The present invention concerns a device for dewatering and drying solids, in particular plastics granulated in water, in the form of a centrifuge dryer wherein most of the water can be separated from the mixture of granulate and water by a screen device arranged before the centrifuge dryer. The granulate with the remaining surface water that still adheres to it is then transferred to the inlet opening of the centrifuge dryer where it is accelerated by means of rotor blades and is at the end conveyed to the outlet opening.
Such a device is for example seen in DE 10 2004 053 929 A1, where a mixture of granulate and cooling water is supplied to a centrifuge dryer which is arranged adjacent to a cooling arrangement. In the method of granulate drying shown therein, the adherent surface water is centrifuged off, together with plastic dust which also clings to the surface. At the same time, evaporative cooling takes place by the drying of the surface moisture of the granulate in an air stream. A screen-like water separator is arranged between the drying arrangement and the centrifuge dryer.
The centrifuge dryer comprises a cylindrical housing and a cylindrical screen fixedly arranged therein. Arranged within the screen is a motor driven rotor that can be driven at high revolutions. The rotor comprises paddle-like arms that accelerate the wet granulate and the water that still adheres to it. Due to the design of the arms, the granulate is propelled from the lower inlet upward and is dewatered at the same time. The water is centrifuged off through the screen.
Residual surface moisture remains on the granulate and is removed by evaporation in the centrifuge dryer. This cooling-down drying is supported by an air stream, which is aspirated from the top into the housing and is exhausted by a blower at approximately half the height of the housing.
Instead of the paddle-like arms, other known devices of the relevant art comprise baffles affixed to the rotor and arranged at an angle to the vertical axis, causing a vertical conveyance of the granulate within the centrifugal dryer from the inlet opening on the bottom upward to the outlet opening.
The disadvantage of these known devices is that the wet granulate is always supplied to the centrifuge dryer radially, whereby the granulate is caught frontally by the paddle-like arms or baffles and first propelled against the fixed screen from where it rebounds and is again captured by the paddle-like arms or baffles. This process is repeated until the granulate reaches the outlet opening and passes through it. The frontal capture of the granulate exposes it to higher mechanical stress in the inlet area. This results in greater amounts of plastic dust, which settles in the immediate area of the inlet opening, aided in particular by air stream eddies. The removal of the dust by means of cleaning fluids introduced into the centrifuge dryer space by nozzles is more difficult in this area than in the remaining inner space of the centrifuge dryer.
This can go so far that, especially for the drying of sensitive granules, in particular of composite granulates, the known centrifuge dryers cannot be used at all for the dewatering and drying of these granulates because too high a proportion of the granulate would be damaged by the known centrifuge dryer.
Due to the frontal capture of the granulate, the fixed screen and the paddle-like arms or baffles in the region near the inlet opening are exposed to much higher wear than in the regions above. Since the outlet opening is also arranged radially, there is also higher wear in the immediate vicinity of the outlet opening, especially at the frontal edge.
A further substantial disadvantage is the overall design of the device which makes it difficult to maintain. The centrifuge dryer has to be cleaned completely after every change of granulate color or composition. Any remnants that are not removed completely before the next load of plastic granulate passes through the centrifuge dryer contaminate the granulate and result in substantial quality flaws.
For this purpose, several nozzles for the cleaning fluid are commonly provided inside the centrifuge dryer. Wherever the deposit of plastic dust is particularly heavy, for example, as mentioned earlier, in the vicinity of the inlet opening, spraying of the cleaning fluid is not always sufficient, or the cleaning is only satisfactory with disproportionately great amounts of the cleaning fluid. However, since the expense of preparing the cleaning fluid is proportionate to the quantity, it is in most cases more economical to open the device, loosen the remaining residue by hand and to rinse it out. In known devices, this requires disproportionately high disassembly and reassembly expenditures.
Therefore an object of the present invention is to provide a device of the generic kind for dewatering and drying solids, especially plastics granulated in water, in form of a centrifuge dryer which reliably avoids the disadvantages of prior art.
According to an aspect of the invention, a device for dewatering and drying solids, in particular plastics granulated in water, in the form of a centrifuge dryer comprises a housing having an inlet opening for the solid material with adhering water and an outlet opening for the dewatered solid material. A screen cylinder is fixedly disposed inside the housing. A rotor is arranged inside the screen cylinder and wings are attached to the rotor at a distance from one another. A water drain and arrangements for the introduction and removal of an air stream passing vertically through the device are provided as well. The inlet opening is arranged tangentially in relation to the screen cylinder.
Other advantages on objects of the invention will become apparent from the present specification, including an advantageous variant aimed at easier cleaning of known devices of the art.
The invention will be explained below in more detail by way of figures. Shown therein are in
As can be seen in
As can be seen in
Another device can be seen in
Due to the essentially tangential introduction of the granulate and water mixture to the fixed screen cylinder 4 or 10 or to the screen segment 10 in the lower region of the device, upon introduction into the device the granulate is first whirled only over the surface of the screen cylinder 4 or 10 or over the surface of the screen segment 10 so that the water clinging to the granulate can be flung off for the most part only by the centrifugal forces created thereby. As a result, the acceleration imparted upon the granulate and water mixture remains limited by the rotor wings 6 so that the mechanical stressing of the granulate at introduction, i.e. the moment when it has the greater weight due to the adhering surface water, is considerably reduced in contrast to the known devices of the relevant art.
This results in considerably reduced damage, especially regarding the more sensitive granulates, and in a considerably reduced separation of plastic dust or composite material dust.
As can also be seen from
As mentioned above, in known devices of the relevant art this represents a particular problem since these deposits, as they collect over the height of the device, gather especially in the lower region, and there especially around the inlet opening 2.
In order to provide more effective cleaning in this region, it has been found advantageous to create the fixed screen cylinder 4 from at least three screen cylinders 10, 11 and 12, arranged vertically one over another where each screen cylinder 10, 11 and 12 is composed of at least two segment shells 10′, 10″, 11′, 11″, 12′, 12″. The lowermost screen cylinder 10, as can be seen in
The inlet opening 2 is positioned inside the solid segment 10″. In addition, the solid segment 10″ is covered on the side facing the inside wall of the housing 1 by a cover element 13 whose horizontal region, not visible in
Construction of the screen cylinders 10, 11 and 12 from at least two segments 10′, 10″, 11′, 11″, 12′, 12″ also contributes to an easier disassembly of the screen cylinder 4 during replacement of worn wings 6. It is self-evident that for taller designs, the screen cylinder 11 can be composed of two or more identical screen cylinders 11. The screen cylinders 10, 11 and 12 are connected to one another in a suitable manner.
This construction of the lower screen cylinder 10 from a screen-like segment 10′ and a completely solid segment 10″ supports in a particularly advantageous way the effect of the tangentially arranged inlet opening 2, which is here in particular arranged inside the segment 10″, which has a solid surface. In an advantageous further development, the uppermost screen cylinder 12 is likewise composed of a screen-like segment 12′ and a completely solid segment 12″ which can substantially reduce the abrasion wear along the edge of the outlet opening 3. This effect is further increased in an advantageous further development by the placement of the outlet 3 tangentially in relation to the screen cylinder 12, and here in particular inside the completely solid segment 12″.
In a further advantageous development, the wings 6 are joined to the rotor 5 so as to be individually detachable by means of mounting surfaces 14 attached thereto. Based on this design, it is possible for the first time to select different installation angles of the wings 6 over the extent of the rotor axle, which permits an advantageous regulation of the granulate flow behavior. This measure also permits the device to be optimized for the granulate material to be dried, in that the impact forces are adjusted by the installation angle.
Since the wings 6 are naturally exposed to very high wear that varies in magnitude along the rotor axis, it is now possible for the first time to replace the wings 6 at different times, due to the possibility of installing the wings individually. In this case, the construction of the screen cylinder 4 comprising multiple cylinders 10, 11 and 12 proves to be particularly service-friendly.
In order to increase in-service time of the wings it has been found advantageous to coat parts or all of the wings on one side with a wear protection coating or to fabricate them from a metallic base material with a wear resistant surface.
Additionally, the in-service time of the lower half-shell 10″ and the upper half-shell 12″ is increased by coating them with a wear resistant coating or fabrication from a metallic base material with a wear resistant surface.
Number | Date | Country | Kind |
---|---|---|---|
06120976 | Sep 2006 | EP | regional |
Number | Name | Date | Kind |
---|---|---|---|
2074265 | Kirby | Mar 1937 | A |
2114776 | Davis | Apr 1938 | A |
2222633 | Sheesley | Nov 1940 | A |
2739669 | Miller | Mar 1956 | A |
2739670 | Miller | Mar 1956 | A |
2920399 | Fry, Jr. | Jan 1960 | A |
3125294 | Lill | Mar 1964 | A |
3197798 | Brown et al. | Aug 1965 | A |
3206950 | Xeros | Sep 1965 | A |
3277583 | Mack | Oct 1966 | A |
3319556 | Fiore | May 1967 | A |
3702488 | Kasper | Nov 1972 | A |
3726756 | Polak | Apr 1973 | A |
3794166 | Converse et al. | Feb 1974 | A |
3837029 | Kasper | Sep 1974 | A |
3879789 | Kasper | Apr 1975 | A |
3951805 | Dodd | Apr 1976 | A |
3956135 | Mercier | May 1976 | A |
4028222 | Prull | Jun 1977 | A |
4164467 | Liller | Aug 1979 | A |
4199459 | Filipowicz et al. | Apr 1980 | A |
4218323 | McCracken | Aug 1980 | A |
4325819 | Altizer | Apr 1982 | A |
4339280 | Mercier | Jul 1982 | A |
4344479 | Bailey | Aug 1982 | A |
4455282 | Marquess et al. | Jun 1984 | A |
4565015 | Hundley, III | Jan 1986 | A |
4716218 | Chen et al. | Dec 1987 | A |
4879075 | Hinton | Nov 1989 | A |
4896435 | Spangler, Jr. | Jan 1990 | A |
4922625 | Farmer | May 1990 | A |
4954222 | Durr et al. | Sep 1990 | A |
4961722 | Taylor et al. | Oct 1990 | A |
4991766 | Hunnicutt et al. | Feb 1991 | A |
5069755 | Durr et al. | Dec 1991 | A |
5073201 | Giesfeldt et al. | Dec 1991 | A |
5090498 | Hamill | Feb 1992 | A |
5125166 | Farmer | Jun 1992 | A |
5136792 | Janecke | Aug 1992 | A |
5265347 | Woodson et al. | Nov 1993 | A |
5279047 | Janecke | Jan 1994 | A |
5331106 | Spas | Jul 1994 | A |
5361711 | Beyerl | Nov 1994 | A |
5366591 | Jewell | Nov 1994 | A |
5534139 | Cadek et al. | Jul 1996 | A |
5556976 | Jewell | Sep 1996 | A |
5626766 | Cadek et al. | May 1997 | A |
5638606 | Bryan et al. | Jun 1997 | A |
5662810 | Willgohs | Sep 1997 | A |
5695130 | Csendes | Dec 1997 | A |
5737674 | Venkatesan et al. | Apr 1998 | A |
5958233 | Willgohs | Sep 1999 | A |
5964985 | Wootten | Oct 1999 | A |
5987769 | Ackerman et al. | Nov 1999 | A |
5988264 | Goldsmith | Nov 1999 | A |
6003500 | Packard et al. | Dec 1999 | A |
6013158 | Wootten | Jan 2000 | A |
6035834 | Packard et al. | Mar 2000 | A |
6106592 | Paranjpe et al. | Aug 2000 | A |
6109452 | Leung et al. | Aug 2000 | A |
6129042 | Smith et al. | Oct 2000 | A |
6138375 | Humphries et al. | Oct 2000 | A |
6138647 | Packard et al. | Oct 2000 | A |
6143221 | Gurol | Nov 2000 | A |
6145498 | Packard et al. | Nov 2000 | A |
6237244 | Bryan et al. | May 2001 | B1 |
6267250 | Leung et al. | Jul 2001 | B1 |
6270708 | Gurol | Aug 2001 | B1 |
6326054 | Smith et al. | Dec 2001 | B1 |
6327994 | Labrador | Dec 2001 | B1 |
6360975 | Csendes | Mar 2002 | B1 |
6368657 | Lee | Apr 2002 | B1 |
6432299 | Hensley et al. | Aug 2002 | B1 |
6438864 | Sandford | Aug 2002 | B1 |
6467188 | Sandford | Oct 2002 | B1 |
6505416 | Sandford | Jan 2003 | B2 |
6514421 | Leung et al. | Feb 2003 | B2 |
6655039 | Hultsch | Dec 2003 | B2 |
6691536 | Severns et al. | Feb 2004 | B2 |
6739457 | Humphries et al. | May 2004 | B2 |
6807748 | Bryan et al. | Oct 2004 | B2 |
6887710 | Call et al. | May 2005 | B2 |
6898951 | Severns et al. | May 2005 | B2 |
6904885 | Osband | Jun 2005 | B2 |
7024794 | Mynes | Apr 2006 | B1 |
7025883 | Olivier | Apr 2006 | B1 |
7040101 | Takeda et al. | May 2006 | B2 |
7044429 | Foreman et al. | May 2006 | B1 |
7171762 | Roberts et al. | Feb 2007 | B2 |
7244356 | Olivier | Jul 2007 | B2 |
7275400 | Severns et al. | Oct 2007 | B2 |
7306733 | Olivier | Dec 2007 | B2 |
7312973 | Sekoguchi et al. | Dec 2007 | B2 |
7421802 | Roberts et al. | Sep 2008 | B2 |
7442306 | Olivier | Oct 2008 | B2 |
7533719 | Hinson et al. | May 2009 | B2 |
7540324 | de Rouffignac et al. | Jun 2009 | B2 |
7562707 | Miller | Jul 2009 | B2 |
7569354 | Okano et al. | Aug 2009 | B2 |
7597147 | Vitek et al. | Oct 2009 | B2 |
7604052 | Roes et al. | Oct 2009 | B2 |
7610962 | Fowler | Nov 2009 | B2 |
7622140 | Whittle et al. | Nov 2009 | B2 |
7631689 | Vinegar et al. | Dec 2009 | B2 |
7631690 | Vinegar et al. | Dec 2009 | B2 |
7635023 | Goldberg et al. | Dec 2009 | B2 |
7635024 | Karanikas et al. | Dec 2009 | B2 |
7638915 | Sentmanat | Dec 2009 | B2 |
7644765 | Stegemeier et al. | Jan 2010 | B2 |
7673681 | Vinegar et al. | Mar 2010 | B2 |
7673786 | Menotti | Mar 2010 | B2 |
7677310 | Vinegar et al. | Mar 2010 | B2 |
7677314 | Hsu | Mar 2010 | B2 |
7681647 | Mudunuri et al. | Mar 2010 | B2 |
7683296 | Brady et al. | Mar 2010 | B2 |
7703513 | Vinegar et al. | Apr 2010 | B2 |
7717171 | Stegemeier et al. | May 2010 | B2 |
7730945 | Pieterson et al. | Jun 2010 | B2 |
7730946 | Vinegar et al. | Jun 2010 | B2 |
7730947 | Stegemeier et al. | Jun 2010 | B2 |
7731163 | Olivier | Jun 2010 | B2 |
7780750 | Carman | Aug 2010 | B2 |
7785427 | Maziasz et al. | Aug 2010 | B2 |
7793722 | Vinegar et al. | Sep 2010 | B2 |
7798220 | Vinegar et al. | Sep 2010 | B2 |
7832484 | Nguyen et al. | Nov 2010 | B2 |
7841401 | Kuhlman et al. | Nov 2010 | B2 |
7841408 | Vinegar | Nov 2010 | B2 |
7841425 | Mansure et al. | Nov 2010 | B2 |
7845411 | Vinegar et al. | Dec 2010 | B2 |
7849922 | Vinegar et al. | Dec 2010 | B2 |
7866385 | Lambirth | Jan 2011 | B2 |
7875173 | Barnes | Jan 2011 | B1 |
7912358 | Stone et al. | Mar 2011 | B2 |
7931086 | Nguyen et al. | Apr 2011 | B2 |
20020014019 | Hultsch | Feb 2002 | A1 |
20020030024 | Leung et al. | Mar 2002 | A1 |
20020062575 | Sandford | May 2002 | A1 |
20020062576 | Sandford | May 2002 | A1 |
20020124664 | Call et al. | Sep 2002 | A1 |
20020133886 | Severns et al. | Sep 2002 | A1 |
20030033725 | Humphries et al. | Feb 2003 | A1 |
20030037757 | Osband | Feb 2003 | A1 |
20030131623 | Suppes | Jul 2003 | A1 |
20030221438 | Rane et al. | Dec 2003 | A1 |
20040000069 | Gurol | Jan 2004 | A1 |
20040000734 | Kapphan et al. | Jan 2004 | A1 |
20040007000 | Takeda et al. | Jan 2004 | A1 |
20040086774 | Munoz et al. | May 2004 | A1 |
20040129032 | Severns et al. | Jul 2004 | A1 |
20040147767 | Whittle et al. | Jul 2004 | A1 |
20050050644 | Severns et al. | Mar 2005 | A1 |
20050109695 | Olivier | May 2005 | A1 |
20050133423 | Olivier | Jun 2005 | A1 |
20050159309 | Hubbell et al. | Jul 2005 | A1 |
20050168907 | Sekoguchi et al. | Aug 2005 | A1 |
20060080854 | Mynes | Apr 2006 | A1 |
20060130353 | Eloo | Jun 2006 | A1 |
20060144784 | Olivier | Jul 2006 | A1 |
20060169627 | Olivier | Aug 2006 | A1 |
20060202369 | Foreman et al. | Sep 2006 | A1 |
20060257287 | Call et al. | Nov 2006 | A1 |
20070036881 | Griffith | Feb 2007 | A1 |
20070059763 | Okano et al. | Mar 2007 | A1 |
20070245934 | Carman | Oct 2007 | A1 |
20070284108 | Roes et al. | Dec 2007 | A1 |
20070289733 | Hinson et al. | Dec 2007 | A1 |
20080017380 | Vinegar et al. | Jan 2008 | A1 |
20080035346 | Nair et al. | Feb 2008 | A1 |
20080035347 | Brady et al. | Feb 2008 | A1 |
20080035348 | Vitek et al. | Feb 2008 | A1 |
20080035705 | Menotti | Feb 2008 | A1 |
20080038144 | Maziasz et al. | Feb 2008 | A1 |
20080054745 | Sentmanat | Mar 2008 | A1 |
20080072447 | Hehenberger et al. | Mar 2008 | A1 |
20080128134 | Mudunuri et al. | Jun 2008 | A1 |
20080135244 | Miller | Jun 2008 | A1 |
20080135253 | Vinegar et al. | Jun 2008 | A1 |
20080135254 | Vinegar et al. | Jun 2008 | A1 |
20080142216 | Vinegar et al. | Jun 2008 | A1 |
20080142217 | Pieterson et al. | Jun 2008 | A1 |
20080166468 | Meduri | Jul 2008 | A1 |
20080173442 | Vinegar et al. | Jul 2008 | A1 |
20080173444 | Stone et al. | Jul 2008 | A1 |
20080173449 | Fowler | Jul 2008 | A1 |
20080173450 | Goldberg et al. | Jul 2008 | A1 |
20080174115 | Lambirth | Jul 2008 | A1 |
20080185147 | Vinegar et al. | Aug 2008 | A1 |
20080201980 | Bullinger et al. | Aug 2008 | A1 |
20080217003 | Kuhlman et al. | Sep 2008 | A1 |
20080217004 | de Rouffignac et al. | Sep 2008 | A1 |
20080217015 | Vinegar et al. | Sep 2008 | A1 |
20080217016 | Stegemeier et al. | Sep 2008 | A1 |
20080236831 | Hsu | Oct 2008 | A1 |
20080250933 | Yun | Oct 2008 | A1 |
20080276498 | Soderberg et al. | Nov 2008 | A1 |
20080277113 | Stegemeier et al. | Nov 2008 | A1 |
20080283246 | Karanikas et al. | Nov 2008 | A1 |
20080289208 | Bryan | Nov 2008 | A1 |
20080313917 | Fraza | Dec 2008 | A1 |
20080314356 | Kamen et al. | Dec 2008 | A1 |
20090014180 | Stegemeier et al. | Jan 2009 | A1 |
20090014181 | Vinegar et al. | Jan 2009 | A1 |
20090042200 | Okano et al. | Feb 2009 | A1 |
20090042739 | Okano et al. | Feb 2009 | A1 |
20090062427 | Tornow et al. | Mar 2009 | A1 |
20090071652 | Vinegar | Mar 2009 | A1 |
20090078461 | Mansure et al. | Mar 2009 | A1 |
20090084547 | Farmayan et al. | Apr 2009 | A1 |
20090090158 | Davidson et al. | Apr 2009 | A1 |
20090090509 | Vinegar et al. | Apr 2009 | A1 |
20090095476 | Nguyen et al. | Apr 2009 | A1 |
20090095477 | Nguyen et al. | Apr 2009 | A1 |
20090095478 | Karanikas et al. | Apr 2009 | A1 |
20090095479 | Karanikas et al. | Apr 2009 | A1 |
20090095480 | Vinegar et al. | Apr 2009 | A1 |
20090120646 | Kim et al. | May 2009 | A1 |
20090126216 | Eloo et al. | May 2009 | A1 |
20090126929 | Vinegar | May 2009 | A1 |
20090149571 | Lux et al. | Jun 2009 | A1 |
20090181126 | Wicking et al. | Jul 2009 | A1 |
20090241753 | Mann | Oct 2009 | A1 |
20090261486 | Olivier | Oct 2009 | A1 |
20090321071 | Zhang et al. | Dec 2009 | A1 |
20090321075 | Harris et al. | Dec 2009 | A1 |
20090321417 | Burns et al. | Dec 2009 | A1 |
20090325215 | Okano et al. | Dec 2009 | A1 |
20100016568 | Okano et al. | Jan 2010 | A1 |
20100016569 | Okano et al. | Jan 2010 | A1 |
20100018862 | Okano et al. | Jan 2010 | A1 |
20100021933 | Okano et al. | Jan 2010 | A1 |
20100037477 | Veltel et al. | Feb 2010 | A1 |
20100050458 | Aaron et al. | Mar 2010 | A1 |
20100101929 | Kamen et al. | Apr 2010 | A1 |
20100119606 | Whittle et al. | May 2010 | A1 |
20100133143 | Roes et al. | Jun 2010 | A1 |
20100150658 | Bilhete et al. | Jun 2010 | A1 |
20100152524 | Sentmanat | Jun 2010 | A1 |
20100272595 | Maziasz et al. | Oct 2010 | A1 |
20100276141 | Stegemeier et al. | Nov 2010 | A1 |
20110011078 | Kamen et al. | Jan 2011 | A1 |
20110011079 | Kamen et al. | Jan 2011 | A1 |
20110017529 | Durney | Jan 2011 | A1 |
20110061601 | Correa et al. | Mar 2011 | A1 |
Number | Date | Country |
---|---|---|
3902730 | Aug 1990 | DE |
4219173 | Dec 1993 | DE |
4338030 | Nov 1994 | DE |
102004053929 | May 2006 | DE |
173676 | Mar 1986 | EP |
455259 | Nov 1991 | EP |
560693 | Sep 1993 | EP |
891812 | Jan 1999 | EP |
925899 | Jun 1999 | EP |
2000338 | Dec 2008 | EP |
2062762 | May 2009 | EP |
2577149 | Aug 1986 | FR |
54128051 | Oct 1979 | JP |
55123930 | Sep 1980 | JP |
55149609 | Nov 1980 | JP |
56040493 | Apr 1981 | JP |
56165842 | Dec 1981 | JP |
57065345 | Apr 1982 | JP |
57086272 | May 1982 | JP |
57135216 | Aug 1982 | JP |
57204218 | Dec 1982 | JP |
58028242 | Feb 1983 | JP |
58076125 | May 1983 | JP |
58202015 | Nov 1983 | JP |
59131164 | Jul 1984 | JP |
59200143 | Nov 1984 | JP |
60095127 | May 1985 | JP |
60142128 | Jul 1985 | JP |
60144537 | Jul 1985 | JP |
60201339 | Oct 1985 | JP |
60251325 | Dec 1985 | JP |
61035896 | Feb 1986 | JP |
61061333 | Mar 1986 | JP |
61261216 | Nov 1986 | JP |
62091732 | Apr 1987 | JP |
63033396 | Feb 1988 | JP |
63092101 | Apr 1988 | JP |
63103821 | May 1988 | JP |
01060601 | Mar 1989 | JP |
01060602 | Mar 1989 | JP |
01142004 | Jun 1989 | JP |
01152206 | Jun 1989 | JP |
01174883 | Jul 1989 | JP |
01208630 | Aug 1989 | JP |
01268593 | Oct 1989 | JP |
01288300 | Nov 1989 | JP |
02023220 | Jan 1990 | JP |
02063507 | Mar 1990 | JP |
02074754 | Mar 1990 | JP |
03070102 | Mar 1991 | JP |
05311253 | Nov 1993 | JP |
05329396 | Dec 1993 | JP |
06115936 | Apr 1994 | JP |
07034064 | Feb 1995 | JP |
07155737 | Jun 1995 | JP |
07232321 | Sep 1995 | JP |
07256637 | Oct 1995 | JP |
08122242 | May 1996 | JP |
09075904 | Mar 1997 | JP |
09163930 | Jun 1997 | JP |
11061700 | Mar 1999 | JP |
11063831 | Mar 1999 | JP |
11178503 | Jul 1999 | JP |
11304358 | Nov 1999 | JP |
11325722 | Nov 1999 | JP |
2000018820 | Jan 2000 | JP |
2000018821 | Jan 2000 | JP |
2000035280 | Feb 2000 | JP |
2000105077 | Apr 2000 | JP |
2000237632 | Sep 2000 | JP |
2001017888 | Jan 2001 | JP |
2001054728 | Feb 2001 | JP |
2003050087 | Feb 2003 | JP |
2010006958 | Jan 2010 | JP |
WO 9741290 | Nov 1997 | WO |
WO 2006133530 | Dec 2006 | WO |
Number | Date | Country | |
---|---|---|---|
20080072447 A1 | Mar 2008 | US |