The present invention relates to a current conductor for a galvanic cell, as well as a galvanic cell comprising such a current conductor.
Galvanic cells, such as lithium ion cells, comprise, in many cases, multiple alternatingly stacked electrodes and separating elements, wherein a current conductor is either formed or attached to each electrode. Such a stack is usually accommodated in a packaging, from which the current conductors protrude, wherein the protrusion of these current conductors is sealed by the packaging. Several of these cells can, for example, be included in a lithium ion accumulator.
Recently, lithium ion cells have been used increasingly in electric vehicles and in electric hybrid vehicles. In these cases, during charging and discharging processes, very high currents flow through the current collectors, which are connected to the electrodes. Based on a permanent current flow of about 200 A, the temperature of a current collector is not allowed to rise, for example, above 50° C., since this not only leads to a loss of energy but also reduces the reliability of the lithium ion cell.
The cross section of the current conductor can, for example, be increased to reduce the energy conversion into heat. However, the dimensions of a lithium ion cell are often pre-defined or limited, due to limited assembly space, so that the current conductor often cannot be made wider. For this reason, thicker current collectors need to be used in many cases.
The aim of the present invention is therefore to provide a current conductor for galvanic cells, which ensures secure and durable sealing, independently of its thickness.
This problem is solved by a plate-shaped current conductor for galvanic cells, comprising the features of claim 1. Advantageous embodiments and developments and of the invention are the subject of the dependent claims.
The plate-shaped current conductor for a galvanic cell has a first surface and a second surface, which essentially face each other, and are connected with each other via a first side surface and a second side surface.
According to the present invention, it is envisioned that the plate-shaped current conductor has; in the area of the first and/or second side surface, a segment, which has a thickness, which is reduced in regard to its cross section vis-à-vis the thickness as defined by the first and second surface of the current conductor, which segment extends at least substantially over a sealing area of the current conductor.
By creating a segment with a thickness that us reduced in regard to its cross section, in the area of at least one side surface of the current conductor, a safe and a stable sealing can be formed between the current conductor and an appropriate packaging, so that a reliable and durable sealing of the galvanic cell is possible.
In the present invention, the term “galvanic cell” refers to cells for batteries and primary cells, respectively, as well as, in particular, rechargeable batteries and secondary batteries or accumulators, respectively. Generally, the current conductor is an element, which is connected with an electrode (anode or cathode) of the galvanic cell, or which is integrally formed with it, connected to it, being made of an electrically conductive material, to lead the charging current to the electrode or to dissipate the discharging current from the electrode.
The current conductor is an essentially plate-shaped body with a first surface and a second surface, which essentially face each other and, for example, form the two largest side surfaces of the body in the case of a cuboidal-shaped current conductor, which usually is aligned in parallel to the main extension plane of the corresponding electrode. The first and second side surface essentially face each other and connect the first and the second surface of the current conductor. The two side surfaces, which are the remaining surfaces in case of a cuboidal-shaped current conductor, have no relevance for the present invention.
A thickness D is defined by the first and the second surface of the plate-shape current conductor. This thickness D is the essentially constant thickness of the current conductor between the two side surface areas, in case of essentially parallel side surfaces. In case of side surfaces, which are not in parallel to each other, the thickness D of the current conductor can also be the maximum thickness between the two side surface areas, or alternately, the average thickness between the two side surface areas. The segment of reduced thickness in regard to its cross section has a reduced thickness (d) in the area of the first and second side surface compared to the defined thickness D of the current conductor, which, for example, can be the minimum thickness over the entire area of the body of the current conductor. In the area of a side surface, generally, one or several such segments of reduced thickness can be envisioned, having the same or a different thickness.
The sealing area does not surround the entire surfaces and sides surfaces of the current conductor, but usually only a part of it, i.e. a vertical section of it. In a galvanic cell, the sealing area of the current conductor is aligned with an appropriate sealing area of a packaging, in order to produce a tight sealing between the two components.
Although the invention is exemplified below in more detail in regard to an essentially cuboidal-shaped current conductor, it is obvious, that the person skilled in the art may also define the surfaces for the plate-shaped current conductor for other geometric forms (for example: no parallel side surfaces, no rectangular-shaped surfaces etc.) in the sense explained above.
In one embodiment of the invention, the segment of reduced thickness extends over the area of the first and/or the second side surface, essentially over the entire height of the first or second side surface. In an alternative embodiment of the invention, the area of reduced thickness in the area of the first and/or second side surfaces only extends essentially over the sealing area of the current conductor.
In another embodiment of the invention, the segment of reduced thickness in the area of the first and/or the second side surface is realized by an area segment, which merges into the first and second surface. Alternatively, the segment of reduced thickness in the area of the first and/or the second side surface is realized by at least two area segments, which on one hand, merge into each other, and, on the other hand, merge into the first and the second surface.
In a further embodiment of the invention, the area segment(s) of the segment of reduced thickness in the area of the first and/or second side surface is/are realized as essentially flat surfaces. Alternatively, the area segment(s) of the segment of reduced thickness in the range of the first and/or the second side surface is/are realized as curved surfaces. In case of several area segments, these segments can alternatively also comprise area segments, which are realized as essentially flat surfaces, and area segments, which are realized as curved surfaces.
In case of curved area segments, these segments can be selected to be concave or convex, or partially concave and partially convex.
In a further embodiment of the invention, the area segment(s) of the segment of reduced thickness in the area of the first and/or second side surface is/are realized to be inclined relative to the first or the second surface, having an average inclination angle of approximately 15° to 40°, preferably of about 20° to about 30°.
Further, the area segment(s) of the segment of reduced thickness in the area of the first and/or second side surface can be optionally realized symmetrically or asymmetrically.
Analogously, the area of the first and the area of the second side surface can optionally be realized symmetrically or asymmetrically to each other.
In still a further embodiment of the invention, the transition regions between the area segments and the surfaces and/or the transition regions between several area segments are realized to be steady, i.e. continuous or with no edges. Alternatively, these transition regions can also be non-steady, i.e. with edges.
In one embodiment of the invention, the current conductor is provided with a sealing layer in the sealing area. In other words, the current conductor is pre-sealed.
In this case, the sealing layer encloses the first and second surface, as well as the first and the second side surface of the current conductor around the circumference. The sealing layer is preferably made of a plastic material such as polyethylene, polypropylene, polyimide, polyethylene terephthalate, PVC, PDFE or any combination thereof. The sealing layer has, for example, a thickness in the range of about 0.02 mm to about 0.3 mm, preferably from about 0.05 mm to about 0.2 mm.
The sealing area and the sealing layer have, for example, a width of approximately 4 mm to about 15 mm, preferably from about 6 mm to about 10 mm.
In principle, the current conductor described above can be used in a galvanic cells for both electrodes, i.e. for the anode and the cathode. Furthermore, the current conductor is particularly advantageous for galvanic cells, which comprise a stack of several first electrodes and several second electrodes, which are alternatingly stacked onto each other, and which are each separated by a separation element.
In a first embodiment of the galvanic cell, the first and the second electrode(s) are contained in a packaging, through which the first and the second current conductor protrude. The packaging comprises a sealing area, and the first and/or the second current conductor is realized as a pre-sealed current conductor, which is sealed with the packaging in the sealing area of these two components.
In a second embodiment of the galvanic cell, the first and the second electrode(s) as well as the separating element(s) are accommodated in a packaging out of which the first and second current conductor protrude, and which features a sealing area pre-sealed with a sealing layer and, moreover, the first and/or the second current conductor is/are realized as a current conductor without its own sealing layer, which is sealed via the sealing layer of the packaging in the sealing areas of these two components.
In a third embodiment of the galvanic cell, the first and the second electrode(s) as well as the separating element(s) are accommodated in a packaging, out of which the first and second current conductor protrude, and which features a sealing area without its own sealing, and, moreover, the first and/or second current conductor is/are realized as current conductors without its own sealing. In this case, the sealing between these two components is realized by a interposed, separate sealing layer, or, in case of an appropriate packaging material, directly between the two components.
Finally, in a fourth embodiment of the galvanic cell, the first and the second electrode(s) as well as the separating elements(s) are accommodated in a packaging out of which the first and the second current conductor protrude, and which features a sealing area, which is pre-sealed with a sealing layer and, moreover, the first and/or the second current conductor is/are realized as a pre-sealed current conductor sealed with the packaging in the sealing area of the current conductor via the sealing layer of the current conductor and via the sealing layer of the packaging.
It is of particular advantage to use of the current conductor according to the present invention in galvanic cells, which are realized as lithium ion cells.
Features and advantages of the invention as disclosed above and in the following are better understandable in the context of the following descriptions of preferred, non-limiting embodiments, in context with the attached figures, in which:
The basic structure of a current conductor according to the present invention is first described on the basis of
The electrode (10) is a first electrode (anode) or a second electrode (cathode) of a galvanic cell. The current conductor (12) of the present invention, which is hereinafter described in detail is, in particular, advantageously applicable for lithium ion cells with a stack of several first electrodes and several second electrodes, which are alternatingly stacked onto each other, each separated from each other with a separating element, without limiting the present invention to only such galvanic cells. Generally, the current conductor of the present invention can be used for layered cells and wound cells, for primary cells and for secondary cells.
In a lithium ion cell, the current conductor, which is connected to the anode, is usually made of copper, and the current conductor, which is connected with the cathode, is usually made of aluminium. Evidently, however, the present invention is not limited to these materials and for other kinds of secondary or primary batteries, with other electrolytes and other electrodes, other materials may be preferred.
As indicated in
The essentially plate-shaped current conductor (12) is illustrated as a cuboid body, which comprises a first surface (16) and a second surface, (17), which are essentially—not necessarily in parallel—opposite to each other. The two surfaces 16 and 17 form the main surfaces of the current conductor (12) with the largest areas, and are essentially arranged in parallel to the main extension plane of the electrode (10), as indicated in
The plate-shaped cuboid body, further comprises two additional side surfaces (20) (above and in
The current conductor (12) has a sealing area (14), with which the conductor is sealed tightly with the packaging of the galvanic cell. This sealing area encloses the first and second surface (16, 17) across the circumference, as well as the first and second side surfaces (18, 19), via a certain partial height (h), i.e. not over the entire height (H), of the current conductor (12).
Even if the sealing area (14) is essentially in parallel to the edges of the two surfaces (16, 17) and to the two side surfaces (18, 19), this is not mandatory, and the course of the sealing area (14) can also be adapted to the configuration of the cell packaging. The thickness (b) of the sealing area also does not have to be of constant thickness over the entire area of the current conductor, as depicted in
While the current conductor (12) in the embodiment of
The seal layer (22) consists of a high-melting plastic material, which is chemically compatible and inert with respect to the content of the galvanic cell. Suitable materials for the sealing layer (22) include, for example, polyethylene, polypropylene, polyimide, polyethylene terephthalate, PVC, PDFE or any combination thereof. The sealing layer (22) has, for example, a thickness (t) in the range of about 0.02 mm to about 0.3 mm, preferably in the range of about 0.05 mm to about 0.2 mm, and most preferably from about 0.1 mm. The width of the sealing layer (22) essentially corresponds to the width (b) of the sealing area (14) of the current conductor (12).
The other characteristics of the current conductor (12) of embodiment
The current conductor (12) of
In an exemplified embodiment, the current conductor (12) consists of copper (for connecting the same to an anode) or aluminium (for connecting the same to a cathode) and has, for example, a thickness (D) of about 0.3 mm (copper), or about 0.5 mm (aluminium), respectively, a height (H) of about 35 mm and a length (L) of about 105 mm. The sealing area (14) or the sealing layer (15), respectively, have a width (b) of about 7 mm and can be added, for example, in a distance of about 50 to 10 mm from the lower edge of the current conductor (12).
The sealing between the current conductor (12) and the packaging of the galvanic cell can be achieved differently, depending on the embodiment of the current conductor (12). In a first embodiment, the current conductor (12) comprises only a sealing area (14), but no pre-sealed sealing layer (22). If the packaging of the galvanic cell also only comprises a sealing area, but no sealing layer, the sealing between the two components can either be accomplished via an intervening separate sealing layer, or—in case of an appropriate packaging material—directly.
In a second embodiment, the current conductor (12) again only comprises the sealing area (14) (see
Furthermore, in a third embodiment according to
As another embodiment, it is also possible, to provide the sealing area (14) of the current conductor (12) with a sealing layer (22), as well as to provide the sealing area of the cell packaging with a sealing layer. In this case, the sealing is performed by means of the connection of the two sealing layers on the current conductor and on the packaging.
Referring to
However, in case of a thicker current conductor (12), non-tight areas in form of continuous channels (26) may occur on both side surfaces (18, 19), as illustrated in
To reduce these types of problems for conventional current conductors, it is suggested to modify the current conductor (12) for galvanic cells. Subsequently, in reference to
In a first embodiment of
A segment of reduced thickness is realized in the area of the side surface (19) of the current conductor by means of these three area segments (24a, 24b, 24c). The thickness (d) of the segment is reduced in cross section compared to the thickness (D) of the current conductor (12) between the two side surfaces (18, 19). As clearly illustrated in
In the embodiment of
The two area segments (24a and 24c) are inclined, with a mean inclination angle (α), with respect to the respective surface (16 or 17). This inclination angle (α) is, for example, in the range of about 15° to about 40°, preferably from about 20° to about 30°, most preferably at about 30°. Although the two area segments (24a, 24c) are both illustrated in
The second embodiment of
Specifically, the segment of reduced thickness (d) is realized, in the area of the side surface (18), via two area segments (24a, 24b), which each are realized as flat surfaces and merge non-steadily into the surfaces (16, 17), and into each other.
The third embodiment, shown in
As an asymmetric alternative of this embodiment, it is also possible to replace the two area segments (24d, 24e) in
The fourth embodiment, illustrated in
As an asymmetric alternative of this embodiment, it is also possible, for example, to replace the curved third area segment (24c) of
In the fifth embodiment of
The sixth embodiment, illustrated in
The seventh embodiment, which will now be described in the context of
In the eighth embodiment of
The ninth embodiment, illustrated in
As a tenth embodiment,
The eleventh embodiment, illustrated in
The present invention has been described in detail above, exemplified by numerous embodiments of the current conductor (12). However, it is obvious that the person skilled in the art will find additional variations and modifications of the present invention, based on the illustrated embodiments, without departing the from scope of protection, defined by the attached claims.
In particular, the embodiments of the current conductor (12), as illustrated in
The cross-sectional configurations of the current conductor (12), illustrated in
The mean inclination angle (α) in the area of the side surface (18, 19), which is illustrated by means of embodiment of
Due to the outlined advantages, the current conductor configured according to the present invention is particularly suitable for lithium ion cells, for example for electrical vehicles and for electrical hybrid vehicles, for which thicker current conductors must be used, due to the arising strong currents.
Number | Date | Country | Kind |
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10 2007 059 768.3 | Dec 2007 | DE | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/EP08/10397 | 12/8/2008 | WO | 00 | 8/5/2010 |