Patent Grant
7318470
The invention relates to a device for exchanging heat, in particular for use in motor vehicles and in particular for use in motor vehicle air-conditioning systems, Such devices are used, for example, as condensers and evaporators in motor vehicle air-conditioning systems.
The present invention will be discussed with reference to motor vehicle air-conditioning systems, although it should be pointed out that the device for exchanging heat may be used in other air-conditioning systems or for the transfer of heat between two media.
Such devices for exchanging heat are already known, and are used in particular for the air-conditioning of a passenger compartment in a motor vehicle.
Only incombustible coolants are currently used in these air-conditioning systems, since combustible coolants increase the safety risk for people in the motor vehicle passenger compartment owing to the potential danger of explosion. Such coolants are in particular coolants which absorb heat by evaporation at a relatively low temperature and a low pressure, and release heat by liquefaction at a high temperature and a high pressure.
Coolants, for example conventional coolants such as R22 (chlorodifluoromethane), are generally used at present in air-conditioning systems. In even older systems, the coolant R12 (dichlorodifluoromethane) is still found, although its use in cooling systems and air-conditioning systems has been banned for a long time. Since the year 2000, the same has applied to the coolant R22.
The banning of other coolants is also under consideration, for example R134a, so there is an incentive to use alternative coolants.
Such coolants may, for example, be substances or substance compositions which have CO2 as at least one component.
It is an object of the present invention to provide a device for exchanging heat which makes it possible to use alternative coolants and, at the same time, improves the efficiency and economic viability of such apparatus.
The invention achieves this object by providing a device according to an embodiment of the present invention. Such a device can be operated with at least one coolant which makes it possible to transport thermal energy inside the device and the components which are in flow communication with the device.
The device furthermore has at least one coolant inlet and at least one coolant outlet, which open in at least one head tube (or also called a header tube) according to a preferred embodiment.
According to a preferred embodiment, the head tube (or header tube) itself is subdivided by at least one partition element into at least one inlet section and at least one outlet section, which are preferably assigned to a respective coolant inlet and a respective coolant outlet.
The inlet and outlet sections of the head tube, which are separated from one another in a liquid-tight and/or gas-tight manner by at least one partition element, are fluidically connected by means of at least one flow device and preferably at least one transverse distributor. The flow device has at least two flow paths oriented mutually parallel at least in sections, the openings of which open into the inlet and outlet sections of the head tube, or into the channel of at least one transverse distributor.
According to a preferred embodiment of the present invention, at least one head tube, at least one coolant inlet, at least one coolant outlet, at least one flow device and at least one transverse distributor form components which, when assembled together, form a module in the scope of the present invention.
According to a preferred embodiment of the present invention, at least two modules of the aforementioned type are connected together so that the coolant inlets and coolant outlets, respectively, are fluidically connected together.
According to a particularly preferred embodiment, the coolant inlets and coolant outlets are tubes with a defined cross section, in whose circumference bores are made which are arranged essentially perpendicular to the longitudinal mid-axis of the coolant inlet tube or coolant outlet tube, and according to a particularly preferred embodiment, intersect the longitudinal mid-axes of the coolant inlet tubes and coolant outlet tubes with their midline or are arranged at a predetermined distance from it.
According to a particularly preferred embodiment, the midline of the bore is offset from the longitudinal mid-axis of the head tube, so that it constitutes a tangent to the outer circumference of the coolant inlet tube or coolant outlet tube, respectively.
According to another preferred embodiment, the device for exchanging heat comprises modules which are hydraulically connected in parallel by means of coolant inlets and coolant outlets, that is to say coolant is delivered to and discharged from the head tube sections in parallel.
For example, the modules are connected with two coolant tubes so that the inlet sections of the head tubes are fluidically connected via a coolant inlet tube and, correspondingly, the outlet sections of the head tubes are fluidically connected by means of a coolant outlet tube.
According to a particularly preferred configuration, two modules hydraulically connected in parallel communicate with one another via at least one transverse distributor. On the one hand, such a connection insures pressure equilibration of the two modules at respectively determined positions inside the modules, so that more uniform exposure of the modules to coolant is possible where applicable. On the other hand, blending of the coolant flows in the modules is made possible under certain circumstances, which under certain circumstances entails a more uniform temperature distribution over the device for exchanging heat.
According to one embodiment of the present invention, the coolant inlets and outlets, respectively, of a plurality of interconnected modules are formed integrally.
According to a preferred embodiment, the coolant inlets and outlets, the head tube and the transverse distributor are arranged on one side of the module.
The module then in particular has an approximately square basic shape, which preferably has a front face and a back face which, according to a particular embodiment, constitute the sides of the module through which essentially the gaseous medium flows, for example air, in order to release or absorb energy, in particular heat energy. These front and back faces of the module are bounded by four side faces, which are essentially defined by the width of the flow device being used and the cooling fins attached to them and their configuration.
Alternative designs to this preferred rectangular basic shape may be nevertheless selected, which in particular correspond to the requirements for arrangement in an air-conditioning system or a ventilation device.
It is also within the scope of the present invention for the coolant inlets and outlets, the head tube and the transverse distributor to be arranged on different sides of the module, this having a direct effect on the position and the profile of the flow device, as will be discussed in more detail below.
According to another embodiment of the present invention, the arrangement of the components of a module is dictated by the arrangement of the flow device. In particular the alignment of the flow paths, the number of curves and the curvature angle, which according to the present invention is between 0° and 180°, preferably between 30° and 110° and particularly preferably between 45° and 90°, defines the position of the other components on or in the device.
According to a particularly preferred embodiment, the flow device has between 1 and 10 curves, the head tubes and the transverse distributors being arranged on the same or opposite sides of the module, depending on the even or odd number of 180° curvature angles.
For example, in the case of 2, 4, 6, 8 and 10 curves with a curvature angle of 180° for the flow device, the head tubes are arranged on the opposite side to the transverse distributors of a module. In the case of 1, 3, 5, 7 and 9 curves with a curvature angle of 180°, the head tubes and the transverse distributors of a module are arranged on one side of the module.
According to a preferred embodiment, the segments of the flow device between the head tube and the flow device, or between two curves of the flow devices, are essentially of equal length.
According to a particularly preferred embodiment of the present invention, the segments of the flow device which comprise the openings of the flow paths may differ from the length between two curves of the flow device.
According to another particularly preferred embodiment, the openings of the flow paths of the flow device open into the interior of the head tube or of the transverse tube. The components are furthermore connected together by material bonding, by friction locking and/or by a form-fit, so that the interior of the components is gas-tight and/or liquid-tight in particular even at high pressures of up to about 300 bar, or the flow paths are gas-tight and/or liquid-tight in particular even at high pressures of up to about 300 bar.
According to a preferred embodiment of the present invention, the partition element, which subdivides the head tube into an inlet section and an outlet section, is connected to the head tube so as to prevent gaseous or liquid media from being exchanged between the sections.
According to another particularly preferred embodiment, the flow device is a flat tube, the channel of which is subdivided into at least two flow paths by plates.
The flat tube is furthermore characterized in cross section by the width, which is between 10 mm and 200 mm, preferably between 30 mm and 70 mm, and by a height which is between 1.0 mm and 3 mm, preferably between 1.4 mm and 2.4 mm, and an outer wall thickness which is between 0.2 mm and 0.8 mm, preferably between 0.35 mm and 0.5 mm.
The flow paths furthermore have a circular or elliptical shape in cross section, which however is matched to the outer contours of the flat tube, in particular in the edge region of the flat tube, so as not to fall below a minimum wall thickness.
According to a preferred embodiment, the flow device may also have two flat tubes, which are arranged mutually parallel at least in sections and the channels of which constitute at least one flow path.
According to a particularly preferred embodiment, the components, in particular the flow device, for example the flat tubes, are made of at least one material which is selected from the group of materials which contains metals, in particular aluminum, manganese, magnesium, silicon, iron, brass, copper, tin, zinc, titanium, chromium, molybdenum, vanadium and their alloys, in particular wrought aluminum alloys with a silicon content of from 0 to 0.7% and a magnesium content of between 0.0-1%, preferably between 0.0-0.5% and particularly preferably between 0.1 and 0.4%, preferably EN-AW 3003, EN-AW 3102, EN-AW 6060 and EN-AW 1110, plastics, fiber-reinforced plastics, composites etc.
According to another preferred embodiment, a module has cooling fins as a further component, which are connected in particular to a region of the outer surface of the flow device so that the transport of thermal energy is promoted.
According to a particularly preferred embodiment, the cooling fins are connected by material bonding to the surface of the flow device, in which case soldering methods, welding methods and adhesive methods in particular are used to produce the material bond.
The cooling fins are preferably connected to the surfaces of the flow device so that the material bonding takes place in particular at the turning points of the cooling fins.
According to a particularly preferred embodiment, the cooling fins have a coil-like basic structure in the flow direction, the depth of which corresponds essentially to the overall depth of the module, or the width of the flow device. Slots, which extend essentially between the two connection points or turning points of the cooling fins, may furthermore be made in the cooling fins.
According to a particularly preferred embodiment, these slots in the cooling fins are between 1 and 15 mm, preferably between 2 and 13 mm and particularly preferably from 3.7 to 11.7 mm long. The slots furthermore have a width of between 0.1 and 0.6 mm, preferably between 0.1 and 0.5 mm and particularly preferably between 0.2 and 0.3 mm. These so-called “gills” of the coolant fins allow improved heat transfer between the gas flowing through and the cooling fins, or the walls of the flow devices. The cooling fins are furthermore characterized by a wall thickness which is between 0.01 and 0.5 mm, preferably between 0.02 and 0.07 mm and particularly preferably between 0.07 and 0.15 mm. The fin density of the cooling fins is from 10 to 150 fins per dm, preferably from 25 to 100 fins per dm and particularly preferably from 50 to 80 fins per dm. In a particularly preferred embodiment, the fin height is from 1 to 20 mm, preferably from 2 to 15 mm and particularly preferably from 3 to 12 mm.
According to a preferred embodiment, the head tube has an essentially cylindrical basic shape, in the circumference of which a predetermined number of feeds are arranged, through which the coolant inlets and outlets and at least one flow device, in particular a flat tube, extend into the interior of the head tube.
According to a particularly preferred embodiment, the feeds for the flat tubes in the interior of the head tube are configured so that not only are the flat tubes connected to the head tube by means of a material bond, but also a flat tube or flat tubes, once inserted, are connected by friction locking to the walls of the head tube through additional compression of the head tube.
According to a particularly preferred embodiment, the head tube for this connection method has a basically Ω-shaped cross section, in the narrowest region of which the feeds are provided for the flow devices, in particular for a flat tube. According to another embodiment, a plurality of flat tubes may also be accommodated in one or more feeds.
According to a particularly preferred embodiment, the feeds have an outer contour which corresponds to that of the object to be inserted, in particular to that of the coolant inlet or coolant outlet tube, and to that of the flat tube, or are at a predetermined distance from it.
The holes are furthermore arranged offset, with reference to their midline, by a predetermined distance from the midline of the head tube, or of the transverse distributor.
The holes are arranged at a predetermined distance from the mid-axis of the head tube.
According to an advantageous configuration, the head tube has a projection on an edge of at least one feed, which engages in a feed of the coolant inlet or outlet. This fixes the head tube with respect to the coolant inlet or outlet during assembly of the device, which facilitates manufacture of the device for exchanging heat.
In a preferred embodiment, a coolant which has at least one component from a group which comprises gases, in particular carbon dioxide, nitrogen, oxygen, air, ammonia, hydrocarbons, in particular methane, propane, n-butane and liquids, in particular water, floe-ice, sols, etc. is used in the device for exchanging heat.
According to a particularly preferred embodiment, carbon dioxide, the physical properties of which as a colorless incombustible gas can be used to increase the cooling power, possibly reduce the size of the apparatus or reduce power losses, is used as the coolant.
According to a preferred embodiment, a preferably gaseous medium, in particular air, flows around the device for exchanging heat in full, and moreover at least the flow device as a component of the device, and in particular the cooling fins.
According to a particularly preferred embodiment, the heat transfer between the coolant inside the flow device and the gaseous medium, flowing around the cooling fins and the flow device, takes place essentially by convection and heat conduction. For example, the air flowing around releases heat energy to the cooling fins, from which the heat can be transferred via the cooling fins and the wall of the flow device to the coolant.
For heat conduction, the component of the module and the modules are connected together so as to promote the transport of thermal energy. This is done, in particular, by a connection using material bonding, friction locking and a form-fit, for example soldering, welding, flanging or adhesive bonding.
The junction regions of the components and modules through which fluid flows are furthermore connected together in a gas-tight and liquid-tight manner so as to prevent mixing of the coolant with the medium flowing around. In particular when coolants with a low molecular weight are used, for example carbon dioxide, it is particularly important to obtain a connection between the components and the modules which prevents the coolant, or components of the coolant, from escaping.
In a preferred embodiment, the device for exchanging heat has frame elements on two mutually opposite sides, which extend over at least a part of the side area of the device. These frame elements are preferably profiled elements which, inter alia, may have a U-shaped, V-shaped, L-shaped or other typical profiled structures. These frame elements are furthermore connected by friction locking and/or by a form-fit to at least one component in the device for exchanging heat. Material bonding, for example by soldering, welding and adhesive bonding, also lies within the scope of the invention.
According to another particularly preferred embodiment of the device for exchanging heat, the flat tube has at least one recess in the vicinity of the feeds that enter the head tube, in which for example the partition element which subdivides the head tube into an inlet section and an outlet section engages.
In another embodiment, the device for exchanging heat has a partition element with a recess in which the flow device, in particular a flat tube, engages in the head tube in the vicinity of the feed.
This arrangement insures that the regions of the inlet section and of the outlet section in the head tube are sealed from one another in a liquid-tight or gas-tight manner, and defined positioning and fastening of the flow device is insured.
According to another embodiment, the head tubes and/or the coolant inlet or outlet are configured so that the pressure of the coolant is essentially equal or has a predetermined value over the inlet or outlet sections.
Preferably for the coolant inlet, under certain circumstances this can be achieved in that the flow cross section of the coolant inlet tapers over the number of head tubes fluidically connected to it, so that the pressure drop at each “take-off point” is substantially compensated for. In this case, it is particularly preferable for the coolant outlet to have a flow cross section that is as large as possible.
Alternative embodiments lie within the scope of the present invention, and in particular the configuration of the opening or the coolant feed of the head tube, or its size, may likewise be used to equilibrate the pressure or density level of the head tubes arranged on the coolant inlet.
According to a particularly preferred embodiment, the various take-off points from the coolant inlet or outlet may also be subdivided into flow regions by using a profile which is inserted and connected to the sleeve tube by material bonding. For example, the tube is subdivided into 2, 3 or 4 or more flow regions. The flow regions of the coolant inlet or coolant outlet are connected to the corresponding take-off regions, for example the bore which opens into the head tube, by a predetermined rotation of the profile in the tube.
According to another preferred embodiment, the volumes of the inlet and outlet sections of a head tube have a predetermined ratio to one another, in which case this ratio may in particular be 1:1, 1:2, 1:4, 1:10 and any intermediate values between these. In particular, this accommodates the varying density of the coolant when it evaporates or cools.
When the device for exchanging heat is used as an evaporator, for example, this arrangement can accommodate the fact that the volume increases significantly when the coolant evaporates, so that a larger flow cross section is needed for transporting the mass flow of coolant.
For example, the density ratio for CO2 between a coolant inlet and a coolant outlet is between 1:2 and 1:10, preferably between 1:3 and 1:7, and particularly preferably about 1:5.
A simplified design is facilitated according to another advantageous embodiment of the invention by tubes restructured in a U-shape, the tubes being restructured once or several times, for an even simpler design. This may possibly obviate a transverse distributor in the vicinity of the U-shaped restructuring. If only U-tubes are used, it is even possible to place all the head tubes and transverse distributors on one side of the device.
According to a preferred configuration, a transverse distributor connects together flow paths which are arranged one behind the other in a primary flow direction of a medium flowing around the flow device. This makes it possible to interconnect flow paths for the coolant either parallel or antiparallel with a primary flow direction of a medium flowing around the flow device. This leads to an at least partial counterflow design of the device for exchanging heat.
According to a preferred configuration, the number of flow paths of at least one module is divisible by two. This means that a two-row arrangement of the flow paths can be readily interconnected by arranging the first half of the flow paths of a module in a first row and connecting them together, while the second half of the sections is arranged in a second row and likewise connected together, the two halves of the module being connected together with overlap of the rows. This connection with overlap of the rows is carried out, for example, in a transverse distributor on an opposite side of the device for exchanging heat to the coolant inlet and outlet.
The number of flow paths of the module is particularly preferably divisible by four. This means that in the case of a two-row arrangement of the flow paths with the interconnection described above, the connection with overlap of the rows is carried out on the same side of the device for exchanging heat as the one where the coolant inlet and the coolant outlet are located.
In one configuration, the outermost flow paths within one or more flow-path rows are not exposed as hydraulically first flow paths of modules since, in the outermost regions of the coolant inlet or outlet, the flow and/or pressure conditions of the coolant may possibly be unfavorable for the exposure of modules.
According to an advantageous embodiment, the flow paths of two neighboring modules extend with mirror symmetry with respect to one another. In particular, this facilitates communication between the neighboring modules via a transverse distributor.
In another preferred embodiment, a flow cross section of a module changes along a coolant flow profile inside the module. This is very easy to do, for example by connecting a small number of flow paths to a large number of flow paths via appropriately configured transverse distributors. Adaptation of the flow cross section of a module to a density of the coolant varying along the module is particularly preferred.
A configuration in which all the flow paths of at least one module are flush with one another in the primary flow direction of a medium flowing around the flow device is advantageous. It is particularly advantageous for all the modules of the device for exchanging heat to be designed in this way, which facilitates a pure counterflow design of the device in a straightforward way, namely by appropriately arranged transverse distributors.
According to another preferred embodiment, at least one transverse distributor has a second partition element which subdivides the transverse distributor into at least two flow sections.
A device for exchanging heat according to a preferred embodiment furthermore has at least one flow device which extends into the interior of a transverse distributor.
According to a particularly preferred embodiment, an apparatus for exchanging air, in particular for motor vehicle air-conditioning systems, with air flow paths and airflow control elements, has at least one air delivery device and, in a housing, a holding device in which at least one device for exchanging heat, is accommodated or arranged.
At least one device for exchanging heat is furthermore arranged in an apparatus for exchanging heat which, in particular, is intended for motor vehicle air-conditioning systems with at least a condenser, a compressor, a throttle and a manifold.
It should furthermore be pointed out that besides an exactly cylindrical or tubular configuration, the essentially cylindrical head tubes, coolant inlets and coolant outlets, and the transverse distributor, may also have modified shapes which, for example, are deformed cylindrical or elliptical, polygonal or rectangular cross sections.
Advantages, features and possible applications of the present invention can be found in the description of the exemplary embodiments in conjunction with the claims and the drawings.
The exemplary embodiments are not intended to imply limitation of the invention. Rather, many changes and modifications are possible in the scope of the present disclosure, in particular those variants of the elements and combinations and/or materials which, for example, may be found by the person skilled in the art with a view to achieving the object by combining or altering individual features or elements or method steps described in connection with the the general description, embodiments, and the claims, and contained in the drawings, and which lead by combinable features to novel subject-matter or to novel method steps, or method steps insofar as they relate to production, testing and working methods.
Preferred aspects of the invention will be described below with reference to the figures, in which
a shows a schematic representation of a head tube for a device for exchanging heat according to the present invention;
b shows a schematic representation of the feeds of a head tube for a flow device;
c shows a sectional representation through the head tube in
Accordingly,
According to a particularly preferred embodiment, the head tubes 7, 8 and 9 have at least one partition element (not shown) which is arranged, for example, in the middle of the head tube. By means of this, the head tubes are subdivided into at least two sections from which the coolant is introduced into the flow device 19 and is conveyed, via the flow paths of the flow device, into the transverse distributors 10′, 10″, 11′, 11″ and 12. The coolant, which has already absorbed heat to some extent from the medium flowing around, flows from there for example into the rear region of the transverse distributor, and is in turn conveyed from this into the rear flow paths of the flow device 19. At the end, these flow paths open into the outlet section of the head tube 7, 8 and 9 and are fed back via the coolant outlet tube 4 into the pipe system of the air-conditioning system. Here as well, for example, the coolant return tube has a seal 6 and, for example, a coupling system 5 for connection to the pipe system. Besides the components of the device for exchanging heat that carry the coolant, this embodiment also has frame elements 16 and 17. The reference 18 denotes the position of the cooling fins for the device.
In accordance with the plan view in
According to this exemplary embodiment, in particular, the flow device is a flat tube which is bent in a coiled fashion and provides the connection between the head tube and the transverse distributor. Cooling fins 18, in particular, are arranged between the respective coil sections of the flow device and improve the heat transfer between the medium flowing through, for example air, and the coolant flowing in the flow device.
According to a particularly preferred embodiment, the cooling fins are configured so that they likewise extend in a coiled fashion between the coil sections of the flow device, and are additionally provided with so-called gills over the depth of the device for exchanging heat, that is to say with slots which are used, in particular, to produce turbulence and hence for improved heat transfer between the medium flowing through and the cooling fins that dissipate heat.
The representation in
According to an advantageous configuration seen in
According to a particularly preferred embodiment, the transverse distributors and the head tubes are closed in a fluid-tight fashion at their outer limits by means of additional partition elements. These partition elements are preferably connected to the head tube, transverse distribution tube or the coolant inlet or coolant outlet tube by material bonding, friction locking and/or a form-fit.
According to a particularly preferred embodiment, these tubes have an Ω-shaped cross section, in whose constriction region recesses are provided, for example, through which the flow devices are accommodated. Here, it should be emphasized particularly that the flow device has a predetermined penetration depth into the head tube or the transverse distribution tube, and that the flow device may be clamped to the head tubes or transverse distributors in order to assemble the components when producing the device for transferring heat. According to a particularly preferred embodiment, the penetration depth is from 0.01 to 10 mm, preferably from 0.1 to 5 mm and particularly preferably from 0.15 to 1 mm. The head tubes 45 and 47, or the transverse distributors 44 and 46, furthermore exhibit embodiments in which two flow devices open into the interior of the head tubes or transverse distributors. Here, the outlet branches of the head tubes or of the transverse distributors are adapted to the entry angle of the flow devices so that they extend parallel to it at least in one section.
According to a particularly preferred embodiment,
The burst pressure range of a device is, in particular, >300 bar according to the present invention, the wall thickness needing to have a minimum thickness depending on the material. According to a particularly preferred embodiment, the wall between the outer limit of the flat tube and the inner limits of the flow paths has a wall thickness which is between 0.1 and 0.3 mm, particularly preferably between 0.15 and 0.25 mm and particularly preferably between 1.17 and 2.2 mm.
In a corresponding way for the section 102, heat energy is also drawn from the medium flowing around in the section 105, for example the air, and is transferred to the coolant. This coolant is collected as a liquid-gas mixture in the outlet section of the head tubes 106, and is returned via the coolant discharge 107 into the pipe system which follows, for example of an air-conditioning system.
a shows a schematic representation of a header tube in the side view where, besides the partition elements 110, 111 and 112, it is also possible to see the feeds for the coolant inlet or outlet 113′ and 113″, respectively. According to a particularly preferred embodiment, the holes 113′ and 113″ are offset from the mid-axis of the header tube 114 by a distance 115, this distance being between 0 and 20 mm according to the present invention, preferably between 0 and 10 mm and particularly preferably between 0 and 5 mm. The partition element 110 subdivides the header tube into two sections 116 and 116′, which constitute either the coolant inlet section or the coolant outlet section depending on the arrangement of the header tube. The partition elements 111 and 112 close the header tube off from the surroundings, and these partition elements may be arranged at a distance from the outer edge of the header tube or may be arranged flush next to it. According to another preferred embodiment, the section of the header tube may also be sealed by a solder or weld point. The feeds for the flow device are not represented in
b shows an alternative embodiment of a feed of the flow device into a head tube. Here, besides the two branches 120 and 121 of the head tube, it is also possible to see the feed 122 which, according to a preferred embodiment, is configured so that it corresponds to the outer shape of the flat tube to be inserted. According to another embodiment the hole may also be configured so that, for example, two or more flat tubes can be accommodated in the head tube.
c shows the cross section through a head tube according to
According to another particularly preferred embodiment, two or more flow devices may also open in a head tube with the configuration in
Besides the different flow cross sections for the coolant inlet 703 and the coolant outlet 702, this embodiment has four feeds 705, 706, 707 and 708 for a flow device, which open in the channel, i.e. the interior, of the head tube.
| Number | Date | Country | Kind |
|---|---|---|---|
| 101 63 202 | Dec 2001 | DE | national |
| 102 34 118 | Jul 2002 | DE | national |
| 102 40 556 | Aug 2002 | DE | national |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/EP02/14576 | 12/19/2002 | WO | 00 | 6/21/2004 |
| Publishing Document | Publishing Date | Country | Kind |
|---|---|---|---|
| WO03/054465 | 7/3/2003 | WO | A |
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