Information
-
Patent Grant
-
6505465
-
Patent Number
6,505,465
-
Date Filed
Tuesday, July 10, 200123 years ago
-
Date Issued
Tuesday, January 14, 200322 years ago
-
Inventors
-
Original Assignees
-
Examiners
- Denion; Thomas
- Nguyen; Tu M.
Agents
-
CPC
-
US Classifications
Field of Search
US
- 060 274
- 060 276
- 060 277
- 060 285
- 060 278
- 060 286
- 123 40648
- 123 519
-
International Classifications
-
Abstract
A device for controlling an internal combustion engine capable of estimating the amount of NOx emission within short periods of time maintaining high precision and realizing improved control performance without increasing the cost as a result of not using map data in the ROM. The device includes NOx operation circuit for estimating the amount of NOx in the exhaust gas from a theoretical formula and an empirical formula based upon the intake air amount Qa, intake air temperature To, pressure Pb, air-fuel ratio λ and EGR rate β, and control circuit for controlling at least either the NOx purifying catalyst or the combustion state in the internal combustion engine in order to lower the amount of NOx emission.
Description
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a device for controlling an internal combustion engine by using a NOx purifying catalyst to reduce NOx (nitrogen oxides) in the exhaust gas. More particularly, the invention relates to a device for controlling an internal combustion engine capable of estimating the amount of NOx emission within short periods of time maintaining high precision and realizing improved control performance without increasing the cost that results when a memory having a large capacity is used.
2. Prior Art
Devices for controlling internal combustion engines of this kind have heretofore been provided with NOx amount estimating means for estimating the amount of NOx adsorbed by a NOx adsorbing agent as taught in, for example, Japanese Patent No. 2586739.
FIG. 3
is a block diagram illustrating the constitution of a conventional device that is adapted to a gasoline engine.
To avoid complexity, here, the description deals with one cylinder only. It should, however, be noted that the same constitution applies to plural cylinders.
In
FIG. 3
, an internal combustion engine
1
includes a piston
2
, a combustion chamber
3
, a spark plug
4
, an intake valve
5
, an intake port
6
, an exhaust valve
7
and an exhaust port
8
.
The intake port
6
is coupled to a surge tank
10
through a corresponding intake pipe
9
which is provided with a fuel injection valve
11
for injecting fuel into the intake port
6
.
The surge tank
10
is coupled to an air cleaner
13
through an intake duct
12
in which a throttle valve
14
is disposed. The intake duct
12
is further provided with an air flow sensor (not shown) for detecting the amount of the air taken in.
On the other hand, the exhaust port
8
is connected, through an exhaust manifold
15
and an exhaust pipe
16
, to a casing
18
in which a NOx adsorbing agent
17
is contained.
The NOx adsorbing agent
17
adsorbs NOx in the exhaust gas and works as a NOx purifying catalyst.
An electronic control unit (ECU)
30
comprises a digital computer which includes a ROM
32
, a RAM
33
, a CPU
34
, an input port
35
and an output port
36
which are connected to each other through a bidirectional bus
31
, as well as A/D converters
37
,
38
inserted on the input side of the input port
35
and drive circuits
39
inserted on the output side of the output port
36
.
A pressure sensor
19
is mounted in the surge tank
10
to generate an output voltage in proportion to an absolute pressure in the surge tank
10
. An output voltage of the pressure sensor
19
is fed to the input port
35
through the A/D converter
37
.
An air-fuel ratio sensor
25
is mounted on the exhaust pipe
16
. An output voltage of the air-fuel ratio sensor
25
is fed to the input port
35
through the A/D converter
38
.
Further, a known EGR pipe (not shown) is provided between the exhaust pipe
16
and the intake pipe
9
to recirculate part of the exhaust gas. The EGR pipe is provided with an EGR valve for adjusting the EGR amount.
An idle switch
20
is attached to the throttle valve
14
to detect the idle opening degree of the throttle valve
14
. An output signal of the idle switch
20
is input to the input port
35
. Similarly, an output signal (engine rotational speed Ne) of a rotational speed sensor
26
is fed to the input port
35
.
The operation of the conventional device shown in
FIG. 3
will be briefly described below with reference to
FIGS. 4 and 5
. The control operation of the conventional device is as disclosed in detail in the above-mentioned patent publication, and is not described here.
The CPU
34
in the ECU
30
constitutes NOx amount estimating means in cooperation with the ROM
32
and RAM
33
, and estimates the amount of NOx adsorbed by the NOx adsorbing agent
17
.
It is difficult to directly detect the amount of NOx adsorbed by the NOx adsorbing agent
17
. Therefore, the amount of NOx in the exhaust gas emitted from the engine
1
is found to estimate the amount of NOx adsorbed by the NOx adsorbing agent
17
from the amount of NOx in the exhaust gas.
In general, the amount of the exhaust gas emitted from the engine
1
per a unit time increases with an increase in the engine rotational speed Ne. Accordingly, the amount of NOx emitted from the engine
1
per a unit time increases with an increase in the engine rotational speed Ne.
Further, as the engine load increases (i.e., as the absolute pressure PM in the surge tank
10
increases), the amount of the exhaust gas emitted from the combustion chamber
3
increases and the combustion temperature increases. As the engine load increases (absolute pressure PM in the surge tank
10
increases), therefore, the amount of NOx emitted from the engine
1
per a unit time increases.
FIG. 4
is a diagram illustrating the amount of NOx emitted from the engine
1
per a unit time, and wherein the values found through experiment are related to the absolute pressure PM (ordinate) in the surge tank
10
and the engine rotational speed Ne (abscissa).
In
FIG. 4
, the continuous curves represent the same amounts of NOx.
As shown in
FIG. 4
, the amount of NOx emitted from the engine
1
per a unit time increases with an increase in the absolute pressure PM in the surge tank
10
and with an increase in the engine rotational speed Ne.
The amounts of NOx shown in
FIG. 4
have been stored in advance in the ROM
32
in the form of map data N
11
to Nij shown in FIG.
5
.
The map data shown in
FIG. 5
vary depending upon other various operating conditions. When it is attempted to correctly find the amount of NOx by operating the map, a large amount of memory capacity is necessary driving up the cost.
According to the conventional device of controlling the internal combustion engine as described above, the data used by the NOx amount estimating means in the ECU
30
are stored as map data N
11
to Nij as shown in FIG.
5
. Therefore, the map data must be formed for every operating condition of the engine
1
and must be stored in the ROM
32
, requiring laborious work and extended periods of time and driving up the cost.
SUMMARY OF THE INVENTION
The present invention was accomplished in order to solve the above-mentioned problem, and has an object of providing a device for controlling an internal combustion engine by estimating the amount of NOx emission within short periods of time maintaining high precision and improving control performance without the need of storing great amounts of map data in the ROM and, hence, without driving up the cost.
A device for controlling an internal combustion engine according to the present invention comprises:
an air flow sensor provided in an intake pipe of the internal combustion engine to detect the amount of the intake air;
temperature detector means and pressure detector means for detecting the temperature and the pressure of the air taken in by the internal combustion engine;
air-fuel ratio detector means provided in the exhaust pipe of the internal combustion engine and for detecting the air-fuel ratio in the exhaust gas;
EGR rate detector means for detecting the EGR rate of the exhaust gas recirculated into the intake air;
a NOx purifying catalyst provided in the exhaust pipe of the internal combustion engine;
NOx operation means for estimating the amount of NOx in the exhaust gas from a theoretical formula and an empirical formula based upon the amount of the intake air, temperature and pressure of the intake air, air-fuel ratio and EGR rate; and
control means for controlling at least either the NOx purifying catalyst or the combustion state in the internal combustion engine in order to lower the amount of NOx emission.
In the device for controlling an internal combustion engine according to the present invention, the theoretical formula and the empirical formula contain a correction coefficient that varies depending upon at least either the model of the internal combustion engine or the combustion mode.
In the device for controlling an internal combustion engine according to the present invention, the combustion mode includes a stratified combustion mode and a homogeneous combustion mode.
In the device for controlling an internal combustion engine according to the present invention, the NOx operation means estimates the oxygen concentration, nitrogen concentration and temperature of the combustion gas in the internal combustion engine from the theoretical formula and the empirical formula, and estimates the amount of NOx emission in the exhaust gas based upon the oxygen concentration, nitrogen concentration and temperature of the combustion gas.
In the device for controlling an internal combustion engine according to the present invention, the control means controls the air-fuel ratio to control the NOx purifying catalyst.
In the device for controlling an internal combustion engine according to the present invention, the control means controls at least one of the fuel injection amount, fuel injection timing, ignition timing and EGR rate of the internal combustion engine as the combustion state of the internal combustion engine.
In the device for controlling an internal combustion engine according to the present invention, the air-fuel ratio detector means includes:
an air-fuel ratio sensor provided in the exhaust pipe upstream of the NOx purifying catalyst and for producing an oxygen concentration detection signal depending upon the oxygen concentration in the exhaust gas; and
air-fuel ratio operation means for estimating the air-fuel ratio based upon the oxygen concentration detection signal.
In the device for controlling an internal combustion engine according to the present invention, the air-fuel ratio detector means includes air-fuel ratio operation means for estimating the air-fuel ratio from the fuel injection amount and from the intake air amount of the internal combustion engine.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1
is a block diagram illustrating the constitution of an embodiment 1 of the present invention;
FIG. 2
is a flowchart illustrating the estimation processing operation and the control operation according to the embodiment 1 of the present invention;
FIG. 3
is a block diagram illustrating the constitution of a conventional device for controlling an internal combustion engine;
FIG. 4
is a diagram illustrating the amount of NOx emitted by a general internal combustion engine per a unit time; and
FIG. 5
is a diagram illustrating map data representing the amounts of NOx emission by using a conventional device for controlling the internal combustion engine.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
Embodiment 1
An embodiment 1 of the present invention will now be described in detail with reference to the drawings.
FIG. 1
is a block diagram illustrating the constitution of the embodiment 1 of the present invention, wherein the same portions as those described above (see
FIG. 3
) are denoted by the same reference numerals or by putting “A” to the ends of the numerals but are not desired here again in detail.
For simplifying the diagram, the A/D converters
37
,
38
and the drive circuits
39
(see
FIG. 3
) in the ECU
30
A are not shown here.
In
FIG. 1
, an intake air temperature sensor
21
is provided on the upstream of the air cleaner
13
in the intake pipe
9
to detect the temperature To of the intake air.
Further, an air flow sensor
22
is provided on the downstream of the air cleaner
13
in the intake pipe
9
to detect the flow rate Qa of the intake air.
The pressure sensor
19
detects the pressure Pb in the intake pipe
9
as the pressure of the intake air, and substantially works as an intake-air-pressure sensor.
The intake air pressure Pb, intake air temperature To and intake air flow rate Qa are fed, together with the air-fuel ratio λ from the air-fuel ratio sensor
25
, to the input port
35
in the ECU
30
A as various sensor data representing the operating conditions of the engine
1
.
As various sensor means, further, there is provided an EGR sensor for detecting the EGR rate from the opening degree β of the EGR valve that adjusts the EGR amount in the EGR pipe (not shown). The EGR rate representing the amount of the exhaust gas recirculated into the intake air is fed to the input port
35
.
As operating conditions, further, not only the engine rotational speed Ne and the accelerator opening degree α but also the intake air amount Qa from the air flow sensor, are fed to the input port
35
.
The CPU
34
A in the ECU
30
A includes NOx operation means for estimating the amount of NOx emission in the exhaust gas from a theoretical formula and an empirical formula (described later) based upon the intake air amount Qa, intake air temperature To, intake air pressure Pb and upon the air-fuel ratio λ and the EGR rate (EGR opening degree β).
The CPU
34
A includes control means for controlling at least either the NOx purifying catalyst
17
or the combustion state in the engine
1
so as to decrease the amount of NOx emission.
Here, the theoretical formula and the empirical formula contain a correction coefficient that has been stored in advance in the ROM
32
A and that varies depending upon at least either the model of the engine
1
or the combustion mode.
The combustion modes may include a stratified combustion mode of the case of an direct cylinder injection engine and a homogeneous combustion mode during the normal stoichiometric operation control.
The NOx operation means in the CPU
34
A estimates the oxygen concentration, nitrogen concentration and temperature of the combustion gas in the engine
1
from the theoretical formula and the empirical formula, and estimates the amount of NOx emission in the exhaust gas based upon the oxygen concentration, nitrogen concentration and temperature of the combustion gas.
The control means in the CPU
34
A controls the air-fuel ratio λ to control the NOx purifying catalyst
17
.
The control means in the CPU
34
A further controls at least one of the fuel injection amount, fuel injection timing, ignition timing and EGR rate of the engine
1
as the combustion state of the engine
1
.
As shown, the air-fuel ratio detector means is constituted by an air-fuel ratio sensor
25
provided in the exhaust pipe
16
upstream of the NOx purifying catalyst
17
and for producing an oxygen concentration detection signal depending upon the oxygen concentration in the exhaust gas, and air-fuel ratio operation means in the CPU
34
A for estimating the air-fuel ratio A/F based upon the oxygen concentration detection signal.
Further, the air-fuel ratio detector means may be constituted by air-fuel ratio operation means in the CPU
34
A for estimating the air-fuel ratio A/F from the fuel injection amount and the intake air amount Qa of the engine
1
.
Next, described below is the operation for estimating the amount of NOx emission according to the embodiment 1 of the present invention shown in FIG.
1
.
First, NOx (nitrogen oxide) formed by the engine
1
comprises chiefly Zeldvich NO (nitrogen monoxide), the reaction mechanism being expressed by the following formulas (1) and (2),
N2+O→NO+N (1)
N+O2→NO+O (2)
The rate of NO formation based on the above formulas (1) and (2) is expressed by the following formulas (3) and (4),
In the formula (3), [NO], [N2] and [O2] are concentrations of NO, N2 (nitrogen) and O2 (oxygen) and in the formula (4), T is a temperature.
The combustion reaction mechanism in the engine
1
is expressed by the following formula (5),
In the formula (5), β is an EGR rate and λ is an air-fuel ratio.
The concentrations [N2] and [O2](kmol/m3] of N2 and O2 are expressed by the following formulas (6) and (7),
In the formulas (6) and (7), ε is a compression ratio, P (atom) is an intake air pressure, and To (K) is an intake air temperature.
Further, the nitrogen concentration [N2] is approximately expressed by the following formula (8),
From the above formulas (3), (4), (7) and (8), the concentration [NO] of NO emitted per a stroke (per a combustion) is expressed by the following formulas (9) and (10),
In the above formulas (9) and (10), nE (rpm) is an engine rotational speed Ne.
Here, if the amount of fuel injection per a stroke is denoted by Gf (kg), the amount of NO Gno(kg) emitted by a four-cycle engine per a stroke is expressed by the following formulas (11) and (12),
Further, a total amount of NO GnoT (kg) emitted per a unit time is expressed by the following formulas (13) and (14),
In formulas (13) and (14), C is a correction coefficient.
As the temperature T, there is typically employed a maximum adiabatic frame temperature of the case where there is no heat loss. The flame temperature T is expressed by the following formulas (15) to (17) by using an average specific heat at constant pressure Cp, an intake air temperature To and a polytropic index κ,
Cp: average specific heat at constant pressure (kcal/kg° C.),
To: intake air temperature (K),
κ: polytropic index.
Here, the average specific heat at constant pressure Cp is approximated by the following formula (18),
c
p
=0.518−0.219(λ/15)+0.0521(λ/15)
2
(18)
Accordingly, the flame temperature T is expressed by the following formulas (19) and (20),
If the formula (20) is substituted for the above formula (14), there is obtained the following formula (21),
The formula (21) can be further approximated as expressed by the following formulas (22) to (24),
G
noT
=f
(λ)
g
(β)
h
(ε)
i
(
Tb
0
)
×P
3/2
×G
f
×C
(22)
=14.7×10
17
×(−1.839×10
−7
+4.2374×10
−8
λ−3.9847×10
−9
λ
2
+1.9701×10
−10
λ
3
−5.415×10
−12
λ
4
+7.8535×10
−14
λ
5
−4.698×10
−16
λ
6
)
×(1−14.27β+69.16β
2
−110.97 β
3
)
×(1.693−0.004644T
0
+7.776×10
−6
T
0
2
)
×(−6.26+1.98ε)
×P
3/2
×G
f
×C
(23)
G
noT
=f
(λ)
g
(β)
h
(ε)
i
(
T
0)
×P
3/2
×G
f
×C
=(−1.839×10
−7
×4.2374×10
−8
λ−3.9847×10
−9
λ
2
+1.9701×10
−10
λ
3
−5.415×10
−12
λ
4
+7.8535×10
−14
λ
5
−4.698×10
−16
λ
6
)
×(1−14.27β+69.16β
2
−110.97β
3
)
×(1.693−0.004644T
0
+7.776×10
−6
T
0
2
)
×(−6.26+1.98ε)
×P
3/2
×G
f
×C
0
(24)
In the formulas (22) to (24), C and C0 are correction coefficients which vary depending upon the model of the engine
1
and the combustion mode (stratified combustion, homogeneous combustion).
The amount of NOx emitted per a unit time is calculated based on the formula (21), (23) or (24) from the thus detected air-fuel ratio λ, EGR rate β, intake air pressure Pb and intake air temperature To, and is integrated to estimate the total amount of NOx emission QNT as expressed by the following formula (25) and (26),
QNT=∫G
noT
dt (25)
=ΣG
noT
Δt (26)
Next, the procedure for processing NOx according to the embodiment 1 of the invention will be described with reference to a flowchart of FIG.
2
.
In
FIG. 2
, first, operating conditions (accelerator opening degree α, EGR rate β, air-fuel ratio γ, engine rotational speed Ne, intake pipe pressure Pb, intake air amount Qa, intake air temperature To, etc.) of the engine
1
are detected from various sensor means (step S
1
).
Then, depending upon the operating conditions, a target torque Tqo is set (step S
2
), a target air-fuel ratio λo is set (step S
3
), and a target EGR opening degree βo is set (step S
4
).
Next, the NOx (NO) concentration [NO], oxygen concentration [O2] and nitrogen concentration [N2] in the combustion gas of the engine
1
are estimated in compliance with the above formulas (6) to (10), and a maximum adiabatic flame temperature T of when there is no heat loss is estimated as the temperature of the combustion gas in compliance with the formulas (19) and (20) (step S
5
).
Thereafter, the amount of NOx emission QNT in the exhaust gas is estimated in compliance with the above formulas (22) to (26) based on the oxygen concentration [O2], nitrogen concentration [N2] and the combustion gas temperature T (step S
6
), and the air-fuel ratio λ is controlled and the NOx purifying catalyst
17
is controlled to purify the amount of NOx emission QNT (step S
7
).
By using the theoretical formula and empirical formula based upon the air-fuel ratio λ, EGR rate β, intake air pressure Pb and intake air temperature To from various sensor means, it is allowed to operate the amount of NOx emission QNT within short periods of time and highly precisely without increasing the memory capacity.
That is, there is no need of forming a great amount of data to meet various operation modes, and the adjustment may be effected depending upon the combustion mode (stratified combustion, homogeneous combustion) and by using several correction coefficients (e.g., see C of the formula 23)) corresponding to a change in the model of the engine
1
. Thus, the control operation can be executed depending upon the individual engines
1
easily and in short periods of time.
Therefore, the NOx purifying catalyst
17
is effectively controlled depending upon the amount of NOx emission QNT that is highly precisely estimated within a short period of time thereby to decrease the amount of NOx emission QNT.
The NOx purifying catalyst
17
was controlled above depending upon the amount of NOx emission QNT. It is, however, also allowable to control the combustion condition operation quantities of the engine
1
so as to decrease the amount of NOx emission QNT.
In this case, the combustion condition operation quantities controlled by the ECU
30
include a fuel injection amount, a fuel injection timing, an ignition timing and an EGR rate shown in FIG.
1
.
Further, the air-fuel ratio sensor
25
provided in the exhaust pipe
15
on the upstream of the NOx purifying catalyst
17
was used as the air-fuel ratio detector means. The operation, however, may be executed by using the intake air amount Qa from the air flow sensor
22
provided in the intake pipe
9
and the fuel injection quantity controlled by the ECU
30
A.
In this case, the air-fuel ratio λ is estimated in the ECU
30
A from the air flow rate detection value Qa and the fuel injection amount (control quantity of the ECU
30
A).
Further, the NOx absorbing agent
17
was used as the NOx purifying catalyst. It is, however, also allowable to use any other NOx purifying catalyst.
Claims
- 1. A device for controlling an internal combustion engine comprising:an air flow sensor provided in an intake pipe of the internal combustion engine to detect the amount of the intake air; temperature detector means and pressure detector means for detecting the temperature and the pressure of the air taken in by said internal combustion engine; air-fuel ratio detector means provided in the exhaust pipe of said internal combustion engine and for detecting the air-fuel ratio in the exhaust gas; EGR rate detector means for detecting the EGR rate of the exhaust gas recirculated into the intake air; a NOx purifying catalyst provided in the exhaust pipe of said internal combustion engine; NOx operation means for estimating the amount of NOx in the exhaust gas from a theoretical formula and an empirical formula based upon the amount of the intake air, temperature and pressure of the intake air, air-fuel ratio and EGR rate; and control means for controlling at least either said NOx purifying catalyst or a combustion state in said internal combustion engine in order to lower the amount of NOx emission wherein said NOx operation means estimates the oxygen concentration, nitrogen concentration and temperature of the combustion gas in said internal combustion engine from said theoretical formula and said empirical formula, and estimates the amount of NOx emission in the exhaust gas based upon said oxygen concentration, nitrogen concentration and temperature of the combustion gas.
- 2. A device for controlling an internal combustion engine according to claim 1, wherein said control means controls the air-fuel ratio to control said NOx purifying catalyst.
- 3. A device for controlling an internal combustion engine according to claim 1, wherein said control means at least one of said fuel injection amount, fuel injection timing, ignition timing and EGR rate of said internal combustion engine as the combustion state of said internal combustion engine.
- 4. A device for controlling an internal combustion engine according to claim 1, wherein said air-fuel ratio detector means includes:an air-fuel ratio sensor provided in the exhaust pipe upstream of said NOx purifying catalyst and for producing an oxygen concentration detection signal depending upon the oxygen concentration in the exhaust gas; and air-fuel ratio operation means for estimating the air-fuel ratio based upon said oxygen concentration detection signal.
- 5. A device for controlling an internal combustion engine according to claim 1, wherein said air-fuel ratio detector means includes air-fuel ratio operation means for estimating the air-fuel ratio from the fuel injection amount and from the intake air amount of said internal combustion engine.
- 6. A device for controlling an internal combustion engine according to claim 1, wherein said theoretical formula and said empirical formula contain a correction coefficient that varies depending upon at least either a model of said internal combustion engine or a combustion mode.
- 7. A device for controlling an internal combustion engine according to claim 6, wherein said combustion mode includes a stratified combustion mode and a homogeneous combustion mode.
- 8. A method for controlling at least either a NOx purifying catalyst or a combustion state in an internal combustion engine comprising:detecting an amount of intake air; detecting a temperature and pressure of air taken in by said internal combustion engine; detecting an air-fuel ratio in exhaust gas; detecting an EGR rate of the exhaust gas recirculated into the intake air; estimating the amount of NOx in the exhaust gas from a theoretical formula and an empirical formula based upon the detected amounts of the intake air, temperature and pressure of the intake air, air-fuel ratio and EGR rate; wherein said theoretical formula and said empirical formula contain a correction coefficient that varies depending upon at least either a model of said internal combustion engine or a combustion mode; and controlling at least either said NOx purifying catalyst or a combustion state in said internal combustion engine in order to lower the amount of NOx emission; wherein said estimating step estimates the oxygen concentration, nitrogen concentration and temperature of the combustion gas in said internal combustion engine from said theoretical formula and said empirical formula, and estimates the amount of NOx emission in the exhaust gas based upon said oxygen concentration, nitrogen concentration and temperature of the combustion gas.
Priority Claims (1)
Number |
Date |
Country |
Kind |
2000-393090 |
Dec 2000 |
JP |
|
US Referenced Citations (8)
Number |
Name |
Date |
Kind |
5437153 |
Takeshima et al. |
Aug 1995 |
A |
5595060 |
Togai et al. |
Jan 1997 |
A |
5655363 |
Ito et al. |
Aug 1997 |
A |
5894725 |
Cullen et al. |
Apr 1999 |
A |
5956948 |
Nagashima et al. |
Sep 1999 |
A |
6012435 |
Takahashi et al. |
Jan 2000 |
A |
6199372 |
Wakamoto |
Mar 2001 |
B1 |
6279537 |
Yonekura et al. |
Aug 2001 |
B1 |
Foreign Referenced Citations (1)
Number |
Date |
Country |
9325806 |
Dec 1993 |
JP |