Claims
- 1. Detergent compositions containing a high sudsing amine oxide surfactant and an antifoaming combination, and having low-foaming and accelerated defoaming characteristics; said antifoaming combination consisting essentially of a foam inhibiting amount of the following:
- (a) a carboxylated poly(oxyalkylated) alcohol cosurfactant having the formula ##STR7## wherein R is a hydrocarbon-containing group having from about 6 to about 18 carbon atoms; each R' is independently selected from the group of hydrogen, methyl and carboxylic acid-containing groups having from 1 to 6 carbon atoms wherein said cosurfactant contains at least one such carboxylic acid-containing group; M is selected from the group of sulfate and hydrogen; and x is a number from about 3 to about 75; and
- (b) a silicone antifoaming agent, wherein the weight ratio of the cosurfactant to the silicone antifoaming agent is from about 40:1 to about 5:1, wberein said silicone antifoaming agent has siloxane moieties having The formula: ##STR8## wherein x is a number from about 20 to about 2,000, and R.sub.6 and R.sub.7 are each independently alkyl groups each independently containing from 1 to about 4 carbon atoms.
- 2. A detergent composition according to claim 1 wherein said composition is a granular formulation.
- 3. A detergent composition according to claim 1 wherein said composition is an aqueous liquid.
- 4. A detergent composition according to claim 3 wherein said composition is titrated with an acid to a pH of from about 3 to about 6 and comprises from about 1% to about 50% by weight of an amine oxide surfactant.
- 5. A detergent composition according to claim 4 wherein said composition comprises from about 2% to about 30% by weight of an amine oxide surfactant.
- 6. A detergent composition comprising:
- (a) a carboxylated poly(oxyalkylated) alcohol cosurfactant having the formula: ##STR9## wherein R is a hydrocarbon-containing group having from about 6 to about 18 carbon atoms; each R' is independently selected from the group of hydrogen, methyl and carboxylic acid-containing groups having from 1 to 6 carbon atoms; M is selected from the group of sulfate and hydrogen; and x is a number from about 3 to about 75; and wherein said cosurfactant contains at least one carboxylic acid-containing group having from 1 to 6 carbon atoms;
- (b) from about 0.006% to about 1%, by weight of the composition, silicone antifoam agent; and
- (c) from about 1% to about 60%, by weight of the composition, amine oxide surfactant;
- wherein the weight ratio of carboxylated poly(oxyalkylated) alcohol to silicone antifoaming agent is from about40:1 to about 5:1.
- 7. A detergent composition according to claim 6 in the form of a liquid wherein the liquid has a pH of from about 8 to about 10.
- 8. A method of improving sudsing inhibition by a silicone antifoaming agent comprising the step of adding a carboxylated poly(oxyalkylated) alcohol to the silicone antifoaming agent in a weight ratio of from about 40:1 to about 5:1 carboxylated poly(oxyalkylated) alcohol to silicone antifoaming agent; wherein the carboxylated poly(oxyalkylated) alcohol has the formula: ##STR10## wherein R is a hydrocarbon-containing group having from about 6 to about 18 carbon atoms; each R' is independently selected from the group of hydrogen, methyl and carboxylic acid-containing groups having from 1 to 6 carbon atoms; M is selected from the group of sulfate and hydrogen; and x is a number from about 3 to about 75; and wherein said cosurfactant contains at least one carboxylic acid-containing group having from 1 to 6 carbon atoms.
- 9. A method according to claim 8 further comprising the step of adding a surfactant to form a detergent composition, wherein the silicone antifoaming agent is present at a level of from about 0.006% to about 1.0%, by weight of the detergent composition, and the carboxylated poly(oxylated) alcohol is present at a level of from about 1.0% to about 2.0%, by weight of the detergent composition.
Parent Case Info
This is a continuation of application Ser. No. 08/674,045, filed on Jul. 1, 1996 now abandoned which is a continuation of Ser. No. 08/392,534, filed Mar. 1, 1995, now abandoned, which is a Continuation-in-Part of Ser. No. 08/220,137 filed Mar. 30, 1994 in the name of Thomas J. Wierenga, now abandoned.
US Referenced Citations (17)
Non-Patent Literature Citations (3)
Entry |
Olin Chemicals, Technical Bulletin, poly-tergent C- series sequestering polycarboxylated surfactants, CD-1541 (Apr. 26, 1991). |
Olin Chemicals, Technical Bulletin, "Olin Surfactants Product Data", 721-052 (Jun. 1989). |
Olin Chemicals, Technical Bulletin, "Olin Surfactants Product Data", 721-053R (Jun. 1991). |
Continuations (3)
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674045 |
Jul 1996 |
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392534 |
Mar 1995 |
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220137 |
Mar 1994 |
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