This application is a national phase filing under 35 USC § 371 from PCT Application serial number PCT/EP2014/003378 filed on Dec. 16, 2014, and claims priority therefrom. This application further claims priority from European Patent Application EP 13005959.5 filed on Dec. 20, 2013. PCT Application Number PCT/EP2014/003378 and European Patent Application Number EP 13005959.5 are each incorporated herein in their entireties by reference.
The invention relates to a device, a special paper and a method for producing three-dimensional objects.
A method for producing three-dimensional objects from computer data is described in the European patent specification EP 0 431 924 B1. In this method, a particulate material is applied in a thin layer to a platform, and a binder material is selectively printed onto the particulate material, using a print head. The particle area onto which the binder is printed sticks together and solidifies under the influence of the binder and, if necessary, an additional hardener. The platform is then lowered by a distance of one layer thickness into a build cylinder and provided with a new layer of particulate material, which is also printed as described above. These steps are repeated until a certain, desired height of the object is reached. A three-dimensional object is thereby produced from the printed and solidified areas.
After it is completed, this object produced from solidified particulate material is embedded in loose particulate material and is subsequently removed therefrom. This is done, for example, using an extractor. This leaves the desired objects, from which powder deposits are removed, for example by manual brushing.
Of all the layering techniques, 3D printing based on powdered materials and the supply of liquid binder is the fastest method.
This method may be used to process different particulate materials, including natural biological raw materials, polymers, metals, ceramics and sands (not an exhaustive list).
In the powder bed-based system, a complex powder handling is characteristic, which makes any use outside of an industrial environment more difficult.
Additive manufacturing methods for producing three-dimensional object according to a data record are known from the literature, some of which work with layered source materials such as paper and thus circumvent the powder handling.
The layer data that represents a section of the model at the particular height may be used, for example, in a method for the purpose of cutting a special paper along the desired layer contour, using a laser or a blade guided on a plotter mechanism. The paper may be coated on one side, for example, with an adhesive. Another layer of paper is then placed on the cut paper layer and glued to the preceding layer. Another cutting operation now takes place, whereby only the current paper layer should be separated on the basis of the current contour data. The operations of applying paper and cutting are repeated until the desired component is completely contained in the paper stack. Lastly, the paper surrounding the contour must be separated from the component. This may be made easier if additional auxiliary cutting paths are introduced into the paper stack.
A procedure of this type is described, e.g., in U.S. Pat. No. 5,730,817 and is generally known under the term, Laminated Object Manufacturing, or LOM for short.
Another advantage of the technology lies in the use of paper or paper-like materials, which are cost-effectively available and may be purchased in a high standard of quality. In this case, the paper is fed to the device in the form of a roll.
In another specific embodiment by the MCor company, commercial paper in the form of sheets is used in the A4 size typical for printers. The sheet of paper is again cut with a blade. With the aid of a special apparatus, adhesive is applied to the paper only in the locations where the later object will be produced. This has the advantage that the surrounding paper layers may be very easily detached from the actual model. A new sheet of paper is subsequently placed on the stack, recut and glued. The operation is repeated until the desired paper is present in the paper stack. Once again, the surrounding paper must then be removed to obtain the component.
The disadvantage of the aforementioned systems is that expensive special machines are needed for producing the 3D object, which the customer must first acquire and install.
The investment in the technology is generally too high, in particular, for customers who have only an occasional need for printed 3D objects.
One object of the application was therefore to provide a method which makes it possible to create three-dimensional objects according to a CAD data record without high investment costs.
Another object of the application was to provide materials which may be used to produce three-dimensional objects easily and cost-effectively, using common printers.
A further object of the application was to provide methods and, if necessary, materials which at least partially mitigate the disadvantages of the prior art or avoid them altogether.
In one aspect, the invention relates to a device for producing 3D objects.
In another aspect, the invention relates to a special paper which is suitable for producing 3D objects.
In another aspect, the invention relates to a method for producing 3D objects.
In another aspect, the invention relates to a method for producing 3D objects for use as casting molds, which are preferably subjected to additional method steps following a first method step.
A number of terms in the invention are explained in greater detail below.
Within the meaning of the invention, “3D printing method” relates to all methods known from the prior art which facilitate the construction of components in three-dimensional molds and are compatible with the described method components and devices.
“Selective binder application” or “selective binder system application” within the meaning of the invention may take place using any currently available printing technology. This includes ink-jet printers, laser printers and dot matrix printers.
“Molded body” or “component” or “object” within the meaning of the invention are all three-dimensional objects that are produced with the aid of the method according to the invention and/or the device according to the invention and which have a nondeformability.
A printing machine, which has a similar or identical design to a paper printing machine, is used as the “device” for carrying out the method according to the invention, also generally referred to as a “printer.” It may be designed as a sheet or roll machine. As a result, it contains paper feeding, separating, guiding and centering apparatuses, typically a printing unit, a fixing unit, a product storage apparatus and other components known to those skilled in the art, which therefore do not need to be discussed in greater detail here.
According to the invention, “paper” or “special paper” is understood to be a flat, smooth material layer of a defined thickness. The thickness is much less than the other two dimensions. However, “paper” is not strictly understood to be paper in the classic sense but rather film-like or sheet-like materials that are structured in such a way that they have the necessary properties for the method described. In particular, they may be selectively bound, and a molded part may be removed from the unbound special paper. In particular, the materials described below may be used for this special paper.
A “sheet” is a piece of paper which has two dimensions of approximately the same size. The factor between the dimensions is typically not more than three.
A “roll” is also a piece of paper, the dimensions deviating greatly from each other. Factors of up to several thousand are not atypical.
“Binding” is the step according to the method, in which a block is formed from the loose paper stack. At least the printed or the unprinted areas are bound.
“Remove” or “separate from unbound special paper” means that the component is released from the paper stack or the roll. Baths for dissolving unwanted material may be used, as may melting processes or burn-off processes that pulverize the paper.
“Finishing” is an intermediate step in the method, which makes it possible to intensify the effect of the material or the information applied by the printing process for subsequent processes such as binding or removal.
Within the meaning of the invention, “positive printing” is understood to be the fact that an object is produced directly, which forms the essentially desired shape. This object may still be finished or subjected to additional method steps.
“Negative printing” within the meaning of the invention is understood to be that a 3D body is produced, which may be used as a casting mold either directly or after additional treatment steps for the purpose of producing the ultimately desired object.
The invention, along with its preferred specific embodiments, is described in greater detail below.
One core of the invention is the finding that nearly every consumer in an industrial country today owns a 2D printer. According to the invention, this printer is used to produce layers with the aid of special paper. The 3D body is then produced from the layers in one or multiple finishing treatment steps. Another step then deals with releasing the object from the paper stack. Both steps following printing and stacking should be able to be carried out using simple means, at best those available in the home.
In other embodiments, the advantages of this method are transferred to new types of devices, since this offers significant advantages over the prior art, not only in the area of low investments.
In one aspect, the invention relates to a device that is suitable for producing a three-dimensional body from individual layers, including:
All known and suitable printer units may be used in this device, the device preferably being or having an ink-jet print unit, a laser print unit and/or a dot matrix print unit.
The device may furthermore include a temperature control unit.
In another aspect, the invention relates to a special paper that is suitable for producing a three-dimensional body from individual layers. The special paper preferably has the following properties:
The special paper may contain all materials that may be glued or bound together, or it may be made therefrom; the basic substance of the special paper is preferably made of cellulose fibers, or it is selected from the materials of plastic, naturally occurring substance, metal, stone, mineral or ceramic, or it is a combination of these substances.
It is advantageous from an environmental standpoint if the components contained in the special paper are essentially non-toxic.
As described, printing preferably takes place in multiple layers, i.e. on a series of sheets of special paper, and the sheets obtained in this manner are then bound together in a selected sequence in another step for the purpose of producing the three-dimensional object. The special paper has a binding capacity which may take place due to a fluid or a powder.
The binding capacity preferably takes place by adding a substance or changing a property of the special paper, preferably the activation takes place by transferring fluid or powder on the ink ribbon of a dot matrix printer, an ink-jet printer or by the fixed powder of a laser printer or copier. The binding capacity more preferably takes place due to a variable microwave selectability in the special paper, or the binding capacity takes place due to the presence or lack of a diffusible medium. The binding capacity more preferably takes place via the diffusion of a temperature-activatable substance.
The special paper may be provided in all suitable forms, preferably in the form of sheets or rolls.
In another aspect, the invention relates to a method for producing a three-dimensional body, including the steps:
In the method according to the invention, the special paper is preferably used in individual sheets, unseparated or perforated paper rolls.
Printing takes place with the aid of suitable printing means, preferably an ink-jet, dot matrix or laser printer.
In one preferred step, a water-containing substance is applied to the special paper, preferably by an ink-jet printer, a thermoplastic is applied to the special paper, preferably by a laser printer, or a highly viscous adhesive is applied to the paper, preferably by the ribbon of a dot matrix printer, and the selected areas are thus preferably bound.
The binding of the material of the selected areas may preferably be triggered by thermal energy and/or by pressure. The binding is more preferably triggered by another substance.
The three-dimensional body obtained in this manner may preferably be removed from the unbound special paper by a dissolution process in a solvent, by a thermal process or mechanically.
Following the method according to the invention, the three-dimensional molded body may preferably be subjected to additional processing steps, preferably a saturation or a perfusion of the three-dimensional molded body and/or an application or introduction of a substance for hardening the three-dimensional molded body.
The special paper according to the invention may furthermore be used in all methods which are suitable for producing three-dimensional objects.
One aspect of the invention is furthermore a three-dimensional object produced with the aid of one of the methods described above.
Preferred aspects of the invention are described in greater detail below.
In one aspect, the invention relates to an application in the home area. This refers to users who only rarely require a 3D object and own a normal 2D printer.
According to the invention, the user is to insert and print a special paper (100) into the normal printer. The particular printouts are the sectional drawings of the 3D object. The layer thickness, and thus the cutting position in the data record, are defined by the layers already printed and the sheet thickness. For example, a laser printer, an ink-jet printer or a dot matrix printer is used as the printer (
For example, the printed material may be largely water which is used solely as an information carrier. It may itself change a property in special paper (100), or it may be used after a finishing process (
Alternatively, an image (203) made of a polymer is melted with the paper using a laser printer.
A dot-matrix printer usually applies a highly viscous ink. It may again be used in a finishing process.
Sheet stack (102) from the printer is subsequently sorted thereon and precisely stacked. The user then places the stack, e.g., in the home oven, for the purpose of binding the individual layers. Heat (103) melts, for example, part of the printed image and diffuses into one or both adjacent sheets, preferably the top sheet.
Different mechanisms may be activated. On the one hand, the molten material is distributed in all spatial directions (402). On the other hand, additional constraining forces become active, such as gravity or an externally applied pressure (403, 404).
It is likewise possible to place the sheet stack in a home microwave. This is suitable, in particular in connection with the use of an ink-jet printer. The printed water may be prevented from evaporating by components, such as solid thickeners (e.g., xanthan gum, gelatin, polyvinyl alcohol, polyethylene glycoles, molar mass >600 g/mol) and/or liquid thickeners (e.g., propylene glycol, glycerin, polyethylene glycol, molar mass <600 g/mol) in special paper (100). In the microwave, energy is absorbed in the printed locations in a targeted manner and heat is effectively produced, due to the high absorption of the microwave radiation of the water. The high heat development, in turn, may be used to locally melt a component provided in special paper (100) and thus bind sheet stack (102).
In an alternative specific embodiment, only the unprinted areas melt, since the evaporation cold results in the fact that the temperature in the printed locations is not high enough to melt the component (e.g., plastic) contained on the special paper, e.g. due to the lack of a humectant and/or more volatile constituents in the printing medium.
Thus solidified, sheet stack (102, 401) is placed in a solvent, e.g., a water bath (501). The unprinted paper dissolves, and desired molded body (104) is released.
In an alternative specific embodiment, the user removes the sheet stack from the printer and sorts and stacks it. The user now places the stack into a liquid medium, e.g. an artificial resin, for binding the individual layers. The liquid then penetrates only the printed areas, because the special paper has developed a special absorption capacity, for example due to the dissolution of a protective layer with respect to the resin and the ability to mix with the print medium. In another case, the liquid penetrates only the unprinted areas, since the printed areas have been sealed against the introduction of liquid, and the resin is unable to mix with the print medium. The liquid now hardens, e.g. due to chemical reaction, after a certain waiting time or by the action of energy in the form of heat or radiation, and binds the desired molded body. At the end of the reaction, the special paper surrounding the molded body is dissolved, e.g. in a solvent.
One essential prerequisite for this method is the use of non-toxic and easy-to-handle special paper and the ability to use preferably commercial print media. No toxic substances should be released either during handling or during binding. Likewise, the dissolution process should preferably not cause waste water pollution.
A method is thus created, which makes it possible to carry out production at home in the case of low demand for 3D objects. Only a stack (102) of special paper (100) is needed for this purpose. The remaining requirements already exist in most homes.
A key component in this method is special paper (100). It must be activatable with the aid of commercial printers without damaging them. The activation must result in a binding of the individual paper sheets, and the mold must be removed after the process.
The activation may take place using a commercial laser printer (
To be able to carry out the other steps, paper (100) may have a water-soluble design. Layers (203) applied by the printing process penetrate the paper, due to the oven process, and change the solubility. After dipping the sheet stack into a water bath (501), molded part (104) is available.
Interestingly, a full color molded part may also be obtained by means of the method, if the color information for the printout is contained in the molded part. For this purpose, the data, including the layer-precise color information, is printed onto the special paper with the aid of an ink-jet printer or laser printer and further processed as described above.
In a second aspect, the method according to the invention also offers advantages for industrial applications. The investments here are secondary. However, new properties may be achieved by piling papers into a stack, binding and removing them.
In particular, the main point here is the achievable production capacity. For example, different sheets may be printed simultaneously. The sheets are subsequently placed in the layer sequence by forming a stack (102).
It would likewise be possible to print on a paper roll (600). The roll acts as a paper stack during removal. The data must be adapted to the circumstances. Once again, different parallelizations are possible here. For example, multiple rolls may be printed and wound together.
Another advantage of the use of special paper (100) lies in the special properties that may be achieved within the layer. A wide range of base materials may be used. For example, a higher density may be produced within a layer, compared to powder-based 3D printing. This constitutes a significant advantage, e.g., in the case of sintering materials.
This system may also be used to process solidifying materials that tend to shrink. Thus, thermal expansions are not active if the special paper is adequately dense.
Additional details, examples of preferred specific embodiments and advantages of the invention are discussed below.
Exemplary Embodiments
Exemplary embodiment 1 (special paper—laser printer—home oven:
In this embodiment of the invention, the focus is on home application. The embodiment facilitates the following scenario. A user is particularly interested in a 3D object on the Internet. He buys the special paper that is compatible with his 2D printer. Special software then allows him to convert a 3D format into individual 2D images. The operation is also accompanied by the program, and software assistants are provided that control the sheet sequence. The user can now print out his stack. After careful layering, the entire stack is placed in the oven. After a cooling phase, the user flushes his component out of the stack.
This technology enables the user to produce a 3D component at home in less than 1 day. He does not have to make any investment or possess any special technical skills.
The paper composition is crucial to the process steps. In this application example, cellulose-based paper is used. The fibers are short and have a length that is far less than the sheet thickness. The sheet thickness is 80 μm, and the fibers are therefore 20 to 30 μm in length.
The grammage of the paper must be far less than 60 g/m2. It is thus a very loose and lightweight paper.
The paper is bound by means of a water-soluble substance. In this example, the polymer polyvinyl alcohol (PVA) is used. The latter may be easily removed in the flushing process. Warm water increases the speed. If residues of PVA enter the sewage system, this does not pose an environmental hazard, since this plastic is biodegradable.
The polymer must be selected in terms of its melting point or glass transition in such a way that it survives the fixing process during laser printing and does not melt. Otherwise, the printout would be damaged.
This special paper (100) is subsequently printed according to layer data (101). The printing program ensures a numbering of sheets (100) and the highest possible toner application in each case. Individual sheets (100) are compiled into a stack (102, 400).
Toner based on polymethyl methacrylate (PMMA) is generally used in laser printers. This toner, which is made of micro-balls, is stuck to the paper in a layer (203) according to the data and subsequently melted with the paper due to high heat.
A paper printed in this manner demonstrates the desired hydrophobic property when placed in water. The image remains in the form of a thin film. The rest of the paper dissolves when gently stirred.
This stack (400) is then subjected to finishing treatment by heat (103) in the oven. Since paper (100) is generally a poor heat conductor, the operation must last several hours, for example in the case of a 10-cm stack made of DIN A4 papers (400). The glass transition temperature of PMMA must again be exceeded to bind the paper. The glass transition temperature of the PVA should advantageously not be exceeded so that entire stack (401) is not compressed and thus harder to dissolve later on. The oven must therefore be expediently set to approximately 100° C.
Paper stack (401) is then removed from the oven. To avoid internal distortion of the component because the thermoplastic is still soft, stack (401) must be cooled after the oven treatment. Once again, a certain amount of time is needed in this case, due to the heat conductivity. Stack (401) described above, which is 10 cm high and has the dimensions of a DIN A4 paper, should be age-hardened at room temperature for one hour.
To dissolve (
According to the invention, it is highly preferred that the basic substance of paper (100) is absolutely non-toxic and does not harm the environment. Dissolved material (502) may now be roughly separated from the water using a sieve and placed in the household trash. The rest is rinsed into the waste water.
Exemplary embodiment 2 (ceramic special paper—ink-jet printer—industrial oven):
The second example describes an industrial application of the aforementioned principle. The further benefits of the method are used here. An investment must be made prior to use.
This time, a ceramic film in the green state is used as paper. It is essentially made of a silicate ceramic compound. This compound is mixed with PVA and water and rolled out into a paper/film. A drying process the follows, in which all evaporable liquid is removed. The drying process must take place below the glass transition point of the PVA and in a gentle manner to avoid cracking. The temperatures must be kept below 100° C. The paper may subsequently be plasticized between two heated rollers, due to the action of heat, and calibrated for good parallelism and layer thickness control.
This paper may be further processed into sheets or used as a roll (600). After drying, it is elastically pliable, due to a thickness of less than 100 μm, and may be bent into relatively narrow rolls having a radius of 50 mm.
A device according to the invention for printing this roll provides for an unrolling unit, from which the material is fed to the process units. It is fed in a straight web under an ink-jet print head (602), an intermediate heating system and a calibration station (603).
In the example according to the invention, wax is used as the ink. The melting point is set by adding a low-melt polymer (polyethylene PE). This material may be safely processed with the aid of an ink-jet print module at a temperature of 70° C. Ceramic particles may preferably be added to the ink to reinforce the ceramic films.
The wax striking the paper is immediately cooled by the films and remains on the surface. A targeted local heating is therefore carried out in a subsequent step. The wax penetrates the paper. A precise setting of the speed of the web and the heating power are necessary to bind the paper roll afterward.
Another possible unit comprises diametrically opposed rollers. The projecting wax after the heating process, which is still flexible, is calibrated to an exact projection over the film.
The web is then rolled up onto a roller (601) under a defined pretension. Ideally, the images should now be situated one on top of the other, so that the desired components would be accurate in terms of geometry and size with imaginary cuts through the roll.
Since inaccuracies in the system are to be anticipated, sensors are used which continuously monitor the roll thickness. This signal is used to actively adjust the position and content of the printed images. All necessary conversions, such as conversion to polar coordinates, must take place.
The printing process runs continuously. The speed is limited only by the ink-jet print head and its design. All processing units may also be present multiple times. A true high-capacity production process is thus to be implemented by the invention.
At the end of the printing process, the roll is subjected to binding. As in the process for the home user, an oven is used for this purpose. The wax layers now melt into each other, and water-insoluble bodies form. The exact calibration and the high density of the rolled ceramic paper results in a highly dense ceramic green body.
The removal in this case takes place in the same manner as described, using a water bath. Water changes, other temperature controls, filtration at the dissolving medium, mechanical cleaning by means of high-pressure jets and automatic brushing may take place on an industrial scale. The loose parts may be removed from the solution by sieving.
In this example using ceramic paper, a sintering step advantageously takes place after these processes. The wax is burned off in a first step. This takes place at a temperature of up to 500° C. The molds are self-supporting, due to the high packing density even after this so-called unbinding. The burning takes place at 1,200° C.
Number | Date | Country | Kind |
---|---|---|---|
13005959 | Dec 2013 | EP | regional |
Filing Document | Filing Date | Country | Kind |
---|---|---|---|
PCT/EP2014/003378 | 12/16/2014 | WO | 00 |
Publishing Document | Publishing Date | Country | Kind |
---|---|---|---|
WO2015/090567 | 6/25/2015 | WO | A |
Number | Name | Date | Kind |
---|---|---|---|
3913503 | Becker | Oct 1975 | A |
4247508 | Housholder | Jan 1981 | A |
4575330 | Hull | Mar 1986 | A |
4591402 | Evans et al. | May 1986 | A |
4600733 | Ohashi et al. | Jul 1986 | A |
4665492 | Masters | May 1987 | A |
4669634 | Leroux | Jun 1987 | A |
4711669 | Paul et al. | Dec 1987 | A |
4752352 | Feygin | Jun 1988 | A |
4752498 | Fudim | Jun 1988 | A |
4863538 | Deckard | Aug 1989 | A |
4938816 | Beaman et al. | Jul 1990 | A |
4944817 | Bourell et al. | Jul 1990 | A |
5017753 | Deckard | May 1991 | A |
5031120 | Pomerantz et al. | Jul 1991 | A |
5047182 | Sundback et al. | Sep 1991 | A |
5053090 | Beaman et al. | Oct 1991 | A |
5059266 | Yamane et al. | Oct 1991 | A |
5076869 | Bourell et al. | Dec 1991 | A |
5120476 | Scholz | Jun 1992 | A |
5126529 | Weiss et al. | Jun 1992 | A |
5127037 | Bynum | Jun 1992 | A |
5132143 | Deckard | Jul 1992 | A |
5134569 | Masters | Jul 1992 | A |
5136515 | Helinski | Aug 1992 | A |
5140937 | Yamane et al. | Aug 1992 | A |
5147587 | Marcus et al. | Sep 1992 | A |
5149548 | Yamane et al. | Sep 1992 | A |
5155324 | Deckard et al. | Oct 1992 | A |
5156697 | Bourell et al. | Oct 1992 | A |
5182170 | Marcus et al. | Jan 1993 | A |
5204055 | Sachs et al. | Apr 1993 | A |
5216616 | Masters | Jun 1993 | A |
5229209 | Gharapetian et al. | Jul 1993 | A |
5248456 | Evans, Jr. et al. | Aug 1993 | A |
5252264 | Forderhase et al. | Oct 1993 | A |
5263130 | Pomerantz et al. | Nov 1993 | A |
5269982 | Brotz | Dec 1993 | A |
5284695 | Barlow et al. | Feb 1994 | A |
5296062 | Bourell et al. | Mar 1994 | A |
5316580 | Deckard | May 1994 | A |
5324617 | Majima et al. | Jun 1994 | A |
5340656 | Sachs et al. | Aug 1994 | A |
5342919 | Dickens, Jr. et al. | Aug 1994 | A |
5352405 | Beaman et al. | Oct 1994 | A |
5354414 | Feygin | Oct 1994 | A |
5382308 | Bourell et al. | Jan 1995 | A |
5387380 | Cima et al. | Feb 1995 | A |
5398193 | deAngelis | Mar 1995 | A |
5418112 | Mirle et al. | May 1995 | A |
5427722 | Fouts et al. | Jun 1995 | A |
5431967 | Manthiram et al. | Jul 1995 | A |
5433261 | Hinton | Jul 1995 | A |
5482659 | Sauerhoefer | Jan 1996 | A |
5490962 | Cima et al. | Feb 1996 | A |
5503785 | Crump et al. | Apr 1996 | A |
5506607 | Sanders, Jr. et al. | Apr 1996 | A |
5518060 | Cleary et al. | May 1996 | A |
5518680 | Cima et al. | May 1996 | A |
5555176 | Menhennett et al. | Sep 1996 | A |
5573721 | Gillette | Nov 1996 | A |
5589222 | Thometzek et al. | Dec 1996 | A |
5597589 | Deckard | Jan 1997 | A |
5616294 | Deckard | Apr 1997 | A |
5616631 | Kiuchi et al. | Apr 1997 | A |
5637175 | Feygin et al. | Jun 1997 | A |
5639070 | Deckard | Jun 1997 | A |
5639402 | Barlow et al. | Jun 1997 | A |
5647931 | Retallick et al. | Jun 1997 | A |
5658412 | Retallick et al. | Aug 1997 | A |
5665401 | Serbin et al. | Sep 1997 | A |
5717599 | Menhennett et al. | Feb 1998 | A |
5730925 | Mattes et al. | Mar 1998 | A |
5740051 | Sanders, Jr. et al. | Apr 1998 | A |
5747105 | Haubert | May 1998 | A |
5749041 | Lakshminarayan et al. | May 1998 | A |
5753274 | Wilkening et al. | May 1998 | A |
5807437 | Sachs et al. | Sep 1998 | A |
5837960 | Lewis et al. | Nov 1998 | A |
5851465 | Bredt | Dec 1998 | A |
5884688 | Hinton et al. | Mar 1999 | A |
5897825 | Fruth et al. | Apr 1999 | A |
5902441 | Bredt et al. | May 1999 | A |
5902537 | Almquist et al. | May 1999 | A |
5904889 | Serbin et al. | May 1999 | A |
5934343 | Gaylo et al. | Aug 1999 | A |
5940674 | Sachs et al. | Aug 1999 | A |
5943235 | Earl et al. | Aug 1999 | A |
5989476 | Lockard et al. | Nov 1999 | A |
6007318 | Russell et al. | Dec 1999 | A |
6036777 | Sachs | Mar 2000 | A |
6042774 | Wilkening et al. | Mar 2000 | A |
6048188 | Hull et al. | Apr 2000 | A |
6048954 | Barlow et al. | Apr 2000 | A |
6133353 | Bui et al. | Oct 2000 | A |
6146567 | Sachs et al. | Nov 2000 | A |
6147138 | Hochsmann et al. | Nov 2000 | A |
6155331 | Langer et al. | Dec 2000 | A |
6164850 | Speakman | Dec 2000 | A |
6165406 | Jang et al. | Dec 2000 | A |
6169605 | Penn et al. | Jan 2001 | B1 |
6175422 | Penn et al. | Jan 2001 | B1 |
6193922 | Ederer | Feb 2001 | B1 |
6210625 | Matsushita | Apr 2001 | B1 |
6216508 | Matsubara et al. | Apr 2001 | B1 |
6217816 | Tang | Apr 2001 | B1 |
6259962 | Gothait | Jul 2001 | B1 |
6270335 | Leyden et al. | Aug 2001 | B2 |
6305769 | Thayer et al. | Oct 2001 | B1 |
6318418 | Grossmann et al. | Nov 2001 | B1 |
6316060 | Elvidge et al. | Dec 2001 | B1 |
6335052 | Suzuki et al. | Jan 2002 | B1 |
6335097 | Otsuka et al. | Jan 2002 | B1 |
6350495 | Schriener et al. | Feb 2002 | B1 |
6355196 | Kotnis et al. | Mar 2002 | B1 |
6375874 | Russell et al. | Apr 2002 | B1 |
6395811 | Nguyen et al. | May 2002 | B1 |
6401001 | Jang et al. | Jun 2002 | B1 |
6403002 | Van Der Geest | Jun 2002 | B1 |
6405095 | Jang et al. | Jun 2002 | B1 |
6416850 | Bredt et al. | Jul 2002 | B1 |
6423255 | Hoechsmann et al. | Jul 2002 | B1 |
6460979 | Heinzl et al. | Oct 2002 | B1 |
6476122 | Leyden | Nov 2002 | B1 |
6485831 | Fukushima et al. | Nov 2002 | B1 |
6500378 | Smith | Dec 2002 | B1 |
6554600 | Hofmann et al. | Apr 2003 | B1 |
6596224 | Sachs et al. | Jul 2003 | B1 |
6610429 | Bredt et al. | Aug 2003 | B2 |
6616030 | Miller | Sep 2003 | B2 |
6658314 | Gothait | Dec 2003 | B1 |
6672343 | Perret et al. | Jan 2004 | B1 |
6713125 | Sherwood et al. | Mar 2004 | B1 |
6722872 | Swanson et al. | Apr 2004 | B1 |
6733528 | Abe et al. | May 2004 | B2 |
6742456 | Kasperchik et al. | Jun 2004 | B1 |
6764636 | Allanic et al. | Jul 2004 | B1 |
6827988 | Krause et al. | Dec 2004 | B2 |
6830643 | Hayes | Dec 2004 | B1 |
6838035 | Ederer et al. | Jan 2005 | B1 |
6855205 | McQuate et al. | Feb 2005 | B2 |
6896839 | Kubo et al. | May 2005 | B2 |
6972115 | Ballard | Dec 2005 | B1 |
6989115 | Russell et al. | Jan 2006 | B2 |
7004222 | Ederer et al. | Feb 2006 | B2 |
7037382 | Davidson et al. | May 2006 | B2 |
7048530 | Gaillard et al. | May 2006 | B2 |
7049363 | Shen | May 2006 | B2 |
7087109 | Bredt et al. | Aug 2006 | B2 |
7120512 | Kramer et al. | Oct 2006 | B2 |
7137431 | Ederer et al. | Nov 2006 | B2 |
7153463 | Leuterer et al. | Dec 2006 | B2 |
7204684 | Ederer et al. | Apr 2007 | B2 |
7220380 | Farr et al. | May 2007 | B2 |
7291002 | Russell et al. | Nov 2007 | B2 |
7296990 | Devos et al. | Nov 2007 | B2 |
7332537 | Bredt et al. | Feb 2008 | B2 |
7348075 | Farr et al. | Mar 2008 | B2 |
7378052 | Harryson | May 2008 | B2 |
7381360 | Oriakhi et al. | Jun 2008 | B2 |
7387359 | Hernandez et al. | Jun 2008 | B2 |
7402330 | Pfeiffer et al. | Jul 2008 | B2 |
7431987 | Pfeiffer et al. | Oct 2008 | B2 |
7435072 | Collins et al. | Oct 2008 | B2 |
7435368 | Davidson et al. | Oct 2008 | B2 |
7455804 | Patel et al. | Nov 2008 | B2 |
7455805 | Oriakhi et al. | Nov 2008 | B2 |
7497977 | Nielsen et al. | Mar 2009 | B2 |
7531117 | Ederer et al. | May 2009 | B2 |
7550518 | Bredt et al. | Jun 2009 | B2 |
7578958 | Patel et al. | Aug 2009 | B2 |
7597835 | Marsac | Oct 2009 | B2 |
7641461 | Khoshnevis | Jan 2010 | B2 |
7665636 | Ederer et al. | Feb 2010 | B2 |
7722802 | Pfeiffer et al. | May 2010 | B2 |
7807077 | Ederer et al. | May 2010 | B2 |
7736578 | Ederer et al. | Jun 2010 | B2 |
7748971 | Hochsmann et al. | Jul 2010 | B2 |
7767130 | Elsner et al. | Aug 2010 | B2 |
7795349 | Bredt et al. | Sep 2010 | B2 |
7799253 | Höchsmann et al. | Sep 2010 | B2 |
7879393 | Ederer et al. | Feb 2011 | B2 |
7887264 | Naunheimer et al. | Feb 2011 | B2 |
7927539 | Ederer | Apr 2011 | B2 |
8020604 | Hochsmann et al. | Sep 2011 | B2 |
8096262 | Ederer et al. | Jan 2012 | B2 |
8186415 | Marutani et al. | May 2012 | B2 |
8349233 | Ederer et al. | Jan 2013 | B2 |
8506870 | Hochsmann et al. | Aug 2013 | B2 |
8524142 | Unkelmann et al. | Sep 2013 | B2 |
8574485 | Kramer | Nov 2013 | B2 |
8715832 | Ederer et al. | May 2014 | B2 |
8727672 | Ederer et al. | May 2014 | B2 |
8741194 | Ederer et al. | Jun 2014 | B1 |
8911226 | Gunther et al. | Dec 2014 | B2 |
8951033 | Höchsmann et al. | Feb 2015 | B2 |
8956140 | Hartmann | Feb 2015 | B2 |
8956144 | Grasegger et al. | Feb 2015 | B2 |
8992205 | Ederer et al. | Mar 2015 | B2 |
9174391 | Hartmann et al. | Nov 2015 | B2 |
9174392 | Hartmann | Nov 2015 | B2 |
9242413 | Hartmann et al. | Jan 2016 | B2 |
9321934 | Mögele et al. | Apr 2016 | B2 |
9327450 | Hein et al. | May 2016 | B2 |
9333709 | Hartmann | May 2016 | B2 |
9358701 | Gnuchtel et al. | Jun 2016 | B2 |
20010045678 | Kubo et al. | Nov 2001 | A1 |
20010050031 | Bredt et al. | Dec 2001 | A1 |
20020016387 | Shen | Feb 2002 | A1 |
20020026982 | Bredt et al. | Mar 2002 | A1 |
20020079601 | Russell et al. | Jun 2002 | A1 |
20020090410 | Tochimoto et al. | Jul 2002 | A1 |
20020111707 | Li et al. | Aug 2002 | A1 |
20020155254 | McQuate et al. | Oct 2002 | A1 |
20020167100 | Moszner et al. | Nov 2002 | A1 |
20030004599 | Herbak | Jan 2003 | A1 |
20030065400 | Beam et al. | Apr 2003 | A1 |
20030069638 | Barlow et al. | Apr 2003 | A1 |
20030083771 | Schmidt | May 2003 | A1 |
20030113729 | DaQuino et al. | Jun 2003 | A1 |
20030114936 | Sherwood et al. | Jun 2003 | A1 |
20040003738 | Imiolek et al. | Jan 2004 | A1 |
20040012112 | Davidson et al. | Jan 2004 | A1 |
20040025905 | Ederer et al. | Feb 2004 | A1 |
20040026418 | Ederer et al. | Feb 2004 | A1 |
20040035542 | Ederer et al. | Feb 2004 | A1 |
20040036200 | Patel et al. | Feb 2004 | A1 |
20040038009 | Noel et al. | Feb 2004 | A1 |
20040045941 | Herzog et al. | Mar 2004 | A1 |
20040056378 | Bredt et al. | Mar 2004 | A1 |
20040084814 | Boyd et al. | May 2004 | A1 |
20040094058 | Kasperchik et al. | May 2004 | A1 |
20040104515 | Swanson et al. | Jun 2004 | A1 |
20040112523 | Crom | Jun 2004 | A1 |
20040138336 | Bredt et al. | Jul 2004 | A1 |
20040145088 | Patel et al. | Jul 2004 | A1 |
20040170765 | Ederer et al. | Sep 2004 | A1 |
20040187714 | Napadensky et al. | Sep 2004 | A1 |
20040207123 | Patel et al. | Oct 2004 | A1 |
20040239009 | Collins et al. | Dec 2004 | A1 |
20050003189 | Bredt et al. | Jan 2005 | A1 |
20050017386 | Harrysson | Jan 2005 | A1 |
20050017394 | Hochsmann et al. | Jan 2005 | A1 |
20050093194 | Oriakhi et al. | May 2005 | A1 |
20050167872 | Ederer et al. | Aug 2005 | A1 |
20050174407 | Johnson et al. | Aug 2005 | A1 |
20050179167 | Hachikian | Aug 2005 | A1 |
20050212163 | Bausinger et al. | Sep 2005 | A1 |
20050218549 | Farr et al. | Oct 2005 | A1 |
20050280185 | Russell et al. | Dec 2005 | A1 |
20060105102 | Hochsmann et al. | May 2006 | A1 |
20060108090 | Ederer et al. | May 2006 | A1 |
20060159896 | Pfeifer et al. | Jul 2006 | A1 |
20060175346 | Ederer et al. | Aug 2006 | A1 |
20060208388 | Bredt et al. | Sep 2006 | A1 |
20060237159 | Hochsmann | Oct 2006 | A1 |
20060251535 | Pfeifer et al. | Nov 2006 | A1 |
20060254467 | Farr et al. | Nov 2006 | A1 |
20070045891 | Martinoni | Mar 2007 | A1 |
20070057412 | Weiskopf et al. | Mar 2007 | A1 |
20070126157 | Bredt | Jun 2007 | A1 |
20080001331 | Ederer | Jan 2008 | A1 |
20080018018 | Nielsen et al. | Jan 2008 | A1 |
20080047628 | Davidson et al. | Feb 2008 | A1 |
20080138515 | Williams | Jun 2008 | A1 |
20080187711 | Alam et al. | Aug 2008 | A1 |
20080233302 | Elsner et al. | Sep 2008 | A1 |
20080237933 | Hochsmann et al. | Oct 2008 | A1 |
20080241404 | Allaman et al. | Oct 2008 | A1 |
20080260945 | Ederer et al. | Oct 2008 | A1 |
20090011066 | Davidson et al. | Jan 2009 | A1 |
20090068376 | Philippi et al. | Mar 2009 | A1 |
20090261497 | Ederer et al. | Oct 2009 | A1 |
20100007062 | Larsson et al. | Jan 2010 | A1 |
20100207288 | Dini | Aug 2010 | A1 |
20100212584 | Ederer et al. | Aug 2010 | A1 |
20100243123 | Ederer et al. | Sep 2010 | A1 |
20100244301 | Ederer et al. | Sep 2010 | A1 |
20100247742 | Shi et al. | Sep 2010 | A1 |
20100272519 | Ederer et al. | Oct 2010 | A1 |
20100279007 | Briselden et al. | Nov 2010 | A1 |
20100291314 | Kashani-Shirazi | Nov 2010 | A1 |
20100323301 | Tang et al. | Dec 2010 | A1 |
20110049739 | Uckelmann et al. | Mar 2011 | A1 |
20110059247 | Kuzusako et al. | Mar 2011 | A1 |
20110177188 | Bredt et al. | Jul 2011 | A1 |
20110223437 | Ederer et al. | Sep 2011 | A1 |
20110308755 | Hochsmann | Dec 2011 | A1 |
20120046779 | Pax et al. | Feb 2012 | A1 |
20120094026 | Ederer et al. | Apr 2012 | A1 |
20120097258 | Hartmann | Apr 2012 | A1 |
20120113439 | Ederer et al. | May 2012 | A1 |
20120126457 | Abe et al. | May 2012 | A1 |
20120291701 | Grasegger et al. | Nov 2012 | A1 |
20130000549 | Hartmann et al. | Jan 2013 | A1 |
20130004610 | Hartmann et al. | Jan 2013 | A1 |
20130026680 | Ederer et al. | Jan 2013 | A1 |
20130029001 | Gunther et al. | Jan 2013 | A1 |
20130092082 | Ederer et al. | Apr 2013 | A1 |
20130189434 | Randall et al. | Jul 2013 | A1 |
20130199444 | Hartmann | Aug 2013 | A1 |
20130234355 | Hartmann et al. | Sep 2013 | A1 |
20130302575 | Mogele et al. | Nov 2013 | A1 |
20130313757 | Kashani-Shirazi | Nov 2013 | A1 |
20140048980 | Crump et al. | Feb 2014 | A1 |
20140202381 | Ederer et al. | Jul 2014 | A1 |
20140202382 | Ederer | Jul 2014 | A1 |
20140212677 | Gnuchtel et al. | Jul 2014 | A1 |
20140227123 | Gunster | Aug 2014 | A1 |
20140271961 | Khoshnevis | Sep 2014 | A1 |
20140306379 | Hartmann et al. | Oct 2014 | A1 |
20140322501 | Ederer et al. | Oct 2014 | A1 |
20150042018 | Gunther et al. | Feb 2015 | A1 |
20150069659 | Ederer et al. | Mar 2015 | A1 |
20150110910 | Hartmann et al. | Apr 2015 | A1 |
20150165574 | Ederer et al. | Jun 2015 | A1 |
20150210822 | Ederer et al. | Jul 2015 | A1 |
20150224718 | Ederer et al. | Aug 2015 | A1 |
20150266238 | Ederer et al. | Sep 2015 | A1 |
20150273572 | Ederer et al. | Oct 2015 | A1 |
20150290881 | Ederer et al. | Oct 2015 | A1 |
20150375418 | Hartmann | Dec 2015 | A1 |
20150375419 | Gunther et al. | Dec 2015 | A1 |
20160001507 | Hartmann et al. | Jan 2016 | A1 |
20160052165 | Hartmann | Feb 2016 | A1 |
20160052166 | Hartmann | Feb 2016 | A1 |
20160107386 | Hartmann et al. | Apr 2016 | A1 |
20160114533 | Grasegger et al. | Apr 2016 | A1 |
20160263828 | Ederer et al. | Sep 2016 | A1 |
20160303762 | Gunther | Oct 2016 | A1 |
20160311167 | Gunther et al. | Oct 2016 | A1 |
20160311210 | Gunther et al. | Oct 2016 | A1 |
Number | Date | Country |
---|---|---|
720255 | May 2000 | AU |
832937 | Mar 1952 | DE |
3221357 | Dec 1983 | DE |
3930750 | Mar 1991 | DE |
4102260 | Jul 1992 | DE |
4305201 | Apr 1994 | DE |
4 325 573 | Feb 1995 | DE |
29506203.5 | Jun 1995 | DE |
4440397 | Sep 1995 | DE |
19525307 | Jan 1997 | DE |
19530295 | Jan 1997 | DE |
19533960 | Jan 1997 | DE |
19528215 | Feb 1997 | DE |
29701279 | May 1997 | DE |
19545167 | Jun 1997 | DE |
69031808 | Apr 1998 | DE |
19853834 | May 2000 | DE |
69634921 | Dec 2005 | DE |
201 22 639 | Nov 2006 | DE |
10 2006 040 305 | Mar 2007 | DE |
102006029298 | Dec 2007 | DE |
102007040755 | Mar 2009 | DE |
102007047326 | Apr 2009 | DE |
102011053205 | Mar 2013 | DE |
102015006363 | Dec 2016 | DE |
0076781 | Apr 1983 | EP |
0 224 621 | Jun 1987 | EP |
0361847 | Apr 1990 | EP |
0870622 | Oct 1998 | EP |
1415792 | May 2004 | EP |
1457590 | Sep 2004 | EP |
515824 | Apr 1981 | FR |
1025694 | Apr 1966 | GB |
2297514 | Aug 1996 | GB |
S62275734 | Nov 1987 | JP |
2003136605 | May 2003 | JP |
2004082206 | Mar 2004 | JP |
2009202451 | Sep 2009 | JP |
0140866 | Jun 2001 | WO |
2001078969 | Oct 2001 | WO |
2004014637 | Feb 2004 | WO |
2006100166 | Sep 2006 | WO |
2008061520 | May 2008 | WO |
2009049384 | May 2009 | WO |
2011063786 | Jun 2011 | WO |
2013075696 | May 2013 | WO |
2014090207 | Jun 2014 | WO |
2014166469 | Oct 2014 | WO |
2015081926 | Jun 2015 | WO |
2015085983 | Jun 2015 | WO |
2015090265 | Jun 2015 | WO |
2015090567 | Jun 2015 | WO |
2015096826 | Jul 2015 | WO |
2015078430 | Aug 2015 | WO |
2015149742 | Oct 2015 | WO |
2015180703 | Dec 2015 | WO |
2016019937 | Feb 2016 | WO |
2016019942 | Feb 2016 | WO |
2016058577 | Apr 2016 | WO |
2016095888 | Jun 2016 | WO |
2016101942 | Jun 2016 | WO |
2016146095 | Sep 2016 | WO |
Entry |
---|
US 4,937,420 A, 06/1990, Deckard (withdrawn) |
International Search Report, Application No. PCT/EP2014/003378, dated Mar. 11, 2015. |
Written Opinion of the International Search Authority, Application No. PCT/EP2014/003378, dated Mar. 11, 2015. |
Marcus et al., Solid Freedom Fabrication Proceedings, Nov. 1993. |
Cima et al., “Computer-derived Microstructures by 3D Printing: Bio- and Structural Materials,” SFF Symposium, Austin, TX, 1994. |
Marcus, et al., Solid Freeform Fabrication Proceedings, Sep. 1995, p. 130-133. |
Gebhart, Rapid Prototyping, pp. 118-119, 1996. |
Feature Article—Rapid Tooling—Cast Resin and Sprayed Metal Tooling by Joel Segal, Apr. 2000. |
EOS Operating Manual for Laser Sintering Machine with Brief Summary. |
EOS Operating Manual for Laser Feb. 22, 2005 Sintering Machine, Part 1 with Brief Summary, Feb. 22, 2005. |
EOS Operating Manual for Laser Feb. 22, 2005 Sintering Machine, Part 2 with Brief Summary, Feb. 22, 2005. |
Sachs, E., P. Williams, D. Brancazio, M. Cima, and K. Kremmin, Three dimensional printing: Rapid Tooling and Prototypes Directly from a CAD Model. In Proceedings of Manufacturing International 1990 (Atlanta, GA, Mar. 25-28). ASME, New York, 1990, pp. 131-136. |
Sachs et al., “Three-Dimensional Printing: Rapid Tooling and Prototypes Directly from a CAD Model”, Massachusetts Institute of Technology, pp. 143-151, Jan. 1990. |
Williams, “Feasibility Study of Investment Casting Pattern Design by Means of Three Dimensional Printing”, Department of Mechanical Engineering, pp. 2-15. |
Number | Date | Country | |
---|---|---|---|
20160311210 A1 | Oct 2016 | US |