This application claims the benefit of Taiwan Patent Application Serial No. 110142418 filed Nov. 15, 2021, the subject matter of which is incorporated herein by reference.
The present invention relates to a curved plastic panel and a processing method and device thereof, especially a processing method and device for firstly providing a hard coating layer and an optical function layer onto a flat plastic substrate and then hot pressing the flat plastic substrate into a curved plastic panel.
Most of the traditional vehicles use glass as the material for the sunroof, the windshield, and the front panel of the vehicle display. Because glass has disadvantages such as heavy in weight, fragile, and difficulty in shaping, some people have developed transparent plastic plates in recent years to replace traditional glass in order to produce the sunroof, the windshield, and the front panel of the vehicle display. Because the vehicle display needs a curved design that is more in streamline with the interior of the car, in recent years, some manufacturers have begun to think of a vehicle display with a curved surface to replace the traditional flat-panel car display. However, one of the biggest difficulties in the product design of the curved vehicle display is the material of the curved panel covering the front of the curved vehicle display and its manufacturing process.
The conventional curved glass panel needs to first process the flat glass plate into curved glass plate by ultra-high temperature thermoforming, and then carry out the surface grinding and polishing of the curved glass plate, and finally carry out optical surface treatments (such as anti-glare or anti-reflection coatings, etc.). However, it is very difficult to control the coating uniformity for optical surface treatments on curved substrates, especially the thickness uniformity of the anti-reflective coating must reach the coating tolerance specification of +/−10 nm, in order to achieve the request of reflectivity of the vehicle front panel <1%. It is quite difficult to achieve this specification in flat panel coating, and it is almost impossible to achieve this on curved panels.
Of course, in recent years, various technologies have also been developed to use plastic materials to make vehicle display panels. There are many types of plastics. Among them, engineering plastics composed of polycarbonate (PC for short) have the advantages of high transparency and free dyeing, high strength and elastic coefficient, high impact strength, wide applicable temperature range, low molding shrinkage, good dimensional stability, good weather resistance, tasteless and odorless, harmless to the human body, fulfilling health and safety requirements, easy to shape, and etc. Therefore, it is more suitable for making transparent substrates with curved surfaces or special structures to replace fragile and unshaped glass plates. However, polycarbonate (PC) also has the disadvantages of being non-abrasive and prone to yellowing under ultraviolet light. Thus, in the prior art, a wear-resistant hard coating layer and an optical function layer are added on the outer surface of the polycarbonate (PC) substrate to improve its wear resistance, UV resistance, anti-glare, and anti-reflect properties.
However, the conventional technologies still encounter a very difficult problem in manufacturing a plastic panel with a curved surface. As shown in
As shown in
Step 21: making a flat plastic substrate (commonly known as a raw board) by plastic extrusion molding. This plastic substrate may be a single-layer PC plate, a PMMA/PC double-layer composite plate, or a PMMA/PC/PMMA three-layer composite plate.
Step 22: hot pressing the flat plastic substrate into a curved plastic substrate by means of hot pressing curvature forming.
Step 23: performing HC surface treatment on the plastic substrate having a curved surface, so as to form a hard coating layer on the upper surface of the plastic substrate having the curved surface. However, due to the difficulty of HC surface treatment on curved plastic substrates, the yield rate is not good.
Step 24: performing optical surface treatment on the plastic substrate having the curved surface, so as to form an optical function layer on the hard coating layer of the plastic substrate having the curved surface. However, due to the difficulty of optical surface treatment on curved plastic substrates, the yield rate is not good.
Step 25: performing a printing process on the plastic substrate having the curved surface, so as to form a printing layer on the lower surface of the plastic substrate having the curved surface. However, because the curved plastic substrate is difficult to print, the yield rate is not good.
Step 26: The plastic substrate having the curved surface is processed by a plane computer numerical control (referred to as CNC) processing machine to cut the plastic substrate having the curved surface into a predetermined contour. However, because it is difficult to perform plane CNC machining on curved plastic substrates, the yield rate is not good.
Step 27: Complete the finished plastic panel with a curved surface. Since the defective rate from Step 23 to Step 26 has a cumulative effect, the yield rate of the final finished product is very low, so there is still room for improvement.
As shown in
The traditional curvature surface molding of polymer substrates is to first heat the polymer substrate to a temperature higher than the softening point (Tg; glass transition temperature) of the polymer, and then transfer the heated polymer substrate to a hot pressing mold for curvature surface thermoforming. The temperature change of the substrate caused by the thermal convection of the air at room temperature during the transfer process will affect the curvature and contour accuracy of the hot pressing. The longer the transfer time, the longer the cooling time, the less conducive to controlling the temperature uniformity of the substrate, and the worse the control of the curvature and contour accuracy of the hot pressing. Therefore, reducing the transfer time and cooling time is more conducive to the precision control of curvature and contour. The most ideal process design is that high temperature heating and curvature forming are carried out simultaneously in an automated mold. The key point of the present invention is the sensing elements that can monitor the local temperatures and local curvatures in real time, and feed back to the heating mechanism and the hot pressing mechanism, so as to adjust the plate to reach the optimum forming temperature and target curvature in real time.
The primary objective of the invention is to provide a method for processing a curved plastic panel. The method first forms a hard coating layer, an optical function layer, and a printing layer on a flat plastic substrate, and then uses a CNC machine to cut it into a predetermined shape, and then uses a hot pressing and curving device to perform a hot pressing and curving process to the flat plastic substrate in order to make it becoming a curved plastic substrate. The method of the present invention has the advantages of optical function (anti-reflection or anti-glare) and safety and non-breakage in addition to the production of multifunctional polymer material panels for displays with partially or fully curved surfaces. Moreover, since the processing of the hard coating layer, optical function layer, printing layer and CNC cutting are all carried out on the flat plastic substrate, the yield rate is very high, which overcomes various deficiencies of the prior art.
The second objective of the invention is to provide a device for processing a curved plastic panel. The device includes a hot pressing and curving device which can simultaneously perform hot pressing process during the heating process to the plastic substrate. In addition, the device has the function of real-time monitoring of local temperatures and real-time monitoring of local curvatures forming state, which can be feedback to local heaters and local pressing mechanisms for real-time adjustments of the temperatures and curvatures of different parts of the plastic substrate being processed. The monitoring of temperatures and curvatures can be divided into multiple stages, and the monitoring and adjustment of heating or curvature shaping can be performed stage by stage. Such that, the production yield rate of hot pressing a flat plastic substrate with a hard coating layer, an optical function layer and a printing layer into a curved plastic panel can be improved, while the thermoforming processing of full-curved or partially-curved plastic panels can also be accomplished.
The third objective of the invention is to provide a material composition of the hard coating layer and the optical function layer of the curved plastic panel suitable for the processing method of the present invention. Through the polymer material formulation, coating formulation design and precision coating technology, the ductility properties of polymer surfaces of the plastic substrate having the hard coating layer and the optical function layer can be improved to the level suitable for hot bending, while the original optical and physical properties of the plastic substrate can also be maintained after passing various weather resistance tests.
In order to achieve the aforementioned objectives, the present invention provides a processing method of a curved plastic panel. The processing method comprises the steps of: providing a flat plastic substrate; forming a flat hard coating layer on at least one surface of the flat plastic substrate; forming a flat optical functional layer on the hard coating layer of the flat plastic substrate; forming a flat printing layer on at least one surface of the flat plastic substrate; cutting the flat plastic substrate into a predetermined shape by a cutting machine; and using a hot pressing and curving device to perform a hot pressing and curving processing on the flat plastic substrate having the hard coating layer, the optical function layer and the printing layer formed with the predetermined shape, in order to obtain a curved plastic substrate having the hard coating layer, the optical function layer and the printing layer with the predetermined shape.
Wherein, the hot pressing and curving device comprises: an upper die with variable curvature, a lower die with variable curvature, a plurality of upper heaters, a plurality of upper temperature sensors, a plurality of lower heaters, and a plurality of lower temperature sensors; the plurality of the upper heaters and the plurality of the upper temperature sensors are distributed in each area of the upper die; the plurality of the lower heaters and the plurality of the lower temperature sensors are distributed in each area of the lower die; the upper die and the lower die are matched correspondingly, and curvatures of the upper die and the lower die can be adjusted at least locally; the hot pressing and curving device is used to process the hot pressing and curving process of the flat plastic substrate in the following steps:
adjusting the curvatures of the upper die and the lower die to be flat, and sandwiching the flat plastic substrate between the upper die and the lower die, and using the plurality of the upper heaters and the plurality of the lower heaters to heat the flat plastic substrate to a predetermined temperature, and using the plurality of the upper temperature sensors and the plurality of the lower temperature sensors to sense and monitor the temperature of each area of the flat plastic substrate in order to maintain the temperature of each area of the flat plastic substrate at the predetermined temperature;
adjusting the curvatures of the upper die and the lower die to a first curvature, such that the flat plastic substrate sandwiched between the upper die and the lower die is processed by the upper die and the lower die into the curved plastic substrate with the first curvature; in the meantime, the plurality of the upper temperature sensors and the plurality of the lower temperature sensors continue to sense and monitor that the temperature of each area of the curved plastic substrate with the first curvature is maintained at the predetermined temperature; and
adjusting the curvatures of the upper die and the lower die to a second curvature, such that the curved plastic substrate sandwiched between the upper die and the lower die is processed by the upper die and the lower die into the curved plastic substrate with the second curvature; in the meantime, the plurality of the upper temperature sensors and the plurality of the lower temperature sensors continue to sense and monitor that the temperature of each area of the curved plastic substrate with the second curvature is maintained at the predetermined temperature; wherein the second curvature is larger than the first curvature.
In a preferred embodiment, the hot pressing and curving device further comprises a plurality of cameras for capturing curvature images of the upper die and the lower die, in order to determine whether the curvature of the curved plastic substrate has reached a predetermined curvature.
In a preferred embodiment, the upper die at least includes a first upper template, a second upper template and a third upper template; a first upper joint is connected between the first upper template and the second upper template, so that the first upper template can perform a first curvature adjustment movement relative to the second upper template by means of the first upper joint; a second upper joint is connected between the second upper template and the third upper template, so that the third upper template can perform a second curvature adjustment movement relative to the second upper template by means of the second upper joint;
the lower die at least includes a first lower template, a second lower template and a third lower template; a first lower joint is connected between the first lower template and the second lower template, so that the first lower template can perform a third curvature adjustment movement relative to the second lower template by means of the first lower joint; a second lower joint is connected between the second lower template and the third lower template, so that the third lower template can perform a fourth curvature adjustment movement relative to the second lower template by means of the second lower joint;
wherein, the shape and position of the first upper template are corresponding to the first lower template, the shape and position of the second upper template are corresponding to the second lower template, the shape and position of the third upper template are corresponding to the third lower template.
In a preferred embodiment, the plurality of the upper heaters and the plurality of the upper temperature sensors are provided in the first upper template, the second upper template and the third upper template; the plurality of the lower heaters and the plurality of the lower temperature sensors are provided in the first lower template, the second lower template and the third lower template; the first upper joint, the second upper joint, the first lower joint and the second lower joint each includes a linear sliding rail respectively; the curvature between two adjacent said templates is adjusted by a torque driven by the linear sliding rails.
In a preferred embodiment, wherein: a material composition of the flat plastic substrate is one of the following: polymethyl methacrylate (PMMA) plate, Polycarbonate (PC) plate, PMMA/PC double-layer composite plate, or PMMA/PC/PMMA three-layer composite plate; a material composition of the hard coating layer comprises at least one of the following: organic-inorganic hybrid ultraviolet (UV) oligomers/monomers, inorganic particle materials, or UV-curable long-chain oligomers/monomers with high elongation properties (elongation ratio>200%); wherein the organic-inorganic hybrid ultraviolet oligomers/monomers include one of the following: UV-curable elastic oligomer with a high glass transition temperature (Tg), or high Tg monomer; wherein the Tg of the UV-curable elastic oligomer is Tg≥120° C.; wherein the Tg of the high Tg monomer is Tg≥240° C.; the optical function layer is composed of at least one of the following: UV-curable oligomers/monomers with high refractive index (RI), inorganic materials with high RI, UV-curable oligomers/monomers with low RI, or inorganic materials with low RI; wherein, the inorganic materials with high RI contain one of the following: titanium dioxide (TiO2) or niobium pentoxide (Nb2O5); the inorganic materials with low RI contain one of the following: silicon dioxide (SiO2) or magnesium fluoride (MgF2); the RI value range of the high refractive index UV-curable oligomers/monomers is: RI=1.55˜1.75; the RI value range of the low refractive index UV-curable oligomers/monomers is: RI=1.4˜1.48; the RI value range of the high RI inorganic material is: RI=1.8˜2.5; the RI value range of the low RI inorganic material is: RI=1.2˜1.45.
The present invention provides a method for processing a curved plastic panel, which first forms a hard coating layer, an optical function layer, and a printing layer on a flat plastic substrate, and then uses a CNC machine to cut it into a predetermined shape, and then uses a hot pressing and curving device to perform a hot pressing and curving process to the flat plastic substrate in order to make it becoming a curved plastic substrate having the hard coating layer, optical function layer, and printing layer. The method of the present invention has the advantages of optical function (anti-reflection or anti-glare) and safety and non-breakage in addition to the production of multifunctional polymer material panels for displays with partially or fully curved surfaces. Moreover, since the processing of the hard coating layer, optical function layer, printing layer and CNC cutting are all carried out on the flat plastic substrate, the yield rate is very high, which overcomes various deficiencies of the prior art. The hot pressing and curving device of the invention can simultaneously perform hot pressing process during the heating process to the plastic substrate. In addition, the device has the function of real-time monitoring of local temperatures and real-time monitoring of local curvatures forming state, which can be feedback to local heaters and local pressing mechanisms for real-time adjustments of the temperatures and curvatures of different parts of the plastic substrate being processed. The monitoring of temperatures and curvatures can be divided into multiple stages, and the monitoring and adjustment of heating or curvature shaping can be performed stage by stage. Such that, the production yield rate of hot pressing a flat plastic substrate with a hard coating layer, an optical function layer and a printing layer into a curved plastic panel can be improved, while the thermoforming processing of full-curved or partially-curved plastic panels can also be accomplished. The present invention also provides a material composition of the hard coating layer and the optical function layer of the curved plastic panel suitable for the processing method of the present invention. Through the polymer material formulation, coating formulation design and precision coating technology, the ductility properties of polymer surfaces of the plastic substrate having the hard coating layer and the optical function layer can be improved to the level suitable for hot bending, while the original optical and physical properties of the plastic substrate can also be maintained after passing various weather resistance tests.
In order to more clearly describe the curved plastic panel and method and device for processing the same proposed by the present invention, the following embodiments will be illustrated in detail with the drawings.
The structure of the curved plastic panel described in the present invention is similar to or the same with the typical plastic panel 10 generally suitable for a curved vehicle display as shown in
In the present invention, the material formulation of the hard coating (HC) layer 12 comprises an organic-inorganic hybrid ultraviolet oligomer. Compared with the traditional high cross-link density HC formula, it has a relatively low cross-link density, and can form a wear-resistant hard coating layer 12 with low shrinkage and good flexibility. Wherein, inorganic materials can contribute to the physical properties of the surface, making the coating to have high hardness and high wear resistance.
In addition, the formulation composition of the hard coating layer 12 of the present invention includes a high Tg ultraviolet photo-elastomer oligomer (such as high Tg UV-curable elastic oligomer) and a high Tg monomer, which has better high temperature stability in comparison with traditional high crosslinking density HC formulations. Therefore, it has better thermos-formability during high temperature process, and can bend the UV-cured formable polymer front panel material to a free curvature. The formulation composition of the hard coating layer 12 of the present invention includes UV-curable long-chain oligomers or monomers with high elongation properties (elongation ratio>200%), which has better high extensibility in comparison with traditional high crosslinking density HC formulations. Therefore, it has better thermos-formability during high temperature process, and can bend the UV-cured formable polymer front panel material to a free curvature. The flat plastic panel 10 with the hard coating layer 12 and the optical function layer 13 of the present invention is subjected to flat ink printing and flat surface CNC machining before hot pressing. Then, combining with the hot pressing and curving process of the present invention, it can directly produce curved surface products with optical function after the hot pressing and curving process. For the conventional curved front panel production process, the curved surface hot pressing is performed first, and then the curved surface treatment and curved surface optical processing, curved surface printing, and curved surface CNC cutting processing are performed; due to the difficult processing of curved surfaces, the yield rate of each station is poor, and the reduction in pass-through rate leads to high production costs. In the other hand, the processing method of the present invention has lower processing cost because each processing technology is completed on a plane, and the yield rate and pass-through rate of each station are high. In this embodiment, the RI value range of the high refractive index (RI) UV-curable oligomers/monomers is: RI=1.55˜1.75; the RI value range of the low refractive index (RI) UV-curable oligomers/monomers is: RI=1.4˜1.48; the RI value range of the high RI inorganic material is: RI=1.8˜2.5; the RI value range of the low RI inorganic material is: RI=1.2˜1.45. Anti-reflection is defined as: Reflectance <2%; Anti-glare is defined as: Gloss <100.
Please refer to
Step 31: making a flat plastic substrate (commonly known as a plastic raw board) by plastic extrusion molding; The flat plastic substrate may be a single-layer PC plate, a single-layer PMMA plate, a PMMA/PC double-layer composite plate, or a PMMA/PC/PMMA three-layer composite plate;
Step 32: performing an HC surface treatment on the flat plastic substrate, so as to form a hard coating layer on the upper surface (outer surface) of the flat plastic substrate; because the flat plastic substrate is easy to carry out the HC surface treatment, the yield rate is very high;
Step 33: performing an optical surface treatment on the flat plastic substrate to form an optical function layer on the hard coating layer of the flat plastic substrate; because the flat plastic substrate is easy to carry out the optical surface treatment, the yield rate is very high;
Step 34: performing a printing process on the flat plastic substrate, so as to form a printing layer on the lower surface (inner surface) of the flat plastic substrate; because the flat plastic substrate is easy to carry out the printing process, the yield rate is very high;
Step 35: the flat plastic substrate is cut with a plane computer numerical control (CNC) processing machine (cutting machine) to cut the flat plastic substrate into a flat plastic substrate with a predetermined contour; because the flat plastic substrate is easy to carry out the CNC cutting process, the yield rate is very high;
Step 36: using a hot pressing and curving device to perform a hot pressing and curving process on the flat plastic substrate which has been cut with the predetermined shape and formed with the hard coating layer, the optical function layer and the printing layer, in order to make it a curved plastic substrate having the hard coating layer, the optical function layer and the printing layer and having the predetermined shape; and
Step 37: completing the finished curved plastic panel; since the processing yield rates from steps 32 to 35 are high, the final finished product has high yield rate and precision, and can pass subsequent product testing.
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In this embodiment, the door 52 is installed on the machine body 51. When the door 52 is opened (as shown in
The plurality of cameras 55 constitute the curvature sensors, which can capture (photograph) the curvature (appearance) images of the upper and lower dies 42 and 43 in real time during the hot pressing and curving process. By analyzing the curvature (appearance) images of the upper and lower dies 42 and 43, the curving state of the plastic substrate 41 sandwiched between the upper and lower dies 42 and 43 at that time, that is, the curvature state, can be obtained; and then, it can be determined immediately that whether the curvature of the curved plastic substrate 41 has reached the predetermined curvature or not.
The heating module 61 is electrically connected to the upper heaters 421 and lower heaters 431 for controlling the heating operation of the upper heaters 421 and the lower heaters 431. The detecting module further includes a temperature sensing module 62 and an image capturing module 64. The temperature sensing module 62 is electrically connected to a plurality of the upper temperature sensors 422 and a plurality of the lower temperature sensors 432 for obtaining sensed temperature information from the upper temperature sensors 422 and the lower temperature sensors 432. The image capturing module 64 is electrically connected to the plurality of cameras 55 for capturing/receiving the curvature (appearance) images of the upper die 42 and the lower die 43 captured by the plurality of cameras 55. The database 65 stores the computer software and related parameters required to control the operation of the hot pressing and curving device 50, and also includes the data of the predetermined temperature, the first curvature, the second curvature and the predetermined curvature.
The analysis module 66 can receive the temperature information and the curvature images from the detecting module, and can retrieve the data of the predetermined temperature and the first, second and predetermined curvatures from the database 65. The analysis module 66 can compare the temperature information with the predetermined temperature; when the temperature of the temperature information is lower than the predetermined temperature, the analysis module 66 generates a heating signal to the heating module 61 to actuate the heating module 61 to control a plurality of the upper heaters 421 and a plurality of the lower heaters 431 to heat the plastic substrate 41. The heating operations described here may be global or localized heating. In other words, according to the heating signal from the analysis module 66, the heating module 61 can not only control all the heaters to heat the plastic substrate 41 comprehensively, on the other hand, the heating module 61 can of course only controls some of the heaters to locally heat the plastic substrate 41 according to the heating signal from the analysis module 66, such feature is uniquely created by the present invention and cannot be achieved by conventional technologies. Besides, the analysis module 66 can also compare the curvature images with the predetermined curvature; when the curvature of the curvature image is smaller than the predetermined curvature, the analysis module 66 generates a curvature increase signal to the driving device 63, so that the driving device 63 drives the hydraulic devices 53 and 54 to drive the upper die 42 and the lower die 43 to perform a hot pressing operation that can increase the bending curvature globally or locally. The user interface 69 can allow the user to operate the hot pressing and curving device 50 and also allow the user to input or set-up various information such as the predetermined temperature and the predetermined curvature in the database 65. In this embodiment, the user interface 69 includes a transmission port for connecting with an external computer device. The user can transmit the predetermined temperature, the predetermined curvature and other processing parameters through the user interface 69 and store them in the database 65 by operating the computer device. In another embodiment, the user interface 69 may also include a touch screen and/or a keyboard. The user can set-up the predetermined temperature, the predetermined curvature and other processing parameters in the database 65 by operating the touch screen and/or the keyboard. The control module 67 includes a micro-controller unit (MCU) or a central processing unit (CPU), which is electrically connected to and controls the operations of the driving device 63, the heating module 61, the detecting module, the database 65, the analysis module 66 and the user interface 69. The power module 68 is connected to the control module 67 for providing power to the control unit 60.
Please refer to
This technology uses PMMA/PC/PMMA or PMMA/PC composite material as the base material, and uses the wet coating process of the extensible coating formulation to produce the extensible composite material front panel. The hot pressing and curving process is performed only after all surface treatments are completed, and moreover, all surface treatments will not endure any appearance and functional abnormalities at this stage of the hot pressing and curving process. The key to the breakthrough of this process lies in the matching of extensible coating formulations. Extensible coating formulations include: extensible high hardness coating, extensible high refractive index coating, and extensible low refractive index coating. The formula of extensible coating can change the process that the glass used in the old conventional technology must be hot-pressed to form the curved surface first and then subjected to optical surface treatments next, which greatly reduces the defect rate of the curved surface coating process. The surface hardness of the front plastic panel with the extensible composite material after hot pressing and curving process can be increased to more than 4H (4H˜9H); the chemical wear resistance test can pass the vehicle standard level; UV yellowing resistance test (1000 hours) can maintain the specification of ΔE<3.
The Applicant tested a variety of plastic substrates with different structures with different hard coating and optical function layers composed of different materials. The following Table 1 shows the structural information of each sample tested. For example, the substrate of Sample 6 in Table 1 selects A3/A4 structure in column A, that is, either “PMMA/PC double-layer plate structure” or “PMMA/PC/PMMA three-layer plate structure” is selected. In column B for Sample 6, whether there is “Inorganic hybrid composition” (organic-inorganic hybrid oligomer/monomer) added to the hard coating layer is to choose B2, that is, Sample 6 is added “with” Inorganic hybrid composition. In column C for Sample 6, whether there is added “High Tg composition” (high glass transition temperature oligomer/monomer) in the hard coating layer is to choose C2, that is, Sample 6 is added “with” High Tg composition. In column D for Sample 6, whether there is “High Elongation Composition” (high elongation oligomer/monomer) added to the hard coating layer is to choose D2, that is, Sample 6 is added “with” High Elongation Composition (oligomer/monomer). In column E for Sample 6, whether to add “Optical Function Composition” (optical function component) to its optical function layer is to choose E2, that is, Sample 6 is added “with” Optical Function Composition. In column F for Sample 6, whether the “new mold and hot pressing and curving process” of the present invention being applied is to select F2, that is, Sample 6 is applied “with” the new mold and hot pressing and curving process of the present invention. The structure of other samples (Samples 0˜5, and 7˜9) can be learned in the same way, so it is not repeated here.
It can be seen from Table 1 that, the curved plastic panel of Sample 6 has OK hardness, heat resistance, and molding, and has optical functions, which is a relatively optimal curved plastic panel sample. Relatively, other samples 0˜5, 8, and 9 are more or less including some deficiencies.
In this embodiment, the material compositions described in each column A to E can be selected from currently commercially available commodities. For example, the “Inorganic hybrid composition” described in the column B can be selected from Allenx EBECRYL 8311 or other products of the same type or brand. The “High Tg composition” described in column C can be selected from Allenx EBECRYL 4859 or similar products of other models or brands. The “High Elongation Composition” described in column D can be selected from Allenx EBECRYL 8804 or similar products of other models or brands. The “Optical Function Composition” described in column E can be selected from Nippon Shokubai ZIRCOSTAR series products or products of the same nature of other models or brands.
It can be seen from the testing results of the samples of curved plastic panel listed in the Table 2 that, because Sample 6 uses PC/PMMA or PMMA/PC/PMMA composite plate as the plastic substrate, and is provided with the hard coating layer containing organic-inorganic hybrid oligomer/monomer with high Tg and high elongation properties and the optical function layer, and is processed by using the new mold and hot pressing and curving process of the present invention; that is, Sample 6 is similar to the embodiment shown in
While the present invention has been particularly shown and described with reference to a preferred embodiment, it will be understood by those skilled in the art that various changes in form and detail may be without departing from the spirit and scope of the present invention.
Number | Date | Country | Kind |
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110142418 | Nov 2021 | TW | national |