The invention relates to a system and method for determining degradation of a NOx sensor coupled to an internal combustion engine.
Engine and vehicle fuel efficiency can be improved by lean burn internal combustion engines. To reduce emissions, these lean burn engines are coupled to emission control devices known as three-way catalytic converters optimized to reduce CO, HC, and NOx. When operating at air-fuel ratio mixtures lean of stoichiometry, an additional three-way catalyst, known as a NOx trap or catalyst, is typically coupled downstream of the three-way catalytic converter, where the NOx trap is optimized to further reduce NOx. The NOx trap typically stores NOx when the engine operates lean and release NOx to be reduced when the engine operates rich or near stoichiometry.
One method to provide emission control in a lean burn engine uses a sensor downstream of the NOx trap. The sensor is capable of measuring an amount of NOx in exhaust gas exiting the NOx trap. Engine air-fuel ratio is changed from lean of stoichiometry to rich of stoichiometry when measured NOx reaches a predetermined threshold. Such a method is described in U.S. Pat. No. 5,942,199.
The inventors herein have recognized a disadvantage with the above approach. In particular, if the output of the NOx sensor inadvertently indicates a NOx concentration greater than the predetermined threshold when NOx concentration is actually less that the threshold, lean operation will be ended prematurely. In other words, lean operation will be ended when it is actually possible to continue lean operation.
An object of the invention claimed herein is to provide a method for determining degradation of a sensor coupled to an internal combustion engine.
The above object is achieved, and disadvantages of prior approaches overcome, by a method for determining degradation in an emission control system coupled to an internal combustion engine having an emission control device coupled downstream of the engine, the method comprising: providing an output signal of a sensor coupled downstream of the emission control device, said output signal indicative of an exhaust gas constituent flowing through the emission control system; generating an estimate of said exhaust gas constituent based at least on an engine operating condition; and indicating when said estimate of said exhaust gas constituent and said second quantity differ by a predetermined value.
By comparing an actual sensor output to an estimate based on other operating conditions, it is possible to determine when the sensor output has degraded.
An advantage of the above aspect of the present invention is improved emissions is achieved since it is possible to determine when the sensor has degraded.
Other objects, features and advantages of the resent invention will be readily appreciated by the reader of this specification.
The objects and advantages described herein will be more fully understood by reading an example of an embodiment in which the invention is used to advantage, referred to herein as the Description of Preferred Embodiment, with reference to the drawings, wherein:
Direct injection spark ignited internal combustion engine 10, comprising a plurality of combustion chambers, is controlled by electronic engine controller 12 as shown in FIG. 1. Combustion chamber 30 of engine 10 includes combustion chamber walls 32 with piston 36 positioned therein and connected to crankshaft 40. In this particular example, piston 36 includes a recess or bowl (not shown) to help in forming stratified charges of air and fuel. Combustion chamber 30 is shown communicating with intake manifold 44 and exhaust manifold 48 via respective intake valves 52a and 52b (not shown), and exhaust valves 54a and 54b (not shown). Fuel injector 66 is shown directly coupled to combustion chamber 30 for delivering liquid fuel directly therein in proportion to the pulse width of signal fpw received from controller 12 via conventional electronic driver 68. Fuel is delivered to fuel injector 66 by a conventional high pressure fuel system (not shown) including a fuel tank, fuel pumps, and a fuel rail.
Intake manifold 44 is shown communicating with throttle body 58 via throttle plate 62. In this particular example, throttle plate 62 is coupled to electric motor 94 so that the position of throttle plate 62 is controlled by controller 12 via electric motor 94. This configuration is commonly referred to as electronic throttle control (ETC), which is also utilized during idle speed control. In an alternative embodiment (not shown), which is well known to those skilled in the art, a bypass air passageway is arranged in parallel with throttle plate 62 to control inducted airflow during idle speed control via a throttle control valve positioned within the air passageway.
Exhaust gas oxygen sensor 76 is shown coupled to exhaust manifold 48 upstream of catalytic converter 70. In this particular example, sensor 76 provides signal UEGO to controller 12, which converts signal UEGO into a relative air-fuel ratio λ. Signal UEGO is used to advantage during feedback air-fuel ratio control in a manner to maintain average air-fuel ratio at a desired air-fuel ratio as described later herein. In an alternative embodiment, sensor 76 can provide signal EGO (not shown), which indicates whether exhaust air-fuel ratio is either lean of stoichiometry or rich of stoichiometry.
Conventional distributorless ignition system 88 provides ignition spark to combustion chamber 30 via spark plug 92 in response to spark advance signal SA from controller 12.
Controller 12 causes combustion chamber 30 to operate in either a homogeneous air-fuel ratio mode or a stratified air-fuel ratio mode by controlling injection timing. In the stratified mode, controller 12 activates fuel injector 66 during the engine compression stroke so that fuel is sprayed directly into the bowl of piston 36. Stratified air-fuel ratio layers are thereby formed. The strata closest to the spark plug contains a stoichiometric mixture or a mixture slightly rich of stoichiometry, and subsequent strata contain progressively leaner mixtures. During the homogeneous mode, controller 12 activates fuel injector 66 during the intake stroke so that a substantially homogeneous air-fuel ratio mixture is formed when ignition power is supplied to spark plug 92 by ignition system 88. Controller 12 controls the amount of fuel delivered by fuel injector 66 so that the homogeneous air-fuel ratio mixture in chamber 30 can be selected to be substantially at (or near) stoichiometry, a value rich of stoichiometry, or a value lean of stoichiometry. Operation substantially at (or near) stoichiometry refers to conventional closed loop oscillatory control about stoichiometry. The stratified air-fuel ratio mixture will always be at a value lean of stoichiometry, the exact air-fuel ratio being a function of the amount of fuel delivered to combustion chamber 30. An additional split mode of operation wherein additional fuel is injected during the exhaust stroke while operating in the stratified mode is available. An additional split mode of operation wherein additional fuel is injected during the intake stroke while operating in the stratified mode is also available, where a combined homogeneous and split mode is available.
Nitrogen oxide (NOx) absorbent or trap 72 is shown positioned downstream of catalytic converter 70. NOx trap 72 absorbs NOx when engine 10 is operating lean of stoichiometry. The absorbed NOx is subsequently reacted with HC and catalyzed during a NOx purge cycle when controller 12 causes engine 10 to operate in either a rich mode or a near stoichiometric mode.
Controller 12 is shown in
Controller 12 is shown receiving various signals from sensors coupled to engine 10, in addition to those signals previously discussed, including: measurement of inducted mass air flow (MAF) from mass air flow sensor 100 coupled to throttle body 58; engine coolant temperature (ECT) from temperature sensor 112 coupled to cooling sleeve 114; a profile ignition pickup signal (PIP) from Hall effect sensor 118 coupled to crankshaft 40 giving an indication of engine speed (RPM); throttle position TP from throttle position sensor 120; and absolute Manifold Pressure Signal MAP from sensor 122. Engine speed signal RPM is generated by controller 12 from signal PIP in a conventional manner and manifold pressure signal MAP provides an indication of engine load.
In this particular example, temperature Tcat of catalytic converter 70 and temperature Ttrp of NOx trap 72 are inferred from engine operation as disclosed in U.S. Pat. No. 5,414,994, the specification of which is incorporated herein by reference. In an alternate embodiment, temperature Tcat is provided by temperature sensor 124 and temperature Ttrp is provided by temperature sensor 126.
Fuel system 130 is coupled to intake manifold 44 via tube 132. Fuel vapors (not shown) generated in fuel system 130 pass through tube 132 and are controlled via purge valve 134. Purge valve 134 receives control signal PRG from controller 12.
Exhaust sensor 140 is a sensor that produces two output signals. First output signal (SIGNAL1) and second output signal (SIGNAL2) are both received by controller 12. Exhaust sensor 140 can be a sensor known to those skilled in the art that is capable of indicating both exhaust air-fuel ratio and nitrogen oxide concentration.
In a preferred embodiment, SIGNAL1 indicates exhaust air-fuel ratio and SIGNAL2 indicates nitrogen oxide concentration. In this embodiment, sensor 140 has a first chamber (not shown) in which exhaust gas first enters where a measurement of oxygen partial pressure is generated from a first pumping current. Also, in the first chamber, oxygen partial pressure of the exhaust gas is controlled to a predetermined level. Exhaust air-fuel ratio can then be indicated based on this first pumping current. Next, the exhaust gas enters a second chamber (not shown) where NOx is decomposed and measured by a second pumping current using the predetermined level. Nitrogen oxide concentration can then be indicated based on this second pumping current.
In one aspect of the present invention, a determination of degradation of the nitrogen oxide concentration measurement can be made if it is determined that the exhaust air-fuel ratio measurement is degraded. This is because nitrogen oxide concentration is not accurately detected in the second chamber unless the first chamber controls oxygen partial pressure properly. In other words, if it is determined that operation of the first chamber (where partial pressure of oxygen is measured) is degraded, then it is possible to determine that the second signal (SIGNAL2) indicating nitrogen oxide concentration is degraded as described later herein with particular reference to FIG. 13.
Referring now to
Those skilled in the art will recognize, in view of this disclosure, that the methods of the present invention can be used to advantage with either port fuel injected or directly injected engines.
Referring now to
Referring now specifically to
Continuing with
Continuing, the controller 12 determines a value SAVINGS representative of the cumulative fuel savings to be achieved by operating at the selected lean operating condition relative to the reference stoichiometric operating condition, based upon the air mass value AM, the current (lean or rich) lean-burn air-fuel ratio (LAMBSE) and the determined lean-burn torque ratio TR_LB, wherein
SAVINGS=SAVINGS+(AM*LAMBSE*14.65*(1−TR)).
The controller 12 then determines a value DIST_ACT_CUR representative of the actual miles traveled by the vehicle since the start of the last trap purge or desulfurization event. While the “current” actual distance value DIST_ACT_CUR is determined in any suitable manner, in the exemplary system, the controller 14 determines the current actual distance value DIST_ACT_CUR by accumulating detected or determined instantaneous values VS for vehicle speed.
Because the fuel economy benefit to be obtained using the lean-burn feature is reduced by the “fuel penalty” of any associated trap purge event, in the exemplary system, the controller 12 determines the “current” value FE_CUR for fuel economy benefit only once per NOx fill cycle. And, because the purge event's fuel penalty is directly related to the preceding trap “fill,” the current fuel economy benefit value FE_CUR is preferably determined at the moment that the purge event is deemed to have just been completed, as described below.
Continuing with
Those skilled in the art will recognize, in view of this disclosure, this as a single pole low pass filter.
output=(1−fk)output+(fk)input or,
output=(1−fk)old_output+(fk)input, old_output=output
Thus, according to the present invention, it is possible to determine the fuel economy benefit provided by a decontaminated emission control device.
Referring now to
In a preferred embodiment, function (f2) represents the rolling average function described above herein. Thus, according to the present invention, a fuel economy benefit averaged over several NOx fill/purge cycles can be determined. This value can then be used to advantage in various ways, since it indicates an on-line measure of the improved fuel economy performance provided by lean operation averaged to remove cycle-to-cycle variation.
Referring now to
Those skilled in the art will recognize, in view of this disclosure, various alterations of the present invention that achieve a similar result. For example, the average excess fuel used during several decontamination cycles can be divided by the total distance between all of the decontamination cycles, thereby providing an averaged fuel economy penalty for performing a decontamination cycle.
In an alternate embodiment, fuel economy penalty to perform a decontamination cycle can be stored as a function of vehicle and/or engine operating parameters. For example, fuel economy penalty can be stored versus vehicle speed and exhaust gas temperature experienced before performing said decontamination cycle. Those skilled in the art will recognize, in view of this disclosure, various other factors that affect a fuel economy penalty to perform a decontamination cycle such as, for example, engine speed, mass air flow, manifold pressure, ignition timing, air-fuel ratio, exhaust gas recirculation amount, and engine torque.
In yet another embodiment, fuel economy penalty can be determined as now described. First, controller 12 updates a stored value DIST_ACT_DSX representing the actual distance that the vehicle has traveled since the termination or “end” of the immediately-preceding desulfurization, or decontamination, event. Then, the controller 12 determines whether a desulfurization event is currently in progress. While any suitable method is used for desulfurizing the trap, an exemplary desulfurization event is characterized by operation of some of the engine's cylinders with a lean air-fuel mixture and other of the engine's cylinders with a rich air-fuel mixture, thereby generating exhaust gas with a slightly-rich bias. Next, the controller 12 determines the corresponding fuel-normalized torque values TQ_DSX_LEAN and TQ_DSX_RICH, as a function of current operating conditions. In particular, TQ_DSX_LEAN and TQ_DSX_RICH are determined as functions of desired engine torque, engine speed, desired air-fuel ratio, an d DELTA_SPARK. Then, the controller 12 further determines the corresponding fuel-normalized stoichiometric torque value TQ_STOICH as a function of desired engine torque and engine speed. The controller 12 then calculates a cumulative fuel economy penalty value, as follows:
PENALTY=PENALTY+(AM/2*LAMBSE*14.65*(1TR_DSX_LEAN)) +(AM/2*LAMBSE*14.65*(1−TR_DSX_RICH))
Then, the controller 12 sets a fuel economy penalty calculation flag to thereby ensure that the current desulfurization fuel economy penalty measure FE_PENALTY_CUR is determined immediately upon termination of the on-going desulfurization event.
If the controller 12 determines that a desulfurization event has just been terminated, the controller 12 then determines the current value FE_PENALTY_CUR for the fuel economy penalty associated with the terminated desulfurization event, calculated as the cumulative fuel economy penalty value PENALTY divided by the actual distance value DIST_ACT_DSX. In this way, the fuel economy penalty associated with a desulfurization event is spread over the actual distance that the vehicle has traveled since the immediately-prior desulfurization event. Next, the controller 12 calculates a rolling average value FE_PENALTY of the last m current fuel economy penalty values FE_PENALTY_CUR to thereby provide a relatively-noise-insensitive measure of the fuel economy performance impact of such desulfurization events. The value FE_PENALTY can be used in place of value FIL_FE_PENALTY. By way of example only, the average negative performance impact or “penalty” of desulfurization typically ranges between about 0.3 percent to about 0.5 percent of the performance gain achieved through lean-burn operation. Finally, the controller 23 resets the fuel economy penalty calculation flag FE_PNLTY_CALC_FLG, along with the previously determined (and summed) actual distance value DIST_ACT_DSX and the current fuel economy penalty value PENALTY, in anticipation for the next desulfurization event.
Referring now to
Referring now to
Referring now to
Referring now to
Continuing with
Referring now to
Thus, according to the present invention, it is possible to calculate a value representing a consistent and normalized NOx storage value that can be used in determining degradation and determining whether to perform a decontamination cycle.
Referring now to
When the step 1110 is NO, the routine continues to step 1116 and calculates fuel injection signal (fpw) based on the cylinder charge amount and the desired air-fuel ratio using function g1. Thus, according to the present invention, it is possible to improve open-loop fueling control using the first output of sensor 140, which is located downstream of NOx trap 72, whenever the first output signal indicates a value away from stoichiometry. In this way, NOx storage and oxygen storage, as well as NOx reduction, do not adversely closed-loop feedback air-fuel control using a sensor located downstream of a NOx trap.
Referring now to
Continuing with
In other words, duration D2 and duration D3 represent periods before which first output of exhaust sensor 140 cannot be used for feedback control because it will indicate stoichiometric even when the exhaust air-fuel ratio entering NOx trap 72 is not stoichiometric. Thus, when changing from stoichiometric or rich to lean, first output of exhaust sensor 140 is valid for monitoring or feedback control after duration D3. Similarly, when changing from lean operation to rich or stoichiometric operation, first output of exhaust sensor 140 is valid for monitoring or feedback control after duration D2. In a preferred embodiment, duration D2 is based on oxygen storage of trap 72 and duration D3 is based on both oxygen storage and NOx storage of trap 72. Stated another way, once the oxygen storage is saturated when changing from rich to lean, SIGNAL1 is indicative of the air-fuel ratio entering trap 72. And, once the oxygen stored and NOx stored is reduced when changing from lean to rich, SIGNAL1 is indicative of the air-fuel ratio entering trap 72.
Continuing with
When the answers to either step 1218 or step 1220 are NO, the routine continues to step 1228 to calculate fuel injection signal (fpw) as described herein in step 1116. Thus, according to the present invention, it is possible to utilize the first output of exhaust sensor 140 for feedback air-fuel control.
Referring now to
Thus, according to the present invention, it is possible to determine when the NOx sensor, which is the second output of exhaust sensor 140, has degraded by comparing to an estimated value of exiting NOx trap 72.
Referring now to
Continuing with
Referring now to
Before time t1, the entering air-fuel ratio and exiting air-fuel ratio are both lean and first output signal (SIGNAL1) is valid for control or monitoring. Then, at time t1, a determination is made to end lean operation and purge NOx stored in trap 72 due to tailpipe grams of NOx/mile, or because a fuel economy benefit is no longer provided by operating lean, or for various other reasons as described above herein. At time t1, entering air-fuel ratio is changed from lean to rich. Similarly, at time t1, air-fuel ratio exiting changes to stoichiometric until all stored NOx and oxygen are reduced, which occurs at time t2. Thus, according to the present invention, the stoichiometric air-fuel ratio measured downstream of NOx trap 72 during the interval from time t1 to time t2, is not equal to the air-fuel ratio upstream of NOx trap 72. After time t2, a rich exhaust air-fuel ratio is measured downstream of NOx trap 72 and this measurement can be used for air-fuel control or monitoring. At time t3, entering air-fuel is changed back to a lean air-fuel ratio. Again, air-fuel ratio exiting changes to stoichiometric until all the oxygen storage capacity of NOx trap 72 is saturated at time t4. Thus, according to the present invention, the stoichiometric air-fuel ratio measured downstream of NOx trap 72 during the interval from time t3 to time t4 is not equal to the air-fuel ratio upstream of NOx trap 72. After time t4, the entering air-fuel ratio can be measured by sensor 140 and thus can be used for control or monitoring.
Referring to
While the current effective-distance-traveled measure DIST_EFF_CUR is determined in any suitable manner, in the exemplary system, the controller 12 generates the current effective-distance-traveled measure DIST_EFF_CUR at step 1620 by accumulating detected or determined values for instantaneous vehicle speed VS, as may itself be derived, for example, from engine speed N and selected-transmission-gear information. Further, in the exemplary system, the controller 12 “clips” the detected or determined vehicle speed at a minimum velocity VS_MIN, for example, typically ranging from perhaps about 0.2 mph to about 0.3 mph (about 0.3 km/hr to about 0.5 km/hr), in order to include the corresponding “effective” distance traveled, for purposes of emissions, when the vehicle is traveling below that speed, or is at a stop. Most preferably, the minimum predetermined vehicle speed VS_MIN is characterized by a level of NOx emissions that is at least as great as the levels of NOx emissions generated by the engine 10 when idling at stoichiometry.
At step 1622, the controller 12 determines a modified emissions measure NOX_CUR as the total emissions measure TP_NOX_TOT divided by the effective-distance-traveled measure DIST_EFF_CUR. As noted above, the modified emissions measure NOX_CUR is favorably expressed in units of “grams per mile.”
Because certain characteristics of current vehicle activity impact vehicle emissions, for example, generating increased levels of exhaust gas constituents upon experiencing an increase in either the frequency and/or the magnitude of changes in engine output, the controller 12 determines a measure ACTIVITY representing a current level of vehicle activity (at step 1624 of
While the vehicle activity measure ACTIVITY is determined at step 1624 in any suitable manner based upon one or more measures of engine or vehicle output, including but not limited to a determined desired power, vehicle speed VS, engine speed N, engine torque, wheel torque, or wheel power, in the exemplary system, the controller 12 generates the vehicle activity measure ACTIVITY based upon a determination of instantaneous absolute engine power Pe, as follows:
Pe=TQ*N*kI,
where TQ represents a detected or determined value for the engine's absolute torque output, N represents engine speed, and kI is a predetermined constant representing the system's moment of inertia. The controller 12 filters the determined values Pe over time, for example, using a high-pass filter G1(s), where s is the Laplace operator known to those skilled in the art, to produce a high-pass filtered engine power value Hpe. After taking the absolute value AHPe of the high-pass-filtered engine power value Hpe, the resulting absolute value AHPe is low-pass-filtered with filter G1(s) to obtain the desired vehicle activity measure ACTIVITY.
Similarly, while the current permissible emissions lend NOX_MAX is modified in any suitable manner to reflect current vehicle activity, in the exemplary system, at step 1626, the controller 12 determines a current permissible emissions level NOX_MAX as a predetermined function f5 of the predetermined maximum emissions threshold NOX_MAX_STD based on the determined vehicle activity measure ACTIVITY. By way of example only, in the exemplary system, the current permissible emissions level NOX_MAX typically varies between a minimum of about 20 percent of the predetermined maximum emissions threshold NOX_MAX_STD for relatively-high vehicle activity levels (e.g., for many transients) to a maximum of about seventy percent of the predetermined maximum emissions threshold NOX_MAX_STD (the latter value providing a “safety factor” ensuring that actual vehicle emissions do not exceed the proscribed government standard NOX_MAX_STD). See also FIG. 8.
Referring again to
If, at step 1614 of
Those skilled in the art will recognize in view of this disclosure that the above methods are applicable with any decontamination method. In a preferred embodiment, the decontamination method described in U.S. Pat. No. 5,758,493, which is hereby incorporated by reference, can be used.
Although several examples of embodiments which practice the invention have been described herein, there are numerous other examples which could also be described. The invention is therefore to be defined only in accordance with the following claims.
The present application claims priority from provisional application U.S. Ser. No. 60/190,249, filed Mar. 17, 2000.
Number | Name | Date | Kind |
---|---|---|---|
3696618 | Boyd et al. | Oct 1972 | A |
3969932 | Rieger et al. | Jul 1976 | A |
4033122 | Masaki et al. | Jul 1977 | A |
4036014 | Ariga | Jul 1977 | A |
4178883 | Herth | Dec 1979 | A |
4251989 | Norimatsu et al. | Feb 1981 | A |
4416497 | Brandsness et al. | Nov 1983 | A |
4622809 | Abthoff et al. | Nov 1986 | A |
4854123 | Inoue | Aug 1989 | A |
4884066 | Miyata et al. | Nov 1989 | A |
4887576 | Inamoto et al. | Dec 1989 | A |
4913122 | Uchida et al. | Apr 1990 | A |
4915080 | Nakaniwa et al. | Apr 1990 | A |
4964272 | Kayanuma | Oct 1990 | A |
5009210 | Nakagawa et al. | Apr 1991 | A |
5059947 | Chen | Oct 1991 | A |
5088281 | Izutani et al. | Feb 1992 | A |
5097700 | Nakane | Mar 1992 | A |
5165230 | Kayanuma et al. | Nov 1992 | A |
5174111 | Nomura et al. | Dec 1992 | A |
5189876 | Hirota et al. | Mar 1993 | A |
5201802 | Hirota et al. | Apr 1993 | A |
5209061 | Takeshima | May 1993 | A |
5222471 | Stueven | Jun 1993 | A |
5233830 | Takeshima et al. | Aug 1993 | A |
5267439 | Raff et al. | Dec 1993 | A |
5270024 | Kasahara et al. | Dec 1993 | A |
5272871 | Oshima et al. | Dec 1993 | A |
5325664 | Seki et al. | Jul 1994 | A |
5331808 | Koike | Jul 1994 | A |
5331809 | Takeshima et al. | Jul 1994 | A |
5335538 | Blischke et al. | Aug 1994 | A |
5341643 | Hamburg et al. | Aug 1994 | A |
5357750 | Ito et al. | Oct 1994 | A |
5377484 | Shimizu | Jan 1995 | A |
5402641 | Katoh et al. | Apr 1995 | A |
5410873 | Tashiro | May 1995 | A |
5412945 | Katoh et al. | May 1995 | A |
5412946 | Oshima et al. | May 1995 | A |
5414994 | Cullen et al. | May 1995 | A |
5419122 | Tabe et al. | May 1995 | A |
5423181 | Katoh et al. | Jun 1995 | A |
5426934 | Hunt et al. | Jun 1995 | A |
5433074 | Seto et al. | Jul 1995 | A |
5437153 | Takeshima et al. | Aug 1995 | A |
5444977 | Kawabata | Aug 1995 | A |
5448887 | Takeshima | Sep 1995 | A |
5450722 | Takeshima et al. | Sep 1995 | A |
5452576 | Hamburg et al. | Sep 1995 | A |
5472673 | Goto et al. | Dec 1995 | A |
5473887 | Takeshima et al. | Dec 1995 | A |
5473890 | Takeshima et al. | Dec 1995 | A |
5483795 | Katoh et al. | Jan 1996 | A |
5531972 | Rudy | Jul 1996 | A |
5544482 | Matsumoto et al. | Aug 1996 | A |
5551231 | Tanaka et al. | Sep 1996 | A |
5554269 | Joseph et al. | Sep 1996 | A |
5564283 | Yano et al. | Oct 1996 | A |
5577382 | Kihara et al. | Nov 1996 | A |
5595060 | Togai et al. | Jan 1997 | A |
5598703 | Hamburg et al. | Feb 1997 | A |
5622047 | Yamashita et al. | Apr 1997 | A |
5626014 | Hepburn et al. | May 1997 | A |
5626117 | Wright et al. | May 1997 | A |
5642709 | Ozaki et al. | Jul 1997 | A |
5655363 | Ito et al. | Aug 1997 | A |
5657625 | Koga et al. | Aug 1997 | A |
5657732 | Wolters et al. | Aug 1997 | A |
5693877 | Ohsuga et al. | Dec 1997 | A |
5713199 | Takeshima et al. | Feb 1998 | A |
5715679 | Asanuma et al. | Feb 1998 | A |
5722236 | Cullen et al. | Mar 1998 | A |
5724808 | Ito et al. | Mar 1998 | A |
5727528 | Hori et al. | Mar 1998 | A |
5729971 | Matsuno et al. | Mar 1998 | A |
5732554 | Sasaki et al. | Mar 1998 | A |
5735119 | Asanuma et al. | Apr 1998 | A |
5740669 | Kinugasa et al. | Apr 1998 | A |
5743084 | Hepburn | Apr 1998 | A |
5746049 | Cullen et al. | May 1998 | A |
5746052 | Kinugasa et al. | May 1998 | A |
5752492 | Kato et al. | May 1998 | A |
5758493 | Asik et al. | Jun 1998 | A |
5771685 | Hepburn | Jun 1998 | A |
5771686 | Pischinger et al. | Jun 1998 | A |
5778666 | Cullen et al. | Jul 1998 | A |
5792436 | Feeley et al. | Aug 1998 | A |
5802843 | Kurihara et al. | Sep 1998 | A |
5803048 | Yano et al. | Sep 1998 | A |
5832722 | Cullen et al. | Nov 1998 | A |
5842339 | Bush et al. | Dec 1998 | A |
5842340 | Bush et al. | Dec 1998 | A |
5865027 | Hanafusa et al. | Feb 1999 | A |
5877413 | Hamburg et al. | Mar 1999 | A |
5910096 | Hepburn et al. | Jun 1999 | A |
5929320 | Yoo | Jul 1999 | A |
5938715 | Zhang et al. | Aug 1999 | A |
5953907 | Kato et al. | Sep 1999 | A |
5966930 | Hatano et al. | Oct 1999 | A |
5970707 | Sawada et al. | Oct 1999 | A |
5974788 | Hepburn et al. | Nov 1999 | A |
5974791 | Hirota et al. | Nov 1999 | A |
5974793 | Kinugasa et al. | Nov 1999 | A |
5974794 | Gotoh et al. | Nov 1999 | A |
5979161 | Hanafusa et al. | Nov 1999 | A |
5983627 | Asik | Nov 1999 | A |
5992142 | Pott | Nov 1999 | A |
5996338 | Hirota | Dec 1999 | A |
6003308 | Tsutsumi et al. | Dec 1999 | A |
6012282 | Kato et al. | Jan 2000 | A |
6012428 | Yano et al. | Jan 2000 | A |
6014859 | Yoshizaki et al. | Jan 2000 | A |
6023929 | Ma | Feb 2000 | A |
6026640 | Kato et al. | Feb 2000 | A |
6058700 | Yamashita et al. | May 2000 | A |
6073440 | Douta et al. | Jun 2000 | A |
6082176 | Kondo et al. | Jul 2000 | A |
6092369 | Hosogai et al. | Jul 2000 | A |
6119449 | Köhler | Sep 2000 | A |
6128899 | Oono et al. | Oct 2000 | A |
6134883 | Kato et al. | Oct 2000 | A |
6138453 | Sawada et al. | Oct 2000 | A |
6148612 | Yamashita et al. | Nov 2000 | A |
6161378 | Hanaoka et al. | Dec 2000 | A |
6167695 | Itou et al. | Jan 2001 | B1 |
6214207 | Miyata et al. | Apr 2001 | B1 |
6263666 | Kubo et al. | Jul 2001 | B1 |
6309536 | Inagaki et al. | Oct 2001 | B1 |
6311480 | Suzuki et al. | Nov 2001 | B1 |
6375828 | Ando et al. | Apr 2002 | B2 |
Number | Date | Country |
---|---|---|
196 07 151 | Jul 1997 | DE |
0 351 197 | Jan 1990 | EP |
0 351 197 | Jan 1990 | EP |
0 444 783 | Sep 1991 | EP |
0 503 882 | Sep 1992 | EP |
0 580 389 | Jan 1994 | EP |
0859232 | Aug 1998 | EP |
1 597 752 | Sep 1981 | GB |
2 270 777 | Mar 1994 | GB |
2 307 313 | May 1997 | GB |
62-97630 | May 1987 | JP |
62-117620 | May 1987 | JP |
64-53042 | Mar 1989 | JP |
2-30915 | Feb 1990 | JP |
2-33408 | Feb 1990 | JP |
3-135417 | Jun 1991 | JP |
5-26080 | Feb 1993 | JP |
5-106493 | Apr 1993 | JP |
5-106494 | Apr 1993 | JP |
6-58139 | Mar 1994 | JP |
6-264787 | Sep 1994 | JP |
7-94941 | Apr 1995 | JP |
11-101154 | Apr 1999 | JP |
2000-282942 | Oct 2000 | JP |
WO 9827322 | Jun 1998 | WO |
Number | Date | Country | |
---|---|---|---|
60190249 | Mar 2000 | US |