Diamond tool

Abstract

A diamond tool, e.g., cutting tool, dresser, wire drawing die, etc., having excellent wear resistance, heat resistance and oxidation resistance and with an improved tool life is provided, which is mainly composed of a synthetic diamond single crystal containing boron or boron and nitrogen.

Description

BACKGROUND OF THE INVENTION

1. Field of the Invention

This invention relates to a diamond tool, in particular, a diamond cutting tool, a diamond dresser used for forming and dressing a grinding wheel, or a wire drawing die and more particularly, it is concerned with a synthetic diamond single crystal cutting tool used for precision machining or super-precision machining for cutting nonferrous metals such as aluminum and copper and soft materials such as plastics with high precision.

2. Description of the Prior Art

Natural diamond or synthetic diamond has been used as a diamond single crystal for tools, e.g. precision or super-precision cutting tools, and such diamond contains nitrogen as an impurity but no boron.

In the precision machining or super-precision machining for cutting nonferrous metals such as aluminum and copper or soft materials such as plastics with high precision using a diamond cutting tool, there arises a problem that the diamond cutting tool tends to wear and its life is short. During cutting, the edge part of the cutting tool wears so that the surface smoothness of the cut of a workpiece is deteriorated and the cutting resistance is increased, thus shortening the life of the cutting tool.

When a workpiece 1 of a soft material is cut by a diamond cutting tool 2 as shown in FIG. 5, a cut chip 4 slides continuously at a high speed in contact with a rake face 3 of the diamond cutting tool 2 and the rake face 3 is partially oxidized by the friction heat generated during the same time and the heat of the chip 4 itself which is heated at about 300.degree. to 400.degree. C., to produce a crater depth 5 as shown in FIG. 6. If the crater depth 5 is increased, it is hard for the chip 4 to slide on the rake face 3 and this tends to scratch the surface of the workpiece, thus resulting in deterioration of the surface smoothness thereof.

An edge part 7 of the diamond cutting tool 2 is also worn by the heat of friction with the workpiece 1 resulting in mechanical wearing as shown by 8 in FIG. 7, so that the cutting resistance is increased and a desired cutting precision is hardly obtained. In diamond dressers and wire drawing dies, similarly, a desired shape precision or wire drawing precision is hardly obtained by such wearing.

On the other hand, synthesis of a large-sized diamond single crystal used as a diamond cutting tool has generally been carried out by the temperature gradient method wherein a single crystal is grown on seed crystal, as disclosed, for example, in U.S. Pat. Nos. 3,297,407, 4,034,066 and 4,073,380 and Japanese Patent Laid-Open Publication No. 88289/1977. It has been known for a long time that the diamond single crystals synthesized by these methods contain nitrogen as an impurity from raw materials.

A technique of adding boron to synthetic diamond single crystals has hitherto been disclosed in U.S. Pat. Nos. 4,042,673 and 4,082,185. In this case, however, the addition of boron is carried out for the purpose of converting diamond into an n-type semiconductor or yielding blue color diamond for decoration, but no study as to the addition of boron has been made in the relationship with cutting properties in the field of tools.

Furthermore, there has been proposed a diamond single crystal whose resistivity is lowered by adding boron so as to provide a diamond tool in such a manner as to precisely work the diamond single crystal in a desired shape with a high efficiency through discharge working (Japanese Patent Laid-Open Publication No. 126003/1983), but this is not directed to improvement of the mechanical properties.

In the case of cutting a workpiece of aluminum, copper or plastics by a diamond cutting tool, for example, wearing of the edge part of the cutting tool has hitherto occurred during cutting so that the surface smoothness of the workpiece cut is deteriorated and the cutting resistance is increased, thus shortening the life of the cutting tool. Diamond dressers or wire drawing dies have similarly lost their useful life through wearing.

SUMMARY OF THE INVENTION

It is an object of the present invention to provide a diamond tool excellent in wear resistance, heat resistance and oxidation resistance.

It is another object of the present invention to provide a diamond tool with a decreased wear in cutting soft materials with a high precision, dressing a grinding wheel, drawing a wire, etc. and with an improved tool life as compared with that of the prior art.

It is a further object of the present invention to provide a synthetic diamond single crystal containing boron, suitable for use as, in particular, cutting tools, dressers, wire drawing dies, etc.

These objects can be attained by a diamond tool composed of a synthetic diamond single crystal containing boron and optionally nitrogen, preferably the content of boron being 0.1 to 500 ppm and that of nitrogen being 1 to 500 ppm.

BRIEF DESCRIPTION OF THE DRAWINGS

The accompanying drawings illustrate in detail the principle and merits of the present invention.

FIGS. 1 (a) and (b), FIGS. 2 (a) and (b) and FIGS. 3 (a) and (b) are respectively plan views and cross-sectional views of the diamond cutting tools of the present invention.

FIG. 4 is a cross-sectional view of a diamond cutting tool to illustrate the worn state thereof in Example 9, FIG. 5 is a cross-sectional view of a diamond cutting tool to illustrate the cutting state of the cutting tool, FIG. 6 is a cross-sectional view of a diamond cutting tool to show the crater depth and FIG. 7 is a cross-sectional view of a diamond cutting tool to show the edge wear.

FIG. 8 is a perspective view of a diamond dresser composed of a diamond single crystal according to the present invention to show the orientation thereof and FIG. 9 is a similar perspective view of a diamond wire drawing die.

DETAILED DESCRIPTION OF THE INVENTION

The inventors have made studies on the mechanism of occurrence of crater wear, or edge wear in a diamond cutting tool during cutting non-ferrous materials and plastics and have come to a conclusion that if the wear resistance, heat resistance and oxidation resistance of a diamond cutting tool are improved, the above described wear can be reduced to lengthen the life of the tool, and in a similar manner, the life of a single crystal diamond dresser or wire drawing die, which needs wear resistance, can be lengthened. Thus, we have conducted thorough research as to the relationship between the wear resistance, heat resistance and oxidation resistance of a synthetic diamond single crystal and the impurities contained therein, in particular, nitrogen and boron, which has hitherto not been apparent.

Consequently, it is found that when the synthetic diamond single crystal contains nitrogen, the wear resistance thereof is improved and when containing boron, the heat resistance and oxidation resistance are more improved than when containing no boron. Based on this finding, a diamond tool with a reduced tool wear, e.g. crater depth or edge wear, and with a longer life can be attained by simultaneously adding predetermined amounts of nitrogen and boron.

In the diamond cutting tool, for example, the tool wear can be reduced and its life can be lengthened by preventing the diamond material from oxidation wear due to wearing heat and mechanical wear caused by flowing of the chip at a high temperature and high speed, which occur during cutting a workpiece by the cutting tool, on the rake face, and by contact of the edge part with a finished surface.

Accordingly, the present invention provides a diamond tool composed of a synthetic diamond single crystal containing boron or boron and nitrogen, in general, the content of boron being 0.1 to 500 ppm, preferably 0.1 to 100 ppm, more preferably 10 to 100 ppm, and that of nitrogen being 1 to 500 ppm, preferably 3 to 100 ppm. The present invention aims at improving the wear resistance of the material of a synthetic diamond crystal by incorporating 1 to 500 ppm of nitrogen in the synthetic diamond crystal and improving the heat resistance and oxidation resistance thereof by incorporating 0.1 to 500 ppm of boron therein, thus lengthening the life of the diamond tool. If the content of nitrogen is less than 1 ppm, the wear resistance is too small and if the content of boron is less than 0.1 ppm, the heat resistance and oxidation resistance are too small, to maintain the effect of lengthening the life of the tool. On the other hand, if the content of nitrogen exceeds 500 ppm, the wear resistance is lowered and if the content of boron exceeds 500 ppm, the diamond single crystal is too brittle to work the edge part. Therefore, it is preferred to adjust the content of nitrogen to 1 to 500 ppm and that of boron to 0.1 to 500 ppm.

Improvement of the wear resistance can be found when the content of nitrogen is in the range of 1 to 500 ppm, but in a more preferable embodiment of the present invention, it is in the range of 3 to 100 ppm. When the content of nitrogen is less than 3 ppm, the growth speed of diamond is largely lowered by the presence of a nitrogen getter to suppress contamination with nitrogen and the production cost is increased by 5 times or more. When the content of nitrogen exceeds 100 ppm, a solvent metal tends to be incorporated in diamond single crystal as an impurity and accordingly, it is hard to obtain a good quality diamond single crystal suitable for use as a cutting tool. This means that the yield of a good quality diamond single crystal for use as a cutting tool is decreased and from an economical point of view, the production cost is increased by about 3 to 10 times, which is uneconomical.

The effects on the heat resistance and oxidation resistance can be found when the content of boron is in the range of 0.1 to 500 ppm. When the content of boron exceeds 500 ppm, the diamond single crystal is too brittle to work the edge part, and when exceeding 100 ppm, a solvent metal tends to be incorporated in the diamond single crystal as an impurity, as in the case of nitrogen, and accordingly, it is hard to obtain a good quality diamond single crystal for a cutting tool. In addition, because of lowering of the yield, the production cost is increased by about 3 to 10 times. In a more preferable embodiment of the present invention, therefore, the content of boron is in the range of 0.1 to 100 ppm, in particular, 10 to 100 ppm.

In the present invention, incorporation of boron and nitrogen in diamond single crystals is, for example, carried out by adding elementary boron and iron nitride respectively to raw materials used for the synthesis of diamond single crystals.

In the present invention, determination of boron is generally carried out by irradiating diamond with oxygen or argon ions to generate ions and subjecting the ions to a mass spectrometer using a Secondary Ion Mass Spectrometer (SIMS).

When using a cutting tool for cutting metallic materials, the cutting tool should preferably have low reactivity with a workpiece to be cut in addition to the above described wear resistance, because the temperature becomes very high at the contact point of the cutting tool with the workpiece.

Wear resisting tools such as wire drawing dies are generally used at or near room temperature because of using lubricants and thus the wear resistance at low temperatures is particularly important.

On the other hand, dressers are generally used for cutting materials containing high hardness materials such as grinding wheels, etc. Since the high hardness materials of this kind contain ordinarily fine powders, the dressers often encounter fine breakage and cannot be put to practical use. Therefore, diamond suitable for use as a dresser should be a material capable of resisting fine breakages.

It is found that the diamond single crystal of the present invention is capable of thoroughly satisfying the above described various properties.

The boron-containing or nitrogen and boron-containing synthetic diamond single crystal tool according to the present invention is more excellent in wear resistance, heat resistance and oxidation resistance than a nitrogen-free or boron-free diamond single crystal tool. In a cutting tool composed of the synthetic diamond single crystal of the present invention, therefore, the mechanical wearing due to friction with chips during cutting, and the wearing due to oxidation phenomenon can markedly be reduced and accordingly, such a cutting tool can effectively be applied to a use such that the life of the tool is lengthened by minimizing the tool wearing in the field of precision cutting tools, super-precision cutting tools, etc. Furthermore, in dressers and wire-drawing dies, the tool wearing due to mechanical contact and the oxidation of diamond material due to friction heat generated through contact of the tool with a finished surface can effectively be prevented by the use of the synthetic diamond single crystal of the present invention, thereby lengthening the life of the tool.

The following examples are given in order to illustrate the present invention in detail without limiting the same.

EXAMPLE 1

Four kinds of materials were used, i.e. a synthetic diamond single crystal containing 100 ppm of nitrogen and 300 ppm of boron, synthetic diamond single crystal containing 100 ppm of nitrogen and no boron, synthetic diamond single crystal containing no nitrogen but containing 300 ppm of boron, and synthetic diamond single crystal containing no nitrogen nor boron. Using these materials, super-precision cutting tools with a rake angle .beta. of 0.degree., relief angle .alpha. of 5.degree., edge width l of 1.2 mm, nose R of 0.4 mm, rake face 3 orientation of (110) plane and edge direction (orientation or direction towards the cutting edge) of <100> were prepared as shown in FIGS. 1 (a) and (b) and subjected to wet turning of the end surface of a workpiece of aluminum alloy A 5086-Japanese Industrial Standard-with an outer diameter of 150 mm, inner diameter of 20 mm and thickness of 30 mm under conditions of a cutting speed of 113 m/min (inner diameter)- 848 m/min (outer diameter), depth of cut of 0.01 mm and feed of 0.03 mm/rev until the surface roughness of the cut surface became 0.04 .mu.m Rmax, after which the life of the tool was evaluated. The test results are shown in Table 1:

TABLE 1______________________________________Cutting Distance Until Expired (km) Sample Con- Sample Con- Sample Con- Sample taining 100 taining 100 taining No ContainingTest ppm N and ppm N and N and 300 No NNo. 300 ppm B No B ppm B Nor B______________________________________1 890 490 750 4002 930 540 800 4303 1010 620 800 4904 990 590 700 2505 1080 450 850 300Aver- 980 538 780 374age______________________________________

EXAMPLE 2

Using a synthetic diamond single crystal containing 10 ppm of boron and synthetic diamond single crystal containing no boron, precision cutting tools with a rake angle .beta. of 2.degree., relief angle .alpha. of 5.degree., nose R of 1 mm, rake face 3 orientation of (100) plane and edge direction of <100> were prepared as shown in FIGS. 2 (a) and (b) and then subjected to wet turning of the end surface of a workpiece of no oxygen-containing copper with an outer diameter of 150 mm, inner diameter of 20 mm and thickness of 10 mm under conditions of a cutting speed of 113 m/min (inner diameter)-848 m/min (outer diamter), depth of cut of 0.005 mm and feed of 0.02 mm/rev until the surface roughness became 0.2 .mu.mRmax, after which the life of the tool was evaluated. The test results are shown in Table 2.

TABLE 2______________________________________Cutting Distance Until Expired (km)Test No. Sample Containing 10 ppm B Sample Containing No B______________________________________1 1250 5302 1000 3203 1430 2904 1320 4805 1150 410Average 1230 406______________________________________

EXAMPLE 3

Using a synthetic diamond single crystal containing 100 ppm of boron and synthetic diamond single crystal containing no boron superprecision cutting tools with a rake angle .beta. of 2.degree., relief angle .alpha. of 5.degree., edge width 1 of 1.2 mm, rake face orientation of (100) plane and edge direction of <110> were prepared as shown in FIGS. 3 (a) and (b) and then subjected to wet turning of the end surface of a workpiece of aluminum alloy A 5086 (commercial name) with an outer diameter of 150 mm, inner diameter of 20 mm and thickness of 30 mm under conditions of a cutting speed of 113 m/min (inner diameter)-848 m/min (outer diameter), depth of cut of 0.01 mm and feed of 0.03 mm/rev to give a cutting distance of 200 km, after which wearing .DELTA..gamma. of the edge part and crater depth .DELTA..alpha. of the rake face, as shown in FIG. 4, were measured. The test results are shown in Table 3:

TABLE 3______________________________________Wear Quantity of Edge of Cutting Tool Sample Containing Sample 100 ppm B Containing No BTest No. .DELTA..gamma. .DELTA..alpha. .DELTA..gamma. .DELTA..alpha.______________________________________1 0.05 0.1 0.30 1.52 0.07 0.2 0.45 1.93 0.06 0.1 0.32 3.04 0.10 0.3 0.21 1.85 0.09 0.3 0.29 2.7Average 0.07 0.2 0.31 2.2______________________________________

EXAMPLE 4

Using a synthetic diamond single crystal containing 0.05 ppm of boron and synthetic diamond single crystal containing no boron, super-precision cutting tools with a rake angle .beta. of 2.degree., relief angle .alpha. of 5.degree., edge width 1 of 1.2 mm, rake face orientation of (100) plane and edge direction of <110> were prepared and then subjected to wet cutting of the end surface of a workpiece of no oxygen-containing copper with an outer diameter of 150 mm, inner diameter of 20 mm and thickness of 10 mm under conditions of a cutting speed of 113 m/min (inner diameter)-848 m/min (outer diameter), depth of cut of 0.01 mm and feed of 0.02 mm/rev until the surface roughness of the cut surface became 0.03 .mu.m Rmax, after which the life of the tool was evaluated. The test results are shown in Table 4:

TABLE 4______________________________________Cutting Distance Until Expired SampleTest No. Containing 0.05 ppm B Sample Containing No B______________________________________1 530 4802 580 4503 460 2904 380 5805 550 600Average 500 480______________________________________

EXAMPLE 5

Using 4 kinds of a synthetic diamond single crystal containing 10 ppm of nitrogen and 1 ppm of boron, synthetic diamond single crystal containing 0.5 ppm of nitrogen and 1 ppm of boron, synthetic diamond single crystal containing 10 ppm of nitrogen and 0.05 ppm of boron, and synthetic diamond single crystal containing 0.5 ppm of nitrogen and 0.05 ppm of boron, super-precision cutting tools with a rake angle .beta. of 2.degree., relief angle .alpha. of 5.degree., nose R of 1 mm, rake face 3 orientation of (100) plane and edge direction of <100> were prepared as shown in FIGS. 2 (a) and (b) and then subjected to wet turning of the end surface of a workpiece of oxygen-free copper with an outer diameter of 150 mm, inner diameter of 20 mm and thickness of 10 mm under conditions of a cutting speed of 113 m/min (inner diameter)-848 m/min (outer diameter), depth of cut of 0.005 mm and feed of 0.02 mm/rev until the surface roughness of the cut surface became 0.2 .mu.m Rmax, after which the life of the tool was evaluated. The test results are shown in Table 5:

TABLE 5______________________________________Cutting Distance Until Expired Sample Sample Con- Sample Con- Sample Con- Containing taining 10 taining 10 taining 0.5 0.5 ppm NTest ppm N and ppm N and ppm N and and 0.05No. 1 ppm B 0.05 ppm B 1 ppm B ppm B______________________________________1 1450 720 1200 5102 1290 850 1130 3403 1320 630 1090 3004 1280 800 1210 4505 1470 780 1050 400Aver- 1362 756 1136 400age______________________________________

EXAMPLE 6

Using four kinds of materials, i.e. a synthetic diamond single crystal containing 50 ppm of nitrogen and 100 ppm of boron, synthetic diamond single crystal containing 50 ppm of nitrogen and 0.05 ppm of boron, synthetic diamond single crystal containing 0.5 ppm of nitrogen and 100 ppm of boron, and synthetic diamond single crystal containing 0.5 ppm of nitrogen and 0.05 ppm of boron, super-precision cutting tools with a rake angle .beta. of 2.degree., relief angle .alpha. of 5.degree., edge width 1 of 1.2 mm, rake face orientation of (100) plane and edge direction of <110> were prepared as shown in FIGS. 3 (a) and (b) and then subjected to wet turning of the end surface of a workpiece of aluminum alloy A 5086 with an outer diameter of 150 mm, inner diameter of 20 mm and thickness of 30 mm under conditions of a cutting speed of 113 m/min (inner diameter)-848 m/min (outer diameter), depth of cut of 0.01 mm and feed of 0.03 mm/rev to give a cutting distance of 200 km, after which wearing .DELTA..gamma. of the edge part and crater depth .DELTA..alpha. of the rake face, as shown in FIG. 4, were measured. The test results are shown in Table 6.

TABLE 6______________________________________Wear Quantity of Edge of Cutting Tool Sample Sample Sample Sample Con- Con- Con- Con- taining 50 taining 50 taining 0.05 taining 0.5 ppm N and ppm N and ppm N and ppm N andTest 100 ppm B 0.05 ppm B 100 ppm B 0.05 ppm BNo. .DELTA..gamma. .DELTA..alpha. .DELTA..gamma. .DELTA..alpha. .DELTA..gamma. .DELTA..alpha. .DELTA..gamma. .DELTA..alpha.______________________________________1 0.03 0.08 0.18 0.92 0.05 0.11 0.28 1.32 0.06 0.15 0.23 0.73 0.07 0.23 0.40 1.83 0.05 0.09 0.12 0.88 0.06 0.13 0.33 1.34 0.03 0.23 0.10 0.52 0.10 0.36 0.18 1.55 0.06 0.21 0.17 1.23 0.09 0.34 0.25 2.9Average 0.05 0.15 0.16 0.86 0.07 0.23 0.29 2.2______________________________________

EXAMPLE 7

Using 5 kinds of samples of synthetic diamond single crystals having varied contents of nitrogen and boron as shown in the following Table 7, super-precision diamond cutting tools 2 with a rake angle .beta. of 0.degree., relief angle .alpha. of 5.degree., edge part 7 width 1 of 1.2 mm, R of edge part 7 at both ends of 0.4 mm, rake face 3 orientation of (110) plane and edge direction of <100> were prepared as shown in FIG. 1 and then subjected to wet turning of the end surface of a workpiece of aluminum alloy A 5086 with an outer diameter of 150 mm, inner diameter of 20 mm and thickness of 30 mm under conditions of a cutting speed of 113 m/min (inner diameter)-848 m/min (outer diameter), depth of cut of 0.01 mm and feed of 0.03 mm/rev until the surface roughness of the cut surface became 0.04 .mu.m Rmax, after which the life of the tool was evaluated.

As to each of these samples, the cutting distances until the lives of the five diamond cutting tools were expired and average values thereof, and the production costs of the synthetic diamond single crystals of the diamond cutting tools were compared, based on Sample No. 1 as one preferred embodiment of the present invention, to give results shown in Table 7:

TABLE 7__________________________________________________________________________Cutting Distance Until Expired (km) Comparison ofSample No. 1 2 3 4 5 Average Production Costs__________________________________________________________________________1 1050 1110 960 930 920 994 1N 30 ppmB 50 ppm2 890 930 1010 990 1080 980 3N 100 ppmB 300 ppm3 520 440 470 620 530 516 3N 200 ppmB 0.05 ppm4 520 570 650 630 570 588 8N noB 50 ppm5 400 430 490 250 300 374 10N noB no__________________________________________________________________________

EXAMPLE 8

Using 5 kinds of samples of synthetic diamond single crystals having varied contents of nitrogen and boron as shown in the following Table 8, super-precision diamond cutting tools 2 with a rake angle .beta. of 2.degree., relief angle .alpha. of 5.degree., nose R of edge part 7 of 1 mm, rake face 3 orientation of (100) plane and edge direction of <100> were prepared as shown in FIG. 2 and then subjected to wet turning of the end surface of a workpiece of oxygen-free copper with an outer diameter of 150 mm, inner diameter of 20 mm and thickness of 10 mm under conditions of a cutting speed of 113 m/min (inner diameter)-848 m/min (outer diameter), depth of cut of 0.005 mm and feed of 0.02 mm/rev until the surface roughness of the cut surface became 0.2 .mu.m Rmax, after which the lives of the tools were evaluated.

As to each of these samples, the cutting distances until the lives of the five diamond cutting tools were expired and average values thereof, and the production costs of the synthetic diamond single crystals of the cutting tools were compared, based on Sample No. 6 as one preferred embodiment of the present invention, in a similar manner to Example 7, thus obtaining results as shown in Table 8. Results of determining impurities contained in Sample No. 6 are shown in Table 9.

TABLE 8__________________________________________________________________________Cutting Distance Until Expired (km) Comparison ofSample No. 1 2 3 4 5 Average Production Costs__________________________________________________________________________6 1450 1290 1320 1280 1470 1362 1N 10 ppmB 1 ppm7 480 530 620 390 470 498 6N 0.5 ppmB 800 ppm8 510 340 300 450 400 400 6N 0.5 ppmB 0.05 ppm9 280 230 350 140 190 238 8N 900 ppmB 800 ppm10 980 1400 1250 1310 1150 1218 4N 300 ppmB 0.2 ppm__________________________________________________________________________ TABLE 9______________________________________Impurities Contained Content (ppm)______________________________________Nitrogen 10Boron 1Iron 1Nickel 10Silicon 0.5Cobalt 0.1______________________________________

EXAMPLE 9

Using 5 kinds of samples of synthetic diamond single crystals having varied contents of nitrogen and boron as shown in the following Table 10, super-precision diamond cutting tools 2 with a rake angle .beta. of 0.degree., relief angle .alpha. of 5.degree., edge part 7 width 1 of 1.2 mm, rake face 3 orientation of (100) and edge direction of <100> were prepared as shown in FIG. 3 and then subjected to wet turning of the end surface of a workpiece of the same material and dimensions as those of Example 7 under the same conditions as in Example 7 to measure wearing .DELTA..gamma. of the edge part 7 and crater depth .DELTA..alpha. of the rake face 3 as shown in FIG. 4 at a cutting distance of 200 km as to the five samples. The results are shown in Table 10. In addition, the production costs of these synthetic diamond single crystals were compared, based on Sample No. 11 as one preferred embodiment of a present invention, in the similar manner to Example 7, thus obtaining results as shown in Table 10.

TABLE 10______________________________________ .DELTA..alpha. (lower Comparison.DELTA..gamma. (upper column, mm) ofcolumn, mm) Aver- ProductionSample No. 1 2 3 4 5 age Cost______________________________________11N 5 ppm 0.04 0.03 0.06 0.05 0.06 0.05 1B 80 ppm 0.10 0.13 0.22 0.15 0.20 0.1612N 400 ppm 0.05 0.08 0.04 0.06 0.08 0.06 5B 400 ppm 0.06 0.07 0.18 0.14 0.30 0.1513N 10 ppm 0.29 0.51 0.45 0.38 0.40 0.41 3B 800 ppm 0.71 0.58 0.81 0.67 0.78 0.7114N 2 ppm 0.04 0.07 0.09 0.08 0.07 0.07 5B 300 ppm 0.13 0.15 0.17 0.13 0.19 0.1515N 0.2 ppm 0.45 0.74 0.66 0.68 0.56 0.62 7B 0.2 ppm 1.02 0.95 0.88 1.10 1.08 1.01______________________________________

EXAMPLE 10

Using 5 kinds of samples of synthetic diamond single crystals having varied contents of nitrogen and boron as shown in the following Table 11, diamond dressers were prepared with the orientation shown in FIG. 8, in which an arrow shows the dressing direction, and then subjected to dressing of a grinding wheel of silicon carbide with a grain size of 400 mesh at a grinding wheel peripheral speed of 2000 m/min and dressing cut (depth of cut of dressing) of 0.02 mm/pass. After dressing 500 times, the wear quantity of diamond was determined.

As to each of these samples, the wear quantity of the single crystal diamond was determined and the production costs of the synthetic diamond single crystals were compared, based on Sample No. 1 as one preferred embodiment of the present invention, thus obtaining respectively results as shown in Table 11:

TABLE 11______________________________________Wear Quantity of Compari-Diamond (.times. 10.sup.-3 mm.sup.3) son of Aver- ProductionSample No. 1 2 3 4 5 age Cost______________________________________1 5.2 3.3 6.5 4.6 4.7 4.9 1N 30 ppmB 50 ppm2 6.5 6.6 5.7 4.4 3.2 5.3 3N 100 ppmB 300 ppm3 10.1 9.9 11.3 10.7 9.7 10.3 3N 200 ppmB 0.05 ppm4 8.7 11.2 9.1 9.8 10.5 9.9 8N noB 50 ppm5 13.8 14.4 13.5 15.2 15.5 14.5 10N noB no______________________________________

EXAMPLE 11

Using 5 kinds of samples of synthetic diamond single crystals having varied contents of nitrogen and boron as shown in Table 12, wire drawing dies were prepared with the orientation shown in FIG. 9 and then subjected to drawing of a copper wire of 0.08 mm in diameter, during which the quantity of the drawn wire was measured until the life of the die expired.

As to these samples, the quantity of the drawn wire by the three dies was determined and the production costs of the synthetic diamond crystals were compared, based on Sample No. 1 as one preferred embodiment of the present invention, thus obtaining respectively results as shown in Table 12.

TABLE 12______________________________________ Quantity of Drawn Wire (kg) Comparison ofSample No. 1 2 3 Average Production Costs______________________________________1 920 830 1120 957 1N 10 ppmB 1 ppm2 520 630 490 547 6N 0.5 ppmB 800 ppm3 530 550 400 493 6N 0.5 ppmB 0.05 ppm4 350 520 290 387 8N 900 ppmB 800 ppm5 860 790 1050 900 4N 300 ppmB 0.2 ppm______________________________________

Claims

1. A cutting tool comprising a shank to which a blank is fixed, wherein the blank is shaped in an edge by polishing a synthetic diamond single crystal containing 3 to 100 ppm of nitrogen and 0.1 to 100 ppm of boron.

2. A wire drawing die wherein the outer circumference of a blank is fixed to a metallic support, the blank being shaped in the die shape by polishing a synthetic diamond single crystal containing 3 to 100 ppm of nitrogen and 0.1 to 100 ppm of boron.

3. A dresser wherein a blank is fixed to a metallic support by burying the blank therein, the blank being shaped in a desired shape by polishing a synthetic diamond single crystal containing 3 to 100 ppm of nitrogen and 0.1 to 100 ppm of boron.