Devolatilization of anhydride multi-polymers

Abstract

The present invention relates to the formation of low volatile anhydride-containing vinyl polymers by polymerizing the half ester of the anhydride with a vinyl aromatic monomer followed by devolatilizing the half-ester multi-polymer at elevated temperature and reduced pressures.

Description

Claims

1. A process for producing a multi-polymers of an aromatic vinyl monomer of 8 to 12 carbon atoms with and an unsaturated dicarboxylic acid anhydride of 4 to 8 carbon atoms having low volatiles which comprises forming the half ester of a volatile alcohol having up to four carbon atoms with the anhydride of the unsaturated dicarboxylic acid, polymerizing the half ester with the aromatic vinyl monomer and subjecting the resulting polymer to devolatilization at temperatures above 180° C.

2. The process of claim 1 wherein the aromatic vinyl monomer is styrene and the anhydride is maleic anhydride.

3. The process of claim 2 wherein the maleic anhydride content is from 0.5 to 25% by weight of the polymerized anhydride and styrene.

4. The process of claim 1 wherein the alcohol is methanol or ethanol.

5. Claim 1 wherein the residual monomer level in the resulting copolymer is reduced by the stripping action of the molecularly dispersed volatile alcohol.

6. Claim 2 wherein the improved heat resistance imparted by the maleic anhydride is retained.

7. The press of claim 2 wherein the monomer mixture contains from 0.5 to 15% by weight of the total mixture of an unsaturated rubber.

8. A process for the devolatilization of vinyl aromatic monomer maleic anhydride copolymers comprising devolatilizing copolymer of the half ester of maleic anhydride and a volatile alcohol at elevated temperatures above 180° C. at reduced pressures.

9. The process of claim 8 where the vinyl aromatic polymer is styrene.

10. The process of claim 8 where the maleic anhydride content is 33 wt % of the copolymer or less.

11. The process of claim 8 where the maleic anhydride content is more than 2.0 wt % of the copolymer.

12. The process of claim 8 where the maleic anhydride content is more than 4.0 wt % of the copolymer.

13. The process of claim 8 wherein the half ester of the maleic anhydride and the volatile alcohol is formed in situ in the polymerization reactor.

14. The process of claim 8 where the alcohol is methanol, ethanol or isopropanol.

15. The process of claim 8 where the alcohol is contains from 1 to 4 carbon atoms

16. The process of claim 8 wherein a heater and a vacuum chamber is used in the devolatilization.

17. The process of claim 16 where the volatile organic content of the partial polymer entering the devolatilization vacuum chamber is between 6 and 55 wt %.

18. The process of claim 16 where the temperature of the polymer leaving the devolatilizer heater is above 200° C.

19. The process of claim 16 where the temperature of the polymer leaving the devolatilizer heater is between 200 and 260° C.

20. The process of claim 16 where the temperature of the polymer entering the vacuum chamber is between 200° C. and 260° C. and the pressure in the vacuum chamber is between 2 and 50 mm of mercury.