This invention relates to drill bits, specifically drill bit assemblies for use in oil, gas and geothermal drilling. More particularly, the invention relates to cutting elements in drill bits comprised of a carbide substrate with an abrasion resistant layer of superhard material.
Such cutting elements are often subjected to intense forces, torques, vibration, high temperatures and temperature differentials during operation. As a result, stresses within the structure may begin to form. Drag bits for example may exhibit stresses aggravated by drilling anomalies during well boring operations such as bit whirl or bounce often resulting in spalling, delamination or fracture of the superhard abrasive layer or the substrate thereby reducing or eliminating the cutting elements efficacy and decreasing overall drill bit wear life. The superhard material layer of a cutting element sometimes delaminates from the carbide substrate after the sintering process as well as during percussive and abrasive use. Damage typically found in drag bits may be a result of shear failures, although non-shear modes of failure are not uncommon. The interface between the super hard material layer and substrate is particularly susceptible to non-shear failure modes due to inherent residual stresses.
U.S. Pat. No. 6,332,503 by Pessier et al, which is herein incorporated by reference for all that it contains, discloses an array of chisel-shaped cutting elements are mounted to the face of a fixed cutter bit. Each cutting element has a crest and an axis which is inclined relative to the borehole bottom. The chisel-shaped cutting elements may be arranged on a selected portion of the bit, such as the center of the bit, or across the entire cutting surface. In addition, the crest on the cutting elements may be oriented generally parallel or perpendicular to the borehole bottom.
U.S. Pat. No. 6,408,959 by Bertagnolli et al., which is herein incorporated by reference for all that it contains, discloses a cutting element, insert or compact which is provided for use with drills used in the drilling and boring of subterranean formations.
U.S. Pat. No. 6,484,826 by Anderson et al., which is herein incorporated by reference for all that it contains, discloses enhanced inserts formed having a cylindrical grip and a protrusion extending from the grip.
U.S. Pat. No. 5,848,657 by Flood et al, which is herein incorporated by reference for all that it contains, discloses domed polycrystalline diamond cutting element wherein a hemispherical diamond layer is bonded to a tungsten carbide substrate, commonly referred to as a tungsten carbide stud. Broadly, the inventive cutting element includes a metal carbide stud having a proximal end adapted to be placed into a drill bit and a distal end portion. A layer of cutting polycrystalline abrasive material disposed over said distal end portion such that an annulus of metal carbide adjacent and above said drill bit is not covered by said abrasive material layer.
U.S. Pat. No. 4,109,737 by Bovenkerk which is herein incorporated by reference for all that it contains, discloses a rotary bit for rock drilling comprising a plurality of cutting elements mounted by interence-fit in recesses in the crown of the drill bit. Each cutting element comprises an elongated pin with a thin layer of polycrystalline diamond bonded to the free end of the pin.
US patent Application Ser. No. 2001/0004946 by Jensen, although now abandoned, is herein incorporated by reference for all that it discloses. Jensen teaches that a cutting element or insert with improved wear characteristics while maximizing the manufacturability and cost effectiveness of the insert. This insert employs a superabrasive diamond layer of increased depth and by making use of a diamond layer surface that is generally convex.
In one aspect of the invention, a degradation assembly has a working portion with at least one impact tip brazed to a carbide extension. The carbide extension has a cavity formed in a base end and is adapted to interlock with a shank assembly of the cutting element assembly. The shank assembly has a locking mechanism adapted to interlock a first end of the shank assembly within the cavity. The locking mechanism has a radially extending catch formed in the first end of the shank assembly. The shank assembly has an outer surface at a second end of the shank assembly adapted to be press-fitted within a recess of a driving mechanism. The outer surface of the shank assembly has a coefficient of thermal expansion of 110 percent or more than a coefficient of thermal expansion of a material of the driving mechanism.
The cavity may have an inwardly protruding catch. The inwardly protruding catch may be adapted to interlock with the radially extending catch. An insert may be intermediate the inwardly protruding catch and the radially extending catch. The insert may be a ring, a snap ring, a split ring, or a flexible ring. The insert may also be a plurality of balls, wedges, shims or combinations thereof. The insert may be a spring.
The locking mechanism may have a locking shaft extending from the first end of the shank assembly towards the second end of the shank assembly. The locking mechanism of the shank assembly may be mechanically connected to the outer surface of the shank assembly. Mechanically connecting the locking mechanism to the outer surface may apply tension along a length of the locking shaft. The locking mechanism may have a coefficient of thermal expansion equal to or less than the coefficient of thermal expansion of the outer surface. The shank assembly may comprise steel.
The tip may comprise a superhard material bonded to a cemented metal carbide substrate at a non-planar interface. The cemented metal carbide substrate may be brazed to the carbide extension. The cemented metal carbide substrate may have the same coefficient of thermal expansion as the carbide extension. The cemented metal carbide substrate may have a thickness of 0.30 to 0.65 times a thickness of the superhard material. At least two impact tips may be brazed to the carbide extension
The assembly may be incorporated in drill bits, shear bits, percussion bits, roller cone bits or combinations thereof. The assembly may be incorporated in mining picks, trenching picks, asphalt picks, excavating picks or combinations thereof. The carbide extension may comprise a drill bit blade, a drill bit working surface, a pick bolster, or combinations thereof.
Referring now to the figures,
Referring now to
The shank assembly 303 may comprise a hard material such as steel, stainless steel, hardened steel, or other materials of similar hardness. The carbide extension 404 may comprise tungsten, titanium, tantalum, molybdenum, niobium, cobalt and/or combinations thereof.
The shank assembly 303 may be work-hardened or cold-worked in order to provide resistance to cracking or stress fractures due to forces exerted on the degradation assembly 301 by the formation 105. The shank assembly 303 may be work-hardened by shot-peening or by other methods of work-hardening. At least a portion of the shank assembly 303 may also be work-hardened by stretching it during the manufacturing process.
The shank assembly 303 comprises a locking mechanism 411 and an outer surface 412. The locking mechanism 411 is axially disposed within a bore 413 of the outer surface 412 and the second end 402 of the locking mechanism 411 is secured within or below the bore 413. The first end 401 of the locking mechanism 411 protrudes into the cavity 405 in the base end 406 of the carbide extension 404 and the first end 401 of the outer surface 412 may be adapted to fit into the cavity 405 in the base end 406 of the carbide extension 404. The locking mechanism 411 is adapted to lock the first end 401 of the shank assembly 303 within the cavity 405. The locking mechanism 411 may attach the shank assembly 303 to the carbide extension 404 and restrict movement of the shank assembly 303 with respect to the carbide extension 404. The locking mechanism 411 comprises a radially extending catch 415 that is formed in the first end 401 of the shank assembly 303. The shank assembly 303 may be prevented by the locking mechanism 411 from moving in a direction parallel to a central axis 416 of the degradation assembly 301. In some embodiments the shank assembly 303 may be prevented by the locking mechanism 411 from rotating about the central axis 416.
In
When the first end 401 of the locking mechanism 411 is inserted into the cavity 405, the locking head 420 may be extended away from the bore 413 of the outer surface 412. The insert 418 may be disposed around the locking shaft 419 and be intermediate the locking head 420 and the bore 413. The insert 418 may comprise stainless steel. In some embodiments the insert 418 may comprise an elastomeric material and may be flexible. The insert 418 may be a ring, a snap ring, a split ring, a coiled ring, a rigid ring, segments, balls, wedges, shims, a spring or combinations thereof.
The insert 418 may comprise a breadth 422 that is larger than an opening 423 of the cavity 405. In such embodiments the insert 418 may compress to have a smaller breadth 422 than the opening 423. Once the insert 418 is past the opening 423, the insert 418 may expand to comprise its original or substantially original breadth 422. With both the insert 418 and the locking head 420 inside the cavity 405, the rest of the first end 401 of the shank assembly 303 may be inserted into the cavity 405 of the carbide extension 404. Once the entire first end 401 of the shank assembly 303 is inserted into the cavity 405 to a desired depth a nut 424 may be threaded onto an exposed end 425 of the locking shaft 419 until the nut 424 contacts a ledge 426 proximate the bore 413 mechanically connecting the locking mechanism 411 to the outer surface 412. This contact and further threading of the nut 424 on the locking shaft 419 may cause the locking shaft 419 to move toward the second end 402 of the shank assembly 303 in a direction parallel to the central axis 416 of the shank assembly 303. This may also result in bringing the radially extending catch 415 of the locking head 420 into contact with the insert 418, and bringing the insert 418 into contact with the inwardly protruding catch 417 of the cavity 405. The nut 424 is an embodiment of a tensioning mechanism 427. The tensioning mechanism 427 is adapted to apply a rearward force on the first end 401 of the shank assembly 303. The rearward force may pull the first end 401 of the shank assembly 303 in the direction of the second end 402 and applies tension along a length of the locking shaft 419. In some embodiments the tensioning mechanism 427 may comprise a press fit, a taper, and/or a nut 424.
Once the nut 424 is threaded tightly onto the locking shaft 419, the locking head 420 and insert 418 are together too wide to exit the opening 423. In some embodiments the contact between the locking head 420 and the carbide extension 404 via the insert 418 may be sufficient to prevent both rotation of the shank assembly 303 about its central axis 416 and movement of the shank assembly 303 in a direction parallel to its central axis 416. In some embodiments the locking mechanism 411 is also adapted to inducibly release the shank assembly 303 from attachment with the carbide extension 404 by removing the nut 424 from the locking shaft 419.
In some embodiments the insert 418 may be a snap ring. The insert 418 may comprise stainless steel and may be deformed by the pressure of the locking head 420 being pulled towards the second end 402 of the shank assembly 303. As the insert 418 deforms it may become harder. The deformation may also cause the insert 418 to be complementary to both the inwardly protruding catch 417 and the radially extending catch 415. This dually complementary insert 418 may avoid point loading or uneven loading, thereby equally distributing contact stresses. In such embodiments the insert 418 may be inserted when it is comparatively soft, and then may be work hardened while in place proximate the catches 236, 237.
In some embodiments at least part of the shank assembly 303 of the degradation assembly 301 may also be cold worked. The locking mechanism 411 may be stretched to a critical point just before the strength of the locking mechanism 411 is compromised. In some embodiments, the locking shaft 419, locking head 420, and insert 418 may all be cold worked by tightening the nut 424 until the locking shaft and head 419, 420, and the insert 418, reach a stretching critical point. During this stretching the insert 418, and the locking shaft and head 419, 420, may all deform to create a complementary engagement, and may then be hardened in that complementary engagement. In some embodiments the complementary engagement may result in an interlocking between the radially extending catch 415 and the inwardly protruding catch 417.
In the embodiment of
Referring now to
The superhard material 407 and comprises a substantially conical geometry with an apex 501. Preferably, the interface 502 between the substrate 408 and the superhard material 407 is non-planar, which may help distribute loads on the tip 403 across a larger area of the interface 502. At the interface 502 the substrate 408 may comprise a tapered surface starting from a cylindrical rim 503 of the substrate 408 and ending at an elevated flatted central region formed in the substrate 408. The flatted central region may have a diameter of 0.20 to 0.60 percent of a diameter of the cylindrical rim 503. A thickness from the apex 501 to the non-planar interface 502 is at least 1.5 times a thickness of the substrate 408 from the non-planar interface 502 to its base 504. In some embodiments the thickness from the apex 501 to the non-planar interface 502 may be at least 2 times a thickness of the substrate 408 from the non-planar interface to its base 504. The substrate 408 may comprise a thickness of 0.30 to 0.65 times the thickness of the superhard material 407. In some embodiments, the thickness of the substrate is less than 0.100 inches, preferably less than 0.060 inches. The thickness from the apex 501 to the non-planar interface 502 may be 0.190 to 0.290 inches. Together, the superhard material 407 and the substrate 408 may comprise a total thickness of 0.200 to 0.500 inches from the apex 501 to the base of the substrate 504. The superhard material 407 bonded to the substrate 408 may comprise a substantially conical geometry with an apex 501 comprising a 0.065 to 0.095 inch radius. The substantially conical geometry comprises a first side 505 that may form a 50 to 80 degree included angle 507 with a second side 506 of the substantially conical geometry. In asphalt milling applications, the inventors have discovered that an optimal included angle is 45 degrees, whereas in mining applications the inventors have discovered that an optimal included angle is between 35 and 40 degrees. The tip 403 may comprise an included angle 507 to the thickness from the apex 501 to the non-planar interface 502 ratio of 240 to 440. The tip 403 may comprise an included angle 507 to a total thickness from the apex 501 to a base 504 of the substrate 408 ratio of 160 to 280. A tip that maybe compatible with the present invention is disclosed in U.S. patent application Ser. No. 11/673,634 to Hall and is currently pending.
The superhard material 407 may be a material selected from the group consisting of diamond, polycrystalline diamond, natural diamond, synthetic diamond, vapor deposited diamond, silicon bonded diamond, cobalt bonded diamond, thermally stable diamond, polycrystalline diamond with a binder concentration of 1 to 40 weight percent, infiltrated diamond, layered diamond, monolithic diamond, polished diamond, course diamond, fine diamond, cubic boron nitride, diamond impregnated matrix, diamond impregnated carbide, metal catalyzed diamond, or combinations thereof. The superhard material 407 may also comprise infiltrated diamond. The superhard material 407 may comprise an average diamond grain size of 1 to 100 microns. The superhard 407 material may comprise a monolayer of diamond. For the purpose of this patent the word monolayer is defined herein as a singular continuous layer of a material of indefinite thickness.
The superhard material 407 may comprise a metal catalyst concentration of less than 5 percent by volume. The superhard material 407 may be leached of a catalyzing material to a depth of no greater than at least 0.5 mm from a working surface 508 of the superhard material 407. A description of leaching and its benefits is disclosed in U.S. Pat. No. 6,562,462 to Griffin et al, which is herein incorporated by reference for all that it contains. Isolated pockets of catalyzing material may exist in the leached region of the superhard material 407. The depth of at least 0.1 mm from the working surface 508 may comprise a catalyzing material concentration of 5 to 1 percent by volume.
The impact tip 403 may be brazed onto the carbide extension 404 at a braze interface 509. Braze material used to braze the tip 403 to the carbide extension 404 may comprise a melting temperature from 700 to 1200 degrees Celsius; preferably the melting temperature is from 800 to 970 degrees Celsius. The braze material may comprise silver, gold, copper nickel, palladium, boron, chromium, silicon, germanium, aluminum, iron, cobalt, manganese, titanium, tin, gallium, vanadium, phosphorus, molybdenum, platinum, or combinations thereof. The braze material may comprise 30 to 62 weight percent palladium, preferable 40 to 50 weight percent palladium. Additionally, the braze material may comprise 30 to 60 weight percent nickel, and 3 to 15 weight percent silicon; preferably the braze material may comprise 47.2 weight percent nickel, 46.7 weight percent palladium, and 6.1 weight percent silicon. Active cooling during brazing may be critical in some embodiments, since the heat from brazing may leave some residual stress in the bond between the carbide substrate 408 and the superhard material 407. The farther away the superhard material 407 is from the braze interface 509, the less thermal damage is likely to occur during brazing. Increasing the distance between the brazing interface 509 and the superhard material 407, however, may increase the moment on the carbide substrate 408 and increase stresses at the brazing interface 509 upon impact. The shank assembly 303 may be press fitted into the carbide extension 404 before or after the tip 403 is brazed onto the carbide extension 404.
Referring now to
Referring now to
Whereas the present invention has been described in particular relation to the drawings attached hereto, it should be understood that other and further modifications apart from those shown or suggested herein, may be made within the scope and spirit of the present invention.
This application is a continuation of U.S. patent application Ser. No. 12/051,689 filed Mar. 19, 1998 which is a continuation of U.S. patent application Ser. No. 12/051,586 filed Mar. 19, 1998 which is a continuation-in-part of U.S. patent application Ser. No. 12/021,051 filed Jan. 28, 1998 which is a continuation-in-part of U.S. patent application Ser. No. 12/021,019 filed Jan. 28, 1998 which was a continuation-in-part of U.S. patent application Ser. No. 11/971,965 filed Jan. 10, 2008 which is a continuation of U.S. patent application Ser. No. 11/947,644, filed Nov. 29, 2007 which was a continuation-in-part of U.S. patent application Ser. No. 11/844,586 filed Aug. 24, 20007 now U.S. Pat. No 7,600,823. U.S. patent application Ser. No. 11/844,586 is a continuation-in-part of U.S. patent application Ser. No. 11/829,761 filed Jul. 27, 2008. U.S. patent application Ser. No. 11/829,761 is a continuation-in-part of U.S. patent application Ser. No. 11/773,271 filed Jul. 03, 2007. U.S. patent application Ser. No. 11/773,271 is a continuation-in-part of U.S. patent application Ser. No. 11/766,903 filed Jul. 22, 2007. U.S. patent application Ser. No. 11/766,903 is a continuation of U.S. patent application Ser. No. 11/766,865 filed Jun. 22, 2007. U.S. patent application Ser. No. 11/766,865 is a continuation-in-part of U.S. patent application Ser. No. 11/742,304 filed Apr. 30, 2007 now U.S. Pat No. 7,475,948. U.S. patent application Ser. No. 11/742,304 is a continuation of U.S. patent application Ser. No. 11/742,261 filed Apr. 30, 2007 now U.S. Pat. No. 7,469,971. U.S. patent application Ser. No. 11/742,261 is a continuation-in-part of U.S. patent application Ser. No. 11/464,008 filed Aug. 11, 2006 now U.S. Pat. No. 7,338,135. U.S. patent application Ser. No. 11/464,008 is a continuation-in-part of U.S. patent application Ser. No. 11/463,998 filed Aug. 11, 2006 now U.S. Pat. No. 7,384,105. U.S. patent application Ser. No. 11/463,998 is a continuation-in-part of U.S. patent application Ser. No. 11/463,990 filed Aug. 11, 2006 now U.S. Pat. No. 7,320,505. U.S. patent application Ser. No. 11/463,990 is a continuation-in-part of U.S. patent application Ser. No. 11/463,975 filed Aug. 11, 2006 now U.S. Pat. No. 7,445,294. U.S. patent application Ser. No. 11/463,975 is a continuation-in-part of U.S. patent application Ser. No. 11/463,962 filed Aug. 11, 2006 now U.S. Pat. No. 7,413,256. U.S. patent application Ser. No. 11/463,962 is a continuation-in-part of U.S. patent application Ser. No. 11/463,953 filed Aug. 11, 2006 now U.S. Pat. No 7,464,993. The present application is also a continuation-in-part of U.S. patent application Ser. No. 11/695,672 filed Dec. 27, 2007. U.S. patent application Ser. No. 11/695,672 is a continuation-in-part of U.S. patent application Ser. No. 11/686,831 filed Mar. 15, 2007 now U.S. Pat. No. 7,568,770. All of these applications are herein incorporated by reference for all that they contain.
Number | Name | Date | Kind |
---|---|---|---|
2004315 | Fean | Jun 1935 | A |
2124438 | Struk | Jul 1938 | A |
3254392 | Novkov | Jun 1966 | A |
3746396 | Radd | Jul 1973 | A |
3807804 | Kniff | Apr 1974 | A |
3830321 | McKenry | Aug 1974 | A |
3932952 | Helton | Jan 1976 | A |
3945681 | White | Mar 1976 | A |
4005914 | Newman | Feb 1977 | A |
4006936 | Crabiel | Feb 1977 | A |
4098362 | Bonnice | Jul 1978 | A |
4109737 | Bovenkerk | Aug 1978 | A |
4156329 | Daniels | May 1979 | A |
4199035 | Thompson | Apr 1980 | A |
4201421 | Den Besten | May 1980 | A |
4277106 | Sahley | Jul 1981 | A |
4439250 | Acharya | Mar 1984 | A |
4465221 | Acharya | Aug 1984 | A |
4484644 | Cook | Nov 1984 | A |
4489986 | Dziak | Dec 1984 | A |
4678237 | Collin | Jul 1987 | A |
4682987 | Brady | Jul 1987 | A |
4688856 | Elfgen | Aug 1987 | A |
4694918 | Hall | Sep 1987 | A |
4725098 | Beach | Feb 1988 | A |
4729603 | Elfgen | Mar 1988 | A |
4765686 | Adams | Aug 1988 | A |
4765687 | Parrott | Aug 1988 | A |
4776862 | Wiand | Oct 1988 | A |
4880154 | Tank | Nov 1989 | A |
4932723 | Mills | Jun 1990 | A |
4940288 | Stiffler | Jul 1990 | A |
4944559 | Sionnet | Jul 1990 | A |
4951762 | Lundell | Aug 1990 | A |
5011515 | Frushour | Apr 1991 | A |
5112165 | Hedlund | May 1992 | A |
5119714 | Scott et al. | Jun 1992 | A |
5141289 | Stiffler | Aug 1992 | A |
5154245 | Waldenstrom | Oct 1992 | A |
5186692 | Pope | Feb 1993 | A |
5251964 | Ojanen | Oct 1993 | A |
5261499 | Grubb | Nov 1993 | A |
5332348 | Lemelson | Jul 1994 | A |
5417475 | Graham | May 1995 | A |
5447208 | Lund | Sep 1995 | A |
5535839 | Brady | Jul 1996 | A |
5542993 | Rabinkin | Aug 1996 | A |
5653300 | Lund | Aug 1997 | A |
5662720 | O'Tighearnaigh | Sep 1997 | A |
5738698 | Kapoor | Apr 1998 | A |
5823632 | Burkett | Oct 1998 | A |
5837071 | Anderson | Nov 1998 | A |
5845547 | Sollami | Dec 1998 | A |
5875862 | Jurewicz | Mar 1999 | A |
5890552 | Scott et al. | Apr 1999 | A |
5934542 | Nakamura | Aug 1999 | A |
5935718 | Demo | Aug 1999 | A |
5944129 | Jensen | Aug 1999 | A |
5967250 | Lund | Oct 1999 | A |
5992405 | Sollami | Nov 1999 | A |
6000483 | Jurewicz et al. | Dec 1999 | A |
6006846 | Tibbitts | Dec 1999 | A |
6019434 | Emmerich | Feb 2000 | A |
6044920 | Massa | Apr 2000 | A |
6051079 | Andersson | Apr 2000 | A |
6056911 | Griffin | May 2000 | A |
6065552 | Scott | May 2000 | A |
6113195 | Mercier | Sep 2000 | A |
6170917 | Heinrich | Jan 2001 | B1 |
6193770 | Sung | Feb 2001 | B1 |
6196636 | Mills | Mar 2001 | B1 |
6196910 | Johnson | Mar 2001 | B1 |
6199956 | Kammerer | Mar 2001 | B1 |
6216805 | Lays | Apr 2001 | B1 |
6270165 | Peay | Aug 2001 | B1 |
6341823 | Sollami | Jan 2002 | B1 |
6354771 | Bauschulte | Mar 2002 | B1 |
6364420 | Sollami | Apr 2002 | B1 |
6371567 | Sollami | Apr 2002 | B1 |
6375272 | Ojanen | Apr 2002 | B1 |
6419278 | Cunningham | Jul 2002 | B1 |
6460637 | Siracki et al. | Oct 2002 | B1 |
6478383 | Ojanen | Nov 2002 | B1 |
6499547 | Scott | Dec 2002 | B2 |
6517902 | Drake | Feb 2003 | B2 |
6585326 | Sollami | Jul 2003 | B2 |
6601662 | Matthias et al. | Aug 2003 | B2 |
6685273 | Sollami | Feb 2004 | B1 |
6709065 | Peay | Mar 2004 | B2 |
6719074 | Tsuda | Apr 2004 | B2 |
6733087 | Hall | May 2004 | B2 |
6739327 | Sollami | May 2004 | B2 |
6758530 | Sollami | Jul 2004 | B2 |
6786557 | Montgomery, Jr. | Sep 2004 | B2 |
6824225 | Stiffler | Nov 2004 | B2 |
6651758 | Beach | Feb 2005 | B2 |
6854810 | Montgomery, Jr. | Feb 2005 | B2 |
6861137 | Griffin | Mar 2005 | B2 |
6889890 | Yamazaki | May 2005 | B2 |
6966611 | Sollami | Nov 2005 | B1 |
6994404 | Sollami | Feb 2006 | B1 |
7204560 | Mercier | Apr 2007 | B2 |
20020175555 | Mercier | Nov 2002 | A1 |
20030140350 | Noro | Jul 2003 | A1 |
20030209366 | McAlvain | Nov 2003 | A1 |
20030234280 | Cadden | Dec 2003 | A1 |
20040026983 | McAlvain | Feb 2004 | A1 |
20040065484 | McAlvain | Apr 2004 | A1 |
20050159840 | Lin | Jul 2005 | A1 |
20050173966 | Mouthaan | Aug 2005 | A1 |
20060237236 | Sreshia | Oct 2006 | A1 |
Number | Date | Country | |
---|---|---|---|
20080164073 A1 | Jul 2008 | US |
Number | Date | Country | |
---|---|---|---|
Parent | 12051689 | Mar 2008 | US |
Child | 12051738 | US | |
Parent | 12051586 | Mar 2008 | US |
Child | 12051689 | US | |
Parent | 11947644 | Nov 2007 | US |
Child | 11971965 | US | |
Parent | 11766865 | Jun 2007 | US |
Child | 11766903 | US | |
Parent | 11742261 | Apr 2007 | US |
Child | 11742304 | US |
Number | Date | Country | |
---|---|---|---|
Parent | 12021051 | Jan 2008 | US |
Child | 12051586 | US | |
Parent | 12021019 | Jan 2008 | US |
Child | 12021051 | US | |
Parent | 11971965 | Jan 2008 | US |
Child | 12021019 | US | |
Parent | 11844586 | Aug 2007 | US |
Child | 11947644 | US | |
Parent | 11829761 | Jul 2007 | US |
Child | 11844586 | US | |
Parent | 11773271 | Jul 2007 | US |
Child | 11829761 | US | |
Parent | 11766903 | Jun 2007 | US |
Child | 11773271 | US | |
Parent | 11742304 | Apr 2007 | US |
Child | 11766865 | US | |
Parent | 11464008 | Aug 2006 | US |
Child | 11742261 | US | |
Parent | 11463998 | Aug 2006 | US |
Child | 11464008 | US | |
Parent | 11463990 | Aug 2006 | US |
Child | 11463998 | US | |
Parent | 11463975 | Aug 2006 | US |
Child | 11463990 | US | |
Parent | 11463962 | Aug 2006 | US |
Child | 11463975 | US | |
Parent | 11463953 | Aug 2006 | US |
Child | 11463962 | US | |
Parent | 11965672 | Dec 2007 | US |
Child | 12021051 | Jan 2008 | US |
Parent | 11686831 | Mar 2007 | US |
Child | 11965672 | US |