector, which has been described above, so that a detailed description thereof will be omitted.
Next, the base material is pre-preprocessed (S110).
The pre-processing may be a general chemical pre-processing method, and the chemical pre-processing method may be a method, such as acid washing and fat removal, of removing oil, contaminants, and impurities on a surface of the metal material by submerging a target material, that is, the base material in an acidic or alkaline solution or spraying the solution to the target material.
In the present invention, the pre-processing may be a chemical pre-processing method by a method of submerging the base material in a water tank 601 for pre-processing in which the pre-processing solution is accommodated, but the pre-processing method is not limited in the present invention, and the pre-processing process may be omitted as necessary.
Next, a first washing operation of washing the pre-processed base material is performed (S120).
The first washing operation, which is a process for removing the pre-processing solution and the like used in the pre-processing process, may be performed by a method of submerging the base material in a water tank 602 for first washing in which a washing fluid is accommodated, but the washing method is not limited in the present invention, and the first washing process may be omitted as necessary.
Next, adhesive layers are formed on the base material (S130).
The adhesive layer may be a solder layer, and the solder layer may be formed by a publicly known electroplating method or electroless plating method using the method of submerging the base material in a water tank 603 for plating including a plating liquid, but the method of forming the solder layer is not limited in the present invention.
In this case, the solder layers may be formed on the first surface and the second surface of the base material, respectively.
Next, a second washing operation of washing the base material 612, on which the adhesive layers are formed, is performed (S140).
The second washing operation, which is a process for washing the plating liquid and the like used in the adhesive layer forming process, may be performed by a method of submerging the base material in a water tank 604 for the second washing in which a washing fluid is accommodated, but the washing method is not limited in the present invention, and the second washing process may be omitted as necessary.
Next, an operation of drying the base material, on which the adhesive layers are formed, is performed (S150).
The drying operation may be hot-air drying performed by a hot-air drying furnace 605, but the drying method is not limited in the present invention, and the drying process may be omitted as necessary.
Subsequently, referring to
In this case, as described above, the metal mesh layer may include the metal mesh patterns and the holes between the metal mesh patterns, and this has been described above, so that a detailed description thereof will be omitted.
In the meantime, as illustrated in
Next, the metal mesh layer is positioned on the adhesive layer of the base material including the adhesive layer, and the metal mesh layer are compressed by compression rollers 630a and 630b.
In this case, in the current collector for the rechargeable battery according to the first embodiment of the present invention, the first metal mesh layer provided from the first metal mesh layer supply unit 620a may be positioned on the first adhesive layer positioned on the first surface of the base material, the second metal mesh layer provided from the second metal mesh layer supply unit 620b may be positioned on the second adhesive layer positioned on the second surface of the base material, and then the first metal mesh layer and the second metal mesh layer may be compressed on the first adhesive layer and the second adhesive layer through the compression rollers, respectively.
In this case, the first metal mesh layer and the second metal mesh layer may be compressed at a predetermined temperature in order to improve performance of adhesion of the adhesive layers and the metal mesh layers, and the predetermined temperature may be 150 to 500° C.
Accordingly, it is possible to manufacture the current collector for the rechargeable battery including the metal mesh layer according to the first embodiment of the present invention.
That is, as illustrated in
Next, referring to
Next, the base material is pre-preprocessed.
The pre-processing may be a chemical pre-processing method using a method of submerging the base material in a water tank 701 for pre-processing in which a pre-processing solution is accommodated.
Next, a first washing operation of washing the pre-processed base material is performed.
The first washing operation may be performed by a method of submerging the base material in a water tank 702 for first washing in which a washing fluid is accommodated.
Next, adhesive layers are formed on the base material.
The adhesive layer may be a solder layer, and the solder layer may be formed by a publicly known electroplating method or electroless plating method using a method of submerging the base material in a water tank 703 for plating including a plating liquid.
In this case, the solder layer may be formed on any one surface between the first surface and the second surface of the base material, for example, the first surface, and in this case, a separate protection film is attached onto the second surface of the base material, so that the solder layer is not formed on the second surface of the base material.
Next, a second washing operation of washing the base material 712, on which the adhesive layers are formed, is performed.
The second washing operation, which is a process for washing the plating liquid and the like used in the adhesive layer forming process, may be performed by a method of submerging the base material in a water tank 704 for second washing in which a washing fluid is accommodated.
Next, an operation of drying the base material, on which the adhesive layers are formed, is performed.
The drying operation may be hot-air drying performed by a hot-air drying furnace 705.
Next, referring to
In this case, as described above, the metal mesh layer may include the metal mesh patterns and the holes between the metal mesh patterns, and this has been described above, so that a detailed description thereof will be omitted below.
In the meantime, as illustrated in
As described above, in the rechargeable battery, for example, in a positive electrode, a positive electrode active material may be applied onto one surface or both surfaces of a positive electrode current collector.
That is, the method of manufacturing the current collector for the rechargeable battery according to the second embodiment of the present invention is an embodiment in which the metal mesh layer is formed on only one surface of the base material, so that the metal mesh layer may be formed on the first surface and/or the second surface of the base material in the present invention.
Next, the metal mesh layer is positioned on the adhesive layer of the base material including the adhesive layer, and the metal mesh layers are compressed by compression rollers 730a and 730b.
In this case, in the current collector for the rechargeable battery according to the second embodiment of the present invention, the first metal mesh layer provided from the first metal mesh layer supply unit 720a may be positioned on the first adhesive layer positioned on the first surface of the base material, and the first metal mesh layer may be compressed onto the first adhesive layer through the compression rollers.
In this case, the first metal mesh layer may be compressed at a predetermined temperature in order to improve performance of adhesion of the adhesive layer and the metal mesh layer, and the predetermined temperature may be 150 to 500° C.
Accordingly, it is possible to manufacture the current collector for the rechargeable battery including the metal mesh layer according to the second embodiment of the present invention.
That is, as illustrated in
First, referring to
Next, the base material is pre-preprocessed (S210).
The pre-processing may be a chemical pre-processing method using a method of submerging the base material in a water tank 801 for pre-processing in which a pre-processing solution is accommodated.
Next, a first washing operation of washing the pre-processed base material is performed (S220).
The first washing operation may be performed by a method of submerging the base material in a water tank 802 for first washing in which a washing fluid is accommodated.
Next, adhesive layers are formed on the base material (S230).
The adhesive layer may be a solder layer, and the solder layer may be formed by a publicly known electroplating method or electroless plating method using a method of submerging the base material in a water tank 803 for plating including a plating liquid.
In this case, the solder layers may be formed on the first surface and the second surface of the base material, respectively.
Next, a second washing operation of washing the base material 812, on which the adhesive layers are formed, is performed (S240).
The second washing operation may be performed by a method of submerging the base material in a water tank 804 for second washing in which a washing fluid is accommodated.
Next, an operation of drying the base material, on which the adhesive layers are formed, is performed (S250).
The drying operation may be hot-air drying performed by a hot-air drying furnace 805.
Subsequently, referring to
As described above, in the pre-deposited layer peeling operation of manufacturing the metal mesh layer, an adhesive may be applied onto the protection film, the protection film may be laminated on the metal mesh layer formed on the mesh of the surface of the mesh type negative electrode drum, and then the protection film and the metal mesh layer may be peeled together.
By contrast, only the metal mesh layer may be separated from the mesh of the mesh type negative electrode drum without a separate protection film, and in this case, the metal mesh, which is washed through the pre-deposited layer washing operation, may be attached to a separate protection film and used for easiness in the process.
The method of manufacturing the current collector for the rechargeable battery according to the modified example of the first embodiment of the present invention corresponds to the case where the metal mesh layer including the protection film is used.
Subsequently, referring to
In the meantime, as illustrated in
Next, the metal mesh layer is positioned on the adhesive layer of the base material including the adhesive layer, and the metal mesh layers are compressed by compression rollers 830a and 830b (S270).
When the metal mesh layer is positioned on the adhesive layer, an opposing surface to the surface of the metal mesh layer, on which the protection film is positioned, is positioned on the adhesive layer.
In this case, in the current collector for the rechargeable battery according to the modified example of the first embodiment of the present invention, a first metal mesh layer provided from the first metal mesh layer supply unit 820a may be positioned on a first adhesive layer positioned on a first surface of the base material, a second metal mesh layer provided from the second metal mesh layer supply unit 820b may be positioned on a second adhesive layer positioned on a second surface of the base material, and then the first metal mesh layer and the second metal mesh layer may be compressed on the first adhesive layer and the second adhesive layer through the compression rollers, respectively.
In this case, the first metal mesh layer and the second metal mesh layer may be compressed at a predetermined temperature in order to improve performance of adhesion of the adhesive layers and the metal mesh layers, and the predetermined temperature may be 150 to 500° C.
In the meantime, in the current collector 831 for the rechargeable battery, on which up to operation S270 is performed, the metal mesh layer includes the protection film, so that an opposing surface of the metal mesh layer, which is not attached to the adhesive layer, includes the protection film.
Accordingly, in the method of manufacturing the current collector for the rechargeable battery according to the modified example of the first embodiment of the present invention, the protection film is removed from the metal mesh layer during final use (S280).
In the meantime, compared to the first embodiment, in the modified example of the first embodiment, the protection film is included on the metal mesh layer, more particularly, on the opposing surface of the metal mesh layer, which is not attached to the adhesive layer, so that it is possible to easily achieve a protection property and a storage property of the current collector for the rechargeable battery.
Accordingly, it is possible to manufacture the current collector for the rechargeable battery including the metal mesh layer according to the modified example of the first embodiment of the present invention.
Next, referring to
Next, the base material is pre-preprocessed.
The pre-processing may be a chemical pre-processing method using a method of submerging the base material in a water tank 901 for pre-processing in which a pre-processing solution is accommodated.
Next, a first washing operation of washing the pre-processed base material is performed.
The first washing operation may be performed by a method of submerging the base material in a water tank 902 for first washing in which a washing fluid is accommodated.
Next, adhesive layers are formed on the base material.
The adhesive layer may be a solder layer, and the solder layer may be formed by a publicly known electroplating method or electroless plating method using a method of submerging the base material in a water tank 903 for plating including a plating liquid.
In this case, the solder layer may be formed on any one surface between the first surface and the second surface of the base material, for example, the first surface, and in this case, a separate protection film is attached onto the second surface of the base material, so that the solder layer may not be formed on the second surface of the base material.
Next, a second washing operation of washing the base material, on which the adhesive layers are formed, is performed.
The second washing operation, which is a process for washing the plating liquid and the like used in the adhesive layer forming process, may be performed by a method of submerging the base material in a water tank 904 for second washing in which a washing fluid is accommodated.
Next, an operation of drying the base material, on which the adhesive layers are formed, is performed.
The drying operation may be hot-air drying performed by a hot-air drying furnace 905.
Subsequently, referring to
In this case, as described above, the metal mesh layer may include the metal mesh patterns and the holes between the metal mesh patterns, and this has been described above, so that a detailed description thereof will be omitted.
In the meantime, as illustrated in
As described above, in the rechargeable battery, for example, in a positive electrode, a positive electrode active material may be applied onto one surface or both surfaces of a positive electrode current collector.
That is, the method of manufacturing the current collector for the rechargeable battery according to the modified example of the second embodiment of the present invention is an embodiment in which the metal mesh layer is formed on only one surface of the base material, so that the metal mesh layer may be formed on the first surface and/or the second surface of the base material in the present invention.
Next, the metal mesh layer is positioned on the adhesive layer of the base material including the adhesive layer, and the metal mesh layers are compressed by compression rollers 930a and 930b.
In this case, in the current collector for the rechargeable battery according to the modified example of the second embodiment of the present invention, the first metal mesh layer provided from the first metal mesh layer supply unit 920a may be positioned on the first adhesive layer positioned on the first surface of the base material, and the first metal mesh layer may be compressed onto the first adhesive layer through the compression rollers.
In this case, the first metal mesh layer may be compressed at a predetermined temperature in order to improve performance of adhesion of the adhesive layer and the metal mesh layer, and the predetermined temperature may be 150 to 500° C.
In the meantime, as described above, in the current collector 931 for the rechargeable battery, on which up to the above operation is performed, the metal mesh layer includes the protection film, so that an opposing surface of the metal mesh layer, which is not attached to the adhesive layer, includes the protection film.
Accordingly, in the method of manufacturing the current collector for the rechargeable battery according to the modified example of the second embodiment of the present invention, the protection film is removed from the metal mesh layer during final use.
In the meantime, compared to the second embodiment, in the modified example of the second embodiment, the protection film is included on the metal mesh layer, more particularly, on the opposing surface of the metal mesh layer, which is not attached to the adhesive layer, so that it is possible to easily achieve a protection property and a storage property of the current collector for the rechargeable battery.
Accordingly, it is possible to manufacture the current collector for the rechargeable battery including the metal mesh layer according to the modified example of the second embodiment of the present invention.
A plane shape of the metal mesh layer according to the present invention may be an approximate quadrangle as illustrated in
As described above, when the metal mesh layer according to the present invention is manufactured by using the continuous electroforming device for manufacturing the metal mesh, the continuous electroforming device includes the cylindrical drum, and the shape of the metal mesh layer may be determined according to the shape of the mesh formed on the surface of the cylindrical drum.
That is, the mesh having the shape desired to be fabricated is formed on the surface of the cylindrical drum of the continuous electroforming device, and in this case, the mesh may be formed in a net shape, in which a plurality of approximate hexagons is connected, and shaped like a honeycomb, and further, the mesh may be formed in a shape, such as a quadrangle, a triangle, a pentagon, and when the shape of the mesh is a hexagon, the plane shape of the metal mesh layer may also be a hexagon, and when the shape of the mesh is a quadrangle, the plane shape of the metal mesh layer may also be a quadrangle. However, in the present invention, the shape of the metal mesh layer is not limited.
In this case, current collectors for a rechargeable battery according to third to fifth embodiments may be the same as the current collector for the rechargeable battery according to the first embodiment except for the matter to be described below.
First, referring to
In this case, a shape of the metal mesh pattern in the current collector 300 for the rechargeable battery according to the third embodiment of the present invention may be different from that of the current collector for the rechargeable battery according to the first embodiment of the present invention.
More particularly, the first metal mesh pattern 331a of the first metal mesh layer 330a includes a lower end 331a2 and an upper end 331a1, and the second metal mesh pattern 331b of the second metal mesh layer 330b includes a lower end 331b2 and an upper end 331b1, and in this case, widths of the upper ends 331a1 and 331b1 are greater than widths of the lower ends 331a2 and 331b2.
That is, the widths of the upper ends 331a1 and 331b1 are formed to be greater than the widths of the lower ends 331a2 and 331b2, so that the present invention may more efficiently prevent an active material applied onto the metal mesh layers through the holes 332a and 332b from being deintercalated.
In the meantime, a reference of the upper end and the lower end in the present invention is a surface of the base material to which each of the metal mesh layers is bonded, that is, the first metal mesh pattern may be divided into the upper end and the lower end based on the first surface of the base material, and the second metal mesh pattern may be divided into the upper end and the lower end based on the second surface of the base material.
Next, referring to
In this case, a shape of the metal mesh pattern in the current collector 400 for the rechargeable battery according to the fourth embodiment of the present invention may be different from that of the current collector for the rechargeable battery according to the first embodiment of the present invention.
More particularly, the first metal mesh pattern 431a of the first metal mesh layer 430a includes a lower end 431a2 and an upper end 431a1, and the second metal mesh pattern 431b of the second metal mesh layer 430b includes a lower end 431b2 and an upper end 431b1, and in this case, widths of the upper ends 431a1 and 431b1 are greater than widths of the lower ends 431a2 and 431b2.
That is, the widths of the upper ends 431a1 and 431b1 are formed to be greater than the widths of the lower ends 431a2 and 431b2, so that the present invention may more efficiently prevent an active material applied onto the metal mesh layers through the holes 431a and 432b from being deintercalated.
In this case, as illustrated in
In the meantime, a reference of the upper end and the lower end in the present invention is a surface of the base material to which each of the metal mesh layers is bonded, that is, the first metal mesh pattern may be divided into the upper end and the lower end based on the first surface of the base material, and the second metal mesh pattern may be divided into the upper end and the lower end based on the second surface of the base material.
Next, referring to
In this case, a shape of the metal mesh pattern in the current collector 500 for the rechargeable battery according to the fifth embodiment of the present invention may be different from that of the current collector for the rechargeable battery according to the first embodiment of the present invention.
More particularly, the first metal mesh pattern 531a of the first metal mesh layer 530a includes a lower end 531a2 and an upper end 531a1, and the second metal mesh pattern 531b of the second metal mesh layer 530b includes a lower end 531b2 and an upper end 531b1, and in this case, widths of the upper ends 531a1 and 531b1 are smaller than widths of the lower ends 531a2 and 531b2.
That is, the widths of the upper ends 531a1 and 531b1 are formed to be smaller than the widths of the lower ends 531a2 and 531b2, so that the present invention may more efficiently apply an active material onto the metal mesh layers through the holes 531a and 531b.
In this case, it is illustrated in
In the meantime, a reference of the upper end and the lower end in the present invention is a surface of the base material to which each of the metal mesh layers is bonded, that is, the first metal mesh pattern may be divided into the upper end and the lower end based on the first surface of the base material, and the second metal mesh pattern may be divided into the upper end and the lower end based on the second surface of the base material.
As illustrated in
Referring to
In this case, a structure of the adhesive layers in the current collector for the rechargeable battery according to the sixth embodiment of the present invention may be different from that of the current collector for the rechargeable battery according to the first embodiment of the present invention.
That is, as illustrated in
Referring to
The base material 1011 may be varied according to whether the current collector is a positive electrode current collector or a negative electrode current collector, which has been described above, so that a detailed description thereof will be omitted.
Next, the base material is pre-preprocessed (S310).
The pre-processing may be a chemical pre-processing method using a method of submerging the base material in a water tank 1001 for pre-processing in which a pre-processing solution is accommodated.
Next, a first washing operation of washing the pre-processed base material is performed (S320).
The first washing operation may be performed by a method of submerging the base material in a water tank 2602 for first washing in which a washing fluid is accommodated.
Next, first adhesive layers are formed on the base material (S330).
The first adhesive layer may be a solder layer, and the solder layer may be formed by a publicly known electroplating method or electroless plating method using a method of submerging the base material in a water tank 1003 for plating including a plating liquid.
In this case, the solder layers may be formed on the first surface and the second surface of the base material, respectively.
Next, a second washing operation of washing the base material 1012, on which the first adhesive layers are formed, is performed (S340).
The second washing operation may be performed by a method of submerging the base material in a water tank 1004 for second washing in which a washing fluid is accommodated.
Next, an operation of drying the base material, on which the first adhesive layers are formed, is performed (S350).
The drying operation may be hot-air drying performed by a hot-air drying furnace 1005.
Subsequently, referring to
In this case, as described above, the metal mesh layer may include the metal mesh patterns and the holes between the metal mesh patterns, and this has been described above, so that a detailed description thereof will be omitted.
In the meantime, as illustrated in
Next, the metal mesh layers are pre-preprocessed (S361).
The pre-processing may be a general chemical pre-processing method, and the chemical pre-processing method may be a method, such as acid washing and fat removal, of removing oil, contaminants, and impurities on a surface of the metal material by submerging a target material, that is, the metal mesh layer in an acidic or alkaline solution or spraying the solution to the target material.
In the present invention, the pre-processing may be a chemical pre-processing method by a method of submerging the metal mesh layer in water tanks 1021a and 1021b for pre-processing in which the pre-processing solution is accommodated, but the pre-processing method is not limited in the present invention, and the pre-processing process may be omitted as necessary.
Next, a first washing operation of washing the pre-processed metal mesh layers is performed (S362).
The first washing operation, which is a process for removing the pre-processing solution and the like used in the pre-processing process, may be performed by a method of submerging the metal mesh layers in water tanks 1022a and 1022b for the first washing in which a washing fluid is accommodated, but the washing method is not limited in the present invention, and the first washing process may be omitted as necessary.
Next, second adhesive layers are formed on the metal mesh layers (S363).
The adhesive layer may be a solder layer, and the solder layer may be formed by a publicly known electroplating method or electroless plating method using the method of submerging the metal mesh layers in water tanks 1023a and 1023b for plating including a plating liquid, but the method of forming the solder layer is not limited in the present invention.
Next, a second washing operation of washing a metal mesh layer 1022, on which the second adhesive layers are formed, is performed (S364).
The second washing operation, which is a process for washing the plating liquid and the like used in the adhesive layer forming process, may be performed by a method of submerging the metal mesh layer in water tanks 1024a and 1024b for the second washing in which a washing fluid is accommodated, but the washing method is not limited in the present invention, and the second washing process may be omitted as necessary.
Next, an operation of drying the metal mesh layer, on which the second adhesive layers are formed, is performed (S365).
The drying operation may be hot-air drying performed by hot-air drying furnaces 1025a and 1025b, but the drying method is not limited in the present invention, and the drying process may be omitted as necessary.
Next, the base material including the first adhesive layers and the metal mesh layer including the second adhesive layers are disposed in such a manner than the second adhesive layers are positioned on the first adhesive layers, and the second adhesive layers and the first adhesive layers are compressed by compression rollers 1030a and 1030b (S370).
In this case, the first adhesive layer and the second adhesive layer may be compressed at a predetermined temperature in order to improve performance of adhesion of the adhesive layers, and the predetermined temperature may be 150 to 500° C.
Accordingly, it is possible to manufacture the current collector for the rechargeable battery including the metal mesh layer according to the sixth embodiment of the present invention.
That is, as illustrated in
In the meantime, although it is not illustrated in the drawing, the metal mesh layer may be positioned on only any one surface of the first surface and the second surface of the base material in the sixth embodiment of the present invention, similar to the first embodiment of the present invention.
Referring to
Next, the base material is pre-preprocessed (S410).
The pre-processing may be a chemical pre-processing method using a method of submerging the base material in a water tank 1101 for pre-processing in which a pre-processing solution is accommodated.
Next, a first washing operation of washing the pre-processed base material is performed (S420).
The first washing operation may be performed by a method of submerging the base material in a water tank 1102 for first washing in which a washing fluid is accommodated.
Next, first adhesive layers are formed on the base material (S430).
The first adhesive layer may be a solder layer, and the solder layer may be formed by a publicly known electroplating method or electroless plating method using a method of submerging the base material in a water tank 1103 for plating including a plating liquid.
In this case, the solder layers may be formed on the first surface and the second surface of the base material, respectively.
Next, a second washing operation of washing the base material 1112 on which the first adhesive layers are formed, is performed (S440).
The second washing operation may be performed by a method of submerging the base material in a water tank 1104 for second washing in which a washing fluid is accommodated.
Next, an operation of drying the base material, on which the adhesive layers are formed, is performed (S450).
The drying operation may be hot-air drying performed by a hot-air drying furnace 1105.
Subsequently, referring to
As described above, in the pre-deposited layer peeling operation of manufacturing the metal mesh layer, an adhesive may be applied onto the protection film, the protection film may be laminated on the metal mesh layer formed on the mesh of the surface of the mesh type negative electrode drum, and then the protection film and the metal mesh layer may be peeled together.
By contrast, only the metal mesh layer may be separated from the mesh of the mesh type negative electrode drum without a separate protection film, and in this case, the metal mesh, which is washed through the pre-deposited layer washing operation, may be attached to a separate protection film and used for easiness in the process.
The method of manufacturing the current collector for the rechargeable battery according to the modified example of the sixth embodiment of the present invention corresponds to the case where the metal mesh layer including the protection film is used.
Subsequently, referring to
In the meantime, as illustrated in
Next, the metal mesh layers are pre-preprocessed (S461).
The pre-processing may be a chemical pre-processing method using a method of submerging the mesh metal layers in water tanks 1121a and 1121b for pre-processing in which a pre-processing solution is accommodated.
Next, a first washing operation of washing the pre-processed metal mesh layers is performed (S462).
The first washing operation may be performed by a method of submerging the metal mesh layer in water tanks 1122a and 1122b for first washing in which a washing fluid is accommodated.
Next, second adhesive layers are formed on the metal mesh layers (S463).
The second adhesive layer may be a solder layer, and the solder layer may be formed by a publicly known electroplating method or electroless plating method using a method of submerging the metal mesh layer in water tanks 1123a and 1123b for plating including a plating liquid.
Next, a second washing operation of washing a metal mesh layer 1122 on which the second adhesive layers are formed, is performed (S464).
The second washing operation may be performed by a method of submerging the metal mesh layer in water tanks 1124a and 1124b for the second washing in which a washing fluid is accommodated, but the washing method is not limited in the present invention, and the second washing process may be omitted as necessary.
Next, an operation of drying the metal mesh layer, on which the second adhesive layers are formed, is performed (S465).
The drying operation may be hot-air drying performed by hot-air drying furnaces 1125a and 1125b, but the drying method is not limited in the present invention, and the drying process may be omitted as necessary.
Next, the base material including the first adhesive layers and the metal mesh layer including the second adhesive layers are disposed in such a manner than the second adhesive layers are positioned on the first adhesive layers, and the second adhesive layers and the first adhesive layers are compressed by compression rollers 1130a and 1130b (S470).
In this case, the first adhesive layer and the second adhesive layer may be compressed at a predetermined temperature in order to improve performance of adhesion of the adhesive layers, and the predetermined temperature may be 150 to 500° C.
In the meantime, in the current collector 1131 for the rechargeable battery, on which up to operation S470 is performed, the metal mesh layer includes the protection film, so that an opposing surface of the metal mesh layer, which is not attached to the adhesive layer, includes the protection film.
Accordingly, in the method of manufacturing the current collector for the rechargeable battery according to the modified example of the sixth embodiment of the present invention, the protection film is removed from the metal mesh layer during final use (S480).
Accordingly, it is possible to manufacture the current collector for the rechargeable battery including the metal mesh layer according to the modified example of the sixth embodiment of the present invention.
In the meantime, although it is not illustrated in the drawing, the metal mesh layer may be positioned on only any one surface of the first surface and the second surface of the base material in the modified example of the sixth embodiment of the present invention, similar to the first embodiment of the present invention.
First, referring to
The base material 3110 may be varied according to whether the current collector is a positive electrode current collector or a negative electrode current collector.
Subsequently, referring to
The metal mesh layers 3130a and 3130b may be formed of at least one material among copper (Cu), silver (Ag), chrome (Cr), nickel (Ni), iron (Fe), cobalt (Co), and an alloy thereof, but a material of the metal mesh layer is not limited in the present invention.
In this case, the first metal mesh layer 3130a includes first holes 3132a positioned between a plurality of first metal mesh patterns 3131a, and the second metal mesh layer 3130b includes second holes 3132b positioned between a plurality of second metal mesh patterns 3131b.
Subsequently, referring to
More particularly, the first adhesive layer is positioned between the first surface of the base material 3110 and the first metal mesh patterns 3131a, the second adhesive layer is positioned between the second surface of the base material 3110 and the second metal mesh patterns 3131b.
The first adhesive layer 3120a and the second adhesive layer 3120b are provided for attaching the metal mesh layers onto the base material 110, and the first adhesive layer and the second adhesive layer may be solder layers, and in this case, the solder layer may be formed of lead (Pb), tin (Sn), zinc (Zn), indium (In), cadmium (Cd), bismuth (Bi), and an alloy thereof.
That is, the current collector 3100 for the rechargeable battery according to the seventh embodiment of the present invention includes the metal mesh layers 3130a and 3130b formed on the first surface and the second surface of the base material 3110, respectively, and each of the metal mesh layers includes the plurality of metal mesh patterns 3131a and 3131b, and the holes 3132a and 3132b positioned between the metal mesh patterns 3131a and 3131b, respectively, and in this case, the current collector 3100 includes the adhesive layers 3120a and 3120b for attaching the base material and the metal mesh layers.
As described above, the active material is deintercalated from the current collector due to degradation of the active material according to the repeat of charging and discharging several tens to several hundreds of times in the rechargeable battery having a general structure, so that battery efficiency deteriorates.
However, in the present invention, since the metal mesh layers are attached onto the current collector, on which the active material is coated, more particularly, the base material, through the adhesive layers, and the metal mesh layers include the holes 3132a and 3132b positioned between the metal mesh patterns, the active material is applied onto the metal mesh layers through the holes 3132a and 3132b, and thus contact areas of the metal mesh layers and the active material are increased, thereby restricting the active material from being deintercalated from the current collector and improving a cycle lifespan property of the battery.
In the present invention, the active material is applied onto the metal mesh layer, and in this case, the active material is also applied onto the base material through the holes positioned between the metal mesh patterns.
That is, the active material includes a region in which the active material is in direct contact with the base material, so that it is possible to prevent in and out of electrons and the like from being restricted by the adhesive layers in a charging and discharging process of the rechargeable battery.
Next, referring to
The current collector 3200 for the rechargeable battery according to the eighth embodiment of the present invention includes an adhesive layer 3220 positioned between the base material 3210 and the metal mesh patterns 3231.
As described above, in the rechargeable battery, for example, in a positive electrode, a positive electrode active material may be applied onto one surface or both surfaces of a positive electrode current collector.
That is, the current collector 3200 for the rechargeable battery according to the eighth embodiment of the present invention is an embodiment in which the metal mesh layer 3230 is formed on only one surface of the base material 3210, so that the metal mesh layer may be formed on a first surface and/or a second surface of the base material in the present invention.
The current collector for the rechargeable battery according to the eighth embodiment of the present invention may be the same as the current collector for the rechargeable battery according to the seventh embodiment of the present invention except for the aforementioned matter, so that a detailed description thereof will be omitted below.
First, referring to
In the meantime, it has been described that the metal mesh layer is manufactured by an electroforming method using the continuous electroforming device, but, by contrast, the metal mesh layer may be manufactured by a weaving or mechanical processing method, and thus, the method of manufacturing the metal mesh layer is not limited in the present invention.
In this case, a width d1 of the metal mesh layer 3130 may be 1 to 500 μm, and a thickness d2 of the metal mesh layer may be 1 to 500 μm, and further, an interval between the metal mesh patterns, that is, a size of the hole 3132 positioned between the metal mesh patterns 3131 may be 1 μm to 3 mm, but numerical values thereof are not limited in the present invention.
Subsequently, referring to
The adhesive layer 3120 may be a solder layer, and the solder layer may be formed by a publicly known electroplating method or electroless plating method, but the method of forming the solder layer is not limited in the present invention.
In this case, a thickness d3 of the adhesive layer may be 1 to 20 μm, but the numerical value thereof is not limited in the present invention.
Next, referring to
In this case, a thickness d4 of the base material 3110 may be 1 to 100 μm, but the numerical value thereof is not limited in the present invention.
Next, referring to
More particularly, the first metal mesh layer 3130a including the first adhesive layer 3120a formed on one surface thereof may be positioned on the first surface of the base material, and the second metal mesh layer 3130b including the second adhesive layer 3120b formed on one surface thereof may be positioned on the second surface of the base material, and the metal mesh layers may be compressed by the compression rollers, so that the first metal mesh layer is formed on the first surface of the base material and the second metal mesh layer is formed on the second surface of the base material.
In this case, the first metal mesh layer and the second metal mesh layer may be compressed at a predetermined temperature in order to improve performance of adhesion of the adhesive layers and the base material, and the predetermined temperature may be 150 to 500° C.
Accordingly, it is possible to manufacture the current collector for the battery including the metal mesh layer according to the present invention.
That is, as illustrated in
First, referring to
In this case, as described above, the metal mesh layer may include the metal mesh patterns and the holes between the metal mesh patterns, and this has been described above, so that a detailed description thereof will be omitted.
In the meantime, as illustrated in
That is, the current collector for the rechargeable battery according to the seventh embodiment of the present invention includes a first metal mesh layer supply unit 4020a for providing the first metal mesh layer onto the first surface of the base material, and a second metal mesh layer supply unit 4020b for providing the second metal mesh layer onto the second surface of the base material.
Hereinafter, the processes of forming the first metal mesh layer and the second metal mesh layer, which is to be performed below, are the same as each other, so that the first metal mesh layer and the second metal mesh layer are referred to as the metal mesh layer without being discriminated for convenience of the description.
Next, the metal mesh layers are pre-preprocessed (S4110).
The pre-processing may be a general chemical pre-processing method, and the chemical pre-processing method may be a method, such as acid washing and fat removal, of removing oil, contaminants, and impurities on a surface of the metal material by submerging a target material, that is, the metal mesh layer in an acidic or alkaline solution or spraying the solution to the target material.
In the present invention, the pre-processing may be a chemical pre-processing method by a method of submerging the metal mesh layer in water tanks 4021a and 4021b for pre-processing in which a pre-processing solution is accommodated, but the pre-processing method is not limited in the present invention, and the pre-processing process may be omitted as necessary.
Next, a first washing operation of washing the pre-processed metal mesh layers is performed (S4120).
The first washing operation, which is a process for removing the pre-processing solution and the like used in the pre-processing process, may be performed by a method of submerging the metal mesh layers in water tanks 4022a and 4022b for the first washing in which a washing fluid is accommodated, but the washing method is not limited in the present invention, and the first washing process may be omitted as necessary.
Next, adhesive layers are formed on the metal mesh layers (S4130).
The adhesive layer may be a solder layer, and the solder layer may be formed by a publicly known electroplating method or electroless plating method using the method of submerging the metal mesh layers in water tanks 4023a and 4023b for plating including a plating liquid, but the method of forming the solder layer is not limited in the present invention.
In this case, the first adhesive layer may be formed on the first metal mesh layer, and the second adhesive layer may be formed on the second metal mesh layer.
In the meantime, when the adhesive layers are formed by the method of submerging the metal mesh layers in the water tanks 4023a and 4023b for plating of operation S4130 illustrated in
As a matter of course, in the present invention, the adhesive layers may be formed on both surfaces of the metal mesh layer, but it is sufficient that the adhesive layer is formed on only one surface of the metal mesh layer in the present invention, so that the description will be given below based on that the adhesive layer is formed on only one surface of both surfaces of the metal mesh layer.
In the meantime, it is apparent that the adhesive layer may be selectively formed on only one surface of the metal mesh layer by a publicly known printing method, deposition method, and the like.
Next, a second washing operation of washing a metal mesh layer 4022, on which the adhesive layers are formed, is performed (S4140).
The second washing operation, which is a process for washing the plating liquid and the like used in the adhesive layer forming process, may be performed by a method of submerging the metal mesh layer in water tanks 4024a and 4024b for the second washing in which a washing fluid is accommodated, but the washing method is not limited in the present invention, and the second washing process may be omitted as necessary.
Next, an operation of drying the metal mesh layer, on which the adhesive layers are formed, is performed (S4150).
The drying operation may be hot-air drying performed by hot-air drying furnaces 4025a and 4025b, but the drying method is not limited in the present invention, and the drying process may be omitted as necessary.
Subsequently, referring to
The base material 4011 may be varied according to whether the current collector is a positive electrode current collector or a negative electrode current collector, which has been described above, so that a detailed description thereof will be omitted.
In the meantime, as described above, in the current collector for the rechargeable battery according to the seventh embodiment of the present invention, the metal mesh layer supply units 4020a and 4020b may be positioned on the first surface and the second surface of the base material, respectively, in order to supply the metal mesh layers onto the first surface and the second surface of the base material.
That is, the current collector for the rechargeable battery according to the seventh embodiment of the present invention includes the first metal mesh layer supply unit 4020a for providing the first metal mesh layer onto the first surface of the base material and the second metal mesh layer supply unit 4020b for providing the second metal mesh layer onto the second surface of the base material, and thus, the first metal mesh layer including the first adhesive layer may be provided onto the first surface of the base material and the second metal mesh layer including the second adhesive layer may be provided onto the second surface of the base material.
Next, the metal mesh layer 4022 including the adhesive layers is positioned on the base material, and the metal mesh layer 4022 is compressed by using compression rollers 4130a and 4130b (S4170).
In the current collector for the rechargeable battery according to the seventh embodiment of the present invention, the first metal mesh layer including the first adhesive layer is positioned on the first surface of the base material, and the second metal mesh layer including the second adhesive layer is positioned on the second surface of the base material, and then the first metal mesh layer and the second metal mesh layer may be compressed onto the first surface and the second surface of the base material through the first adhesive layer and the second adhesive layer by using the compression rollers, respectively.
In this case, the first metal mesh layer and the second metal mesh layer may be compressed at a predetermined temperature in order to improve performance of adhesion of the adhesive layers and the metal mesh layers, and the predetermined temperature may be 150 to 500° C.
Accordingly, it is possible to manufacture the current collector for the rechargeable battery including the metal mesh layer according to the seventh embodiment of the present invention.
That is, as illustrated in
Next, referring to
In this case, as described above, the metal mesh layer may include the metal mesh patterns and the holes between the metal mesh patterns, and this has been described above, so that a detailed description thereof will be omitted.
In the meantime, as illustrated in
That is, the current collector for the rechargeable battery according to the eighth embodiment of the present invention includes the metal mesh layer supply unit 5020a for providing the metal mesh layer onto the first surface of the base material.
As described above, in the rechargeable battery, for example, in a positive electrode, a positive electrode active material may be applied onto one surface or both surfaces of a positive electrode current collector.
That is, the method of manufacturing the current collector for the rechargeable battery according to the eighth embodiment of the present invention is an embodiment in which the metal mesh layer is formed on only one surface of the base material, so that the metal mesh layer may be formed on the first surface and/or the second surface of the base material in the present invention.
Next, the metal mesh layers are pre-preprocessed.
The pre-processing may be a chemical pre-processing method using a method of submerging the mesh metal layers in a water tank 2021a for pre-processing in which a pre-processing solution is accommodated.
Next, a first washing operation of washing the pre-processed metal mesh layers is performed.
The first washing operation may be performed by a method of submerging the metal mesh layer in a water tank 5022a for first washing in which a washing fluid is accommodated.
Next, adhesive layers are formed on the metal mesh layer.
The adhesive layer may be a solder layer, and the solder layer may be formed by a publicly known electroplating method or electroless plating method using a method of submerging the metal mesh layer in a water tank 5023a for plating including a plating liquid.
Next, a second washing operation of washing a metal mesh layer 5022, on which the adhesive layers are formed, is performed.
The second washing operation may be performed by a method of submerging the metal mesh layer in a water tank 5024a for second washing in which a washing fluid is accommodated.
Next, an operation of drying the metal mesh layer, on which the adhesive layers are formed, is performed.
The drying operation may be hot-air drying performed by a hot-air drying furnace 5025a.
Subsequently, referring to
The base material 5011 may be varied according to whether the current collector is a positive electrode current collector or a negative electrode current collector, which has been described above, so that a detailed description thereof will be omitted.
In the meantime, as described above, in the current collector for the rechargeable battery according to the eighth embodiment of the present invention, the metal mesh layer supply unit 5020a may be positioned only on the first surface of the base material in order to supply the metal mesh layer onto the first surface of the base material.
Next, the metal mesh layer 5022 including the adhesive layer is positioned on the base material, and the metal mesh layer 5022 is compressed by using compression rollers 5130a and 5130b.
In the current collector for the rechargeable battery according to the eighth embodiment of the present invention, the metal mesh layer including the adhesive layers may be positioned on the first surface of the base material, and the metal mesh layer may be compressed onto the first surface of the base material through the adhesive layer by using the compression rollers.
In this case, the metal mesh layer may be compressed at a predetermined temperature in order to improve performance of adhesion of the adhesive layer and the metal mesh layer, and the predetermined temperature may be 150 to 500° C.
Accordingly, it is possible to manufacture the current collector for the rechargeable battery including the metal mesh layer according to the eighth embodiment of the present invention.
That is, as illustrated in
First, referring to
As described above, in the pre-deposited layer peeling operation of manufacturing the metal mesh layer, an adhesive may be applied onto the protection film, the protection film may be laminated on the metal mesh layer formed on the mesh of the surface of the mesh type negative electrode drum, and then the protection film and the metal mesh layer may be peeled together.
By contrast, only the metal mesh layer may be separated from the mesh of the surface of the mesh type negative electrode drum without a separate protection film, and in this case, the metal mesh, which is washed through the pre-deposited layer washing operation, may be attached to a separate protection film and used for easiness in the process.
The method of manufacturing the current collector for the rechargeable battery according to the modified example of the seventh embodiment of the present invention corresponds to the case where the metal mesh layer including the protection film is used.
Subsequently, referring to
In the meantime, as illustrated in
That is, the current collector for the rechargeable battery according to the modified example of the seventh embodiment of the present invention includes a first metal mesh layer supply unit 6120a for providing the first metal mesh layer onto the first surface of the base material, and a second metal mesh layer supply unit 6120b for providing the second metal mesh layer onto the second surface of the base material.
Hereinafter, the processes of forming the first metal mesh layer and the second metal mesh layer, which is to be performed below, are the same as each other, so that, for convenience of the description, the first metal mesh layer and the second metal mesh layer are referred to as the metal mesh layer without being discriminated.
Next, the metal mesh layers are pre-preprocessed (S6210).
The pre-processing may be a chemical pre-processing method using a method of submerging the mesh metal layers in water tanks 6121a and 6121b for pre-processing in which a pre-processing solution is accommodated.
Next, a first washing operation of washing the pre-processed metal mesh layers is performed (S6220).
The first washing operation may be performed by a method of submerging the metal mesh layer in water tanks 6122a and 6122b for first washing in which a washing fluid is accommodated.
Next, adhesive layers are formed on the metal mesh layers (S6230).
The adhesive layer may be a solder layer, and the solder layer may be formed by a publicly known electroplating method or electroless plating method using a method of submerging the metal mesh layer in water tank 6123a and 6123b for plating including a plating liquid.
In this case, the first adhesive layer may be formed on the first metal mesh layer, and the second adhesive layer may be formed on the second metal mesh layer.
Next, a second washing operation of washing a metal mesh layer 6122, on which the adhesive layers are formed, is performed (S6240).
The second washing operation may be performed by a method of submerging the metal mesh layer in water tanks 6124a and 6124b for second washing in which a washing fluid is accommodated.
Next, an operation of drying the metal mesh layer, on which the adhesive layers are formed, is performed (S6250).
The drying operation may be hot-air drying performed by hot-air drying furnaces 6125a and 6125b.
Subsequently, referring to
The base material 6111 may be varied according to whether the current collector is a positive electrode current collector or a negative electrode current collector, which has been described above, so that a detailed description thereof will be omitted.
In the meantime, as described above, in the current collector for the rechargeable battery according to the modified example of the seventh embodiment of the present invention, the metal mesh layer supply units 6120a and 6120b may be positioned on the first surface and the second surface of the base material, respectively, in order to supply the metal mesh layers onto the first surface and the second surface of the base material.
That is, the first metal mesh layer including the first adhesive layer may be provided onto the first surface of the base material, and the second metal mesh layer including the second adhesive layer may be provided onto the second surface of the base material.
Next, the metal mesh layer 6122 including the adhesive layers is positioned on the base material, and the metal mesh layer 6122 is compressed by using compression rollers 6130a and 6130b (S6270).
When the metal mesh layer including the adhesive layers is positioned on the base material, the adhesive layer positioned on an opposing surface, on which the protection film is positioned, is positioned on the base material.
In the current collector for the rechargeable battery according to the modified example of the seventh embodiment of the present invention, the first metal mesh layer including the first adhesive layer is positioned on the first surface of the base material, and the second metal mesh layer including the second adhesive layer is positioned on the second surface of the base material, and then the first metal mesh layer and the second metal mesh layer may be compressed onto the first surface and the second surface of the base material through the first adhesive layer and the second adhesive layer by using the compression rollers, respectively.
In this case, the first metal mesh layer and the second metal mesh layer may be compressed at a predetermined temperature in order to improve performance of adhesion of the adhesive layers and the metal mesh layers, and the predetermined temperature may be 150 to 500° C.
In the meantime, in the current collector 6131 for the rechargeable battery, on which up to operation S6270 is performed, the metal mesh layer includes the protection film, so that the opposing surface of the metal mesh layer, which is not attached to the base material, includes the protection film.
Accordingly, in the method of manufacturing the current collector for the rechargeable battery according to the modified example of the seventh embodiment of the present invention, the protection film is removed from the metal mesh layer during final use (S6280).
In the meantime, compared to the seventh embodiment, in the modified example of the seventh embodiment, the protection film is included on the metal mesh layer, more particularly, on the opposing surface of the metal mesh layer, which is not attached to the base material, so that it is possible to easily achieve a protection property and a storage property of the current collector for the rechargeable battery.
Accordingly, it is possible to manufacture the current collector for the rechargeable battery including the metal mesh layer according to the modified example of the seventh embodiment of the present invention.
Next, referring to
In this case, as described above, the metal mesh layer may include the metal mesh patterns and the holes between the metal mesh patterns, and this has been described above, so that a detailed description thereof will be omitted.
In the meantime, as illustrated in
That is, the current collector for the rechargeable battery according to the modified example of the eighth embodiment of the present invention includes the metal mesh layer supply unit 7120a for providing the metal mesh layer onto the first surface of the base material.
As described above, in the rechargeable battery, for example, in a positive electrode, a positive electrode active material may be applied onto one surface or both surfaces of a positive electrode current collector.
That is, the method of manufacturing the current collector for the rechargeable battery according to the modified example of the eighth embodiment of the present invention is an embodiment in which the metal mesh layer is formed on only one surface of the base material, so that the metal mesh layer may be formed on the first surface and/or the second surface of the base material in the present invention.
Next, the metal mesh layer is pre-preprocessed.
The pre-processing may be a chemical pre-processing method using a method of submerging the mesh metal layers in a water tank 7121a for pre-processing in which a pre-processing solution is accommodated.
Next, a first washing operation of washing the pre-processed metal mesh layers is performed.
The first washing operation may be performed by a method of submerging the base material in a water tank 7122a for first washing in which a washing fluid is accommodated.
Next, adhesive layers are formed on the metal mesh layer.
The adhesive layer may be a solder layer, and the solder layer may be formed by a publicly known electroplating method or electroless plating method using a method of submerging the metal mesh layer in a water tank 7123a for plating including a plating liquid.
Next, a second washing operation of washing a metal mesh layer 7122, on which the adhesive layers are formed, is performed.
The second washing operation may be performed by a method of submerging the metal mesh layer in a water tank 7124a for second washing in which a washing fluid is accommodated.
Next, an operation of drying the metal mesh layer, on which the adhesive layers are formed, is performed.
The drying operation may be hot-air drying performed by a hot-air drying furnace 7125a.
Subsequently, referring to
The base material 7111 may be varied according to whether the current collector is a positive electrode current collector or a negative electrode current collector, which has been described above, so that a detailed description thereof will be omitted.
In the meantime, as described above, in the current collector for the rechargeable battery according to the modified example of the eighth embodiment of the present invention, the metal mesh layer supply unit 7120a may be positioned only on the first surface of the base material in order to supply the metal mesh layer onto the first surface of the base material.
Next, the metal mesh layer 7122 including the adhesive layers is positioned on the base material, and the metal mesh layer 7122 is compressed by using compression rollers 7130a and 7130b.
In the current collector for the rechargeable battery according to the modified example of the eighth embodiment of the present invention, the metal mesh layer including the adhesive layers may be positioned on the first surface of the base material, and the metal mesh layer may be compressed onto the first surface of the base material through the adhesive layers by using the compression rollers.
In this case, the metal mesh layer may be compressed at a predetermined temperature in order to improve performance of adhesion of the adhesive layer and the metal mesh layer, and the predetermined temperature may be 150 to 500° C.
In the meantime, as described above, in the current collector 7131 for the rechargeable battery, on which up to the above operation is performed, the metal mesh layer includes the protection film, so that the opposing surface of the metal mesh layer, which is not attached to the base material, includes the protection film.
Accordingly, in the method of manufacturing the current collector for the rechargeable battery according to the modified example of the eighth embodiment of the present invention, the protection film is removed from the metal mesh layer during final use.
In the meantime, compared to the eighth embodiment, in the modified example of the eighth embodiment, the protection film is included on the metal mesh layer, more particularly, on the opposing surface of the metal mesh layer, which is not attached to the base material, so that it is possible to easily achieve a protection property and a storage property of the current collector for the rechargeable battery.
Accordingly, it is possible to manufacture the current collector for the rechargeable battery including the metal mesh layer according to the modified example of the eighth embodiment of the present invention.
In the meantime, although it is not illustrated in the drawings, the shape of the metal mesh pattern may be varied even in the seventh and eighth embodiments of the present invention, as illustrated in
The foregoing is illustrative of the present invention and is not to be construed as limiting thereof. Although a few embodiments of the present invention have been described, those skilled in the art will readily appreciate that many modifications are possible in the embodiments without materially departing from the novel teachings and advantages of the present invention. Accordingly, all such modifications are intended to be included within the scope of the present invention as defined in the claims. Therefore, it is to be understood that the foregoing is illustrative of the present invention and is not to be construed as limited to the specific embodiments disclosed, and that modifications to the disclosed embodiments, as well as other embodiments, are intended to be included within the scope of the appended claims. The present invention is defined by the following claims, with equivalents of the claims to be included therein.
| Number | Date | Country | Kind |
|---|---|---|---|
| 10-2012-0049224 | May 2012 | KR | national |
| 10-2012-0049228 | May 2012 | KR | national |
| 10-2012-0049231 | May 2012 | KR | national |
| 10-2012-0049234 | May 2012 | KR | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/KR2013/003371 | 4/22/2013 | WO | 00 |
| Publishing Document | Publishing Date | Country | Kind |
|---|---|---|---|
| WO2013/168910 | 11/14/2013 | WO | A |
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| Number | Date | Country | |
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| 20150125756 A1 | May 2015 | US |
