Patent Grant
8845862
The present invention relates to a device for producing a fibrous sheet.
The present application claims priority on Japanese Patent Application No. 2010-282381, filed Dec. 17, 2010, the content of which is incorporated herein by reference.
Devices that convert a fibrous sheet composed of an aggregation of fibers into a nonwoven fabric form or paper-like form using a wet papermaking method are already known. The device for producing this fibrous sheet is equipped with a water squeezing section which squeezes the dispersion medium from a dispersion containing the fibers to generate a web, a drying section which dries the web to generate a fibrous sheet, and a winding section for winding the fibrous sheet (for example, see Japanese Unexamined Patent Application, First Publication No. 2008-274525).
A wire mesh (hereafter referred to as a “fabric sheet”) is provided in the water squeezing section. In the water squeezing section, by running the fabric sheet while discharging the dispersion onto the upper surface of the sheet, thereby separating the dispersion medium through the pores in the fabric sheet, the dispersion medium is squeezed from the dispersion to generate a web.
However, in recent years, in the development of fibrous sheets, a reduction in the pore diameter and an increase in the porosity of the fibrous sheet are being demanded.
For example, electrical storage devices such as batteries and capacitors exhibit electrical storage performance by moving an electrolyte between a positive electrode and a negative electrode. In order to prevent short-circuits between the positive and negative electrodes in these electrical storage devices, a separator formed from a fibrous sheet is disposed between the positive and negative electrodes.
Here, in order to improve the electrical storage performance of the electrical storage devices, it is necessary to facilitate the movement of the electrolyte while preventing short-circuits between the positive and negative electrodes. In order to prevent short-circuits between the positive and negative electrodes, a reduction in the pore diameter is required for the fibrous sheet that constitutes the separator. Further, in order to facilitate the movement of the electrolyte, an increase in the porosity is required for the fibrous sheet that constitutes the separator.
Reducing the pore diameter and increasing the porosity of the fibrous sheet is achieved by producing a fibrous sheet using fine fibers. For example, nanofiber cellulose or the like is used as the fine fibers.
The water retention properties of fine fibers is generally extremely high. As a result, in the water squeezing section, it is necessary to lengthen the travelling distance of the fabric sheet used for separating the dispersion medium, so that the dispersion medium is squeezed from the dispersion containing the fine fibers over a long period of time.
However, if the fabric sheet is lengthened, the following types of problems occur.
In the water squeezing section, a suction pump is usually disposed beneath the fabric sheet. Then, the vacuum pressure difference and the like provided by the suction pump is used to squeeze the dispersion medium through the pores in the fabric sheet. As a result, the fabric sheet is suctioned toward the suction pump, and therefore if the travelling distance of the fabric sheet is lengthened, a large frictional force will act on the fabric sheet. Then, if the fabric sheet is run with the sheet pulled with a strong tension in order to counteract this frictional force, then there is a possibility that the fabric sheet may undergo slipping, or suffer damage such as stretching or rupture. In contrast, if the vacuum pressure is lowered to enable the tension to be weakened, then the amount of dewatering decreases, and there is a possibility that the basis weight may decrease.
Accordingly, the present invention has an object of providing a device for producing a fibrous sheet that enables production of a fibrous sheet while preventing damage to the fabric sheet.
In order to achieve the above object, a device for producing a fibrous sheet according to the present invention is a device for producing a fibrous sheet from a dispersion containing fine fibers, the device including a water squeezing section which squeezes the dispersion medium from the dispersion to generate a web, and a drying section which dries the web to generate a fibrous sheet, wherein the water squeezing section has a plurality of first fabric sheets arranged longitudinally along the transport direction of a web substrate that is partway through web generation, and water squeezing units which are provided beneath the plurality of first fabric sheets and squeeze the dispersion medium from the dispersion, and in the water squeezing section, a continuous sheet is positioned so as to extend over the upper surface of the plurality of first fabric sheets, and the dispersion is discharged onto the upper surface of the continuous sheet.
According to the present invention, because the plurality of first fabric sheets are arranged longitudinally, when the dispersion medium is squeezed from the dispersion, the frictional force that acts on the first fabric sheets can be dispersed across the plurality of first fabric sheets. As a result, the first fabric sheets can be run without pulling the first fabric sheets with a strong tension. Accordingly, a fibrous sheet can be produced while preventing slipping and damage of the first fabric sheets.
Further, because the continuous sheet is positioned so as to extend over the upper surface of the plurality of first fabric sheets, in the water squeezing section, the frictional force during squeezing causes the lower surface of the continuous sheet and the upper surface of the first fabric sheets to adopt a state of close contact. When the first fabric sheets are run in this state, the continuous sheet is transported by the first fabric sheets. As a result, the continuous sheet can be transported without having to pull the continuous sheet with a strong tension. Accordingly, a fibrous sheet can be produced while preventing slipping and damage of the continuous sheet.
Moreover, according to this device configuration, the web substrate that is partway through web generation is transported between the plurality of first fabric sheets in a state mounted on the upper surface of the continuous sheet, and therefore damage of the web substrate during transfer between the plurality of first fabric sheets can be avoided. Accordingly, a fibrous sheet formed from fine fibers can be produced reliably.
In one aspect of the present invention, the continuous sheet is a second fabric sheet.
According to this aspect of the present invention, the dispersion medium can be squeezed from the dispersion through the pores in the second fabric sheet.
Further, because the second fabric sheet can be run without pulling the second fabric sheet with a strong tension, slipping and damage of the second fabric sheet can be prevented.
In another aspect of the present invention, the continuous sheet is composed of a filter material for papermaking disposed on the upper surface of the second fabric sheet.
According to this aspect of the present invention, by installing a filter material for papermaking having smaller pores than the second fabric sheet, finer fibers can be trapped. Accordingly, a further reduction in the pore diameter and a further increase in the porosity of the fibrous sheet can be achieved.
Further, because the filter material for papermaking can be run together with the second fabric sheet without having to pull the filter material for papermaking with a strong tension, damage to the second fabric sheet and the filter material for papermaking can be prevented.
In another aspect of the present invention, the continuous sheet may use a filter material for papermaking instead of the second fabric sheet. In this case, because the strength of the filter material for papermaking is weak, it is preferable that the filter material is supported by rollers or the like between the first fabric sheets.
In another aspect of the present invention, the water squeezing section has side walls which stand upward facing each other so as to extend along the aforementioned transport direction at both outside edges of the continuous sheet in a direction orthogonal to the transport direction, and is provided with a side sealing mechanism that blocks the gaps between the edges of the continuous sheet and the side walls.
According to this aspect of the present invention, the side sealing mechanism can prevent leakage of the dispersion onto the first fabric sheets and the water squeezing units from gaps between the edges of the continuous sheet and the side walls. Accordingly, the continuous sheet can trap fine fibers, and the dispersion medium can be squeezed out with good efficiency.
In another aspect of the present invention, the first fabric sheets are endless belts.
According to this aspect of the present invention, by forming the first fabric sheets as endless belts, the device for producing fibrous sheets can be made more compact.
In another aspect of the present invention, a drying section which dries the web to generate a fibrous sheet is provided downstream from the water squeezing section, and the second fabric sheet extends from the water squeezing section across to the drying section.
According to this aspect of the present invention, because there is no necessity to transfer the web from the water squeezing section to the drying section, even if the strength of the web weakens due to the use of fine fibers, damage of the web during transfer can be avoided. Accordingly, a fibrous sheet formed from fine fibers can be produced reliably.
In another aspect of the present invention, panel strips that contact the lower surface of the first fabric sheets are provided on the upper side of the water squeezing units, and through-holes are formed in the panel strips.
According to this aspect of the present invention, because the panel strips having through-holes formed therein contact the lower surface of the first fabric sheets, when the first fabric sheets are run, the lower surface of the first fabric sheets is swept clean by the edges of the through-holes. As a result, the dispersion medium that has passed through the pores of the first fabric sheets can be rapidly removed, and therefore the squeezing operation can be made more efficient.
In another aspect of the present invention, the plurality of first fabric sheets in the water squeezing section are arranged so that the heights of the first fabric sheets increase from the upstream side to the downstream side in the transport direction.
According to this aspect of the present invention, by arranging the first fabric sheets so that the heights of the fabric sheets increase from the upstream side to the downstream side, the web substrate can be gently lifted and pulled out of the deeply accumulated dispersion at the upstream side. Accordingly, a well-formed fibrous sheet having a smooth surface can be produced.
In another aspect of the present invention, the water squeezing section has a solvent application unit which applies a solvent that forms cavities in the fibrous sheet to the web substrate.
According to this aspect of the present invention, a porous fibrous sheet can be produced.
In other words, the present invention relates to the following.
According to the present invention, because the plurality of first fabric sheets are arranged longitudinally, when the dispersion medium is squeezed from the dispersion, the frictional force that acts on the first fabric sheets can be dispersed across the plurality of first fabric sheets. As a result, the first fabric sheets can be run without pulling the first fabric sheets with a strong tension. Accordingly, a fibrous sheet can be produced while preventing slipping and damage of the first fabric sheets.
Further, because the continuous sheet is positioned so as to extend over the upper surface of the plurality of first fabric sheets, in the water squeezing section, the frictional force during squeezing causes the lower surface of the continuous sheet and the upper surfaces of the first fabric sheets to adopt a state of close contact. When the first fabric sheets are run in this state, the continuous sheet is transported by the first fabric sheets. As a result, the continuous sheet can be transported without having to pull the continuous sheet with a strong tension. Accordingly, a fibrous sheet can be produced while preventing slipping and damage of the continuous sheet.
Moreover, according to this device configuration, the web substrate that is partway through web generation is transported between the plurality of first fabric sheets in a state mounted on the upper surface of the continuous sheet, and therefore damage of the web substrate during transfer between the plurality of first fabric sheets can be avoided. Accordingly, a fibrous sheet formed from fine fibers can be produced reliably.
A device for producing a fibrous sheet according to a first embodiment of the present invention is described below with reference to the drawings.
The present embodiment relates to a device for producing a fibrous sheet from a dispersion containing fine fibers. The fibrous sheet is composed of an aggregate of the fine fibers (in the form of a nonwoven fabric or paper). Nanofiber cellulose (NFCe) obtained by mechanically grinding and refining a pulp can be used as the fine fibers.
Specifically, examples of the raw material include plant-derived cellulose, animal-derived cellulose and bacteria-derived cellulose, more specific examples include chemical pulp fibers obtained by digesting softwood or hardwood by the Kraft method, sulfite method, soda method or polysulfite method or the like, mechanical pulp fibers obtained by performing pulping using the mechanical force of a refiner or grinder or the like, semi-chemical pulp fibers obtained by performing a pretreatment using a chemical agent and then performing pulping using mechanical force, and recycled paper pulp fibers, and each of these fibers can be used in either an unbleached state (prior to bleaching) or a bleached state (following bleaching). Further, examples of non-timber-based pulps produced from herbaceous species include pulped fibers obtained from cotton, Manila hemp, linen, straw, bamboo, bagasse and kenaf and the like using the same methods as those used for timber pulps.
Examples of tree species used for the aforementioned pulp include softwood trees such as Douglas fir, Japanese red pine, Japanese black pine, Sakhalin fir, Jezo spruce, Oregon pine, Japanese larch, fir, hemlock fir, Japanese cedar, Japanese cypress, Veitch's fir, Hondo spruce, cypress, Douglas fir, hemlock, white fir, spruce, balsam fir, cedar, pine, Sumatran pine and radiata pine, and hardwood trees such as beech, birch, alder, oak, laurel, Japanese stone oak, Japanese white birch, cottonwood, poplar, ash, Japanese poplar, eucalyptus, mangrove and lauan. Further, various hemps, mitsumata plants, bamboo and straw can also be pulped and used.
Then, by subjecting the pulp to a mechanical treatment such as a refiner treatment to shorten the fibers, subsequently subjecting the shortened fiber pulp to a treatment with a cellulase-based enzyme, and then performing a refining treatment with a high-speed rotational defibrator or a high-pressure homogenizer, a nanofiber cellulose can be obtained.
The dispersion is prepared by dispersing the fine fibers in a dispersion medium composed of water, an organic solvent, or a mixed liquid containing water and an organic solvent.
Nanofiber cellulose is a cellulose fiber or a rod-shaped particle of cellulose having a far narrower width than a pulp fiber used in typical paper manufacturing applications. The nanofiber cellulose is an aggregate of cellulose molecules in a crystalline state, and the crystal structure thereof is the I-type (parallel chain). The width of the nanofiber cellulose when viewed under a scanning electron microscope (SEM) is preferably from 2 nm to 1,000 nm, more preferably from 2 nm to 500 nm, and still more preferably from 4 nm to 100 nm. If the width of the fiber is less than 2 nm, then the cellulose dissolves in water as cellulose molecules, and therefore the cellulose is unable to exhibit the physical properties (strength, rigidity, and dimensional stability) of a fine fiber. If the width of the fiber exceeds 1,000 nm, then because the cellulose cannot be called a fine fiber, and is simply the type of fiber included in ordinary pulp, the physical properties (strength, rigidity, and dimensional stability) of a fine fiber cannot be obtained. Furthermore, in the case of an application that requires transparency in a composite of the nanofiber cellulose, the width of the fine fibers is preferably not more than 50 nm. In other words, the width of the aforementioned fine fibers is preferably from 2 nm to 50 nm, and more preferably from 4 nm to 50 nm.
Further, the fiber length of the nanofiber cellulose in the present embodiment (the weighted average fiber length measured in accordance with Japan TAPPI paper pulp test method No. 52:2000) is preferably from 1 to 1,000 μm, more preferably from 10 to 600 μm, and particularly preferably from 50 to 300 μm. The aspect ratio, which is the value obtained by dividing the fiber length by the fiber width, is preferably from 100 to 30,000, more preferably from 500 to 15,000, and particularly preferably from 1,000 to 10,000.
If a fibrous sheet is produced from these types of fine fibers, then the thickness of the fibrous sheet can be reduced and the porosity can be increased, and the pore diameter can also be reduced. If this fibrous sheet is employed as the separator of an electrical storage device, then the electrical storage performance of the electrical storage device can be improved.
The device 1 for producing a fibrous sheet includes a water squeezing section 20 which squeezes a dispersion medium from a dispersion 3a containing fine fibers to generate a web 3c, a drying section 40 which dries the web 3c to generate a fibrous sheet 3d, and a winding section 60 which winds the generated fibrous sheet 3d.
(Water Squeezing Section)
The water squeezing section 20 includes a plurality (four in the present embodiment) of first fabric sheets 15 (15a to 15d) arranged longitudinally in a linear manner, and a continuous sheet 10 which is positioned so as to extend over the top of the first fabric sheets 15 (15a to 15d).
The wire diameter D of the wire material 11 that constitutes the first fabric sheets 15 is preferably from Ø50 to 1,000 μm, more preferably from 70 to 500 μm, and particularly preferably from 90 to 400 μm. If the wire diameter D is less than 50 μm, then the strength decreases, and the tension cannot be raised. If the wire diameter D exceeds 1,000 μm, then the unevenness becomes too great, and there is a possibility that this unevenness may be transferred to the fibrous sheet, causing roughening of the sheet surface. A specific example of the wire diameter D is Ø200 μm. Further, the mesh aperture dimension W of the mesh pores 12 of the first fabric sheets 15 is preferably from 100 to 5,000 μm, more preferably from 120 to 1,000 μm, and particularly preferably from 140 to 750 μm. If the aperture dimension W is less than 100 μm, then there is a possibility that the dewatering properties may worsen. If the aperture dimension W exceeds 5,000 μm, then the strength decreases, and the tension cannot be raised.
The first fabric sheets 15 extend as endless belts around a plurality of rollers. The first fabric sheets 15 run in a circulatory manner around an orbital trajectory by rotationally driving the rollers with a motor (not shown in the drawings). Then, each of the first fabric sheets 15 is positioned so that the travel direction of the upper circulating portion of the first fabric sheet 15 coincides with the transport direction of the web substrate 3b. The travel direction of the upper circulating portions of the first fabric sheets 15 becomes the transport direction for the web substrate 3b that is partway through generation of the web 3c. In the water squeezing section 20, four first fabric sheets 15a to 15d are arranged linearly in sequence from the downstream side of the transport direction (the left side in
Each of the first fabric sheets 15 formed in this manner can be run at a travel speed of 0.05 m/min to 50 m/min. A preferred range for the travel speed of each first fabric sheet 15 is from 0.1 to 50 m/min, and a more preferred range is from 0.5 to 20 m/min.
Here, all or some of the first fabric sheets 15 are preferably arranged with an incline that increases in height from the upstream side toward the downstream side. By inclining the first fabric sheets 15, the web substrate 3b can be gently lifted and pulled out from the dispersion 3a accumulated in a storage unit 17 described below. Hence, a well-formed fibrous sheet having a smooth surface can be produced. The angle of inclination of the first fabric sheets 15 is preferably from 0.1 degrees to 30 degrees, and particularly preferably from 0.5 degrees to 15 degrees, relative to the horizontal plane.
In the present embodiment, the first fabric sheets 15a to 15c are installed with an inclination of approximately 1.5 degrees relative to the horizontal plane. In the region where the most downstream first fabric sheet 15d is installed, a solvent is applied to the web substrate 3b as described below. Accordingly, in order to enable application of the solvent with no irregularities, the most downstream first fabric sheet 15d is installed substantially horizontally.
(Continuous Sheet)
In the water squeezing section 20, the continuous sheet 10 extends across the upper surface of each of the first fabric sheets 15a to 15d. The continuous sheet 10 extends from the water squeezing section 20 across to the drying section 40 described below.
The continuous sheet 10 is formed by superimposing a second fabric sheet 10a and a filter material for papermaking 10b which is disposed on the upper surface of the second fabric sheet 10a.
At the upstream side of the water squeezing section 20, the second fabric sheet 10a and the filter material for papermaking 10b are supplied from a second fabric sheet supply reel 75 and a papermaking filter material supply reel 70 respectively. Subsequently, the continuous sheet 10 is formed by superimposing the second fabric sheet 10a and the filter material for papermaking 10b at a base end roller 28 at the upstream side of the water squeezing section 20. In the present embodiment, when supplying the filter material for papermaking 10b, the material is passed through an impregnation tank 71 containing stored water, thereby impregnating the filter material for papermaking 10b with water. Impregnating the filter material for papermaking 10b with water in advance can inhibit the generation of wrinkles in the filter material for papermaking 10b when the dispersion medium of the dispersion 3a penetrates through the filter material for papermaking 10b. Accordingly, a smooth web 3c can be formed on the upper surface of the filter material for papermaking 10b.
(Second Fabric Sheet)
The second fabric sheet 10a is formed by interweaving a wire material 11 formed from a metal such as stainless steel or a resin such as polyester into a mesh-like form in the same manner as the first fabric sheets 15 (see
Whereas the first fabric sheets 15 are run by driving the rollers with a motor (not shown in the drawings), the second fabric sheet 10a is mainly transported by the first fabric sheets 15 in the manner described below. In other words, during operation, the second fabric sheet 10a is not subjected to a pulling force provided by rollers as is the case with the first fabric sheets 15, and therefore the second fabric sheet 10a does not require the high level of strength of the first fabric sheets 15. Accordingly, the wire material 11 of the second fabric sheet 10a can employ a stainless steel wire or plastic wire having a narrow wire diameter and a small mesh aperture.
The wire diameter D of the wire material 11 that constitutes the second fabric sheet 10a is typically from Ø10 to 40 μm. Specific examples of the wire diameter D are Ø20 μm and Ø34 μm. Further, the mesh aperture dimension W of the mesh pores 12 of the second fabric sheet 10a is typically from 5 to 50 μm. A preferred range for the mesh aperture dimension W of the second fabric sheet 10a is from 10 to 40 μm.
(Filter Material for Papermaking)
The filter material for papermaking 10b is disposed on the upper surface of the second fabric sheet 10a.
The filter material for papermaking 10b can use a paper substrate, a nonwoven fabric, a woven fabric, or a membrane filter or the like. Among these, a paper substrate or a nonwoven fabric or woven fabric of fibers of polyester or nylon or the like can be used favorably, but a paper substrate, which exhibits minimal elongation, can easily be produced as a long object and has minimal pores is particularly favorable. There are no particular limitations on the paper substrate, but a smooth paper substrate having air permeability is preferable. Specific examples of the paper substrate include high-quality paper, medium-quality paper, inkjet paper, copy paper, art paper, coated paper, craft paper, paperboard, white paperboard, newspaper and woody paper, but an inkjet paper having a porous coating layer on at least one surface of the paper substrate is preferable. The porous coating layer is a porous layer having a multitude of pores, and may be composed of either a single layer or multiple layers.
The pore diameter of the filter material for papermaking 10b preferably has, within the pore diameter distribution curve for the porous coating layer of
As illustrated in
As the die head 22, a sealed pressurized head that pressurizes and discharges the dispersion 3a, or an open head (for example, a free fall curtain head) that discharges the dispersion 3a under its own weight can be used. Further, a spray head that employs so-called liquid pressure atomization, in which the dispersion 3a is placed under high pressure and then discharged through a fine nozzle, can also be employed. In
As illustrated in
The side walls 18 are substantially triangular in shape with the apex at the upstream side, and when viewed from the transport direction, are positioned at the outside of the edges 10c of the continuous sheet 10. Further, the upstream wall 17a stands at the upstream side of the pair of side walls 18, in a direction orthogonal to the pair of side walls 18.
The first fabric sheets 15 and the continuous sheet 10, which are inclined so that the height increases from the upstream side toward the downstream side (from the left side to the right side in
(Side Sealing Mechanism)
The side sealing mechanisms 24, which block the gaps G between the side walls 18 of the storage unit 17 and the edges 10c of the continuous sheet 10, are provided inside the storage unit 17.
The side sealing mechanism 24 is an endless belt composed of a timing belt 24a which is itself an endless belt, and a plurality (three in the present embodiment) of timing pulleys 24b which regulate the position of the timing belt 24a. The side sealing mechanism 24 is arranged so that the travel direction of the timing belt 24a aligns with the travel direction of the continuous sheet 10.
The width of the side sealing mechanisms 24 is formed so as to be wider than the width of the gap G formed between the edge 10c of the continuous sheet 10 and the side wall 18 of the storage unit 17. The side sealing mechanisms 24 are installed on top of the edges 10c of the continuous sheet 10, and press down on the edges 10c of the continuous sheet 10, covering the gaps G, either under their own weight or via pressure application units not shown in the drawings. As a result, the side sealing mechanisms 24 block the gaps G, and prevent leakage of the dispersion 3a onto the first fabric sheets 15 and the suction devices 32 from gaps between the edges 10c of the continuous sheet 10 and the side walls 18.
Further, the length of the side sealing mechanisms 24 is formed so as to be longer than the length of the suction devices 32 described below. As a result, when the gaps G are blocked, leakage of the dispersion 3a onto the suction devices 32 from the edges of the side sealing mechanisms 24 in the travel direction is prevented.
(Water Squeezing Units)
The suction devices 32 (water squeezing units) which suck the dispersion medium are provided beneath the first fabric sheets 15. In the present embodiment, four suction devices 32 are provided, with one device provided beneath each of the first fabric sheets 15a to 15d. Each suction device 32 has negative pressure chambers 35, and a panel strip 34 which contacts the lower surface of the first fabric sheet 15. A plurality of the negative pressure chambers 35 (six in the present embodiment) are provided in each suction device 32, and a vacuum pump (not shown in the drawings) is connected to the negative pressure chambers 35.
As illustrated in
The through-holes 36 formed in the panel strip 34 may be formed with all manner of shapes, including substantially circular shapes and slit shapes when viewed from above. The through-holes 36 of the present embodiment are slits which extend in a direction orthogonal to the travel direction of the first fabric sheets 15, and a plurality of these slits are disposed in parallel from the upstream side toward the downstream side. The ratio of the surface area of the openings of the through-holes 36 relative to the surface area of the panel strip 34 (hereafter referred to as the “hole area ratio”) is preferably from 0.5 to 60%, more preferably from 2 to 50%, and particularly preferably from 5 to 35%.
When the first fabric sheet 15 is run and the suction pump of the suction device 32 is operated, the insides of the negative pressure chambers 35 and the through-holes 36 adopt a negative pressure. As a result, the dispersion medium contained in the dispersion 3a passes through the pores in the continuous sheet 10 and the first fabric sheet 15 and is suctioned through the through-holes 36 of the suction device 32. Moreover, because the upper surface of the panel strip 34 and the lower surface of the first fabric sheet 15 are in contact, the downstream edges 36a of the through-holes 36 sweep clean the lower surface of the first fabric sheet 15. In this manner, because the through-holes 36 of the panel strip 34 have a blade function that scrapes off the dispersion medium adhered to the lower surface of the first fabric sheet 15, the suction device 32 can rapidly remove and suction off the dispersion medium that has passed through the pores of the first fabric sheet 15.
As a result of the above, only the fine fibers contained in the dispersion 3a remain on the upper surface of the continuous sheet 10 to form the web 3c.
Returning to
The cavities in the fibrous sheet 3d are formed by applying and impregnating the organic solvent within the web substrate 3b, and then evaporating (drying) the water and the organic solvent in the drying section 40 described below.
Examples of the applied organic solvent include methanol, ethanol, 2-propanol, ethylene glycol-based compounds, glycol ethers such as dipropylene glycol methyl ether, ethylene glycol monobutyl ether, ethylene glycol mono-t-butyl ether and diethylene glycol monoethyl ether, glymes such as diethylene glycol dimethyl ether, diethylene glycol dibutyl ether, tetraethylene glycol dimethyl ether, triethylene glycol dimethyl ether, diethylene glycol diethyl ether, ethylene glycol diethyl ether, ethylene glycol dimethyl ether and diethylene glycol isopropyl methyl ether, dihydric alcohols such as 1,2-butanediol and 1,6-hexanediol, diethylene glycol monoethyl ether acetate, and ethylene glycol monomethyl ether acetate. Combinations of two or more of these organic solvents may also be used.
Among these, ethylene glycol-based compounds, diethylene glycol dimethyl ether and diethylene glycol isopropyl methyl ether, which exhibit excellent solubility in water, and display a good balance between boiling point, surface tension and molecular weight, are particularly preferred as they make it easier to achieve porosity.
Examples of the organic solvent application unit 30 include a spray coater, curtain coater, gravure coater, bar coater, blade coater, size press coater, gate roll coater, cap coater, microgravure coater, die coater, rod coater, comma coater and screen coater, but for the reasons of facilitating control of the amount of the organic solvent applied (the impregnation amount) and enabling uniform application (impregnation), at least one method selected from among spray, curtain, gravure, bar, blade and size press coating is preferable. The water-containing web substrate 3b has poor strength, and if contact is made with a coater head, then there is a possibility that bands or irregularities may develop in the web substrate 3b, and therefore a spray or curtain coating method that has no contact is the most preferable.
(Drying Section)
As illustrated in
The first dryer 42 and the second dryer 52 are each composed of a cylinder dryer. A cylinder dryer is a device in which a heating medium is introduced into the interior of the cylinder to hold the outer peripheral surface at a high temperature, and the liquid component contained within a sample positioned around the outer peripheral surface is evaporated to dry the sample. A hood 49 is provided so as to cover the drying section 40.
The continuous sheet 10 that emerges from the water squeezing section 20 is wound around the first drier 42 in the drying section 40. The continuous sheet 10 is disposed around approximately ⅔ of the circumference of the outer peripheral surface of the first drier 42. Further, the continuous sheet 10 is then wound from the first drier 42 onto the second drier 52 via a plurality of sub-rollers 48. The continuous sheet 10 is disposed around approximately ⅔ of the circumference of the outer peripheral surface of the second drier 52. The continuous sheet 10 then passes from the second drier 52 via a plurality of sub-rollers 58 into the winding section 60. The first drier 42 and the second drier 52 are designed to rotate at the same angular velocity as the continuous sheet 10 that is disposed around the outer peripheral surfaces of the driers.
The felt 44 is formed from a blanket, and runs in a circulatory manner around the inside of the drying section 40. The felt 44 is positioned outside the continuous sheet 10 in the radial direction of the first drier 42 and the second drier 52. In the same manner as the continuous sheet 10, the felt 44 is disposed around approximately ⅔ of the circumference of the outer peripheral surfaces of the first drier 42 and the second drier 52. The felt 44 is designed to run around the outer peripheral surfaces of the first drier 42 and the second drier 52 at the same angular velocity as the continuous sheet 10.
The web 3c that has been introduced into the drying section 40 mounted on the upper surface of the continuous sheet 10 is wound around the outer peripheral surface of the first drier 42 in a state where the upper surface of the web 3c contacts the outer peripheral surface of the first drier 42. As a result, the web 3c, the continuous sheet 10 and the felt 44 are disposed in sequence, from the inside in the radial direction toward the outside, around the outer peripheral surface of the first drier 42. Because the outer peripheral surface of the first drier 42 is heated to a high temperature, the dispersion medium retained within the web 3c evaporates. The evaporated dispersion medium passes through the pores of the continuous sheet 10 and is absorbed by the felt 44. Accordingly, the evaporated dispersion medium can be prevented from re-adhering to the web 3c, and therefore the web 3c can be dried reliably and efficiently.
Next, the web 3c is wound around the outer peripheral surface of the second drier 52. The second drier 52 dries the web 3c in a similar manner to the first drier 42, and therefore description of the second drier 52 is omitted. By using a plurality of driers, the web 3c can be dried more reliably. The above process completes drying of the web 3c, and the fibrous sheet 3d is formed.
(Winding Section)
The winding section 60 is provided downstream from the drying section 40. The winding section 60 is equipped with a pair of first separation rollers 62a and 62b which separate the second fabric sheet 10a from the filter material for papermaking 10b, and a second fabric sheet recovery reel 76 which recovers the separated second fabric sheet 10a.
Further, downstream from the first separation rollers 62a and 62b are provided a pair of second separation rollers 63a and 63b which separate the fibrous sheet 3d and the filter material for papermaking 10b, a papermaking filter material recovery reel 72 which recovers the filter material for papermaking 10b, and a winding reel 64 which winds the fibrous sheet 3d.
The pair of first separation rollers 62a and 62b are positioned on either side of the continuous sheet 10. By sandwiching the continuous sheet 10 and the fibrous sheet 3d between the pair of first separation rollers 62a and 62b, the second fabric sheet 10a is separated from the filter material for papermaking 10b and moves around the surface of one of the first separation rollers 62b.
The second fabric sheet recovery reel 76 pulls the second fabric sheet 10a away from the surface of the first separation roller 62b, and winds the second fabric sheet 10a.
The fibrous sheet 3d, in a state superimposed with the filter material for papermaking 10b, moves around the surface of the other first separation roller 62a. Subsequently, by sandwiching the filter material for papermaking 10b and the fibrous sheet 3d between the pair of second separation rollers 63a and 63b, the filter material for papermaking 10b is separated from the fibrous sheet 3d and moves around the surface of one of the second separation rollers 63b.
The papermaking filter material recovery reel 72 pulls the filter material for papermaking 10b away from the surface of the second separation roller 63b, and winds the filter material for papermaking 10b.
Further, the winding reel 64 pulls the fibrous sheet 3d away from the surface of the other second separation roller 63a and winds the fibrous sheet 3d. By using this configuration, a fibrous sheet 3d in a wound state can be produced.
(Effects of First Embodiment)
According to the present embodiment, because the plurality of first fabric sheets 15a to 15d are arranged longitudinally, when the dispersion medium is squeezed from the dispersion 3a, the frictional force that acts on the first fabric sheets 15a to 15d can be dispersed across the plurality of first fabric sheets 15a to 15d. As a result, the first fabric sheets 15a to 15d can be run without pulling the first fabric sheets 15a to 15d with a strong tension. Accordingly, a fibrous sheet can be produced while preventing damage of the first fabric sheets 15a to 15d.
Further, because the continuous sheet 10 is positioned so as to extend over the upper surface of the plurality of first fabric sheets 15a to 15d, in the water squeezing section 20, the frictional force during squeezing causes the lower surface of the continuous sheet 10 and the upper surfaces of the first fabric sheets 15a to 15d to adopt a state of close contact. When the first fabric sheets 15a to 15d are run in this state, the continuous sheet 10 is transported by the first fabric sheets 15a to 15d. As a result, the continuous sheet 10 can be transported without having to pull the continuous sheet 10 with a strong tension. Accordingly, the fibrous sheet 3d can be produced while preventing damage of the continuous sheet 10.
Moreover, according to this device configuration, the web substrate 3b that is partway through web generation is transported between the plurality of first fabric sheets 15a to 15d in a state mounted on the upper surface of the continuous sheet 10, and therefore damage of the web substrate 3b during transfer between the plurality of first fabric sheets 15a to 15d can be avoided. Accordingly, a fibrous sheet 3d formed from fine fibers can be produced reliably.
Furthermore, according to the present embodiment, because the continuous sheet 10 is composed of the filter material for papermaking 10b disposed on the upper surface of the second fabric sheet 10a, by installing a filter material for papermaking 10b having smaller pores than the second fabric sheet 10a, finer fibers can be trapped. Accordingly, a further reduction in the pore diameter and a further increase in the porosity of the fibrous sheet 3d can be achieved.
Further, because the second fabric sheet 10a and the filter material for papermaking 10b are transported by the first fabric sheets 15a to 15d, damage of the second fabric sheet 10a and the filter material for papermaking 10b can be prevented.
Furthermore, according to the present embodiment, because the side sealing mechanisms 24 which block the gaps G between the edges 10c of the continuous sheet 10 and the side walls 18 of the storage unit 17 are provided, leakage of the dispersion 3a onto the first fabric sheets 15 and the suction devices 32 from the edges 10c of the continuous sheet 10 can be prevented. Accordingly, finer fibers can be trapped by the continuous sheet 10, and the dispersion medium can be removed with good efficiency.
Further, according to the present embodiment, because the first fabric sheets 15 are formed as endless belts, the device 1 for producing fibrous sheets can be made more compact.
Moreover, according to the present embodiment, because the continuous sheet 10 extends from the water squeezing section 20 across to the drying section 40, there is no necessity to transfer the web 3c from the water squeezing section 20 across to the drying section 40. Accordingly, even if the strength of the web 3c weakens due to the use of fine fibers, damage of the web 3c during transfer can be avoided, and a fibrous sheet 3d formed from fine fibers can be produced reliably.
Further, according to the present embodiment, because the panel strips 34 having the through-holes 36 contact the lower surfaces of the first fabric sheets 15, when the first fabric sheets 15 are run, the lower surfaces of the first fabric sheets 15 are swept clean by the downstream edges 36a of the through-holes 36. As a result, the dispersion medium that has passed through the pores of the first fabric sheets 15 can be rapidly removed, and therefore the squeezing operation can be made more efficient.
Furthermore, according to the present embodiment, because the first fabric sheets 15 are arranged so that the height increases from the upstream side toward the downstream side, the web substrate 3b can be gently lifted and pulled out of the deeply accumulated dispersion 3a at the upstream side of the storage unit 17. Accordingly, a well-formed fibrous sheet 3d having a smooth surface can be produced.
Moreover, according to the present embodiment, because the water squeezing section 20 has a solvent application unit which applies an organic solvent that forms cavities in the fibrous sheet 3d to the web substrate 3b, a porous fibrous sheet 3d can be produced.
Next is a description of a device for producing a fibrous sheet according to a second embodiment.
In the device 1 for producing a fibrous sheet according to the first embodiment, the web 3c was transferred from the water squeezing section 20 to the drying section 40 while still mounted on top of the continuous sheet 10.
In contrast, the device 100 for producing a fibrous sheet according to the second embodiment differs in that the continuous sheet 10 is recovered at the downstream side of the water squeezing section 20, so that only the web 3c is transferred between the water squeezing section 20 and the drying section 40. Detailed descriptions are omitted for those structural components that are the same as the first embodiment.
As illustrated in
In a similar manner to the first embodiment, by sandwiching the continuous sheet 10 and the web 3c between the pair of first separation rollers 62a and 62b, the filter material for papermaking 10b and the second fabric sheet 10a are separated, and the second fabric sheet 10a moves around the surface of one of the first separation rollers 62b.
The second fabric sheet recovery reel 76 pulls the second fabric sheet 10a away from the surface of the first separation roller 62b, and winds the second fabric sheet 10a.
The web 3c, in a state superimposed with the filter material for papermaking 10a, moves around the surface of the other first separation roller 62a.
Subsequently, in a similar manner to the first embodiment, by sandwiching the filter material for papermaking 10b and the web 3c between the pair of second separation rollers 63a and 63b, the web 3c and the filter material for papermaking 10b are separated, and the filter material for papermaking 10b moves around the surface of one of the second separation rollers 63b.
The papermaking filter material recovery reel 72 pulls the filter material for papermaking 10b away from the surface of the second separation roller 63b, and winds the filter material for papermaking 10b.
The web 3c moves alone around the surface of the other second separation roller 63a.
Subsequently, the web 3c runs alone around the outer peripheral surfaces of the first drier 42 and the second drier 52.
The web 3c is wound around the outer peripheral surface of the first drier 42 in a state where the upper surface of the web 3c contacts the outer peripheral surface of the first drier 42. As a result, the web 3c and the felt 44 are disposed in sequence, from the inside in the radial direction to the outside, around the outer peripheral surface of the first drier 42. Next, the web 3c is wound around the outer peripheral surface of the second drier 52. The second drier 52 dries the web 3c in a similar manner to the first drier 42, and therefore description of the second drier 52 is omitted.
(Effects of Second Embodiment)
In the first embodiment, the continuous sheet 10 composed of the second fabric sheet 10a and the filter material for papermaking 10b, and the web 3c were in a superimposed state when run around the outer peripheral surfaces of the first drier 42 and the second drier 52. As a result, in the drying section 40, the second fabric sheet 10a and the filter material for papermaking 10b were interposed between the web 3c and the felt 44.
In contrast, in the present embodiment, following separation of the second fabric sheet 10a and the filter material for papermaking 10b, the web 3c is run alone around the outer peripheral surfaces of the first drier 42 and the second drier 52. Accordingly, because nothing is interposed between the web 3c and the felt 44, the web 3c can be dried more rapidly than the first embodiment.
However, in terms of the strength of the continuous sheet 10 during running around the outer peripheral surfaces of the first drier 42 and the second drier 52, the first embodiment is superior.
Next is a description of a device for producing a fibrous sheet according to a third embodiment.
In the device 1 for producing a fibrous sheet according to the first embodiment and the device 100 for producing a fibrous sheet according to the second embodiment, the continuous sheet 10 was formed from the second fabric sheet 10a and the filter material for papermaking 10b. Further, the second fabric sheet 10a and the filter material for papermaking 10b were both open-ended belts, supplied from the second fabric sheet supply reel 75 and the papermaking filter material supply reel 70 respectively, and recovered onto the second fabric sheet recovery reel 76 and the papermaking filter material recovery reel 72 respectively.
However, the device 101 for producing a fibrous sheet according to the third embodiment differs from the first embodiment and the second embodiment in terms of the point that the continuous sheet 10 is composed only of the second fabric sheet 10a, and the point that the continuous sheet 10 is an endless belt. Detailed descriptions are omitted for those structural components that are the same as the first embodiment and the second embodiment.
As illustrated in
(Effects of Third Embodiment)
According to this embodiment, because the continuous sheet 10 is formed from only the second fabric sheet 10a, and the continuous sheet 10 is formed as an endless belt, there is no necessity to provide a reel for supplying the continuous sheet 10 or a reel for recovering the continuous sheet 10. Accordingly, the device 101 for producing a fibrous sheet can be made more compact.
Further, when travelling around the outer peripheral surfaces of the first drier 42 and the second drier 52 during drying, because only the second fabric sheet 10a is interposed between the web 3c and the felt 44, the web 3c can be dried more rapidly than the first embodiment.
However, in the first embodiment and the second embodiment, installing the filter material for papermaking 10b with small pores on the upper surface of the second fabric sheet 10a enables fine fibers to be trapped in the water squeezing section, and therefore in terms of enabling a reduction in the pore diameter of the fibrous sheet and an increase in the porosity, the first embodiment and the second embodiment are superior.
This invention is not limited to the embodiments described above.
In each of the devices 1, 100 and 101 for forming fibrous sheets according to the embodiments, four first fabric sheets 15 are provided, but the number of first fabric sheets 15 is not limited to this number.
Further, in each of the embodiments, four suction devices 32 are provided, and six negative pressure chambers 35 are provided within each suction devices 32, but the numbers of suction devices 32 and negative pressure chambers 35 are not limited to these numbers.
In each of the devices 1, 100 and 101 for forming fibrous sheets according to the embodiments, each of the first fabric sheets 15 is an endless belt. However, a supply reel for the first fabric sheet 15 and a recovery reel for the first fabric sheet 15 may be provided, with the first fabric sheet 15 being recovered following running. However, forming the first fabric sheets 15 as endless belts is preferable in terms of making the devices 1, 100 and 101 for forming fibrous sheets more compact.
In the device 100 for producing a fibrous sheet according to the second embodiment, the pair of first separation rollers 62a and 62b and the pair of second separation rollers 63a and 63b were disposed on the downstream side of the most downstream first fabric sheet 15d and on the upstream side of the first drier 42, and the second fabric sheet 10a and the filter material for papermaking 10b were recovered at the upstream side of the first drier 42. However, the position for the recovery of the second fabric sheet 10a and the filter material for papermaking 10b is not limited to this position. Accordingly, for example, the pair of first separation rollers 62a and 62b may be positioned on the downstream side of the first drier 42 and on the upstream side of the second drier 52, so that the second fabric sheet 10a is recovered at the upstream side of the second drier 52.
Further, in a similar manner, the positioning of the second separation rollers 63a and 63b may also be altered, thus altering the recovery position for the filter material for papermaking 10b.
In the device 100 for producing a fibrous sheet according to the second embodiment, only the web 3c is run through the first drier 42 and the second drier 52 for drying. Further, in the device 101 for producing a fibrous sheet according to the third embodiment, the second fabric sheet 10a and the web 3c are run in a superimposed state through the first drier 42 and the second drier 52 for drying. However, the second fabric sheet 10a may be separated from the web 3c at the upstream side of the first drier 42, so that only the web 3c is run through the first drier 42 and the second drier 52 for drying.
According to the present invention, a device for producing a fibrous sheet can be provided that enables production of a fibrous sheet while preventing damage to the fabric sheet.
1, 100, 101: Device for producing a fibrous sheet
3
a: Dispersion
3
b: Web substrate
3
c: Web
3
d: Fibrous sheet
10: Continuous sheet
10
a: Second fabric sheet
10
b: Filter material for papermaking
10
c: Edge
15 (15a, 15b, 15c, 15d): First fabric sheet
18: Side wall
20: Water squeezing section
24: Side sealing mechanism
30: Organic solvent application unit (solvent application unit)
32: Suction device (water squeezing unit)
34: Panel strip
36: Through-hole
40: Drying section
G: Gap
| Number | Date | Country | Kind |
|---|---|---|---|
| 2010-282381 | Dec 2010 | JP | national |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/JP2011/079192 | 12/16/2011 | WO | 00 | 6/12/2013 |
| Publishing Document | Publishing Date | Country | Kind |
|---|---|---|---|
| WO2012/081698 | 6/21/2012 | WO | A |
| Number | Name | Date | Kind |
|---|---|---|---|
| 1514011 | Pope | Nov 1924 | A |
| 1577897 | Alois | Mar 1926 | A |
| 1754370 | Raynes | Apr 1930 | A |
| 2392150 | Hornbostel et al. | Jan 1946 | A |
| 2870819 | Heyman | Jan 1959 | A |
| 2881677 | Reginald | Apr 1959 | A |
| 3013605 | Justus | Dec 1961 | A |
| 3082819 | Justus et al. | Mar 1963 | A |
| 3115439 | Austin | Dec 1963 | A |
| 3127308 | Justus et al. | Mar 1964 | A |
| 3222246 | Lee | Dec 1965 | A |
| 3330723 | Henrik | Jul 1967 | A |
| 3399111 | Beaumont et al. | Aug 1968 | A |
| 3477905 | Rogers, Jr. | Nov 1969 | A |
| 3480509 | Stein | Nov 1969 | A |
| 3560334 | Ardledter | Feb 1971 | A |
| 3642573 | Genz et al. | Feb 1972 | A |
| 3650892 | Genz et al. | Mar 1972 | A |
| 3676294 | Opderbeck et al. | Jul 1972 | A |
| 3764465 | Bartley et al. | Oct 1973 | A |
| 3775244 | Hubschmann | Nov 1973 | A |
| 3785922 | Keller | Jan 1974 | A |
| 3846233 | Kankaanpaa | Nov 1974 | A |
| 3876500 | Csordas et al. | Apr 1975 | A |
| 3907635 | Bringman | Sep 1975 | A |
| 4306934 | Seppanen | Dec 1981 | A |
| 4780184 | Salovaara | Oct 1988 | A |
| 5011575 | Keller | Apr 1991 | A |
| 5034100 | Sides | Jul 1991 | A |
| 5622599 | Sproule et al. | Apr 1997 | A |
| 6123882 | Uchida et al. | Sep 2000 | A |
| 6413674 | Mizobuchi et al. | Jul 2002 | B1 |
| 7597779 | Gupta et al. | Oct 2009 | B2 |
| 8070916 | Scherb et al. | Dec 2011 | B2 |
| 8157965 | Saito | Apr 2012 | B2 |
| 20020096302 | Scherb et al. | Jul 2002 | A1 |
| 20040163787 | Bartelmuss et al. | Aug 2004 | A1 |
| 20050098282 | Scherb | May 2005 | A1 |
| 20050133186 | Hultcrantz | Jun 2005 | A1 |
| 20050167062 | Herman et al. | Aug 2005 | A1 |
| 20070068645 | Silva | Mar 2007 | A1 |
| 20100300635 | Mausser et al. | Dec 2010 | A1 |
| 20130025809 | Godsay et al. | Jan 2013 | A1 |
| 20130269898 | Shirao et al. | Oct 2013 | A1 |
| Number | Date | Country |
|---|---|---|
| 1409787 | Apr 2003 | CN |
| 1914374 | Feb 2007 | CN |
| 2345984 | Mar 1975 | DE |
| 3635889 | Apr 1987 | DE |
| 0043290 | Jan 1982 | EP |
| 774541 | May 1997 | EP |
| 2017384 | Jan 2009 | EP |
| 1179729 | May 1959 | FR |
| 1218040 | May 1960 | FR |
| A-57-039300 | Mar 1982 | JP |
| A-60-167990 | Aug 1985 | JP |
| A-63-112790 | May 1988 | JP |
| A-10-140493 | May 1998 | JP |
| A-2008-274525 | Nov 2008 | JP |
| 2012132103 | Jul 2012 | JP |
| 2013096026 | May 2013 | JP |
| Entry |
|---|
| EPO Machine Translation of the First office Action on Application/Publication No. CN-201180060361.X, issued on Jul. 15, 2014. |
| International Search Report mailed on Feb. 28, 2012 in International Application No. PCT/JP2011/079192. |
| Extended European Search Report mailed May 26, 2014 in European Application No. 11849094.5. |
| Office Action issued in Chinese Patent Application No. 201180060361.X on Jul. 15, 2014. |
| Number | Date | Country | |
|---|---|---|---|
| 20130269898 A1 | Oct 2013 | US |
