The present disclosure relates to the preservation of substances and objects sensitive to humidity, such as particular foods, pharmaceuticals, and herbs. Particularly, the present disclosure relates to devices for controlling the relative humidity within consumer product packages, and methods for making such devices.
The background description provided herein is for the purpose of generally presenting the context of the disclosure. Work of the presently named inventors, to the extent it is described in this background section, as well as aspects of the description that may not otherwise qualify as prior art at the time of filing, are neither expressly nor impliedly admitted as prior art against the present disclosure.
For many packaged products, including packaged consumer products, it is beneficial to maintain a particular moisture content of the product and/or within the package containing the product. In some cases, the space within a product package that is not taken up by the product itself, may be referred to as the headspace of the packaged product. Some devices are configured to help maintain a consistent relative humidity (RH) of the headspace of packaged products. The RH may be maintained at a level or range deemed optimum for the particular packaged product. It is understood to those skilled in the art that the % RH in the package headspace will result in a % by weight product moisture content, but that the % RH in the headspace and the product % moisture by weight are different values that differ based on the characteristics of the product and its propensity to absorb moisture from the surrounding atmosphere. Many products may be consumed or utilized by a consumer over a period of time, and maintaining a consistent RH may help preserve the life, integrity, freshness, flavor, or other features of the product.
One commonly used device for controlling headspace RH in packaged products is a loose pouch containing a salt solution. As disclosed in U.S. Pat. No. 5,936,178, entitled Humidity Control Device, and filed Jun. 10, 1997, the contents of which are hereby incorporated herein by reference in their entirety, the RH of closed environments can be stabilized by the use of humidity control systems comprised of moisture permeable pouches containing specific salt solutions. However, a growing number of existing and potential customers have indicated that the method of providing the humidity control feature through pouches that are loose in the product package is unsatisfactory, and they refuse to, or are prevented from, using this standard approach for a variety of reasons. For example, consumer confusion may arise as to whether the packet is something other than a humidity control device. In some cases, loose packets may be intentionally or mistakenly discarded by consumers when opening and closing the product packaging, particularly with repeated opening and closing of the packaging over time. Such approaches may also require specialized materials.
Obvious remedies, such as spot gluing pouches to an inside surface of the product package, while easy to implement, have also been deemed by manufacturers or distributors to be unsatisfactory, and in some cases, a product package of that type runs afoul of regulatory requirements for certain products in certain jurisdictions.
Thus, there is a need in the art for a new humidity control device and methods of making such devices. More particularly, there is a need for a humidity control device that may be integral with the product packaging so as to overcome the potential issues associated with loose humidity control packets.
The following presents a simplified summary of one or more embodiments of the present disclosure in order to provide a basic understanding of such embodiments. This summary is not an extensive overview of all contemplated embodiments, and is intended to neither identify key or critical elements of all embodiments, nor delineate the scope of any or all embodiments.
The present disclosure, in one or more embodiments, relates to a humidity control device for controlling headspace relative humidity in a consumer product package.
While multiple embodiments are disclosed, still other embodiments of the present disclosure will become apparent to those skilled in the art from the following detailed description, which shows and describes illustrative embodiments of the invention. As will be realized, the various embodiments of the present disclosure are capable of modifications in various obvious aspects, all without departing from the spirit and scope of the present disclosure. Accordingly, the drawings and detailed description are to be regarded as illustrative in nature and not restrictive.
While the specification concludes with claims particularly pointing out and distinctly claiming the subject matter that is regarded as forming the various embodiments of the present disclosure, it is believed that the invention will be better understood from the following description taken in conjunction with the accompanying Figures, in which:
The present disclosure relates to novel and advantageous humidity control devices for consumer products and methods for making the same. Particularly, the present disclosure relates to novel and advantageous humidity control devices, such as packets, pockets, or other shapes or devices, containing a humidity control agent for controlling the relative humidity (RH) within a packaged consumer product, such as a food, pharmaceutical, herb, or any other suitable consumer product. In some embodiments, the humidity controlling device may be attached to, or integrated with, the product packaging. For example, the device may be fixedly or removably adhered to an inside wall of a product package. In some embodiments, the device may be constructed or formed on the product packaging material, such that the device is an integral part of the product packaging material. In other embodiments, the humidity control device may be freely moveable within the product package, or within a portion of the interior of the product package, for example.
A humidity control device of the present disclosure may generally include a humidity control agent, which may be a solid, dispersion, emulsion, gel, or saturated or unsaturated solution, contained within a relatively secure and durable containment. The humidity control device may be configured to create and/or maintain a RH within a product package throughout the life of the product, or at least a portion of the life of the product, including through multiple openings and reclosings of the product package by a consumer. In some embodiments, the humidity control device may generally include two layers of material, such as a base layer and a permeable layer, between which the humidity control agent is sealed. The permeable layer may generally allow gases and/or water vapor to penetrate the device such that the humidity control agent may control humidity of the headspace within a product package. In some embodiments, the base layer of the humidity control device may be fixedly or removably arranged on or adhered to an inner surface of a product package. In other embodiments, the base layer may be or include an inner wall of a product package, such that the permeable layer may generally hold the humidity control agent against the product package material. In other embodiments, the humidity control device may include a different configuration with a humidity control agent arranged within or between one or more layers of material. One or more surfaces of the device may be permeable to gases and/or water vapor such that the humidity control agent may control humidity of the headspace within a product package. The device may be fixedly or removably adhered to an inner surface of a product package, or may be freely placed within a product package.
Turning now to
The humidity control agent may be comprised of a solid, a dispersion, an emulsion, a gel, or a saturated or unsaturated aqueous solution comprised of a salt, sugar, polyol such as glycerin or propylene glycol, mannitol, sorbitol, xylitol, amino acid, or other solute modulating the relative humidity. For example, in some embodiments, the humidity control agent may be or include a saturated or unsaturated salt solution, such as those described in U.S. Pat. No. 9,750,811, entitled Devices and Methods for Controlling Headspace Humidity and Oxygen Levels, filed Sep. 15, 2015; U.S. Pat. No. 5,936,178, entitled Humidity Control Device, filed Jun. 10, 1997; and/or U.S. Pat. No. 6,921,026, entitled Preservation of Intermediate Moisture Foods by Controlling Humidity and Inhibition of Mold Growth, filed Feb. 5, 2002, the content of each of which is hereby incorporated herein by reference in its entirety. In other embodiments, other suitable materials for controlling humidity may be used as the humidity control agent 120. The humidity control agent 120 may allow for one-way or two-way humidity control in some embodiments. That is, the humidity control agent 120 may be configured to remove moisture from the air and/or to add moisture to the air. In some embodiments, one or more additives may be combined with the humidity control agent, including but not limited to the additives described in U.S. patent application Ser. No. 14/854,159, U.S. Pat. No. 5,936,178, and/or U.S. Pat. No. 6,921,026. For example, some additives may be used to increase or otherwise control viscosity levels of the humidity control agent. One example of an additives one or more gums for thickening or altering viscosity of the humidity control agent. For example, in some embodiments, between approximately 1% and approximately 3% of the humidity control agent may comprise one or more gums. Other additives may include one or more salts, water, and/or other additives.
The quantity of humidity control agent 120 contained within the humidity control device 100 may vary based on desired RH control capacity, size of product package, and/or other factors. The quantity of humidity control agent 120 may vary from, for example, less than 1 gram to more than 500 grams of material for each humidity control device 100. In some embodiments, the humidity control device 100 may have a quantity of humidity control agent 120 ranging from between approximately 1 gram and approximately 350 grams. In particular embodiments, the quantity of humidity control agent 120 may range between approximately 2 and 8 grams, between approximately 4 and 16 grams, between approximately 57 and 77 grams, or between approximately 300 and 340 grams. In some embodiments, the quantity of humidity control agent 120 may correspond or relate to the quantity of product in the product package, and/or the size of the product package. For example, in some embodiments, the humidity control agent 120 for the humidity control device 100 may be provided in a ratio of between 1:2 and 1:20 to the amount of product in the product package. In particular, the ratio between the amount of humidity control agent 120 and the amount of product in the product package may be between approximately 1:4 and 1:12, or between 1:6 and 1:10. In other embodiments, other ratios of humidity control agent 120 to product in the product package, or to size of product package, may be provided.
It is to be appreciated that the humidity control material 120 may be applied over a “footprint” or a particular area of the base layer. Moreover, the humidity control material 120 may be applied with a desired thickness. It may be advantageous to achieve a workable balance between the footprint of the humidity control agent 120 on the base layer 110, and the thickness of the humidity control agent, in order to achieve a desired level of humidity control and desired size and shape of the humidity control device. Too large a footprint of the humidity control material 120, while reducing humidity control device 100 thickness, may increase width, length, or other dimension(s) of the device and thus require more base layer 110 and permeable layer 130 materials. This may increase material cost for the added permeable material and base material as well as require more product packaging interior space for the humidity control device 100, which may in turn lead to difficulties in forming and/or sealing the packaging. However, a relatively small footprint of the humidity control agent 120, while reducing other dimensions of the humidity control device 100, may lead to a relatively thick humidity control device, and may interfere with forming product packages and filling them.
The base layer 110, as shown in
In some embodiments, the base layer 110 may be configured to fixedly or removably adhere to an inner surface of a product package or a component thereof. For example, the base layer 110 may have an adhesive backing for adhering to an inner wall of a carton, cup, canister, box, pouch, jar, case, bag, or other product package. In some embodiments, the package may be a pouch such as a standup pouch like a gusset pouch, a layflat pouch, or another type of pouch which may optionally include a resealable zipper or other reclosable seal to enclose the interior product compartment. In other embodiments, the base layer 110 may be glued or otherwise adhered to an inner product package surface using any suitable means. In still further embodiments, the base layer 110 may be or include an inner surface of a product package. For example, the base layer 110 may be or include an inner wall of a carton, cup, canister, box, pouch, jar, case, bag, or other product package, such that the permeable layer 130 may hold the humidity control agent 120 directly on or against the product package wall. In one embodiment, the base layer 110 may be or include an inner surface of a paperboard box configured to hold dry food goods, for example, such that the permeable layer 130 may be configured to form a seal with the inner surface of the paperboard box so as to contain the humidity control agent 120 while permitting gas exchange through the permeable layer. In such embodiments where the base layer 110 comprises an inner surface of a product package, the product package itself may be preassembled before receiving the humidity control agent 120 and permeable layer 130, or may be assembled after receiving the humidity control agent and permeable layer.
In some embodiments, the base layer 110 may have an adhesive surface for adhering to the permeable layer 130. For example, the base layer 110 may have a patterned adhesive side—that is, a side having adhesive on select locations or areas—configured to provide an adhesive surface for adhering to the permeable layer 130 without interfering with the humidity control agent 120.
The permeable layer 130 may generally be configured to couple or adhere to the base layer 110 so as to contain the humidity control agent 120, and may include one or more materials arranged in one or more layers. The permeable layer 130 may generally be permeable to water vapor and/or oxygen or other gases, allowing water vapor and/or oxygen or other gases to flow through the layer without allowing the humidity control agent 120 to flow through the permeable layer. It may thus be appreciated that the permeable layer 130 may be impermeable to aqueous solutions, such as saturated or unsaturated salt solutions used as a humidity control agent 120 in some embodiments. In other embodiments, for example where the humidity control agent 120 is a gel or a liquid with a relatively high viscosity, the permeable layer 130 may be configured to be impermeable to gels or liquids having a minimum viscosity. The water vapor transport, known as water vapor transmission rate (WVTR) is measured in terms of grams of water passed per 100 square inches of material per 24 hours under standard test conditions. WVTR is generally a function of the type and thickness of materials used. For a humidity control device of the present disclosure, the total moisture transferred may be determined by the area of the permeable layer 130 exposed to a humidity control material in a given application. In some embodiments, for example, a WVTR of about 1-120, or about 5-100, about 10-85, or about 10-60 grams of water per 100 square inches over 24 hours may provide relatively good results for a device in accordance with the invention. In other embodiments, a different WVTR may be used.
Materials that may be employed for the permeable layer 130 may include, but are not limited to, a polymeric film, fibrous polyethylene (TYVEK®) or other non-woven structures, polyesters such as an elastomer, or polyamide Pebax laminated onto a suitable substrate such, but not limited to, as paper. In some embodiments, a thermoplastic polyester elastomer may be used as or with the permeable layer 130. Such thermoplastic polyester elastomer materials may offer a combination of relatively high water vapor permeability, resistance to solutions, such as salt solutions for example, toughness, and the ability to create relatively strong and robust seals with itself. Other materials that may be used as or included with the permeable layer 130 may include, but are not limited to, paper, foil, polyesters, metalized polyesters, copolyesters, polyolefins, copolymers, polyurethanes, polylactic acid, and/or other suitable materials. In some embodiments, the permeable layer 130 may be or include a microperforated material or any other suitable material configured to maintain the humidity control agent 120 at static and/or dynamic pressures encountered during product filling, distribution, storage, and customer use of the packaged product.
Turning now to
The packet or pouch 140 may comprise any suitable material or materials in any suitable number of layers. In some embodiments, the packet 140 may have one or more sides or faces. For example, as shown in
The packet 140 may generally be configured to control humidity within a product package. In some embodiments, the packet 140 may be configured to be fixedly or removably adhered to an inner surface of a product package. For example, the packet 140 may have an adhesive surface in some embodiments, such that it may be fixedly or removably adhered to an inner wall of a paperboard box, as an example. In other embodiments, the packet 140 may be glued or otherwise adhered to an inner surface of a product package using any suitable means. In other embodiments, the packet 140 may be configured to be loose within a product package, such that it may generally move around within the package.
As described above, a humidity control device of the present disclosure may be adhered to or incorporated on an inner surface of a product package.
In an alternative embodiment, a pre-assembly product package 180 of
Turning now to
As shown in
As additionally shown in
In some embodiments, a pocket, bubble, or generally recessed or concave area may be formed in the permeable material before it is placed over the patch of humidity control agent 222 in order to accommodate the humidity control agent 222 and to ensure a smooth contact with the base layer 212 and avoid folds, channels, or gathers. That is, a shallow pocket may be formed in a central region of the permeable material that will directly cover a patch of humidity control agent 222, as shown for example in
When the permeable material is placed over the patch, due to the viscosity of the humidity control agent 222, contact between the permeable material and patch may beneficially aid in temporarily holding the permeable material in place while the perimeter of the permeable layer 232 is sealed or otherwise adhered to the perimeter of the base layer 212.
In some embodiments, one or more registration devices 250, 260 may be configured to sense a registration marker. A registration marker may be, for example, a printed indicator printed on the base layer 212 or permeable layer 232, an indicator on the conveyer belt 205 or another surface, or any other visually or electronically detected cue. A registration device 250, 260 may sense a registration marker to determine a condition related to the process 200. For example, a registration marker may indicate whether the humidity control agent 222 is appropriately positioned on the base layer 212, whether the permeable layer 232 is appropriately positioned on the base layer, whether the permeable layer has properly adhered to the base layer, and/or other elements of the process 200. In some embodiments, the one or more registration devices 250, 260 may produce an electronic signal—or cause an electronic signal to be produced—upon detecting a registration marker. Such signals may result in initiating an automated adjustment to a component of the humidity control device or a component of the process, providing an alert to an operator, halting production, making one or more adjustments, or other actions. In some embodiments, one or more automated or partially automated inspection devices may be incorporated into the process 200 or other processes of the present disclosure, providing a defect detection function to increase consistency and/or quality.
A sealing system 240 may be used to adhere the perimeter of the permeable layer 232 to the exposed perimeter of the base layer 212. For example, the sealing system 240 may include a heater for heat sealing the permeable layer 232 and base layer 212, an ultrasonic welding system, a pressure sealing system, an adhesive application system, and/or other means for bonding the two layers together. In some embodiments, the permeable material and base material may be configured to seal or adhere together, via heat sealing for example. In some embodiments, where the base layer 212 and/or permeable layer 232 are comprised of multiple layers of material(s), one or more of the layers may be sealed or adhered to one or more other layers. In some embodiments, the base layer 212 and/or permeable layer 232 may be pre-treated with, or may include, a bonding material such as an adhesive material or a heat sealable material. In some embodiments, the two materials may be chemically compatible to form heat seals or other seals at particular temperatures, pressure, and/or dwell times. A few examples of such sealant materials are polyethylene and some of its copolymers and ionomers, heat seal coated oriented films such as polypropylene or polyethylene terephthalate, nylon or others polymer types and films. In other embodiments, an adhesive, such as a heat activated adhesive, may be applied to the surface of the base material and/or the perimeter surface of the permeable material that will contact the base material. The adhesive may be applied to an entire surface of the base material and/or permeable material, or may be applied to a perimeter, for example, so as not to interfere with the humidity control agent 222.
In at least one embodiment, a hot-melt type adhesive material may be applied to the base layer 212 in a molten state. The adhesive material may be applied with a suitable temperature and in a suitable amount such that the adhesive material may be configured to retain sufficient heat to bond the permeable layer 232 to the base layer 212. In some embodiments, the adhesive material may be heated to a temperature of between approximately 250 degrees Fahrenheit and approximately 400 degrees Fahrenheit before being applied to the base layer 212. In some embodiments, the adhesive material may be applied on the base layer 212 to form a continuous perimeter or partial perimeter around the humidity control agent 222. In other embodiments, the adhesive material may be applied to the base layer 212 in a plurality of discrete locations, such as in dots. Where the adhesive material is applied at discrete locations, such as in dots, the application temperature and time between application and contact of the permeable layer 232 may be configured such that as the permeable layer is applied, the adhesive material may be configured to remain above its solidification temperature. In this way, when the permeable layer 232 and suitable pressure are applied, the discrete locations or dots may flow together and form a continuous perimeter or partial perimeter that operates to contain the humidity control agent 222 between the base layer 212 and the permeable layer. The hot-melt type adhesive material may be selected to retain a relatively high degree of tackiness, so as to facilitate maintenance of bonding the two layers through distribution and use of the humidity control device.
Generally, any suitable method known in the art may be used to strongly and robustly couple the base layer and permeable layer together, creating strong and robust seals capable of performing satisfactorily through the remaining package formation, filling, closing/sealing operations, as well as distribution, storage, sale, and use by the ultimate consumer.
When the process 200 is used to manufacture discrete humidity control devices in the form of separate units such pouches or packets, for example, they may be cut apart or otherwise separated from each other before, during, or after the operations depicted in
In still other embodiments, the process 200 of
For example, turning to
As described above, in some embodiments, the base layer of a humidity control device of the present disclosure may be or include a product packaging material, such that the humidity control device may be constructed directly on a material that will ultimately be an inner surface of a product package. As shown for example in
Turning now to
A humidity control device of the present disclosure may generally be constructed of materials that not only allow relatively high permeability of water vapor through at least a portion of the containment, but also are sufficiently tough to resist abuse that may otherwise result in the containment rupturing and contaminating the product with the humidity control agent. The humidity control devices of the present disclosure may additionally be constructed economically, such that the devices may be applied to a wide variety of product packaging. The humidity control devices described herein may additionally meet applicable performance standards and requirements.
As generally described above, and as shown in
In some embodiments, humidity control devices including a base layer, a permeable layer, and a humidity control material contained between the base layer and the permeable layer, may be provided in a continuous roll for use in assembly of product packages including the humidity control devices. In
Another example is shown in
The rolls or stacks of humidity control devices (or other delivery configurations) may be used in processes of assembling product packages to supply humidity control devices to the interior spaces of the product package, where the product will be stored. The humidity control devices may be supplied as loose items within the product packages or may be removably or permanently adhered to an interior surface of the product packages.
An example of a process by which a roll of humidity control devices may be used in the process of assembling a package, or may be added to packing material prior to being assembled into a package, is shown in
Another example of a process by which a roll of humidity control devices may be used in the process of assembling a package is shown in
In each of examples 8A and 8B, the choice of adhesive 922972 may be compatible with the product to be supplied within the package. For example, if the package is for use with food products or other consumables such as tobacco or cannabis products, a food grade adhesive may be used. Furthermore, an adhesive may be selected which is sufficiently strong to maintain attachment of the humidity control device 932982 to the package layer 912962 throughout package production, filling, transportation, and end use by a consumer, for example. In addition, the choice of sealing system 940990 used may depend upon the type of adhesive 922972 and how it is applied (such as pattern of delivery (sheet, line, dots, etc.), temperature, etc.). For example, if the adhesive is heat activated, the sealing system may include a heater, though other adhesives and/or sealing systems may alternatively be used as described above such as a hot melt adhesive applied in a molten state with a sealing system providing pressure.
It should further be understood that in each of examples 8A and 8B and in other variations, the package material layer 912962 with adhered humidity control devices 932972 may continue directly, such as further along the conveyor system, or indirectly, to the folding, cutting, sealing and/or other steps of forming the package material layer 912962 into a package component such as a package lid or a final finished package. In some embodiments, one or more steps of the manufacture of the package such as folding, cutting, sealing of the package material layer and/or other steps may occur prior to the adhesion of the humidity control device 932972 the package material layer 912962. The package material layer 912962 may be formed into pouches, packets, or other complete or precursor package structures before, during, or after the operations depicted in
The processes described with regard to
While the processes described with regard to
In one particular example, a humidity control device was formed with a base layer, a humidity control material, and a permeable layer. A base layer of material was constructed with oriented polypropylene having a thickness of 0.00075 inches, metallized polyester having a thickness of 0.0005 inches, and polyethylene having a thickness of 0.0025 inch. Approximately eight grams of a humidity control material, in the form of a gel, was applied to approximately a 2-3 inch area of the base layer. A pressure sensitive hot melt adhesive was deposited on the base layer in a perimeter around the humidity control material. The adhesive was applied with a thickness or depth of approximately 0.075 inches. While the adhesive material was still relatively hot and molten, the permeable layer was positioned over the humidity control material and the adhesive so as to bond to the base layer via the adhesive. The permeable layer was a cast nylon film with a thickness of approximately 0.001 inches. The humidity control device was subject to various stresses, including physical manipulation, exposure to temperatures of at least 110 degrees Fahrenheit, and shipment across 500 miles via the United States Postal Services. Despite these various stresses, the base layer and permeable layer remained bonded to one another, and the gel remained in place between the two layers.
As used herein, the terms “substantially” or “generally” refer to the complete or nearly complete extent or degree of an action, characteristic, property, state, structure, item, or result. For example, an object that is “substantially” or “generally” enclosed would mean that the object is either completely enclosed or nearly completely enclosed. The exact allowable degree of deviation from absolute completeness may in some cases depend on the specific context. However, generally speaking, the nearness of completion will be so as to have generally the same overall result as if absolute and total completion were obtained. The use of “substantially” or “generally” is equally applicable when used in a negative connotation to refer to the complete or near complete lack of an action, characteristic, property, state, structure, item, or result. For example, an element, combination, embodiment, or composition that is “substantially free of” or “generally free of” an element may still actually contain such element as long as there is generally no significant effect thereof.
In the foregoing description various embodiments of the present disclosure have been presented for the purpose of illustration and description. They are not intended to be exhaustive or to limit the invention to the precise form disclosed. Obvious modifications or variations are possible in light of the above teachings. The various embodiments were chosen and described to provide the best illustration of the principals of the disclosure and their practical application, and to enable one of ordinary skill in the art to utilize the various embodiments with various modifications as are suited to the particular use contemplated. All such modifications and variations are within the scope of the present disclosure as determined by the appended claims when interpreted in accordance with the breadth they are fairly, legally, and equitably entitled.
This application claims priority to Provisional Application No. 62/407,269, entitled Device for Controlling Headspace Humidity and Methods for Making the Same, and filed Oct. 12, 2016, the content of which is hereby incorporated by reference herein in its entirety. This application also claims priority to application Ser. No. 15/782,363, entitled Device for Controlling Headspace Humidity and Methods for Making the Same, and filed Oct. 12, 2017, the content of which is also hereby incorporated by reference herein in its entirety.
Number | Name | Date | Kind |
---|---|---|---|
339492 | Smith | Apr 1886 | A |
1241695 | Alexander | Oct 1914 | A |
1222656 | Moyer | Apr 1917 | A |
1268135 | McElroy | Jun 1918 | A |
1425790 | Moyer | Aug 1922 | A |
1481971 | Whiting | Jan 1924 | A |
1556951 | Marshall | Oct 1925 | A |
1841889 | Grunwald | Jan 1932 | A |
1866560 | Gordon et al. | Jul 1932 | A |
1871418 | McKee | Aug 1932 | A |
1871419 | McKee | Aug 1932 | A |
1967554 | Gross et al. | Jul 1934 | A |
1972118 | McDill | Sep 1934 | A |
1998683 | Montgomery | Apr 1935 | A |
2080402 | Herman | May 1937 | A |
2085600 | Petersen | Jun 1937 | A |
2169055 | Overshiner | Aug 1939 | A |
2227158 | Saul | Dec 1940 | A |
2236024 | Tyler | Mar 1941 | A |
2270603 | Ridder | Jan 1942 | A |
2300041 | Samuel | Oct 1942 | A |
2329908 | Johnson | Sep 1943 | A |
2365185 | Gailey | Dec 1944 | A |
2368140 | Johnson | Jan 1945 | A |
2452957 | Sabin | Nov 1948 | A |
2458695 | Edelston | Jan 1949 | A |
2545710 | Snyder | Mar 1951 | A |
2758932 | Scott | Aug 1956 | A |
2807514 | Williams | Sep 1957 | A |
3135566 | Charles | Jun 1964 | A |
3204388 | Asker | Sep 1965 | A |
3211503 | Barnes | Oct 1965 | A |
3254784 | Lancesseur | Jun 1966 | A |
3315447 | Meier | Apr 1967 | A |
3419400 | Hayhurst | Dec 1968 | A |
3567085 | Flores | Mar 1971 | A |
3578545 | Carson et al. | May 1971 | A |
3719033 | Den Boer | Mar 1973 | A |
3722188 | Cullen | Mar 1973 | A |
3785556 | Watkins | Jan 1974 | A |
3801011 | Guehler et al. | Apr 1974 | A |
3815828 | Engel | Jun 1974 | A |
3820309 | Cullen et al. | Jun 1974 | A |
3897226 | Doherty | Jul 1975 | A |
3990872 | Cullen | Nov 1976 | A |
4027068 | Saad | May 1977 | A |
4091930 | Buchner | May 1978 | A |
4127503 | Yoshikawa et al. | Nov 1978 | A |
4145001 | Weyenberg et al. | Mar 1979 | A |
4146277 | Santoro | Mar 1979 | A |
4150372 | Foote | Apr 1979 | A |
4158440 | Sullivan et al. | Jun 1979 | A |
4161283 | Hyman | Jul 1979 | A |
4192773 | Yoshikawa et al. | Mar 1980 | A |
4223070 | Hahn et al. | Sep 1980 | A |
4279350 | King | Jul 1981 | A |
4285468 | Hyman | Aug 1981 | A |
4287995 | Moriya | Sep 1981 | A |
4384972 | Nakamura et al. | May 1983 | A |
4406843 | Nakamura et al. | Sep 1983 | A |
4421235 | Moriya | Dec 1983 | A |
4423080 | Bedrosian et al. | Dec 1983 | A |
4445641 | Baker et al. | May 1984 | A |
4524015 | Takahashi et al. | Jun 1985 | A |
4528228 | Clevenger | Jul 1985 | A |
4572051 | Laskin | Feb 1986 | A |
4594082 | Catherwood, Sr. | Jun 1986 | A |
4614528 | Lennen | Sep 1986 | A |
4615923 | Marx | Oct 1986 | A |
4645698 | Matsubara | Feb 1987 | A |
4649793 | Blackshear et al. | Mar 1987 | A |
4686776 | Matsubara | Aug 1987 | A |
RE32513 | Seaber et al. | Oct 1987 | E |
4749392 | Aoki et al. | Jun 1988 | A |
4756436 | Morita | Jul 1988 | A |
4756726 | Peace | Jul 1988 | A |
4772300 | Cullen et al. | Sep 1988 | A |
4783206 | Cullen et al. | Nov 1988 | A |
4813791 | Cullen | Mar 1989 | A |
4822500 | Dobson, Jr. et al. | Apr 1989 | A |
4834234 | Sacherer et al. | May 1989 | A |
4840280 | Schvester | Jun 1989 | A |
4891141 | Christensen et al. | Jan 1990 | A |
4903827 | Phelps et al. | Feb 1990 | A |
4923059 | Evers et al. | May 1990 | A |
4934524 | St. Charles | Jun 1990 | A |
4997082 | Dorocher | Mar 1991 | A |
5019212 | Morita et al. | May 1991 | A |
5035731 | Spruill et al. | Jul 1991 | A |
5037459 | Spruill | Aug 1991 | A |
5096724 | Zenner | Mar 1992 | A |
5114003 | Jackisch et al. | May 1992 | A |
5130018 | Tolman et al. | Jul 1992 | A |
5135787 | Bair | Aug 1992 | A |
5219075 | White | Jun 1993 | A |
5224383 | Williams | Jul 1993 | A |
5284871 | Graf | Feb 1994 | A |
5289751 | Light | Mar 1994 | A |
5378428 | Inoue et al. | Jan 1995 | A |
5390475 | Iwauchi | Feb 1995 | A |
5641425 | McKedy et al. | Jun 1997 | A |
5698217 | Wilking | Dec 1997 | A |
5773105 | Klett | Jun 1998 | A |
5846450 | Atkinson | Dec 1998 | A |
5885481 | Venkateshwaran et al. | Mar 1999 | A |
5934458 | Duron | Aug 1999 | A |
5934773 | Ferrell | Aug 1999 | A |
5936178 | Saari | Aug 1999 | A |
5944306 | Maeda | Aug 1999 | A |
5975288 | Crowder | Nov 1999 | A |
5977212 | Ebner et al. | Nov 1999 | A |
6041575 | Vonderhorst | Mar 2000 | A |
6119855 | Yeager | Sep 2000 | A |
6139935 | Cullen et al. | Oct 2000 | A |
6156421 | Stopper | Dec 2000 | A |
6158580 | Davis | Dec 2000 | A |
6244432 | Saari et al. | Jun 2001 | B1 |
6274209 | Pagidas et al. | Aug 2001 | B1 |
6436872 | McKedy | Aug 2002 | B2 |
6508955 | DelDuca et al. | Jan 2003 | B1 |
6514321 | Lehto et al. | Feb 2003 | B1 |
6571942 | Riemenschneider et al. | Jun 2003 | B2 |
6620992 | Kinnaird | Sep 2003 | B1 |
6646121 | El Kabbani et al. | Nov 2003 | B2 |
6666988 | DelDuca et al. | Dec 2003 | B2 |
6740145 | Boroson et al. | May 2004 | B2 |
6921026 | Saari et al. | Jul 2005 | B2 |
6926846 | DelDuca et al. | Aug 2005 | B1 |
6932267 | Potenza | Aug 2005 | B2 |
6986807 | Brunk | Jan 2006 | B2 |
7147799 | DelDuca et al. | Dec 2006 | B2 |
7475773 | Lancesseur et al. | Jan 2009 | B2 |
8033391 | D'Abusco | Oct 2011 | B1 |
8048201 | Dukes et al. | Nov 2011 | B2 |
8087645 | Hepple | Jan 2012 | B2 |
8211209 | Neff | Jul 2012 | B2 |
8220782 | Hepple | Jul 2012 | B2 |
8528469 | Doglioni Majer | Sep 2013 | B2 |
8590719 | Sprishen et al. | Nov 2013 | B2 |
8748723 | Egberg et al. | Jun 2014 | B1 |
8771770 | Crump | Jul 2014 | B1 |
9616382 | Glorioso et al. | Apr 2017 | B2 |
9750811 | Egberg et al. | Sep 2017 | B2 |
10081465 | Biesecker Longacre | Sep 2018 | B2 |
10220992 | Biesecker Longacre et al. | Mar 2019 | B2 |
20030029739 | Riemenschneider et al. | Feb 2003 | A1 |
20030203081 | Saari et al. | Oct 2003 | A1 |
20040022676 | Hamilton et al. | Feb 2004 | A1 |
20040045969 | Chiang | Mar 2004 | A1 |
20040198611 | Atkinson et al. | Oct 2004 | A1 |
20040224144 | Saari et al. | Nov 2004 | A1 |
20050172814 | Brunk | Aug 2005 | A1 |
20060097223 | Powers et al. | May 2006 | A1 |
20060144726 | Foust | Jul 2006 | A1 |
20070014686 | Arnold et al. | Jan 2007 | A1 |
20070114140 | Portier | May 2007 | A1 |
20080012172 | Merical et al. | Jan 2008 | A1 |
20080178559 | DeFedericis | Jul 2008 | A1 |
20080314772 | Saari et al. | Dec 2008 | A1 |
20100221393 | Lim et al. | Sep 2010 | A1 |
20100304357 | Meyers et al. | Dec 2010 | A1 |
20110017615 | Logel et al. | Jan 2011 | A1 |
20110079525 | Peck et al. | Apr 2011 | A1 |
20110221393 | Billmaier | Sep 2011 | A1 |
20110253232 | Seline et al. | Oct 2011 | A1 |
20120020833 | Cook et al. | Jan 2012 | A1 |
20130056369 | Jorgensen | Mar 2013 | A1 |
20130153445 | Cullison | Jun 2013 | A1 |
20130334074 | Wada et al. | Dec 2013 | A1 |
20140209488 | Dai | Jul 2014 | A1 |
20140270581 | Jons | Sep 2014 | A1 |
20140339106 | Schanin et al. | Nov 2014 | A1 |
20150053579 | Lebon et al. | Feb 2015 | A1 |
20150136618 | Patel et al. | May 2015 | A1 |
20150201673 | Houmani | Jul 2015 | A1 |
20150259115 | Yeh | Sep 2015 | A1 |
20150328584 | Egberg et al. | Nov 2015 | A1 |
20160031627 | Yeh | Feb 2016 | A1 |
20170225867 | Dasgupta et al. | Aug 2017 | A1 |
20180099797 | Biesecker Longacre et al. | Apr 2018 | A1 |
20180099804 | Biesecker Longacre et al. | Apr 2018 | A1 |
20180257830 | Biesecker Longacre et al. | Sep 2018 | A1 |
20190002140 | Riley et al. | Jan 2019 | A1 |
20190177058 | Biesecker Longacre et al. | Jun 2019 | A1 |
Number | Date | Country |
---|---|---|
667514 | Oct 1988 | CH |
101128891 | Feb 2008 | CN |
201901339 | Jul 2011 | CN |
202014103600 | Aug 2014 | DE |
102014106507 | Nov 2015 | DE |
0212913 | Mar 1987 | EP |
317041 | May 1989 | EP |
348840 | Jan 1990 | EP |
363194 | Nov 1990 | EP |
0531075 | Mar 1993 | EP |
0866111 | Sep 1998 | EP |
1645521 | Apr 2006 | EP |
1140952 | Aug 1957 | FR |
1238709 | Aug 1960 | FR |
1246918 | Oct 1960 | FR |
2620685 | Mar 1989 | FR |
2222816 | Mar 1990 | GB |
S407759 | Mar 1965 | JP |
2002274575 | Sep 2002 | JP |
M452154 | May 2013 | TW |
9857321 | Dec 1998 | WO |
2006125834 | Nov 2006 | WO |
Entry |
---|
Office Action issued Jun. 29, 2018 in U.S. Appl. No. 15/978,713 by Biesecker Longacre. |
Ageless® Oxygen Absorber Instruction Manual, Mitsubishi Gas Chemical Company, Inc., May 2011 (32 pages). |
Ageless® Product Page, Mitsubishi Gas Chemical America, copyright 2015. Accessed on the Internet Aug. 10, 2015 URL:<http://ageless.mgc-a.com/product/ageless> (2 pages). |
Altura Company, Division of Peak Innovations, Inc. Quality Preserved, 6159 Omni Park Drive, Suite B, Mobile, AL 36609; Phone (334) 639-0345; Fax (334) 639-8983; e-mail: peak@mobls.com; “Humi-Pouch”; “Humi-Ship”; “Humi-Box”; patent pending. Cited with respect to U.S. Pat. No. 5,936,178; Dec. 22, 1997 (1 page). |
Caribbean Cigar Company of Miami, Florida; “Simple 70 Solution & Humidification”; The Humidification Solution. Cited with respect to U.S. Pat. No. 5,936,178; Dec. 22, 1997 (1 page). |
Credo of Marseille, France: “the Tube”; Humidity Regulator for Pocket Humidor. Cited with respect to U.S. Pat. No. 5,936,178; Dec. 22, 1997 (1 page). |
DuPont Tyvek for Graphics: Features & Benefits, Dupont USA, p. 1 (Year: 2015). |
Deutsch, JC “Ascorbic acid oxidation by hydrogen peroxide”, Anal Biochem, Jan. 1, 1998, 255(1): 1-7. Abstract only (1 page). |
Esse et al., “Competitive Humidity Control Devices,” Seiyge, 6 pages (Dec. 22, 1997). |
FreshPax® Oxygen Absorber Product Page, Multisorb Technologies, copyright 2015. Accessed on the Internet Aug. 10, 2015 URL:<http://www.multisorb.com/products-and-systems/freshpax-oygen-absorber-packets-and-strips> (6 pages). |
International Search Report and Written Opinion for related PCT Application No. PCT/US2014/015547 mailed May 26, 2014 (10 pages). |
International Search Report and Written Opinion for related PCT Application No. PCT/US2016/021496 mailed Jun. 15, 2016 (10 pages). |
International Search Report and Written Opinion for related PCT Application PCT/US2017/056341 mailed Feb. 7, 2018 (11 pages). |
International Search Report and Written Opinion for related PCT Application PCT/US2017/056394 mailed Jan. 9, 2018 (15 pages). |
International Search Report for related PCT Application No. PCT/US98/11968 mailed Sep. 15, 1998 (1 page). |
Mechanical and Electrical Products Rust-Proof, Packaging Handbook, Zhang KF et al. Aviation Industry Press, Oct. 31, 1990. https://vpn.hw.sipo/proxy*99148242/n/print.jsp (8 pages). |
Owner unknown; “DHS”; Disposable Humidifcation System. Cited with respect to U.S. Pat. No. 5,936,178; Dec. 22, 1997 (1 pages). |
PTCA Industries, Inc., P.O. Box 16360 (Office), San Francisco, CA 94116; P.O. Box 250 (Factory), San Carlos, CA 94070; Phone (415) 592 7311; “Humatic 50”; Conditions and maintains up to 50 cigars; U.S. and foreign patents pending. Cited with respect to U.S. Pat. No. 5,936,178; Dec. 22, 1997 (1 page). |
StayFresh® SF5CS1500EE-500cc Oxygen Absorbers Product Page, Impak Corporation, copyright 2014. Accessed on the Internet Aug. 10, 2015 URL:<http://www.impakcorporation.com/oxygen_absorbers/SF5CS1500EE> (2 pages). |
Tyvek FAQ, DuPont USA, p. 2 (Year: 2013). |
Western Humidor Corporation of USA; “Torpedo”, Humidifier Portable Humidification System, cited with respect to U.S. Pat. No. 5,936,178; Dec. 22, 1997 (1 page). |
Number | Date | Country | |
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20200207534 A1 | Jul 2020 | US |
Number | Date | Country | |
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62407269 | Oct 2016 | US |
Number | Date | Country | |
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Parent | 15782363 | Oct 2017 | US |
Child | 16780968 | US |