Patent Grant
7350601
This invention generally relates to cutting elements formed from ultra hard materials and, more specifically, to polycrystalline diamond cutting elements having one or more layers that are specially engineered to provide an enhanced degree of cutting and/or thermal performance when compared to conventional polycrystalline diamond cutting elements, thereby providing an improved degree of service life in desired cutting and/or drilling applications.
Cutting or wear elements formed from ultra hard materials such as polycrystalline diamond (PCD) used in applications such as with drill bits used for subterranean drilling are well known in the art. Such known cutting elements comprise PCD that is formed by combining synthetic diamond grains with a suitable solvent catalyst material to form a mixture. The mixture is subjected to processing conditions of extremely high pressure/high temperature (HPHT), where the solvent catalyst material promotes desired intercrystalline diamond-to-diamond bonding between the grains, thereby forming a PCD structure. The resulting PCD structure has enhanced properties of wear resistance and hardness, making PCD materials extremely useful in aggressive wear and cutting applications where high levels of wear resistance and hardness are desired.
Such cutting elements typically include a metallic substrate material that is joined to a layer or body of the PCD material during the same HPHT process that is used to form the PCD body. The metallic substrate facilitates attachment of the PCD cutting element to the cutting or drilling device being used, e.g., a drill bit used for subterranean drilling, by conventional attachment method such as welding and the like.
Techniques have been used to improve the wear resistance of the surface of the PCD material, i.e., the surface placed into cutting engagement, for the purpose of extending the service life of the cutting element. PCD is known to suffer thermal degradation at a temperature starting at about 400° C. and extending to 1200° C. and, thus conventional PCD cutting elements are known to have poor thermal stability when exposed to operating temperatures approaching 700° C. Therefore, some of the techniques used for improving the wear resistance of PCD have focused at improving the thermal stability of the PCD. One such approach has involved acid leaching an uppermost layer of an otherwise conventional PCD body to remove substantially all of the solvent metal catalyst material therefrom, while leaving the solvent metal catalyst in the remaining portion of the PCD body.
While this technique is known to improve the thermal stability of the treated uppermost layer, PCD cutters that have been treated in this manner are known to suffer from delamination and spalling during use, leading to premature failure of the cutting element and the drilling device including the same.
It is, therefore, desired that a PCD cutting element be developed that provides improved properties of wear resistance and thermal stability when compared to conventional PCD cutting elements in a manner that reduces or minimizes unwanted delamination and/or spalling, thereby providing improved cutting element service life. It is further desired that such PCD cutting element be constructed using available materials and methods.
Cutting elements of this invention formed from ultra hard materials generally include an ultra hard body that is joined together with a metallic substrate. In an example embodiment, the ultra hard body is a diamond body that includes an uppermost layer comprising a plurality of bonded diamond crystals and a plurality of interstitial regions disposed among the crystals. The uppermost layer includes an outer surface that is a working surface of the body. In one invention embodiment, the outer region extends from at least a portion of the outer surface to a depth within the uppermost layer, and is substantially free of a catalyst material. In this invention embodiment, the uppermost layer also includes a remaining region that includes the catalyst material. In another invention embodiment, the uppermost layer outer region includes the catalyst material as does the remaining region of the uppermost later.
The diamond body further includes an intermediate layer that is joined to the uppermost layer and that comprises a plurality of bonded diamond crystals. The intermediate layer is specifically designed to have a wear resistance that is less than that of the uppermost layer remaining region to provide for the preferential wear of the intermediate layer relative to the uppermost layer, and to eliminate or resist any cracking during use. Such differential wear resistance can be achieved by using differently sized diamond grains to form the uppermost and intermediate layers and/or by using different diamond grain content.
The diamond body may additionally include lowermost layer that is interposed between and attached to the intermediate layer and the substrate. The lowermost layer is optional and is useful in those constructions where a further polycrystalline diamond layer is needed to provide a strong bond between the diamond body and the metallic substrate. In an example embodiment, the lowermost layer is formed from diamond grains having an average particle size greater than the average particle size of the diamond grains used to form the intermediate layer. In another example embodiment, the lowermost layer has a diamond content that is greater than that of the intermediate layer.
Cutting elements constructed in accordance with the principles of this invention, when formed from PCD, provide improved properties of wear resistance and thermal stability when compared to conventional PCD cutting elements in a manner that reduces or minimizes unwanted delamination and/or spalling, thereby providing improved cutting element service life.
These and other features and advantages of the present invention will be appreciated as the same becomes better understood by reference to the following detailed description when considered in connection with the accompanying drawings wherein:
Cutting elements, constructed in accordance with the principles of this invention, are specially engineered having improved characteristics designed to enhance cutting and drilling performance of a drill bit when compared to cutting elements formed from conventional ultra hard materials such as PCD. Cutting elements of this invention generally comprise an ultra hard material body having a multi-layer construction including an uppermost layer and an underlying intermediate layer interposed between the uppermost layer and a metallic substrate.
The uppermost layer is formed from an ultra hard material selected from PCD, PcBN, and mixtures thereof, wherein the ultra hard material is made from coarse-grade or coarse-sized grains, and includes an outer surface region. In one invention embodiment, the outer surface region has been treated to render it relatively more thermally stable than a remaining or untreated region of the uppermost layer. In another invention embodiment, the outer surface region is formed from an untreated ultra hard material. The intermediate layer is formed from a material that is relatively less wear resistant than the uppermost layer to both facilitate preferential wear or erosion of the intermediate layer when the cutter is placed into a drilling operation to keep a cutting edge of the uppermost layer sharp, and to provided a related reduced contact area beneath the uppermost layer, which operates to reduce unwanted friction and the transfer of related friction generated thermal energy into the cutting element.
Cutting elements of this invention may include a further ultra hard material layer, interposed between the intermediate layer and the substrate, if needed to provide a desired bond with the metallic substrate and/or to provide an enhanced degree of toughness for eliminating or reducing the severity of any cracking in that layer.
It is to be understood that the working or cutting surface of the shear cutter can extend from an upper surface of the ultra hard material body to a beveled surface of the body that defines a circumferential edge of the upper surface. Additionally, if desired, the wear resistant and thermally stable region of the body can extend from the beveled or other working surface a distance axially along a side surface of the body to provide an enhanced degree of thermal stability and thermal resistance to the cutter. It is to be understood that cutting elements of this invention can be embodied as shear cutters having geometries other than that specifically described above and illustrated in
In this example embodiment, the uppermost layer 32 includes an outer region 34 that includes an outer surface 35 that defines a working or cutting surface of the cutting element. The outer region 34 is treated to a predetermined depth extending below the outer surface to render it relatively more thermally stable than a remaining region 36 of the uppermost layer 32.
Coarse-sized diamond grains are used to form the uppermost layer for the purpose of inhibiting any unwanted loss of the thermally stable outer region 34 through spalling and delamination along the boundary between the thermally stable outer region 34 and the remaining region 36 of the uppermost layer. In an example embodiment, the uppermost layer 32 is formed by using synthetic or natural diamond grains having an average particle size in the range of from about 10 to 80 micrometers, preferably greater than about 20 micrometers in size, and more preferably within the range of from about 20 to 40 micrometers in size. It is to be understood that the diamond grain sizes noted above are intended to be representative of an average grain size of the diamond grains that are used. Additionally, the diamond grains used to form the uppermost layer may be of a single size, i.e., have a mono-modal size distribution, or may be a mixture of two or more different diamond grains sizes, i.e., have a multi-modal size distribution.
It is to be understood that the exact size of the diamond grains and/or the exact distribution of differently sized diamond grains used to form the uppermost layer 32 will vary depending on the particular use application. Additionally, the diamond grain particle size and particle size distribution may also vary based on the type of treatment that is used to render the uppermost layer outer region 34 thermally stable. For example, if the treatment used is acid leaching, to remove substantially all of the matrix material, e.g., solvent metal catalyst, then the diamond size and/or particular size distribution can be specifically tailored to facilitate leaching to achieve a desired depletion depth.
Because it is desired that the uppermost layer outer region be relatively more thermally stable than the remaining layers or portions of the PCD body 28, it is desired that the diamond grain material used to form the uppermost layer have a controlled amount of matrix material, or material other than diamond, present during the process of sintering and consolidation. An example of such matrix materials include those conventionally used to form PCD, such as the solvent metal catalyst materials included in Group VIII of the Periodic table, with cobalt (Co) being the most common.
Conventional PCD materials, comprising sintered diamond grains and such solvent metal catalyst material, are known to suffer from certain unwanted thermal related events as the operating temperature in the PCD material increases. For example, differential expansion is known to occur at temperatures of about 400° C. between the diamond phase in the PCD and the solvent metal catalyst disposed within interstitial regions between the bonded together diamonds. Such differential thermal expansion can cause ruptures to occur in the diamond-to-diamond bonding, and eventually result in the formation of cracks and chips in the PCD structure, rendering the PCD structure unsuited for further use. As the temperature approaches 700° C., the solvent metal catalyst within the PCD material is known to cause an undesired catalyzed phase transformation in diamond (converting it to carbon monoxide, carbon dioxide, or graphite), thereby limiting practical use of the PCD material to about 750° C.
Accordingly, for the purpose of controlling the occurrence of such undesired thermal effects at or adjacent the working or cutting surface, it is desired that the uppermost layer 32 be formed from diamond grains having no greater than about 5 percent by weight solvent metal catalyst, and preferably having less than about 2 percent by weight solvent metal catalyst. Thus, in an example embodiment, the uppermost layer 32 has a diamond volume fraction greater than about 95 percent.
In an effort to obtain better control over the presence of solvent metal catalyst in the uppermost layer, the use of natural diamond may be desired. Unlike synthetic diamond, natural diamond does not include solvent catalyst metal material in its crystals. Since natural diamond does not include diamond crystals having such solvent catalyst materials trapped within the diamond crystals, the use of natural diamond allows the post-pressing removal of a greater percentage of the solvent catalyst material that is used to facilitate intercrystalline diamond bonding for the purpose of forming a thermally stable outer region 34. Alternatively, the uppermost layer may comprise a blend of synthetic diamond and natural diamond, or segregated layers of natural diamond and synthetic diamond. For example, the uppermost layer can be formed by using natural diamond grains in that region that will later become the outer region 34, and synthetic diamond grains can be used to form the remaining region of the uppermost layer.
The thickness of the PCD body uppermost layer 32 will vary on a number of factors such as the diamond grain particle size and/or distribution, the diamond volume fraction, the matrix material, and the particular PCD cutting element use application. In an example embodiment, where the PCD cutting element is a shear cutter used for subterranean drilling, the uppermost layer may have a thickness of generally less than about two millimeters, and preferably within the range of from about 0.25 to 1 millimeters.
The uppermost layer outer region 34 is treated for the purpose of rendering it relatively more thermally stable than the remaining region 36 of the uppermost layer. The technique used for rending the outer region 34 thermally stable can be any one that operates to minimize or eliminate the unwanted thermal impact that the matrix material, e.g., the solvent metal catalyst, has on the PCD material. This can be done, for example, by removing substantially all of the solvent metal catalyst material from the selected region by suitable process, e.g., by acid leaching, aqua regia bath, electrolytic process, or combinations thereof.
Alternatively, rather than actually removing the solvent metal catalyst from the PCD body, the outer region 34 can be rendered thermally stable by treating the solvent metal catalyst in a manner that reduces or eliminates its potential to adversely impact the intercrystalline bonded diamond at elevated temperatures. For example, the solvent metal catalyst can be combined chemically with another material to cause it to no longer act as a catalyst material, or can be transformed into another material that again causes it to no longer act as a catalyst material. Accordingly, as used herein, the terms “removing substantially all” or “substantially free” as used in reference to the solvent metal catalyst is intended to cover the different techniques in treating the solvent metal catalyst to ensure that it no longer adversely impacts the intercrystalline diamond in the uppermost PCD layer with increasing temperature.
In an example embodiment, the outer region is rendered thermally stable by having substantially all of the catalyst solvent material removed therefrom by an appropriate treatment. The thermally stable outer region extends a predetermined depth beneath the outer surface 35. The thermally stable outer region 34 can extend from the outer surface 35 to a depth of up to about 0.09 mm in one example embodiment, from about 0.02 mm to 0.09 mm in another example embodiment, and from about 0.04 mm to about 0.08 mm in a further example embodiment. It is to be understood that the depth of the outer region 34 will vary depending on factors such as the diamond volume fraction, the diamond particle size, the end use application or the like.
In an example embodiment, substantially all of the catalyst material is removed from the uppermost layer outer region 34 by exposing the desired outer surface 35 or surfaces to acid leaching, as disclosed for example in U.S. Pat. No. 4,224,380, which is incorporated herein by reference. Generally, after the PCD cutting element is made by HPHT process, the identified surface or surfaces to be treated, e.g., the outer surface 35 of the uppermost layer outer region 34, are placed into contact with the acid leaching agent for a sufficient period of time to produce the desired leaching or catalyst material depletion depth. In an example embodiment, this is done after the cutting element has been machine finished to an approximate final dimension. The PCD cutting element is prepared for treatment by protecting the substrate surface and other portions of the PCD body 28 adjacent the desired treated region from contact (liquid or vapor) with the leaching agent. Methods for protecting the remaining surface of the substrate and/or PCD body include covering, coating or encapsulating the substrate and/or PCD body surface with a suitable barrier member or material such as wax, plastic or the like.
Suitable leaching agents for treating the selected region to be rendered thermally stable include materials selected from the group consisting of inorganic acids, organic acids, mixtures and derivatives thereof. The particular leaching agent that is selected can depend on such factors as the type of catalyst material used, and the type of other non-diamond metallic materials that may be present in the uppermost PCD layer. In an example embodiment, suitable leaching agents include hydrofluoric acid (HF), hydrochloric acid (HCl), nitric acid (HNO3), and mixtures thereof. The leaching agent may be heated to achieve a desired leaching performance.
Although not illustrated in
Additionally, while the thermally stable outer region has been described and illustrated as projecting a depth along the entire outside surface 35, it is to be understood that there may be applications where thermally stability along the entire outside surface is not desired or not necessary. It is, therefore, to be understood that the outer region can be constructed to occupy either the entire region along the uppermost layer outside surface, or a partial region depending on the particular application.
While a particular example embodiment of the invention has been described and illustrated as having an uppermost layer outer region that is treated for rendering it relatively more thermally stable that the remaining region of the uppermost layer, embodiments of this invention can alternatively be constructed comprising an uppermost layer outer region that has not been treated, e.g., when formed from PCD such outer region is not substantially free of the catalyst material. In such alternative embodiment, the uppermost layer may include an outer region and remaining region that are each formed from the same or different ultra hard material, depending on the particular use application. For example, the outer region and remaining region of the uppermost layer each can be formed from PCD of the same type noted above for forming the uppermost layer. Alternatively, when the uppermost layer is formed from PCD or other type of ultra hard material, it can be constructed to comprise the same grain size and volume fraction of ultra hard material throughout, or can be constructed to have different regions each comprising a different grain size and/or volume fraction of the ultra hard material, again depending on the particular end use application and related desired properties of the uppermost layer.
Alternatively, for certain use applications such as those calling for a high degree of wear resistance and/or thermal stability, it is understood that the entire portion of the uppermost can be treated to render it thermally stable, i.e., can be treated so that it is substantially free of the catalyst material.
Referring back to
The intermediate layer can be formed from the same types of ultra hard materials described above for forming the uppermost layer. Such preferential wearing of the intermediate layer relative to the uppermost layer can be achieved in a number of ways. In one embodiment, such preferential wearing can be achieved by forming the intermediate layer from an ultra hard material such as PCD material having a relatively larger amount of matrix material, e.g., solvent metal catalyst or other material, than that present in the uppermost layer to thereby dilute the diamond content within the intermediate layer. Using this approach, the diamond volume fraction in the intermediate layer can be diluted by using an amount of solvent metal catalyst in excess of that noted above for the uppermost layer, i.e., by using greater than about 5 percent by weight solvent metal catalyst. Alternatively, or in addition to using the solvent metal catalyst, other materials can be used as the matrix material to lower the diamond volume fraction in the intermediate layer to reduce its wear resistance. Such other materials useful in this capacity include cubic boron nitride (cBN), cermet materials, ceramic material, and materials that generally include a hard grain phase and a ductile binder phase, wherein the hard grains can be selected from the group W, Ti, Mo, Nb, V, Hf, Ta, and Cr carbides, and the ductile binder phase can be selected from the group consisting of steel, Co, Ni, Fe, W, Mo, Ti, Ta, V, Nb, C, B, Cr, Mn, and alloys thereof.
Such preferential wearing of the intermediate layer relative to the uppermost layer can also be achieved by forming the intermediate layer from an ultra hard material having grains sized differently from that used to form the uppermost later. For example, when the intermediate layer is formed from a PCD material, by using diamond grains that are sized differently from that used to form the uppermost layer. Like the uppermost PCD layer 32, the intermediate layer can be formed from a mono-modal or multi-modal distribution of differently sized ultra hard material grains, e.g., diamond grains. For example, a PCD material formed from fine-sized diamond grains can provide an intermediate layer having a desired reduction in wear resistance relative to the uppermost layer. In an example embodiment, a desired reduction in wear resistance can be achieved by using diamond grains that have an average particle size of less than about 20 micrometers, with 10 percent by weight or more of the matrix material, e.g., having a diamond composition or content of 90 percent by weight or less.
Additionally, forming the intermediate layer from a PCD material using coarse-sized diamond grains can also provide a desired reduction in wear resistance relative to the uppermost layer. In an example embodiment, coarse-sized diamond grains having an average particle size of greater than about 40 micrometers can be used, preferably having an average particle size within the range of from about 40 to 100 micrometers, with or without a matrix material or second phase.
The choice of diamond grain size selected will also impact the ability of the intermediate PCD layer to form a desired bond with an adjacent PCD layer or the substrate during HPHT processing. For example, if diamond grains having a fine particle size are used for forming the intermediate layer, it may be necessary to use a further intervening PCD layer to join the intermediate layer to the substrate. If diamond grains having a relatively coarse particle size are used for forming the intermediate layer, a bond of sufficient strength may be formed between the intermediate layer and the substrate so as to avoid the need to use a further intervening PCD layer.
In the first embodiment PCD cutter element illustrated in
The thickness of the intermediate layer 38 can and will vary on a number of factors such as the diamond grain particle size and/or distribution, the diamond volume fraction, the type of matrix material that is used, whether or not the PCD body includes a further intervening PCD layer between the intermediate layer and the substrate, and the cutting element use application. In an example first embodiment illustrated in
Referring still to
The lowermost layer 40 can be formed form the same types of ultra hard materials discussed above for forming the uppermost and intermediate layers. In an example embodiment, the lowermost layer 40 is a PCD material that is formed by using diamond grains having an average particle size of 20 micrometers or greater for the purpose of providing a desired interface with the substrate to promote formation of a strong bond therebetween during HPHT processing. The diamond grains may include a matrix material content of about 2 percent by weight or greater. In such example embodiment, the matrix material is a solvent metal catalyst such as cobalt.
The thickness of the lowermost layer 40 can and will vary on a number of factors such as the ultra hard material grain particle size and/or distribution, the ultra hard material volume fraction, the type of matrix material, and the cutting element use application. In the first embodiment illustrated in
Although present in the construction of the first embodiment ultra hard material cutting element comprising PCD illustrated in
In this second embodiment, the use of a lowermost layer is avoided by the selective choice of materials used to form the intermediate layer 38. Specifically, in this particular embodiment, the intermediate layer is a PCD material that is formed from diamond grains having a sufficient particle size to provide a desired bond strength between the intermediate layer and the substrate, thereby permitting joining the PCD construction to the substrate without using a further intervening PCD layer. Additionally, the material selected for forming the intermediate layer is chosen to provide a degree of wear resistance that is less than that of the uppermost layer 32 to provide the desired level of preferential wearing for the same reasons noted above with respect to the first invention embodiment.
In an example second embodiment, the intermediate layer is formed using diamond grains that have an average particle size of 20 micrometers or greater, and that has a matrix material content of 2 percent by weight or greater. The matrix material used in this embodiment can be any one of the material materials noted above useful for forming the intermediate layer of the first invention embodiment, and in a preferred embodiment is cobalt.
The thickness of the intermediate layer 38 used in the second embodiment can and will vary on a number of factors such as the diamond grain particle size and/or distribution, the diamond volume fraction, the type of matrix material, and the cutting element use application. In the second embodiment illustrated in
Referring to
While cutter element embodiments of this invention have been disclosed and illustrated as being generally cylindrical in shape and having a planar disk-shaped outer surface, it is understood that these are but a few example embodiments and that cutter elements of this invention can be configured other than as specifically disclosed or illustrated. It is further to be understood that cutting elements of this invention may be configured having working or cutting surfaces disposed along the disk-shaped outer surface and/or along outer side surfaces of the ultra hard body, depending on the particular cutting or wear application.
Alternatively, the cutting element may be configured having an altogether different shape but generally comprising a substrate and an ultra hard body bonded to the substrate, wherein the ultra hard body is provided with working or cutting surfaces oriented as necessary to perform working or cutting service when the ultra hard cutting element is mounted to a desired drilling or cutting device, e.g., a drill bit.
For example, cutting elements of this invention can be configured having the ultra hard body (comprising the uppermost layer, intermediate layer, and if needed a lowermost layer) disposed onto an interface surface of an underlying substrate that is provided at an angle relative to an axis running through the substrate. Configured in this manner, the cutting element includes a generally disk-shaped outer surface, that is the working or cutting surface of the cutting element, and that is positioned at an angle relative to the axis running through the substrate.
In another example, cutting elements of this invention can be configured with an ultra hard body attached to a substrate, wherein the ultra hard construction includes a dome-shaped or convex outside surface forming the working or cutting surface of the cutting element.
Further, while cutting elements of this invention have been described and illustrated as comprising an ultra hard body attached to a generally planar interface surface of an underlying substrate, it is to be understood that ultra hard bodies of this invention can be joined with substrates having interface surfaces that are not uniformly planar, e.g., that can be canted or otherwise non-axially symmetric. Thus, cutting elements of this invention can be configured having ultra hard body-substrate interfaces that are uniformly planar or that are not uniformly planar in a manner that is symmetric or nonsymmetric relative to an axis running through the substrate.
Cutting elements of this invention are formed by HPHT processes. Specifically, for PCD cutting elements, the diamond grain powder and matrix material mixture for each PCD body layer is preferably cleaned, arranged, and loaded into a desired container for placement adjacent a desired substrate. The container and substrate is placed within a suitable HPHT consolidation and sintering device, and the device is then activated to subject the container and the substrate to a desired HPHT condition to consolidate and sinter the different diamond powder mixtures, forming the different layers of the PCD body, and joining the PCD body to the substrate.
Alternatively, the different materials used for making the uppermost layer, intermediate layer, and lowermost layer can each be provided in the form of a green-state part, e.g., in the form of a disc or tape casting, made by the process of combining the respective powder materials with a suitable binding agent to enable shaping the resulting mixture into the shape of a part that can be formed, arranged, and loaded into the desired container for subsequent HPHT processing as disclosed above. Wherein, in the event that the layers forming the PCD body are provided in the form of green-state parts, the process of HPHT processing may be prompted by a preheating step to drive off the binding agent prior to consolidation and sintering.
In an example embodiment, the device is controlled so that the container is subjected to a HPHT process comprising a pressure in the range of from 5 to 7 GPa and a temperature in the range of from about 1320 to 1600° C., for a sufficient period of time. During this HPHT process, the matrix material, e.g., solvent metal catalyst material, in each of the respective diamond grain mixtures melts and infiltrates the respective diamond grain powders to facilitate intercrystalline diamond bonding. During the formation of such intercrystalline diamond bonding, the catalyst material migrates into the interstitial regions of the respective different layers within the PCD body that exists between the diamond-bonded grains.
Once the HPHT process is completed, the so-formed PCD cutting element is removed from the device and is prepared for treatment to render the outer region of the uppermost layer thermally stable as disclosed above. In an example embodiment, the PCD cutting element is finished machined to an approximate final dimension prior to treatment so that the depth of the thermally stable outer region remains substantially constant and does not change from treatment to use of the so-formed element.
Cutting elements of this invention, comprising a PCD body made up of the multiple layers described above, provide properties of improved thermal stability while also providing improved service life when compared to conventional thermally stable PCD cutting elements that may include an leached upper region. PCD cutting elements of this invention, having an uppermost layer formed from coarse-sized diamond grains and that includes a thermally stable outer region, provide an improved degree of thermal stability while at the same time resisting spalling an delamination of the thermally stable region. PCD cutting elements of this invention, having an intermediate layer formed from a diamond mixture providing a degree of wear resistance that is less than that of the uppermost layer, operate to maintain the sharpness of the cutting edge while at the same time minimize unwanted frictional heat generation and related heat transfer into the PCD body. Together, these features operate to provide PCD cutting elements having an improved service life when compared to conventional thermally stable PCD cutting elements having a leached upper region.
Other modifications and variations of cutting elements constructed according to the principles of this invention will be apparent to those skilled in the art. It is, therefore, to be understood that within the scope of the appended claims, this invention may be practiced otherwise than as specifically described.
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| Number | Date | Country | |
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| 20060162969 A1 | Jul 2006 | US |
