The present invention relates to a coated cutting insert with a wear-resistant coating scheme that exhibits wear indication and a method of making the same. More specifically, the invention pertains to a coated cutting insert with a wear-resistant coating scheme that exhibits wear indication via visually contrasting colors of an outer wear-indicating coating layer that operatively adheres to an alumina coating layer, as well as a method of making the coated cutting insert.
Milling cutters and other tools used for the removal of material from a workpiece (e.g., machining of a workpiece) sometimes present one or several cutting inserts. Each one of these cutting inserts exhibits a certain tool life so that from time-to-time the operator must replace the used cutting inserts with unused cutting inserts. The operator will make a complete replacement of the cutting insert when it has only one cutting edge. In reference to a cutting insert with multiple cutting edges, the operator will index the cutting insert to expose an unused cutting edge when the engaged cutting edge nears the end of its useful tool life.
It can be detrimental to the overall material removal operation for a used cutting edge to be placed back in service. Thus, it would be advantageous to identify easily a used cutting edge to avoid placing a used cutting edge back in service.
Heretofore, there have been coating schemes for cutting inserts useful to detect the use of a specific cutting edge. In this regard, U.S. Pat. No. 6,682,274 B2 to Vtsch et al. pertains to a coated cutting insert with wear indicating properties wherein the flank or flanks of the cutting insert according to the invention is (are) provided with a wearable indicating layer, having a color that differs from the color of the surface or layer underneath. The wear indicating coating layer does not extend to the cutting edge and is “sensitive enough, so that even a short-term use of the adjacent cutting edge leaves clear traces on the indicating layer.” See Abstract.
European Patent Application No. 1 757 389 A1, which was not published until Feb. 28, 2007 (the PCT equivalent (PCT WO 2006/067956) carries a publication date of Jun. 29, 2006), appears to disclose a coating arrangement on the surface of a cutting tool that comprises four basic layers. The layers are in the following order moving out from the substrate: third layer (next to substrate), first layer, second layer and fourth layer. The first layer is underneath the second layer and comprises titanium boronitride (TiBN) or titanium boron-oxynitride (TiBNO). The second layer is, “ . . . implemented as a single layer or a plurality of layers, by at least one selected from the group consisting of aluminum oxide, zirconium oxide, hafnium oxide and a solid solution mainly including two or more of these components, and the second coating layer is located directly on the first coating layer.” The third layer is between the first layer and the substrate and includes TiC, TiN, TiCN, TiCNO, TiB2, TiBN, TiCBN, ZrC, ZrO2HfC, HfN, TiAIN, AlCrN, CrN, VN, TiSiN, TiSiCN, AlTiCrN, and TiAlCN. The fourth layer is the coating layer that functions as a wear indicating coating layer and can include TiCNO and is removed from the cutting area by blasting.
Kennametal Inc. of Latrobe, Penn. 15650 United States of America makes and sells a commercial prior art coated cutting insert. This prior art coated cutting insert presents a coating scheme as follows: a titanium nitride base coating layer on the substrate, a titanium carbonitride coating layer on the titanium nitride coating layer, a bonding layer that includes Ti, Al, O, C and N on the titanium carbonitride coating layer and an alpha-alumina coating layer on the bonding layer. During the manufacture of the prior art cutting insert, a titanium nitride/titanium carbonitride coating layer is applied to the alpha-alumina coating layer and then removed by blasting whereby the alpha-alumina coating layer experiences reduced tensile residual stress or compressive residual stress.
U.S. Pat. No. 7,153,562 to Rodmar et al. pertains to a coated cutting insert that includes a TiCON layer and wherein the titanium carbonitride is the outer coating layer.
U.S. Pat. No. 6,472,060 to Ruppi et al., as well as related issued U.S. Pat. No. 6,620,498 to Ruppi et al. and U.S. Pat. No. 6,652,913 to Ruppi et al., pertains to a coated cutting insert that includes in the coating scheme a nanocrystalline coating of Ti(C,N,O) applied via a MTCVD process at a temperature that ranges between 700-900° C. See Column 2, lines 36-45.
U.S. Pat. No. 6,015,614 to Ruppi pertains to a multi-layer coating scheme for a cutting insert wherein the process includes a post-coating blasting treatment. The '614 Patent appears to show an α-Al2O3 layer with a bonding layer ((Ti,Al)(C,O,N) thereon, as well as a single or multiple layer TiN scheme on the bonding layer. See Examples Nos. 9 and 10 in Table 3. The multiple layer TiN scheme comprises alternating layers of TiN and TiC. See Example No. 8 in Table 3. The '614 patent includes the step of blasting the surface of the coated insert using Al2O3 particles (320 mesh, medium grain size 30 μm). See Col. 3, line 66 through Col. 4, line 3.
U.S. Pat. No. 7,192,637 to Ruppi et al. pertains to disclose a multi-layer coating scheme for a cutting insert. The '637 Patent appears to show an α-Al2O3 layer with a bonding layer of Ti(C,O,N) (or Ti(C,N) [see Col. 2, lines 37-47]) thereon, as well as a TiN layer on the bonding layer. See Col. 4, lines 31-44. There is a TiCN/TiN coating scheme on the α-Al2O3 layer. See Col. 5, lines 1-3.
U.S. Pat. No. 6,379,798 to Yazaki appears to show an inner Al2O3 layer with a titanium carbonitroxide outermost layer. See Col. 3, lines 8-20. The outermost layer comes off when subjected to mechanical stress to provide wear-indicating properties via color differentiation. See Col. 2, lines 9-38. Along this line, U.S. Pat. No. 7,097,901 to Larsson et al. appears to disclose a layer of TiCxNyOz on an Al2O3 layer (see Col. 4, lines 55-59), and U.S. Pat. No. 7,132,153 to Zackrisson et al. appears to disclose a layer of TiCxNyOz on an Al2O3 layer (see Col. 4, lines 56-59).
U.S. Patent Application Publication No. US 2006/0177584 to Gates, Jr., et al. (assigned to the assignee of the present patent application) includes a disclosure of the coating combination of TiAlOCN/TiOCN. See Table 8 (Inventive Heat No. 9). However, this bonding arrangement is below the alumina layer so that the TiAlOCN/TiOCN coating scheme is a part of a modification scheme that is between the outer alumina coating and the inner TiCN coating layer.
U.S. Patent Application Publication No. US 2007/0128469 to Okada et al. presents a general description of the coating scheme that comprises a base coating, an intermediate coating and an outermost coating. In this regard, Paragraphs [0013]-[0021] read in part:
The outermost layer may be removed by wet blasting.]
The '469 Okada et al. publication also appears to present variations of wet blasting to remove a portion of the coating from the as-coated cutting insert. See Paragraphs [0029]-[0033].
U.S. Pat. No. 5,372,873 to Yoshimura et al. discloses the benefits of shot peening a coated cutting insert. The shot peening can convert tensile stresses to compressive stresses. The shot peening can be localized so selected surfaces exhibit selected stress conditions. See Col. 6, lines 32-52. The relevant coating scheme comprises alumina that has a titanium carbonitride layer thereon, which in turn, has a titanium nitride layer thereon. See Col. 8, lines 4-10; Tests 5-8 and 13-16 in Table 2. The '873 Patent is technically along the lines of the following patents: U.S. Pat. No. 5,576,093 to Yoshimura et al., U.S. Pat. No. 5,374,471 to Yoshimura et al., and U.S. Pat. No. 5,681,651 to Yoshimura et al.
U.S. Pat. No. 6,884,496 to Westphal et al. discloses the basic benefits of dry blasting a coated cutting insert wherein there is an increase in the compressive stress. See Col. 2, lines 42-67. U.S. Pat. No. 4,674,365 to Reed discloses a mechanical treatment. U.S. Pat. No. 5,861,210 to Lenander et al., which discloses a TiCxNyOz layer on alumina (see Col. 2, lines 30-43), discloses that it is known to vary the blasting parameters (see Example 1, Col. 4, line 48 through Col. 5, line 11) to achieve different results.
United States Patent Application Publication No. US2006/0257690 to Bjormander (European Patent Application No. 1 717 348 A2 is the European counterpart) pertains to a coated cutting tool insert wherein the post-treatment (preferably blasting or brushing) removes the outermost coating layer on the edge-line and on the rake face.
In one form thereof, the invention is a coated cutting insert for use in a chip-forming material removal operation wherein the coated cutting insert comprises a substrate that has a flank surface and a rake surface wherein the flank surface intersects the rake surface to form a cutting edge at the intersection. There is a wear-resistant coating scheme that adheres to at least a portion of the substrate. The wear-resistant coating scheme comprises one or more coating layers of one or more of alumina, hafnia and zirconia. There is a wear indicating coating that adheres to at least a portion of the wear-resistant coating scheme. The wear indicating coating comprises M(OxCyNz) wherein M is selected from the group comprising one or more of the following titanium, hafnium, zirconium, chromium, titanium-aluminum alloy, hafnium-aluminum alloy, zirconium-aluminum alloy, chromium-aluminum alloy, and their alloys, and x>0, y≧0, z≧0 and y+z>0.
In another form thereof, the invention is a coated cutting insert for use in a chip-forming material removal operation. The coated cutting insert comprises a substrate that has a flank surface and a rake surface wherein the flank surface intersects the rake surface to form a cutting edge at the intersection. A wear-resistant coating scheme adheres to at least a portion of the substrate wherein the wear-resistant coating scheme comprises one or more coating layers of one or more of alumina, hafnia and zirconia, and the wear-resistant coating scheme exhibiting compressive residual stress. A wear indicating coating adheres to at least a portion of the wear-resistant coating scheme. The wear indicating coating comprises M(OxCyNz) wherein M is selected from the group comprising one or more of the following titanium, hafnium, zirconium, chromium, titanium-aluminum alloy, hafnium-aluminum alloy, zirconium-aluminum alloy, chromium-aluminum alloy, and their alloys, and x>0, y≧0, z≧0 and y+z>0. After use, the wear indicating coating exhibits a visually perceivable color indication of usage.
In yet another form thereof, the invention is a coated cutting insert for use in a chip-forming material removal operation. The coated cutting insert comprises a substrate that has a flank surface and a rake surface wherein the flank surface intersects the rake surface to form a cutting edge at the intersection. There is a wear-resistant coating scheme adhering to at least a portion of the substrate wherein the wear-resistant coating scheme comprises one or more coating layers of one or more of alumina, hafnia and zirconia. There is a first wear indicating coating adhering to at least a portion of the wear-resistant coating scheme on the rake surface wherein the first wear indicating coating has a first visually perceivable color. There is a second wear indicating coating adhering to at least a portion of the wear-resistant coating scheme on the flank surface wherein the second wear indicating coating has a second visually perceivable color.
In still another form thereof, the invention is a method of making a cutting insert with wear indicating comprising the steps of: providing a substrate with an outer alumina coating layer; applying an as-deposited non-wear indicating coating layer to the alumina coating layer; and treating the non-wear indicating coating layer to convert it to a wear indicating coating layer.
In still another form thereof, the invention is a method of making a cutting insert with wear indicating coating comprising the steps of: providing a substrate with an outer alumina coating layer; applying a wear indicating coating scheme to the alumina coating layer wherein the wear-indicating coating scheme has an outermost wear-indicating coating layer having a first thickness; and treating the wear indicating coating scheme so as to partially remove the outermost wear-indicating coating layer whereby the outermost wear-indicating coating layer is of a second thickness, and the first thickness being greater than the second thickness.
The following is a brief description of the drawings that form a part of this patent application:
Referring to
As mentioned above, the invention pertains to a coated cutting insert 20 with a wear-resistant coating scheme that exhibits wear indication via visually contrasting colors of an outer wear-indicating coating layer that operatively adheres to an alumina coating layer. A comparison of the rake surfaces of the coated cutting inserts illustrated in
The substrates can be made from cemented carbides, carbides, ceramics and cermets. A typical cemented carbide is a cemented (cobalt) tungsten carbide wherein the cobalt content ranges between about 0.2 weight percent and about 15 weight percent. In the case of a cemented (cobalt) tungsten carbide, some of the substrates may exhibit a zone of binder enrichment beginning at and extending inwardly from the surface of the substrate. The cemented carbide substrate may also have the following elements and/or their compounds: titanium, niobium, vanadium, tantalum, chromium, zirconium and/or hafnium. When the substrate is a carbide, there is an absence of a binder alloy (e.g., cobalt).
The ceramic substrates include silicon nitride-based ceramics, SiAlON-based ceramics, titanium carbonitride-based ceramics, titanium diboride-based ceramics, alumina-based ceramics, and aluminum oxynitride-based ceramics. Cermets substrates include cermets that have nickel-cobalt binder and a high level of titanium and could further include tungsten carbide, titanium carbide, and nitrogen.
In regard to the specific embodiment of
In reference to the inventive coating, a coating interlayer of titanium aluminum oxycarbonitride 54 is applied by CVD to the surface of the alpha-alumina coating layer 52. The coating interlayer 54 is of a thickness that ranges between greater than 0 micrometers and about 3 micrometers with an alternate range being greater than 0 micrometers and about 1 micrometer.
The outer coating layer of titanium oxycarbonitride 56, which also includes a base portion of titanium carbonitride to provide a base for the nucleation of the outer coating layer of titanium carbonitride, is applied by CVD to the surface of the coating interlayer 54. The titanium oxycarbonitride (TiOxCyNz wherein x>0, y>0 and z>0) coating layer 56 is of a thickness that ranges between about 0.1 micrometers and about 3 micrometers with an alternate range being between about 0.5 micrometers and about 2 micrometers.
In the above description, the alpha-alumina coating layer may be a wear-resistant coating scheme which may comprise one or more layers. In this regard, the wear-resistant coating scheme can comprise one or more coating layers of one or more of alumina, hafnia and zirconia, and the wear-resistant coating scheme exhibiting compressive residual stress wherein one range of the compressive residual stress is between about 100 MPa and about 2000 MPa and an alternate range of compressive residual stress is between about 200 MPa and about 1000 MPa.
In the above description, the outer coating layer is titanium oxycarbonitride. There should be an appreciation that the outer coating layer (or wear indicating coating layer) can comprise M(OxCyNz) wherein M is selected from the group comprising one or more of the following titanium, hafnium, zirconium, chromium, titanium-aluminum alloy, hafnium-aluminum alloy, zirconium-aluminum alloy, chromium-aluminum alloy, and their alloys, and x>0, y≧0, z≧0 and y+z>0. When aluminum is present in the “M” component of the wear indicating layer, it is in combination with another one or more of the other elements (i.e., titanium, hafnium, zirconium, chromium). There should be an appreciation that the outer coating layer can include titanium oxycarbide, titanium oxynitride, titanium aluminum oxycarbide, or titanium aluminum oxynitride.
Finally, a light gray outer coating layer of titanium oxycarbonitride, which also includes a base layer of titanium carbonitride as a base for nucleation of the titanium oxycarbonitride, is on the titanium aluminum carbo-oxynitride interlayer.
As shown in
In addition to smoothing the surface of the outer coating layer, the blasting treatment converts the as-deposited outer coating layer from a coating layer not suitable to be a wear indicating layer into a coating layer that is suitable to be a wear indicating coating layer. The blasting the surface of the outer coating layer resulted in a change in the color of the coating layer from a black or dark red (i.e., a dark color) to a bronze (i.e., a lighter color). There should be an appreciation that a coating layer with a dark color is unsuitable as a wear indicating layer and a coating layer with a lighter color is suitable as a wear indicating coating layer. When the outer coating layer is a lighter color, it is able to provide an indication of wear through any one or more of the following mechanisms that occur during use: discoloration of the cutting insert, build-up of the workpiece material on the cutting insert, or the removal of the outer coating layer to expose the alumina coating layer which has a visually perceivable color contrast with the outer coating layer.
Still another result of blasting is the reduction of the tensile residual stress levels in the alumina coating layer from the levels extant in the as-deposited alumina coating layer. The reduction can be such to reduce the amount of tensile residual stress wherein the stress remains tensile or it can be such to reduce the residual stresses into being compressive residual stress.
In reference to the impact of the use of the post-coating blasting treatment to reduce the residual stresses present in the alumina coating layer after coating,
As shown by
The XRD residual stress in the alumina coating layer was measured by a Psi tilt method and the reflection (024) in the alumina coating layer was chosen for the measurement. Psi tilts of 0, 33.9, 52.1 and 75 degrees were selected for the measurement of the residual stress levels. Positive and negative Psi tilts were chosen to supply the data required to determine possible shear stresses. Additionally, three Phi rotation angles were selected (0, 45, and 90) to provide the data required to determine the biaxial stress state of the material.
Biaxial stress calculations were completed using the following equation:
where:
Cutting tests were conducted to compare the inventive coated cutting inserts against the prior art cutting inserts. The inventive cutting inserts in these tests were made according to the process set forth in Table 1. The prior art cutting insert exhibited a coating scheme like that of the inventive samples, except that the outer layer of the prior art cutting inserts comprised alpha-alumina that had been blasted to reduce the residual to compressive residual stress. Prior to the blasting of the prior art cutting inserts, the alumina coating layer was covered by a TiN/TiCN layer. However, the blasting removed the TiN/TiCN layer to expose the alumina coating layer as the black outer layer.
The substrates for both the prior art cutting inserts and the inventive cutting inserts comprised cemented (cobalt) tungsten carbide with the following approximate composition: 1.8 weight percent tantalum, 0.4 weight percent titanium, 0.3 weight percent niobium, 6 weight percent cobalt and the balance tungsten carbide and recognized impurities.
In reference to the metalcutting tests, the parameters of test were as follows:
The failure criteria were: flank wear, nose wear and depth of cut notching (DOCN) equal to 0.012 inches (0.0305 millimeters). For these tests, the failure mode was depth of cut notching and flank wear. The test results are set out in Table 2 and Table 3.
Table 2 and Table 3 indicate that the cutting insert of the invention shows similar tool life on the average with the prior art cutting insert. However, The cutting insert of the invention possesses better edge identification ability compared to prior art cutting insert.
One should appreciate that in certain circumstances, there are advantages extant due to the rake surface being of a different visually perceivable color than the flank surface(s) of the coated cutting insert. Typically, this is due to a difference in the composition of the coating at the respective surface of the coated cutting insert. Advantages connected with difference in the visually perceivable color include, without limitation, cosmetic appeal of the cutting insert, ability to provide for visual grade identification, and the ability to provide for different surface roughness and internal stress associated with different compositions, which one can engineer to suit different applications.
Different techniques can be useful to make a coated cutting insert in which there is a difference in the composition between the rake surface and the flank surface(s). The specific coated cutting insert of
Referring to
As shown in
Referring to
On top of the underlayer coating arrangement is an alumina coating layer (designated as ALUMINA in
A titanium oxycarbonitride coating layer (designated as TITANIUM OXYCARBONITRIDE in
It is apparent that the coated cutting insert 200 has different visually perceivable colors on the rake surface and the flank surface(s). The difference is due to the mechanical treatment via blasting of the rake surface to remove the titanium carbonitride coating layer/titanium nitride coating layer to expose the titanium oxycarbonitride. The titanium nitride has a gold color in contrast to the titanium oxycarbonitride, which has a bronze color. One can characterize the wear indicating coating as comprising M2(N) wherein M2 is selected from the group comprising one or more of the following titanium, hafnium, zirconium, chromium, titanium-aluminum alloy, hafnium-aluminum alloy, zirconium-aluminum alloy, chromium-aluminum alloy, and their alloys.
The coating scheme 222 includes a CVD underlayer coating arrangement (designated as UNDERLAYERS in
A CVD titanium aluminum oxycarbonitride coating layer (designated as TITANIUM ALUMINUM OXYCARBONITRIDE in
A CVD titanium carbonitride coating layer (designated as TITANIUM CARBONITRIDE in
In some situations, a surface of the coated cutting insert is not subjected to a surface treatment. As mentioned above, this is the case for the coating scheme as illustrated in
On top of the underlayer coating arrangement is a CVD alumina coating layer (designated as ALUMINA in
A CVD titanium aluminum oxycarbonitride coating layer (designated as TITANIUM ALUMINUM OXYCARBONITRIDE in
A CVD titanium carbonitride coating layer (designated as TITANIUM CARBONITRIDE in
In comparing the thickness of the titanium nitride coating layer of the embodiments of
It can be appreciated that the present invention provides an improved coating cutting insert with wear (or usage) indication properties. These properties utilize a color contrast on the wear indicating coating layer, which in the unused condition presents substantially uniform or consistent visual appearance. However, if during usage the wear indicating coating layer is removed to expose the underlying wear-resistant coating layer (e.g., an alumina coating layer), there is a visually perceivable color contrast between the top coating layer and the alumina coating layer to indicate usage or wear. The top coating layer may also visually indicate usage through discoloration caused by thermal oxidation wherein there is a contrast in color between the oxidized top coating layer and the non-oxidized top coating layer. The top coating layer may also visually indicate usage through adherence or build-up of workpiece material on the cutting insert wherein there is a color contrast between the built-up workpiece material and the top coating layer. The operator can thus look at the cutting insert and discern the used cutting edge(s) from the unused cutting edge(s).
Further, the present invention provides such a cutting insert that exhibits a smooth surface. In addition, the present invention provides a cutting insert that enhances useful tool life, as well as has both wear indication properties and a smooth surface.
All patents, patent applications, articles and other documents identified herein are hereby incorporated by reference herein. Other embodiments of the invention may be apparent to those skilled in the art from a consideration of the specification or the practice of the invention disclosed herein. It is intended that the specification and any examples set forth herein be considered as illustrative only, with the true spirit and scope of the invention being indicated by the following claims.
This patent application is a continuation-in-part of earlier-filed and co-pending U.S. patent application Ser. No 11/823,679 filed on Jun. 28, 2007 by Zhigang Ban, Mark J. Rowe, Yixiong Liu, and Alfred S. Gates, Jr. for a CUTTING INSERT WITH A WEAR-RESISTANT COATING SCHEME EXHIBITING WEAR INDICATION AND METHOD OF MAKING THE SAME. Applicants (Zhigang Ban, Mark J. Rowe, Yixiong Liu, Alfred S. Gates, Jr., Kent P. Mizgalski and Mark S. Greenfield) claim under the United States Patent Statute (Title 35, United States Code) including 35 U.S.C. §120 the benefit of the filing date of such earlier parent patent application (Ser. No. 11/823,679).
Number | Name | Date | Kind |
---|---|---|---|
3793627 | Darrell et al. | Feb 1974 | A |
4420253 | Pryor | Dec 1983 | A |
4674365 | Reed | Jun 1987 | A |
4714660 | Gates, Jr. | Dec 1987 | A |
4818153 | Strandell et al. | Apr 1989 | A |
4831365 | Thomas et al. | May 1989 | A |
4886009 | Gondar et al. | Dec 1989 | A |
4984940 | Bryant et al. | Jan 1991 | A |
5000036 | Yellowley et al. | Mar 1991 | A |
5059905 | Drits | Oct 1991 | A |
5071696 | Chatfield et al. | Dec 1991 | A |
5192578 | Ramm et al. | Mar 1993 | A |
5226929 | Carmichael et al. | Jul 1993 | A |
5228478 | Kleisle | Jul 1993 | A |
5303574 | Matossian et al. | Apr 1994 | A |
5372873 | Yoshimura et al. | Dec 1994 | A |
5374471 | Yoshimura et al. | Dec 1994 | A |
5442981 | Vegh | Aug 1995 | A |
5487625 | Ljungberg et al. | Jan 1996 | A |
5543176 | Chatfield et al. | Aug 1996 | A |
5576093 | Yoshimura et al. | Nov 1996 | A |
5597272 | Moriguchi et al. | Jan 1997 | A |
5603161 | Welsh | Feb 1997 | A |
5635247 | Ruppi | Jun 1997 | A |
5652045 | Nakamura et al. | Jul 1997 | A |
5674564 | Ljungberg et al. | Oct 1997 | A |
5681651 | Yoshimura et al. | Oct 1997 | A |
5700551 | Kukino et al. | Dec 1997 | A |
5700569 | Ruppi | Dec 1997 | A |
5702808 | Ljungberg | Dec 1997 | A |
5766782 | Ljungberg et al. | Jun 1998 | A |
5776588 | Moriguchi et al. | Jul 1998 | A |
5851687 | Ljungberg et al. | Dec 1998 | A |
5861210 | Lenander et al. | Jan 1999 | A |
5863640 | Ljungberg et al. | Jan 1999 | A |
5906834 | Tseng | May 1999 | A |
5912051 | Olsson et al. | Jun 1999 | A |
5945207 | Kutscher et al. | Aug 1999 | A |
5968595 | Kutscher | Oct 1999 | A |
6007909 | Rolander et al. | Dec 1999 | A |
6015614 | Ruppi | Jan 2000 | A |
6090476 | Thysell et al. | Jul 2000 | A |
6177178 | Ostlund et al. | Jan 2001 | B1 |
6293739 | Uchino et al. | Sep 2001 | B1 |
6309738 | Sakurai | Oct 2001 | B1 |
6333098 | Olsson et al. | Dec 2001 | B1 |
6333103 | Ishii et al. | Dec 2001 | B1 |
6344265 | Blomstedt et al. | Feb 2002 | B1 |
6350510 | Konig et al. | Feb 2002 | B1 |
6379798 | Yazaki | Apr 2002 | B1 |
6406224 | Ostlund et al. | Jun 2002 | B1 |
6449998 | Takeda et al. | Sep 2002 | B1 |
6457566 | Toby | Oct 2002 | B1 |
6472060 | Ruppi | Oct 2002 | B1 |
6599062 | Oles et al. | Jul 2003 | B1 |
6620498 | Ruppi et al. | Sep 2003 | B2 |
6627335 | Kodama et al. | Sep 2003 | B2 |
6652913 | Ruppi et al. | Nov 2003 | B2 |
6662570 | Prevey, III | Dec 2003 | B2 |
6682274 | Votsch | Jan 2004 | B2 |
6713172 | Ljungberg et al. | Mar 2004 | B2 |
6730392 | Vetter et al. | May 2004 | B2 |
6794064 | Vetter | Sep 2004 | B2 |
6824823 | Kodama et al. | Nov 2004 | B2 |
6869668 | Nartensson | Mar 2005 | B2 |
6884386 | Saka et al. | Apr 2005 | B2 |
6884496 | Westphal | Apr 2005 | B2 |
7021872 | Hauptmann | Apr 2006 | B2 |
7033643 | Sugita | Apr 2006 | B2 |
7067203 | Joelsson et al. | Jun 2006 | B2 |
7090914 | Yamagata et al. | Aug 2006 | B2 |
7097901 | Larsson et al. | Aug 2006 | B2 |
7132153 | Zackrisson et al. | Nov 2006 | B2 |
7135221 | Ruppi | Nov 2006 | B2 |
7150772 | Larsson et al. | Dec 2006 | B2 |
7153562 | Rodmar et al. | Dec 2006 | B2 |
7159425 | Prevey et al. | Jan 2007 | B2 |
7163735 | Ruppi | Jan 2007 | B2 |
7169485 | Kohara et al. | Jan 2007 | B2 |
7192637 | Ruppi et al. | Mar 2007 | B2 |
7192660 | Ruppi | Mar 2007 | B2 |
7226670 | Derflinger et al. | Jun 2007 | B2 |
7232603 | Hessman | Jun 2007 | B2 |
RE39884 | Ostlund et al. | Oct 2007 | E |
RE39912 | Nordgren et al. | Nov 2007 | E |
RE39986 | Reineck et al. | Jan 2008 | E |
RE39987 | Ljungberg et al. | Jan 2008 | E |
RE40005 | Kutscher et al. | Jan 2008 | E |
RE40026 | Waldenstrom et al. | Jan 2008 | E |
RE40082 | Nordgren et al. | Feb 2008 | E |
7655293 | Ljungberg | Feb 2010 | B2 |
20020187370 | Yamagata et al. | Dec 2002 | A1 |
20050202283 | Gates et al. | Sep 2005 | A1 |
20060147755 | Hessman | Jul 2006 | A1 |
20060257690 | Bjormander | Nov 2006 | A1 |
20070009763 | Littecke et al. | Jan 2007 | A1 |
20070134517 | Martensson et al. | Jun 2007 | A1 |
20070148497 | Sundstrom et al. | Jun 2007 | A1 |
20070292672 | Ljungberg et al. | Dec 2007 | A1 |
20070298230 | Omori et al. | Dec 2007 | A1 |
20070298281 | Andersson et al. | Dec 2007 | A1 |
20070298282 | Andersson et al. | Dec 2007 | A1 |
20080028684 | Schier | Feb 2008 | A1 |
20080107882 | Littecke et al. | May 2008 | A1 |
Number | Date | Country |
---|---|---|
0596619 | May 1994 | EP |
1717348 | Nov 1996 | EP |
1201386 | Jan 2004 | EP |
1734155 | Dec 2006 | EP |
1757389 | Feb 2007 | EP |
2006059551 | Jun 2006 | WO |
Number | Date | Country | |
---|---|---|---|
20090004440 A1 | Jan 2009 | US |
Number | Date | Country | |
---|---|---|---|
Parent | 11823679 | Jun 2007 | US |
Child | 12057564 | US |