This specification relates to devices and processes for pressing waste, in particular for pressing organic waste at a pressure higher than the bursting pressure of biological cells.
The following background description is not an admission that anything described below is common general knowledge or citable prior art.
Municipal solid waste (MSW) typically contains inert material, such as plastic, glass and metal, as well as an organic fraction made up of, for example, food waste and garden waste. In some cases, organic waste is collected separately from households. In other cases, inert material may be separated from organic waste at a central facility. Overall, waste streams may be created that consist entirely, or at least primarily, of organic waste or that have an organic fraction mixed with inert material. Agricultural and industrial waste may also consist of organic waste, or may have an organic fraction mixed with inert material.
The organic waste can be processed by anaerobic digestion. US Publication No. 2013/0316428 describes a process of pressing organic waste through a grid of small bore holes under a pressure higher than the bursting pressure of the cell membranes. The bursting pressure is typically about 50 bar. A pressate gel of doughy consistency is produced and loaded into an anaerobic digester. The press may be as described in European Publication Nos. 1207040 and 1568478. In general, these presses use a plunger to compress waste that has been loaded into a cylinder. The sides of the cylinder are perforated with radial holes.
The following summary is intended to introduce the reader to the detailed description that follows, and not to limit or define any claimed invention.
A press described in this specification has two plungers. Preferably, the plungers have rectangular cross sections. The two plungers are mounted in the press such that they are perpendicular to each other in a plane and have partially overlapping stokes. The press also has walls that partially enclose a pressing chamber. The pressing chamber covers a rectangular area of the plane that is as wide as one plunger on one side of the rectangle, and as wide as the other plunger on the other side of the rectangle.
In operation, one of the two plungers is used to partially enclose the pressing chamber while the waste is compressed, to eject compressed waste from the pressing chamber and, optionally, to load organic waste into the pressing chamber. The other plunger is used to compress waste in the pressing chamber. The other plunger may also partially enclose the pressing chamber while compressed waste is ejected.
The press 100 has a frame 1, only parts of which are shown in
Optionally, the frame 1 also extends outwards from the pressing chamber 3 to support a first plunger 4 and a second plunger 12. The first plunger 4 and the second plunger 12 each have a height essentially equal to the height of the pressing chamber 3. The precise height of the plungers 4, 12 is reduced relative to the height of the pressing chamber 3 to provide a tolerance and allow the plungers 4, 12 to move into the pressing chamber 3 from the positions shown in
The frame 1 includes a wall 9 that provides an end wall of the pressing chamber 3. A door, preferably a sliding door 10, is available to selectively provide a wall on one side of the pressing chamber 3. When the first plunger 4 and the second plunger 12 are positioned as shown in
As shown in
Perforations 6 are provided in at least one wall of the pressing chamber 3. The perforations 6 preferably have a diameter of 12 mm or less, more preferably 8 mm or less. Optionally, perforations 6 can be provided in any one or more walls of the pressing chamber 3. For example, perforations 6 can also be provided in part of the frame 1 that provides the bottom wall of the pressing chamber 3, or in the face of the first plunger 4 that provides another end wall of the pressing chamber 3, or both. Preferably, at least some of the perforations 6 are located in end wall 9 or in the face of the first plunger 4. Perforations 6 in these surfaces are oriented parallel to the movement of the first plunger 4 and do not plug as often as perforations 6 in other walls of the pressing chamber 3.
The second plunger 12 can be moved between at least 2 positions. In the example shown, the second plunger 12 can be moved between 3 positions. In
The first plunger 4 can also be moved between at least 2 positions. In
In use, the press 100 operates through a repeated cycle of steps to press batches of waste. In a first step, waste is loaded into the pressing chamber 3. The second plunger 12 is retracted to position C and waste is dropped from above onto the frame 1 between the front of second plunger 12 and the pressing chamber 3. Then, with the first plunger 4 in position A and the sliding door 10 closed, the second plunger 12 advances from position C to position D. Preferably, the distance between position C and position D is greater than the distance across the pressing chamber 3 in the direction of motion of the second plunger 12. In this way, the waste is pre-compressed as it is loaded into the pressing chamber 3. Alternatively, waste can be pre-compressed in the pressing chamber 3 by repeating the second step a sufficient number of times.
In another option, waste could be loaded through the top or bottom of the pressing chamber 3. However, this is likely to weaken the frame 1 and could make it more difficult to use the second plunger 12 to pre-compress the waste. In yet another option, the waste could be loaded into pressing chamber 3 using the first plunger 4, but this is not preferred. First plunger 4 will be used to provide the final compression of the waste, preferably to a pressure of 50 bar or more, for example 180 bar. Accordingly, the first plunger 4 is driven by a powerful device such as a large diameter hydraulic piston. The time required to press a batch of waste, or the energy required to press a batch of waste, or both, are likely to increase with increased movement of the first plunger 4.
Even when pre-compressing material as described above, some types of waste are still not efficiently loaded into the pressing chamber 3. In these cases, the waste can also be compressed as it is being loaded onto the frame 1. For example, the waste can be pushed through a hopper that becomes narrower towards its exit. Alternatively, a flap or other mechanism can be used to press the waste onto the frame 1 rather than merely dropping the waste onto the frame 1 by force of gravity alone. Even when additional pre-compression is not required, using a flap to press waste onto the frame 1 in front of the second plunger 12 can be useful because it prevents long items, such as sticks and wire, from protruding upwards beyond the top of the second plunger 12. Although the second plunger 12 could be made strong enough to shear long items against the frame 1 as they are pushed into the pressing chamber 3, there is less risk of stopping production if long items are pushed down onto the frame 1 before pushing them into the pressing chamber 3.
In a second step, the waste is compressed. With the sliding door 10 closed and the second plunger 12 at position D, the first plunger 4 moves from position A to position B. As the waste is compressed, pressate is pushed through the perforations 6 and falls from the press 100. The precise location of position B may be predetermined based on design calculations to predict when the waste will reach a desired minimum pressure or degree of compaction. In some cases, position B could be near to or at the end wall 9. Alternatively, the first plunger 4 may be advanced until a specified pressure is reached in the pressing chamber 3. Optionally, the first plunger 4 may dwell in its advanced position for a period of time to allow liquids and small solid particles to travel through the waste to the perforations 6.
While the waste is being compressed, a substantial force is created against the second plunger 12. This force is resisted by sliding one or more locks 25 to the position shown in dashed lines in
In a third step, remaining waste is ejected from the pressing chamber 3. The first plunger 4 is retracted to position A and sliding door 10 is opened. Second plunger 12 is moved from position D to position E. The remaining waste is thereby ejected through the side of the pressing chamber. Alternatively, the first plunger 4 could eject the waste, but this is not preferred. As discussed above, it is preferable to avoid moving the first plunger 4 other than to compress the waste and retract in the second step. Energy consumption or time, or both, can be reduced by having the first plunger 4 travel only part way through the pressing chamber 3 when possible.
Preferably, the second plunger 12 scrapes waste from the top, bottom and end walls of the pressing chamber 3, including the front face of the first plunger 4, as it ejects the waste. The pressate, and similar material remaining in the pressing chamber 3, flows like a liquid only under the high pressures created within the pressing chamber 3. Once the pressure is released, the pressate acts like a solid. If allowed to dry, the pressate becomes extremely difficult to remove. Therefore, it is useful to have the second plunger 12 sweep through the pressing chamber 3 and remove substantially all of the remaining waste from the pressing chamber 3 and the front of the first plunger 4. From time to time, for example before turning the press 100 off for a period of time, a scraping sweep with the second plunger 12 can be followed by sweeping the first plunger 4 through the entire pressing chamber 3 to scrape waste from the inside of the sliding door 10 and the front of the second plunger 12. Waste removed by the first plunger 4 in this way may be pressed trough the perforations 6 in end wall 9 or compacted against the end wall 9 so that one more sweep with the second plunger 12 can substantially clean the pressing chamber 3. In the more detailed examples to be described further below, the outside surface of any wall with perforations 6 is also scraped, preferably in every cycle, to remove pressate from these surfaces.
The sliding door 10 covers a side of the pressing chamber 3 that is essentially the same size and shape as the front of the second plunger 12. This helps the second plunger 12 clean out the pressing chamber 3 as described above. Even though most waste is sorted to some extent, the waste can still sometimes contain large incompressible pieces such as bricks or metal. These items can block the first plunger 4 from reaching its expected position or pressure, and so the process stops and the first plunger 4 must be retracted. With a large sliding door 10 and second plunger 12 that can sweep through the entire pressing chamber 3, almost anything that entered the pressing chamber 3 can be removed and the press 100 can return to production quickly.
The press 100 may be used in a process for treating organic waste. As the first plunger 4 advances into the pressing chamber 3, a pressate is forced out of the press 100 through perforations 6. Preferably, the pressure applied to the organic waste is 50 bar or more, which causes cells in the organic waste to burst. The pressate includes liquid from within the cells, liquid from the organic waste generally, and solids suspended or dissolved in these liquids. Despite the presence of some liquid, the pressate typically has a high solids concentration and is handled as a biosolid. For example, the pressate may drop from the press 100 to a screw auger or conveyor belt to be carried away from the press 100. The pressate may be loaded into an anaerobic digester for further treatment.
The press 100 may be used to provide the extrusion press in a device or process as described in US Publication No. US 2013/0316428 A1, Process for the Production of Fuel Gas from Municipal Solid Waste. US 2013/0316428 A1 is incorporated herein by reference. International application No. PCT/NL2014/000026 is also incorporated herein by reference.
The term ‘perpendicularly’ and related terms are understood in the context of the invention to mean ‘at least substantially perpendicularly’. Pressing perpendicularly of the surface can, in some cases, result in a more effective and efficient pressing. Perforations can also be arranged here in the first pressing member. Preferably, there are perforations in both the fixed wall and the first pressing member. The first pressing member preferably comprises a first plunger. Using a plunger, in contrast to for instance an auger, the pressure in the pressing chamber and the compacted material can be properly controlled and a high pressure can be readily realized.
The device preferably also comprises a second pressing member, more preferably a second plunger, for discharging compacted waste from the pressing chamber through the discharge opening. The pressing direction of the second pressing member preferably lies perpendicularly of the pressing direction of the first pressing member and the cross-section of the second pressing member is the same as the cross-section of the discharge opening. The term ‘the same’ and similar terms are understood in the context of the invention to mean ‘at least substantially the same’. The term ‘cross-section’ is understood here to mean ‘the active cross-section perpendicularly of the direction of movement’. It is thus found that the discharge of compacted material can take place simply with only a small chance of malfunctions, for instance due to larger pieces of solid material becoming jammed in the device.
These devices preferably also have, a second feed opening for feeding waste into the device; and, an infeed chamber, which infeed chamber is located between the first feed opening and the second feed opening.
In a first extreme position of the first pressing member the infeed chamber can be situated here between the pressing surface of the first pressing member and the first feed opening. Waste fed into the infeed chamber can then be displaced by means of the second pressing member via the first feed opening to the pressing chamber and there subsequently compacted by means of the first pressing member. In a first extreme position of the second pressing member the infeed chamber can also be situated between the pressing surface of the second pressing member and the first feed opening. Waste fed into the infeed chamber can then be displaced by means of the second pressing member via the first feed opening to the pressing chamber and there subsequently compacted by means of the first pressing member. The term ‘pressing surface’ is understood in the context of the invention to mean ‘the part of the periphery exerting pressure on the relevant material during pressing or displacement’. ‘Between the pressing surface of a pressing member and a feed opening’ is understood here to mean ‘between a first plane in which the pressing surface lies and a second plane in which the feed opening lines’. A pre-compaction takes place during the displacement of waste fed into the infeed chamber to the pressing chamber via the first feed opening. In some cases, this may further increase the effectiveness, efficiency and yield of the pressing.
The device (100) shown in
First plunger (4) is movable between two extreme positions by means of a drive, here a first hydraulic cylinder (15). In the first extreme position (shown in
Device (100) also comprises a discharge opening (8) for discharging compacted waste from pressing chamber (3). Discharge opening (8) can be closed by means of a first door, here a sliding door (10). Device (100) also comprises a second pressing member, here a second plunger (12), movable by means of a drive, here a second hydraulic cylinder (16), for discharging compacted waste out of pressing chamber (3) through discharge opening (8). The pressing direction of second plunger (12) lies perpendicularly here of the pressing direction of first plunger (4). Second plunger (12) is movable between two extreme positions, a first extreme position (shown in
The device (200) shown in
First plunger (4) is again movable by means of a drive, here again a first hydraulic cylinder (15), again between two extreme positions. In the first extreme position (shown in
Discharge opening (8) can again be closed by means of a first door, here again a sliding door (10), driven here by means of a third hydraulic cylinder (22). Second plunger (12) is again movable between two extreme positions. In a first extreme position (shown in
The cross-section, i.e. the active cross-section perpendicularly of the direction of movement, of second plunger (12) is the same as the cross-section of discharge opening (8). All waste compacted in pressing chamber (3) can in principle thus be removed from pressing chamber (3) via discharge opening (8) by means of second plunger (12) when sliding door (10) is opened and first plunger (4) is in its first extreme position (as shown in
Device (200) also comprises a provision, here a slide (18) driven by means of a fourth hydraulic cylinder (19), for discharging pressed-out organic material, present here in a space (17) provided for this purpose in first plunger (4). Slide 18 and fourth hydraulic cylinder 19 also scrape pressate from the back side of perforations 6 of first plunger (4). Device (200) can comprise more of such provisions (not shown), for instance also for the purpose of removing pressed-out material in the vicinity of the perforated wall (9).
Device (300) shown in
Device (400) shown in
Device 400 also has second a slide (18) driven by means of another fourth hydraulic cylinder (19), to scrape pressate from the back side of perforations 6 in frame 1. A first slide 18 scrapes pressate from the back of perforations 6 in the first plunger 4. Device 400 also has a lock 25 that can slide in a whole in the frame 1. The lock 25 can be selectively slid into indentation (not shown) in second plunger 12 to hold second plunger 12 in place while first plunger 4 compresses the waste.
In a device (200; 400) according to the invention comprising an infeed chamber (13) 30 located between second feed opening (2) and the first feed opening the waste is not fed directly into pressing chamber (3) but via infeed chamber (13). In addition to the stated advantages of pre-compaction and limiting the stroke required by first plunger (4), this also has structural advantages. The walls of pressing chamber (3) then have fewer openings, whereby they can better absorb the great forces exerted thereon.
Operation with a device (100; 200; 300; 400) according to the invention can take place as 5 follows. Perforations (6) have for instance a size of 4 to 8 mm. When during pressing a desired final pressure of for instance 50 bar or more, 100 bar or more or between 200-300 bar has been reached, first plunger (4) can be moved back. Discharge opening (8) can subsequently be opened by sliding away the sliding door (10) present in a side wall of pressing chamber (3). The remaining solid material can then be pressed out of pressing chamber (3) from an opposite side wall of 10 pressing chamber (3) by means of second plunger (12). Plungers (4, 12) then return to their rest positions (first extreme positions) and sliding door (10) is closed for the following cycle. The organic material pressed through perforations (6) is collected and carried away, optionally using additional plungers or slides.
Owing to the relatively high pressure, whereby the cell walls break and the organic material becomes more pasty and fluid, but also due to pressing through the relatively small perforations (6), very few interfering substances will be present in the pressed-out material. Stainless steel objects, such as knives and forks, which cannot be removed in a magnetic pre-processing, will thus not appear in the pressed-out material. The pressed-out material will also be greatly reduced in size as it passes through the relatively small perforations, and the proportion of glass and sand will decrease, as will the proportion of plastics. As a result of all this it will be possible to digest the pressed-out material more easily, completely and rapidly compared to un-pressed waste. Further, downtime caused by interfering substances is limited.
What remains in the pressing chamber after pressing is largely free of organic material and moisture. The remaining material has a greatly reduced moisture content, whereby the calorific value is greatly increased. Because the remaining material is relatively dry, it can also be further separated more easily since dry material adheres less than moist material.
Owing to the relatively simple construction with a pressing chamber that is wholly closed during pressing and with few moving parts, the device is robust. It has also become easy to replace wearing parts, such as the perforated parts. The drives and guides of the plungers are loaded less than in some other devices.
It will be apparent that the invention is not limited to the shown and described exemplary presses but that diverse variants which may appear to a skilled person are possible within the scope of the invention. In addition to being used for pressing organic material out of waste, the invention can also be applied for pressing another softer, more deformable or liquid fraction from a mixture also comprising a more solid and less deformable fraction.
Number | Date | Country | Kind |
---|---|---|---|
1040442 | Oct 2013 | NL | national |
This application claims the benefit of U.S. Provisional Application No. 62/044,625 filed on Sep. 2, 2014; and is a continuation-in-part of PCT Application No. PCT/NL2014/000026 filed on Aug. 28, 2014 which claims priority to Dutch Application No. NL 1040442 filed Oct. 13, 2013. U.S. Provisional Application No. 62/044,625; PCT Application No. PCT/NL2014/000026; and Dutch Application No. NL 1040442 are incorporated by reference.
Number | Name | Date | Kind |
---|---|---|---|
1014893 | Henry | Jan 1912 | A |
1328259 | Barbet | Jan 1920 | A |
2000444 | Hechenbleikner | May 1935 | A |
2289953 | Aldridge | Jul 1942 | A |
2854827 | Lockerbie et al. | Oct 1958 | A |
2937506 | Stirlen | May 1960 | A |
3005403 | Endert | Oct 1961 | A |
3255887 | Walker et al. | Jun 1966 | A |
3365860 | Boris | Jan 1968 | A |
3451185 | Kunitoshi | Jun 1969 | A |
3491682 | Nils et al. | Jan 1970 | A |
3517732 | Robert | Jun 1970 | A |
3618905 | Primus | Nov 1971 | A |
3858504 | Boyer | Jan 1975 | A |
3864440 | Giocoechea | Feb 1975 | A |
4036356 | Reist | Jul 1977 | A |
4036359 | Strickland, Jr. | Jul 1977 | A |
4098690 | Semmens | Jul 1978 | A |
4121515 | Tea | Oct 1978 | A |
4162147 | Haverkamp | Jul 1979 | A |
4198359 | Todd | Apr 1980 | A |
4232600 | Le Jeune | Nov 1980 | A |
4294812 | Oler | Oct 1981 | A |
4343233 | Burgin | Aug 1982 | A |
4414103 | Farrell | Nov 1983 | A |
4417510 | Sharp | Nov 1983 | A |
4477341 | Schweiss et al. | Oct 1984 | A |
4594942 | Denneboom | Jun 1986 | A |
4613431 | Miller | Sep 1986 | A |
4618462 | Fisher | Oct 1986 | A |
4650546 | Le Jeune | Mar 1987 | A |
4691628 | Simpson | Sep 1987 | A |
4770748 | Cellini et al. | Sep 1988 | A |
4861524 | Sielaff et al. | Aug 1989 | A |
4880504 | Cellini et al. | Nov 1989 | A |
5030362 | Da et al. | Jul 1991 | A |
5146848 | Dufour | Sep 1992 | A |
5203261 | Davis | Apr 1993 | A |
5273572 | Baker et al. | Dec 1993 | A |
5400726 | Dumons | Mar 1995 | A |
5458789 | Dickerson et al. | Oct 1995 | A |
5593590 | Steyskal | Jan 1997 | A |
5863444 | Murphy et al. | Jan 1999 | A |
6139601 | Wernimont | Oct 2000 | A |
6149887 | Lagas et al. | Nov 2000 | A |
6162284 | Mitchell et al. | Dec 2000 | A |
6178822 | Manning | Jan 2001 | B1 |
6178882 | Wagner | Jan 2001 | B1 |
6299774 | Ainsworth et al. | Oct 2001 | B1 |
6368849 | Norddahl | Apr 2002 | B1 |
6383544 | Elkins | May 2002 | B1 |
6409788 | Sower | Jun 2002 | B1 |
6464875 | Woodruff | Oct 2002 | B1 |
6569332 | Ainsworth et al. | May 2003 | B2 |
6682578 | Sower | Jan 2004 | B2 |
6692642 | Josse et al. | Feb 2004 | B2 |
6715743 | Zhang | Apr 2004 | B2 |
6838069 | Blonigen et al. | Jan 2005 | B2 |
6846343 | Sower | Jan 2005 | B2 |
6866779 | Burke | Mar 2005 | B1 |
6916426 | Van et al. | Jul 2005 | B2 |
6920983 | Gabl | Jul 2005 | B2 |
6984323 | Khudenko | Jan 2006 | B2 |
6994021 | Krammer | Feb 2006 | B2 |
7014768 | Li et al. | Mar 2006 | B2 |
7153427 | Burke | Dec 2006 | B2 |
7204967 | Bierle et al. | Apr 2007 | B2 |
7416644 | Bonde | Aug 2008 | B2 |
7731850 | Choi et al. | Jun 2010 | B2 |
7806957 | Burke | Oct 2010 | B1 |
7814826 | Ribas-Blanes | Oct 2010 | B2 |
7927491 | Kotelko et al. | Apr 2011 | B2 |
8470567 | Facey et al. | Jun 2013 | B2 |
9045355 | Kumar et al. | Jun 2015 | B2 |
20010004063 | Oh | Jun 2001 | A1 |
20010033816 | Blonigen et al. | Oct 2001 | A1 |
20020134254 | Sebright et al. | Sep 2002 | A1 |
20020158024 | Van et al. | Oct 2002 | A1 |
20030084693 | Sower | May 2003 | A1 |
20030201225 | Josse et al. | Oct 2003 | A1 |
20040164021 | Li et al. | Aug 2004 | A1 |
20050047995 | Wylie | Mar 2005 | A1 |
20050139546 | Burke | Jun 2005 | A1 |
20060006055 | Bonde | Jan 2006 | A1 |
20070048212 | Bierle et al. | Mar 2007 | A1 |
20070141691 | Hirl | Jun 2007 | A1 |
20070297953 | Kemp et al. | Dec 2007 | A1 |
20080053909 | Fassbender | Mar 2008 | A1 |
20080053913 | Fassbender | Mar 2008 | A1 |
20080152571 | Hu et al. | Jun 2008 | A1 |
20080156709 | Johnson | Jul 2008 | A1 |
20080156726 | Fassbender | Jul 2008 | A1 |
20080302722 | Burke | Dec 2008 | A1 |
20090014377 | Janssen et al. | Jan 2009 | A1 |
20090095673 | Choate et al. | Apr 2009 | A1 |
20090206028 | Jiang et al. | Aug 2009 | A1 |
20090272282 | Fortier | Nov 2009 | A1 |
20100065250 | Frommann | Mar 2010 | A1 |
20100170845 | Baur et al. | Jul 2010 | A1 |
20100187182 | Vago | Jul 2010 | A1 |
20100218573 | Van | Sep 2010 | A1 |
20110091954 | Chen et al. | Apr 2011 | A1 |
20120122194 | Dumons | May 2012 | A1 |
20130316428 | Gonella | Nov 2013 | A1 |
20140033776 | Josse et al. | Feb 2014 | A1 |
20140144195 | Callendrello et al. | May 2014 | A1 |
20140157846 | Jeppson et al. | Jun 2014 | A1 |
20140314657 | Zhao et al. | Oct 2014 | A1 |
20170334739 | Theodoulou et al. | Nov 2017 | A1 |
Number | Date | Country |
---|---|---|
1117851 | Feb 1982 | CA |
2343832 | Oct 2002 | CA |
2381623 | Oct 2002 | CA |
2416690 | Jul 2004 | CA |
2416690 | Aug 2008 | CA |
2799408 | Nov 2011 | CA |
655048 | Mar 1986 | CH |
201841684 | May 2011 | CN |
101683771 | Dec 2011 | CN |
102442011 | May 2012 | CN |
2726233 | Dec 1978 | DE |
2841015 | Apr 1980 | DE |
8103406 | Apr 1981 | DE |
3113515 | Nov 1982 | DE |
4444032 | May 1996 | DE |
102008007818 | Aug 2009 | DE |
102009058166 | Jun 2011 | DE |
0043770 | Jan 1982 | EP |
0091365 | Oct 1983 | EP |
0468852 | Jan 1992 | EP |
0468853 | Jan 1992 | EP |
0494561 | Jul 1992 | EP |
0494154 | Sep 1995 | EP |
1215187 | Jun 2002 | EP |
1273393 | Jan 2003 | EP |
1173325 | Jul 2003 | EP |
1568478 | Aug 2005 | EP |
2014455 | Jan 2009 | EP |
2335914 | Jun 2011 | EP |
2344284 | Aug 2016 | EP |
2510474 | Feb 1983 | FR |
2615443 | Nov 1988 | FR |
2677579 | Dec 1992 | FR |
710383 | Jun 1954 | GB |
2139610 | Nov 1984 | GB |
2383034 | Jun 2003 | GB |
TO20111068 | May 2013 | IT |
S5533900 | Mar 1980 | JP |
H069793 | Feb 1994 | JP |
4678751 | Apr 2011 | JP |
9942423 | Aug 1999 | WO |
2009011906 | Jan 2009 | WO |
2010096899 | Sep 2010 | WO |
2010097177 | Sep 2010 | WO |
WO 2010097177 | Sep 2010 | WO |
2011156767 | Dec 2011 | WO |
2012109737 | Aug 2012 | WO |
2013091094 | Jun 2013 | WO |
2014094162 | Jun 2014 | WO |
Entry |
---|
Machine Translation of DE 3113515, Retrieved from Espacenet Apr. 1, 2021, 4 Pages. (Year: 1982). |
Machine Translation of JP 4678751, Retrieved from Espacenet Apr. 1, 2021, 13 Pages. (Year: 2011). |
Ammonia Recovery Process, http://www.thermoenergy.com/water-technologies/, retrieved on line 2011, 1 page. |
Bonmati et al., “Air Stripping of Ammonia From Pig Slurry: Characterisation and Feasibility as a Pre- or Post-Treatment to Mesophilic Anaerobic Digestion,” Waste Management, 2003, vol. 23 (3), pp. 261-272. |
Canadian Patent Application No. 2,826,025, Office Action dated Oct. 16, 2017. |
Cast Systems, www.thermoenergy.com/water-technologies/technologies . . . , 2011, retrieved from the Internet Nov. 2, 2011, 1 Page. |
CASTion Corporation, A Thermo Energy Company, “Ammonia Removal in Municipal Sludge Dewatering Centrate,” Pilot Test Results on Centrate, Dec. 1, 2008, 16 Pages. |
Chinese Patent Application No. 201480062263.3, Office Action dated Jul. 9, 2018—English Translation Available. |
Chinese Patent Application No. 201480062263.3, Office Action dated Dec. 13, 2017—English Translation Available. |
Chinese Patent Application No. 201480062263.3, Office Action dated Jun. 12, 2017 with English Translation. |
Chinese Patent Application No. 201480062263.3, Office Action dated Oct. 9, 2016—with English Translation. |
Chinese Patent Application No. 201480062263.3, Third Office Action dated Dec. 29, 2017—English Translation Available. |
Constantine, “An Overview of Ammonia and Nitrogen Removal in Wastewater Treatment”, CH2M Hill Canada, Feb. 19, 2008. |
Constantine, “North American Experience with Centrate Treatment Technologies for Ammonia and Nitrogen Removal,” WEFTEC Conference, 2006, pp. 5271-5281. |
Dhaliwal et al., “Distillation of Ammonia from Water and Wastewater,” Water Pollution Control Federation, Oct. 1985, vol. 57 (10), pp. 1036-1039. |
EPA, “Wastewater Technology Fact Sheet Ammonia Stripping,” United States Environmental Protection Agency, Sep. 2000, 4 pages. |
European Patent Application No. 12746463.4, Examination Report dated Jun. 21, 2018. |
European Application No. 12860692, Supplementary European Search Report dated Jul. 16, 2015. |
European Application No. 13866334.9, Supplementary Partial European Search Report dated Feb. 20, 2017. |
European Application No. 13866334.9, Supplementary Partial European Search Report dated Oct. 21, 2016. |
European Patent Application No. 12746463.4 Communication pursuant to Rule 70(2) and 70a(2) EPC dated Jul. 7, 2017. |
European Patent Application No. 12746463.4, Extended European Search Report dated Jun. 21, 2017. |
European Patent Application No. 12860692.8, Office Action dated Dec. 12, 2016. |
European Patent Application No. 12860692.8, Office Action dated Jan. 4, 2018. |
European Patent Application No. 15857098.6, Extended European Search Report dated Jun. 6, 2018. |
European Patent Application No. 16177423.7, European Search Report dated Dec. 5, 2016. |
Fernandez-Seara et al., “Distillation Column Configurations in Ammonia-Water Absorption Refrigeration Systems,” International Journal of Refrigeration, Jan. 2003, vol. 26 (1), pp. 28-34. |
Groth et al., English Language Abstract of DE4444032 entitled “Manure treatment in two stages, to release ammonia and concentrate slurry”, published May 2, 1996, 1 page. |
International Patent Application No. PCT/CA2012/000144, International Preliminary Reporton Patentability dated Aug. 29, 2013. |
International Patent Application No. PCT/CA2012/000144, International Search Report dated Jul. 10, 2012. |
International Patent Application No. PCT/CA2012/050907, International Preliminary Report on Patentability dated Jul. 3, 2014. |
International Patent Application No. PCT/CA2012/050907, International Search Report dated Mar. 25, 2013. |
International Patent Application No. PCT/CA2013/050985, International Preliminary Report on Patentability dated Jul. 2, 2015. |
International Patent Application No. PCT/CA2013/050985, International Search Report and Written Opinion dated Apr. 24, 2014. |
International Patent Application No. PCT/CA2015/051154, International Search Report and Written Opinion dated Jan. 25, 2016. |
International Patent Application No. PCT/NL2014/000026, International Preliminary Reporton Patentability dated Apr. 28, 2016. |
International Patent Application No. PCT/NL2014/000026, International Search Report and Written Opinion dated Dec. 5, 2014. |
Jorgensen et al., “Ammonia Removal from Wastewater by Ion Exchange in the Presence of Organic Contaminants,” Water Research, 2003, vol. 37, pp. 1723-1728. |
Netherland Patent Application No. 1040442, Search Report dated Apr. 16, 2014—No English Translation Available. |
Office Action for Canadian Application No. 20142926816 dated May 1, 2017. |
Oilgae, “New Technologies in Ammonia Removal from Wastewater”, http://www.oilge.com/algae/cult/sew/new/amm/amm.html, retrieved online Dec. 14, 2011, 10 Pages. |
Orentlicher et al., “Savings from Integration of Centrate Ammonia Reduction with BNR Operation: Simulation of Plant Operation,” ThermoEnergy Corporation, HydroQual Inc., undated, 25 pages, http://web2.uconn.edu/seagrantnybight/documents/nutrient%20docs/Orentlicher%20Savings%20Integration%20Centrate%20Ammonia%20Reduction.pdf. |
Thermoenergy, Ammonia Removal and Recovery Systems for Industrial Wastewater Treatment, http://www.thermoenergy.com/water-technologies/industrial-solutions/ammonia-removal . . . , retrieved online Dec. 14, 2011, 2 Pages. |
U.S. Appl. No. 15/209,293, Non-Final Office Action dated May 14, 2018. |
U.S. Appl. No. 13/823,404, Final Office Action dated Feb. 9, 2016. |
U.S. Appl. No. 13/823,404, Office Action dated Feb. 13, 2015. |
U.S. Appl. No. 13/823,404, Office Action dated May 21, 2015. |
U.S. Appl. No. 13/982,585, Office Action dated Dec. 14, 2015. |
U.S. Appl. No. 13/982,585, Office Action dated Sep. 18, 2015. |
U.S. Appl. No. 14/652,615, Final Office Action dated Jun. 7, 2017. |
U.S. Appl. No. 14/652,615, Notice of Allowance dated Jul. 21, 2017. |
U.S. Appl. No. 14/652,615, Office Action dated Feb. 10, 2017. |
U.S. Appl. No. 14/934,780, Non-Final Office Action dated Dec. 15, 2017. |
U.S. Appl. No. 14/934,780, Notice of Allowance dated Apr. 5, 2018. |
U.S. Appl. No. 14/934,780, Restriction Requirement dated Sep. 14, 2017. |
U.S. Appl. No. 15/027,885, Final Office Action dated Apr. 4, 2018. |
U.S. Appl. No. 15/027,885, Non-Final Office Action dated Jun. 15, 2017. |
U.S. Appl. No. 15/209,293, Restriction Requirement dated Feb. 16, 2018. |
U.S. Appl. No. 15/360,574, Non-Final Office Action dated Feb. 8, 2018. |
U.S. Appl. No. 15/475,028, Non-Final Office Action dated Jan. 25, 2018. |
Written Opinion for Application No. PCT/CA2012/000144, dated Jul. 10, 2012, 5 pages. |
Written Opinion for Application No. PCT/CA2012/050907, dated Mar. 25, 2013, 10 pages. |
Written Opinion for Application No. ITTO20111068, dated Apr. 26, 2012, 9 pages. |
U.S. Appl. No. 15/475,028, Final Office Action dated Sep. 21, 2018. |
U.S. Appl. No. 15/027,885, Non-Final Office Action dated Dec. 14, 2018. |
Canadian Patent Application No. 2,926,816, Office Action dated Dec. 11, 2018. |
Canadian Patent Application No. 2,926,816, Office Action dated Oct. 4, 2019. |
Chinese Patent Application No. 201480062263.3, Office Action dated Aug. 22, 2019. |
Chinese Patent Application No. 201480062263.3, Office Action dated May 8, 2019. |
U.S. Appl. No. 14/934,780, Notice of Allowance dated Dec. 13, 2018. |
U.S. Appl. No. 15/027,885, Final Office Action dated Aug. 19, 2019. |
U.S. Appl. No. 15/524,886, Non Final Office Action dated Feb. 20, 2019. |
U.S. Appl. No. 14/934,780, Non-Final Office Action dated Jul. 26, 2018. |
U.S. Appl. No. 15/209,293, Final Office Action dated Dec. 14, 2018. |
U.S. Appl. No. 15/360,574, Final Office Action dated Oct. 31, 2018. |
U.S. Appl. No. 15/360,574, Notice of Allowance dated Dec. 12, 2018. |
U.S. Appl. No. 15/475,028, Non-Final Office Action dated Jul. 23, 2019. |
Chinese Patent Application No. 201480062263.3, Office Action dated Jan. 9, 2020. |
Indian Patent Application No. 201617014280, Office Action dated Dec. 31, 2019. |
United Kingdom Patent Application No. 1608258.8, Examination Report dated Dec. 3, 2019. |
U.S. Appl. No. 15/475,028, Final Office Action dated Jan. 8, 2020. |
U.S. Appl. No. 15/027,885, Notice of Allowance dated Nov. 8, 2019. |
Canadian Patent Application No. 2,826,025, Office Action dated Jul. 3, 2018. |
Canadian Patent Application No. CA2926816, Office Action dated Sep. 15, 2020. |
European Application No. 14786373.2, Communication pursuant to Article 94(3), dated Jan. 14, 2021. |
European Application No. 16177423.7, Communication pursuant to Article 94(3), dated Aug. 23, 2018. |
European Patent Application No. 14786373.2, Office Action dated May 14, 2020. |
U.S. Appl. No. 15/475,028, Non-Final Office Action dated Nov. 16, 2020. |
United Kingdom Patent Application No. 1608258.8, Examination Report dated Mar. 6, 2020. |
United Kingdom Patent Application No. 1608258.8, Search and Examination Report dated Jul. 29, 2020. |
Office Action received in Chinese Application No. 202010939317.7, dated Jan. 5, 2022. |
Office Action received for Canadian Application No. 2,926,816 dated, May 5, 2021. |
Office Action received for Canadian Application No. 2,926,816, dated Sep. 15, 2020. |
Office Action received for European Application No. 14786373.2, dated Aug. 25, 2021. |
Office Action received for European Application No. 14786373.2, dated Jan. 14, 2021. |
Number | Date | Country | |
---|---|---|---|
20150283779 A1 | Oct 2015 | US |
Number | Date | Country | |
---|---|---|---|
62044625 | Sep 2014 | US |
Number | Date | Country | |
---|---|---|---|
Parent | PCT/NL2014/000026 | Aug 2014 | US |
Child | 14684127 | US |