Claims
- 1. A process for the preparation of block copolymers of vinyl-substituted aromatic compounds and conjugated dienes of broadened molecular weight distribution comprising:
- (a) polymerizing vinyl-substituted aromatic compounds in the presence of initiator selected from organoalkali metal or organomagnesium initiators until the consumption of monomer is substantially complete,
- (b) adding one or more conjugated diene monomers and polymerizing until substantially complete conversion of monomer(s) to polymer has taken place, and
- (c) reacting the resulting block copolymer from said steps (a) and (b) by ring-opening coupling with a compound of the general formula: ##STR15## wherein, Z is a 1,2-phenylene, 1,2-cyclohexylene, or ##STR16## grouping wherein n=0 or 1 and R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 are the same or different and are selected from hydrogen or a hydrocarbyl group containing 1 to 12 carbon atoms and A, B and Y are oxygen or sulfur and X is carbon or sulfur, with the stipulation that when X is sulfur, Y must be oxygen, in an amount of from 0.2 to 3 moles of compound per mole of said organoalkali metal or organomagnesium initiator.
- 2. The process according to claim 1, wherein in the first step (a) the monomer is selected from the group consisting of styrene, .alpha.-methylstyrene, p-isopropyl .alpha.-methylstyrene, vinyl toluene, chlorostyrene, 1-vinylnaphthalene, 2-vinylnaphthalene, and the initiator is an organolithium or organosodium compound and in the second step (b) the diene monomer is selected from the group consisting of 1,3-butadiene, isoprene, piperylene, 2-ethyl-1,3-butadiene, and 2,3-dimethylbutadiene.
- 3. The process according to claim 1, wherein in the first step (a) the initiator is an organolithium compound and in the third step (c) the coupling agent is selected from the group consisting of ethylene carbonate, propylene carbonate, O,O-ethylene monothiocarbonate, O,S-ethylene monothiocarbonate, O,S-ethylene dithiocarbonate, S,S-ethylene dithiocarbonate, ethylene trithiocarbonate, ethylene sulfite, propylene sulfite, o-phenylene carbonate, 1,2-cyclohexylene carbonate, 1,2-cyclohexylene sulfite, and o-phenylene sulfite.
- 4. A process according to claim 1 wherein the organolithium initiator is selected from the group consisting of n-butyllithium, sec-butyllithium, phenyllithium, 1,4-dilithio-1,1,4,4-tetraphenylbutane, 1,4-dilithio-1,4-dimethyl-2-butene, DiLi-1 and DiLi-3.
- 5. The process according to claim 3 wherein the organolithium initiator is selected from the group consisting of n-butyllithium, sec-butyllithium, phenyllithium, 1,4-dilithio-1,1,4,4-tetraphenylbutane, 1,4-dilithio-1,4-dimethyl-2-butene, DiLi-1 and DiLi-3.
- 6. The process of claim 1, wherein the vinyl-substituted monomer is styrene, the conjugated diene is butadiene, the polymerization initiator is an organolithium compound, and the coupling agent is selected from the group consisting of ethylene carbonate, O,O-ethylene monothiocarbonate, O,S-ethylene monothiocarbonate, O,S-ethylene dithiocarbonate, S,S-ethylene dithiocarbonate, o-phenylene carbonate, 1,2-cyclohexylene carbonate, ethylene trithiocarbonate, ethylene sulfite, 1,2-cyclohexylene sulfite, o-phenylene sulfite and propylene carbonate.
- 7. Block copolymers of vinyl-substituted aromatic compounds and conjugated dienes of broadened molecular weight distribution prepared by:
- (a) polymerizing a vinyl-substituted aromatic compound in the presence of an initiator selected from organoalkali metal or organomagnesium initiators until the consumption of monomer is substantially complete,
- (b) adding one or more conjugated diene monomers and polymerizing until substantially complete conversion of monomer(s) to polymer has taken place, and
- (c) reacting the resulting block copolymer from said steps (a) and (b) by ring-opening coupling with a compound of the general formula: ##STR17## wherein, Z is a 1,2-phenylene, 1,2-cyclohexylene, or ##STR18## grouping wherein n=0 or 1 and R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 are the same or different and are selected from hydrogen or a hydrocarbyl group containing 1 to 12 carbon atoms and A, B and Y are oxygen or sulfur and X is carbon or sulfur with the stipulation that when X is sulfur, Y must be oxygen, in an amount of from 0.2 to 3 moles of compound per mole of said organoalkali metal or organomagnesium initiator.
- 8. Block copolymers according to claim 7 wherein in the first step (a) the monomer is selected from the group consisting of styrene, .alpha.-methylstyrene, p-isopropyl .alpha.-methylstyrene, vinyltoluene, chlorostyrene, 1-vinylnaphthalene, 2-vinylnaphthalene, and the initiator is an organolithium or organosodium compound and in the second step (b) the diene monomer is selected from the group consisting of 1,3-butadiene, isoprene, piperylene, 2-ethyl-1,3-butadiene, and 2,3-dimethylbutadiene.
- 9. Block copolymers according to claim 7 wherein in the first step (a) the initiator is an organolithium compound and in the third step (c) the coupling agent is selected from the group consisting of ethylene carbonate, propylene carbonate, O,S-ethylene monothiocarbonate, O,S-ethylene dithiocarbonate, S,S-ethylene dithiocarbonate, ethylene trithiocarbonate, O,O-ethylene monothiocarbonate, ethylene sulfite, propylene sulfite, o-phenylene carbonate, 1,2-cyclohexylene carbonate, 1,2-cyclohexylene sulfite and o-phenylene sulfite.
- 10. Block copolymers according to claim 7, wherein the vinyl-substituted monomer is styrene, the conjugated diene is butadiene, the polymerization initiator is an organolithium compound, and the coupling agent is selected from the group consisting of ethylene carbonate, o-phenylene carbonate, 1,2-cyclohexylene carbonate, O,O-ethylene monothiocarbonate, O,S-ethylene monothiocarbonate, O,S-ethylene dithiocarbonate, S,S-ethylene dithiocarbonate, ethylene trithiocarbonate, ethylene sulfite, 1,2-cyclohexylene sulfite, o-phenylene sulfite and propylene carbonate.
Parent Case Info
This is a division, of application Ser. No. 153,121 filed May 27, 1980 now U.S. Pat. No. 4,301,258.
US Referenced Citations (9)
Foreign Referenced Citations (1)
Number |
Date |
Country |
992210 |
May 1965 |
GBX |
Divisions (1)
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Number |
Date |
Country |
Parent |
153121 |
May 1980 |
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