Cutting elements including non-planar interfaces, earth-boring tools including such cutting elements, and methods of forming cutting elements

Information

  • Patent Grant
  • 9140072
  • Patent Number
    9,140,072
  • Date Filed
    Thursday, February 28, 2013
    12 years ago
  • Date Issued
    Tuesday, September 22, 2015
    10 years ago
Abstract
Cutting elements for earth-boring tools may comprise a substrate, a polycrystalline table comprising superhard material secured to the substrate at an end of the substrate, and a non-planar interface defined between the polycrystalline table and the substrate. The non-planar interface may comprise a cross-shaped groove extending into one of the substrate and the polycrystalline table and L-shaped grooves extending into the other of the substrate and the polycrystalline table proximate corners of the cross-shaped groove. Transitions between surfaces defining the non-planar interface may be rounded. Methods of forming cutting elements for earth-boring tools may comprise forming a substrate to have a non-planar end. The non-planar end of the substrate may be provided adjacent particles of superhard material to impart an inverse shape to the particles. The particles may be sintered to form a polycrystalline table, with a non-planar interface defined between the substrate and the polycrystalline table.
Description
FIELD

The disclosure relates generally to cutting elements for earth-boring tools. More specifically, disclosed embodiments relate to non-planar interfaces between polycrystalline tables and substrates of cutting elements for earth-boring tools that may manage stress in regions of the polycrystalline table and interrupt crack propagation through the polycrystalline table.


BACKGROUND

Earth-boring tools for forming wellbores in subterranean earth formations may include cutting elements secured to a body. For example, fixed-cutter earth-boring rotary drill bits (also referred to as “drag bits”) include cutting elements that are fixedly attached to a bit body of the drill bit. Roller cone earth-boring rotary drill bits may include cones that are mounted on bearing pins extending from legs of a bit body such that each cone is capable of rotating about the bearing pin on which it is mounted. Cutting elements may extend from each cone of the drill bit.


The cutting elements used in such earth-boring tools often include polycrystalline diamond compact (PDC) cutting elements, also termed “cutters,” which are cutting elements including a polycrystalline diamond (PCD) material, which may be characterized as a superabrasive or superhard material. Such polycrystalline diamond materials are formed by sintering and bonding together relatively small synthetic, natural, or a combination of synthetic and natural diamond grains or crystals, termed “grit,” under conditions of high temperature and high pressure in the presence of a catalyst, such as, for example, cobalt, iron, nickel, or alloys and mixtures thereof, to form a layer of polycrystalline diamond material, also called a diamond table. These processes are often referred to as high temperature/high pressure (HTHP) processes. The polycrystalline diamond material may be secured to a substrate, which may comprise a cermet material, i.e., a ceramic-metallic composite material, such as, for example, cobalt-cemented tungsten carbide. In some instances, the polycrystalline diamond table may be formed on the cutting element, for example, during the HTHP sintering process. In such instances, cobalt or other catalyst material in the cutting element substrate may be swept among the diamond grains or crystals during sintering and serve as a catalyst material for forming a diamond table from the diamond grains or crystals. Powdered catalyst material may also be mixed with the diamond grains or crystals prior to sintering the grains or crystals together in an HTHP process. In other methods, however, the diamond table may be formed separately from the cutting element substrate and subsequently attached thereto.


As the diamond table of the cutting element interacts with the underlying earth formation, for example by shearing or crushing, the diamond table may delaminate, spall, or otherwise fracture because of the high forces acting on the cutting element and resulting high internal stresses within the diamond table of the cutting element. Some cutting elements may include non-planar interfaces, such as, for example, grooves, depressions, indentations, and notches, formed in one of the substrate and the diamond table, with the other of the substrate and the diamond table including corresponding, mating interface features. Illustrative non-planar interface designs are disclosed in, for example, U.S. Pat. No. 6,283,234, issued Sep. 4, 2001, to Torbet, U.S. Pat. No. 6,527,069, issued Mar. 4, 2003, to Meiners et al., U.S. Pat. No. 7,243,745, issued Jul. 17, 2007, to Skeem et al., and U.S. Pat. No. 8,020,642, issued Sep. 20, 2011, to Lancaster et al., the disclosure of each of which is incorporated herein in its entirety by this reference.


BRIEF SUMMARY

In some embodiments, cutting elements for earth-boring tools may comprise a substrate, a polycrystalline table comprising superhard material secured to the substrate at an end of the substrate, and a non-planar interface defined between the polycrystalline table and the substrate. The non-planar interface may comprise a cross-shaped groove extending into one of the substrate and the polycrystalline table and L-shaped grooves extending into the other of the substrate and the polycrystalline table proximate corners of the cross-shaped groove. Transitions between surfaces defining the non-planar interface may be rounded.


In other embodiments, earth-boring tools may comprise a body and cutting elements secured to the body. At least one of the cutting elements may comprise a substrate, a polycrystalline table comprising superhard material secured to the substrate at an end of the substrate, and a non-planar interface defined between the polycrystalline table and the substrate. The non-planar interface may comprise a cross-shaped groove extending into one of the substrate and the polycrystalline table and L-shaped grooves extending into the other of the substrate and the polycrystalline table proximate corners of the cross-shaped groove. Transitions between surfaces defining the non-planar interface may be rounded.


In still other embodiments, methods of forming cutting elements for earth-boring tools may comprise forming a substrate to have a non-planar end. The non-planar end comprises a cross-shaped groove extending into the substrate and L-shaped protrusions extending from a remainder of the substrate proximate corners of the cross-shaped groove. Transitions between surfaces defining the non-planar end are shaped to be rounded. Particles of superhard material are positioned adjacent the non-planar end of the substrate in a container. The particles are sintered in a presence of a catalyst material to form a polycrystalline table secured to the substrate, with a non-planar interface being defined between the substrate and the polycrystalline table.





BRIEF DESCRIPTION OF THE DRAWINGS

While the disclosure concludes with claims particularly pointing out and distinctly claiming embodiments within the scope of the disclosure, various features and advantages of embodiments encompassed by the disclosure may be more readily ascertained from the following description when read in conjunction with the accompanying drawings, in which:



FIG. 1 is a perspective view of an earth-boring tool;



FIG. 2 is a perspective partial cross-sectional view of a cutting element of the earth-boring tool of FIG. 1;



FIG. 3 is a perspective view of a substrate of the cutting element of FIG. 2;



FIG. 4 is an end view of the substrate of the cutting element of FIG. 2;



FIG. 5 is a perspective view of another embodiment of a substrate for a cutting element;



FIG. 6 is an end view of the substrate of FIG. 5;



FIG. 7 is a perspective view of another embodiment of a substrate for a cutting element;



FIG. 8 is an end view of the substrate of FIG. 7;



FIG. 9 is a perspective view of another embodiment of a substrate for a cutting element;



FIG. 10 is an end view of the substrate of FIG. 9;



FIG. 11 is a perspective view of another embodiment of a substrate for a cutting element;



FIG. 12 is an end view of the substrate of FIG. 11;



FIG. 13 is a perspective view of another embodiment of a substrate for a cutting element;



FIG. 14 is an end view of the substrate of FIG. 13;



FIG. 15 is a cross-sectional view of a container in a first stage of a process for forming a cutting element; and



FIG. 16 is a cross-sectional view of the container of FIG. 15 in a second stage of a process for forming a cutting element.





DETAILED DESCRIPTION

The illustrations presented herein are not meant to be actual views of any particular earth-boring tool, cutting element, non-planar interface, component thereof, or act in a method of forming such structures, but are merely idealized representations employed to describe illustrative embodiments. Thus, the drawings are not necessarily to scale.


Disclosed embodiments relate generally to non-planar interfaces between polycrystalline tables and substrates of cutting elements for earth-boring tools that may manage stress in regions of the polycrystalline table and interrupt crack propagation through the polycrystalline table. More specifically, disclosed are embodiments of non-planar interfaces that may strengthen high-stress regions within the polycrystalline table, interrupt crack propagation tending to extend circumferentially around the polycrystalline table, and reduce stress concentrations associated with conventional non-planar interface designs.


As used herein, the term “earth-boring tool” means and includes any type of bit or tool used for removing earth material during the formation or enlargement of a wellbore in a subterranean formation. For example, earth-boring tools include fixed-cutter bits, rolling cone bits, impregnated bits, percussion bits, core bits, eccentric bits, bicenter bits, mills, reamers, drag bits, hybrid bits, and other drilling bits and tools known in the art.


As used herein, the terms “polycrystalline table” and “polycrystalline material” mean and include any structure or material comprising grains (e.g., crystals) of a material (e.g., a superabrasive material) that are bonded directly together by inter-granular bonds. The crystal structures of the individual grains of the material may be randomly oriented in space within the polycrystalline table. For example, polycrystalline tables include polycrystalline diamond compacts (PDCs) characterized by diamond grains that are directly bonded to one another to form a matrix of diamond material with interstitial spaces among the diamond grains.


As used herein, the terms “inter-granular bond” and “interbonded” mean and include any direct atomic bond (e.g., covalent, metallic, etc.) between atoms in adjacent grains of superabrasive material.


As used herein, the term “superhard” means and includes any material having a Knoop hardness value of about 3,000 Kgf/mm2 (29,420 MPa) or more. Superhard materials include, for example, diamond and cubic boron nitride. Superhard materials may also be characterized as “superabrasive” materials.


As used herein, the phrase “substantially completely removed” when used in connection with removal of catalyst material from a polycrystalline material means and includes removal of all catalyst material accessible by known catalyst removal processes. For example, substantially completely removing catalyst material includes leaching catalyst material from all accessible interstitial spaces of a polycrystalline material by immersing the polycrystalline material in a leaching agent (e.g., aqua regia) and permitting the leaching agent to flow through the network of interconnected interstitial spaces until all accessible catalyst material has been removed. Residual catalyst material located in isolated interstitial spaces, which are not connected to the rest of the network of interstitial spaces and are not accessible without damaging or otherwise altering the polycrystalline material, may remain.


As used herein, the term “L-shaped” means and includes any shape defined by two rays extending from an intersection, wherein an angle defined by the rays is between 80° and 100°. For example, L-shapes include right angles, T-squares, perpendicular rays, and other known L-shapes.


Referring to FIG. 1, a perspective view of an earth-boring tool 100 is shown. The earth-boring tool 100 may include a body 102. An upper end 104 of the body 102 may include a connector 106 (e.g., an American Petroleum Institute (API) threaded connection) configured to connect the earth-boring tool 100 to other components of a drill string (e.g., drill pipe). A lower end 108 of the body 102, for example, may be configured to engage with an underlying earth formation. For example, the lower end 108 of the body 102 may include blades 110 extending outward from a remainder of the body 102 and extending radially over the lower end 108 of the body 102. Cutting elements 112 may be secured to the blades 110, such as, for example, by brazing the cutting elements 112 within pockets 114 formed in the blades 110, at rotationally leading faces of the blades 110. The cutting elements 112 and blades 110 may cooperatively define a cutting structure configured to engage with and remove an underlying earth formation.


Referring to FIG. 2, a perspective partial cross-sectional view of a cutting element 112 of the earth-boring tool 100 of FIG. 1 is shown. The cutting element 112 may include a polycrystalline table 116 of a superhard material configured to directly contact and remove earth material. The polycrystalline table 116 may comprise a generally disk-shaped structure formed from individual grains of superhard material that have interbonded to form a polycrystalline matrix of grains with interstitial spaces located among the grains. The superhard material may comprise, for example, diamond or cubic boron nitride.


The polycrystalline table 116 may be positioned on an end of a substrate 118 and secured to the substrate 118. The substrate 118 may comprise a hard material suitable for use in earth-boring applications such as, for example, a ceramic-metallic composite material (i.e., a cermet) (e.g., cemented tungsten carbide), and may be formed in a generally cylindrical shape. The polycrystalline table 116 may be secured to the substrate 118 by, for example, a continuous metal material extending into the polycrystalline table 116 and the substrate 118, such as, for example, matrix material of the substrate 118 that has infiltrated among and extends continuously into the interstitial spaces of the polycrystalline table 116. An interface 120 between the polycrystalline table 116 and the substrate 118, defined by their abutting surfaces, may be non-planar. The non-planar interface 120 of the cutting element 112 may be configured to strengthen high-stress regions within the polycrystalline table 116, interrupt crack propagation tending to extend circumferentially around the polycrystalline table 116, and reduce stress concentrations associated with conventional non-planar interface designs.


Referring collectively to FIGS. 3 and 4, a perspective view and an end view of the substrate 118 of the cutting element 112 of FIG. 2 are shown. An end 122 of the substrate 118 on which the polycrystalline table 116 (see FIG. 2) will be formed or otherwise attached may be non-planar. The non-planar end 122 of the substrate 118 may include a cross-shaped (e.g., cruciform) feature 124, which is depicted as a cross-shaped groove extending into the substrate 118 in the embodiment of FIGS. 3 and 4. In other embodiments, the non-planar end 122 of the substrate 118 may comprise a cross-shaped protrusion extending away from a remainder of the substrate 118. A mating cross-shaped feature, embodied as the other of a groove or a protrusion, may be located on the polycrystalline table 116 (see FIG. 2). A center point 126 of the cross-shaped feature 124 defined at an intersection of perpendicular centerlines 128 of individual radially extending features 130 (e.g., grooves or protrusions) may be located at a central axis 132 of the substrate 118. The individual radially extending features 130 may extend to the periphery of the substrate 118, such that the planar surface 134 at the periphery is interrupted by the cross-shaped feature 124.


A depth D of the cross-shaped feature 124, as measured from a planar surface 134 at a periphery of the end 122 of the substrate 118 extending into the substrate 118 or into the polycrystalline table 116 (see FIG. 2), may be, for example, between about 0.25 mm and about 0.50 mm. As a specific, non-limiting example, the depth D of the cross-shaped feature 124 may be about 0.40 mm. The depth D of the cross-shaped feature 124 may be uniform in some embodiments. In other embodiments, the depth D of the cross-shaped feature 124 may not be constant. For example, the depth D of the cross-shaped feature may change (e.g., increase or decrease) as distance from the central axis 132 increases, which change may be constant (e.g., linear) or may vary (e.g., exponentially). A width WCSF of each individual radially extending feature 130 of the cross-shaped feature 124 may be, for example, between about 0.75 mm and about 1.75 mm. As a specific, non-limiting example, the width WCSF of each individual radially extending feature of the cross-shaped feature 124 may be about 1.25 mm. The width WCSF of each individual radially extending feature 130 of the cross-shaped feature 124 may be uniform in some embodiments. In other embodiments, the width WCSF of each individual radially extending feature 130 of the cross-shaped feature 124 may not be constant. For example, width WCSF of each individual radially extending feature 130 of the cross-shaped feature 124 may change (e.g., increase or decrease) as distance from the central axis 132 increases, which change may be constant (e.g., linear) or may vary (e.g., exponentially). In embodiments where the cross-shaped feature 124 comprises a cross-shaped groove extending into the substrate 118, the cross-shaped feature may strengthen the polycrystalline table 116 (see FIG. 2) in regions where the polycrystalline table 116 (see FIG. 2) is particularly susceptible to damage, such as, for example, at and around the central axis 132 of the substrate 118, which may also define a central axis of the cutting element 112 (see FIG. 2) and at the peripheral edge, by thickening the superhard material of the polycrystalline table 116 at those locations. In addition, the cross-shaped feature 124 may act as a conduit to channel stress away from the peripheral edge.


The non-planar end 122 of the substrate 118 may include L-shaped features 136 located proximate corners of the cross-shaped feature 124 in each quadrant defined by the cross-shaped feature 124, which L-shaped features 136 are depicted as L-shaped protrusions extending away from the remainder of the substrate 118 in the embodiment of FIGS. 3 and 4. In other embodiments, the non-planar end 122 of the substrate 118 may comprise L-shaped grooves extending into the substrate 118. A mating L-shaped feature, embodied as the other of a groove or a protrusion, may be located on the polycrystalline table 116 (see FIG. 2). Arms 138 of the L-shaped features 136 may not extend to the periphery of the substrate 118 such that a portion of the planar surface 134 at the periphery is uninterrupted by the L-shaped features 136.


A height H of each L-shaped feature 136, as measured from the planar surface 134 at a periphery of the end 122 of the substrate 118 extending into the substrate 118 or into the polycrystalline table 116 (see FIG. 2), may be greater than the greatest depth D of the cross-shaped feature 124. For example, the height H of each L-shaped feature 136 may be at least about 2 times, at least about 3 times, or even at least about 4 times greater than the greatest depth D of the cross-shaped feature 124. The height H of each L-shaped feature 136 may be, for example, between about 1.50 mm and about 0.50 mm. As a specific, non-limiting example, the height H of each L-shaped feature 136 may be about 1.27 mm.


A width WLSF of each arm 138 of the L-shaped features 136 may be greater than or equal to the greatest width WCSF of each radially extending feature 130 of the cross-shaped feature 124. For example, the width WLSF of each arm 138 of the L-shaped features 136 may be at least about 1.25 times, at least about 1.5 times, or even at least about 1.75 times greater than the greatest width WCSF of each radially extending feature 130 of the cross-shaped feature 124. The width WLSF of each arm 138 of the L-shaped features 136 may be, for example, between about 1.00 mm and about 3.00 mm. As a specific, non-limiting example, the width WLSF of each arm 138 of the L-shaped features 136 may be about 2.00 mm.


In embodiments where each L-shaped feature 136 comprises an L-shaped protrusion extending away from the remainder of the substrate 118, the L-shaped feature 136 may strategically weaken regions where the polycrystalline table 116 (see FIG. 2) is not particularly susceptible to damage, such as, for example, in intermediate regions between the periphery and center of the cutting element 112 (see FIG. 2), by thinning the polycrystalline table 116 (see FIG. 2) at those locations. In addition, the L-shaped features 136 may interrupt crack propagation through the polycrystalline table 116 (see FIG. 2) such that the likelihood that cracks propagate to complete an entire circle within the polycrystalline table 116 (see FIG. 2) may be reduced, which may reduce the occurrence of spalling of the polycrystalline table 116 (see FIG. 2).


Transitions between surfaces defining the non-planar end 122 of the substrate 118 may be rounded. For example, a radius of curvature of each transition between surfaces defining the non-planar end 122 may be about 0.5 times the depth D of the cross-shaped feature 124 or greater. More specifically, the radius of curvature of each transition between surfaces defining the non-planar end 122 may be at least about 0.75 times the depth D of the cross-shaped feature 124, at least equal to the depth D of the cross-shaped feature 124, or at least 1.25 times the depth D of the cross-shaped feature 124. The radius of curvature of each transition between surfaces defining the non-planar end 122 may be, for example, at least about 0.25 mm. As a specific, non-limiting example, radiuses of curvature of each transition between surfaces defining the non-planar end 122 may be about 0.6 mm. In some embodiments, different transitions between different surfaces defining the non-planar end 122 (e.g., between the planar surface 134 and the L-shaped features 136, and between the L-shaped features 136 and the cross-shaped feature 124, between surfaces of each individual L-shaped feature 136 or of each cross-shaped feature 124) may exhibit different radiuses of curvature. In other embodiments, each transition may have the same radius of curvature. Because the features 124 and 136 described herein are curved, the location at which one feature 124 or 136 ends and another 124 or 136 begins may not be readily visible. Accordingly, the height H, depth D, and widths WCSF and WLSF described previously herein are to be measured from a point where the feature 124 or 136 intersects with the elevation of the planar surface 134. By making all transitions rounded, the non-planar interface 120 (see FIG. 2) may exhibit reduced stress concentrations as compared to conventional non-planar interfaces.


Referring collectively to FIGS. 5 and 6, a perspective view and an end view of another embodiment of a substrate 118 for a cutting element 112 (see FIG. 2) are shown. The non-planar end 122 of the substrate 118 may include all the features 124 and 136 described previously in connection with FIGS. 3 and 4. In addition, the non-planar end 122 may include a curved feature 140 in each quadrant defined by the L-shaped features 136. For example, the curved feature 140 is depicted as a curved protrusion extending from a remainder of the substrate 118 in the embodiment of FIGS. 5 and 6. In other embodiments, the curved feature 140 may be a curved groove extending into the substrate 118. A mating curved feature, embodied as the other of a groove or a protrusion, may be located on the polycrystalline table 116 (see FIG. 2). The curved feature 140 may extend between the arms 138 of each of the L-shaped features 136, with a center of curvature of each curved feature 140 being located at the central axis 132 of the substrate 118, which may also define the central axis of the cutting element 112 (see FIG. 2). None of the curved features 140 may intersect with the arms 138 of the L-shaped features 136, such that a portion of the planar surface 134 may be interposed between each curved feature 140 and adjacent arms 138 of the L-shaped features 136. Radially outermost portions of each curved feature 140 may be located at the same radial position of, or radially closer to the central axis 132 than, radially outermost portions of the L-shaped features 136. For example, a circle defined by connecting radially outermost points of the arms 138 of each L-shaped feature 136 may also define an outermost extent of each curved feature 140.


A width WCF of each curved feature 140 may be less than or equal to the greatest width WCSF of the radially extending features 130 of the cross-shaped feature 124. For example, the width WCF of each curved feature 136 may be about 1.0 time or less, about 0.75 times or less, or about 0.5 times or less than the greatest width WCSF of the radially extending features 130 of the cross-shaped feature 124. The width WCF of each curved feature 140 may be, for example, between about 1.25 mm and about 0.50 mm. As a specific, non-limiting example, the width WCF of each curved feature 136 may be about 0.75 mm. A height HCF of each curved feature 140, as measured from the planar surface 134 at the periphery of the end 122 of the substrate 118 extending into the substrate 118 or into the polycrystalline table 116 (see FIG. 2), may be less than or equal to the height H of each L-shaped feature 136. For example, the height HCF of each curved feature 140 may be about 1.0 time or less, about 0.75 times or less, or about 0.50 times or less than the height H of each L-shaped feature 136. The height HCF of each curved feature 140 may be, for example, between about 1.25 mm and about 0.50 mm. As a specific, non-limiting example, the height HCF of each curved feature 140 may be about 1.00 mm. The curved features 140 may interrupt crack propagation within the polycrystalline table 116 (see FIG. 2) and strategically weaken the polycrystalline table 116 (see FIG. 2) to channel stress away from critical regions of the polycrystalline table 116 (see FIG. 2), such as, for example, the peripheral edge.


Referring collectively to FIGS. 7 and 8, a perspective view and an end view of another embodiment of a substrate 118 for a cutting element 112 (see FIG. 2) are shown. The non-planar end 122 of the substrate 118 may include all the features 124, 136, and 140 described previously in connection with FIGS. 5 and 6. In addition, the non-planar end 122 may include a trench 142 formed in each curved feature 140. For example, the trench 142 is depicted as a extending into the substrate 118 in the embodiment of FIGS. 5 and 6. In other embodiments, the trench 142 extend away from the substrate 118. A mating trench, embodied as the other of a extending away from or into the polycrystalline table 116 (see FIG. 2), may be located on the polycrystalline table 116 (see FIG. 2). Each trench 142 may extend for an entire length of each curved feature 140, with each trench 142 following the curve of an associated curved feature 140. For example, a center of curvature of each trench 142 may be located at the central axis 132 of the substrate 118, which may also define the central axis of the cutting element 112 (see FIG. 2). Each trench 142 may be centrally located on its associated curved feature 140, such that the curved feature 140 extends radially an equal distance from each of the radially innermost and radially outermost portion of the trench 142.


A width WT of each trench 142 may be less than the width WCF of its associated curved feature 140. For example, the width WT of each trench 142 may be about 0.5 times or less, about 0.25 times or less, or about 0.125 times or less than the width WCF of its associated curved feature 140. The width WT of each trench 142 may be, for example, between about 0.75 mm and about 0.12 mm. As a specific, non-limiting example, the width WT of each trench 142 may be about 0.25 mm. A depth DT of each trench 142, as measured from an uppermost point on its associated curved feature 140 extending into or away from the curved feature 140, may be less than or equal to the height HCF of the associated curved feature 140. For example, the depth DT of each trench 142 may be about 0.75 times or less, or about 0.50 times or less, or about 0.25 times or less than the height HCF of each associated curved feature 140. The depth DT of each curved feature 140 may be, for example, between about 0.75 mm and about 0.25 mm. As a specific, non-limiting example, the depth DT of each trench 142 may be about 0.50 mm. The trenches 142 may interrupt crack propagation within the polycrystalline table 116 (see FIG. 2) and channel stress away from critical regions of the polycrystalline table 116 (see FIG. 2), such as, for example, the peripheral edge.


Referring collectively to FIGS. 9 and 10, a perspective view and an end view of another embodiment of a substrate 118 for a cutting element 112 are shown. The non-planar end 122 of the substrate 118 may include all the features 124 and 136 described previously in connection with FIGS. 3 and 4. In addition, the non-planar end 122 may include a tapered surface 144 in an area between the arms 138 of each of the L-shaped features 136, extending from an intersect point 146 of each of the L-shaped features toward the one of the substrate 118 and the polycrystalline table 116 (see FIG. 2). For example, the tapered surface 144 is depicted as extending from an intersect point 146 positioned at the radially outermost location of intersection of the two arms 138 at maximum height H above the planar surface 134 toward the remainder of the substrate 118. In other embodiments, the tapered surface 144 may extend toward the polycrystalline table 116 and may extend from an intersect point defined by other features of the arms 138 (e.g., centerlines, radially innermost portion at maximum height H, midway to maximum height H, etc.). The tapered surface 144 may intersect with the arms 138 of the L-shaped features 136 along their length, such that no portion of the planar surface 134 is interposed between each tapered surface 144 and adjacent arms 138 of the L-shaped features 136 and the gradual taper of the tapered surface 144 is visible as compared to a more abrupt transition to the maximum height H of each L-shaped feature 136. Radially outermost portions of each tapered surface may be located at the same radial position of, or radially closer to the central axis 132 than, radially outermost portions of the L-shaped features 136. For example, a circle defined by connecting radially outermost points of the arms 138 of each L-shaped feature 136 may also define an outermost extent of each tapered surface 144.


A slope of each tapered surface 144 may be less than or equal to the height H of each L-shaped feature 136 divided by the length of an arm 138 of each L-shaped feature. For example, the slope of each tapered surface 144 may be less than or equal to the height H of each L-shaped feature 136 divided by the length of an arm 138 as measured from a radially outermost point of the arm 138 at an elevation of the planar surface 134 to a radially innermost point of the arm 138 at the elevation of the planar surface 134. The slope of each tapered surface 144 may be, for example, between about 0.50 and about 0.10. As a specific, non-limiting example, the slope of each tapered surface 144 may be about 0.30. The sloped surfaces 144 may strategically weaken the polycrystalline table 116 (see FIG. 2) to channel stress away from critical regions of the polycrystalline table 116 (see FIG. 2), such as, for example, the peripheral edge.


Referring collectively to FIGS. 11 and 12, a perspective view and an end view of another embodiment of a substrate 118 for a cutting element 112 are shown. The non-planar end 122 of the substrate 118 may include all the features 124, 136, and 140 described previously in connection with FIGS. 9 and 10. In addition, the non-planar end 122 may include a pear-shaped feature 148 in each quadrant defined by the L-shaped features 136. For example, the pear-shaped feature 148 is depicted as a pear-shaped protrusion extending from the tapered surface 144 in the embodiment of FIGS. 11 and 12. In other embodiments, the curved feature 140 may be a pear-shaped depression extending into the tapered surface 144. A mating pear-shaped feature, embodied as the other of a depression or a protrusion, may be located on the polycrystalline table 116 (see FIG. 2). An axis of symmetry 150 of each pear-shaped feature 148 may bisect an angle θ defined between the arms 138 of each of the L-shaped features 136. Radially outermost portions of each pear-shaped feature 148 may be located radially closer to the central axis 132 than radially outermost portions of the tapered surface 144. For example, the distance between a radially innermost portion of each pear-shaped feature 148 and the intersect point 146 described previously in connection with FIGS. 9 and 10 may be equal to the shortest distance between a radially outermost portion of each pear-shaped feature 148 and the radially outermost portion of the tapered surface 144.


A greatest width WPSF of each pear-shaped feature 148 taken in a direction perpendicular to the axis of symmetry 150 of a respective pear-shaped feature 148 may be less than or equal to the greatest width WCSF of the radially extending features 130 of the cross-shaped feature 124. For example, the greatest width WPSF of each pear-shaped feature 148 may be about 1.0 time or less, about 0.75 times or less, or about 0.5 times or less than the greatest width WCSF of the radially extending features 130 of the cross-shaped feature 124. The greatest width WPSF of each pear-shaped feature 148 may be, for example, between about 1.25 mm and about 0.50 mm. As a specific, non-limiting example, the greatest width WPSF of each pear-shaped feature 148 may be about 0.75 mm. A length LCF of each pear-shaped feature 148 taken in a direction parallel to the axis of symmetry 150 of a respective pear-shaped feature 148 may be greater than or equal to the greatest width WPSF of the pear-shaped feature 148. For example, a length LPSF of each pear-shaped feature 148 may be about 1.0 time or greater, about 1.1 times the greater, or about 1.25 times or greater than the greatest width WPSF of the pear-shaped feature 148. The length LPSF of each pear-shaped feature 148 may be, for example, between about 1.50 mm and about 0.50 mm. As a specific, non-limiting example, the length LPSF of each pear-shaped feature 148 may be about 1.00 mm. A height HPSF of each pear-shaped feature 148, as measured from the planar surface 134 at the periphery of the end 122 of the substrate 118 extending into the substrate 118 or into the polycrystalline table 116 (see FIG. 2), may be less than or equal to the height H of each L-shaped feature 136. For example, the height HPSF of each pear-shaped feature 148 may be about 1.0 time or less, about 0.75 times or less, or about 0.50 times or less than the height H of each L-shaped feature 136. The height HPSF of each curved feature 148 may be, for example, between about 1.25 mm and about 0.50 mm. As a specific, non-limiting example, the height HPSF of each curved feature 148 may be about 1.00 mm. The pear-shaped features 148 may interrupt crack propagation within the polycrystalline table 116 (see FIG. 2) and strategically weaken the polycrystalline table 116 (see FIG. 2) to channel stress away from critical regions of the polycrystalline table 116 (see FIG. 2), such as, for example, the peripheral edge.


Referring collectively to FIGS. 13 and 14, a perspective view and an end view of another embodiment of a substrate 118 for a cutting element 112 are shown. The non-planar end 122 of the substrate 118 may include all the features 124, 136, and 140 described previously in connection with FIGS. 9 and 10. In addition, the non-planar end 122 may include concentric arcs 152 in each quadrant defined by the L-shaped features 136. For example, the concentric arcs 152 are depicted as concentric arc-shaped protrusions extending from the tapered surface 144 in the embodiment of FIGS. 13 and 14. In other embodiments, the concentric arcs 152 may be a concentric arc-shaped grooves extending into the tapered surface 144. Mating concentric arcs, embodied as the other of a groove or a protrusion, may be located on the polycrystalline table 116 (see FIG. 2). The concentric arcs 152 may extend between the arms 138 of each of the L-shaped features 136, with a center of curvature of each concentric arc 152 being located at the central axis 132 of the substrate 118, which may also define the central axis of the cutting element 112 (see FIG. 2). None of the concentric arcs 152 may intersect with the arms 138 of the L-shaped features 136, such that a portion of the tapered surface 144 may be interposed between each concentric arc 152 and adjacent arms 138 of the L-shaped features 136. Radially outermost portions of radially outermost concentric arcs 152 may be located radially closer to the central axis 132 than radially outermost portions of the L-shaped features 136. For example, a circle defined by connecting radially outermost points of the arms 138 of each L-shaped feature 136 may be located radially outward from the radially outermost portions of radially outermost concentric arcs 152.


A width WCA of each concentric arc 152 may be less than the greatest width WCSF of the radially extending features 130 of the cross-shaped feature 124. For example, the width WCA of each concentric arc 152 may be about 0.50 times or less, about 0.25 times or less, or about 0.125 times or less than the greatest width WCSF of the radially extending features 130 of the cross-shaped feature 124. The width WCA of each concentric arc may be, for example, between about 0.75 mm and about 0.10 mm. As a specific, non-limiting example, the width WCA of each concentric arc 152 may be about 0.25 mm. A height HCA of each concentric arc 152, as measured from the tapered surface 144 extending into the substrate 118 or into the polycrystalline table 116 (see FIG. 2) may be sufficiently small that the concentric arcs 152 do not extend above any L-shaped feature 136. For example, the height HCA of each concentric arc 152 may be between about 0.50 mm and about 0.10 mm. As a specific, non-limiting example, the height HCA of each concentric arc 152 may be about 0.25 mm. A distance D between adjacent concentric arcs 152 may be greater than or equal to the height HCA of each concentric arc 152. For example, the distance D between adjacent concentric arcs 152 may be 1.0 times or greater, 1.25 times or greater, or 1.5 times or greater than the height HCA of each concentric arc 152. The distance D between adjacent concentric arcs 152 may be, for example, between about 0.75 mm and about 0.25 mm. As a specific, non-limiting example, the distance D between adjacent concentric arcs 152 may be about 0.50 mm. A number of arcs may be between about three and about six. For example, the number of arcs may be about four. The concentric arcs 152 may interrupt crack propagation within the polycrystalline table 116 (see FIG. 2) and strategically weaken the polycrystalline table 116 (see FIG. 2) to channel stress away from critical regions of the polycrystalline table 116 (see FIG. 2), such as, for example, the peripheral edge.


In some embodiments, the polycrystalline table 116 (see FIG. 2) may be formed by subjecting particles of superhard material to a high temperature/high pressure (HTHP) process, sintering the particles to one another to form the polycrystalline material of the polycrystalline table 116 (see FIG. 2). Such a process may be performed by placing a container in which the particles are located into a press and subjecting the particles to the HTHP process. The HTHP process may also be used to attach the polycrystalline table 116 to a substrate 118 to form a cutting element 112 (see FIG. 2). For example, a cross-sectional view of such a container 154 for forming a cutting element 112 (see FIG. 2) is shown in FIG. 15 in a first stage of a process for forming the cutting element 112 (see FIG. 2). The container 154 may include one or more generally cup-shaped members, such as cup-shaped member 156c, which may act as a receptacle. Particles 158 may be placed in the cup-shaped member 156c, which may have a circular end wall and a generally cylindrical lateral side wall extending perpendicularly from the circular end wall, such that the cup-shaped member 156c is generally cylindrical and includes a first closed end and a second, opposite open end. The particles 158 may include a superhard material in the form of, for example, powdered diamond (e.g., natural, synthetic, or natural and synthetic diamond) or powdered cubic boron nitride, which may optionally be mixed with a liquid (e.g., alcohol) to form a slurry (e.g., a paste). The particles 158 may include a catalyst material (e.g., iron, nickel, or cobalt) selected to catalyze formation of inter-granular bonds between individual particles of the superhard material in some embodiments. The particles 158 may exhibit a monomodal or multimodal (e.g., bimodal, trimodal, etc.) particle size distribution.


Referring to FIG. 16, a cross-sectional view of the container 154′ of FIG. 15 is shown in a second stage of a process for forming a cutting element 112 (see FIG. 2). The container 154′ may include the cup-shaped member 156c and two additional cup-shaped members 156a and 156b, which may be assembled and swaged and/or welded together to form the container 154′. A substrate 118 having a non-planar end 122, such as, for example, any of those shown in FIGS. 3 through 14, may be placed in the container 154′ with the non-planar end 122 facing the particles 158. In some embodiments, the substrate 118 may be in a green state (i.e., an unsintered state with less than a final density) with hard particles (e.g., tungsten carbide) held in place by a binder material (e.g., wax). In other embodiments, the substrate may be in a brown state (i.e., a sintered state still with less than a final density) with hard particles bound in a matrix material (e.g., a solvent metal catalyst). In still other embodiments, the substrate 118 may be a fully sintered part (e.g., cemented tungsten carbide at a final density). The non-planar end 122 may be pressed against the particles 158 to impart a shape inverse to the shape of the non-planar end 122 to the particles 158. In other embodiments, the substrate 118 may be placed in the container 154′ before the particles 158, and the particles 158 may simply conform to the shape of the non-planar end 122 when they are placed adjacent the non-planar end 122 within the container 154′. Assembly of the container 154′ may be completed, and the substrate 118 and particles 158 may be subjected to a high temperature/high pressure (HTHP) process to cause the particles 158 to interbond with one another in the presence of catalyst material (e.g., melted to flow among the rest of the particles 158 or swept among the particles 158 from within the substrate 118) to form the polycrystalline table 116 and to secure the polycrystalline table 116 to the substrate 118 at the non-planar interface 120. In embodiments where the substrate 118 has less than a final density, the HTHP process may also sinter the substrate 118 to a final density. Conventional HTHP processing may be used to form the cutting element 112 (see FIG. 2).


Additional, non-limiting embodiments within the scope of the present disclosure include, but are not limited to, the following:


Embodiment 1

A cutting element for an earth-boring tool comprises a substrate, a polycrystalline table comprising superhard material secured to the substrate at an end of the substrate, and a non-planar interface defined between the polycrystalline table and the substrate. The non-planar interface comprises a cross-shaped groove extending into one of the substrate and the polycrystalline table and L-shaped grooves extending into the other of the substrate and the polycrystalline table proximate corners of the cross-shaped groove. Transitions between surfaces defining the non-planar interface are rounded.


Embodiment 2

The cutting element of Embodiment 1, further comprising a tapered surface in an area between arms of each of the L-shaped grooves, the tapered surface extending from an intersect point of each of the L-shaped grooves toward the one of the substrate and the polycrystalline table.


Embodiment 3

The cutting element of Embodiment 2, further comprising concentric grooves extending from each tapered surface into the other of the substrate and the polycrystalline table, wherein the concentric grooves do not intersect with the arms of the L-shaped grooves and a center of curvature of each of the concentric grooves is located at a central axis of the cutting element.


Embodiment 4

The cutting element of Embodiment 2, further comprising a pear-shaped depression extending from each tapered surface into the other of the substrate and the polycrystalline table, wherein an axis of symmetry of the pear-shaped depression bisects an angle defined between the arms of each of the L-shaped grooves.


Embodiment 5

The cutting element of Embodiment 4, wherein a depth of each pear-shaped depression is less than a depth of each of the L-shaped grooves.


Embodiment 6

The cutting element of Embodiment 1, further comprising a curved groove extending between arms of each of the L-shaped grooves into the other of the substrate and the polycrystalline table, wherein a center of curvature of each curved groove is located at a central axis of the cutting element and wherein the curved grooves do not intersect with the arms of the L-shaped grooves.


Embodiment 7

The cutting element of Embodiment 6, wherein a circle defined by connecting outermost points of the arms of the L-shaped grooves also defines an outermost extent of the curved grooves.


Embodiment 8

The cutting element of Embodiment 6 or Embodiment 7, further comprising a trench formed in each curved groove extending into the one of the substrate and the polycrystalline table, wherein the trench follows the curve of each curved groove.


Embodiment 9

The cutting element of any one of Embodiments 1 through 8, wherein a depth of the cross-shaped groove is less than a depth of each of the L-shaped grooves.


Embodiment 10

The cutting element of any one of Embodiments 1 through 9, wherein the transitions between the surfaces defining the non-planar interface have a radius of curvature of at least 0.25 mm.


Embodiment 11

An earth-boring tool comprises a body and cutting elements secured to the body. At least one of the cutting elements comprises a substrate, a polycrystalline table comprising superhard material secured to the substrate at an end of the substrate, and a non-planar interface defined between the polycrystalline table and the substrate. The non-planar interface comprises a cross-shaped groove extending into one of the substrate and the polycrystalline table and L-shaped grooves extending into the other of the substrate and the polycrystalline table proximate corners of the cross-shaped groove. Transitions between surfaces defining the non-planar interface are rounded.


Embodiment 12

A method of forming a cutting element for an earth-boring tool comprises forming a substrate to have a non-planar end. The non-planar end comprises a cross-shaped groove extending into the substrate and L-shaped protrusions extending from a remainder of the substrate proximate corners of the cross-shaped groove. Transitions between surfaces defining the non-planar end are shaped to be rounded. Particles of superhard material are positioned adjacent the non-planar end of the substrate in a container. The particles are sintered in a presence of a catalyst material to form a polycrystalline table secured to the substrate, with a non-planar interface being defined between the substrate and the polycrystalline table.


Embodiment 13

The method of Embodiment 12, further comprising forming the non-planar end to comprise a tapered surface in an area between arms of each of the L-shaped grooves, the tapered surface extending from an intersect point of each of the L-shaped grooves toward the remainder of the substrate.


Embodiment 14

The method of Embodiment 13, further comprising forming the non-planar end to comprise concentric protrusions extending from each tapered surface away from the remainder of the substrate, wherein the concentric protrusions do not intersect with the arms of the L-shaped protrusions and a center of curvature of each of the concentric protrusions is located at a central axis of the substrate.


Embodiment 15

The method of Embodiment 13, further comprising forming the non-planar end to comprise a pear-shaped protrusion extending from each tapered surface away from the remainder of the substrate, wherein an axis of symmetry of the pear-shaped protrusion bisects an angle defined between the arms of each of the L-shaped protrusions.


Embodiment 16

The method of Embodiment 12, further comprising forming the non-planar end to comprise a curved protrusion extending between arms of each of the L-shaped protrusions into the substrate, wherein a center of curvature of each curved protrusion is located at a central axis of the substrate and wherein the curved protrusions do not intersect with the arms of the L-shaped protrusions.


Embodiment 17

The method of Embodiment 16, wherein forming the non-planar end to comprise the curved protrusion extending between the arms of each of the L-shaped protrusions comprises forming an outermost extent of each curved protrusion to coincide with a circle defined by connecting outermost points of the arms of the L-shaped protrusions.


Embodiment 18

The method of Embodiment 16 or Embodiment 17, further comprising forming the non-planar end to comprise a trench extending toward the substrate formed in each curved protrusion, wherein the trench follows the curve of each curved protrusion.


Embodiment 19

The method of any one of Embodiments 12 through 18, further comprising forming a depth of the cross-shaped groove to be less than a height of each of the L-shaped protrusions.


Embodiment 20

The cutting element of any one of Embodiments 12 through 18, further comprising pressing the non-planar end of the substrate against the particles to impart an inverse shape of the non-planar end to the particles.


While certain illustrative embodiments have been described in connection with the figures, those of ordinary skill in the art will recognize and appreciate that the scope of the disclosure is not limited to those embodiments explicitly shown and described herein. Rather, many additions, deletions, and modifications to the embodiments described herein may be made to produce embodiments within the scope of the disclosure, such as those hereinafter claimed, including legal equivalents. In addition, features from one disclosed embodiment may be combined with features of another disclosed embodiment while still being within the scope of the disclosure, as contemplated by the inventors.

Claims
  • 1. A cutting element for an earth-boring tool, comprising: a substrate;a polycrystalline table comprising superhard material secured to the substrate at an end of the substrate; anda non-planar interface defined between the polycrystalline table and the substrate, the non-planar interface comprising a cross-shaped groove extending into one of the substrate and the polycrystalline table to a first maximum elevation of the non-planar interface along a central axis of the substrate, an intersection between arms of the cross-shaped groove being aligned with the central axis of the substrate, and L-shaped grooves extending into the other of the substrate and the polycrystalline table proximate corners of the cross-shaped groove to a second, opposing maximum elevation of the non-planar interface along the central axis of the substrate, each L-shaped groove being defined by intersecting arms, the arms separating a surface of the non-planar interface from the cross-shaped groove,wherein an elevation of the surface along the central axis of the substrate is between the first maximum elevation to which the cross-shaped groove extends and the second maximum elevation to which the L-shaped grooves extend, andwherein transitions between surfaces defining the non-planar interface are rounded.
  • 2. The cutting element of claim 1, further comprising each surface of the non-planar interface separated from the cross-shaped groove by the L-shaped grooves to be a tapered surface, the tapered surface extending from an intersect point of each of the L-shaped grooves toward the one of the substrate and the polycrystalline table.
  • 3. The cutting element of claim 2, further comprising concentric grooves extending from each tapered surface into the other of the substrate and the polycrystalline table, wherein the concentric grooves do not intersect with the arms of the L-shaped grooves and a center of curvature of each of the concentric grooves is located at a central axis of the cutting element.
  • 4. The cutting element of claim 2, further comprising a pear-shaped depression extending from each tapered surface into the other of the substrate and the polycrystalline table, wherein an axis of symmetry of the pear-shaped depression bisects an angle defined between the arms of each of the L-shaped grooves.
  • 5. The cutting element of claim 4, wherein a depth of each pear-shaped depression is less than a depth of each of the L-shaped grooves.
  • 6. The cutting element of claim 1, further comprising a curved groove extending between arms of each of the L-shaped grooves into the other of the substrate and the polycrystalline table, wherein a center of curvature of each curved groove is located at a central axis of the cutting element and wherein the curved grooves do not intersect with the arms of the L-shaped grooves.
  • 7. The cutting element of claim 6, wherein a circle defined by connecting outermost points of the arms of the L-shaped grooves also defines an outermost extent of the curved grooves.
  • 8. The cutting element of claim 6, further comprising a trench formed in each curved groove extending into the one of the substrate and the polycrystalline table, wherein the trench follows the curve of each curved groove.
  • 9. The cutting element of claim 1, wherein a greatest depth of the cross-shaped groove is less than a depth of each of the L-shaped grooves.
  • 10. The cutting element of claim 1, wherein the transitions between the surfaces defining the non-planar interface have a radius of curvature of at least 0.25 mm.
  • 11. An earth-boring tool, comprising: a body; andcutting elements secured to the body, at least one of the cutting elements comprising: a substrate;a polycrystalline table comprising superhard material secured to the substrate at an end of the substrate; anda non-planar interface defined between the polycrystalline table and the substrate, the non-planar interface comprising a cross-shaped groove extending into one of the substrate and the polycrystalline table to a first maximum elevation of the non-planar interface along a central axis of the substrate, an intersection between arms of the cross-shaped groove being aligned with the central axis of the substrate, and L-shaped grooves extending into the other of the substrate and the polycrystalline table proximate corners of the cross-shaped groove to a second, opposing maximum elevation of the non-planar interface along the central axis of the substrate, each L-shaped groove being defined by intersecting arms, the arms separating a surface of the non-planar interface from the cross-shaped groove,wherein an elevation of the surface along the central axis of the substrate is between the first maximum elevation to which the cross-shaped groove extends and the second maximum elevation to which the L-shaped grooves extend, andwherein transitions between surfaces defining the non-planar interface are rounded.
  • 12. A method of forming a cutting element for an earth-boring tool, comprising: forming a substrate to have a non-planar end, the non-planar end comprising a cross-shaped groove extending into the substrate to a first maximum elevation of the non-planar interface along a central axis of the substrate, an intersection between arms of the cross-shaped groove being aligned with the central axis of the substrate, and L-shaped protrusions extending from a remainder of the substrate proximate corners of the cross-shaped groove to a second, opposing maximum elevation of the non-planar interface along the central axis of the substrate, each L-shaped groove being defined by intersecting arms, the arms separating a surface of the non-planar interface from the cross-shaped groove, wherein an elevation of the surface along the central axis of the substrate is between the first maximum elevation to which the cross-shaped groove extends and the second maximum elevation to which the L-shaped grooves extend;shaping transitions between surfaces defining the non-planar end to be rounded;positioning particles of superhard material adjacent the non-planar end of the substrate in a container; andsintering the particles in a presence of a catalyst material to form a polycrystalline table secured to the substrate, with a non-planar interface being defined between the substrate and the polycrystalline table.
  • 13. The method of claim 12, further comprising forming each surface of the non-planar interface separated from the cross-shaped groove by the L-shaped grooves to comprise a tapered surface in an area between the arms of each of the L-shaped grooves, the tapered surface extending from an intersect point of each of the L-shaped grooves toward the remainder of the substrate.
  • 14. The method of claim 13, further comprising forming the non-planar end to comprise concentric protrusions extending from each tapered surface away from the remainder of the substrate, wherein the concentric protrusions do not intersect with the arms of the L-shaped protrusions and a center of curvature of each of the concentric protrusions is located at a central axis of the substrate.
  • 15. The method of claim 13, further comprising forming the non-planar end to comprise a pear-shaped protrusion extending from each tapered surface away from the remainder of the substrate, wherein an axis of symmetry of the pear-shaped protrusion bisects an angle defined between the arms of each of the L-shaped protrusions.
  • 16. The method of claim 12, further comprising forming the non-planar end to comprise a curved protrusion extending between the arms of each of the L-shaped protrusions into the substrate, wherein a center of curvature of each curved protrusion is located at a central axis of the substrate and wherein the curved protrusions do not intersect with the arms of the L-shaped protrusions.
  • 17. The method of claim 16, wherein forming the non-planar end to comprise the curved protrusion extending between the arms of each of the L-shaped protrusions comprises forming an outermost extent of each curved protrusion to coincide with a circle defined by connecting outermost points of the arms of the L-shaped protrusions.
  • 18. The method of claim 16, further comprising forming the non-planar end to comprise a trench extending toward the substrate formed in each curved protrusion, wherein the trench follows the curve of each curved protrusion.
  • 19. The method of claim 12, further comprising forming a greatest depth of the cross-shaped groove to be less than a height of each of the L-shaped protrusions.
  • 20. The cutting element of claim 12, further comprising pressing the non-planar end of the substrate against the particles to impart an inverse shape of the non-planar end to the particles.
US Referenced Citations (384)
Number Name Date Kind
734515 Collins Jul 1903 A
1650492 Allan Nov 1927 A
2641446 Haglund et al. Jun 1953 A
2707897 Beeson May 1955 A
2735656 Hoglund et al. Feb 1956 A
2777672 Haglund et al. Jan 1957 A
2842342 Haglund Jul 1958 A
2888247 Haglund May 1959 A
3388757 Fittinger Jun 1968 A
3745623 Wentorf, Jr. et al. Jul 1973 A
3913280 Hall Oct 1975 A
4148368 Evans Apr 1979 A
4200159 Peschel et al. Apr 1980 A
4224380 Bovenkerk et al. Sep 1980 A
4255165 Dennis et al. Mar 1981 A
4311490 Bovenkerk et al. Jan 1982 A
4353958 Kita et al. Oct 1982 A
4412980 Tsuji et al. Nov 1983 A
4512426 Bidegaray Apr 1985 A
4525179 Gigl Jun 1985 A
4538690 Short Sep 1985 A
4539018 Whanger et al. Sep 1985 A
4545441 Williamson Oct 1985 A
4552232 Frear Nov 1985 A
4554986 Jones Nov 1985 A
4558753 Barr Dec 1985 A
4572722 Dyer Feb 1986 A
4592433 Dennis Jun 1986 A
4593777 Barr Jun 1986 A
4604106 Hall Aug 1986 A
4605343 Hibbs et al. Aug 1986 A
4629373 Hall Dec 1986 A
4636253 Nakai et al. Jan 1987 A
4640375 Barr et al. Feb 1987 A
4664705 Horton et al. May 1987 A
4679639 Barr et al. Jul 1987 A
4686080 Hara et al. Aug 1987 A
4690691 Komanduri et al. Sep 1987 A
4726432 Scott et al. Feb 1988 A
4726718 Meskin et al. Feb 1988 A
4762492 Nagai Aug 1988 A
4766040 Hillert et al. Aug 1988 A
4784023 Dennis Nov 1988 A
4797241 Peterson et al. Jan 1989 A
4858707 Jones et al. Aug 1989 A
4861350 Phaal et al. Aug 1989 A
4866885 Dodsworth Sep 1989 A
4872520 Nelson Oct 1989 A
4907377 Csillag Mar 1990 A
4940180 Martell Jul 1990 A
4944772 Cho Jul 1990 A
4976324 Tibbitts Dec 1990 A
4981184 Knowlton et al. Jan 1991 A
4984642 Renard et al. Jan 1991 A
4997049 Tank et al. Mar 1991 A
5007207 Phaal et al. Apr 1991 A
5007493 Coolidge et al. Apr 1991 A
5011514 Cho et al. Apr 1991 A
5027912 Juergens Jul 1991 A
5054246 Phaal et al. Oct 1991 A
5061293 Barr et al. Oct 1991 A
5078219 Morrell et al. Jan 1992 A
5096465 Chen et al. Mar 1992 A
5127923 Bunting et al. Jul 1992 A
5145017 Holster et al. Sep 1992 A
5172778 Tibbitts Dec 1992 A
5174374 Hailey Dec 1992 A
5217081 Waldenstrom et al. Jun 1993 A
5222566 Taylor Jun 1993 A
5244039 Newton Sep 1993 A
5248006 Scott Sep 1993 A
5279375 Tibbitts Jan 1994 A
5314033 Tibbitts May 1994 A
5332051 Knowlton Jul 1994 A
5333699 Thigpen Aug 1994 A
5337844 Tibbitts Aug 1994 A
5351769 Scott et al. Oct 1994 A
5351772 Smith Oct 1994 A
5355969 Hardy et al. Oct 1994 A
5364423 Bigelow et al. Nov 1994 A
5377773 Tibbitts Jan 1995 A
5379853 Lockwood et al. Jan 1995 A
5379854 Dennis et al. Jan 1995 A
5435403 Tibbitts Jul 1995 A
5437343 Cooley et al. Aug 1995 A
5443337 Katayama et al. Aug 1995 A
5445231 Scott et al. Aug 1995 A
5447208 Lund et al. Sep 1995 A
5449048 Thigpen et al. Sep 1995 A
5460233 Meany et al. Oct 1995 A
5468268 Tank et al. Nov 1995 A
5472376 Olmstead et al. Dec 1995 A
5486137 Flood et al. Jan 1996 A
5492188 Smith et al. Feb 1996 A
5505748 Tank et al. Apr 1996 A
5533582 Tibbitts Jul 1996 A
5549171 Mensa-Wilmot et al. Aug 1996 A
5558170 Thigpen et al. Sep 1996 A
5560716 Tank et al. Oct 1996 A
5564511 Frushour et al. Oct 1996 A
5569000 Littecke et al. Oct 1996 A
5590729 Cooley et al. Jan 1997 A
5607024 Keith Mar 1997 A
5641921 Dennis et al. Jun 1997 A
5645617 Frushour et al. Jul 1997 A
5653300 Lund et al. Aug 1997 A
5655612 Grimes et al. Aug 1997 A
5663512 Schader et al. Sep 1997 A
5667028 Truax et al. Sep 1997 A
5685769 Adia et al. Nov 1997 A
5706906 Jurewicz et al. Jan 1998 A
5711702 Devlin Jan 1998 A
5722499 Nguyen et al. Mar 1998 A
5755298 Langford et al. May 1998 A
5755299 Langford et al. May 1998 A
5778994 Spatz Jul 1998 A
5848657 Flood et al. Dec 1998 A
5855247 Scott et al. Jan 1999 A
5871060 Jensen et al. Feb 1999 A
5881830 Cooley Mar 1999 A
5924501 Tibbitts Jul 1999 A
5935323 Tanga et al. Aug 1999 A
5944129 Jensen Aug 1999 A
5954147 Overstreet et al. Sep 1999 A
5957228 Yorston et al. Sep 1999 A
5971087 Chaves Oct 1999 A
5979577 Fielder Nov 1999 A
5979578 Packer Nov 1999 A
5984005 Hart et al. Nov 1999 A
5996713 Pessier et al. Dec 1999 A
6000483 Jurewicz et al. Dec 1999 A
6006846 Tibbitts et al. Dec 1999 A
6009963 Chaves et al. Jan 2000 A
6011232 Matthias Jan 2000 A
6026919 Thigpen et al. Feb 2000 A
6045440 Johnson et al. Apr 2000 A
6050354 Pessier et al. Apr 2000 A
6053263 Meiners et al. Apr 2000 A
6054693 Barmatz et al. Apr 2000 A
6059054 Portwood et al. May 2000 A
6065554 Taylor et al. May 2000 A
6068071 Jurewicz et al. May 2000 A
6068913 Cho et al. May 2000 A
6082474 Matthias Jul 2000 A
6098730 Scott et al. Aug 2000 A
6124564 Sue et al. Sep 2000 A
6145608 Lund et al. Nov 2000 A
6148937 Mensa-Wilmot et al. Nov 2000 A
6149695 Adia et al. Nov 2000 A
6164394 Mensa-Wilmot et al. Dec 2000 A
6167975 Estes Jan 2001 B1
6173797 Dykstra et al. Jan 2001 B1
6187068 Frushour et al. Feb 2001 B1
6196340 Jensen et al. Mar 2001 B1
6196910 Johnson et al. Mar 2001 B1
6202770 Jurewicz et al. Mar 2001 B1
6202771 Scott et al. Mar 2001 B1
RE37127 Schader et al. Apr 2001 E
6216805 Lays et al. Apr 2001 B1
6220376 Lundell Apr 2001 B1
6227319 Radford May 2001 B1
6230828 Beuershausen et al. May 2001 B1
6241034 Steinke et al. Jun 2001 B1
6241035 Portwood Jun 2001 B1
6269894 Griffin Aug 2001 B1
6272753 Packer Aug 2001 B2
6283234 Torbet Sep 2001 B1
6315067 Fielder Nov 2001 B1
6315652 Snyder et al. Nov 2001 B1
6325165 Eyre Dec 2001 B1
6328117 Berzas et al. Dec 2001 B1
6344149 Oles Feb 2002 B1
6361873 Yong et al. Mar 2002 B1
6394199 Skyles et al. May 2002 B1
6397958 Charles et al. Jun 2002 B1
6405814 Eyre et al. Jun 2002 B1
6408958 Isbell et al. Jun 2002 B1
6443248 Yong Sep 2002 B2
6447560 Jensen et al. Sep 2002 B2
6481511 Matthias et al. Nov 2002 B2
6488106 Dourfaye Dec 2002 B1
6513608 Eyre et al. Feb 2003 B2
6524363 Gates, Jr. et al. Feb 2003 B2
6527065 Tibbitts et al. Mar 2003 B1
6527069 Meiners et al. Mar 2003 B1
6544308 Griffin et al. Apr 2003 B2
6550556 Middlemiss et al. Apr 2003 B2
6562462 Griffin et al. May 2003 B2
6564886 Mensa-Wilmot et al. May 2003 B1
6571891 Smith et al. Jun 2003 B1
6601662 Matthias et al. Aug 2003 B2
6659199 Swadi Dec 2003 B2
6672406 Beuershausen Jan 2004 B2
6684966 Lin et al. Feb 2004 B2
6719074 Tsuda et al. Apr 2004 B2
6739417 Smith et al. May 2004 B2
6779613 Dykstra et al. Aug 2004 B2
6810972 Sved Nov 2004 B2
6810973 Sved Nov 2004 B2
6814168 Sved Nov 2004 B2
6827159 Sved Dec 2004 B2
6830598 Sung Dec 2004 B1
6843333 Richert et al. Jan 2005 B2
D502952 Achilles et al. Mar 2005 S
6872356 Butcher et al. Mar 2005 B2
6883623 McCormick et al. Apr 2005 B2
6904983 Thigpen et al. Jun 2005 B2
6904984 Estes et al. Jun 2005 B1
6933049 Wan et al. Aug 2005 B2
6935444 Lund et al. Aug 2005 B2
6962218 Eyre Nov 2005 B2
6986297 Scott Jan 2006 B2
6991049 Eyre et al. Jan 2006 B2
7000715 Sinor et al. Feb 2006 B2
7048081 Smith et al. May 2006 B2
7070635 Frushour Jul 2006 B2
7074247 Tank et al. Jul 2006 B2
7140448 Estes et al. Nov 2006 B2
7147687 Mirkin et al. Dec 2006 B2
7243745 Skeem et al. Jul 2007 B2
7261752 Sung Aug 2007 B2
7316279 Wiseman et al. Jan 2008 B2
7350599 Lockwood et al. Apr 2008 B2
7350601 Belnap et al. Apr 2008 B2
7360608 Brackin et al. Apr 2008 B2
7363992 Stowe et al. Apr 2008 B2
7367875 Slutz et al. May 2008 B2
7368079 Yao et al. May 2008 B2
7373998 Cariveau et al. May 2008 B2
7377341 Middlemiss et al. May 2008 B2
D570384 Morozov Jun 2008 S
7435296 Sung Oct 2008 B1
7435478 Keshavan Oct 2008 B2
7458765 Stiles et al. Dec 2008 B2
7462003 Middlemiss Dec 2008 B2
7487849 Radtke Feb 2009 B2
7493972 Schmidt et al. Feb 2009 B1
7493973 Keshavan et al. Feb 2009 B2
7497280 Brackin et al. Mar 2009 B2
7517589 Eyre Apr 2009 B2
7533740 Zhang et al. May 2009 B2
7572332 Gruen Aug 2009 B2
7585342 Cho Sep 2009 B2
7608333 Eyre Oct 2009 B2
7628234 Middlemiss Dec 2009 B2
7647992 Fang et al. Jan 2010 B2
7647993 Middlemiss Jan 2010 B2
7690589 Kerns Apr 2010 B2
7740090 Shen et al. Jun 2010 B2
7740673 Eyre Jun 2010 B2
7748475 McClain et al. Jul 2010 B2
7754333 Eyre et al. Jul 2010 B2
7757785 Zhang et al. Jul 2010 B2
7757790 Schmidt et al. Jul 2010 B1
7762355 McClain et al. Jul 2010 B2
7762359 Miess Jul 2010 B1
7776256 Smith et al. Aug 2010 B2
7798257 Shen et al. Sep 2010 B2
7802495 Oxford et al. Sep 2010 B2
7942218 Cooley et al. May 2011 B2
7942219 Keshavan et al. May 2011 B2
7946363 Zhang et al. May 2011 B2
8016054 Lancaster et al. Sep 2011 B2
8020642 Lancaster et al. Sep 2011 B2
8079428 Lyons et al. Dec 2011 B2
8087478 Patel Jan 2012 B2
8191656 Dourfaye et al. Jun 2012 B2
8210288 Chen et al. Jul 2012 B2
8240405 Lancaster et al. Aug 2012 B2
8267204 Lyons Sep 2012 B2
8268452 Lyons et al. Sep 2012 B2
8277722 Digiovanni Oct 2012 B2
8327955 Patel Dec 2012 B2
8469121 Lancaster et al. Jun 2013 B2
8739904 Patel Jun 2014 B2
20010003932 Packer Jun 2001 A1
20030024351 Pender et al. Feb 2003 A1
20030110707 Rosenflanz et al. Jun 2003 A1
20030116361 Smith et al. Jun 2003 A1
20040009376 Wan et al. Jan 2004 A1
20040025443 Davies Feb 2004 A1
20040037948 Tank et al. Feb 2004 A1
20040049193 Capanni Mar 2004 A1
20040140133 Liang Jul 2004 A1
20040149493 McDonough Aug 2004 A1
20040149495 Thigpen et al. Aug 2004 A1
20040162014 John Aug 2004 A1
20040163851 McDonough et al. Aug 2004 A1
20050019114 Sung Jan 2005 A1
20050137598 Auth Jun 2005 A1
20050139397 Achilles et al. Jun 2005 A1
20050247486 Zhang et al. Nov 2005 A1
20050247491 Mirchandani et al. Nov 2005 A1
20050247492 Shen et al. Nov 2005 A1
20050263328 Middlemiss Dec 2005 A1
20050269139 Shen et al. Dec 2005 A1
20060050392 Schulz Mar 2006 A1
20060060390 Eyre Mar 2006 A1
20060060391 Eyre et al. Mar 2006 A1
20060086540 Griffin et al. Apr 2006 A1
20060113546 Sung Jun 2006 A1
20060162967 Brackin et al. Jul 2006 A1
20060162969 Belnap et al. Jul 2006 A1
20060166615 Tank et al. Jul 2006 A1
20060236616 Wan Oct 2006 A1
20060260850 Roberts et al. Nov 2006 A1
20060266559 Keshavan et al. Nov 2006 A1
20060283640 Estes et al. Dec 2006 A1
20070023206 Keshavan Feb 2007 A1
20070029114 Middlemiss Feb 2007 A1
20070079994 Middlemiss Apr 2007 A1
20070102198 Oxford et al. May 2007 A1
20070102199 Smith et al. May 2007 A1
20070102200 Choe et al. May 2007 A1
20070102202 Choe et al. May 2007 A1
20070181348 Lancaster et al. Aug 2007 A1
20070193782 Fang et al. Aug 2007 A1
20070235230 Cuillier et al. Oct 2007 A1
20070284152 Eyre et al. Dec 2007 A1
20080006448 Zhang et al. Jan 2008 A1
20080023230 Cho Jan 2008 A1
20080023231 Vail Jan 2008 A1
20080035387 Hall et al. Feb 2008 A1
20080083568 Overstreet et al. Apr 2008 A1
20080115421 Sani May 2008 A1
20080142267 Griffin et al. Jun 2008 A1
20080142275 Griffin et al. Jun 2008 A1
20080142276 Griffo et al. Jun 2008 A1
20080156544 Singh Jul 2008 A1
20080156545 Tibbitts Jul 2008 A1
20080178535 Wan Jul 2008 A1
20080179108 McClain et al. Jul 2008 A1
20080179109 Belnap et al. Jul 2008 A1
20080206576 Qian et al. Aug 2008 A1
20080236900 Cooley et al. Oct 2008 A1
20080264696 Dourfaye et al. Oct 2008 A1
20080283305 Overstreet et al. Nov 2008 A1
20080308276 Scott Dec 2008 A1
20080308321 Aliko Dec 2008 A1
20090022952 Keshavan Jan 2009 A1
20090022969 Zhang et al. Jan 2009 A1
20090032169 Dourfaye et al. Feb 2009 A1
20090090918 Hobart et al. Apr 2009 A1
20090114454 Belnap et al. May 2009 A1
20090114628 DiGiovanni May 2009 A1
20090127565 Sung May 2009 A1
20090218146 Fang et al. Sep 2009 A1
20090257942 Sung Oct 2009 A1
20090277839 Linford Nov 2009 A1
20090286352 Sung Nov 2009 A1
20090313908 Zhang et al. Dec 2009 A1
20100012389 Zhang et al. Jan 2010 A1
20100014931 Matthias Jan 2010 A1
20100068503 Neogi et al. Mar 2010 A1
20100069567 Petrov et al. Mar 2010 A1
20100084198 Durairajan et al. Apr 2010 A1
20100101866 Bird Apr 2010 A1
20100129615 Chizik et al. May 2010 A1
20100163310 Vempati et al. Jul 2010 A1
20100200305 Griffin et al. Aug 2010 A1
20100243334 Dourfaye et al. Sep 2010 A1
20100276200 Schwefe et al. Nov 2010 A1
20100307829 Patel Dec 2010 A1
20100326741 Patel Dec 2010 A1
20110023375 Sani et al. Feb 2011 A1
20110031036 Patel Feb 2011 A1
20110036643 Belnap et al. Feb 2011 A1
20110088954 DiGiovanni et al. Apr 2011 A1
20110155472 Lyons et al. Jun 2011 A1
20110171414 Sreshta et al. Jul 2011 A1
20110192651 Lyons et al. Aug 2011 A1
20110259642 DiGiovanni et al. Oct 2011 A1
20110315456 Lyons Dec 2011 A1
20120037431 DiGiovanni et al. Feb 2012 A1
20120056022 Lyons et al. Mar 2012 A1
20120186884 Scott et al. Jul 2012 A1
20120186885 Scott et al. Jul 2012 A1
20120222363 DiGiovanni et al. Sep 2012 A1
20120222364 Lyons et al. Sep 2012 A1
20120225253 DiGiovanni et al. Sep 2012 A1
20120225277 Scott Sep 2012 A1
20120279785 Gavia et al. Nov 2012 A1
20130000992 DiGiovanni Jan 2013 A1
20130068537 DiGiovanni Mar 2013 A1
Foreign Referenced Citations (51)
Number Date Country
0117506 Sep 1984 EP
0117552 Sep 1984 EP
0189212 Jul 1986 EP
0196777 Oct 1986 EP
0236924 Sep 1987 EP
0542237 May 1993 EP
546725 Jun 1993 EP
0604211 Jun 1994 EP
0835981 Apr 1998 EP
0841463 May 1998 EP
0852283 Jul 1998 EP
0659510 Apr 1999 EP
0918135 May 1999 EP
0979699 Aug 1999 EP
0941791 Sep 1999 EP
1190791 Mar 2002 EP
1330323 May 2006 EP
2105256 Sep 2009 EP
2147903 Jan 2010 EP
2344607 Jun 2000 GB
2373522 Sep 2002 GB
2374618 Oct 2002 GB
2378202 Feb 2003 GB
2378721 Feb 2003 GB
59219500 Dec 1984 JP
61270496 Nov 1986 JP
05004102 Jan 1993 JP
2000096972 Apr 2000 JP
2034937 May 1995 RU
566439 Jan 2000 RU
9323204 Nov 1993 WO
9415058 Jul 1994 WO
9427769 Dec 1994 WO
9708420 Mar 1997 WO
9735091 Sep 1997 WO
9929465 Jun 1999 WO
0020149 Apr 2000 WO
0028106 May 2000 WO
0034001 Jun 2000 WO
0038864 Jun 2000 WO
0048789 Aug 2000 WO
0160554 Aug 2001 WO
0224437 Mar 2002 WO
0234437 May 2002 WO
2004106004 Dec 2004 WO
2008014003 Jan 2008 WO
2008006010 May 2008 WO
2008092093 Jul 2008 WO
2008094190 Aug 2008 WO
2009118381 Oct 2009 WO
2010062419 Jun 2010 WO
Non-Patent Literature Citations (20)
Entry
International Search Report for International Application No. PCT/US2014/019240 dated Jun. 23, 2014, 3 pages.
International Written Opinion for International Application No. PCT/US2014/019240 dated Jun. 23, 2014, 5 pages.
Bilen et al., U.S. Appl. No. 13/461,388 entitled, Earth-Boring Tools Having Cutting Elements with Cutting Faces Exhibiting Multiple Coefficients of Friction, and Related Methods, filed May 1, 2012.
Bilen et al., U.S. Appl. No. 61/596,433 entitled, Shaped Cutting Elements for Earth-Boring Tools, Earth-Boring Tools Including Such Cutting Elements, and Related Methods, filed Feb. 8, 2013.
Center. (n.d) The American Heritage Dictionary of the English Language, Fourth Edition. (2003). Retrieved Nov. 9, 2012 from http://www.thefreedictionary.com/center.
Chakraborty, U.S. Appl. No. 61/324,142 entitled, Method of Preparing Polycrystalline Diamond from Derivatized Nanodiamond, filed Apr. 14, 2010.
Clebosky et al., U.S. Appl. No. 13/312,576 entitled, Cutting Structures, Earth-Boring Tools Including Such Cutting Structures, and Related methods, filed Dec. 6, 2011.
Digiovanni et al., U.S. Appl. No. 13/472,377 entitled, Cutting Elements for Earth-Boring Tools, Earth-Boring Tools Including Such Cutting Elements and Related Methods, filed May 15, 2012.
Digiovanni et al., U.S. Appl. No. 13/477,905 entitled, Cutting Elements for Earth-Boring Tools, Earth-Boring Tools Including Such Cutting Elemeents, and Related Methods, filed May 22, 2012.
Vempati et al., U.S. Appl. No. 13/617,604 entitled, Methods of Attaching a Polycrystalline Diamond Compact to a Substrate and Cutting Elements Formed Using Such Methods, filed Sep. 14, 2012.
Digiovanni, Anthony A., U.S. Appl. No. 13/610,123 entitled, Sensor-Enabled Cutting Elements for Earth-Boring Tools, Earth-Boring Tools so Equipped, and Related Methods, filed Sep. 11, 2012.
Digiovanni, U.S. Appl. No. 61/535,772 entitled, Cutting Elements for Earth-Boring Tools, Earth-Boring Tools Including Such Cutting Elements and Related Methods, filed Sep. 16, 2011.
Guilin Color Engineered Diamond Technology (EDT) Co. Ltd., Brochure, Offshore Technology Conference Apr. 30-May 3, 2012.
Guilin Star Diamond Superhard Material Co. Ltd., Brochure, Offshore Technology Conference Apr. 30-May 3, 2012.
Pilkey in Peterson's Stress Concentration Factors (2d ed., Wiley Interscience 1997), in Section 2.6.6, on p. 71 (1997).
Richert et al., U.S. Appl. No. 13/661,605 entitled, Plow-Shaped Cutting Elements for Earth-Boring Tools, Earth-Boring Tools Including Such Cutting Elements, and Related Methods, filed Oct. 26, 2013.
Schwefe et al., U.S. Appl. No. 61/594,768 entitled, Cutting Elements Retention for High Exposure Cutting Elements on Earth Boring Tools, filed Feb. 3, 2012.
Scott, Danny E., U.S. Appl. No. 61/613,846 entitled, Self-Sharpening Cutter with Novel Substrate for Enhanced Performance and Attachment, filed Mar. 21, 2012.
Sumiya et al., Microstructure Features of Polycrystalline Diamond Synthesized Directly from Graphite Under Static High Pressure, Journal of Materials Science, vol. 39 (2004) pp. 445-450.
Sumiya et al., Synthesis of High-Purity Nano-Polycrystalline Diamond and its Characterization, SEI Technical Review, No. 59, Jan. 2005, pp. 52-59.
Related Publications (1)
Number Date Country
20140238753 A1 Aug 2014 US